Pierre Deslongchamps - Publications

Affiliations: 
Chemistry Université de Sherbrooke, Sherbrooke, Québec, Canada 
Area:
Organic Chemistry
Website:
https://www.usherbrooke.ca/chimie/personnel/professeurs/professeurs/pierre-deslongchamps/

156 high-probability publications. We are testing a new system for linking publications to authors. You can help! If you notice any inaccuracies, please sign in and mark papers as correct or incorrect matches. If you identify any major omissions or other inaccuracies in the publication list, please let us know.

Year Citation  Score
2020 Deslongchamps G, Deslongchamps P. The Bent Bond / Antiperiplanar Hypothesis and the Chemical Reactivity of Annulenes. The Journal of Organic Chemistry. PMID 32501012 DOI: 10.1021/Acs.Joc.0C01069  1
2020 Parent JF, Deslongchamps G, Deslongchamps P. The Bent Bond / Antiperiplanar Hypothesis: Modulating the Reactivity and the Selectivity in the Glycosylation of Bicyclic Pyranoside Models. The Journal of Organic Chemistry. PMID 32068401 DOI: 10.1021/Acs.Joc.9B03412  1
2019 Parent JF, Bertrand X, Deslongchamps G, Deslongchamps P. Applying the Bent Bond / Antiperiplanar Hypothesis to the Stereoselective Glycosylation of Bicyclic Furanosides. The Journal of Organic Chemistry. PMID 31820643 DOI: 10.1021/Acs.Joc.9B02791  1
2019 Deslongchamps G, Deslongchamps P. Thermal rearrangement of optically active tetradeuterated 2-methoxymethyl-methylenecyclopropane and the bent bond/antiperiplanar hypothesis. Organic & Biomolecular Chemistry. PMID 31282912 DOI: 10.1039/C9Ob01030K  1
2018 Deslongchamps G, Deslongchamps P. Bent Bonds and the Antiperiplanar Hypothesis. A Model To Account for Sigmatropic [1, n]-Hydrogen Shifts. The Journal of Organic Chemistry. PMID 30041522 DOI: 10.1021/Acs.Joc.8B01472  1
2018 Deslongchamps G, Deslongchamps P. Bent Bonds (tau) and the Antiperiplanar Hypothesis - the Chemistry of Cyclooctatetraene and other C8H8 Isomers. The Journal of Organic Chemistry. PMID 29715429 DOI: 10.1021/Acs.Joc.8B00809  1
2018 Deslongchamps P, Parent JF. High Temperature Isomerization of Benzenoid Polycyclic Aromatic Hydrocarbons. An Analysis Through the Bent Bond and Antiperiplanar Hypothesis Orbital Model. The Journal of Organic Chemistry. PMID 29470083 DOI: 10.1021/Acs.Joc.8B00095  0.56
2016 Parent JF, Deslongchamps P. Bent bonds (τ) and the antiperiplanar hypothesis, and the reactivity at the anomeric center in pyranosides. Organic & Biomolecular Chemistry. PMID 27834970 DOI: 10.1039/C6Ob02263D  0.56
2016 Deslongchamps G, Deslongchamps P. Bent bonds and the antiperiplanar hypothesis - a simple model to rationalize [1,3]-sigmatropic alkyl shifts. Organic & Biomolecular Chemistry. PMID 27466079 DOI: 10.1039/C6Ob01139J  1
2014 Ravindar K, Caron PY, Deslongchamps P. Anionic polycyclization entry to tricycles related to quassinoids and terpenoids: a stereocontrolled total synthesis of (+)-cassaine. The Journal of Organic Chemistry. 79: 7979-99. PMID 25057897 DOI: 10.1021/Jo501122K  1
2014 Somaiah R, Ravindar K, Cencic R, Pelletier J, Deslongchamps P. Synthesis of the antiproliferative agent hippuristanol and its analogues from hydrocortisone via Hg(II)-catalyzed spiroketalization: structure-activity relationship. Journal of Medicinal Chemistry. 57: 2511-23. PMID 24588834 DOI: 10.1021/Jm401799J  1
2013 Ravindar K, Caron PY, Deslongchamps P. Total synthesis of (+)-cassaine utilizing an anionic polycyclization strategy. Organic Letters. 15: 6270-3. PMID 24295200 DOI: 10.1021/Ol4030937  1
2013 Nasr Z, Dow LE, Paquet M, Chu J, Ravindar K, Somaiah R, Deslongchamps P, Porco JA, Lowe SW, Pelletier J. Suppression of eukaryotic initiation factor 4E prevents chemotherapy-induced alopecia. Bmc Pharmacology & Toxicology. 14: 58. PMID 24219888 DOI: 10.1186/2050-6511-14-58  1
2013 Cencic R, Robert F, Galicia-Vázquez G, Malina A, Ravindar K, Somaiah R, Pierre P, Tanaka J, Deslongchamps P, Pelletier J. Modifying chemotherapy response by targeted inhibition of eukaryotic initiation factor 4A. Blood Cancer Journal. 3: e128. PMID 23872707 DOI: 10.1038/Bcj.2013.25  1
2013 Deslongchamps G, Deslongchamps P. Bent bonds and the antiperiplanar hypothesis as a simple model to predict Diels-Alder reactivity: Retrospective or perspective? Tetrahedron. 69: 6022-6033. DOI: 10.1016/J.Tet.2013.05.008  1
2011 Deslongchamps G, Deslongchamps P. Bent bonds, the antiperiplanar hypothesis and the theory of resonance. A simple model to understand reactivity in organic chemistry. Organic & Biomolecular Chemistry. 9: 5321-33. PMID 21687842 DOI: 10.1039/C1Ob05393K  1
2011 Ravindar K, Sridhar Reddy M, Deslongchamps P. A highly efficient access to spiroketals, mono-unsaturated spiroketals, and furans: Hg(II)-catalyzed cyclization of alkyne diols and triols. Organic Letters. 13: 3178-81. PMID 21604735 DOI: 10.1021/Ol201102X  1
2011 Ravindar K, Reddy MS, Lindqvist L, Pelletier J, Deslongchamps P. Synthesis of the antiproliferative agent hippuristanol and its analogues via Suárez cyclizations and Hg(II)-catalyzed spiroketalizations. The Journal of Organic Chemistry. 76: 1269-84. PMID 21268618 DOI: 10.1021/Jo102054R  1
2010 Ravindar K, Reddy MS, Lindqvist L, Pelletier J, Deslongchamps P. Efficient synthetic approach to potent antiproliferative agent hippuristanol via Hg(II)-catalyzed spiroketalization. Organic Letters. 12: 4420-3. PMID 20828120 DOI: 10.1021/Ol1019663  1
2010 Caron PY, Deslongchamps P. Versatile strategy to access tricycles related to quassinoids and triterpenes. Organic Letters. 12: 508-11. PMID 20055501 DOI: 10.1021/Ol902711B  1
2009 Marsault E, Hoveyda HR, Peterson ML, Gagnon R, Vézina M, Pinault JF, Landry A, Saint-Louis C, Ouellet LG, Beauchemin S, Benakli K, Beaubien S, Brassard M, Wang Z, Champagne M, ... ... Deslongchamps P, et al. High throughput solid phase parallel synthesis of macrocyclic peptidomimetics. Advances in Experimental Medicine and Biology. 611: 15-6. PMID 19400074 DOI: 10.1007/978-0-387-73657-0_7  1
2009 Reddy MS, Zhang H, Phoenix S, Deslongchamps P. Total synthesis of ouabagenin and ouabain. Chemistry, An Asian Journal. 4: 725-41. PMID 19294722 DOI: 10.1002/Asia.200800429  1
2009 Dory YL, Roy AL, Soucy P, Deslongchamps P. Study of very reactive tautomeric phenol dienones as dienes in Diels-Alder reactions. Organic Letters. 11: 1197-200. PMID 19228005 DOI: 10.1021/Ol8026768  1
2008 Phoenix S, Reddy MS, Deslongchamps P. Total synthesis of (+)-cassaine via transannular Diels-Alder reaction. Journal of the American Chemical Society. 130: 13989-95. PMID 18817389 DOI: 10.1021/Ja805097S  1
2008 Marsault E, Hoveyda HR, Gagnon R, Peterson ML, Vézina M, Saint-Louis C, Landry A, Pinault JF, Ouellet L, Beauchemin S, Beaubien S, Mathieu A, Benakli K, Wang Z, Brassard M, ... ... Deslongchamps P, et al. Efficient parallel synthesis of macrocyclic peptidomimetics. Bioorganic & Medicinal Chemistry Letters. 18: 4731-5. PMID 18640834 DOI: 10.1016/J.Bmcl.2008.06.085  1
2008 Zhang H, Sridhar Reddy M, Phoenix S, Deslongchamps P. Total synthesis of ouabagenin and ouabain. Angewandte Chemie (International Ed. in English). 47: 1272-5. PMID 18183567 DOI: 10.1002/Anie.200704959  1
2006 Caussanel F, Wang K, Ramachandran SA, Deslongchamps P. Synthetic approach toward the total synthesis of kempane diterpenes via transannular Diels-Alder strategy. The Journal of Organic Chemistry. 71: 7370-7. PMID 16958532 DOI: 10.1021/Jo061230K  1
2006 Ramachandran SA, Kharul RK, Lepage O, Marque S, Soucy P, Jacques F, Chênevert R, Deslongchamps P. Synthetic studies toward highly functionalized 5beta-lanosterol derivatives: a versatile approach utilizing anionic cycloaddition. The Journal of Organic Chemistry. 71: 6149-56. PMID 16872199 DOI: 10.1021/Jo0608725  1
2006 Beaubien S, Deslongchamps P. Total synthesis of 14β-fluorosteroids via a transannular Diels-Alder reaction Canadian Journal of Chemistry. 84: 29-48. DOI: 10.1139/V05-259  1
2006 Canesi S, Berthiaume G, Deslongchamps P. Novel synthetic strategy towards taxol by macrocyclization reaction - Conformational requirement of ring A European Journal of Organic Chemistry. 3681-3686. DOI: 10.1002/Ejoc.200600284  1
2005 Chen L, Deslongchamps P. Studies towards the total synthesis of ouabagenin Canadian Journal of Chemistry. 83: 728-740. DOI: 10.1139/V05-042  1
2004 Deslongchamps P, Li S, Dory YL. Hydrolysis of alpha- and beta-glycosides. New experimental data and modeling of reaction pathways. Organic Letters. 6: 505-8. PMID 14961609 DOI: 10.1021/Ol036220+  1
2004 Trudeau S, Deslongchamps P. Novel synthesis of highly functionalized 14-beta-hydroxysteroids related to batrachotoxin and ouabain. The Journal of Organic Chemistry. 69: 832-8. PMID 14750812 DOI: 10.1021/Jo0355606  1
2003 Soucy P, L'Heureux A, Toró A, Deslongchamps P. Pyranophane transannular diels-alder approach to (+)-chatancin: a biomimetic asymmetric total synthesis. The Journal of Organic Chemistry. 68: 9983-7. PMID 14682691 DOI: 10.1021/Jo035193Y  1
2003 Caussanel F, Deslongchamps P, Dory YL. Comparative effects of conjugated and deconjugated isomeric enones on the transannular Diels-Alder reaction. Organic Letters. 5: 4799-802. PMID 14653677 DOI: 10.1021/Ol035791Z  1
2003 Toró A, Deslongchamps P. Furanophane transannular Diels-Alder approach to (+)-chatancin: an asymmetric total synthesis of (+)-anhydrochatancin. The Journal of Organic Chemistry. 68: 6847-52. PMID 12946121 DOI: 10.1021/Jo034123O  1
2003 Guay B, Deslongchamps P. Cascade polycyclization: exploration of a convergent route to access various tricyclic and tetracyclic products related to sterols. The Journal of Organic Chemistry. 68: 6140-8. PMID 12895042 DOI: 10.1021/Jo034280N  1
2003 Bourque E, Deslongchamps P, Dory YL. First experimental and theoretical evidence of a deactivating enone dienophile in the transannular Diels-Alder reaction. The Journal of Organic Chemistry. 68: 2390-7. PMID 12636407 DOI: 10.1021/Jo0265129  1
2003 Lepage O, Deslongchamps P. New strategy for convergent steroid synthesis. The Journal of Organic Chemistry. 68: 2183-6. PMID 12636378 DOI: 10.1021/Jo026676P  1
2003 Trudeau S, Deslongchamps P. Novel synthesis of a highly functionalized cyclopropane derivative Canadian Journal of Chemistry. 81: 1003-1011. DOI: 10.1139/V03-119  1
2003 Bilodeau F, Dubé L, Deslongchamps P. New approach toward the total synthesis of (+)-aphidicolin by tandem transannular Diels-Alder/aldol strategy Tetrahedron. 59: 2781-2791. DOI: 10.1016/S0040-4020(03)00372-7  1
2003 Rouillard A, Bonin MA, Deslongchamps P. Enantioselective Synthesis of a Polyfunctionalized Tetracycle Related to Pentacyclic Triterpenes by Using an Anionic Cycloaddition Reaction Helvetica Chimica Acta. 86: 3730-3739. DOI: 10.1002/Hlca.200390315  1
2002 Yang Z, Shannon D, Truong VL, Deslongchamps P. Studies directed toward asymmetric synthesis of cardioactive steroids via anionic polycyclization. Organic Letters. 4: 4693-6. PMID 12489963 DOI: 10.1021/Ol027125O  1
2002 Chapdelaine D, Belzile J, Deslongchamps P. A convergent synthesis of the cardenolide skeleton: intramolecular aldol condensation via reduction of alpha-bromoketones. The Journal of Organic Chemistry. 67: 5669-72. PMID 12153266 DOI: 10.1021/Jo025612B  1
2002 Fortin S, Dupont F, Deslongchamps P. A new bis(2,2,2-trifluoroethyl)phosphonate for the synthesis of Z-unsaturated N-methoxy-N-methylamides. The Journal of Organic Chemistry. 67: 5437-9. PMID 12126448 DOI: 10.1021/Jo025816S  1
2002 Germain J, Deslongchamps P. Total synthesis of (+/-)-momilactone A. The Journal of Organic Chemistry. 67: 5269-78. PMID 12126415 DOI: 10.1021/Jo025873L  1
2002 Lepage O, Stone C, Deslongchamps P. Nazarov reagents for convergent and expedient synthesis of new steroids. Organic Letters. 4: 1091-4. PMID 11922790 DOI: 10.1021/Ol017274R  1
2002 Chantigny YA, Dory YL, Toró A, Deslongchamps P. Use of the transannular Diels-Alder (TADA) reaction to probe biological receptors: Rational design and synthesis of tricyclic TADA adducts capable of rigidly holding pharmacophore parts Canadian Journal of Chemistry. 80: 875-884. DOI: 10.1139/V02-064  1
2002 Rouillard A, Deslongchamps P. Synthesis of a pentacyclic lactone related to quinovaic acid and emmolactone using an anionic polycyclization strategy Tetrahedron. 58: 6555-6560. DOI: 10.1016/S0040-4020(02)00665-8  1
2001 Fortin S, Barriault L, Dory YL, Deslongchamps P. Theoretical and experimental determination of the effects governing the transannular Diels-Alder reaction of trans-trans-cis systems with or without activation of the dienophile. Journal of the American Chemical Society. 123: 8210-6. PMID 11516271 DOI: 10.1021/Ja0109491  1
2001 Fortin D, Gaudette F, Marsault E, Deslongchamps P. Total synthesis of 3-azasteroids via the transannular Diels-Alder strategy Tetrahedron. 57: 4167-4177. DOI: 10.1016/S0040-4020(01)00290-3  1
2001 Marsault E. The transannular Diels-Alder strategy: Applications to total synthesis Tetrahedron. 57: 4243-4260. DOI: 10.1016/S0040-4020(01)00121-1  0.84
2000 Phoenix S, Bourque E, Deslongchamps P. Progress toward the total synthesis of cassaine via the transannular diels-alder strategy Organic Letters. 2: 4149-52. PMID 11150186 DOI: 10.1021/Ol006670R  1
2000 Ramaseshan M, Dory YL, Deslongchamps P. Solid phase combinatorial synthesis of a library of macro-heterocycles and related acyclic compounds. Journal of Combinatorial Chemistry. 2: 615-23. PMID 11126291 DOI: 10.1021/Cc000030Y  1
2000 Bélanger G, Deslongchamps P. New approach to aphidicolin and total asymmetric synthesis of unnatural (11R)-(-)-8-epi-11-hydroxyaphidicolin by tandem transannular Diels-Alder/aldol reactions. The Journal of Organic Chemistry. 65: 7070-4. PMID 11031030 DOI: 10.1021/Jo0007635  1
2000 Marsault E, Deslongchamps P. Increasing the efficiency of the transannular diels-alder strategy via stille macrocyclizations Organic Letters. 2: 3317-20. PMID 11029199 DOI: 10.1021/Ol000209H  1
2000 Toró A, L'Heureux A, Deslongchamps P. Transannular Diels-Alder studies on the asymmetric total synthesis of chatancin: the pyranophane approach. Organic Letters. 2: 2737-40. PMID 10964353 DOI: 10.1021/Ol006220Z  1
2000 Magaud D, Dolmazon R, Anker D, Doutheau A, Dory YL, Deslongchamps P. Differential reactivity of alpha- and beta-anomers of glycosyl acceptors in glycosylations. A remote consequence of the endo-anomeric effect? Organic Letters. 2: 2275-7. PMID 10930262 DOI: 10.1021/Ol006039Q  1
2000 Bélanger G, Deslongchamps P. Total asymmetric synthesis of the aphidicolin derivative (11R)-(-)-8-epi-11-hydroxyaphidicolin using tandem transannular Diels-Alder/aldol reactions. Organic Letters. 2: 285-7. PMID 10814303 DOI: 10.1021/Ol990341L  1
2000 Li S, Dory YL, Deslongchamps P. On the relative rate of hydrolysis of a series of ketals and their proton affinities Israel Journal of Chemistry. 40: 209-215. DOI: 10.1560/Qrh5-Q3N0-0Xa6-Pt9Y  1
2000 Chapdelaine D, Dube P, Deslongchamps P. A new allylidene phosphorane reagent for the efficient conversion of aldehydes to γ,δ-unsaturated allyl β-ketoesters Synlett. 1819-1821. DOI: 10.1055/S-2000-8701  1
2000 Soucy P, Dory YL, Deslongchamps P. Use of malonate connectors in Solid Phase Organic Chemistry. Application to the synthesis of macrocarbocycles Synlett. 1123-1126. DOI: 10.1055/S-2000-6750  1
2000 Toro A, Nowak P, Deslongchamps P. Transannular Diels-Alder entry into stemodanes: First asymmetric total synthesis of (+)-maritimol [10] Journal of the American Chemical Society. 122: 4526-4527. DOI: 10.1021/Ja000728F  1
2000 Gagnon R, Dory YL, Deslongchamps P. Solid-phase synthesis of hydroxy-acids leading to macrolactones Tetrahedron Letters. 41: 4751-4755. DOI: 10.1016/S0040-4039(00)00711-5  1
2000 Ramaseshan M, Ellingboe JW, Dory YL, Deslongchamps P. Design of an organic sequence suitable for the solid phase combinatorial synthesis of libraries of macro-heterocycles Tetrahedron Letters. 41: 4743-4749. DOI: 10.1016/S0040-4039(00)00710-3  1
2000 Ramaseshan M, Robitaille M, Ellingboe JW, Dory YL, Deslongchamps P. Design and synthesis of macro-heterocycles structurally related to tirofiban Tetrahedron Letters. 41: 4737-4742. DOI: 10.1016/S0040-4039(00)00709-7  1
2000 Lavoie R, Ouellet SG, Dallaire C, Dory YL, Toró A, Deslongchamps P. Transannular Diels-Alder studies of 14-membered cis-trans-trans macrocyclic trienes having allylic ether or enone dienophile Tetrahedron. 56: 5509-5522. DOI: 10.1016/S0040-4020(00)00455-5  1
2000 Deslongchamps P, Dory YL, Li S. The relative rate of hydrolysis of a series of acyclic and six-membered cyclic acetals, ketals, orthoesters, and orthocarbonates Tetrahedron. 56: 3533-3537. DOI: 10.1016/S0040-4020(00)00270-2  1
1999 Toró A, Deslongchamps P. Facile synthesis of methyl 2-formyl-5-hydroxymethyl-3-furancarboxylate Synthetic Communications. 29: 2317-2321. DOI: 10.1080/00397919908086234  1
1999 Bourque E, Grenon M, Laliberté S, Deslongchamps P. Macrocyclic studies of EZ and ZZ 12-membered aza macrocycles; Novel molecular rearrangement observed Synlett. 1115-1117. DOI: 10.1055/S-1999-2772  1
1999 Germain J, Deslongchamps P. Transannular Diels-Alder approach to the synthesis of Momilactone A Tetrahedron Letters. 40: 4051-4054. DOI: 10.1016/S0040-4039(99)00669-3  1
1999 Toró A, Wang Y, Drouin M, Deslongchamps P. Transannular Diels-Alder model studies on the total synthesis of chatancin. The furanophane approach. Part 2 [1]: Macrocyclization and Diels- Alder reaction Tetrahedron Letters. 40: 2769-2772. DOI: 10.1016/S0040-4039(99)00324-X  1
1999 Toró A, Wang Y, Deslongchamps P. Transannular Diels-Alder model studies on the total synthesis of chatancin. The furanophane approach. Part 1: Assembly of the acyclic substrates Tetrahedron Letters. 40: 2765-2768. DOI: 10.1016/S0040-4039(99)00323-8  1
1999 Lavoie R, Toró A, Deslongchamps P. Synthesis of chiral trans-syn-cis and trans-anti-trans [6.6.6] tricycles by trans-annular Diels-Alder reaction Tetrahedron. 55: 13037-13050. DOI: 10.1016/S0040-4020(99)00796-6  1
1999 Toró A, Lemelin CA, Préville P, Bélanger G, Deslongchamps P. Transannular Diels-Alder studies on the asymmetric synthesis of (+)- maritimol Tetrahedron. 55: 4655-4684. DOI: 10.1016/S0040-4020(99)00128-3  1
1998 Drouin M, Couturier M, Deslongchamps P. Crystallographic evidence of [1,5]prototropic shifts occurring upon transannular diels-alder reaction of a 14-membered macrocycle leading to a 5α-steroid skeleton Acta Crystallographica Section C: Crystal Structure Communications. 54: 256-261. DOI: 10.1107/S0108270197013310  1
1998 Chantigny Y, Toró A, Lemelin CA, Deslongchamps P. Macrocyclization of terminal bis-allylic chlorides via an intramolecular gem-dialkylation of malononitrile or methyl cyanoacetate Tetrahedron Letters. 39: 7839-7840. DOI: 10.1016/S0040-4039(98)01722-5  1
1998 Couturier M, Dory YL, Fortin D, Rouillard A, Deslongchamps P. Ab initio and semiempirical corroboration of the observed stereoselectivity in the transannular Diels-Alder reaction leading to steroids Tetrahedron. 54: 10089-10110. DOI: 10.1016/S0040-4020(98)00600-0  1
1998 Couturier M, Dory YL, Rouillard F, Deslongchamps P. Studies directed towards the total synthesis of aldosterone and naturally occurring analogues. A unified approach using the transannular Diels-Alder reaction Tetrahedron. 54: 1529-1562. DOI: 10.1016/S0040-4020(97)10393-3  1
1998 Dory YL, Hall DG, Deslongchamps P. On the mechanism of the Diels-Alder reaction of enal dienophiles. Competitive reactivity and ab initio calculations using a transannular probe Tetrahedron. 54: 12279-12288.  1
1997 Welch W, Williams AJ, Tinker A, Mitchell KE, Deslongchamps P, Lamothe J, Gerzon K, Bidasee KR, Besch HR, Airey JA, Sutko JL, Ruest L. Structural components of ryanodine responsible for modulation of sarcoplasmic reticulum calcium channel function. Biochemistry. 36: 2939-50. PMID 9062124 DOI: 10.1021/Bi9623901  1
1997 Drouin M, Couturier M, Deslongchamps P. Diastereoselectivity in the transannular Diels-Alder reaction of a trans-trans-trans 14-membered macrocycle leading to steroids Acta Crystallographica, Section C: Crystal Structure Communications. 53: 1698-1701. DOI: 10.1107/S0108270197009578  1
1997 Ouellet L, Langlois P, Deslongchamps P. Synthesis of a 14β-Hydroxysteroid Using the Transannular Diels-Alder Strategy Synlett. 1997: 689-690. DOI: 10.1055/S-1997-3255  1
1997 Barriault L, Quellet SG, Deslongchamps P. Transannular Diels-Alder reaction studies with an activated dienophile. An enantioselective synthesis of an A.B.C.[6.6.6.] trans-syn-cis tricycle Tetrahedron. 53: 14937-14956. DOI: 10.1016/S0040-4020(97)00997-6  1
1997 Miljkovi? M, Yeagley D, Deslongchamps P, Dory YL. Experimental and Theoretical Evidence of Through-Space Electrostatic Stabilization of the Incipient Oxocarbenium Ion by an Axially Oriented Electronegative Substituent during Glycopyranoside Acetolysis Journal of Organic Chemistry. 62: 7597-7604.  1
1997 Deslongchamps P, Jones PG, Li S, Kirby AJ, Kuusela S, Ma Y. Stereoelectronic effects on reactivity. Crystal-structure-reactivity correlations for acetals with synperiplanar lone pairs Journal of the Chemical Society. Perkin Transactions 2. 2621-2626.  1
1997 Drouin M, Hall DG, Caillé AS, Deslongchamps P. Unique trans-syn-cis [6.6.7] tricycle derivative from transannular Diels-Alder contraction of a model 15-membered trans-cis-cis macrocyclic triene Acta Crystallographica Section C: Crystal Structure Communications. 53: 1490-1493.  1
1996 Hall DG, Deslongchamps P. Transannular Diels-Alder/Intramolecular Aldol Tandem Reaction as a Stereocontrolled Route to (+)-Aphidicolin and its Isosteric C8-Epimer. The Journal of Organic Chemistry. 61: 2914. PMID 11667138 DOI: 10.1021/Jo9640027  1
1996 Tinker A, Sutko JL, Ruest L, Deslongchamps P, Welch W, Airey JA, Gerzon K, Bidasee KR, Besch HR, Williams AJ. Electrophysiological effects of ryanodine derivatives on the sheep cardiac sarcoplasmic reticulum calcium-release channel. Biophysical Journal. 70: 2110-9. PMID 9172735 DOI: 10.1016/S0006-3495(96)79777-1  1
1996 Deslongchamps P, Dory YL, Li S. Hydrolysis of isomeric tricyclic orthoesters and AM1 molecular modelling of the reaction pathway further evidence for stereoelectronic control Heterocycles. 42: 617-624. DOI: 10.3987/Com-95-S52  1
1996 Drouin M, Couturier M, Crevisy C, Dory YL, Deslongchamps P. Two 14-membered macrocycles with trans-trans and trans-cis dienes. Trimethyl (2E,4E)-cis- and trimethyl (2Z,4E)-trans-11,15-dioxobicyclo[12.3.0]heptadeca-2,4-diene-7,7,14- tricarboxylate Acta Crystallographica Section C: Crystal Structure Communications. 52: 2084-2087. DOI: 10.1107/S0108270195016817  1
1996 Drouin M, Berthiaume G, Deslongchamps P. 14-membered macrocycles: Methyl trans-(10E)-5-methyl-8-methylene-11,15-dioxobicyclo[12.3.0]heptadec-4-ene-14- carboxylate, (I), and methyl trans-(2E,10E)-10-methyl-7-methylene-4,17-dioxobicyclo[12.3.0]-heptadeca-2,10- diene-1-carboxylate, (II) Acta Crystallographica Section C: Crystal Structure Communications. 52: 107-110. DOI: 10.1107/S0108270195010092  1
1996 Couturier M, Deslongchamps P. Expedient Synthesis of a 5α-Steroid Using the Transannular Diels-Alder Strategy Synlett. 1996: 1140-1142. DOI: 10.1055/S-1996-5686  1
1996 Li S, Dory YL, Deslongchamps P. Hydrolysis of cyclic orthoesters: Experimental observations and theoretical rationalization Tetrahedron. 52: 14841-14854. DOI: 10.1016/0040-4020(96)00915-5  1
1996 Deslongchamps P, Dory YL, Li S. 5. Formation of cyclic ketals from hydroxyalkyl enol ethers, a stereoelectronically controlled endo-trig-cyclizatitm process Helvetica Chimica Acta. 79: 41-50.  1
1995 Dory YL, Soucy P, Drouin M, Deslongchamps P. Experimental and semiempirical calculation studies of transannular Diels-Alder and other competing pericyclic reactions Journal of the American Chemical Society. 117: 518-529. DOI: 10.1021/Ja00106A060  1
1995 Berthiaume G, Deslongchamps P. Formation of 14-membered carbocycles by intramolecular Michael reaction of cyclic β-ketoesters on enones and ynones Bulletin De La Societe Chimique De France. 132: 371-383.  1
1995 Crévisy C, Couturier M, Dugave C, Dory YL, Deslongchamps P. Studies on the formation of 14-membered macrocycles by intramolecular Michael addition Bulletin De La Societe Chimique De France. 132: 360-370.  1
1995 Hall DG, Caille AS, Drouin M, Lamothe S, Muller R, Deslongchamps P. A stereospecific transannular Diels-Alder approach to the [6.6.7] tricyclic skeleton related to aphidicolin and scopadulan natural products Synthesis. 1081-1088.  1
1994 Welch W, Ahmad S, Airey JA, Gerzon K, Humerickhouse RA, Besch HR, Ruest L, Deslongchamps P, Sutko JL. Structural determinants of high-affinity binding of ryanoids to the vertebrate skeletal muscle ryanodine receptor: a comparative molecular field analysis. Biochemistry. 33: 6074-85. PMID 8193121 DOI: 10.1021/Bi00186A006  1
1994 Li S, Deslongchamps P. Experimental evidence for the stereoelectronically controlled hydrolysis of orthocarbonates Tetrahedron Letters. 35: 5641-5644. DOI: 10.1016/S0040-4039(00)77268-6  1
1993 Deslongchamps P. Intramolecular strategies and stereoelectronic effects. Glycosides hydrolysis revisited Pure and Applied Chemistry. 65: 1161-1178. DOI: 10.1351/pac199365061161  1
1993 Xu YC, Roughton AL, Soucy P, Plante R, Goldstein S, Deslongchamps P. Stereocontrolled construction of 1, 7-dimethyl A.B.C.[6.6.6] tricycles. Part II. transannular Diels-Alder reaction of 14-membered macrocycles containing m-dienophiles Canadian Journal of Chemistry. 71: 1169-1183. DOI: 10.1139/v93-153  1
1993 Xu YC, Roughton AL, Plante R, Goldstein S, Deslongchamps P. Stereocontrolled construction of 1, 7-dimethyl A.B.C.[6.6.6] tricycles. Part I. transannular Diels-Alder reactions of 14-membered macrocycles containing frans-dienophiles Canadian Journal of Chemistry. 71: 1152-1168. DOI: 10.1139/V93-152  1
1993 Ruest L, Deslongchamps P. Ryanoids and related compounds. A total synthesis of 3-epiryanodine Canadian Journal of Chemistry. 71: 634-638. DOI: 10.1139/V93-084  1
1993 Li S, Deslongchamps P. Experimental evidence for a synperiplanar stereoelectronic effect in the ozonolysis of a tricyclic acetal Tetrahedron Letters. 34: 7759-7762. DOI: 10.1016/S0040-4039(00)61559-9  1
1993 Li S, Kirby AJ, Deslongchamps P. First experimental evidence for a synperiplanar stereoelectronic effect in the acid hydrolysis of acetal Tetrahedron Letters. 34: 7757-7758. DOI: 10.1016/S0040-4039(00)61558-7  1
1992 Deslongchamps P. Transannular Diels-Alder reaction on macrocycles. a general strategy for the synthesis of polycyclic compounds Pure and Applied Chemistry. 64: 1831-1847. DOI: 10.1351/Pac199264121831  1
1992 Marinier A, Deslongchamps P. Stereocontrolled chiral synthesis of a trans-anti-trans tricycle by a transannular Diels-Alder reaction Canadian Journal of Chemistry. 70: 2350-2364. DOI: 10.1139/V92-297  1
1992 Quimpere M, Ruest L, Deslongchamps P. Transannular Diels-Alder cyclization of a substituted 13-membered macrocyclic triene. An approach to the A.B.C.[6.6.5] rings of the Veratrum alkaloids Canadian Journal of Chemistry. 70: 2335-2349. DOI: 10.1139/V92-296  1
1992 Ruel R, Deslongchamps P. Stereocontrolled synthesis of optically active 14β-hydroxy steroids and other steroid derivatives Canadian Journal of Chemistry. 70: 1939-1949. DOI: 10.1139/V92-243  1
1992 Quimpere M, Ruest L, Deslongchamps P. Synthesis and transannular Diels-Alder reaction of a 13-membered macrocyclic triene. A synthetic approach towards the tricyclic part A.B.C.[6.6.5] of the veratrum alkaloids Synthesis. 132-140. DOI: 10.1055/S-1992-34151  1
1992 Hall DG, Müller R, Deslongchamps P. Transannular diels-alder reaction of trans-trans-cis 15-membered macrocyclic trienes. Evidence for asynchronous transition state. Tetrahedron Letters. 33: 5221-5224. DOI: 10.1016/S0040-4039(00)79137-4  1
1992 Hall DG, Müller R, Deslongchamps P. Transannular diels-alder reaction of trans-trans-trans 15-membered macrocyclic trienes Tetrahedron Letters. 33: 5217-5220. DOI: 10.1016/S0040-4039(00)79136-2  1
1991 Deslongchamps P. Transannular Diels-Alder reaction on macrocycles: A general strategy for the synthesis of polycyclic compounds Aldrichimica Acta. 24: 43-56.  1
1990 Drouin M, Soucy P, Deslongchamps P, Michel AG. Functionalized hydrocarbons with condensed ring skeletons. X. A methyltricyclo[7.4.0.0(2,6)]tetradec-7-ene. Acta Crystallographica. Section C, Crystal Structure Communications. 46: 2411-3. PMID 2085419 DOI: 10.1107/S0108270190003092  1
1990 Ruel R, Deslongchamps P. Synthesis of 14-hydroxy steroids. Total synthesis of methyc 14β-hydroxy-1,7,17-trioxo-5β,8-androstene-10β-oate and related compounds Canadian Journal of Chemistry. 68: 1917-1922. DOI: 10.1139/V90-296  1
1990 Bérub́e G, Deslongchamps P. Synthesis and transannular Diels-Alder reaction of a 13-membered macrocyclic triene having a tetrasubstituted enol ether as dienophile Canadian Journal of Chemistry. 68: 404-411. DOI: 10.1139/V90-062  1
1990 Deslongchamps P, Belanger A, Berney DJF, Borschberg HJ, Brousseau r, Doutheau A, Durand R, Katayama H, Lapalme R, Leturc DM, Liao CC, MacLachlan FN, Maffrand JP, Marazza F, Martino R, et al. The total synthesis of (+)-ryanodol. Part III. Preparation of (+)-anhydroryanodol from a key pentacyclic intermediate Canadian Journal of Chemistry. 68: 153-185. DOI: 10.1139/V90-023  1
1990 Deslongchamps P, Belanger A, Berney JF, Borschberg HJ, Brousseau R, Doutheau A, Durand R, Katayama H, Lapalme R, Leturc DM, Liao CC, MacLachlan FN, Maffrand JP, Marazza F, Martino R, et al. The total synthesis of (+)-ryanodol. Part II. Model studies for rings B and C of (+)-anhydroryanodol. Preparation of a key pentacyclic intermediate Canadian Journal of Chemistry. 68: 127-152. DOI: 10.1139/V90-022  1
1990 Spino C, Deslongchamps P. Highly stereoselective double michael cyclization of 1-phenylsulfinyl and sulfonyl analogues of the nazarov reagent Tetrahedron Letters. 31: 3969-3972. DOI: 10.1016/S0040-4039(00)94474-5  1
1990 Ruel R, Deslongchamps P. Synthesis of an optically active 13β-methyl 14β-hydroxy steroid via base-catalyzed reactions Tetrahedron Letters. 31: 3961-3964. DOI: 10.1016/S0040-4039(00)94472-1  1
1989 Roberge JY, Deslongchamps P. Synthesis Of (Z)- and (E)-3,4-Dimethyl-Hex-3-Ene-L,6-Diols Synthetic Communications. 19: 817-827. DOI: 10.1080/00397918908050999  1
1988 Marinier A, Deslongchamps P. Stereocontrolled synthesis of a trans-anti-trans tricycle via a transannular Diels-Alder strategy Tetrahedron Letters. 29: 6215-6218. DOI: 10.1016/S0040-4039(00)82308-4  1
1988 Lavallée JF, Deslongchamps P. One-step construction of a 13α-methyl 14α-hydroxy steroid via a new anionic polycyclization method Tetrahedron Letters. 29: 6033-6036. DOI: 10.1016/S0040-4039(00)82257-1  1
1988 Lamothe S, Ndibwami A, Deslongchamps P. Transannular Diels-Alder reaction of 14-membered macrocyclic trienes. Part II: Experimental results and synthetic potential Tetrahedron Letters. 29: 1641-1644. DOI: 10.1016/S0040-4039(00)82006-7  1
1988 Lamothe S, Ndibwami A, Deslongchamps P. Transannular Diels-Alder reaction of 14-membered macrocyclic trienes. Part I: Theoretical analysis and stereochemical predictions Tetrahedron Letters. 29: 1639-1640. DOI: 10.1016/S0040-4039(00)82005-5  1
1988 Lavallée JF, Deslongchamps P. Synthesis of cis-decalin via diels-alder and double michael cycloaddition with substituted nazarov reagent Tetrahedron Letters. 29: 5117-5118. DOI: 10.1016/S0040-4039(00)80694-2  1
1987 Brillon D, Deslongchamps P. Synthesis of 11- and 12-membered rings by a direct cyclization method Canadian Journal of Chemistry. 65: 43-55. DOI: 10.1139/V87-010  1
1987 Deslongchamps P, Lamothe S, Lin H. A simple and direct method of cyclization for the synthesis of 10membered rings Canadian Journal of Chemistry. 65: 1298-1307. DOI: 10.1139/V84-412  1
1987 Bérubé G, Deslongchamps P. Synthesis and transannular diels-alder reaction of a 13-membered macrocyclic triene having a tetrasubstituted enol ether as a dienophile Tetrahedron Letters. 28: 5255-5258. DOI: 10.1016/S0040-4039(00)96701-7  1
1987 Baettig K, Marinier A, Pitteloud R, Deslongchamps P. Synthesis and transannular diels-alder reaction of a trans-cis-cis 13-membered macrocyclic trienono Tetrahedron Letters. 28: 5253-5254. DOI: 10.1016/S0040-4039(00)96700-5  1
1987 Baettig K, Dallaire C, Pitteloud R, Deslongchamps P. Synthesis and transannular diels-alder reaction of a cis-trans-trans 13-membered macrocyclic trienone Tetrahedron Letters. 28: 5249-5252. DOI: 10.1016/S0040-4039(00)96699-1  1
1987 Lavallée JF, Deslongchamps P. Synthesis of tricyclic compounds via sequential intramolecular Michael addition and alkylation of β-ketoester ynones Tetrahedron Letters. 28: 3457-3458. DOI: 10.1016/S0040-4039(00)96325-1  1
1987 Brillon D, Deslongchamps P. Synthesis of 13- and 14-membered rings by a direct cyclization method Canadian Journal of Chemistry. 65: 56-68.  1
1987 Berube G, Deslongchamps P. 1,5-Acyclic stereoselection: Synthesis of the optically active side chain of vitamin E | STEREOSELECTION ACYCLIQUE-1,5: SYNTHESE DE LA CHAINE LATERALE OPTIQUEMENT ACTIVE DE LA VITAMINE E Bulletin De La Societe Chimique De France. 103-115.  1
1986 Caron M, Kawamata T, Ruest L, Soucy P, Deslongchamps P. The addition of electrophiles on ester enolates containing an oxygen in the β-position. A stereoelectronically controlled reaction Canadian Journal of Chemistry. 64: 1781-1787. DOI: 10.1139/V86-293  1
1986 Lavallée JF, Berthiaume G, Deslongchamps P, Grein F. Intramolecular Michael addition of cyclic β-ketoester on conjugated acetylenic ketone Tetrahedron Letters. 27: 5455-5458. DOI: 10.1016/S0040-4039(00)85236-3  1
1986 Berthiaume G, Lavallée JF, Deslongchamps P. Intramolecular Michael addition of cyclic β-ketoester on conjugated olefinic ketone, a stereoelectronically controlled process Tetrahedron Letters. 27: 5451-5454. DOI: 10.1016/S0040-4039(00)85235-1  1
1986 Brillon D, Deslongchamps P. Study on the influence of unsaturations on the formation of C-11, C-12, C-13 and C-14 membered rings Tetrahedron Letters. 27: 1131-1134. DOI: 10.1016/S0040-4039(00)84196-9  1
1986 Ndibwami A, Deslongchamps P. Study on the enolization of alkylation of cis and trans 2-ferf-5-X-l,3Iioxaiies (X = CO2CH3, CHO, COPh, NO2, and CN). Evidence for stereoelectronic control Canadian Journal of Chemistry. 64: 1788-1794.  1
1985 Sauvé G, Deslongchamps P. Synthesis of E and Z alkyl tetrahydro-2-pyrilidene and tetrahydro-2-furylidene acetates Synthetic Communications. 15: 201-212. DOI: 10.1080/00397918508063788  1
1984 Sauve G, Schwartz DA, Ruest L, Deslongchamps P. Stereocontrolled synthesis of the C-1 to C-7 fragment of erythronolide A. A model study using the 1,7-dioxaspiro[5.5]undecane system Canadian Journal of Chemistry. 62: 2929-2935. DOI: 10.1139/V84-496  1
1984 Berube G, Deslongchamps P. 1,5-Acyclic stereoselection. The stereocontrolled synthesis of optically active vitamin E fourteen-carbon side chain alcohol Canadian Journal of Chemistry. 62: 1558-1560. DOI: 10.1139/V84-267  1
1982 Know Choi J, Joncich MJ, Lambert Y, Deslongchamps P, Fliszár S. Distributions electroniques et effets chimiques. XXVIII. Etude théorique et expérimentale du tricyclo[4.4.0.03,8] decane ("twistane") Journal of Molecular Structure. 89: 115-122. DOI: 10.1016/0166-1280(82)80158-9  1
1981 Deslongchamps P, Soucy P. A convenient synthesis of triquinacene-2-carboxylic acid and a new approach towards the synthesis of dodecahedrane Tetrahedron. 37: 4385-4390. DOI: 10.1016/0040-4020(81)80004-X  1
1977 Deslongchamps P. Synthetic Studies Towards Ryanodine Pure and Applied Chemistry. 49: 1329-1359. DOI: 10.1351/pac197749091329  1
1976 Ruest L, Blouin G, Deslongchamps P. A Convenient Synthesis of 2-Carbomethoxycyclohexanone Synthetic Communications. 6: 169-174. DOI: 10.1080/00397917608072627  1
1975 Deslongchamps P. Stereoelectronic control in the cleavage of tetrahedral intermediates in the hydrolysis of esters and amides Tetrahedron. 31: 2463-2490. DOI: 10.1016/0040-4020(75)80257-2  1
1975 Deslongchamps P, Cheriyan UO, Patterson DR. Alkylation of 1 methyl 2 piperidones Canadian Journal of Chemistry. 53: 1682-1683.  1
1970 Dubé S, Deslongchamps P. The synthesis of 1-azatwistane Tetrahedron Letters. 11: 101-102. DOI: 10.1016/S0040-4039(01)87574-2  1
1968 Bélanger A, Poupart J, Deslongchamps P. A one-step synthesis of the twistane ring system 8-acetoky-4-twistanone Tetrahedron Letters. 9: 2127-2128.  1
1964 Deslongchamps P, Wilson JS, Valenta Z. The structure of piptanthine a catalytic epimerization of Ormosia alkaloids Tetrahedron Letters. 5: 3893-3898. DOI: 10.1016/S0040-4039(01)93312-X  1
1964 Anet FAL, Haq MZ, Khan NH, Ayer WA, Hayatsu R, Valverde-Lopez S, Deslongchamps P, Riess W, Ternbah M, Valenta Z, Wiesner K. The structure of lyconnotine: A novel lycopodium alkaloid Tetrahedron Letters. 5: 751-757. DOI: 10.1016/0040-4039(64)83031-8  1
1964 Valenta Z, Deslongchamps P, Ellison RA, Wiesner K. Synthesis of Lycopodium alkaloids. I. A synthetic proof for the structure of lyconnotine [18] Journal of the American Chemical Society. 86: 2533-2534.  1
1963 Valenta Z, Deslongchamps P, Rashid MH, Wightman RH, Wilson JS. Ormosia alkaloids, Part I: structure of ormojanine and ormosanine Tetrahedron Letters. 4: 1559-1567. DOI: 10.1016/S0040-4039(01)90871-8  1
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