Anthony J. Downs, Ph.D - Publications

Affiliations: 
Chemistry University of Oxford, Oxford, United Kingdom 
Area:
Inorganic and organometallic chemistry
Website:
http://research.chem.ox.ac.uk/tony-downs.aspx

166 high-probability publications. We are testing a new system for linking publications to authors. You can help! If you notice any inaccuracies, please sign in and mark papers as correct or incorrect matches. If you identify any major omissions or other inaccuracies in the publication list, please let us know.

Year Citation  Score
2012 Morris LJ, Greene TM, Green JC, Downs AJ. Matrix photochemistry of ethyltrioxorhenium(VII), C 2H 5ReO 3: Tautomerisation via β-hydrogen migration with the sequential formation of two different ethene derivatives Journal of Molecular Structure. 1025: 84-91. DOI: 10.1016/J.Molstruc.2011.11.005  0.379
2011 Evans R, Downs AJ, Köppe R, Peake SC. Vibrational properties of the disulfur dinitride molecule, S2N2: IR and Raman spectra of the matrix-isolated molecule. The Journal of Physical Chemistry. A. 115: 5127-37. PMID 21528874 DOI: 10.1021/Jp202284B  0.413
2011 Aldridge S, Downs AJ, Kays DL. Formal Oxidation State +3: Organometallic Chemistry The Group 13 Metals Aluminium, Gallium, Indium and Thallium: Chemical Patterns and Peculiarities. 148-245. DOI: 10.1002/9780470976548.ch4  0.645
2011 Aldridge S, Downs AJ. Preface The Group 13 Metals Aluminium, Gallium, Indium and Thallium: Chemical Patterns and Peculiarities. viii-x. DOI: 10.1002/9780470976548.ch1  0.35
2011 Aldridge S, Downs AJ. The Group 13 Metals Aluminium, Gallium, Indium and Thallium: Chemical Patterns and Peculiarities The Group 13 Metals Aluminium, Gallium, Indium and Thallium: Chemical Patterns and Peculiarities. DOI: 10.1002/9780470976548  0.401
2010 Downs AJ, Greene TM, Johnsen E, Pulham CR, Robertson HE, Wann DA. The digallane molecule, Ga2H6: experimental update giving an improved structure and estimate of the enthalpy change for the reaction Ga2H6(g) --> 2GaH3(g). Dalton Transactions (Cambridge, England : 2003). 39: 5637-42. PMID 20419186 DOI: 10.1039/C000694G  0.627
2010 Picone AL, Della Védova CO, Willner H, Downs AJ, Romano RM. Experimental and theoretical characterization of molecular complexes formed between OCS and XY molecules (X, Y = F, Cl and Br) and their role in photochemical matrix reactions. Physical Chemistry Chemical Physics : Pccp. 12: 563-71. PMID 20066342 DOI: 10.1039/B914862K  0.393
2009 Aldridge S, Downs AJ, Tang CY, Parsons S, Clarke MC, Johnstone RD, Robertson HE, Rankin DW, Wann DA. Structures and aggregation of the methylamine-borane molecules, Me(n)H(3-n)N.BH(3) (n = 1-3), studied by X-ray diffraction, gas-phase electron diffraction, and quantum chemical calculations. Journal of the American Chemical Society. 131: 2231-43. PMID 19170515 DOI: 10.1021/Ja807545P  0.549
2008 del Rio D, Resa I, Rodriguez A, Sánchez L, Köppe R, Downs AJ, Tang CY, Carmona E. IR and Raman characterization of the zincocenes (eta(5)-C5Me5)2Zn2 and (eta(5)-C5Me5)(eta(1)-C5Me5)Zn. The Journal of Physical Chemistry. A. 112: 10516-25. PMID 18821745 DOI: 10.1021/Jp805291E  0.349
2008 Geronés M, Downs AJ, Erben MF, Ge M, Romano RM, Yao L, Della Védova CO. HeI photoelectron and valence synchrotron photoionization studies of the thioester molecule CH3C(O)SCH3: evidence of vibronic structure. The Journal of Physical Chemistry. A. 112: 5947-53. PMID 18543885 DOI: 10.1021/Jp801295G  0.349
2008 Tang CY, Cowley AR, Downs AJ, Marchant S, Parsons S. Formation and characterization of the cationic gallane derivatives [(RH2N)2GaH2]Cl (R = Me or iPr) and [{(iPrH2N)GaH2NHiPr}2GaH2]Cl European Journal of Inorganic Chemistry. 737-744. DOI: 10.1002/Ejic.200701120  0.399
2007 Romano RM, Della Védova CO, Downs AJ. Methanesulfenyl fluoride, CH3SF, a missing link in the family of sulfenyl halides: formation and characterization through the matrix photochemistry of methyl thiofluoroformate, FC(O)SCH3. Chemistry (Weinheim An Der Bergstrasse, Germany). 13: 8185-92. PMID 17639538 DOI: 10.1002/Chem.200700118  0.348
2007 Tang CY, Cowley AR, Downs AJ, Parsons S. Preparation and characterization of lithium imidoalanate complexes Li(2)[(RN)(4)(AlH(2))(6)] (R = Me or (t)()Bu): first examples of aluminum-rich imidoalanes with an adamantoid structure. Inorganic Chemistry. 46: 5439-46. PMID 17539634 DOI: 10.1021/Ic7006827  0.385
2007 Wann DA, Blockhuys F, Van Alsenoy C, Robertson HE, Himmel HJ, Tang CY, Cowley AR, Downs AJ, Rankin DW. Molecular structures of free quinuclidine and its adducts with metal trihydrides, MH3 (M=B, Al or Ga), studied by gas-phase electron diffraction, X-ray diffraction and quantum chemical calculations. Dalton Transactions (Cambridge, England : 2003). 1687-96. PMID 17443261 DOI: 10.1039/B701476G  0.456
2007 Tobón YA, Romano RM, Védova CO, Downs AJ. Formation of new halogenothiocarbonylsulfenyl halides, XC(S)SY, through photochemical matrix reactions starting from CS2 and a dihalogen molecule XY (XY=Cl2, Br2, or BrCl). Inorganic Chemistry. 46: 4692-703. PMID 17411033 DOI: 10.1021/Ic070119+  0.324
2006 Romano RM, Picone AL, Downs AJ. Matrix-isolated van der Waals complexes formed between CS2 and dihalogen molecules XY, Where XY = Cl2, Br2, BrCl, ICl, or IBr. The Journal of Physical Chemistry. A. 110: 12129-35. PMID 17078607 DOI: 10.1021/Jp064432T  0.354
2006 Arce VB, Della Védova CO, Downs AJ, Parsons S, Romano RM. Trichloromethyl chloroformate ("diphosgene"), ClCOOCCl3: structure and conformational properties in the gaseous and condensed phases. The Journal of Organic Chemistry. 71: 3423-8. PMID 16626122 DOI: 10.1021/Jo052260A  0.427
2006 Tang CY, Downs AJ, Greene TM, Kettle L, Rankin DW, Robertson HE, Turner AR. Gas electron diffraction study of the vapour over dimethylamine-gallane leading to an improved structure for dimeric dimethylamidogallane, [Me2NGaH2]2: a cautionary tale. Dalton Transactions (Cambridge, England : 2003). 1204-12. PMID 16482358 DOI: 10.1039/B509975G  0.41
2005 Marchant S, Tang CY, Downs AJ, Greene TM, Himmel HJ, Parsons S. Synthesis and structural characterisation of primary amine adducts of gallane, RH2N.GaH3, and of their decomposition products, [RHNGaH2]n(R = Me, n= 3; R =tBu, n= 2). Dalton Transactions (Cambridge, England : 2003). 3281-90. PMID 16193146 DOI: 10.1039/B508057F  0.423
2005 Tang CY, Downs AJ, Greene TM, Marchant S, Parsons S. Decomposition of monochlorogallane, [H2GaCl]n, and adducts with amine and phosphine bases: formation of cationic gallane derivatives. Inorganic Chemistry. 44: 7143-50. PMID 16180877 DOI: 10.1021/Ic050986J  0.394
2005 McGrady GS, Haaland A, Verne HP, Volden HV, Downs AJ, Shorokhov D, Eickerling G, Scherer W. Valence shell charge concentrations at pentacoordinate d0 transition-metal centers: non-VSEPR structures of Me2NbCl3 and Me3NbCl2. Chemistry (Weinheim An Der Bergstrasse, Germany). 11: 4921-34. PMID 15940736 DOI: 10.1002/Chem.200400808  0.417
2005 Cowley AR, Downs AJ, Himmel HJ, Marchant S, Parsons S, Yeoman JA. 1,1,3,3-Tetramethylguanidine-gallane, (Me2N)2CN(H).GaH3: an unusually strongly bound gallane adduct. Dalton Transactions (Cambridge, England : 2003). 1591-7. PMID 15852107 DOI: 10.1039/B501818H  0.399
2005 Romano RM, Della Védova CO, Downs AJ, Tobón YA, Willner H. New members of an old family: isolation of IC(O)Cl and IC(O)Br and evidence for the formation of weakly bound Br*...CO. Inorganic Chemistry. 44: 3241-8. PMID 15847433 DOI: 10.1021/Ic0484046  0.331
2005 Pardoe JA, Cowley AR, Downs AJ, Greene TM. mer-Triiodotripyridineindium(III). Acta Crystallographica. Section C, Crystal Structure Communications. 61: m200-2. PMID 15805623 DOI: 10.1107/S0108270105006360  0.33
2005 Cowley AR, Downs AJ, Marchant S, Macrae VA, Taylor RA, Parsons S. Crystal structures of tris(tert-butyl)boron, -aluminum, -gallium, and -indium: Nonplanarity of the AlC3 skeleton and evidence of inter- and intramolecular "agostic" or hyperconjugative interactions Organometallics. 24: 5702-5709. DOI: 10.1021/Om050572Y  0.385
2004 Della Védova CO, Downs AJ, Moschione E, Parsons S, Romano RM. Chlorocarbonyl trifluoromethanesulfonate, ClC(O)OSO2CF3: structure and conformational properties in the gaseous and condensed phases. Inorganic Chemistry. 43: 8143-9. PMID 15578854 DOI: 10.1021/Ic0489488  0.401
2004 Gaertner B, Himmel HJ, Macrae VA, Pardoe JA, Randall PG, Downs AJ. Some novel binuclear group 13 metal tin hydrides formed in Ar matrices following the codeposition of the metal vapor with SnH4. Chemistry (Weinheim An Der Bergstrasse, Germany). 10: 5836-47. PMID 15481027 DOI: 10.1002/Chem.200400564  0.4
2004 Gaertner B, Himmel HJ, Macrae VA, Downs AJ, Greene TM. Matrix reactivity of Al and Ga atoms (M) in the presence of silane: generation and characterization of the eta2-coordinated complex M.SiH4, the insertion product HMSiH3, and the MI species MSiH3 in a solid argon matrix. Chemistry (Weinheim An Der Bergstrasse, Germany). 10: 3430-43. PMID 15252789 DOI: 10.1002/Chem.200305493  0.397
2004 Borisenko KB, Downs AJ, Robertson HE, Rankin DW, Tang CY. Molecular structure of Hf(BH4)4 investigated by quantum mechanical calculations and gas-phase electron diffraction. Dalton Transactions (Cambridge, England : 2003). 967-70. PMID 15252486 DOI: 10.1039/B316213C  0.364
2004 Macrae VA, Greene TM, Downs AJ. Matrix studies of the thermal and photolytic reactions of Zn, Cd and Hg (M) atoms with H2O: Formation and characterisation of the adduct M⋯OH2 and photoproduct HMOH Physical Chemistry Chemical Physics. 6: 4586-4594. DOI: 10.1039/B405300A  0.347
2004 Macrae VA, Downs AJ. Matrix studies of the thermal and photolytic reactions of Ga vapour species with H2O: Formation and characterisation of the adducts Ga · OH2 and Ga2 and the photoproducts HGaOH, GaOH and Ga(μ-H)(μ-OH)Ga Physical Chemistry Chemical Physics. 6: 4571-4578. DOI: 10.1039/B405298F  0.388
2004 Romano RM, Védova COD, Downs AJ. Matrix photochemistry of the chlorocarbonyl sulfenyl compounds ClC(O)SY, with Y = Cl or CH3 Journal of Physical Chemistry A. 108: 7179-7187. DOI: 10.1021/Jp048756Y  0.349
2004 Macrae VA, Greene TM, Downs AJ. Matrix reactivity of Zn, Cd, or Hg atoms (M) in the presence of silane: Photogeneration and characterization of the insertion product HMSiH3 in a solid argon matrix Journal of Physical Chemistry A. 108: 1393-1402. DOI: 10.1021/Jp0309769  0.326
2003 Haaland A, Green JC, McGrady GS, Downs AJ, Gullo E, Lyall MJ, Timberlake J, Tutukin AV, Volden HV, Østby K. The length, strength and polarity of metal–carbon bonds: dialkylzinc compounds studied by density functional theory calculations, gas electron diffraction and photoelectron spectroscopy Dalton Transactions. 4356-4366. DOI: 10.1039/B306840B  0.38
2003 Tang CY, Coxall RA, Downs AJ, Greene TM, Kettle L, Parsons S, Rankin DWH, Robertson HE, Turner AR. Molecular structure of trimethylphosphine–gallane, Me3P·GaH3: gas-phase electron diffraction, single-crystal X-ray diffraction, and quantum chemical studies Dalton Transactions. 3526-3533. DOI: 10.1039/B306736J  0.429
2003 Tang CY, Downs AJ, Greene TM, Parsons S. Dimeric piperidino-alane and -gallane: metal hydrides with a cyclic M(μ-N)2M core (M = Al or Ga) Dalton Transactions. 540-543. DOI: 10.1039/B209669M  0.362
2003 Romano RM, Della Védova CO, Downs AJ, Parsons S, Smith C. Structural and vibrational properties of ClC(O)SY compounds with Y = Cl and CH3 New Journal of Chemistry. 27: 514-519. DOI: 10.1039/B209005H  0.406
2003 Boese R, Downs AJ, Greene TM, Hall AW, Morrison CA, Parsons S. Polymorphism in the crystal structures of the group 13 trimethyls Organometallics. 22: 2450-2457. DOI: 10.1021/Om0300272  0.342
2003 Romano RM, Downs AJ. Matrix-isolated van der waals complexes formed between CO and dihalogen molecules, XY with X, Y = Cl, Br, or I Journal of Physical Chemistry A. 107: 5298-5305. DOI: 10.1021/Jp034808S  0.335
2002 Himmel HJ, Manceron L, Downs AJ, Pullumbi P. Characterization and photochemistry of the gallium and indium subhydrides Ga2H2 and In2H2. Angewandte Chemie (International Ed. in English). 41: 796-9. PMID 12491339 DOI: 10.1002/1521-3773(20020301)41:5<796::Aid-Anie796>3.0.Co;2-3  0.351
2002 Downs AJ, Dierker G, Green JC, Greene TM, McGrady GS, Morris LJ, Scherer W, Sirsch P. Vibrational properties and matrix photochemistry of trimethyldioxorhenium(VII), (CH3)3ReO2 Journal of the Chemical Society-Dalton Transactions. 3349-3360. DOI: 10.1039/B204238J  0.371
2002 Downs AJ, Geisberger MR, Green JC, Greene TM, Haaland A, Herrmann WA, Morris LJ, Parsons S, Scherer W, Volden HV. Structure and vibrational properties of ethyltrioxorhenium(VII), C2H5ReO3, investigated by gas electron diffraction, single crystal X-ray diffraction, IR spectroscopy and quantum chemical calculations Journal of the Chemical Society, Dalton Transactions. 3342-3348. DOI: 10.1039/B204235P  0.437
2002 Morris LJ, Downs AJ, Green JC, Greene TM, Teat SJ, Parsons S. Structural studies and matrix photochemistry of tetramethyloxorhenium(VI), (CH3)4ReO, and related compounds Journal of the Chemical Society-Dalton Transactions. 3142-3152. DOI: 10.1039/B202425J  0.406
2002 Romano RM, Della Védova CO, Downs AJ. Matrix photochemistry of CH3C(O)SX molecules with X = H, CH3, and C(O)CH3: Formation of ketene in another decomposition channel of sulfenyl carbonyl compounds Journal of Physical Chemistry A. 106: 7235-7244. DOI: 10.1021/Jp0205261  0.361
2002 Downs AJ, Himmel HJ, Manceron L. Low valent and would-be multiply bonded derivatives of the Group 13 metals Al, Ga and In revealed through matrix isolation Polyhedron. 21: 473-488. DOI: 10.1016/S0277-5387(01)01036-1  0.421
2001 Aldridge S, Downs AJ. Hydrides of the main-group metals: new variations on an old theme. Chemical Reviews. 101: 3305-65. PMID 11840988 DOI: 10.1021/Cr960151D  0.456
2001 Romano RM, Della Védova CO, Downs AJ, Oberhammer H, Parsons S. Structure and conformational properties of diacetyl sulfide in the gaseous and condensed phases explored by gas electron diffraction, single-crystal X-ray diffraction, vibrational spectroscopy, and quantum chemical calculations. Journal of the American Chemical Society. 123: 12623-31. PMID 11741427 DOI: 10.1021/Ja0117884  0.429
2001 Johnsen E, Downs AJ, Goode MJ, Greene TM, Himmel HJ, Müller M, Parsons S, Pulham CR. Some chemical properties of monochlorogallane: decomposition to gallium(I) trichlorogallate(III), Ga(+)[GaCl3H](-), and other reactions. Inorganic Chemistry. 40: 4755-61. PMID 11511226 DOI: 10.1021/Ic010128X  0.624
2001 Downs AJ, Greene TM, Johnsen E, Brain PT, Morrison CA, Parsons S, Pulham CR, Rankin DW, Aarset K, Mills IM, Page EM, Rice DA. Preparation and properties of gallaborane, GaBH(6): structure of the gaseous molecule H(2)Ga(mu-H)(2)BH(2) as determined by vibrational, electron diffraction, and ab initio studies, and structure of the crystalline solid at 110 K as determined by X-ray diffraction. Inorganic Chemistry. 40: 3484-97. PMID 11421696 DOI: 10.1021/Ic001338X  0.607
2001 Romano RM, Della Védova CO, Downs AJ. (Bromocarbonyl)sulfenyl bromide, brC(O)SBr: A novel carbonyl sulfenyl compound formed by the photochemical reaction between Br2 and OCS isolated together in an Ar matrix Chemical Communications. 2638-2639. DOI: 10.1039/B108218C  0.314
2001 Tang CY, Coxall RA, Downs AJ, Greene TM, Parsons S. Oligomeric structures of the crystalline dimethylamine adducts Me2(H)N·MH3 (M = Al or Ga) and the dimethylamido derivative [Me2NGaH2]3 Journal of the Chemical Society-Dalton Transactions. 2141-2147. DOI: 10.1039/B102667B  0.399
2001 McKean DC, Sean McGrady G, Downs AJ, Scherer W, Haaland A. Experimental and density functional theory studies of ethyltrichlorotitanium, EtTiCl3 and of the ethyl group in EtTiCl3 complexes: Vibrational properties of a β-agostic ethyl ligand Physical Chemistry Chemical Physics. 3: 2781-2794. DOI: 10.1039/B102111G  0.327
2001 Himmel H, Downs AJ, Green JC, Greene TM. Compounds featuring a bond between a Group 13 (M) and a Group 15 element (N or P) and with the formulae HmMNHn and HmMPHn: structural aspects and bonding Journal of the Chemical Society-Dalton Transactions. 535-545. DOI: 10.1039/B008724F  0.412
2001 Morris LJ, Downs AJ, Greene TM, McGrady GS, Herrmann WA, Sirsch P, Scherer W, Gropen O. Matrix photochemistry of methyltrioxorhenium(VII), CH3ReO3: Formation of the methylidene tautomer H2C=Re(O)2OH and its potential relevance to olefin metathesis Organometallics. 20: 2344-2352. DOI: 10.1021/Om0100479  0.336
2001 Limberg C, Downs AJ, Greene TM, Wistuba T. The Photochemistry of [CpMo(CO)3(η1-C3H5)] in frozen gas matrices at 10 K and the behaviour of [CpMo(CO)2(η3-C3H5)] isomers in different media European Journal of Inorganic Chemistry. 2613-2618. DOI: 10.1002/1099-0682(200109)2001:10<2613::Aid-Ejic2613>3.0.Co;2-6  0.546
2000 Johnsen E, Downs AJ, Greene TM, Souter PF, Aarset K, Page EM, Rice DA, Richardson AN, Brain PT, Rankin DW, Pulham CR. Monochlorogallane: physical properties and structure of the gaseous molecule H2Ga(mu-Cl)2GaH2 as determined by vibrational, electron diffraction, and ab initio studies. Inorganic Chemistry. 39: 719-27. PMID 11272566 DOI: 10.1021/Ic9908975  0.673
2000 Himmel HJ, Downs AJ, Greene TM. Amidoalane, amidogallane and amidoindane, H2MNH2 (M = Al, Ga or In): A matrix study of three prototypal molecules with the potential for M-N multiple bonding Chemical Communications. 871-872. DOI: 10.1039/B001652G  0.353
2000 Morris LJ, Downs AJ, Greene TM, McGrady GS, Herrmann WA, Sirsch P, Gropen O, Scherer W. Photo-induced tautomerisation of methyltrioxorhenium(vii): the intermediate in olefin metathesis? Chemical Communications. 67-68. DOI: 10.1039/A907908D  0.33
2000 Downs AJ, Green JC, McGrady GS, Munkman N, Parkin RPG. Aspects of transition metal pentacoordination: investigation of the structure and bonding of Me3NbCl2, Me3TaCl2 and Me2NbCl3 by photoelectron spectroscopy and density functional theory calculations Journal of the Chemical Society-Dalton Transactions. 21-27. DOI: 10.1039/A906837F  0.356
2000 Downs AJ, Greene TM, Collin aSE, Whitehurst LA, Brain PT, Morrison CA, Pulham CR, Smart aBA, Rankin DWH, and AK, Barron AR. Dimethylalane, [Me2AlH]n, in the Vapor Phase and in Hydrocarbon Solution: Gas-Phase Electron Diffraction, Spectroscopic, Colligative, and ab Initio Studies Organometallics. 19: 527-538. DOI: 10.1021/Om990811F  0.641
2000 Himmel HJ, Downs AJ, Green JC, Greene TM. Thermal and photolytic reactions of gallium and indium atoms (M) and their dimers ma with carbon monoxide in low-temperature matrices: Formation of terminal, bridged, and ionic carbonyl derivatives Journal of Physical Chemistry A. 104: 3642-3654. DOI: 10.1021/Jp9938359  0.391
1999 Himmel H, Downs AJ, Greene TM, Andrews L. Methylgallium and methylindium: the first sighting of the simplest organic derivatives of Ga(I) and In(I) Chemical Communications. 2243-2244. DOI: 10.1039/A907283G  0.361
1999 Szymańska-Buzar T, Kern K, Downs AJ, Greene TM, Morris LJ, Parsons S. Crystal structure of trans- [W(CO)4(n2-C2H4)2] and IR 1H NMR studies of the reactions of this and related ethene carbonyl complexes of tungsten(0), [W(CO)(n)(n2-C2H4)6-(n)] (n = 3-5) New Journal of Chemistry. 23: 407-416. DOI: 10.1039/A808621D  0.383
1999 Downs AJ. Recent advances in the chemistry of the Group 13 metals: Hydride derivatives and compounds involving multiply bonded Group 13 metal atoms Coordination Chemistry Reviews. 189: 59-100. DOI: 10.1016/S0010-8545(99)00116-2  0.344
1998 Brain PT, Brown HE, Downs AJ, Greene TM, Johnsen E, Parsons S, Rankin DWH, Smart BA, Tang CY. Molecular structure of trimethylamine–gallane, Me3N·GaH3: ab initio calculations, gas-phase electron diffraction and single-crystal X-ray diffraction studies† Journal of the Chemical Society-Dalton Transactions. 3685-3692. DOI: 10.1039/A806289G  0.431
1998 Morrison CA, Smart BA, Brain PT, Rankin DWH, Downs AJ. Molecular structures of tetraborane(10) derivatives: ab initio calculations for (CH3)2MB3H8 (M = B, Al, Ga or In) and gas-phase electron diffraction studies of (CH3)2AlB3H8 and (CH3)2GaB3H8 Journal of the Chemical Society-Dalton Transactions. 2155-2162. DOI: 10.1039/A801554F  0.403
1998 Morrison CA, Smart BA, Brain PT, Pulham CR, Rankin DWH, Downs AJ. Molecular structures of tetraborane(10) derivatives: ab initio calculations for H2MB3H8 (M = B, Al, Ga or In) and gas-phase electron diffraction study of H2GaB3H8 Journal of the Chemical Society-Dalton Transactions. 2147-2154. DOI: 10.1039/A801553H  0.619
1998 Greene TM, Downs AJ, Pulham CR, Haaland A, Verne HP, Volden HV, Timofeeva TV. Molecular structures of pentamethylarsenic(V) and trimethyldichloroarsenic(V) by gas electron diffraction and ab initio calculations: Molecular mechanics calculations on pentamethylarsenic(V), pentaphenylarsenic(V), and related compounds Organometallics. 17: 5287-5293. DOI: 10.1021/Om980520R  0.631
1998 Scherer W, Priermeier T, Haaland A, Volden HV, McGrady GS, Downs AJ, Boese R, Bläser D. Molecular structures of EtTiCl3 and EtTiCl3(dmpe) (dmpe = Me2PCH2CH2PMe2): New insights into β-agostic bonding Organometallics. 17: 4406-4412. DOI: 10.1021/Om980233N  0.38
1998 Greene TM, Lanzisera DV, Andrews L, Downs AJ. A matrix-isolation and density functional theory study of the reactions of laser-ablated beryllium, magnesium, and calcium atoms with methane Journal of the American Chemical Society. 120: 6097-6104. DOI: 10.1021/Ja9804870  0.328
1998 Aldridge S, Downs AJ, Hofmann M, Pulham CR, Von Ragué Schleyer P. Methylzinc tetrahydroborate: Investigation of the vapour phase by spectroscopic and quantum chemical techniques Journal of Molecular Structure. 444: 29-46. DOI: 10.1016/S0022-2860(97)00314-1  0.696
1997 M GS, Downs AJ, Haaland A, Scherer W, McKean DC. Vibrational properties of ethyltitanium trichloride and its 1,2-bis(dimethylphosphino)ethane adduct: Characterisation of isolated v(C-H) modes and implications for agostic bonding Chemical Communications. 1547-1548. DOI: 10.1039/A703975A  0.334
1997 Aldridge S, Blake AJ, Downs AJ, Gould RO, Parsons S, Pulham CR. Some tetrahydroborate derivatives of aluminium: crystal structures ofdimethylaluminium tetrahydroborate and the α and β phases ofaluminium tris(tetrahydroborate) at low temperature Journal of the Chemical Society-Dalton Transactions. 1007-1012. DOI: 10.1039/A607843E  0.68
1997 McGrady GS, Downs AJ, Bednall NC, McKean DC, Thiel W, Jonas V, Frenking G, Scherer W. Infrared spectrum and structure of Me2TiCl2 and quantum mechanical calculations of geometries and force fields for MeTiCl3 and Me2TiCl2 Journal of Physical Chemistry A. 101: 1951-1968. DOI: 10.1021/Jp962976X  0.37
1997 Downs AJ, Parsons S, Pulham CR, Souter PF. Helical, Polymeric Chains in Crystalline Gallaborane[GaBH6]n at 110 K Angewandte Chemie International Edition in English. 36: 890-891. DOI: 10.1002/Anie.199708901  0.564
1997 Downs AJ, Parsons S, Pulham CR, Souter PF. Helicale, polymere Ketten im kristallinen Gallaboran [GaBH6]n bei 110 K Angewandte Chemie. 109: 910-911. DOI: 10.1002/Ange.19971090826  0.537
1996 Downs AJ, Greene TM, McGrady GS, Townson N, Brain PT, Pulham CR, Rankin DW, Robertson HE, Smart BA, Alberts IL. Molecular Structures of Methyldifluoroarsine, CH(3)AsF(2), and Dimethylfluoroarsine, (CH(3))(2)AsF, in the Gas Phase As Determined by Electron Diffraction and ab InitioCalculations. Inorganic Chemistry. 35: 6952-6958. PMID 11666872 DOI: 10.1021/Ic960732L  0.548
1996 Limberg C, Downs AJ, Blake AJ, Parsons S. Modeling the Formation of Molybdenum Oxides from Alkoxides: Crystal Structures of [Mo(4)O(4)Cl(4)(&mgr;(2)-OEt)(4)(HOEt)(2)(&mgr;(3)-O)(2)] and [PPN](+)[Et(3)NH](+)[Cl(2)(O)Mo(&mgr;(2)-O)(2)Mo(O)Cl(2)](2)(-). Inorganic Chemistry. 35: 4439-4448. PMID 11666664 DOI: 10.1021/Ic951468J  0.55
1996 Aldridge S, Blake AJ, Downs AJ, Parsons S, Pulham CR. Methylzinc tetrahydroborate: physical and chemical properties and crystal structure at low temperature Journal of the Chemical Society-Dalton Transactions. 853-859. DOI: 10.1039/Dt9960000853  0.701
1996 Aldridge S, Downs AJ, Parsons S. Dimethylindium octahydrotriborate, Me2InB3H3: synthesis, crystal structure and spectroscopic properties of a volatile indium hydride Chemical Communications. 2055-2056. DOI: 10.1039/Cc9960002055  0.56
1996 Dyke JM, Haggerston D, Warschkow O, Andrews L, Downs AJ, Souter PF. UV Photoelectron Spectra of the μ-Hydrido Bridge-Bonded Molecules B2H6, GaBH6, and Ga2H6 The Journal of Physical Chemistry. 100: 2998-3004. DOI: 10.1021/Jp953039C  0.37
1996 McGrady GS, Downs AJ, McKean DC, Haaland A, Scherer W, Verne H, Volden HV. Molecular Structure of Dimethyldichlorotitanium(IV) by Gas-Phase Electron Diffraction, IR and NMR Spectroscopies, and Density Functional Theory Calculations. Unexpected Distortion from Tetrahedral Coordination Geometry Inorganic Chemistry. 35: 4713-4718. DOI: 10.1021/Ic960177N  0.433
1995 Blake AJ, Parsons S, Downs AJ, Limberg C. Bis(triphenylphosphine)iminium Tetrachlorooxomolybdenum(V) at 150 K Acta Crystallographica Section C Crystal Structure Communications. 51: 571-573. DOI: 10.1107/S0108270194011303  0.548
1995 Blake AJ, Downs AJ, Limberg C, Parsons S. Synthesis and crystal structure of an encapsulated fragment of MoO2 in the unique Mo8 oxo-cluster compound [Mo8O8Cl6(µ3-O)4(OH)2(µ-OH)4(µ-OEt)4(HOEt)4] and its relevance to the sol–gel synthesis of molybdenum oxides Journal of the Chemical Society-Dalton Transactions. 3263-3268. DOI: 10.1039/Dt9950003263  0.587
1995 Brain PT, Rankin DWH, Robertson HE, Alberts IL, Downs AJ, Greene TM, Hofmann M, Schleyer PvR. Molecular structure of 1-(dichloroboryl)pentaborane(9), in the gas phase as determined by electron diffraction and supported by theoretical calculations Journal of the Chemical Society-Dalton Transactions. 2193-2199. DOI: 10.1039/Dt9950002193  0.417
1995 Aldridge S, Blake AJ, Downs AJ, Parsons S. The methylzinc hydroborate derivative [(MeZn)2B3H7]2: synthesis, crystal structure and vibrational spectra of an unprecedented cluster compound Journal of the Chemical Society, Chemical Communications. 1363-1364. DOI: 10.1039/C39950001363  0.59
1995 Greene TM, Andrews L, Downs AJ. The Reaction of Zinc, Cadmium, and Mercury Atoms with Methane: Infrared Spectra of the Matrix-Isolated Methylmetal Hydrides Journal of the American Chemical Society. 117: 8180-8187. DOI: 10.1021/Ja00136A015  0.319
1995 Downs AJ, Greene TM, Gordon CM. Photooxidation of Matrix-Isolated Nickel Tetracarbonyl in the Presence of Dioxygen Inorganic Chemistry. 34: 6191-6198. DOI: 10.1021/Ic00128A034  0.305
1995 Downs AJ, Greene TM, Harman LA, Souter PF, Brain PT, Pulham CR, Rankin DWH, Robertson HE, Hofmann M, Schleyer PvR. Hydridogallium Bis(tetrahydroborate) in the Gas Phase: Vibrational Properties and Structure Determined by Electron Diffraction and ab Initio and Density Functional Theory Computations Inorganic Chemistry. 34: 1799-1809. DOI: 10.1021/Ic00111A030  0.611
1995 Pulham CR, Downs AJ, Goode MJ, Greene TM, Mills IM. Erratum to “The vibrational spectra of natural and perdeuterated monochlorogallane, H2Ga(μ-Cl)2GaH2, and an empirical harmonic potential function” [Spectrochim. Acta Part A, 51 (1995) 769–777] Spectrochimica Acta Part a: Molecular and Biomolecular Spectroscopy. 51: 1455. DOI: 10.1016/0584-8539(95)01503-5  0.568
1995 Pulham CR, Downs AJ, Goode MJ, Mills IM. The vibrational spectra of natural and perdeuterated monochlorogallane, H2Ga(μ-Cl)2GaH2, and an empirical harmonic potential function Spectrochimica Acta Part a: Molecular and Biomolecular Spectroscopy. 51: 769-777. DOI: 10.1016/0584-8539(94)01288-R  0.589
1995 Downs AJ, Harman LA, Thomas PDP, Pulham CR. Hydridogallium bis(tetrahydroborate), HGa(BH4)2: Synthesis and properties Polyhedron. 14: 935-945. DOI: 10.1016/0277-5387(94)00309-3  0.65
1995 Szymańska-Buzar T, Downs AJ, Greene TM, Marshall AS. The photochemical behaviour of matrix-isolated W(CO)6 in the presence of alkynes☆ Journal of Organometallic Chemistry. 495: 163-175. DOI: 10.1016/0022-328X(95)05482-5  0.368
1995 Szymańska-Buzar T, Downs AJ, Greene TM, Marshall AS. Matrix-isolation studies of alkyne complexes in the photochemical reactions of Mo(CO)6 with alkynes Journal of Organometallic Chemistry. 495: 149-161. DOI: 10.1016/0022-328X(95)05481-4  0.375
1995 Brain PT, Rankin DWH, Robertson HE, Downs AJ, Greene TM, Hofmann M, RaguéSchleyer Pv. The molecular structure of chloromethylphosphine, CClH2PH2, as determined by gas-phase electron diffraction and ab initio computations Journal of Molecular Structure. 135-144. DOI: 10.1016/0022-2860(94)08529-Q  0.394
1994 Limberg C, Parsons S, Downs AJ, Watkin DJ. Isolation and crystal structure of a dimeric oxomolybdenum(V) complex containing two ethoxy bridges and one ethanol bridge Journal of the Chemical Society-Dalton Transactions. 1169-1174. DOI: 10.1039/Dt9940001169  0.609
1994 Downs AJ, Edwards AJ, Martin RE, Parsons S. The synthesis and crystal structure of [K(18-crown-6)]+[NCS·SO2]–(18-crown-6 = 1,4,7,10,13,16-hexaoxacyclooctadecane) Journal of the Chemical Society-Dalton Transactions. 753-757. DOI: 10.1039/Dt9940000753  0.349
1994 Downs AJ, Pulham CR. The hydrides of aluminium, gallium, indium, and thallium: a re-evaluation Chemical Society Reviews. 23: 175-184. DOI: 10.1039/Cs9942300175  0.633
1994 Limberg C, Parsons S, Downs AJ. Synthesis and X-ray crystal structure of a unique puckered six-membered metallacycle in Mo6O6Cl6(µ3-O)2(µ2-EtO)6(µ2-Cl)2 Journal of the Chemical Society, Chemical Communications. 497-498. DOI: 10.1039/C39940000497  0.564
1994 Blake AJ, Pulham CR, Greene TM, Downs AJ, Haaland A, Verne HP, Volden HV, Marsden CJ, Smart BA. Structure of Tetramethyltellurium(IV) Determined Experimentally in the Solid and Gas Phases and by ab Initio Calculations Journal of the American Chemical Society. 116: 6043-6044. DOI: 10.1021/Ja00092A095  0.604
1994 Souter PF, Andrews L, Downs AJ, Greene TM, Ma B, Schaefer HF. Observed And Calculated Raman Spectra Of The Ga2H6 And Ga2D6 Molecules The Journal of Physical Chemistry. 98: 12824-12827. DOI: 10.1021/J100100A004  0.314
1994 Downs AJ, Pulham CR. The Hunting of the Gallium Hydrides Advances in Inorganic Chemistry. 41: 171-232. DOI: 10.1016/S0898-8838(08)60172-5  0.598
1994 Downs AJ, Jones LA. Hydridoaluminium bis(tetrahydroborate): A new synthesis and some physical and chemical properties Polyhedron. 13: 2401-2415. DOI: 10.1016/S0277-5387(00)88153-X  0.377
1993 Kurth FA, Eberlein RA, Schnöckel H, Downs AJ, Pulham CR. Molecular aluminium trihydride, AlH3: generation in a solid noble gas matrix and characterisation by its infrared spectrum and Ab initio calculations Journal of the Chemical Society, Chemical Communications. 1302-1304. DOI: 10.1039/C39930001302  0.628
1992 Pulham CR, Downs AJ, Rankin DWH, Robertson HE. 2-Galla-arachno-tetraborane(10), H2GaB3H8: synthesis, properties and structure of the gaseous molecule as determined by electron diffraction Journal of the Chemical Society-Dalton Transactions. 1509-1520. DOI: 10.1039/Dt9920001509  0.646
1992 Fanfarillo M, Downs AJ, Greene TM, Almond MJ. Photooxidation of matrix-isolated iron pentacarbonyl. II: Binary iron oxide reaction products and the overall reaction mechanism Inorganic Chemistry. 31: 2973-2979. DOI: 10.1021/Ic00039A054  0.304
1992 Downs AJ, Duckworth D, Machell JC, Pulham CR. The spectroscopic properties and X-ray crystal structure of a discrete molecular alane, dimethylamidoalane, [Me2NAlH2]3 Polyhedron. 11: 1295-1304. DOI: 10.1016/S0277-5387(00)83358-6  0.615
1991 Brain PT, Downs AJ, Maccallum P, Rankin DWH, Robertson HE, Forsyth GA. The molecular structures of gaseous tetrakis(dimethylamino)-diboron, B2(NMe2)4, and tetrakis(methoxy)diboron, B2(OMe)4, as determined by electron diffraction Journal of the Chemical Society-Dalton Transactions. 1195-1200. DOI: 10.1039/Dt9910001195  0.357
1991 Dain CJ, Downs AJ, Goode MJ, Evans DG, Nicholls KT, Rankin DWH, Robertson HE. Molecular structure of gaseous titanium tris(tetrahydroborate), Ti(BH4)3: experimental determination by electron diffraction and molecular orbital analysis of some Ti(BH4)3 derivatives Journal of the Chemical Society-Dalton Transactions. 967-977. DOI: 10.1039/Dt9910000967  0.429
1991 Downs AJ, Forster AM, McGrady GS, Taylor BJ. Synthesis, physical characterisation and chemical properties of methylsulphur trifluoride, CH3SF3 Journal of the Chemical Society-Dalton Transactions. 81-87. DOI: 10.1039/Dt9910000081  0.344
1991 Pulham CR, Downs AJ, Goode MJ, Rankin DWH, Robertson HE. Gallane: synthesis, physical and chemical properties, and structure of the gaseous molecule Ga2H6 as determined by electron diffraction Journal of the American Chemical Society. 113: 5149-5162. DOI: 10.1021/Ja00014A003  0.631
1991 Greene TM, Downs AJ, Wilkinson AP. The nature of hexafluoroiodate(V) salts of the type MIF·IF5 Journal of Fluorine Chemistry. 54: 415. DOI: 10.1016/S0022-1139(00)83924-X  0.386
1991 Brown DR, Clegg MJ, Downs AJ, Fowler RC, Minihan AR, Stein L. The dixenon(l+) cation: the resolution of some outstanding problems Journal of Fluorine Chemistry. 54: 395. DOI: 10.1016/S0022-1139(00)83904-4  0.341
1991 Szymańska-Buzar T, Downs AJ, Greene TM, Wood MAK. Matrix-isolation studies of intermediates in the photochemical reaction of W(CO)6 with CCl4 Journal of Organometallic Chemistry. 419: 151-162. DOI: 10.1016/0022-328X(91)86171-L  0.334
1991 McKean DC, McQuillan GP, Torto I, Bednell NC, Downs AJ, Dickinson JM. Infrared spectra of MeTiCl3 species, methyl group geometry and a force field Journal of Molecular Structure. 247: 73-87. DOI: 10.1016/0022-2860(91)87064-O  0.356
1991 Downs AJ, Hunt NI, McGrady G, Rankin DW, Robertson HE. The molecular structure of tetramethyldiarsine, As2 (CH3)4, in the gas phase as determined by electron diffraction Journal of Molecular Structure. 248: 393-406. DOI: 10.1016/0022-2860(91)80045-6  0.403
1990 Baxter PL, Downs AJ, Goode MJ, Rankin DWH, Robertson HE. The molecular structures of the gaseous dimeric molecules Me2Ga(µ-H)2GaMe2 and Me2Ga(µ-Cl)2GaMe2 as determined by electron diffraction Journal of the Chemical Society-Dalton Transactions. 2873-2881. DOI: 10.1039/Dt9900002873  0.432
1990 Burczyk K, Downs AJ. Characterisation of monomeric methylsodium and methylpotassium: infrared spectra of the matrix-isolated molecules Journal of the Chemical Society-Dalton Transactions. 2351-2357. DOI: 10.1039/Dt9900002351  0.361
1990 Pulham CR, Downs AJ, Rankin DWH, Robertson HE. Arachno-2-gallatetraborane(10), H2GaB3H8: synthesis, properties and structure of the gaseous molecule as determined by electron diffraction Journal of the Chemical Society, Chemical Communications. 1520-1521. DOI: 10.1039/C39900001520  0.617
1990 Pulham CR, Brain PT, Downs AJ, Rankin DWH, Robertson HE. Gallaborane, H2Ga(µ-H)2BH2: synthesis, properties, and structure of the gaseous molecule as determined by electron diffraction Journal of the Chemical Society, Chemical Communications. 177-178. DOI: 10.1039/C39900000177  0.624
1990 Downs AJ, Efiong AB, Sean McGrady G, Rankin DW, Robertson HE. The molecular structure of trithiazyl trifluoride in the gas phase as determined by electron diffraction Journal of Molecular Structure. 216: 201-212. DOI: 10.1016/0022-2860(90)80328-H  0.41
1989 Downs AJ, McGrady GS, Barnfield EA, Rankin DWH. The molecular structures of gaseous tetrafluorohydridophosphorane, HPF4, and trifluorodihydridophosphorane, H2PF3, as determined by electron diffraction Journal of the Chemical Society-Dalton Transactions. 545-550. DOI: 10.1039/Dt9890000545  0.365
1989 Downs AJ, Goode MJ, Pulham CR. Gallane at last! Synthesis and properties of binary gallium hydride Journal of the American Chemical Society. 111: 1936-1937. DOI: 10.1021/Ja00187A090  0.534
1989 Appelman EH, Downs AJ, Gardner CJ. Matrix photochemistry of hypofluorous acid, HOF: oxygen atom transfer and other reactions The Journal of Physical Chemistry. 93: 598-608. DOI: 10.1021/J100339A021  0.306
1989 Downs AJ, McGrady GS, Barnfield EA, Rankin DWH, Robertson HE, Boggs JE, Dobbs KD. Molecular structures of gaseous trifluoro(methyl)sulfurane, CH3SF3, and trifluoro(trifluoromethyl)sulfurane, CF3SF3: experimental determination by electron diffraction and ab initio calculations Inorganic Chemistry. 28: 3286-3292. DOI: 10.1021/Ic00316A008  0.349
1989 Almond MJ, Forsyth GA, Rice DA, Downs AJ, Jeffery TL, Hagen K. An electron-diffraction study of gaseous tetrasulphur tetranitride, S4N4 Polyhedron. 8: 2631-2636. DOI: 10.1016/S0277-5387(00)81169-9  0.344
1989 Downs A, Foster A, McGrady G, Rankin D, Robertson H. Studies of some substituted arsenic fluorides Journal of Fluorine Chemistry. 45: 34. DOI: 10.1016/S0022-1139(00)84409-7  0.385
1989 Clegg MJ, Downs AJ. Some redox reactions of xenon(II) and chlorine systems Journal of Fluorine Chemistry. 45: 13. DOI: 10.1016/S0022-1139(00)84388-2  0.301
1989 Brain PT, Downs AJ, Fanfarillo M, Goode MJ, Massey AG, Rankin DWH, Robertson HE. The molecular structure of tetraboron tetrachloride in the gas phase, determined by electron diffraction Journal of Molecular Structure. 192: 163-170. DOI: 10.1016/0022-2860(89)87015-2  0.367
1988 Almond MJ, Downs AJ. Production of binary oxides by photolysis of M(CO)6 molecules (M = Cr, Mo, or W) isolated in O2-doped argon matrices Journal of the Chemical Society-Dalton Transactions. 809-817. DOI: 10.1039/Dt9880000809  0.31
1988 Downs AJ, Goode MJ, McGrady GS, Steer IA, Rankin DWH, Robertson HE. The molecular structure of gaseous trimethylarsenic difluoride as determined by electron diffraction Journal of the Chemical Society-Dalton Transactions. 451-456. DOI: 10.1039/Dt9880000451  0.385
1988 Goode MJ, Downs AJ, Pulham CR, Rankin DWH, Robertson HE. Monochlorogallane: synthesis, properties, and structure of the dimer H2Ga(µ-Cl)2GaH2 in the gas phase as determined by electron diffraction Journal of the Chemical Society, Chemical Communications. 768-769. DOI: 10.1039/C39880000768  0.628
1988 Mehner T, Schnöckel H, Almond MJ, Downs AJ. Transition metal derivatives of SiO: interaction of molecular SiO with silver atoms in an argon matrix Journal of the Chemical Society, Chemical Communications. 117-119. DOI: 10.1039/C39880000117  0.309
1986 Downs AJ, Gardner CJ. Some reactions of uranium chloride pentafluoride Journal of the Chemical Society, Dalton Transactions. 1289-1296. DOI: 10.1039/Dt9860001289  0.353
1986 Baxter PL, Downs AJ, Goode MJ, Rankin DWH, Robertson HE. The synthesis and properties of dimethylgallane: structure of the dimer Me2Ga(µ-H)2GaMe2 in the gas phase as determined by electron diffraction Journal of the Chemical Society, Chemical Communications. 805-806. DOI: 10.1039/C39860000805  0.405
1986 Berry A, Dawoodi Z, Derome AE, Dickinson JM, Downs AJ, Green JC, Green MLH, Hare PM, Payne MP, Rankin DWH, Robertson HE. Symmetrical distortion of the methyl group of methyltrichlorotitanium: gas phase structure and H,H coupling constant Journal of the Chemical Society, Chemical Communications. 520-522. DOI: 10.1039/C39860000520  0.34
1986 ALMOND MJ, CRAYSTON JA, DOWNS AJ, POLIAKOFF M, TURNER JJ. ChemInform Abstract: Peroxo and Dioxo Metal Carbonyl Intermediates in the Photooxidation of Matrix- Isolated M(CO)6(M: Cr, Mo, W) in the Presence of Dioxygen: A Vibrational Spectroscopic Study Using 18O. Chemischer Informationsdienst. 17. DOI: 10.1002/Chin.198620272  0.342
1985 Baxter PL, Downs AJ, Forster AM, Goode MJ, Rankin DWH, Robertson HE. The molecular structure of gaseous bis(trifluoromethyl)selenium difluoride as determined by electron diffraction Journal of the Chemical Society-Dalton Transactions. 941-945. DOI: 10.1039/Dt9850000941  0.385
1985 Baxter PL, Downs AJ, Rankin DWH, Robertson HE. The molecular structure of gaseous dimethylamidogallane: characterization of the dimer [Me2NGaH2]2 by electron diffraction and vibrational spectroscopy Journal of the Chemical Society-Dalton Transactions. 807-814. DOI: 10.1039/Dt9850000807  0.409
1985 Forster AM, Downs AJ. Reactions of xenon difluoride: Oxidative fluorination of methyl derivatives of the p-block elements Polyhedron. 4: 1625-1635. DOI: 10.1016/S0277-5387(00)87239-3  0.317
1985 Baxter PL, Downs AJ, Forster AM, Goode MJ, Rankin DWH, Robertson HE. The Molecular Structure Of Gaseous Bis(Trifluoromethyl)Selenium Difluoride As Determined By Electron Diffraction Cheminform. 16. DOI: 10.1002/Chin.198537051  0.36
1985 Baxter PL, Downs AJ, Rankin DWH, Robertson HE. The Molecular Structure Of Gaseous Dimethylamidogallane: Characterization Of The Dimer (Me2Ngah2)2 By Electron Diffraction And Vibrational Spectroscopy Cheminform. 16. DOI: 10.1002/Chin.198532055  0.376
1984 Forster AM, Downs AJ. Fluorination of dimethyl sulphide. Formation of the fluorodimethylsulphonium cation, [Me2SF]+, and dimethylsulphur difluoride, Me2SF2 Journal of the Chemical Society-Dalton Transactions. 2827-2834. DOI: 10.1039/Dt9840002827  0.353
1984 Downs AJ, Gardner CJ. Formation and characterization of uranium(VI) chloride fluorides, UF<inf>n</inf>Cl<inf>6-n</inf> (n = 1-5) Journal of the Chemical Society, Dalton Transactions. 2127-2132. DOI: 10.1039/Dt9840002127  0.322
1984 Baxter PL, Downs AJ, Rankin DWH. The molecular structure of trimethylamine–gallane in the gas phase as determined by electron diffraction Journal of the Chemical Society-Dalton Transactions. 1755-1758. DOI: 10.1039/Dt9840001755  0.395
1984 Hawkins M, Downs AJ. Photochemistry of argon matrixes containing nitric oxide and carbonyl sulfide. 1. The photolysis of the nitric oxide dimer, cis-N2O2 The Journal of Physical Chemistry. 88: 1527-1533. DOI: 10.1021/J150652A017  0.315
1984 Baxter PL, Downs AJ, Rankin DWH. The Molecular Structure Of Trimethylamine-Gallane In The Gas Phase As Determined By Electron Diffraction Cheminform. 15. DOI: 10.1002/Chin.198447073  0.379
1982 Dain CJ, Downs AJ, Rankin DWH. Electron Diffraction Determination Of The Structure Of Gaseous Titanium Tris(Tetrahydridoborate) Cheminform. 13. DOI: 10.1002/Chin.198240001  0.34
1982 Barlow MT, Dain CJ, Downs AJ, Laurenson GS, Rankin DWH. Group Iiia Tetrahydroborates. Part 4. The Molecular Structure Of Hydridogallium Bis(Tetrahydroborate) In The Gas Phase As Determined By Electron Diffraction Cheminform. 13. DOI: 10.1002/Chin.198224001  0.385
1982 Dain CJ, Downs AJ, Rankin DWH. Molecular Structures Of Dimethylaluminum Octahydrotriborate And Dimethylgallium Octahydrotriborate In The Gas Phase As Determined By Electron Diffraction Cheminform. 13. DOI: 10.1002/Chin.198209253  0.378
1982 Dain CJ, Downs AJ, Rankin DWH. The Molecular Structure of Gaseous Titanium Tris(tetrahydridoborate) as Determined by Electron Diffraction Angewandte Chemie. 21: 534-535. DOI: 10.1002/Anie.198205341  0.355
1981 Dain CJ, Downs AJ, Rankin DWH. Molecular structures of dimethylaluminium octahydrotriborate and dimethylgallium octahydrotriborate in the gas phase as determined by electron diffraction Journal of the Chemical Society-Dalton Transactions. 2465-2470. DOI: 10.1039/Dt9810002465  0.391
1981 Dain CJ, Downs AJ, Laurenson GS, Rankin DWH. The molecular structure of tetraborane(10) in the gas phase as determined by a joint analysis of electron-diffraction and microwave data Journal of the Chemical Society-Dalton Transactions. 472-477. DOI: 10.1039/Dt9810000472  0.342
1981 Dain CJ, Downs AJ, Laurenson GS, Rankin DWH. The Molecular Structure Of Tetraborane(10) In The Gas Phase As Determined By A Joint Analysis Of Electron Diffraction And Microwave Data Cheminform. 12. DOI: 10.1002/Chin.198119003  0.367
1980 Barlow MT, Dain CJ, Downs AJ, Thomas PDP, Rankin DWH. Group 3 tetrahydroborates. Part 3. The molecular structure of methylaluminium bis(tetrahydroborate) in the gas phase as determined by electron diffraction Journal of the Chemical Society-Dalton Transactions. 1374-1378. DOI: 10.1039/Dt9800001374  0.353
1980 Findlay RH, Palmer MH, Downs AJ, Egdell RG, Evans R. Electronic structure of the sulfur nitrides. Ab initio calculations and photoelectron spectra Inorganic Chemistry. 19: 1307-1314. DOI: 10.1021/Ic50207A040  0.362
1980 Barlow MT, Dain CJ, Downs AJ, Thomas PDP, Rankin DWH. Group 3A Tetrahydroborates. Part 3. The Molecular Structure Of Methylaluminum M Bis(Tetrahydroborate) In The Gas Phase As Determined By Electron Diffraction Cheminform. 11. DOI: 10.1002/Chin.198046071  0.362
1980 FINDLAY RH, PALMER MH, DOWNS AJ, EGDELL RG, EVANS R. ChemInform Abstract: ELECTRONIC STRUCTURE OF THE SULFUR NITRIDES. AB INITIO CALCULATIONS AND PHOTOELECTRON SPECTRA Chemischer Informationsdienst. 11. DOI: 10.1002/Chin.198030003  0.365
1980 Barlow MT, Downs AJ, Thomas PDP, Rankin DWH. Group 3A-Tetrahydroborates. Part 2. The Molecular Structures Of Dimethylaluminum Tetrahydroborate And Dimethylgallium Tetrahydroborate In The Gas Phase As Determined By Electron Diffraction Cheminform. 11. DOI: 10.1002/Chin.198007086  0.352
1979 Barlow MT, Downs AJ, Thomas PDP, Rankin DWH. Group 3 tetrahydroborates. Part 2. The molecular structures of dimethylaluminium tetrahydroborate and dimethylgallium tetrahydroborate in the gas phase as determined by electron diffraction Journal of the Chemical Society-Dalton Transactions. 1793-1800. DOI: 10.1039/Dt9790001793  0.323
1978 Downs AJ, Egdell RG, Orchard AF, Thomas PDP. Photoelectron spectra of metal tetrahydroborates Journal of the Chemical Society, Dalton Transactions. 1755-1761. DOI: 10.1039/Dt9780001755  0.321
1978 Downs AJ, Thomas PDP. Group 3 tetrahydroborates. Part 1. The synthesis and properties of dimethylgallium tetrahydroborate Journal of the Chemical Society-Dalton Transactions. 809-817. DOI: 10.1039/Dt9780000809  0.444
1978 Stein L, Norris JR, Downs AJ, Minihan AR. Formation of the dixenon cation, Xe<inf>2</inf><sup>+</sup>, in fluoroantimonate(V) media by oxidation-reduction methods: Spectroscopic properties of the ion Journal of the Chemical Society, Chemical Communications. 502-504. DOI: 10.1039/C39780000502  0.311
1978 Bürger H, Pawelke G, Haas A, Willner H, Downs A. Vibrational spectra and normal coordinate analysis of CF3 compounds—XVIII [1]. N(SCF3)3—14N and 15N versions Spectrochimica Acta Part a: Molecular Spectroscopy. 34: 287-292. DOI: 10.1016/0584-8539(78)80147-0  0.571
1974 Peake SC, Downs AJ. Infrared spectra, structures, and force constants of the matrix-isolated thiazyl halides CISN and BrSN Journal of the Chemical Society-Dalton Transactions. 859-864. DOI: 10.1039/Dt9740000859  0.368
1974 Peake SC, Downs AJ. Infrared Spectra, Structures, And Force Constants Of The Matrix-Isolated Thiazyl Halides Clsn And Brsn Cheminform. 5. DOI: 10.1002/Chin.197425002  0.317
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