Alan Armstrong, Ph.D - Publications

Affiliations: 
1990-1992 Chemistry Columbia University, New York, NY 
 1992-1996 Chemistry Bath 
 1996-1999 Chemistry University of Nottingham, Nottingham, England, United Kingdom 
 1999- Chemistry Imperial College London, London, England, United Kingdom 
Area:
Synthetic organic chemistry, Catalysis
Website:
http://www3.imperial.ac.uk/people/a.armstrong

43 high-probability publications. We are testing a new system for linking publications to authors. You can help! If you notice any inaccuracies, please sign in and mark papers as correct or incorrect matches. If you identify any major omissions or other inaccuracies in the publication list, please let us know.

Year Citation  Score
2021 Jamshidiha M, Lanyon-Hogg T, Sutherell CL, Craven GB, Tersa M, De Vita E, Brustur D, Pérez-Dorado I, Hassan S, Petracca R, Morgan RM, Sanz-Hernández M, Norman JC, Armstrong A, Mann DJ, et al. Identification of the first structurally validated covalent ligands of the small GTPase RAB27A. Rsc Medicinal Chemistry. 13: 150-155. PMID 35308027 DOI: 10.1039/d1md00225b  0.471
2019 Craven GB, Affron DP, Raymond PN, Mann DJ, Armstrong A. Vinyl sulfonamide synthesis for irreversible tethering a novel α-selenoether protection strategy. Medchemcomm. 10: 158-163. PMID 30774862 DOI: 10.1039/C8Md00566D  0.322
2018 Craven G, Affron D, Allen C, Matthies S, Greener J, Morgan R, Tate E, Armstrong A, Mann DJ. High-Throughput Kinetic Analysis for Target-Directed Covalent Ligand Discovery. Angewandte Chemie (International Ed. in English). PMID 29480525 DOI: 10.1002/Anie.201711825  0.528
2016 Burés J, Armstrong A, Blackmond DG. Explaining Anomalies in Enamine Catalysis: "Downstream Species" as a New Paradigm for Stereocontrol. Accounts of Chemical Research. PMID 26830669 DOI: 10.1021/Acs.Accounts.5B00394  0.352
2016 Sung S, Sale D, Braddock DC, Armstrong A, Brennan C, Davies RP. Mechanistic Studies on the Copper-Catalyzed N-Arylation of Alkylamines Promoted by Organic Soluble Ionic Bases Acs Catalysis. 6: 3965-3974. DOI: 10.1021/Acscatal.6B00504  0.708
2015 Sung S, Braddock DC, Armstrong A, Brennan C, Sale D, White AJ, Davies RP. Synthesis, characterisation and reactivity of copper(I) amide complexes and studies on their role in the modified Ullmann amination reaction. Chemistry (Weinheim An Der Bergstrasse, Germany). 21: 7179-92. PMID 25788223 DOI: 10.1002/Chem.201405699  0.695
2015 Leung W, Shaffer CD, Reed LK, Smith ST, Barshop W, Dirkes W, Dothager M, Lee P, Wong J, Xiong D, Yuan H, Bedard JE, Machone JF, Patterson SD, Price AL, ... ... Armstrong AR, et al. Drosophila muller f elements maintain a distinct set of genomic properties over 40 million years of evolution. G3 (Bethesda, Md.). 5: 719-40. PMID 25740935 DOI: 10.1534/G3.114.015966  0.361
2015 Allen CE, Curran PR, Brearley AS, Boissel V, Sviridenko L, Press NJ, Stonehouse JP, Armstrong A. Efficient and facile synthesis of acrylamide libraries for protein-guided tethering. Organic Letters. 17: 458-60. PMID 25582165 DOI: 10.1021/Ol503486T  0.327
2014 Burés J, Dingwall P, Armstrong A, Blackmond DG. Rationalization of an unusual solvent-induced inversion of enantiomeric excess in organocatalytic selenylation of aldehydes. Angewandte Chemie (International Ed. in English). 53: 8700-4. PMID 25044727 DOI: 10.1002/Anie.201404327  0.346
2013 Struebing H, Ganase Z, Karamertzanis PG, Siougkrou E, Haycock P, Piccione PM, Armstrong A, Galindo A, Adjiman CS. Computer-aided molecular design of solvents for accelerated reaction kinetics. Nature Chemistry. 5: 952-7. PMID 24153374 DOI: 10.1038/Nchem.1755  0.331
2013 Burés J, Armstrong A, Blackmond DG. The interplay of thermodynamics and kinetics in dictating organocatalytic reactivity and selectivity Pure and Applied Chemistry. 85: 1919-1934. DOI: 10.1351/Pac-Con-13-01-14  0.353
2013 Armstrong A, Braddock DC, Jones AX, Clark S. Catalytic asymmetric bromolactonization reactions using (DHQD)2PHAL-benzoic acid combinations Tetrahedron Letters. 54: 7004-7008. DOI: 10.1016/J.Tetlet.2013.10.043  0.322
2012 Armstrong A, Ferguson A. Synthesis and ring openings of cinnamate-derived N-unfunctionalised aziridines. Beilstein Journal of Organic Chemistry. 8: 1747-52. PMID 23209508 DOI: 10.3762/Bjoc.8.199  0.331
2012 Burés J, Armstrong A, Blackmond DG. Curtin-Hammett paradigm for stereocontrol in organocatalysis by diarylprolinol ether catalysts. Journal of the American Chemical Society. 134: 6741-50. PMID 22452319 DOI: 10.1021/Ja300415T  0.343
2012 Burés J, Armstrong A, Blackmond DG. Kinetic correlation between aldehyde/enamine stereoisomers in reactions between aldehydes with α -stereocenters and chiral pyrrolidine-based catalysts Chemical Science. 3: 1273-1277. DOI: 10.1039/C2Sc01082H  0.357
2011 Hein JE, Burés J, Lam YH, Hughes M, Houk KN, Armstrong A, Blackmond DG. Enamine carboxylates as stereodetermining intermediates in prolinate catalysis. Organic Letters. 13: 5644-7. PMID 21958394 DOI: 10.1021/Ol2023533  0.339
2011 Hein JE, Armstrong A, Blackmond DG. Kinetic profiling of prolinate-catalyzed α-amination of aldehydes Organic Letters. 13: 4300-4303. PMID 21761822 DOI: 10.1021/Ol201639Z  0.345
2011 Burés J, Armstrong A, Blackmond DG. Mechanistic rationalization of organocatalyzed conjugate addition of linear aldehydes to nitro-olefins. Journal of the American Chemical Society. 133: 8822-5. PMID 21568340 DOI: 10.1021/Ja203660R  0.355
2011 Armstrong A, Deacon N, Donald C. Enantioselective synthesis of -aminophosphonates via organocatalytic sulfenylation and [2,3]-sigmatropic sulfimide rearrangement Synlett. 2347-2350. DOI: 10.1055/S-0030-1260309  0.338
2010 Blackmond DG, Moran A, Hughes M, Armstrong A. Unusual reversal of enantioselectivity in the proline-mediated α-amination of aldehydes induced by tertiary amine additives Journal of the American Chemical Society. 132: 7598-7599. PMID 20465280 DOI: 10.1021/Ja102718X  0.323
2010 Blackmond DG, Moran A, Hughes M, Armstrong A. Inversion of Enantioselectivity in Proline Catalysis by BasicAdditives Synfacts. 2010: 950-950. DOI: 10.1055/S-0030-1257799  0.322
2010 LEY SV, ARMSTRONG A. ChemInform Abstract: The Champagne Route to Avermectins and Milbemycins Cheminform. 23: no-no. DOI: 10.1002/chin.199230271  0.302
2009 Armstrong A, Bhonoah Y, White AJ. Constrained beta-proline analogues in organocatalytic aldol reactions: the influence of acid geometry. The Journal of Organic Chemistry. 74: 5041-8. PMID 19485343 DOI: 10.1021/Jo900840V  0.331
2009 Zotova N, Broadbelt LJ, Armstrong A, Blackmond DG. Kinetic and mechanistic studies of proline-mediated direct intermolecular aldol reactions Bioorganic and Medicinal Chemistry Letters. 19: 3934-3937. PMID 19362473 DOI: 10.1016/J.Bmcl.2009.03.112  0.343
2009 Armstrong A, Emmerson DP. Enantioselective synthesis of allenamides via sulfimide [2,3]-sigmatropic rearrangement. Organic Letters. 11: 1547-50. PMID 19254002 DOI: 10.1021/Ol900146S  0.318
2009 Zotova N, Moran A, Armstrong A, Blackmond DG. A coherent mechanistic rationale for additive effects and autoinductive behaviour in proline-mediated reactions Advanced Synthesis and Catalysis. 351: 2765-2769. DOI: 10.1002/Adsc.200900665  0.342
2007 Zotova N, Franzke A, Armstrong A, Blackmond DG. Clarification of the role of water in proline-mediated aldol reactions Journal of the American Chemical Society. 129: 15100-15101. PMID 18001021 DOI: 10.1021/Ja0738881  0.315
2006 Mathew SP, Klussmann M, Iwamura H, Wells DH, Armstrong A, Blackmond DG. A mechanistic rationalization of unusual kinetic behavior in proline-mediated C-O and C-N bond-forming reactions. Chemical Communications (Cambridge, England). 4291-3. PMID 17047844 DOI: 10.1039/B609926B  0.351
2006 Klussmann M, Iwamura H, Mathew SP, Wells DH, Pandya U, Armstrong A, Blackmond DG. Thermodynamic control of asymmetric amplification in amino acid catalysis Nature. 441: 621-623. PMID 16738656 DOI: 10.1038/Nature04780  0.35
2006 Armstrong A, Challinor L, Cooke RS, Moir JH, Treweeke NR. Oxaziridine-mediated amination of branched allylic sulfides: stereospecific formation of allylic amine derivatives via [2,3]-sigmatropic rearrangement. The Journal of Organic Chemistry. 71: 4028-30. PMID 16674092 DOI: 10.1021/Jo060369S  0.353
2005 Armstrong A, Jones LH, Knight JD, Kelsey RD. Oxaziridine-mediated amination of primary amines: scope and application to a one-pot pyrazole synthesis. Organic Letters. 7: 713-6. PMID 15704932 DOI: 10.1021/Ol0474507  0.362
2002 Armstrong A, Cooke RS. Efficient amination of sulfides with a ketomalonate-derived oxaziridine: application to [2,3]-sigmatropic rearrangements of allylic sulfimides. Chemical Communications (Cambridge, England). 904-5. PMID 12123037 DOI: 10.1039/B201791A  0.319
2001 Armstrong A, Atkin MA, Swallow S. Asymmetric electrophilic amination of enolates by a chiral N-alkoxycarbonyloxaziridine Tetrahedron: Asymmetry. 12: 535-538. DOI: 10.1016/S0957-4166(01)00104-5  0.326
2000 Armstrong A, Atkin MA, Swallow S. Electrophilic amination of carbanions by N-carboxamido oxaziridines Tetrahedron Letters. 41: 2247-2251. DOI: 10.1016/S0040-4039(00)00140-4  0.331
1996 Armstrong A, Barsanti PA, Clarke PA, Wood A. Ketone-directed peracid epoxidation of cyclic alkenes Journal of the Chemical Society - Perkin Transactions 1. 1373-1380. DOI: 10.1039/P19960001373  0.536
1996 Armstrong A, Clarke PA, Wood A. Evidence that a dioxirane is not responsible for alkene epoxidation in a ketone–Oxone® system Chemical Communications. 849-850. DOI: 10.1039/Cc9960000849  0.483
1994 Burger MT, Armstrong A, Guarnieri F, M DQ, Still WC. Free energy calculations in molecular design: Predictions by theory and reality by experiment with enantioselective podand ionophores Journal of the American Chemical Society. 116: 3593-3594. DOI: 10.1021/Ja00087A053  0.498
1992 Armstrong A, Still WC. Enantioselective cation binding with a functionalized podand ionophore Journal of Organic Chemistry. 57: 4580-4582. DOI: 10.1021/Jo00043A010  0.512
1991 Ley SV, Armstrong A, Díez-Martín D, Ford MJ, Grice P, Knight JG, Kolb HC, Madin A, Marby CA, Mukherjee S, Shaw AN, Slawin AMZ, Vile S, White AD, Williams DJ, et al. Total synthesis of the anthelmintic macrolide avermectin B1a Journal of the Chemical Society-Perkin Transactions 1. 667-692. DOI: 10.1039/P19910000667  0.649
1990 Armstrong A, Ley SV, Madin A, Mukherjee S. Total Synthesis of Avermectin B1a: Final Coupling Reactions and the Total Synthesis of Avermectin B1a Aglycone Synlett. 1990: 328-330. DOI: 10.1055/S-1990-21080  0.467
1990 Armstrong A, Ley SV. Total Synthesis of Avermectin B1a: Planning of the Synthesis and Preparation of the C1-C10 "Southern" Hydrobenzofuran Fragment Synlett. 1990: 323-325. DOI: 10.1055/S-1990-21078  0.436
1989 Anthony NJ, Armstrong A, Ley SV, Madin A. Total synthesis of (+)-milbemycin β1 Tetrahedron Letters. 30: 3209-3212. DOI: 10.1016/S0040-4039(00)99203-7  0.432
1989 Ley SV, Anthony NJ, Armstrong A, Brasca MG, Clarke T, Culshaw D, Greck C, Grice P, Jones AB, Lygo B, Madin A, Sheppard RN, Slawin AMZ, Williams DJ. A highly convergent total synthesis of the spiroacetal macrolide (+)-milbemycinβ1 Tetrahedron. 45: 7161-7194. DOI: 10.1016/S0040-4020(01)89182-1  0.655
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