Rajendra S. Ghadwal - Publications

Affiliations: 
2002-2006 University of Rajasthan 
 2008-2016 Georg-August-Universität Göttingen, Göttingen, Niedersachsen, Germany 
 2017- Universität Bielefeld, Bielefeld, North Rhine-Westphalia, Germany 
Area:
Molecular inorganic chemistry, catalysis
Website:
https://www.ghadwalgroup.de/rsg

61 high-probability publications. We are testing a new system for linking publications to authors. You can help! If you notice any inaccuracies, please sign in and mark papers as correct or incorrect matches. If you identify any major omissions or other inaccuracies in the publication list, please let us know.

Year Citation  Score
2021 Rottschäfer D, Glodde T, Neumann B, Stammler HG, Andrada DM, Ghadwal RS. Isolation of 1,4-Diarsinine-1,4-diide and 1,4-Diarsinine Derivatives. Angewandte Chemie (International Ed. in English). PMID 34015179 DOI: 10.1002/anie.202105835  1
2021 Rottschäfer D, Ghadwal R, Danés S, Sharma MK, Neumann B, Stammler HG, Andrada DM, van Gastel M, Hinz A. Metalloradical Cations and Dications Based on Divinyldiphosphene and Divinyldiarsene Ligands. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 33470468 DOI: 10.1002/chem.202100213  1
2021 Sharma MK, Rottschäfer D, Glodde T, Neumann B, Stammler HG, Ghadwal RS. An Open-Shell Singlet Sn  Diradical and H  Splitting. Angewandte Chemie (International Ed. in English). PMID 33460280 DOI: 10.1002/anie.202017078  1
2020 Sharma MK, Blomeyer S, Glodde T, Neumann B, Stammler HG, Hinz A, van Gastel M, Ghadwal RS. Isolation of singlet carbene derived 2-phospha-1,3-butadienes and their sequential one-electron oxidation to radical cations and dications. Chemical Science. 11: 1975-1984. PMID 34123292 DOI: 10.1039/c9sc05598c  1
2020 Sharma MK, Ebeler F, Glodde T, Neumann B, Stammler HG, Ghadwal RS. Isolation of a Ge(I) Diradicaloid and Dihydrogen Splitting. Journal of the American Chemical Society. PMID 33373236 DOI: 10.1021/jacs.0c11828  1
2020 Ghadwal R, Rottschäfer D, Neumann B, Stammler HG, Andrada D, Sergeieva T. Isolation of a 16π-Electrons 1,4-Diphosphinine-1,4-diide with a Planar C4P2 Ring. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 33080114 DOI: 10.1002/chem.202003617  1
2020 Rottschäfer D, Neumann B, Stammler HG, Andrada DM, Ghadwal RS. Isolation of Elusive Electrophilic Phosphinidene Complexes with π-Donor N-Heterocyclic Vinyl Substituents. The Journal of Organic Chemistry. PMID 32297512 DOI: 10.1021/Acs.Joc.0C00176  1
2020 Ghadwal R, Sharma MK, Glodde T, Neumann B, Stammler HG. Distannabarrelenes with three Coordinated Sn(II) atoms. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 32216071 DOI: 10.1002/Chem.202001432  1
2020 Sharma MK, Blomeyer S, Neumann B, Stammler HG, Hinz A, van Gastel M, Ghadwal RS. Isolation of singlet carbene derived 2-arsa-1,3-butadiene radical cations and dications. Chemical Communications (Cambridge, England). PMID 32104835 DOI: 10.1039/D0Cc00624F  1
2020 Rottschäfer D, Glodde T, Neumann B, Stammler HG, Ghadwal RS. A crystalline C5-protonated 1,3-imidazol-4-ylidene. Chemical Communications (Cambridge, England). PMID 31967114 DOI: 10.1039/C9Cc09428H  1
2019 Rottschäfer D, Blomeyer S, Neumann B, Stammler HG, Ghadwal RS. Direct functionalization of white phosphorus with anionic dicarbenes and mesoionic carbenes: facile access to 1,2,3-triphosphol-2-ides. Chemical Science. 10: 11078-11085. PMID 32206256 DOI: 10.1039/C9Sc04441H  1
2019 Sharma MK, Neumann B, Stammler HG, Andrada DM, Ghadwal RS. Electrophilic terminal arsinidene-iron(0) complexes with a two-coordinated arsenic atom. Chemical Communications (Cambridge, England). PMID 31746858 DOI: 10.1039/C9Cc08630G  1
2019 Ghadwal R, Sharma M, Blomeyer S, Neumann B, Stammler HG, van Gastel M, Hinz A. Crystalline Divinyldiarsene Radical Cations and Dications. Angewandte Chemie (International Ed. in English). PMID 31553520 DOI: 10.1002/Anie.201909144  1
2019 Sharma MK, Rottschäfer D, Blomeyer S, Neumann B, Stammler HG, van Gastel M, Hinz A, Ghadwal RS. Diphosphene radical cations and dications with a π-conjugated CPC-framework. Chemical Communications (Cambridge, England). PMID 31403648 DOI: 10.1039/C9Cc04701H  1
2019 Ghadwal R, Rottschaefer D, Sharma M, Neumann B, Stammler HG, Andrada D. A Modular Access to Divinyldiphosphenes with a Strikingly Small HOMO-LUMO Energy Gap. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 31038217 DOI: 10.1002/Chem.201901204  1
2019 Ghadwal R, Sharma M, Blomeyer S, Neumann B, Stammler HG. Crystalline Divinyldiarsenes and Cleavage of the As=As Bond. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 31017700 DOI: 10.1002/Chem.201901857  1
2019 Rottschäfer D, Neumann B, Stammler HG, Kishi R, Nakano M, Ghadwal RS. A Phosphorus Analogue of p-Quinodimethane with a Planar P Ring: A Metal-Free Diphosphorus Source. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 30716177 DOI: 10.1002/Chem.201805932  1
2018 Ghadwal R, Rottschäfer D, Busch J, Neumann B, Stammler HG, van Gastel M, Kishi R, Nakano M. Diradical Character Enhancement by Spacing: N-Heterocyclic Carbene Analogues of Müller's Hydrocarbon. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 30187988 DOI: 10.1002/Chem.201804524  1
2018 Rottschäfer D, Neumann B, Stammler HG, Andrada DM, Ghadwal RS. Kekulé diradicaloids derived from a classical N-heterocyclic carbene. Chemical Science. 9: 4970-4976. PMID 29938024 DOI: 10.1039/C8Sc01209A  1
2018 Rottschäfer D, Ho NKT, Neumann B, Stammler HG, van Gastel M, Andrada DM, Ghadwal RS. N-Heterocyclic Carbene Analogues of Thiele and Chichibabin Hydrocarbons. Angewandte Chemie (International Ed. in English). PMID 29668119 DOI: 10.1002/Anie.201713346  1
2018 Ghadwal R, Rottschäfer D, Neumann B, Stammler HG, van Gastel M, Andrada D. Classical N-Heterocyclic Carbenes Derived Crystalline Radicals. Angewandte Chemie (International Ed. in English). PMID 29465816 DOI: 10.1002/Anie.201801596  1
2018 Ghadwal R, Rottschäfer D, Ebeler F, Strothmann T, Neumann B, Stammler HG, Mix A. The Viability of C5-Protonated- and C4,C5-Ditopic Carbanionic- Abnormal NHCs: A New Dimension in NHC Chemistry. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 29363830 DOI: 10.1002/Chem.201800260  1
2017 Ho NKT, Neumann B, Stammler HG, Menezes da Silva VH, Watanabe DG, Braga AAC, Ghadwal RS. Nickel-catalysed direct C2-arylation of N-heterocyclic carbenes. Dalton Transactions (Cambridge, England : 2003). PMID 28853488 DOI: 10.1039/C7Dt03099A  1
2017 Ghadwal R, Rottschäfer D, Blomeyer S, Neumann B, Stammler HG. Silylene-Functionalized N-Heterocyclic Carbene (Si-NHC). Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 28833705 DOI: 10.1002/Chem.201703530  1
2017 Ghadwal RS, Rottschäfer D, Andrada DM, Frenking G, Schürmann CJ, Stammler HG. Normal-to-abnormal rearrangement of an N-heterocyclic carbene with a silylene transition metal complex. Dalton Transactions (Cambridge, England : 2003). 46: 7791-7799. PMID 28590484 DOI: 10.1039/C7Dt01199G  1
2017 Ghadwal RS, Lamm JH, Rottschäfer D, Schürmann CJ, Demeshko S. Facile routes to abnormal-NHC-cobalt(ii) complexes. Dalton Transactions (Cambridge, England : 2003). 46: 7664-7667. PMID 28573296 DOI: 10.1039/C7Dt01778B  1
2017 Rottschäfer D, Neumann B, Stammler HG, Ghadwal RS. N-Heterocyclic Vinylidene-Stabilized Phosphorus Biradicaloid. Chemistry (Weinheim An Der Bergstrasse, Germany). 23: 9044-9047. PMID 28556982 DOI: 10.1002/Chem.201702433  1
2016 Ghadwal RS. Carbon-based two electron σ-donor ligands beyond classical N-heterocyclic carbenes. Dalton Transactions (Cambridge, England : 2003). 45: 16081-16095. PMID 27427200 DOI: 10.1039/C6Dt02158A  0.01
2015 Ghadwal RS, Schürmann CJ, Andrada DM, Frenking G. Mono- and di-cationic hydrido boron compounds. Dalton Transactions (Cambridge, England : 2003). 44: 14359-67. PMID 26200103 DOI: 10.1039/C5Dt02237A  1
2015 Ghadwal RS, Reichmann SO, Herbst-Irmer R. Palladium-catalyzed direct C2-arylation of an N-heterocyclic carbene: an atom-economic route to mesoionic carbene ligands. Chemistry (Weinheim An Der Bergstrasse, Germany). 21: 4247-51. PMID 25639790 DOI: 10.1002/Chem.201405923  1
2015 Sharma NB, Shahai J, Ghadwal RS, Singh A, Jeanneau E, Mishra S. Homometallic glycolates containing hydroxyl functionality for anchoring another metal: synthesis and characterization of heterometallic alkoxide–glycolates of Ti and Zr incorporating Al and Nb Journal of Coordination Chemistry. 1-14. DOI: 10.1080/00958972.2015.1112900  1
2014 Ghadwal RS, Reichmann SO, Carl E, Herbst-Irmer R. Synthesis and structural investigation of R2Si (R = Me, Ph) bridged di-N-heterocyclic carbenes. Dalton Transactions (Cambridge, England : 2003). 43: 13704-10. PMID 25101953 DOI: 10.1039/C4Dt01681E  1
2014 Ghadwal RS, Schürmann CJ, Engelhardt F, Steinmetzger C. Unprecedented borylene insertion into a C-N bond European Journal of Inorganic Chemistry. DOI: 10.1002/Ejic.201402750  1
2013 Ghadwal RS, Reichmann SO, Engelhardt F, Andrada DM, Frenking G. Facile access to silyl-functionalized N-heterocyclic olefins with HSiCl3. Chemical Communications (Cambridge, England). 49: 9440-2. PMID 24005446 DOI: 10.1039/C3Cc45652H  1
2013 Azhakar R, Ghadwal RS, Roesky HW, Hey J, Krause L, Stalke D. Mixed valence η6-arene cobalt(I) and cobalt(II) compound. Dalton Transactions (Cambridge, England : 2003). 42: 10277-81. PMID 23732516 DOI: 10.1039/C3Dt50939G  1
2013 Ghadwal RS, Azhakar R, Pröpper K, Dittrich B, John M. Selective functionalization of a bis-silylene. Chemical Communications (Cambridge, England). 49: 5987-9. PMID 23715462 DOI: 10.1039/C3Cc43199A  1
2013 Azhakar R, Ghadwal RS, Roesky HW, Mata RA, Wolf H, Herbst-Irmer R, Stalke D. Reaction of N-heterocyclic silylenes with thioketone: formation of silicon-sulfur three (Si-C-S)- and five (Si-C-C-C-S)-membered ring systems. Chemistry (Weinheim An Der Bergstrasse, Germany). 19: 3715-20. PMID 23361862 DOI: 10.1002/Chem.201203242  1
2013 Ghadwal RS, Azhakar R, Roesky HW. Dichlorosilylene: a high temperature transient species to an indispensable building block. Accounts of Chemical Research. 46: 444-56. PMID 23181482 DOI: 10.1021/Ar300196U  1
2013 Ghadwal RS, Reichmann SO, Engelhardt F, Andrada DM, Frenking G. Facile access to silyl-functionalized N-heterocyclic olefins with HSiCl3 Chemical Communications. 49: 9440-9442. DOI: 10.1039/c3cc45652h  1
2012 Samuel PP, Azhakar R, Ghadwal RS, Sen SS, Roesky HW, Granitzka M, Matussek J, Herbst-Irmer R, Stalke D. Stable silaimines with three- and four-coordinate silicon atoms. Inorganic Chemistry. 51: 11049-54. PMID 23036040 DOI: 10.1021/Ic301543Y  1
2012 Ghadwal RS, Azhakar R, Roesky HW, Pröpper K, Dittrich B, Goedecke C, Frenking G. Donor-acceptor stabilized silaformyl chloride. Chemical Communications (Cambridge, England). 48: 8186-8. PMID 22786582 DOI: 10.1039/C2Cc32887A  1
2012 Azhakar R, Roesky HW, Ghadwal RS, Holstein JJ, Dittrich B. An access to base-stabilized three-membered silicon heterocycles. Dalton Transactions (Cambridge, England : 2003). 41: 9601-3. PMID 22785327 DOI: 10.1039/C2Dt31326J  1
2012 Singh AP, Ghadwal RS, Roesky HW, Holstein JJ, Dittrich B, Demers JP, Chevelkov V, Lange A. Lewis base mediated dismutation of trichlorosilane. Chemical Communications (Cambridge, England). 48: 7574-6. PMID 22735667 DOI: 10.1039/C2Cc33835A  1
2012 Azhakar R, Ghadwal RS, Roesky HW, Wolf H, Stalke D. A début for base stabilized monoalkylsilylenes. Chemical Communications (Cambridge, England). 48: 4561-3. PMID 22460291 DOI: 10.1039/C2Cc31041D  1
2012 Azhakar R, Ghadwal RS, Roesky HW, Hey J, Stalke D. Facile access to transition-metal-carbonyl complexes with an amidinate-stabilized chlorosilylene ligand. Chemistry, An Asian Journal. 7: 528-33. PMID 22246607 DOI: 10.1002/Asia.201100722  1
2012 Azhakar R, Ghadwal RS, Roesky HW, Wolf H, Stalke D. Stabilization of low valent silicon fluorides in the coordination sphere of transition metals. Journal of the American Chemical Society. 134: 2423-8. PMID 22191508 DOI: 10.1021/Ja210697P  1
2012 Azhakar R, Ghadwal RS, Roesky HW, Hey J, Stalke D. Double N-H bond activation of N,N'-bis-substituted hydrazines with stable N-heterocyclic silylene. Dalton Transactions (Cambridge, England : 2003). 41: 1529-33. PMID 22159089 DOI: 10.1039/C1Dt11708D  1
2011 Ghadwal RS, Azhakar R, Roesky HW, Pröpper K, Dittrich B, Klein S, Frenking G. Donor-acceptor-stabilized silicon analogue of an acid anhydride. Journal of the American Chemical Society. 133: 17552-5. PMID 21999232 DOI: 10.1021/Ja206702E  1
2011 Percival PW, Brodovitch JC, Mozafari M, Mitra A, West R, Ghadwal RS, Azhakar R, Roesky HW. Free radical reactivity of mono- and dichlorosilylene with muonium. Chemistry (Weinheim An Der Bergstrasse, Germany). 17: 11970-3. PMID 21905145 DOI: 10.1002/Chem.201102405  1
2011 Ghadwal RS, Azhakar R, Pröpper K, Holstein JJ, Dittrich B, Roesky HW. N-heterocyclic carbene stabilized dichlorosilylene transition-metal complexes of V(I), Co(I), and Fe(0). Inorganic Chemistry. 50: 8502-8. PMID 21780764 DOI: 10.1021/Ic201096C  1
2011 Ghadwal RS, Roesky HW, Pröpper K, Dittrich B, Klein S, Frenking G. A dimer of silaisonitrile with two-coordinate silicon atoms. Angewandte Chemie (International Ed. in English). 50: 5374-8. PMID 21574229 DOI: 10.1002/Anie.201101320  1
2011 Ghadwal RS, Pröpper K, Dittrich B, Jones PG, Roesky HW. Neutral pentacoordinate silicon fluorides derived from amidinate, guanidinate, and triazapentadienate ligands and base-induced disproportionation of Si2Cl6 to stable silylenes. Inorganic Chemistry. 50: 358-64. PMID 21126009 DOI: 10.1021/Ic1020548  1
2011 Azhakar R, Ghadwal RS, Roesky HW, Hey J, Stalke D. Reactions of stable N -heterocyclic silylenes with ketones and 3,5-Di-tert -butyl-o-benzoquinone Organometallics. 30: 3853-3858. DOI: 10.1021/Om200388A  1
2010 Ghadwal RS, Roesky HW, Granitzka M, Stalke D. A facile route to functionalized N-heterocyclic carbenes (NHCs) with NHC base-stabilized dichlorosilylene. Journal of the American Chemical Society. 132: 10018-20. PMID 20608639 DOI: 10.1021/Ja104386G  1
2010 Ghadwal RS, Sen SS, Roesky HW, Granitzka M, Kratzert D, Merkel S, Stalke D. Convenient access to monosilicon epoxides with pentacoordinate silicon. Angewandte Chemie (International Ed. in English). 49: 3952-5. PMID 20397177 DOI: 10.1002/Anie.201000835  1
2010 Li J, Merkel S, Henn J, Meindl K, Döring A, Roesky HW, Ghadwal RS, Stalke D. Lewis-base-stabilized dichlorosilylene: a two-electron sigma-donor ligand. Inorganic Chemistry. 49: 775-7. PMID 20028104 DOI: 10.1021/Ic9023162  1
2010 Ghadwal RS, Roesky HW, Merkel S, Stalke D. Ambiphilicity of dichlorosilylene in a single molecule. Chemistry (Weinheim An Der Bergstrasse, Germany). 16: 85-8. PMID 19950343 DOI: 10.1002/Chem.200902930  1
2009 Ghadwal RS, Roesky HW, Merkel S, Henn J, Stalke D. Lewis base stabilized dichlorosilylene. Angewandte Chemie (International Ed. in English). 48: 5683-6. PMID 19551793 DOI: 10.1002/Anie.200901766  1
2009 Ghadwal RS, Sen SS, Roesky HW, Tavcar G, Merkel S, Stalke D. Neutral penta- And hexacoordinate N-heterocyclic carbene complexes derived from SiX4 (X = F, Br) Organometallics. 28: 6374-6377. DOI: 10.1021/Om9007696  1
2006 Ghadwal RS, Singh A. Synthesis and spectroscopic characterisation of a new class of heterobimetallic homoleptic diethanolaminate complexes of niobium(V) and tantalum(V) Journal of Chemical Research-S. 2006: 451-455. DOI: 10.3184/030823406777980664  1
2005 Ghadwal RS, Mehrotra RC, Singh A. Preparation and spectroscopic characterisation of a series of heterobimetallic N-phenyldiethanolaminate-alkoxide derivatives of oxovanadium(V) Journal of Chemical Research-S. 2005: 352-355. DOI: 10.3184/0308234054506857  1
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