Karen I. Goldberg, Ph.D. - Publications

Affiliations: 
1989-1995 Illinois State University, Normal, IL, United States 
 1995- Chemistry University of Washington, Seattle, Seattle, WA 
 2017- Chemistry University of Pennsylvania, Philadelphia, PA, United States 
Area:
Inorganic Chemistry
Website:
https://www.chem.upenn.edu/profile/karen-i-goldberg

143 high-probability publications. We are testing a new system for linking publications to authors. You can help! If you notice any inaccuracies, please sign in and mark papers as correct or incorrect matches. If you identify any major omissions or other inaccuracies in the publication list, please let us know.

Year Citation  Score
2024 Phearman AS, Ardon Y, Goldberg KI. Insertion of Molecular Oxygen into a Gold(III)-Hydride Bond. Journal of the American Chemical Society. PMID 38290523 DOI: 10.1021/jacs.3c12285  0.333
2022 Zeitler HE, Phearman AS, Gau MR, Carroll PJ, Cundari TR, Goldberg KI. Metal-Ligand-Anion Cooperation in C-H Bond Formation at Platinum(II). Journal of the American Chemical Society. 144: 14446-14451. PMID 35881991 DOI: 10.1021/jacs.2c05096  0.422
2022 Jain AK, Gau MR, Carroll PJ, Goldberg KI. The underappreciated influence of ancillary halide on metal-ligand proton tautomerism. Chemical Science. 13: 7837-7845. PMID 35865898 DOI: 10.1039/d2sc00279e  0.624
2020 Kuo JL, Goldberg KI. Metal/Ligand Proton Tautomerism Facilitates Dinuclear H Reductive Elimination. Journal of the American Chemical Society. PMID 33297680 DOI: 10.1021/jacs.0c10458  0.612
2020 Goldberg JM, Guard LM, Wong GW, Brayton DF, Kaminsky W, Goldberg KI, Heinekey DM. Preparation and Reactivity of Bimetallic (pincer)Ir Complexes Organometallics. DOI: 10.1021/Acs.Organomet.0C00403  0.709
2020 Zahora BA, Gau MR, Goldberg KI. Synthesis and Reactivity of PtII Methyl Complexes Supported by Pyrazolate Pincer Ligands Organometallics. 39: 1230-1237. DOI: 10.1021/Acs.Organomet.0C00023  0.451
2019 Wright AM, Pahls DR, Gary JB, Warner T, Williams JZ, M Knapp SM, Allen KE, Landis CR, Cundari TR, Goldberg KI. Experimental and Computational Investigation of the Aerobic Oxidation of a Late Transition Metal-Hydride. Journal of the American Chemical Society. PMID 31259542 DOI: 10.1021/Jacs.9B04706  0.808
2019 Bailey WD, Phearman AS, Luconi L, Rossin A, Yakhvarov D, D'Accolti L, Flowers SE, Kaminsky W, Kemp RA, Giambastiani G, Goldberg KI. Hydrogenolysis of dinuclear PCNR ligated PdII μ-hydroxides and their mononuclear PdII hydroxide analogues. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 31090244 DOI: 10.1002/Chem.201900507  0.401
2019 Syed Z, Kaphan D, Perras FA, Pruski M, Ferrandon MS, Wegener EC, Celik G, Wen J, Liu C, Dogan F, Goldberg KI, Delferro M. Electrophilic Organoiridium(III) Pincer Complexes on Sulfated Zirconia for Hydrocarbon Activation and Functionalization. Journal of the American Chemical Society. PMID 30900885 DOI: 10.1021/Jacs.9B00896  0.448
2019 Chu W, Culakova Z, Wang BT, Goldberg KI. Acid-Assisted Hydrogenation of CO2 to Methanol in a Homogeneous Catalytic Cascade System Acs Catalysis. 9: 9317-9326. DOI: 10.1021/Acscatal.9B02280  0.699
2018 Artús Suàrez L, Culakova Z, Balcells D, Bernskoetter WH, Eisenstein O, Goldberg KI, Hazari N, Tilset M, Nova A. The Key Role of the Hemiaminal Intermediate in the Iron-Catalyzed Deaminative Hydrogenation of Amides Acs Catalysis. 8: 8751-8762. DOI: 10.1021/Acscatal.8B02184  0.35
2018 Zeitler HE, Kaminsky WA, Goldberg KI. Insertion of Molecular Oxygen into the Metal–Methyl Bonds of Platinum(II) and Palladium(II) 1,3-Bis(2-pyridylimino)isoindolate Complexes Organometallics. 37: 3644-3648. DOI: 10.1021/Acs.Organomet.8B00573  0.436
2017 Goldberg KI, Goldman AS. Large-Scale Selective Functionalization of Alkanes. Accounts of Chemical Research. 50: 620-626. PMID 28945401 DOI: 10.1021/Acs.Accounts.6B00621  0.336
2017 Goldberg JM, Goldberg KI, Heinekey DM, Burgess SA, Lao DB, Linehan JC. Detection of an Iridium-Dihydrogen Complex: A Proposed Intermediate in Ionic Hydrogenation. Journal of the American Chemical Society. PMID 28862847 DOI: 10.1021/Jacs.7B06480  0.804
2017 Stevens TE, Smoll KA, Goldberg KI. Direct Formation of Carbon(sp(3))-Heteroatom Bonds from Rh(III) To Produce Methyl Iodide, Thioethers, and Alkylamines. Journal of the American Chemical Society. PMID 28574703 DOI: 10.1021/Jacs.7B04169  0.405
2017 Gao Y, Guan C, Zhou M, Kumar A, Emge TJ, Wright AM, Goldberg KI, Krogh-Jespersen K, Goldman AS. β-Hydride Elimination and C-H Activation by an Iridium Acetate Complex, Catalyzed by Lewis Acids. Alkane Dehydrogenation Co-Catalyzed by Lewis Acids and (Phebox)Ir. Journal of the American Chemical Society. PMID 28418249 DOI: 10.1021/Jacs.6B12995  0.75
2017 Smoll KA, Kaminsky W, Goldberg KI. Photolysis of Pincer-Ligated PdII–Me Complexes in the Presence of Molecular Oxygen Organometallics. 36: 1213-1216. DOI: 10.1021/Acs.Organomet.7B00020  0.376
2017 Goldberg JM, Berman JL, Kaminsky W, Goldberg KI, Heinekey DM. Oxidative addition of iodine to (tBu)4(POCOP)Ir(CO) complexes Journal of Organometallic Chemistry. 845: 171-176. DOI: 10.1016/J.Jorganchem.2017.04.036  0.794
2017 Parkes MV, Bailey WD, Goldberg KI, Kemp RA. The Effect of the cis-donor in pincer ligands on hydrogenolysis of Pd-OH: A DFT study Journal of Organometallic Chemistry. 845: 165-170. DOI: 10.1016/J.Jorganchem.2017.04.026  0.461
2017 Goldberg K, Milstein D. Bond Activation by Metal Complexes: Special Issue in Honor of the 2017 Wolf Prize Laureate in Chemistry, Professor Robert G. Bergman Israel Journal of Chemistry. 57: 915-915. DOI: 10.1002/Ijch.201700125  0.36
2016 Brewster TP, Goldberg JM, Tran JC, Heinekey DM, Goldberg KI. High Catalytic Efficiency Combined with High Selectivity for the Aldehyde-Water Shift Reaction using (para-cymene)Ruthenium Precatalysts Acs Catalysis. 6: 6302-6305. DOI: 10.1021/Acscatal.6B02130  0.765
2016 Brewster TP, Rezayee NM, Culakova Z, Sanford MS, Goldberg KI. Base-Free Iridium-Catalyzed Hydrogenation of Esters and Lactones Acs Catalysis. 6: 3113-3117. DOI: 10.1021/Acscatal.6B00263  0.405
2016 Goldberg JM, Cherry SDT, Guard LM, Kaminsky W, Goldberg KI, Heinekey DM. Hydrogen Addition to (pincer)IrI(CO) Complexes: The Importance of Steric and Electronic Factors Organometallics. 35: 3546-3556. DOI: 10.1021/Acs.Organomet.6B00598  0.799
2015 Goldberg JM, Wong GW, Brastow KE, Kaminsky W, Goldberg KI, Heinekey DM. The importance of steric factors in iridium pincer complexes Organometallics. 34: 753-762. DOI: 10.1021/Om501166W  0.799
2015 Bailey WD, Luconi L, Rossin A, Yakhvarov D, Flowers SE, Kaminsky W, Kemp RA, Giambastiani G, Goldberg KI. Pyrazole-Based PCN Pincer Complexes of Palladium(II): Mono- and Dinuclear Hydroxide Complexes and Ligand Rollover C-H Activation Organometallics. 34: 3998-4010. DOI: 10.1021/Acs.Organomet.5B00355  0.455
2014 Clement ML, Grice KA, Luedtke AT, Kaminsky W, Goldberg KI. Platinum(II) olefin hydroarylation catalysts: tuning selectivity for the anti-Markovnikov product. Chemistry (Weinheim An Der Bergstrasse, Germany). 20: 17287-91. PMID 25377546 DOI: 10.1002/Chem.201405174  0.799
2014 Scheuermann ML, Goldberg KI. Reactions of Pd and Pt complexes with molecular oxygen. Chemistry (Weinheim An Der Bergstrasse, Germany). 20: 14556-68. PMID 25303084 DOI: 10.1002/Chem.201402599  0.461
2014 Scheuermann ML, Grice KA, Ruppel MJ, Roselló-Merino M, Kaminsky W, Goldberg KI. Hemilability of P(X)N-type ligands (X = O, N-H): rollover cyclometalation and benzene C-H activation from (P(X)N)PtMe2 complexes. Dalton Transactions (Cambridge, England : 2003). 43: 12018-25. PMID 24975590 DOI: 10.1039/C4Dt01143K  0.703
2014 Scheuermann ML, Boyce DW, Grice KA, Kaminsky W, Stoll S, Tolman WB, Swang O, Goldberg KI. Oxygen-promoted C-H bond activation at palladium. Angewandte Chemie (International Ed. in English). 53: 6492-5. PMID 24817523 DOI: 10.1002/Anie.201402484  0.749
2014 Pahls DR, Allen KE, Goldberg KI, Cundari TR. Understanding the effect of ancillary ligands on concerted metalation-deprotonation by (dmPhebox)Ir(OAc)2(H2O) complexes: A DFT study Organometallics. 33: 6413-6419. DOI: 10.1021/Om500752M  0.646
2014 Gladysz JA, Bedford RB, Fujita M, Gabbaï FP, Goldberg KI, Holland PL, Kiplinger JL, Krische MJ, Louie J, Lu CC, Norton JR, Petrukhina MA, Ren T, Stahl SS, Tilley TD, et al. Organometallics roundtable 2013-2014 Organometallics. 33: 1505-1527. DOI: 10.1021/Om500253Z  0.721
2014 Prantner JD, Kaminsky W, Goldberg KI. Methylplatinum(II) and molecular oxygen: Oxidation to methylplatinum(IV) in competition with methyl group transfer to form dimethylplatinum(IV) Organometallics. 33: 3227-3230. DOI: 10.1021/Om500243N  0.79
2014 Bailey WD, Kaminsky W, Kemp RA, Goldberg KI. Synthesis and characterization of anionic, neutral, and cationic PNP pincer PdII and PtII hydrides Organometallics. 33: 2503-2509. DOI: 10.1021/Om500054F  0.471
2014 Miller AJM, Kaminsky W, Goldberg KI. Arene activation at iridium facilitates C-O bond cleavage of aryl ethers Organometallics. 33: 1245-1252. DOI: 10.1021/Om5000166  0.397
2014 Allen KE, Heinekey DM, Goldman AS, Goldberg KI. Regeneration of an Iridium(III) complex active for alkane dehydrogenation using molecular oxygen Organometallics. 33: 1337-1340. DOI: 10.1021/Om401241E  0.722
2014 Brewster TP, Ou WC, Tran JC, Goldberg KI, Hanson SK, Cundari TR, Heinekey DM. Iridium, rhodium, and ruthenium catalysts for the "aldehyde-water shift" reaction Acs Catalysis. 4: 3034-3038. DOI: 10.1021/Cs500843A  0.668
2014 Gruhn NE, Goldberg KI, Brookhart M. Virtual issue on research in the center for enabling new technologies through catalysis (CENTC) Acs Catalysis. 4: 1318-1319. DOI: 10.1021/Cs500312Z  0.453
2014 Bailey WD, Parkes MV, Kemp RA, Goldberg KI. Reactions of Square-Planar d8 Pincer Complexes with Oxygen and Hydrogen Pincer and Pincer-Type Complexes: Applications in Organic Synthesis and Catalysis. 281-298. DOI: 10.1002/9783527681303.ch11  0.313
2014 Barnett SM, Waidmann CR, Scheuermann ML, Nesvet JC, Goldberg K, Mayer JM. Developing Molecular Copper Complexes for Water Oxidation Molecular Water Oxidation Catalysis: a Key Topic For New Sustainable Energy Conversion Schemes. 187-210. DOI: 10.1002/9781118698648.ch10  0.463
2013 Brewster TP, Miller AJ, Heinekey DM, Goldberg KI. Hydrogenation of carboxylic acids catalyzed by half-sandwich complexes of iridium and rhodium. Journal of the American Chemical Society. 135: 16022-5. PMID 24144194 DOI: 10.1021/Ja408149N  0.743
2013 Miller AJ, Heinekey DM, Mayer JM, Goldberg KI. Catalytic disproportionation of formic acid to generate methanol. Angewandte Chemie (International Ed. in English). 52: 3981-4. PMID 23450724 DOI: 10.1002/Anie.201208470  0.724
2013 Langseth E, Scheuermann ML, Balcells D, Kaminsky W, Goldberg KI, Eisenstein O, Heyn RH, Tilset M. Generation and structural characterization of a gold(III) alkene complex. Angewandte Chemie (International Ed. in English). 52: 1660-3. PMID 23283802 DOI: 10.1002/Anie.201209140  0.399
2013 Scheuermann ML, Luedtke AT, Hanson SK, Fekl U, Kaminsky W, Goldberg KI. Reactions of five-coordinate platinum(IV) complexes with molecular oxygen Organometallics. 32: 4752-4758. DOI: 10.1021/Om4003363  0.814
2013 O'Connor AR, Kaminsky W, Chan BC, Heinekey DM, Goldberg KI. Synthesis and characterization of iridium(I) and iridium(III) complexes containing dialkylbiphenylphosphines Organometallics. 32: 4016-4019. DOI: 10.1021/Om400266D  0.793
2013 Allen KE, Heinekey DM, Goldman AS, Goldberg KI. Alkane dehydrogenation by C-H activation at iridium(III) Organometallics. 32: 1579-1582. DOI: 10.1021/Om301267C  0.738
2013 Lao DB, Owens ACE, Heinekey DM, Goldberg KI. Partial deoxygenation of glycerol catalyzed by iridium pincer complexes Acs Catalysis. 3: 2391-2396. DOI: 10.1021/Cs400551G  0.693
2013 St. John A, Goldberg KI, Heinekey DM. Pincer complexes as catalysts for amine borane dehydrogenation Topics in Organometallic Chemistry. 40: 271-288. DOI: 10.1007/978-3-642-31081-2-9  0.626
2012 Barnett SM, Goldberg KI, Mayer JM. A soluble copper-bipyridine water-oxidation electrocatalyst. Nature Chemistry. 4: 498-502. PMID 22614386 DOI: 10.1038/Nchem.1350  0.541
2012 Boisvert L, Goldberg KI. Reactions of late transition metal complexes with molecular oxygen. Accounts of Chemical Research. 45: 899-910. PMID 22578038 DOI: 10.1021/Ar2003072  0.488
2012 Meredith JM, Goldberg KI, Kaminsky W, Heinekey DM. η6-tetramethylfulvene and μ-η3: η3-benzene complexes of iridium Organometallics. 31: 8459-8462. DOI: 10.1021/Om3010492  0.686
2012 Rhinehart JL, Manbeck KA, Buzak SK, Lippa GM, Brennessel WW, Goldberg KI, Jones WD. Catalytic arene H/D exchange with novel rhodium and iridium complexes Organometallics. 31: 1943-1952. DOI: 10.1021/Om2012419  0.594
2012 Meredith JM, Robinson R, Goldberg KI, Kaminsky W, Heinekey DM. C-H bond activation by cationic iridium(III) NHC complexes: A combined experimental and computational study Organometallics. 31: 1879-1887. DOI: 10.1021/Om2012166  0.726
2012 Ahmed Foskey TJ, Heinekey DM, Goldberg KI. Partial deoxygenation of 1,2-propanediol catalyzed by iridium pincer complexes Acs Catalysis. 2: 1285-1289. DOI: 10.1021/Cs300120D  0.698
2011 Fulmer GR, Herndon AN, Kaminsky W, Kemp RA, Goldberg KI. Hydrogenolysis of palladium(II) hydroxide, phenoxide, and alkoxide complexes. Journal of the American Chemical Society. 133: 17713-26. PMID 21932859 DOI: 10.1021/Ja205824Q  0.815
2011 Lansing RB, Goldberg KI, Kemp RA. Unsymmetrical (R)PNP(R') pincer ligands and their group 10 complexes. Dalton Transactions (Cambridge, England : 2003). 40: 8950-8. PMID 21597616 DOI: 10.1039/C1Dt10265F  0.399
2011 Mrutu A, Dickie DA, Goldberg KI, Kemp RA. A unique three-dimensional coordination cluster based on a silver carbene complex. Inorganic Chemistry. 50: 2729-31. PMID 21366253 DOI: 10.1021/Ic200029C  0.383
2011 Hebden TJ, St John AJ, Gusev DG, Kaminsky W, Goldberg KI, Heinekey DM. Preparation of a dihydrogen complex of cobalt. Angewandte Chemie (International Ed. in English). 50: 1873-6. PMID 21328660 DOI: 10.1002/Anie.201005281  0.716
2011 Fulmer GR, Kaminsky W, Kemp RA, Goldberg KI. Syntheses and characterization of palladium complexes with a hemilabile "pCO" pincer ligand Organometallics. 30: 1627-1636. DOI: 10.1021/Om101150Y  0.826
2011 Schultz KM, Goldberg KI, Gusev DG, Heinekey DM. Synthesis, structure, and reactivity of iridium NHC pincer complexes Organometallics. 30: 1429-1437. DOI: 10.1021/Om101024X  0.721
2011 O'Connor AR, Kaminsky W, Heinekey DM, Goldberg KI. Synthesis, characterization, and reactivity of arene-stabilized rhodium complexes Organometallics. 30: 2105-2116. DOI: 10.1021/Om1009473  0.795
2011 Boro BJ, Lansing R, Goldberg KI, Kemp RA. Reaction of a monomeric titanium hydride with dioxygen does not produce a stable titanium hydroperoxide Inorganic Chemistry Communications. 14: 531-533. DOI: 10.1016/J.Inoche.2011.01.014  0.303
2011 Grice KA, Kaminsky W, Goldberg KI. C-H activation of benzene by platinum(II) complexes with cyclometalated phosphine ligands Inorganica Chimica Acta. 369: 76-81. DOI: 10.1016/J.Ica.2010.11.021  0.782
2011 Grice KA, Scheuermann ML, Goldberg KI. Five-coordinate platinum(IV) complexes Topics in Organometallic Chemistry. 503: 1-28. DOI: 10.1007/978-3-642-17429-2_1  0.777
2011 Heinekey DM, Goldberg KI, Ahmed TJ, Camp ER. Catalytic hydrogenolysis of glycerol Acs National Meeting Book of Abstracts 0.559
2011 Meredith JM, Goldberg KI, Kaminsky W, Heinekey DM. (η5-C5Me5)IrIII(N-heterocyclic carbene) complexes for catalytic alkane oxidation Acs National Meeting Book of Abstracts 0.622
2010 Hebden TJ, Goldberg KI, Heinekey DM, Zhang X, Emge TJ, Goldman AS, Krogh-Jespersen K. Dihydrogen/dihydride or tetrahydride? An experimental and computational investigation of pincer iridium polyhydrides. Inorganic Chemistry. 49: 1733-42. PMID 20095648 DOI: 10.1021/Ic902163W  0.663
2010 Scheuermann ML, Fekl U, Kaminsky W, Goldberg KI. Metal-ligand cooperativity in O2 activation: Observation of a "Pt-O-O-C" peroxo intermediate Organometallics. 29: 4749-4751. DOI: 10.1021/Om1003946  0.74
2010 Fulmer GR, Miller AJM, Sherden NH, Gottlieb HE, Nudelman A, Stoltz BM, Bercaw JE, Goldberg KI. NMR chemical shifts of trace impurities: Common laboratory solvents, organics, and gases in deuterated solvents relevant to the organometallic chemist Organometallics. 29: 2176-2179. DOI: 10.1021/Om100106E  0.755
2010 Mrutu A, Goldberg KI, Kemp RA. Synthesis and characterization of a dinuclear Ni complex containing a bridging CNC pincer ligand Inorganica Chimica Acta. 364: 115-119. DOI: 10.1016/J.Ica.2010.08.049  0.427
2009 Bernskoetter WH, Schauer CK, Goldberg KI, Brookhart M. Characterization of a rhodium(I) sigma-methane complex in solution. Science (New York, N.Y.). 326: 553-6. PMID 19900892 DOI: 10.1126/Science.1177485  0.65
2009 Boisvert L, Denney MC, Hanson SK, Goldberg KI. Insertion of molecular oxygen into a palladium(II) methyl bond: a radical chain mechanism involving palladium(III) intermediates. Journal of the American Chemical Society. 131: 15802-14. PMID 19827779 DOI: 10.1021/Ja9061932  0.442
2009 Bernskoetter WH, Hanson SK, Buzak SK, Davis Z, White PS, Swartz R, Goldberg KI, Brookhart M. Investigations of iridium-mediated reversible C-H bond cleavage: characterization of a 16-electron iridium(III) methyl hydride complex. Journal of the American Chemical Society. 131: 8603-13. PMID 19489584 DOI: 10.1021/Ja901706B  0.639
2009 Boro BJ, Duesler EN, Goldberg KI, Kemp RA. Synthesis, characterization, and reactivity of nickel hydride complexes containing 2,6-C6H3(CH2PR2)2 (R = tBu, cHex, and iPr) pincer ligands. Inorganic Chemistry. 48: 5081-7. PMID 19456134 DOI: 10.1021/Ic8020194  0.475
2009 Fulmer GR, Muller RP, Kemp RA, Goldberg KI. Hydrogenolysis of palladium(II) hydroxide and methoxide pincer complexes. Journal of the American Chemical Society. 131: 1346-7. PMID 19173658 DOI: 10.1021/Ja807936Q  0.803
2009 Look JL, Wick DD, Mayer JM, Goldberg KI. Autoxidation of platinum(IV) hydrocarbyl hydride complexes to form platinum(IV) hydrocarbyl hydroperoxide complexes. Inorganic Chemistry. 48: 1356-69. PMID 19159315 DOI: 10.1021/Ic801216R  0.615
2009 Meredith JM, Goldberg KI, Kaminsky W, Heinekey DM. Dinuclear iridium complexes containing cp * and carbonyl ligands: synthesis, structure, and reactivity Organometallics. 28: 3546-3551. DOI: 10.1021/Om900186J  0.698
2009 Grice KA, Goldberg KI. Insertion of dioxygen into a Platinum(II)-Methyl bond to form a Platinum(II) Methylperoxo complex Organometallics. 28: 953-955. DOI: 10.1021/Om8011272  0.749
2009 Smythe NA, Grice KA, Williams BS, Goldberg KI. Reductive elimination and dissociative β-hydride abstraction from Pt(IV) hydroxide and methoxide complexes Organometallics. 28: 277-288. DOI: 10.1021/Om800905Q  0.82
2009 Heinekey DM, Hebden TJ, Matthews SL, Goldberg KI, Dietrich BL, St John AJ. Dehydrogenation catalysts for BN and CBN hydrogen storage materials Acs National Meeting Book of Abstracts 0.772
2009 Hebden TJ, Piccoli PMB, Koetzle TF, Schultz AJ, Goldberg KI, Heinekey DM, Emge TJ, Krogh-Jespersen K, Goldman AS. Structural investigations of Ir pincer complexes relevant to catalytic H2 release from the chemical hydrogen storage material H3BNH3 Acs National Meeting Book of Abstracts 0.606
2008 Boro BJ, Dickie DA, Duesler EN, Goldberg KI, Kemp RA. [2,6-Bis(di-tert-butyl-phosphinometh-yl)-phen-yl-κP,C,P'](nitrato-κO)nickel(II). Acta Crystallographica. Section E, Structure Reports Online. 64: m1402. PMID 21580852 DOI: 10.1107/S1600536808032376  0.317
2008 Boro BJ, Dickie DA, Goldberg KI, Kemp RA. {2,6-Bis[(di-tert-butyl-phosphino)-methyl]-phenyl}chloridonickel(II). Acta Crystallographica. Section E, Structure Reports Online. 64: m1304. PMID 21201043 DOI: 10.1107/S1600536808029814  0.348
2008 Bridget Williams D, Kaminsky W, Mayer JM, Goldberg KI. Reactions of iridium hydride pincer complexes with dioxygen: new dioxygen complexes and reversible O2 binding. Chemical Communications (Cambridge, England). 4195-7. PMID 18802527 DOI: 10.1039/B802739K  0.628
2008 Dietrich BL, Goldberg KI, Heinekey DM, Autrey T, Linehan JC. Iridium-catalyzed dehydrogenation of substituted amine boranes: kinetics, thermodynamics, and implications for hydrogen storage. Inorganic Chemistry. 47: 8583-5. PMID 18785732 DOI: 10.1021/Ic801161G  0.817
2008 Luedtke AT, Goldberg KI. Intermolecular hydroarylation of unactivated olefins catalyzed by homogeneous platinum complexes. Angewandte Chemie (International Ed. in English). 47: 7694-6. PMID 18726981 DOI: 10.1002/Anie.200800524  0.833
2008 Hebden TJ, Denney MC, Pons V, Piccoli PM, Koetzle TF, Schultz AJ, Kaminsky W, Goldberg KI, Heinekey DM. Sigma-borane complexes of iridium: synthesis and structural characterization. Journal of the American Chemical Society. 130: 10812-20. PMID 18642912 DOI: 10.1021/Ja801898M  0.702
2008 Brayton DF, Goldberg KI, Kaminsky W, Heinekey DM. A convenient one-pot synthesis of Di-t-butylphosphinic chloride Phosphorus, Sulfur and Silicon and the Related Elements. 183: 2534-2540. DOI: 10.1080/10426500801967781  0.596
2008 Hanson SK, Heinekey DM, Goldberg KI. C-H bond activation by rhodium(I) phenoxide and acetate complexes: Mechanism of H-D exchange between arenes and water Organometallics. 27: 1454-1463. DOI: 10.1021/Om7012259  0.718
2008 Boro BJ, Duesler EN, Goldberg KI, Kemp RA. An unprecedented bonding mode for potassium within a PCP-pincer palladium hydride-K-Selectride® complex Inorganic Chemistry Communications. 11: 1426-1429. DOI: 10.1016/J.Inoche.2008.09.021  0.321
2007 Luedtke AT, Goldberg KI. Reductive elimination of ethane from five-coordinate platinum(IV) alkyl complexes. Inorganic Chemistry. 46: 8496-8. PMID 17877340 DOI: 10.1021/Ic701504Z  0.828
2007 Pawlikowski AV, Getty AD, Goldberg KI. Alkyl carbon-nitrogen reductive elimination from platinum(IV)-sulfonamide complexes. Journal of the American Chemical Society. 129: 10382-93. PMID 17672451 DOI: 10.1021/Ja069191H  0.787
2007 Kloek SM, Heinekey DM, Goldberg KI. C-H bond activation by rhodium(I) hydroxide and phenoxide complexes. Angewandte Chemie (International Ed. in English). 46: 4736-8. PMID 17492734 DOI: 10.1002/Anie.200700270  0.666
2007 Kloek SM, Goldberg KI. Competitive C-H bond activation and beta-hydride elimination at platinum(II). Journal of the American Chemical Society. 129: 3460-1. PMID 17341069 DOI: 10.1021/Ja0669629  0.509
2007 Heinekey DM, Mery D, Denney MC, Goldberg KI, Dietrich BL, Bennette NA, Hebden T. New catalysts for dehydrogenation of amine boranes Acs National Meeting Book of Abstracts 0.776
2006 Keith JM, Muller RP, Kemp RA, Goldberg KI, Goddard WA, Oxgaard J. Mechanism of direct molecular oxygen insertion in a palladium(II)-hydride bond. Inorganic Chemistry. 45: 9631-3. PMID 17112254 DOI: 10.1021/Ic061392Z  0.35
2006 Denney MC, Pons V, Hebden TJ, Heinekey DM, Goldberg KI. Efficient catalysis of ammonia borane dehydrogenation. Journal of the American Chemical Society. 128: 12048-9. PMID 16967937 DOI: 10.1021/Ja062419G  0.692
2006 Denney MC, Smythe NA, Cetto KL, Kemp RA, Goldberg KI. Insertion of molecular oxygen into a palladium(II) hydride bond. Journal of the American Chemical Society. 128: 2508-9. PMID 16492014 DOI: 10.1021/Ja0562292  0.739
2006 Kloek SM, Michael Heinekey D, Goldberg KI. Stereoselective decarbonylation of methanol to form a stable iridium(III) trans-dihydride complex Organometallics. 25: 3007-3011. DOI: 10.1021/Om051098Z  0.506
2005 Procelewska J, Zahl A, Liehr G, van Eldik R, Smythe NA, Williams BS, Goldberg KI. Mechanistic information on the reductive elimination from cationic trimethylplatinum(IV) complexes to form carbon-carbon bonds. Inorganic Chemistry. 44: 7732-42. PMID 16241122 DOI: 10.1021/Ic050478+  0.839
2005 Arthur KL, Wang QL, Bregel DM, Smythe NA, O'Neill BA, Goldberg KI, Moloy KG. The gem-dialkyl effect as a test for preliminary diphosphine chelate opening in a reductive elimination reaction Organometallics. 24: 4624-4628. DOI: 10.1021/Om0500467  0.746
2005 Look JL, Fekl U, Goldberg KI. Mechanisms of Reactions Related to Selective Alkane Oxidation by Pt Complexes Cheminform. 36. DOI: 10.1002/chin.200507244  0.701
2005 Pons V, Denney MC, Goldberg KI, Heinekey DM. Coordination of B-N species to transition metal complexes Acs Division of Fuel Chemistry, Preprints. 50: 536-537.  0.576
2005 Pons V, Denney MC, Goldberg KI, Heinekey DM. Coordination of B-N species to transition metal complexes Acs Division of Fuel Chemistry, Preprints. 50: 536-537.  0.576
2003 Fekl U, Kaminsky W, Goldberg KI. Beta-diiminate platinum complexes for alkane dehydrogenation. Journal of the American Chemical Society. 125: 15286-7. PMID 14664561 DOI: 10.1021/Ja037781Z  0.69
2003 Crumpton-Bregel DM, Goldberg KI. Mechanisms of C-C and C-H alkane reductive eliminations from octahedral Pt(IV): reaction via five-coordinate intermediates or direct elimination? Journal of the American Chemical Society. 125: 9442-56. PMID 12889975 DOI: 10.1021/Ja029140U  0.466
2003 Jensen MP, Wick DD, Reinartz S, White PS, Templeton JL, Goldberg KI. Reductive elimination/oxidative addition of carbon-hydrogen bonds at Pt(IV)/Pt(II) centers: mechanistic studies of the solution thermolyses of Tp(Me2)Pt(CH3)2H. Journal of the American Chemical Society. 125: 8614-24. PMID 12848569 DOI: 10.1021/Ja028477T  0.439
2003 FEKL U, GOLDBERG KI. HOMOGENEOUS HYDROCARBON CH BOND ACTIVATION AND FUNCTIONALIZATION WITH PLATINUM Advances in Inorganic Chemistry. 54: 259-320. DOI: 10.1016/S0898-8838(03)54005-3  0.754
2003 Kelman DR, Claborn KA, Kaminsky W, Goldberg KI, Li DT, West DX. Structural studies of N-2-(6-aminopyridine)-N′-arylthioureas Journal of Molecular Structure. 654: 145-152. DOI: 10.1016/S0022-2860(03)00206-0  0.311
2003 Westa DX, Szczepura LF, Giesen JM, Kaminsky W, Kelley J, Goldberg KI. Oxidation of heterocyclic thioureas to form benzothiazoles and their copper(II) complexes Journal of Molecular Structure. 646: 95-102. DOI: 10.1016/S0022-2860(02)00592-6  0.367
2002 Fekl U, Goldberg KI. Five-coordinate platinum(IV) complex as a precursor to a novel Pt(II) olefin hydride complex for alkane activation. Journal of the American Chemical Society. 124: 6804-5. PMID 12059183 DOI: 10.1021/Ja0258677  0.781
2002 Brown CA, Kaminsky W, Claborn KA, Goldberg KI, West DX. Structural studies of 2,6-diacetyl- and 2,6-diformylpyridine bis(thiosemicarbazones) Journal of the Brazilian Chemical Society. 13: 10-18. DOI: 10.1590/S0103-50532002000100003  0.454
2002 Valdés-Martínez J, Hernández-Ortega S, Hermetet AK, Ackerman LJ, Presto CA, Swearingen JK, Kelman DR, Goldberg KI, Kaminsky W, West DX. Structural studies of N-2-(3-picolyl)- and N-2-(4-picolyl)-N′ -tolylthioureas Journal of Chemical Crystallography. 32: 431-438. DOI: 10.1023/A:1021136508168  0.328
2002 Hermetet AK, Ackerman LJ, Swearingen JK, Presto CA, Kelman DR, Giesen JM, Goldberg KI, Kaminsky W, West DX. Structural studies of N-2-(6-picolyl)-N′-tolylthioureas Journal of Chemical Crystallography. 32: 17-25. DOI: 10.1023/A:1015688104995  0.324
2002 Kelman DR, Claborn KA, Kaminsky W, Goldberg KI, West DX. Structural, spectral and thermal studies of N-2-(pyridyl)- and N-2-(picolyl)-N′-(3-chlorophenyl)thioureas Journal of Molecular Structure. 642: 119-127. DOI: 10.1016/S0022-2860(02)00401-5  0.314
2002 Kaminsky W, Kelman DR, Giesen JM, Goldberg KI, Claborn KA, Szczepura LF, West DX. Structural and spectral studies of N-2-(pyridyl)-, N-2-(3-, 4-, 5-, and 6-picolyl)- and N-2-(4,6-lutidyl)-N′-2-thiomethoxyphenylthioureas Journal of Molecular Structure. 616: 79-89. DOI: 10.1016/S0022-2860(02)00300-9  0.305
2002 Kelman DR, Szczepura LF, Goldberg KI, Kaminsky W, Hermetet AK, Ackerman LJ, Swearingen JK, West DX. Structural, spectral and thermal studies of N-2-(4-picolyl)- and N-2-(6-picolyl)-N′-(2-chlorophenyl)thioureas and N-2-(6-picolyl)-N′-(2-bromophenyl)thiourea Journal of Molecular Structure. 610: 143-150. DOI: 10.1016/S0022-2860(02)00020-0  0.31
2002 Kaminsky W, Jasinski JP, Woudenberg R, Goldberg KI, West DX. Structural study of two N(4)-substituted thiosemicarbazones prepared from 1-phenyl-1,2-propanedione-2-oxime and their binuclear nickel(II) complexes Journal of Molecular Structure. 608: 135-141. DOI: 10.1016/S0022-2860(01)00921-8  0.442
2002 Hermetet AK, Ackerman LJ, Eilts KK, Johnson TK, Swearingen JK, Giesen JM, Goldberg KI, Kaminsky W, West DX. Structural, spectral and thermal studies of N-2-(4,6-lutidyl)-N′-chlorophenylthioureas Journal of Molecular Structure. 605: 241-247. DOI: 10.1016/S0022-2860(01)00764-5  0.325
2002 Kaminsky W, Goldberg KI, West DX. Synthesis and structures of two N,N′-bis(2-pyridinyl)thioureas and N-(2-pyridinyl)-N′-(benzoyl)thiourea Journal of Molecular Structure. 605: 9-15. DOI: 10.1016/S0022-2860(01)00655-X  0.334
2001 Williams BS, Goldberg KI. Studies of reductive elimination reactions to form carbon-oxygen bonds from Pt(IV) complexes. Journal of the American Chemical Society. 123: 2576-87. PMID 11456927 DOI: 10.1021/Ja003366K  0.67
2001 Fekl U, Kaminsky W, Goldberg KI. A stable five-coordinate platinum(IV) alkyl complex. Journal of the American Chemical Society. 123: 6423-4. PMID 11427072 DOI: 10.1021/Ja0156690  0.752
2001 Bartlett KL, Goldberg KI, Borden WT. Computational study of reductive elimination reactions to form C-H bonds from platinum(II) and platinum(IV) centers with strongly coordinating trimethylphosphine ligands Organometallics. 20: 2669-2678. DOI: 10.1021/Om010072E  0.369
2001 Getty AD, Goldberg KI. Reaction of a palladium(II) complex chelated by a tridentate PNC ligand with water to produce a [(PN)Pd(μ-OH)]2 2+ dimer: A rare observation of a well-defined hydrolysis of a Pd(II)-aryl compound Organometallics. 20: 2545-2551. DOI: 10.1021/Om001030D  0.802
2000 Fekl U, Eldik R, Lovell S, Goldberg KI. Effects of trifluoromethyl substituents in a tris(pyrazolyl)borate ligand: A structural and spectroscopic study of analogous platinum(IV) trimethyl complexes Organometallics. 19: 3535-3542. DOI: 10.1021/Om000291K  0.75
2000 Bartlett KL, Goldberg KI, Borden WT. A computational study of reductive elimination reactions to form C-H bonds from Pt(II) and Pt(IV) centers. Why does ligand loss precede reductive elimination from six-coordinate but not four-coordinate platinum? Journal of the American Chemical Society. 122: 1456-1465. DOI: 10.1021/Ja9915706  0.382
2000 Crumpton DM, Goldberg KI. Five-coordinate intermediates in carbon-carbon reductive elimination reactions from Pt(IV) [7] Journal of the American Chemical Society. 122: 962-963. DOI: 10.1021/Ja9912123  0.768
1999 Wick DD, Goldberg KI. Insertion of dioxygen into a platinum-hydride bond to form a novel dialkylhydroperoxo Pt(IV) complex [4] Journal of the American Chemical Society. 121: 11900-11901. DOI: 10.1021/Ja992618I  0.449
1999 Williams BS, Holland AW, Goldberg KI. Direct observation of C - O reductive elimination from Pt(IV) [4] Journal of the American Chemical Society. 121: 252-253. DOI: 10.1021/Ja982211Y  0.76
1999 Goldberg KI, Valdes-Martínez J, Espinosa-Pérez G, Ackerman LJ, West DX. Palladium(II) and platinum(II) complexes of 6-methyl-2-acetylpyridine 3-hexamethyleneiminylthiosemicarbazones: A structural and spectral study Polyhedron. 18: 1177-1182. DOI: 10.1016/S0277-5387(98)00412-4  0.457
1998 Rostovtsev VV, Labinger JA, Bercaw JE, Lasseter TL, Goldberg KI. Oxidation of dimethylplatinum(II) complexes with dioxygen Organometallics. 17: 4530-4531. DOI: 10.1021/Om980541L  0.624
1997 Wick DD, Goldberg KI. C-H activation at Pt(II) to form stable Pt(IV) alkyl hydrides Journal of the American Chemical Society. 119: 10235-10236. DOI: 10.1021/Ja971952G  0.403
1994 Goldberg KI, Yan J, Winter EL. Competitive carbon-carbon reductive elimination and carbon-iodide bond formation from a Pt(IV) complex Journal of the American Chemical Society. 116: 1573-1574. DOI: 10.1021/Ja00083A054  0.347
1990 Bursten BE, Gatter MG, Goldberg KI. Valence orbital energetics as a tool for organometallic synthesis: On the scarcity of two-legged piano-stool complexes Polyhedron. 9: 2001-2011. DOI: 10.1016/S0277-5387(00)84012-7  0.549
1989 Goldberg KI, Bergman RG. Synthesis of dialkyl- and alkyl(acyl)rhenium complexes by alkylation of anionic rhenium complexes at the metal center. Mechanism of a double carbonylation reaction that proceeds via the formation of free methyl radicals in solution Journal of the American Chemical Society. 111: 1285-1299. DOI: 10.1021/Ja00186A021  0.569
1989 GOLDBERG KI, BERGMAN RG. ChemInform Abstract: Synthesis of Dialkyl- and Alkylacylrhenium Complexes by Alkylation of Anionic Rhenium Complexes at the Metal Center. Mechanism of a Double Carbonylation Reaction That Proceeds via the Formation of Free Methyl Radicals in Solution. Cheminform. 20. DOI: 10.1002/chin.198922263  0.505
1989 Goldberg KI, Bergman RG. Synthesis of dialkyl- and alkylacylrhenium complexes by alkylation of anionic rhenium complexes at the metal center. Mechanism of a double carbonylation reaction that proceeds via the formation of free methyl radicals in solution Journal of the American Chemical Society. 111: 1285-1299.  0.341
1988 Goldberg KI, Bergman RG. Synthesis and physical properties of a dinuclear tantalum/cobalt radical with spin localized at one metal center Journal of the American Chemical Society. 110: 4853-4855. DOI: 10.1021/Ja00222A069  0.446
1988 Jacobsen EN, Goldberg KI, Bergman RG. Rapid, reversible intramolecular carbon-hydrogen oxidative addition and hydrogen exchange in a heterodinuclear "early-late" transition metal complex Journal of the American Chemical Society. 110: 3706-3707. DOI: 10.1021/Ja00219A081  0.668
1988 GOLDBERG KI, BERGMAN RG. ChemInform Abstract: Synthesis and Physical Properties of a Dinuclear Tantalum-Cobalt Radical with Spin Localized at One Metal Center. Cheminform. 19. DOI: 10.1002/chin.198845284  0.332
1988 JACOBSEN EN, GOLDBERG KI, BERGMAN RG. ChemInform Abstract: Rapid, Reversible Intramolecular C-H Oxidative Addition and Hydrogen Exchange in a Heterodinuclear “Early-Late” Transition-Metal Complex. Cheminform. 19. DOI: 10.1002/chin.198838291  0.473
1987 Goldberg KI, Bergman RG. Electrophilic alkylation of an acyl metalate complex at the metal center leading to a stable methylacetylrhenium complex. Photochemical decomposition to give 2,3-butanedione via a mechanism involving carbonylation of free methyl radicals Organometallics. 6: 430-432. DOI: 10.1021/Om00145A035  0.531
1987 Goldberg KI, Bergman RG. Electrophilic alkylation of an acylmetalate complex at the metal center leading to a stable methylacetylrhenium complex. Photochemical decomposition to give 2,3-butanedione via a mechanism involving carbonylation of free methyl radicals Organometallics. 6: 430-432.  0.323
1982 Goldberg KI, Hoffman DM, Hoffmann R. Existence of binuclear .pi.-bonded dinitrogen complexes Inorganic Chemistry. 21: 3863-3868. DOI: 10.1021/Ic00141A001  0.529
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