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Douglas Stephan, Ph.D. - Publications

Affiliations: 
Chemistry University of Toronto, Toronto, ON, Canada 
Website:
http://www.chem.utoronto.ca/ppl/faculty_profile.php?id=168

354 high-probability publications. We are testing a new system for linking publications to authors. You can help! If you notice any inaccuracies, please sign in and mark papers as correct or incorrect matches. If you identify any major omissions or other inaccuracies in the publication list, please let us know.

Year Citation  Score
2021 Stephan DW, Bamford KL, Qu ZW. Reactions of B2(o-tolyl)4 with Boranes: Assembly of the Pentaborane(9), HB(B(o-tolyl)(μ-H))4. Angewandte Chemie (International Ed. in English). PMID 33539608 DOI: 10.1002/anie.202101054  0.68
2021 Yang X, Wei R, Shi Y, Liu LL, Wu Y, Zhao Y, Stephan DW. Oxyphosphoranes as precursors to bridging phosphate-catecholate ligands. Chemical Communications (Cambridge, England). PMID 33439178 DOI: 10.1039/d0cc07736d  0.6
2021 Xu M, Qu ZW, Grimme S, Stephan DW. Lithium Dicyclohexylamide in Transition-Metal-Free Fischer-Tropsch Chemistry. Journal of the American Chemical Society. PMID 33399459 DOI: 10.1021/jacs.0c11482  0.88
2020 Bamford KL, Stephan DW. Insertion reactions of the C-B-N-substituted borinium cation [MesBNPr]. Dalton Transactions (Cambridge, England : 2003). PMID 33231245 DOI: 10.1039/d0dt03665j  0.64
2020 Zhu D, Qu ZW, Zhou J, Stephan DW. The Reactivity of Isomeric Nitrenium Lewis Acids with Phosphines, Carbenes and Phosphide. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 33137240 DOI: 10.1002/chem.202004798  0.68
2020 Zhou J, Kim H, Liu LL, Cao LL, Stephan DW. An arene-stabilized η-pentamethylcyclopentadienyl antimony dication acts as a source of Sb or Sb cations. Chemical Communications (Cambridge, England). PMID 32985631 DOI: 10.1039/d0cc02710c  0.64
2020 Bodach A, Bamford KL, Longobardi LE, Felderhoff M, Stephan DW. Group 13-derived radicals from α-diimines hydro- and carboalumination reactions. Dalton Transactions (Cambridge, England : 2003). 49: 11689-11696. PMID 32789402 DOI: 10.1039/d0dt02498h  0.64
2020 Nguyen TN, Harreschou IM, Lee JH, Stylianou KC, Stephan DW. A recyclable metal-organic framework for ammonia vapour adsorption. Chemical Communications (Cambridge, England). PMID 32697232 DOI: 10.1039/d0cc00741b  0.44
2020 Murphy MC, Trofimova A, LaFortune JHW, Vogels CM, Geier SJ, Binder JF, Macdonald CLB, Stephan DW, Westcott SA. The phosphinoboration of acyl chlorides. Dalton Transactions (Cambridge, England : 2003). PMID 32167110 DOI: 10.1039/d0dt00579g  0.6
2020 Andrews R, Stephan DW. Isolable Anionic, Neutral and Cationic Radicals from Reactions of  N,N'-dimesityldiamidocarbene and Lewis Acids. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 32149432 DOI: 10.1002/chem.202001191  0.52
2020 Lam J, Cao LL, Farrell JM, Stephan DW. Reactions of carbene-stabilized borenium cations. Dalton Transactions (Cambridge, England : 2003). PMID 31965118 DOI: 10.1039/c9dt04731j  1
2020 Guo J, Cheong O, Bamford KL, Zhou J, Stephan DW. Frustrated Lewis pair-catalyzed double hydroarylation of alkynes with N-substituted pyrroles. Chemical Communications (Cambridge, England). PMID 31950939 DOI: 10.1039/c9cc08654d  0.64
2020 Briceno-Strocchia AI, Johnstone TC, Stephan DW. Using frustrated Lewis pairs to explore C-F bond activation. Dalton Transactions (Cambridge, England : 2003). PMID 31912805 DOI: 10.1039/c9dt04588k  0.36
2019 Zhu D, Qu ZW, Stephan DW. Addition reactions and diazomethane capture by the intramolecular P-O-B FLP: tBuPOBcat. Dalton Transactions (Cambridge, England : 2003). PMID 31859700 DOI: 10.1039/c9dt04560k  0.68
2019 Szkop KM, Jupp AR, Razumkov H, Stephan DW. Avenue to phosphaalkenes from PhGePCO. Dalton Transactions (Cambridge, England : 2003). PMID 31859304 DOI: 10.1039/c9dt04590b  0.48
2019 Stephan DW, Zhou J, Liu LL, Cao LL. Base-Stabilized [PO]+/[PO2]+ Cations. Angewandte Chemie (International Ed. in English). PMID 31609496 DOI: 10.1002/anie.201912009  0.64
2019 Cao L, Zhou J, Qu ZW, Stephan DW. Single Electron Transfer to Diazomethane-Borane Adducts Prompts C-H Bond Activations. Angewandte Chemie (International Ed. in English). PMID 31589360 DOI: 10.1002/anie.201912338  0.68
2019 Liu LL, Zhou J, Cao LL, Stephan DW. Phosphaaluminirenes: Synthons for Main Group Heterocycles. Journal of the American Chemical Society. PMID 31557435 DOI: 10.1021/jacs.9b09330  0.64
2019 Trofimova A, LaFortune JHW, Qu ZW, Westcott SA, Stephan DW. 1,1-Phosphinoboration of diazomethanes. Chemical Communications (Cambridge, England). PMID 31538992 DOI: 10.1039/c9cc06914c  0.68
2019 Liu LL, Zhou J, Kim Y, Cao LL, Stephan DW. Oligomerization of phosphaalkynes mediated by bulky N-heterocyclic carbenes: avenues to novel phosphorus frameworks. Dalton Transactions (Cambridge, England : 2003). PMID 31453597 DOI: 10.1039/c9dt03185e  0.64
2019 Lafortune J, Qu ZW, Bamford K, Trofimova A, Westcott S, Stephan DW. Double Phosphinoboration of CO2: A Facile Route to Diphospha-ureas. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 31355971 DOI: 10.1002/chem.201903407  0.68
2019 Waked AE, Chitnis SS, Stephan DW. P(v) dications: carbon-based Lewis acid initiators for hydrodefluorination. Chemical Communications (Cambridge, England). PMID 31290494 DOI: 10.1039/c9cc04010b  0.44
2019 Stephan DW, Szkop KM, Jupp AR, Razumkov H, Xu M. Diphospha-ureas from the Phosphaketene Ph3GePCO. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 31215687 DOI: 10.1002/chem.201902789  0.68
2019 Guo J, Bamford KL, Stephan DW. 9-Borabicyclo[3.3.l]nonane-induced Friedel-Crafts benzylation of arenes with benzyl fluorides. Organic & Biomolecular Chemistry. PMID 31107484 DOI: 10.1039/c9ob00912d  0.64
2019 Liu LL, Zhou J, Cao LL, Kim Y, Stephan DW. Reversible Intramolecular Cycloaddition of Phosphaalkene to an Arene Ring. Journal of the American Chemical Society. PMID 31055918 DOI: 10.1021/jacs.9b03721  0.64
2019 Major CJ, Bamford KL, Qu ZW, Stephan DW. Hydroboration without a B-H bond: reactions of the borinium cation [(iPrN)B] with alkyne, nitrile, ketone and diazomethane. Chemical Communications (Cambridge, England). PMID 30977476 DOI: 10.1039/c9cc01302d  0.68
2019 Kim Y, Liu L, Stephan DW. N-Heterocyclic Carbene Derived 3-Azabutadiene as a π-Base in Classic and Frustrated Lewis Pair Chemistry. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 30968983 DOI: 10.1002/chem.201901609  0.64
2019 Bamford KL, Qu ZW, Stephan DW. Activation of H and EtSiH by the Borinium Cation [MesB]: Avenues to Cations [MesB(μ-H)(μ-Mes)BMes] and [HB(μ-H)(μ-Mes)B(μ-Mes)(μ-H)BH]. Journal of the American Chemical Society. 141: 6180-6184. PMID 30943365 DOI: 10.1021/jacs.9b02510  0.68
2019 Xu M, Jupp A, Ong M, Burton K, Chitnis S, Stephan DW. Synthesis of Urea Derivatives from CO2 and Silylamines. Angewandte Chemie (International Ed. in English). PMID 30821888 DOI: 10.1002/anie.201900058  0.68
2019 Zhou J, Liu L, Cao L, Stephan DW. The Arene-Stabilized η5-Pentamethylcyclopentadienyl Arsenic Dication [(η5-Cp*)As(toluene)]2. Angewandte Chemie (International Ed. in English). PMID 30802353 DOI: 10.1002/anie.201902039  0.64
2019 Liu LL, Stephan DW. Radicals derived from Lewis acid/base pairs. Chemical Society Reviews. PMID 30724924 DOI: 10.1039/c8cs00940f  0.6
2019 Zhu D, LaFortune JHW, Melen RL, Stephan DW. Electrophilic boron carboxylate and phosphinate complexes. Dalton Transactions (Cambridge, England : 2003). PMID 30656327 DOI: 10.1039/c8dt04818e  1
2019 Xu M, Jupp A, Stephan DW. Acyl-Phosphide Anions from Reactions of K[PtBu2] and CO via an Intermediate with Carbene Character. Angewandte Chemie (International Ed. in English). PMID 30650223 DOI: 10.1002/anie.201814562  0.68
2018 Johnstone TC, Briceno-Strocchia AI, Stephan DW. Frustrated Lewis Pair Oxidation Permits Synthesis of a Fluoroazaphosphatrane, [FP(MeNCHCH)N]. Inorganic Chemistry. PMID 30495935 DOI: 10.1021/acs.inorgchem.8b02605  0.36
2018 Lam J, Sampaolesi S, LaFortune JHW, Coe JW, Stephan DW. Design considerations for chiral frustrated Lewis pairs: B/N FLPs derived from 3,5-bicyclic aryl piperidines. Dalton Transactions (Cambridge, England : 2003). 48: 133-141. PMID 30484790 DOI: 10.1039/c8dt04070b  0.52
2018 Liu L, Cao L, Zhou J, Stephan DW. Facile Cleavage of the P=P Double Bond in Vinyl-Substituted Diphosphenes. Angewandte Chemie (International Ed. in English). PMID 30444313 DOI: 10.1002/anie.201812592  0.64
2018 Hermannsdorfer A, Stephan DW, Driess M. Taming a silyldiium cation and its reactivity towards sodium phosphaethynolate. Chemical Communications (Cambridge, England). PMID 30431626 DOI: 10.1039/c8cc07632d  0.96
2018 Jupp AR, Johnstone TC, Stephan DW. Improving the Global Electrophilicity Index (GEI) as a Measure of Lewis Acidity. Inorganic Chemistry. PMID 30422644 DOI: 10.1021/acs.inorgchem.8b02517  0.48
2018 Szkop KM, Jupp AR, Stephan DW. P, P-Dimethylformylphosphine: The Phosphorus Analogue of N, N-Dimethylformamide. Journal of the American Chemical Society. 140: 12751-12755. PMID 30269479 DOI: 10.1021/jacs.8b09266  0.48
2018 Stepen AJ, Bursch M, Grimme S, Stephan DW, Paradies JHH. Electrophilic phosphonium cation-mediated phosphane oxide reduction using oxalyl chloride and hydrogen. Angewandte Chemie (International Ed. in English). PMID 30230149 DOI: 10.1002/anie.201809275  0.88
2018 Bamford K, Chitnis S, Qu ZW, Stephan DW. Interactions of C-F bonds with hydridoboranes: Reduction, Borylation and Friedel-Crafts Alkylation. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 30222215 DOI: 10.1002/chem.201804705  0.68
2018 Lam J, Szkop KM, Mosaferi E, Stephan DW. FLP catalysis: main group hydrogenations of organic unsaturated substrates. Chemical Society Reviews. PMID 30178796 DOI: 10.1039/c8cs00277k  0.44
2018 Schneider C, LaFortune JHW, Melen RL, Stephan DW. Lewis and Brønsted basicity of phosphine-diazomethane derivatives. Dalton Transactions (Cambridge, England : 2003). PMID 30151513 DOI: 10.1039/c8dt02420k  1
2018 LaFortune JHW, Szkop KM, Farinha FE, Johnstone TC, Postle S, Stephan DW. Probing steric influences on electrophilic phosphonium cations: a comparison of [(3,5-(CF)CH)PF] and [(CF)PF]. Dalton Transactions (Cambridge, England : 2003). PMID 30063062 DOI: 10.1039/c8dt02594k  0.52
2018 Cao LL, Stephan DW. Reversible 1,1-hydroaluminations and C-H activation in reactions of a cyclic (alkyl)(amino) carbene with alane. Chemical Communications (Cambridge, England). PMID 29998266 DOI: 10.1039/c8cc05013a  0.6
2018 Xu M, Jupp A, Qu ZW, Stephan DW. Alkali Metal Species in the Reversible Activation of H2. Angewandte Chemie (International Ed. in English). PMID 29961980 DOI: 10.1002/anie.201806849  0.68
2018 Szkop KM, Zhu D, Longobardi LE, Heck J, Stephan DW. Interception of intermediates in phosphine oxidation by mesityl nitrile-N-oxide using frustrated Lewis pairs. Dalton Transactions (Cambridge, England : 2003). PMID 29922796 DOI: 10.1039/c8dt01717d  0.64
2018 Fan L, Jupp AR, Stephan DW. Remote Stereochemistry of a Frustrated Lewis Pair Provides Thermal and Photochemical Control of Reactivity. Journal of the American Chemical Society. PMID 29901995 DOI: 10.1021/jacs.8b05176  0.48
2018 Liu LL, Zhou J, Andrews R, Stephan DW. A Room-Temperature-Stable Phosphanorcaradiene. Journal of the American Chemical Society. PMID 29860832 DOI: 10.1021/jacs.8b04930  0.64
2018 Liu LL, Cao LL, Zhu D, Zhou J, Stephan DW. Homolytic cleavage of peroxide bonds via a single electron transfer of a frustrated Lewis pair. Chemical Communications (Cambridge, England). PMID 29781011 DOI: 10.1039/c8cc03522a  0.64
2018 Jupp AR, Johnstone TC, Stephan DW. The global electrophilicity index as a metric for Lewis acidity. Dalton Transactions (Cambridge, England : 2003). PMID 29737357 DOI: 10.1039/c8dt01699b  0.48
2018 Zhou J, Liu L, Cao L, Stephan DW. Reductive Coupling and Loss of N2 from Magnesium Diazomethane Derivatives. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 29719075 DOI: 10.1002/chem.201802138  0.64
2018 Eaton SS, Ngendahimana T, Eaton GR, Jupp AR, Stephan DW. Electron paramagnetic resonance of aB-containing heterocyclic radical. Journal of Magnetic Resonance (San Diego, Calif. : 1997). 290: 76-84. PMID 29579535 DOI: 10.1016/j.jmr.2018.03.007  0.6
2018 Chitnis S, Krischer F, Stephan DW. Catalytic hydrodefluorination of C-F bonds by an air-stable P(III) Lewis acid. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 29575313 DOI: 10.1002/chem.201801305  0.32
2018 Zhou J, Liu LL, Cao LL, Stephan DW. An umpolung of Lewis acidity/basicity at nitrogen by deprotonation of a cyclic (amino)(aryl)nitrenium cation. Chemical Communications (Cambridge, England). PMID 29527605 DOI: 10.1039/c8cc01331d  0.64
2018 Cao L, Bamford K, Liu L, Stephan DW. Zinc-Containing Radical Anions via Single Electron Transfer to Donor-Acceptor Adducts. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 29411915 DOI: 10.1002/chem.201800607  0.64
2018 Zhou J, Liu L, Cao L, Stephan DW. Nitrogen-Based Lewis Acids: Synthesis and Reactivity of A Cyclic (Alkyl)(Amino)Nitrenium Cation. Angewandte Chemie (International Ed. in English). PMID 29397010 DOI: 10.1002/anie.201713118  0.64
2017 Liu LL, Zhou J, Cao LL, Andrews R, Falconer R, Russell CA, Stephan DW. A Transient Vinylphosphinidene via a Phosphirene-Phosphinidene Rearrangement. Journal of the American Chemical Society. PMID 29272583 DOI: 10.1021/jacs.7b11791  0.64
2017 Liu LL, Stephan DW. An imine-gallium Lewis pair stabilized oxophosphinidene via an unexpected phosphirene rearrangement. Chemical Communications (Cambridge, England). PMID 29271427 DOI: 10.1039/c7cc09090k  0.6
2017 Tsao FA, Stephan DW. Synthesis and reactions of 4H-1,4-telluraborine. Chemical Communications (Cambridge, England). PMID 29230466 DOI: 10.1039/c7cc08765a  0.56
2017 LaFortune JHW, Bayne JM, Johnstone TC, Fan L, Stephan DW. Catalytic double hydroarylation of alkynes to 9,9-disubstituted 9,10-dihydroacridine derivatives by an electrophilic phenoxyphosphonium dication. Chemical Communications (Cambridge, England). PMID 29139487 DOI: 10.1039/c7cc08037a  0.52
2017 Barrado AG, Bayne JM, Johnstone TC, Lehmann CW, Stephan DW, Alcarazo M. Dicationic phosphonium salts: Lewis acid initiators for the Mukaiyama-aldol reaction. Dalton Transactions (Cambridge, England : 2003). PMID 29134217 DOI: 10.1039/c7dt03197a  0.36
2017 Mallov I, Ruddy A, Zhu H, Grimme S, Stephan DW. C-F Bond Activation by Silylium Cation/Phosphine Frustrated Lewis Pairs: Mono-Hydrodefluorination of PhCF3, PhCF2H and Ph2CF2. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 29116666 DOI: 10.1002/chem.201705276  0.88
2017 Tang C, Liang Q, Jupp A, Johnstone T, Neu R, Song D, Grimme S, Stephan DW. 1,1-Hydroboration and Borane Adduct of Diphenyldiazomethane: A Prelude to FLP-N2 Chemistry? Angewandte Chemie (International Ed. in English). PMID 29108092 DOI: 10.1002/anie.201710337  0.88
2017 Mehta M, Johnstone TC, Lam J, Bagh B, Hermannsdorfer A, Driess M, Stephan DW. Synthesis and oxidation of phosphine cations. Dalton Transactions (Cambridge, England : 2003). PMID 28981130 DOI: 10.1039/c7dt03175k  0.96
2017 Xu M, Jupp A, Stephan DW. Stoichiometric Reactions of CO2 and Indium-Silylamides and Catalytic Synthesis of Ureas. Angewandte Chemie (International Ed. in English). PMID 28922531 DOI: 10.1002/anie.201708921  0.68
2017 Szkop K, Jupp A, Suter R, Gruetzmacher H, Stephan DW. Borane-Stabilized Isomeric Dimers of the Phosphaethynolate Anion. Angewandte Chemie (International Ed. in English). PMID 28922529 DOI: 10.1002/anie.201708646  0.36
2017 Tsao FA, Sathaseevan A, Zhu H, Grimme S, Erker G, Stephan DW. Stoichiometric and catalytic isomerization of alkenylboranes using bulky Lewis bases. Chemical Communications (Cambridge, England). PMID 28795707 DOI: 10.1039/c7cc04904h  0.88
2017 Geier SJ, LaFortune JHW, Zhu D, Kosnik SC, Macdonald CLB, Stephan DW, Westcott SA. The phosphinoboration of carbodiimides, isocyanates, isothiocyanates and CO2. Dalton Transactions (Cambridge, England : 2003). PMID 28766623 DOI: 10.1039/c7dt02305g  0.64
2017 Stephan DW, Erker G. Frustrated Lewis pair chemistry. Philosophical Transactions. Series a, Mathematical, Physical, and Engineering Sciences. 375. PMID 28739971 DOI: 10.1098/rsta.2017.0239  0.56
2017 Xu M, Possart J, Waked AE, Roy J, Uhl W, Stephan DW. Halogenated triphenylgallium and -indium in frustrated Lewis pair activations and hydrogenation catalysis. Philosophical Transactions. Series a, Mathematical, Physical, and Engineering Sciences. 375. PMID 28739969 DOI: 10.1098/rsta.2017.0014  0.68
2017 Liu LL, Cao LL, Shao Y, Stephan DW. Single Electron Delivery to Lewis Pairs: An Avenue to Anions by Small Molecule Activation. Journal of the American Chemical Society. PMID 28654746 DOI: 10.1021/jacs.7b05120  0.6
2017 Mallov I, Johnstone TC, Burns DC, Stephan DW. A model for C-F activation by electrophilic phosphonium cations. Chemical Communications (Cambridge, England). PMID 28632273 DOI: 10.1039/c7cc04057a  0.72
2017 Chi JJ, Johnstone TC, Voicu D, Mehlmann P, Dielmann F, Kumacheva E, Stephan DW. Quantifying the efficiency of CO2 capture by Lewis pairs. Chemical Science. 8: 3270-3275. PMID 28553530 DOI: 10.1039/c6sc05607e  0.36
2017 Zhou J, Cao LL, Liu LL, Stephan DW. FLP reactivity of [Ph3C](+) and (o-tolyl)3P and the capture of a Staudinger reaction intermediate. Dalton Transactions (Cambridge, England : 2003). PMID 28548663 DOI: 10.1039/c7dt01726j  0.64
2017 Tsao FA, Stephan DW. Facile access to unsymmetrically substituted tellurium-boron based heterocycles. Chemical Communications (Cambridge, England). PMID 28548160 DOI: 10.1039/c7cc03648e  0.56
2017 Bamford KL, Longobardi LE, Liu L, Grimme S, Stephan DW. FLP reduction and hydroboration of phenanthrene o-iminoquinones and α-diimines. Dalton Transactions (Cambridge, England : 2003). PMID 28382362 DOI: 10.1039/c7dt01024a  0.88
2017 Liu LL, Zhu D, Cao LL, Stephan DW. N-Heterocyclic carbene stabilized parent sulfenyl, selenenyl, and tellurenyl cations (XH(+), X = S, Se, Te). Dalton Transactions (Cambridge, England : 2003). PMID 28145552 DOI: 10.1039/c7dt00186j  0.64
2017 Caputo CB, Stephan DW. Non-conventional Lewis acids and bases in frustrated Lewis pair chemistry Structure and Bonding. 171. DOI: 10.1007/430_2015_177  1
2016 Eaton SS, Huber K, Elajaili H, McPeak J, Eaton GR, Longobardi LE, Stephan DW. Electron spin relaxation of a boron-containing heterocyclic radical. Journal of Magnetic Resonance (San Diego, Calif. : 1997). 276: 7-13. PMID 28081476 DOI: 10.1016/j.jmr.2016.12.013  0.64
2016 Longobardi LE, Zatsepin P, Korol R, Liu L, Grimme S, Stephan DW. Reactions of Boron-Derived Radicals with Nucleophiles. Journal of the American Chemical Society. PMID 28026172 DOI: 10.1021/jacs.6b11190  0.88
2016 LaFortune JH, Johnstone TC, Pérez M, Winkelhaus D, Podgorny V, Stephan DW. Electrophilic phenoxy-substituted phosphonium cations. Dalton Transactions (Cambridge, England : 2003). PMID 27785488 DOI: 10.1039/c6dt03544b  0.36
2016 Pranckevicius C, Iovan DA, Stephan DW. Three and four coordinate Fe carbodiphosphorane complexes. Dalton Transactions (Cambridge, England : 2003). PMID 27711768 DOI: 10.1039/c6dt03453e  0.4
2016 Augurusa A, Mehta M, Perez M, Zhu J, Stephan DW. Catalytic reduction of amides to amines by electrophilic phosphonium cations via FLP hydrosilylation. Chemical Communications (Cambridge, England). 52: 12195-12198. PMID 27711344 DOI: 10.1039/c6cc06914b  1
2016 Tsao FA, Waked AE, Cao L, Hofmann J, Liu L, Grimme S, Stephan DW. S(vi) Lewis acids: fluorosulfoxonium cations. Chemical Communications (Cambridge, England). PMID 27711343 DOI: 10.1039/c6cc06929k  0.88
2016 Fleige M, Möbus J, Vom Stein T, Glorius F, Stephan DW. Lewis acid catalysis: catalytic hydroboration of alkynes initiated by Piers' borane. Chemical Communications (Cambridge, England). PMID 27425194 DOI: 10.1039/c6cc05360b  1
2016 Lam J, Günther BA, Farrell JM, Eisenberger P, Bestvater BP, Newman PD, Melen RL, Crudden CM, Stephan DW. Chiral carbene-borane adducts: precursors for borenium catalysts for asymmetric FLP hydrogenations. Dalton Transactions (Cambridge, England : 2003). PMID 27383522 DOI: 10.1039/c6dt02202b  1
2016 Longobardi L, Johnstone T, Falconer R, Russell C, Stephan DW. Hydroboration of Phosphaalkynes by HB(C6F5)2. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 27377569 DOI: 10.1002/chem.201602860  1
2016 Mosaferi E, Ripsman D, Stephan DW. The air-stable carbocation salt [(MeOC6H4)CPh2][BF4] in Lewis acid catalyzed hydrothiolation of alkenes. Chemical Communications (Cambridge, England). PMID 27293202 DOI: 10.1039/c6cc03970g  1
2016 Zhu J, Pérez M, Stephan DW. C-C Coupling of Benzyl Fluorides Catalyzed by an Electrophilic Phosphonium Cation. Angewandte Chemie (International Ed. in English). PMID 27239806 DOI: 10.1002/anie.201603627  1
2016 Fan L, Stephan DW. PNPCB heterocycles via thermal and Lewis acid catalyzed trans-hydroborations. Dalton Transactions (Cambridge, England : 2003). PMID 27177164 DOI: 10.1039/c6dt01659f  1
2016 Postle S, Podgorny V, Stephan DW. Electrophilic phosphonium cations (EPCs) with perchlorinated-aryl substituents: towards air-stable phosphorus-based Lewis acid catalysts. Dalton Transactions (Cambridge, England : 2003). PMID 27140402 DOI: 10.1039/c6dt01339b  1
2016 Möbus J, Vom Stein T, Stephan DW. Cooperative Lewis acidity in borane-substituted fluorophosphonium cations. Chemical Communications (Cambridge, England). PMID 27096885 DOI: 10.1039/c6cc02607a  1
2016 Pranckevicius C, Liu L, Bertrand G, Stephan DW. Synthesis of a Carbodicyclopropenylidene: A Carbodicarbene based Solely on Carbon. Angewandte Chemie (International Ed. in English). PMID 27028936 DOI: 10.1002/anie.201600765  1
2016 Cao LL, Daley E, Johnstone TC, Stephan DW. Cationic aluminum hydride complexes: reactions of carbene-alane adducts with trityl-borate. Chemical Communications (Cambridge, England). PMID 27001908 DOI: 10.1039/c6cc01585a  1
2016 Melen RL, Stephan DW. Main group transformations. Dalton Transactions (Cambridge, England : 2003). PMID 26997409 DOI: 10.1039/c6dt90027e  1
2016 Mallov I, Stephan DW. Ferrocenyl-derived electrophilic phosphonium cations (EPCs) as Lewis acid catalysts. Dalton Transactions (Cambridge, England : 2003). PMID 26911641 DOI: 10.1039/c6dt00105j  1
2016 Longobardi LE, Liu L, Grimme S, Stephan DW. Stable Borocyclic Radicals via Frustrated Lewis Pair Hydrogenations. Journal of the American Chemical Society. PMID 26846796 DOI: 10.1021/jacs.5b12823  1
2016 McKinty AM, Stephan DW. Ru alkylidene compounds bearing tridentate, dianionic ligands: Lewis acid activation and olefin metathesis. Dalton Transactions (Cambridge, England : 2003). PMID 26822161 DOI: 10.1039/c5dt04481b  1
2016 Mosaferi E, Pan L, Wang T, Sun Y, Pranckevicius C, Stephan DW. Preparation and reactivity of a Ru(0) phosphino-carbene complex. Dalton Transactions (Cambridge, England : 2003). PMID 26743813 DOI: 10.1039/c5dt04337a  1
2016 Mehta M, Garcia De La Arada I, Perez M, Porwal D, Oestreich M, Stephan DW. Metal-Free Phosphine Oxide Reductions Catalyzed by B(C6F5)3 and Electrophilic Fluorophosphonium Cations Organometallics. 35: 1030-1035. DOI: 10.1021/acs.organomet.6b00158  1
2015 Winkelhaus D, Holthausen MH, Dobrovetsky R, Stephan DW. Phosphine and carbene azido-cations: [(L)N] and [(L)N]. Chemical Science. 6: 6367-6372. PMID 30090255 DOI: 10.1039/c5sc02336j  0.44
2015 Farrell JM, Posaratnanathan RT, Stephan DW. A family of N-heterocyclic carbene-stabilized borenium ions for metal-free imine hydrogenation catalysis. Chemical Science. 6: 2010-2015. PMID 29449920 DOI: 10.1039/c4sc03675a  1
2015 Zhang Z, Edkins RM, Nitsch J, Fucke K, Steffen A, Longobardi LE, Stephan DW, Lambert C, Marder TB. Optical and electronic properties of air-stable organoboron compounds with strongly electron-accepting bis(fluoromesityl)boryl groups. Chemical Science. 6: 308-321. PMID 28966759 DOI: 10.1039/c4sc02410a  0.64
2015 Bayne JM, Holthausen MH, Stephan DW. Pyridinium-phosphonium dications: highly electrophilic phosphorus-based Lewis acid catalysts. Dalton Transactions (Cambridge, England : 2003). PMID 26666332 DOI: 10.1039/c5dt03796d  1
2015 Zhu J, Pérez M, Caputo CB, Stephan DW. Use of Trifluoromethyl Groups for Catalytic Benzylation and Alkylation with Subsequent Hydrodefluorination. Angewandte Chemie (International Ed. in English). PMID 26663711 DOI: 10.1002/anie.201510494  1
2015 Voicu D, Stephan DW, Kumacheva E. Microfluidic Separation of Ethylene and Ethane Using Frustrated Lewis Pairs. Chemsuschem. PMID 26609918 DOI: 10.1002/cssc.201501160  1
2015 Hansmann MM, Melen RL, Rudolph M, Rominger F, Wadepohl H, Stephan DW, Hashmi AS. Cyclopropanation / Carboboration Reactions of Enynes with B(C6F5)3. Journal of the American Chemical Society. PMID 26580316 DOI: 10.1021/jacs.5b09311  1
2015 Tsao FA, Cao L, Grimme S, Stephan DW. Double FLP-Alkyne Exchange Reactions: A Facile Route to Te/B Heterocycles. Journal of the American Chemical Society. 137: 13264-7. PMID 26447492 DOI: 10.1021/jacs.5b09526  1
2015 Farrell JM, Stephan DW. Synthesis of a diboryl-N-heterocycle and its conversion to a bidentate cationic Lewis acid. Chemical Communications (Cambridge, England). 51: 14322-5. PMID 26273801 DOI: 10.1039/c5cc06248a  1
2015 Bayne JM, Stephan DW. Phosphorus Lewis acids: emerging reactivity and applications in catalysis. Chemical Society Reviews. PMID 26255595 DOI: 10.1039/c5cs00516g  1
2015 Stephan DW. Frustrated Lewis Pairs. Journal of the American Chemical Society. 137: 10018-32. PMID 26214241 DOI: 10.1021/jacs.5b06794  1
2015 Vom Stein T, Peréz M, Dobrovetsky R, Winkelhaus D, Caputo CB, Stephan DW. Electrophilic Fluorophosphonium Cations in Frustrated Lewis Pair Hydrogen Activation and Catalytic Hydrogenation of Olefins. Angewandte Chemie (International Ed. in English). 54: 10178-82. PMID 26178268 DOI: 10.1002/anie.201504109  1
2015 Pérez M, Mahdi T, Hounjet LJ, Stephan DW. Electrophilic phosphonium cations catalyze hydroarylation and hydrothiolation of olefins. Chemical Communications (Cambridge, England). 51: 11301-4. PMID 26083901 DOI: 10.1039/c5cc03572d  1
2015 Mehta M, Holthausen MH, Mallov I, Pérez M, Qu ZW, Grimme S, Stephan DW. Catalytic Ketone Hydrodeoxygenation Mediated by Highly Electrophilic Phosphonium Cations. Angewandte Chemie (International Ed. in English). 54: 8250-4. PMID 26032844 DOI: 10.1002/anie.201502579  1
2015 Holthausen MH, Bayne JM, Mallov I, Dobrovetsky R, Stephan DW. 1,2-Diphosphonium dication: a strong P-based Lewis acid in frustrated lewis pair (FLP)-activations of B-H, Si-H, C-H, and H-H bonds. Journal of the American Chemical Society. 137: 7298-301. PMID 26030269 DOI: 10.1021/jacs.5b04109  0.72
2015 Stephan DW, Erker G. Frustrated lewis pair chemistry: development and perspectives. Angewandte Chemie (International Ed. in English). 54: 6400-41. PMID 25974714 DOI: 10.1002/anie.201409800  1
2015 Pranckevicius C, Fan L, Stephan DW. Cyclic bent allene hydrido-carbonyl complexes of ruthenium: highly active catalysts for hydrogenation of olefins. Journal of the American Chemical Society. 137: 5582-9. PMID 25855868 DOI: 10.1021/jacs.5b02203  1
2015 Eller C, Kehr G, Daniliuc CG, Stephan DW, Erker G. Thiophene synthesis via 1,1-carboboration. Chemical Communications (Cambridge, England). 51: 7226-9. PMID 25813555 DOI: 10.1039/c5cc01806d  1
2015 Longobardi LE, Mahdi T, Stephan DW. B(C6F5)3 mediated arene hydrogenation/transannulation of para-methoxyanilines. Dalton Transactions (Cambridge, England : 2003). 44: 7114-7. PMID 25797146 DOI: 10.1039/c5dt00921a  1
2015 Caputo CB, Winkelhaus D, Dobrovetsky R, Hounjet LJ, Stephan DW. Synthesis and Lewis acidity of fluorophosphonium cations. Dalton Transactions (Cambridge, England : 2003). 44: 12256-64. PMID 25785571 DOI: 10.1039/c5dt00217f  1
2015 Pérez M, Qu ZW, Caputo CB, Podgorny V, Hounjet LJ, Hansen A, Dobrovetsky R, Grimme S, Stephan DW. Hydrosilylation of ketones, imines and nitriles catalysed by electrophilic phosphonium cations: functional group selectivity and mechanistic considerations. Chemistry (Weinheim An Der Bergstrasse, Germany). 21: 6491-500. PMID 25758303 DOI: 10.1002/chem.201406356  1
2015 Farrell JM, Stephan DW. Planar N-heterocyclic carbene diarylborenium ions: synthesis by cationic borylation and reactivity with Lewis bases. Angewandte Chemie (International Ed. in English). 54: 5214-7. PMID 25756464 DOI: 10.1002/anie.201500198  1
2015 Melen RL, Stephan DW. Cycloaddition reactions of (C6F5)2BN3 with dialkyl acetylenedicarboxylates. Dalton Transactions (Cambridge, England : 2003). 44: 5045-8. PMID 25687829 DOI: 10.1039/c5dt00316d  1
2015 Tsao FA, Lough AJ, Stephan DW. Intramolecular 1,1-carboboration versus intermolecular FLP addition in reactions of boranes and bis(phenylethynyl)telluroether. Chemical Communications (Cambridge, England). 51: 4287-9. PMID 25672760 DOI: 10.1039/c4cc09258a  0.64
2015 Dobrovetsky R, Takeuchi K, Stephan DW. Metal-free Lewis acid mediated dehydrocoupling of phosphines and concurrent hydrogenation. Chemical Communications (Cambridge, England). 51: 2396-8. PMID 25564430 DOI: 10.1039/c4cc09526j  1
2015 Dahcheh F, Stephan DW. Bis-mixed-carbene ruthenium-thiolate-alkylidene complexes: synthesis and olefin metathesis activity. Dalton Transactions (Cambridge, England : 2003). 44: 1724-33. PMID 25462569 DOI: 10.1039/c4dt03137g  1
2015 Dahcheh F, Stephan DW, Bertrand G. Oxidative addition at a carbene center: synthesis of an iminoboryl-CAAC adduct. Chemistry (Weinheim An Der Bergstrasse, Germany). 21: 199-204. PMID 25414006 DOI: 10.1002/chem.201405887  1
2015 Tsao FA, Stephan DW. 1,1-Carboboration to tellurium-boron intramolecular frustrated Lewis pairs. Dalton Transactions (Cambridge, England : 2003). 44: 71-4. PMID 25408099 DOI: 10.1039/c4dt03241a  0.56
2015 Bagh B, McKinty AM, Lough AJ, Stephan DW. 1,2,3-Triazolylidene ruthenium(II)-cyclometalated complexes and olefin selective hydrogenation catalysis. Dalton Transactions (Cambridge, England : 2003). 44: 2712-23. PMID 25407939 DOI: 10.1039/c4dt03156c  1
2015 Longobardi LE, Wolter V, Stephan DW. Frustrated Lewis pair activation of an N-sulfinylamine: a source of sulfur monoxide. Angewandte Chemie (International Ed. in English). 54: 809-12. PMID 25376102 DOI: 10.1002/anie.201409969  1
2015 Weicker SA, Stephan DW. Main group Lewis acids in frustrated Lewis pair chemistry: Beyond electrophilic boranes Bulletin of the Chemical Society of Japan. 88: 1003-1016. DOI: 10.1246/bcsj.20150131  1
2015 Winkelhaus D, Holthausen MH, Dobrovetsky R, Stephan DW. Phosphine and carbene azido-cations: [(L)N3]+ and [(L)2N3]+ Chemical Science. 6: 6367-6372. DOI: 10.1039/c5sc02336j  1
2015 Holthausen MH, Hiranandani RR, Stephan DW. Electrophilic bis-fluorophosphonium dications: Lewis acid catalysts from diphosphines Chemical Science. 6: 2016-2021. DOI: 10.1039/c5sc00051c  1
2015 Melen RL, Stephan DW. Cycloaddition reactions of (C6F5)2BN3 with dialkyl acetylenedicarboxylates Dalton Transactions. 44: 5045-5048. DOI: 10.1039/c5dt00316d  1
2015 Postle S, Stephan DW. Reactions of iodine-nitrene reagents with boranes Dalton Transactions. 44: 4436-4439. DOI: 10.1039/c5dt00142k  1
2015 Courtemanche MA, Pulis AP, Rochette É, Légaré MA, Stephan DW, Fontaine FG. Intramolecular B/N frustrated Lewis pairs and the hydrogenation of carbon dioxide Chemical Communications. 51: 9797-9800. DOI: 10.1039/c5cc03072b  1
2015 Farrell JM, Posaratnanathan RT, Stephan DW. A family of N-heterocyclic carbene-stabilized borenium ions for metal-free imine hydrogenation catalysis Chemical Science. 6: 2010-2015. DOI: 10.1039/c4sc03675a  1
2015 Zhang Z, Edkins RM, Nitsch J, Fucke K, Steffen A, Longobardi LE, Stephan DW, Lambert C, Marder TB. Optical and electronic properties of air-stable organoboron compounds with strongly electron-accepting bis(fluoromesityl)boryl groups Chemical Science. 6: 308-321. DOI: 10.1039/c4sc02410a  1
2015 Tsao FA, Stephan DW. 1,1-Carboboration to tellurium-boron intramolecular frustrated Lewis pairs Dalton Transactions. 44: 71-74. DOI: 10.1039/c4dt03241a  1
2015 Dahcheh F, Stephan DW. Bis-mixed-carbene ruthenium-thiolate-alkylidene complexes: Synthesis and olefin metathesis activity Dalton Transactions. 44: 1724-1733. DOI: 10.1039/c4dt03137g  1
2015 Tsao FA, Lough AJ, Stephan DW. Intramolecular 1,1-carboboration versus intermolecular FLP addition in reactions of boranes and bis(phenylethynyl)telluroether Chemical Communications. 51: 4287-4289. DOI: 10.1039/c4cc09258a  1
2015 Holthausen MH, Bayne JM, Mallov I, Dobrovetsky R, Stephan DW. 1,2-Diphosphonium Dication: A Strong P-Based Lewis Acid in Frustrated Lewis Pair (FLP)-Activations of B-H, Si-H, C-H, and H-H Bonds Journal of the American Chemical Society. 137: 7298-7301. DOI: 10.1021/jacs.5b04109  1
2015 Stephan DW. Frustrated Lewis pairs: From concept to catalysis Accounts of Chemical Research. 48: 306-316. DOI: 10.1021/ar500375j  1
2015 Melen RL, Wilkins LC, Kariuki BM, Wadepohl H, Gade LH, Hashmi ASK, Stephan DW, Hansmann MM. Diverging Pathways in the Activation of Allenes with Lewis Acids and Bases: Addition, 1,2-Carboboration, and Cyclization Organometallics. 34: 4127-4137. DOI: 10.1021/acs.organomet.5b00546  1
2015 Dobrovetsky R, Stephan DW. TBu3P/ZnR2 (R=Et, I) frustrated lewis pair catalysts for functionalization and reduction of CO2 Israel Journal of Chemistry. 55: 206-209. DOI: 10.1002/ijch.201400121  1
2015 Weicker SA, Stephan DW. Activation of Carbon Dioxide by Silyl Triflate-Based Frustrated Lewis Pairs Chemistry - a European Journal. DOI: 10.1002/chem.201501904  1
2015 Mahdi T, Stephan DW. Stoichiometric and Catalytic Inter- and Intramolecular Hydroamination of Terminal Alkynes by Frustrated Lewis Pairs Chemistry - a European Journal. DOI: 10.1002/chem.201501535  1
2015 Dahcheh F, Stephan DW, Bertrand G. Oxidative addition at a carbene center: Synthesis of an iminoboryl-CAAC adduct Chemistry - a European Journal. 21: 199-204. DOI: 10.1002/chem.201405887  1
2015 Holthausen MH, Colussi M, Stephan DW. B(C6F5)3-mediated transformations and hydrogenation of carbodiimides Chemistry - a European Journal. 21: 2193-2199. DOI: 10.1002/chem.201405014  1
2015 Mahdi T, Stephan DW. Facile Protocol for Catalytic Frustrated Lewis Pair Hydrogenation and Reductive Deoxygenation of Ketones and Aldehydes Angewandte Chemie - International Edition. DOI: 10.1002/anie.201503087  1
2015 Farrell JM, Stephan DW. Planar N-heterocyclic carbene diarylborenium ions: Synthesis by cationic borylation and reactivity with Lewis bases Angewandte Chemie - International Edition. 54: 5214-5217. DOI: 10.1002/anie.201500198  1
2014 Dahcheh F, Martin D, Stephan DW, Bertrand G. Synthesis and reactivity of a CAAC-aminoborylene adduct: a hetero-allene or an organoboron isoelectronic with singlet carbenes. Angewandte Chemie (International Ed. in English). 53: 13159-63. PMID 25267591 DOI: 10.1002/anie.201408371  1
2014 Longobardi LE, Tang C, Stephan DW. Stoichiometric reductions of alkyl-substituted ketones and aldehydes to borinic esters. Dalton Transactions (Cambridge, England : 2003). 43: 15723-6. PMID 25250629 DOI: 10.1039/c4dt02648a  1
2014 Bagh B, Stephan DW. Half sandwich ruthenium(II) hydrides: hydrogenation of terminal, internal, cyclic and functionalized olefins. Dalton Transactions (Cambridge, England : 2003). 43: 15638-45. PMID 25208607 DOI: 10.1039/c4dt02407a  0.44
2014 Holthausen MH, Mallov I, Stephan DW. Phosphinimine-substituted boranes and borenium ions. Dalton Transactions (Cambridge, England : 2003). 43: 15201-11. PMID 25184519 DOI: 10.1039/c4dt02406k  0.72
2014 Longobardi LE, Russell CA, Green M, Townsend NS, Wang K, Holmes AJ, Duckett SB, McGrady JE, Stephan DW. Hydrogen activation by an aromatic triphosphabenzene. Journal of the American Chemical Society. 136: 13453-7. PMID 25166923 DOI: 10.1021/ja5077525  1
2014 Morton JG, Al-Shammari H, Sun Y, Zhu J, Stephan DW. 1,1-Olefin-bridged bis-(2-indenyl) metallocenes of titanium and zirconium. Dalton Transactions (Cambridge, England : 2003). 43: 13219-31. PMID 25072169 DOI: 10.1039/c4dt01583e  1
2014 Ekkert O, Caputo CB, Pranckevicius C, Daniliuc CG, Kehr G, Erker G, Stephan DW. Reactivity of an intramolecular fluorophosphonium fluoroborate. Chemistry (Weinheim An Der Bergstrasse, Germany). 20: 11287-90. PMID 25065355 DOI: 10.1002/chem.201403110  1
2014 Ekkert O, Caputo CB, Pranckevicius C, Daniliuc CG, Kehr G, Erker G, Stephan DW. Reactivity of an intramolecular fluorophosphonium fluoroborate. Chemistry (Weinheim An Der Bergstrasse, Germany). 20: 11287-90. PMID 25065355 DOI: 10.1002/chem.201403110  1
2014 Holthausen MH, Mahdi T, Schlepphorst C, Hounjet LJ, Weigand JJ, Stephan DW. Frustrated Lewis pair-mediated C-O or C-H bond activation of ethers. Chemical Communications (Cambridge, England). 50: 10038-40. PMID 25051013 DOI: 10.1039/c4cc01922a  0.32
2014 Pérez M, Caputo CB, Dobrovetsky R, Stephan DW. Metal-free transfer hydrogenation of olefins via dehydrocoupling catalysis. Proceedings of the National Academy of Sciences of the United States of America. 111: 10917-21. PMID 25002489 DOI: 10.1073/pnas.1407484111  1
2014 Bagh B, McKinty AM, Lough AJ, Stephan DW. 1,2,3-Triazolylidene ruthenium(II)(η⁶-arene) complexes: synthesis, metallation and reactivity. Dalton Transactions (Cambridge, England : 2003). 43: 12842-50. PMID 24931360 DOI: 10.1039/c4dt01174k  1
2014 Wang T, Stephan DW. Phosphine catalyzed reduction of CO2 with boranes. Chemical Communications (Cambridge, England). 50: 7007-10. PMID 24844447 DOI: 10.1039/c4cc02103g  0.56
2014 Holthausen MH, Mehta M, Stephan DW. The highly Lewis acidic dicationic phosphonium salt: [(SIMes)PFPh₂][B(C₆F₅)₄]₂. Angewandte Chemie (International Ed. in English). 53: 6538-41. PMID 24828457 DOI: 10.1002/anie.201403693  1
2014 Holthausen MH, Mehta M, Stephan DW. The highly Lewis acidic dicationic phosphonium salt: [(SIMes)PFPh₂][B(C₆F₅)₄]₂. Angewandte Chemie (International Ed. in English). 53: 6538-41. PMID 24828457 DOI: 10.1002/anie.201403693  1
2014 Hansmann MM, Melen RL, Rominger F, Hashmi AS, Stephan DW. B(C₆F₅)₃ promoted cyclisation of internal propargyl esters: structural characterisation of 1,3-dioxolium compounds. Chemical Communications (Cambridge, England). 50: 7243-5. PMID 24817134 DOI: 10.1039/c4cc01370k  1
2014 Hansmann MM, Melen RL, Rominger F, Hashmi AS, Stephan DW. B(C₆F₅)₃ promoted cyclisation of internal propargyl esters: structural characterisation of 1,3-dioxolium compounds. Chemical Communications (Cambridge, England). 50: 7243-5. PMID 24817134 DOI: 10.1039/c4cc01370k  1
2014 Pranckevicius C, Stephan DW. Ruthenium complexes of an abnormally bound, anionic N-heterocyclic carbene. Chemistry (Weinheim An Der Bergstrasse, Germany). 20: 6597-602. PMID 24782270 DOI: 10.1002/chem.201402080  0.4
2014 Wang T, Stephan DW. Carbene-9-BBN ring expansions as a route to intramolecular frustrated Lewis pairs for CO2 reduction. Chemistry (Weinheim An Der Bergstrasse, Germany). 20: 3036-9. PMID 24677611 DOI: 10.1002/chem.201304870  0.56
2014 Boone MP, Stephan DW. Ru-η(6) -arene cations [{(Ph2 PC6 H4 )2 B(η(6) -Ph)}RuX](+) (X=Cl, H) as Lewis acids. Chemistry (Weinheim An Der Bergstrasse, Germany). 20: 3333-41. PMID 24616079 DOI: 10.1002/chem.201304289  1
2014 Voicu D, Abolhasani M, Choueiri R, Lestari G, Seiler C, Menard G, Greener J, Guenther A, Stephan DW, Kumacheva E. Microfluidic studies of CO2 sequestration by frustrated Lewis pairs. Journal of the American Chemical Society. 136: 3875-80. PMID 24555752 DOI: 10.1021/ja411601a  1
2014 Voicu D, Abolhasani M, Choueiri R, Lestari G, Seiler C, Menard G, Greener J, Guenther A, Stephan DW, Kumacheva E. Microfluidic studies of CO2 sequestration by frustrated Lewis pairs. Journal of the American Chemical Society. 136: 3875-80. PMID 24555752 DOI: 10.1021/ja411601a  1
2014 Dahcheh F, Stephan DW. Reactions of ruthenium hydrides with ethyl-vinyl sulfide. Dalton Transactions (Cambridge, England : 2003). 43: 3501-7. PMID 24441082 DOI: 10.1039/c3dt53326c  1
2014 McKinty AM, Stephan DW. A facile route to Ru-alkylidenes. Dalton Transactions (Cambridge, England : 2003). 43: 2710-2. PMID 24385088 DOI: 10.1039/c3dt53525h  1
2014 Hansmann MM, Melen RL, Rominger F, Hashmi AS, Stephan DW. Activation of alkynes with B(C₆F₅)₃--boron allylation reagents derived from propargyl esters. Journal of the American Chemical Society. 136: 777-82. PMID 24354408 DOI: 10.1021/ja4110842  1
2014 Hatnean JA, Thomson JW, Chase PA, Stephan DW. Imine hydrogenation by alkylaluminum catalysts. Chemical Communications (Cambridge, England). 50: 301-3. PMID 24247254 DOI: 10.1039/c3cc47889k  1
2014 Dornan PK, Longobardi LE, Stephan DW. Reversible frustrated lewis pair addition of n-heterocycles to unsaturated c-c bonds Synlett. 25: 1521-1524. DOI: 10.1055/s-0033-1341072  1
2014 Dornan PK, Longobardi LE, Stephan DW. Reversible frustrated lewis pair addition of n-heterocycles to unsaturated c-c bonds Synlett. 25: 1521-1524. DOI: 10.1055/s-0033-1341072  0.64
2014 Stephan DW, Erker G. Frustrated Lewis pair chemistry of carbon, nitrogen and sulfur oxides Chemical Science. 5: 2625-2641. DOI: 10.1039/c4sc00395k  1
2014 Bagh B, Stephan DW. Half sandwich ruthenium(ii) hydrides: Hydrogenation of terminal, internal, cyclic and functionalized olefins Dalton Transactions. 43: 15638-15645. DOI: 10.1039/c4dt02407a  1
2014 Holthausen MH, Mallov I, Stephan DW. Phosphinimine-substituted boranes and borenium ions Dalton Transactions. 43: 15201-15211. DOI: 10.1039/c4dt02406k  1
2014 Bagh B, McKinty AM, Lough AJ, Stephan DW. 1,2,3-Triazolylidene ruthenium(ii)(η6-arene) complexes: Synthesis, metallation and reactivity Dalton Transactions. 43: 12842-12850. DOI: 10.1039/c4dt01174k  1
2014 Jochmann P, Stephan DW. The synthesis and structure of [Zn(TEMPO)2]2 and [Zn(μ-H)(μ2-η1:η1-TEMPO)] 6 Chemical Communications. 50: 8395-8397. DOI: 10.1039/c4cc03256j  1
2014 Wang T, Stephan DW. Phosphine catalyzed reduction of CO2 with boranes Chemical Communications. 50: 7007-7010. DOI: 10.1039/c4cc02103g  1
2014 Wang T, Stephan DW. Phosphine catalyzed reduction of CO2 with boranes Chemical Communications. 50: 7007-7010. DOI: 10.1039/c4cc02103g  0.56
2014 Holthausen MH, Mahdi T, Schlepphorst C, Hounjet LJ, Weigand JJ, Stephan DW. Frustrated Lewis pair-mediated C-O or C-H bond activation of ethers Chemical Communications. 50: 10038-10040. DOI: 10.1039/c4cc01922a  1
2014 McKinty AM, Stephan DW. A facile route to Ru-alkylidenes Dalton Transactions. 43: 2710-2712. DOI: 10.1039/c3dt53525h  1
2014 McKinty AM, Stephan DW. A facile route to Ru-alkylidenes Dalton Transactions. 43: 2710-2712. DOI: 10.1039/c3dt53525h  1
2014 Dahcheh F, Stephan DW. Reactions of ruthenium hydrides with ethyl-vinyl sulfide Dalton Transactions. 43: 3501-3507. DOI: 10.1039/c3dt53326c  1
2014 Dahcheh F, Stephan DW. Reactions of ruthenium hydrides with ethyl-vinyl sulfide Dalton Transactions. 43: 3501-3507. DOI: 10.1039/c3dt53326c  1
2014 Hatnean JA, Thomson JW, Chase PA, Stephan DW. Imine hydrogenation by alkylaluminum catalysts Chemical Communications. 50: 301-303. DOI: 10.1039/c3cc47889k  1
2014 Hatnean JA, Thomson JW, Chase PA, Stephan DW. Imine hydrogenation by alkylaluminum catalysts Chemical Communications. 50: 301-303. DOI: 10.1039/c3cc47889k  1
2014 Hounjet LJ, Stephan DW. Hydrogenation by frustrated lewis pairs: Main group alternatives to transition metal catalysts? Organic Process Research and Development. 18: 385-391. DOI: 10.1021/op400315m  1
2014 Hansmann MM, Rominger F, Boone MP, Stephan DW, Hashmi ASK. Reactivity of organogold compounds with B(C6F5)3: Gold-boron transmetalation via σ-B/π-Au species Organometallics. 33: 4461-4470. DOI: 10.1021/om5006885  1
2014 Hansmann MM, Rominger F, Boone MP, Stephan DW, Hashmi ASK. Reactivity of organogold compounds with B(C6F5)3: Gold-boron transmetalation via σ-B/π-Au species Organometallics. 33: 4461-4470. DOI: 10.1021/om5006885  1
2014 Sgro MJ, Dahcheh F, Stephan DW. Synthesis and reactivity of ruthenium hydride complexes containing a tripodal aminophosphine ligand Organometallics. 33: 578-586. DOI: 10.1021/om4011388  1
2014 Sgro MJ, Dahcheh F, Stephan DW. Synthesis and reactivity of ruthenium hydride complexes containing a tripodal aminophosphine ligand Organometallics. 33: 578-586. DOI: 10.1021/om4011388  1
2014 Boone MP, Stephan DW. Ancillary metal centers in frustrated lewis pair chemistry: Ruthenium acetylide as a lewis base in the activation of CO2, aldehyde, and alkyne Organometallics. 33: 387-393. DOI: 10.1021/om401118n  1
2014 Boone MP, Stephan DW. Ancillary metal centers in frustrated lewis pair chemistry: Ruthenium acetylide as a lewis base in the activation of CO2, aldehyde, and alkyne Organometallics. 33: 387-393. DOI: 10.1021/om401118n  1
2014 Mahdi T, Stephan DW. Enabling catalytic ketone hydrogenation by frustrated lewis pairs Journal of the American Chemical Society. 136: 15809-15812. DOI: 10.1021/ja508829x  1
2014 Jochmann P, Stephan DW. Zincocene and dizincocene N-heterocyclic carbene complexes and catalytic hydrogenation of imines and ketones Chemistry - a European Journal. 20: 8370-8378. DOI: 10.1002/chem.201402875  1
2014 Pranckevicius C, Stephan DW. Ruthenium complexes of an abnormally bound, anionic N-heterocyclic carbene Chemistry - a European Journal. 20: 6597-6602. DOI: 10.1002/chem.201402080  1
2014 Pranckevicius C, Stephan DW. Ruthenium complexes of an abnormally bound, anionic N-heterocyclic carbene Chemistry - a European Journal. 20: 6597-6602. DOI: 10.1002/chem.201402080  0.4
2014 Wang T, Stephan DW. Carbene-9-BBN ring expansions as a route to intramolecular frustrated lewis pairs for CO2 reduction Chemistry - a European Journal. 20: 3036-3039. DOI: 10.1002/chem.201304870  1
2014 Wang T, Stephan DW. Carbene-9-BBN ring expansions as a route to intramolecular frustrated lewis pairs for CO2 reduction Chemistry - a European Journal. 20: 3036-3039. DOI: 10.1002/chem.201304870  0.56
2014 Boone MP, Stephan DW. Ru-η6-arene cations [{(Ph2PC6H 4)2B(η6-Ph)}RuX]+ (X=Cl, H) as Lewis acids Chemistry - a European Journal. 20: 3333-3341. DOI: 10.1002/chem.201304289  1
2014 Dahcheh F, Martin D, Stephan DW, Bertrand G. Synthesis and reactivity of a CAAC-aminoborylene adduct: A hetero-allene or an organoboron isoelectronic with singlet carbenes Angewandte Chemie - International Edition. 53: 13159-13163. DOI: 10.1002/anie.201408371  1
2014 Winkelhaus D, Stephan DW. Boron perturbed click reactions prompt aromatic C-H activations Angewandte Chemie - International Edition. 53: 5414-5417. DOI: 10.1002/anie.201402567  1
2013 Pérez M, Hounjet LJ, Caputo CB, Dobrovetsky R, Stephan DW. Olefin isomerization and hydrosilylation catalysis by Lewis acidic organofluorophosphonium salts. Journal of the American Chemical Society. 135: 18308-10. PMID 24256456 DOI: 10.1021/ja410379x  1
2013 Pérez M, Hounjet LJ, Caputo CB, Dobrovetsky R, Stephan DW. Olefin isomerization and hydrosilylation catalysis by Lewis acidic organofluorophosphonium salts. Journal of the American Chemical Society. 135: 18308-10. PMID 24256456 DOI: 10.1021/ja410379x  1
2013 Caputo CB, Hounjet LJ, Dobrovetsky R, Stephan DW. Lewis acidity of organofluorophosphonium salts: hydrodefluorination by a saturated acceptor. Science (New York, N.Y.). 341: 1374-7. PMID 24052304 DOI: 10.1126/science.1241764  1
2013 Melen RL, Hansmann MM, Lough AJ, Hashmi AS, Stephan DW. Cyclisation versus 1,1-Carboboration: Reactions of B(C6F5)3 with Propargyl Amides. Chemistry (Weinheim An Der Bergstrasse, Germany). 19: 11928-38. PMID 23922200 DOI: 10.1002/chem.201301899  1
2013 Ménard G, Tran L, Stephan DW. Activation of H2 using P/Al based frustrated Lewis pairs and reactions with olefins. Dalton Transactions (Cambridge, England : 2003). 42: 13685-91. PMID 23903205 DOI: 10.1039/c3dt51739j  1
2013 Jochmann P, Stephan DW. H2 cleavage, hydride formation, and catalytic hydrogenation of imines with zinc complexes of C5Me5 and N-heterocyclic carbenes. Angewandte Chemie (International Ed. in English). 52: 9831-5. PMID 23868720 DOI: 10.1002/anie.201303968  1
2013 Hounjet LJ, Bannwarth C, Garon CN, Caputo CB, Grimme S, Stephan DW. Combinations of ethers and B(C6F5)3 function as hydrogenation catalysts. Angewandte Chemie (International Ed. in English). 52: 7492-5. PMID 23775686 DOI: 10.1002/anie.201303166  1
2013 Sgro MJ, Stephan DW. Synthesis and reactivity of ruthenium tridentate bis-phosphinite ligand complexes. Dalton Transactions (Cambridge, England : 2003). 42: 10460-72. PMID 23760398 DOI: 10.1039/c3dt51065d  1
2013 Boone MP, Stephan DW. A Ru-η6-arene complex as a C-based Lewis acid in the activation of hydrogen and hydrogenation catalysis. Journal of the American Chemical Society. 135: 8508-11. PMID 23718884 DOI: 10.1021/ja403912n  1
2013 Melen RL, Lough AJ, Stephan DW. Boron azides in Staudinger oxidations and cycloadditions. Dalton Transactions (Cambridge, England : 2003). 42: 8674-83. PMID 23652382 DOI: 10.1039/c3dt50791b  1
2013 Ménard G, Hatnean JA, Cowley HJ, Lough AJ, Rawson JM, Stephan DW. C-H bond activation by radical ion pairs derived from R3P/Al(C6F5)3 frustrated Lewis pairs and N2O. Journal of the American Chemical Society. 135: 6446-9. PMID 23594345 DOI: 10.1021/ja402964h  1
2013 Dobrovetsky R, Stephan DW. Stoichiometric metal-free reduction of CO in syn-gas. Journal of the American Chemical Society. 135: 4974-7. PMID 23521150 DOI: 10.1021/ja401492s  1
2013 Stephan DW. Catalysis: A step closer to a methanol economy. Nature. 495: 54-5. PMID 23446350 DOI: 10.1038/nature11955  1
2013 Melen RL, Stephan DW. Cycloaddition reactions between dicyclohexylboron azide and alkynes. Dalton Transactions (Cambridge, England : 2003). 42: 4795-8. PMID 23436044 DOI: 10.1039/c3dt00068k  1
2013 Ménard G, Stephan DW. CO2 reduction via aluminum complexes of ammonia boranes. Dalton Transactions (Cambridge, England : 2003). 42: 5447-53. PMID 23423186 DOI: 10.1039/c3dt00098b  1
2013 Cariou R, Graham TW, Stephan DW. Synthesis and reactivity of nickel-hydride amino-bis-phosphinimine complexes. Dalton Transactions (Cambridge, England : 2003). 42: 4237-9. PMID 23392453 DOI: 10.1039/c3dt33021d  1
2013 Sgro MJ, Stephan DW. Activation of CO2 by phosphinoamide hafnium complexes. Chemical Communications (Cambridge, England). 49: 2610-2. PMID 23385828 DOI: 10.1039/c3cc38286a  1
2013 Dobrovetsky R, Stephan DW. Catalytic reduction of CO(2) to CO by using zinc(II) and in situ generated carbodiphosphoranes. Angewandte Chemie (International Ed. in English). 52: 2516-9. PMID 23364808 DOI: 10.1002/anie.201208817  1
2013 Jiang C, Stephan DW. Hydrophosphination of vinyl-boranes with phosphinoamines. Dalton Transactions (Cambridge, England : 2003). 42: 3318-25. PMID 23292311 DOI: 10.1039/c2dt32677a  1
2013 Stephan DW, Erker G. Frustrated lewis pair mediated hydrogenations. Topics in Current Chemistry. 332: 85-110. PMID 23277382 DOI: 10.1007/128_2012_392  1
2013 Stephan DW, Erker G. Frustrated lewis pair mediated hydrogenations. Topics in Current Chemistry. 332: 85-110. PMID 23277382 DOI: 10.1007/128_2012_392  1
2013 Hounjet LJ, Caputo CB, Stephan DW. The Lewis acidity of fluorophosphonium salts: access to mixed valent phosphorus(III)/(V) species. Dalton Transactions (Cambridge, England : 2003). 42: 2629-35. PMID 23232443 DOI: 10.1039/c2dt32711b  1
2013 Caputo CB, Zhu K, Vukotic VN, Loeb SJ, Stephan DW. Heterolytic activation of H2 using a mechanically interlocked molecule as a frustrated lewis base. Angewandte Chemie (International Ed. in English). 52: 960-3. PMID 23184655 DOI: 10.1002/anie.201207783  1
2013 Neu RC, Jiang C, Stephan DW. Bulky derivatives of boranes, boronic acids and boronate esters via reaction with diazomethanes. Dalton Transactions (Cambridge, England : 2003). 42: 726-36. PMID 23060040 DOI: 10.1039/c2dt31868g  1
2013 Jiang C, Stephan DW. Phosphinimine-borane combinations in frustrated Lewis pair chemistry. Dalton Transactions (Cambridge, England : 2003). 42: 630-7. PMID 22584752 DOI: 10.1039/c2dt30720k  1
2013 Sajid M, Klose A, Birkmann B, Liang L, Schirmer B, Wiegand T, Eckert H, Lough AJ, Fröhlich R, Daniliuc CG, Grimme S, Stephan DW, Kehr G, Erker G. Reactions of phosphorus/boron frustrated Lewis pairs with SO2 Chemical Science. 4: 213-219. DOI: 10.1039/c2sc21161k  1
2013 Thomson JW, Hatnean JA, Hastie JJ, Pasternak A, Stephan DW, Chase PA. Improving the industrial feasibility of metal-free hydrogenation catalysts using chemical scavengers Organic Process Research and Development. 17: 1287-1292. DOI: 10.1021/op4000847  1
2013 Jochmann P, Stephan DW. Reactions of CO2 with heteroleptic zinc and zinc-NHC complexes Organometallics. 32: 7503-7508. DOI: 10.1021/om401000s  1
2013 McKinty AM, Lund C, Stephan DW. A tridentate-dithiolate ruthenium alkylidene complex: An olefin metathesis catalyst activated by BCl3 Organometallics. 32: 4730-4732. DOI: 10.1021/om400794u  1
2013 Dahcheh F, Stephan DW. A new route to ruthenium thiolate alkylidene complexes Organometallics. 32: 5253-5255. DOI: 10.1021/om400740p  1
2013 Takeuchi K, Hounjet LJ, Stephan DW. Frustrated lewis pair route to hydrodesilylation of silylphosphines Organometallics. 32: 4469-4472. DOI: 10.1021/om4007278  1
2013 Ménard G, Gilbert TM, Hatnean JA, Kraft A, Krossing I, Stephan DW. Stoichiometric reduction of CO2 to CO by phosphine/AlX 3-based frustrated Lewis pairs Organometallics. 32: 4416-4422. DOI: 10.1021/om400619y  1
2013 Ménard G, Tran L, McCahill JSJ, Lough AJ, Stephan DW. Contrasting the reactivity of ethylene and propylene with P/Al and P/B frustrated Lewis pairs Organometallics. 32: 6759-6763. DOI: 10.1021/om400222w  1
2013 Ménard G, Tran L, McCahill JSJ, Lough AJ, Stephan DW. Contrasting the reactivity of ethylene and propylene with P/Al and P/B frustrated Lewis pairs Organometallics. 32: 6759-6763. DOI: 10.1021/om400222w  0.8
2013 Pranckevicius C, Stephan DW. Three-coordinate, cyclic bent allene iron complexes Organometallics. 32: 2693-2697. DOI: 10.1021/om400166t  1
2013 Mahdi T, Del Castillo JN, Stephan DW. Metal-free hydrogenation of N -based heterocycles Organometallics. 32: 1971-1978. DOI: 10.1021/om4000727  1
2013 Wang T, Pranckevicius C, Lund CL, Sgro MJ, Stephan DW. Ruthenium carbene-diether ligand complexes: Catalysts for hydrogenation of Olefins Organometallics. 32: 2168-2177. DOI: 10.1021/om400044w  1
2013 Stephan DW. Frustrated Lewis Pairs: Activation of H2 and Other Small Molecules Comprehensive Inorganic Chemistry Ii (Second Edition): From Elements to Applications. 1: 1069-1103. DOI: 10.1016/B978-0-08-097774-4.00136-4  1
2013 Stephan DW, Erker G. Preface Topics in Current Chemistry. 334: v. DOI: 10.1007/978-3-642-37759-4  1
2013 Stephan DW, Erker G. Preface Topics in Current Chemistry. 334: v. DOI: 10.1007/978-3-642-37759-4  1
2013 Stephan DW. Discovery of frustrated Lewis pairs: Intermolecular FLPs for activation of small molecules Topics in Current Chemistry. 332: 1-44. DOI: 10.1007/128-2012-381  1
2013 Mahdi T, Stephan DW. Frustrated lewis pair catalyzed hydroamination of terminal alkynes Angewandte Chemie - International Edition. 52: 12418-12421. DOI: 10.1002/anie.201307254  1
2013 Anderson HL, Lloyd-Jones GC, O'Brien P, Schofield CJ, Stephan DW, Nicolaou KC, Férey G, Meerholz K. New Fellows of the Royal Society: H. L. Anderson, G. C. Lloyd-Jones, P. O'Brien, C. J. Schofield, D. W. Stephan, K. C. Nicolaou / Lavoisier Medal: G. Férey / Richard Willstätter Lectureship: K. Meerholz Angewandte Chemie - International Edition. 52: 7071-7072. DOI: 10.1002/anie.201304013  1
2012 Takeuchi K, Stephan DW. Silyl-migrations in frustrated Lewis pair chemistry: reactions of ((CH3)3Si)3P and B(C6F4H)3 with H2 and CO2. Chemical Communications (Cambridge, England). 48: 11304-6. PMID 23072756 DOI: 10.1039/c2cc36470k  1
2012 Sgro MJ, Stephan DW. Frustrated Lewis pair inspired carbon dioxide reduction by a ruthenium tris(aminophosphine) complex. Angewandte Chemie (International Ed. in English). 51: 11343-5. PMID 23038414 DOI: 10.1002/anie.201205741  1
2012 Zhao X, Liang L, Stephan DW. Facile synthesis of electrophilic vinyl boranes: reactions of alkynyl-borates and diazonium salts. Chemical Communications (Cambridge, England). 48: 10189-91. PMID 22968259 DOI: 10.1039/c2cc35553a  1
2012 Greb L, Oña-Burgos P, Schirmer B, Grimme S, Stephan DW, Paradies J. Metal-free catalytic olefin hydrogenation: low-temperature H2 activation by frustrated Lewis pairs. Angewandte Chemie (International Ed. in English). 51: 10164-8. PMID 22936428 DOI: 10.1002/anie.201204007  1
2012 Farrell JM, Hatnean JA, Stephan DW. Activation of hydrogen and hydrogenation catalysis by a borenium cation. Journal of the American Chemical Society. 134: 15728-31. PMID 22931196 DOI: 10.1021/ja307995f  1
2012 Ménard G, Stephan DW. H2 activation and hydride transfer to olefins by Al(C6F5)3-based frustrated Lewis pairs. Angewandte Chemie (International Ed. in English). 51: 8272-5. PMID 22778027 DOI: 10.1002/anie.201203362  1
2012 Brown CC, Stephan DW. Rearrangements of phosphinoimines to phosphine-imines in ruthenium chelate complexes. Dalton Transactions (Cambridge, England : 2003). 41: 9431-8. PMID 22735623 DOI: 10.1039/c2dt30505d  1
2012 Sgro MJ, Dömer J, Stephan DW. Stoichiometric CO2 reductions using a bis-borane-based frustrated Lewis pair. Chemical Communications (Cambridge, England). 48: 7253-5. PMID 22710806 DOI: 10.1039/c2cc33301e  0.84
2012 Sgro MJ, Stephan DW. Ni(II), Pd(II) and Pt(II) complexes of PNP and PSP tridentate amino-phosphine ligands. Dalton Transactions (Cambridge, England : 2003). 41: 6791-802. PMID 22535417 DOI: 10.1039/c2dt30373f  0.84
2012 Hounjet LJ, Caputo CB, Stephan DW. Phosphorus as a Lewis acid: CO2 sequestration with amidophosphoranes. Angewandte Chemie (International Ed. in English). 51: 4714-7. PMID 22473879 DOI: 10.1002/anie.201201422  1
2012 Granville SL, Welch GC, Stephan DW. Ni, Pd, Pt, and Ru complexes of phosphine-borate ligands. Inorganic Chemistry. 51: 4711-21. PMID 22458594 DOI: 10.1021/ic2026895  1
2012 Ménard G, Stephan DW. C-H activation of isobutylene using frustrated Lewis Pairs: aluminum and boron σ-allyl complexes. Angewandte Chemie (International Ed. in English). 51: 4409-12. PMID 22447372 DOI: 10.1002/anie.201200328  1
2012 Neu RC, Ménard G, Stephan DW. Exchange chemistry of tBu3P(CO2)B(C6F5)2Cl. Dalton Transactions (Cambridge, England : 2003). 41: 9016-8. PMID 22367061 DOI: 10.1039/c2dt30206c  1
2012 Mahdi T, Heiden ZM, Grimme S, Stephan DW. Metal-free aromatic hydrogenation: aniline to cyclohexyl-amine derivatives. Journal of the American Chemical Society. 134: 4088-91. PMID 22335795 DOI: 10.1021/ja300228a  1
2012 Caputo CB, Geier SJ, Winkelhaus D, Mitzel NW, Vukotic VN, Loeb SJ, Stephan DW. Reactions of substituted pyridines with electrophilic boranes. Dalton Transactions (Cambridge, England : 2003). 41: 2131-9. PMID 22186932 DOI: 10.1039/c1dt11820j  0.6
2012 Caputo CB, Geier SJ, Ouyang EY, Kreitner C, Stephan DW. Chloro- and phenoxy-phosphines in frustrated Lewis pair additions to alkynes. Dalton Transactions (Cambridge, England : 2003). 41: 237-42. PMID 21904729 DOI: 10.1039/c1dt11196e  1
2012 Zhao X, Stephan DW. Frustrated Lewis pair olefin addition reactions: P-, N-, C- and H-based nucleophilic additions to an olefin-tethered borane Chemical Science. 3: 2123-2132. DOI: 10.1039/c2sc20262j  1
2012 Caputo CB, Geier SJ, Winkelhaus D, Mitzel NW, Vukotic VN, Loeb SJ, Stephan DW. Reactions of substituted pyridines with electrophilic boranes Dalton Transactions. 41: 2131-2139. DOI: 10.1039/c1dt11820j  1
2012 Reddy JS, Xu BH, Mahdi T, Fröhlich R, Kehr G, Stephan DW, Erker G. Alkenylborane-derived frustrated Lewis pairs: Metal-free catalytic hydrogenation reactions of electron-deficient alkenes Organometallics. 31: 5638-5649. DOI: 10.1021/om3006068  1
2012 Dahcheh F, Stephan DW. Ruthenium and rhodium complexes of thioether-alkynylborates Organometallics. 31: 3222-3227. DOI: 10.1021/om300075r  1
2012 Voss T, Mahdi T, Otten E, Fröhlich R, Kehr G, Stephan DW, Erker G. Frustrated Lewis pair behavior of intermolecular amine/B(C 6F 5) 3 pairs Organometallics. 31: 2367-2378. DOI: 10.1021/om300017u  1
2012 Neu RC, Stephan DW. Insertion reactions of diazomethanes and electrophilic boranes Organometallics. 31: 46-49. DOI: 10.1021/om2011613  1
2012 Caputo CB, Stephan DW. Activation of alkyl C-F Bonds by B(C 6F 5) 3: Stoichiometric and catalytic transformations Organometallics. 31: 27-30. DOI: 10.1021/om200885c  1
2011 Peuser I, Neu RC, Zhao X, Ulrich M, Schirmer B, Tannert JA, Kehr G, Fröhlich R, Grimme S, Erker G, Stephan DW. CO2 and formate complexes of phosphine/borane frustrated Lewis pairs. Chemistry (Weinheim An Der Bergstrasse, Germany). 17: 9640-50. PMID 21961180 DOI: 10.1002/chem.201100286  1
2011 Zhao X, Stephan DW. Olefin-borane "van der Waals complexes": intermediates in frustrated Lewis pair addition reactions. Journal of the American Chemical Society. 133: 12448-50. PMID 21770390 DOI: 10.1021/ja205598k  1
2011 Ménard G, Stephan DW. Stoichiometric reduction of CO2 to CO by aluminum-based frustrated Lewis pairs. Angewandte Chemie (International Ed. in English). 50: 8396-9. PMID 21761539 DOI: 10.1002/anie.201103600  1
2011 Kreitner C, Geier SJ, Stanlake LJ, Caputo CB, Stephan DW. Ring openings of lactone and ring contractions of lactide by frustrated Lewis pairs. Dalton Transactions (Cambridge, England : 2003). 40: 6771-7. PMID 21614351 DOI: 10.1039/c1dt10449g  1
2011 Zhao X, Lough AJ, Stephan DW. Synthesis and reactivity of alkynyl-linked phosphonium borates. Chemistry (Weinheim An Der Bergstrasse, Germany). 17: 6731-43. PMID 21544880 DOI: 10.1002/chem.201100203  1
2011 Stephan DW, Greenberg S, Graham TW, Chase P, Hastie JJ, Geier SJ, Farrell JM, Brown CC, Heiden ZM, Welch GC, Ullrich M. Metal-free catalytic hydrogenation of polar substrates by frustrated Lewis pairs. Inorganic Chemistry. 50: 12338-48. PMID 21534552 DOI: 10.1021/ic200663v  1
2011 Heiden ZM, Stephan DW. Metal-free diastereoselective catalytic hydrogenations of imines using B(C6F5)3. Chemical Communications (Cambridge, England). 47: 5729-31. PMID 21503337 DOI: 10.1039/c1cc10438a  1
2011 Cariou R, Graham TW, Dahcheh F, Stephan DW. Oxidative addition of aryl halides: routes to mono- and dimetallic nickel amino-bis-phosphinimine complexes. Dalton Transactions (Cambridge, England : 2003). 40: 5419-22. PMID 21491049 DOI: 10.1039/c1dt10341e  1
2011 Cariou R, Dahcheh F, Graham TW, Stephan DW. Mononuclear and dinuclear palladium and nickel complexes of phosphinimine-based tridentate ligands. Dalton Transactions (Cambridge, England : 2003). 40: 4918-25. PMID 21431159 DOI: 10.1039/c1dt10131e  1
2011 Dureen MA, Brown CC, Morton JG, Stephan DW. Titanium "constrained geometry" complexes with pendant arene groups. Dalton Transactions (Cambridge, England : 2003). 40: 2861-7. PMID 21298170 DOI: 10.1039/c0dt01530j  0.72
2011 Heiden ZM, Schedler M, Stephan DW. Synthesis and reactivity of o-benzylphosphino- and o-α-methylbenzyl(N,N-dimethyl)amine-boranes. Inorganic Chemistry. 50: 1470-9. PMID 21268612 DOI: 10.1021/ic102044z  1
2011 Sgro MJ, Stephan DW. Non-innocent reactivity of bis-phosphinimine pincer ligands in palladium complexes. Dalton Transactions (Cambridge, England : 2003). 40: 2419-21. PMID 21240415 DOI: 10.1039/c0dt01623c  0.84
2011 Zhao X, Stephan DW. Bis-boranes in the frustrated Lewis pair activation of carbon dioxide. Chemical Communications (Cambridge, England). 47: 1833-5. PMID 21206951 DOI: 10.1039/c0cc04791k  1
2011 Geier SJ, Gilbert TM, Stephan DW. Synthesis and reactivity of the phosphinoboranes R2PB(C6F5)2. Inorganic Chemistry. 50: 336-44. PMID 21126055 DOI: 10.1021/ic102003x  1
2011 Neu RC, Otten E, Lough A, Stephan DW. The synthesis and exchange chemistry of frustrated Lewis pair-nitrous oxide complexes Chemical Science. 2: 170-176. DOI: 10.1039/c0sc00398k  1
2011 Boone MP, Stephan DW. Reactions of Ru-alkynyl complexes with electrophilic boranes Organometallics. 30: 5537-5542. DOI: 10.1021/om200815s  1
2011 Farrell JM, Heiden ZM, Stephan DW. Metal-free transfer hydrogenation catalysis by B(C6F 5)3 Organometallics. 30: 4497-4500. DOI: 10.1021/om2005832  1
2010 Brown CC, Glotzbach C, Stephan DW. Ag(I) and Au(I) complexes of sterically crowded cyclic phosphinimine ligands. Dalton Transactions (Cambridge, England : 2003). 39: 9626-32. PMID 20820602 DOI: 10.1039/c0dt00261e  1
2010 Zhao X, Gilbert TM, Stephan DW. C-C coupling by thermolysis of alkynyl phosphonium borates. Chemistry (Weinheim An Der Bergstrasse, Germany). 16: 10304-8. PMID 20665589 DOI: 10.1002/chem.201001575  1
2010 Brown CC, Stephan DW. Cyclopropanation of Ru-diimino-pyridine ligand complexes. Dalton Transactions (Cambridge, England : 2003). 39: 7211-3. PMID 20593109 DOI: 10.1039/c0dt00437e  1
2010 Geier SJ, Chase PA, Stephan DW. Metal-free reductions of N-heterocycles via Lewis acid catalyzed hydrogenation. Chemical Communications (Cambridge, England). 46: 4884-6. PMID 20548991 DOI: 10.1039/c0cc00719f  1
2010 Neu RC, Ouyang EY, Geier SJ, Zhao X, Ramos A, Stephan DW. Probing substituent effects on the activation of H(2) by phosphorus and boron frustrated Lewis pairs. Dalton Transactions (Cambridge, England : 2003). 39: 4285-94. PMID 20422086 DOI: 10.1039/c001133a  1
2010 Voss T, Chen C, Kehr G, Nauha E, Erker G, Stephan DW. Cyclizations via frustrated Lewis pairs: Lewis acid induced intramolecular additions of amines to olefins and alkynes. Chemistry (Weinheim An Der Bergstrasse, Germany). 16: 3005-8. PMID 20143364 DOI: 10.1002/chem.200903483  1
2010 Zhao X, Otten E, Song D, Stephan DW. Ni-->B interactions in nickel phosphino-alkynyl-borane complexes. Chemistry (Weinheim An Der Bergstrasse, Germany). 16: 2040-4. PMID 20091720 DOI: 10.1002/chem.200902888  1
2010 Ménard G, Stephan DW. Room temperature reduction of CO2 to methanol by Al-based frustrated Lewis pairs and ammonia borane. Journal of the American Chemical Society. 132: 1796-7. PMID 20088527 DOI: 10.1021/ja9104792  1
2010 Stephan DW, Erker G. Frustrated Lewis pairs: metal-free hydrogen activation and more. Angewandte Chemie (International Ed. in English). 49: 46-76. PMID 20025001 DOI: 10.1002/anie.200903708  1
2010 Geier SJ, Stephan DW. Lewis acid mediated P-P bond hydrogenation and hydrosilylation Chemical Communications. 46: 1026-1028. DOI: 10.1039/b925126j  1
2010 Dureen MA, Brown CC, Stephan DW. Deprotonation and addition reactions of frustrated Lewis pairs with alkynes Organometallics. 29: 6594-6607. DOI: 10.1021/om1009044  1
2010 Dureen MA, Brown CC, Stephan DW. Addition of enamines or pyrroles and B(C6F5) 3 "frustrated Lewis Pairs" to alkynes Organometallics. 29: 6422-6432. DOI: 10.1021/om1008346  1
2010 Boone MP, Brown CC, Ancelet TA, Stephan DW. Interconversion of ruthenium-O(CH2CH2PCy 2)2 alkylidene and alkylidyne hydride complexes Organometallics. 29: 4369-4374. DOI: 10.1021/om100707a  1
2010 Ullrich M, Lough AJ, Stephan DW. Dihydrogen activation by B(p-C6F4H)3 and phosphines Organometallics. 29: 3647-3654. DOI: 10.1021/om100563m  1
2010 Birkmann B, Voss T, Geier SJ, Ullrich M, Kehr G, Erker G, Stephan DW. Frustrated lewis pairs and ring-opening of THF, dioxane, and thioxane Organometallics. 29: 5310-5319. DOI: 10.1021/om1003896  1
2010 Zhao X, Otten E, Song D, Stephan DW. Ni→ B interactions in nickel phosphino-alkynyl-borane complexes Chemistry - a European Journal. 16: 2040-2044. DOI: 10.1002/chem.200902888  1
2010 Geier SJ, Dureen MA, Ouyang EY, Stephan DW. New strategies to phosphino-phosphonium cations and zwitterions Chemistry - a European Journal. 16: 988-993. DOI: 10.1002/chem.200902369  1
2009 Chase PA, Gille AL, Gilbert TM, Stephan DW. Frustrated Lewis pairs derived from N-heterocyclic carbenes and Lewis acids. Dalton Transactions (Cambridge, England : 2003). 7179-88. PMID 20449161 DOI: 10.1039/b908737k  1
2009 Neu RC, Otten E, Stephan DW. Bridging binding modes of phosphine-stabilized nitrous oxide to Zn(C6F5)2. Angewandte Chemie (International Ed. in English). 48: 9709-12. PMID 19921733 DOI: 10.1002/anie.200905650  1
2009 McCahill JS, Welch GC, Stephan DW. Sterically hindered phosphine and phosphonium-based activators and additives for olefin polymerization. Dalton Transactions (Cambridge, England : 2003). 8555-61. PMID 19809731 DOI: 10.1039/b911489k  0.76
2009 Dureen MA, Welch GC, Gilbert TM, Stephan DW. Heterolytic cleavage of disulfides by frustrated Lewis pairs. Inorganic Chemistry. 48: 9910-7. PMID 19757814 DOI: 10.1021/ic901590s  0.76
2009 Otten E, Neu RC, Stephan DW. Complexation of nitrous oxide by frustrated Lewis pairs. Journal of the American Chemical Society. 131: 9918-9. PMID 19569691 DOI: 10.1021/ja904377v  1
2009 Yadav K, McCahill JS, Bai G, Stephan DW. Phosphinimide complexes with pendant hemilabile donors: synthesis, structure and ethylene polymerization activity. Dalton Transactions (Cambridge, England : 2003). 1636-43. PMID 19421609 DOI: 10.1039/b817959j  0.36
2009 Welch GC, Prieto R, Dureen MA, Lough AJ, Labeodan OA, Höltrichter-Rössmann T, Stephan DW. Reactions of phosphines with electron deficient boranes. Dalton Transactions (Cambridge, England : 2003). 1559-70. PMID 19421599 DOI: 10.1039/b814486a  0.76
2009 Ullrich M, Seto KS, Lough AJ, Stephan DW. 1,4-Addition reactions of frustrated Lewis pairs to 1,3-dienes. Chemical Communications (Cambridge, England). 2335-7. PMID 19377677 DOI: 10.1039/b901212e  0.64
2009 Alhomaidan O, Beddie C, Bai G, Stephan DW. Titanium complexes of amidophosphinimide ligands. Dalton Transactions (Cambridge, England : 2003). 1991-8. PMID 19259569 DOI: 10.1039/b816184d  0.36
2009 Ramos A, Lough AJ, Stephan DW. Activation of H2 by frustrated Lewis pairs derived from mono- and bis-phosphinoferrocenes and B(C6F5)3 Chemical Communications. 1118-1120. DOI: 10.1039/b819525k  1
2009 Ramos A, Otten E, Stephan DW. Stabilizing Zr and Ti cations by interaction with a ferrocenyl fragment Journal of the American Chemical Society. 131: 15610-15611. DOI: 10.1021/ja9077446  1
2009 Otten E, Neu RC, Stephan DW. Complexation of nitrous oxide by frustrated lewis pairs Journal of the American Chemical Society. 131: 9918-9919. DOI: 10.1021/ja904377v  1
2009 Geier SJ, Stephan DW. Lutidine/B(C6F5)3: At the boundary of classical and frustrated lewis pair reactivity Journal of the American Chemical Society. 131: 3476-3477. DOI: 10.1021/ja900572x  1
2009 Ullrich M, Lough AJ, Stephan DW. Reversible, metal-free, heterolytic activation of H2 at room temperature Journal of the American Chemical Society. 131: 52-53. DOI: 10.1021/ja808506t  1
2009 Geier SJ, Gille AL, Gilbert TM, Stephan DW. From classical adducts to frustrated lewis pairs: Steric effects in the interactions of pyridines and B(C 6F 5) 3 Inorganic Chemistry. 48: 10466-10474. DOI: 10.1021/ic901726b  1
2009 Neu RC, Otten E, Stephan DW. Bridging binding modes of phosphine-stabilized nitrous oxide to Zn(C 6F5)2 Angewandte Chemie - International Edition. 48: 9709-9712. DOI: 10.1002/anie.200905650  1
2009 Mömming CM, Otten E, Kehr G, Fröhlich R, Grimme S, Stephan DW, Erker G. Reversible metal-free carbon dioxide binding by frustrated lewis pairs Angewandte Chemie - International Edition. 48: 6643-6646. DOI: 10.1002/anie.200901636  1
2008 Chase PA, Stephan DW. Hydrogen and amine activation by a frustrated Lewis pair of a bulky N-heterocyclic carbene and B(C6F5)3. Angewandte Chemie (International Ed. in English). 47: 7433-7. PMID 18655208 DOI: 10.1002/anie.200802596  1
2008 Chase PA, Jurca T, Stephan DW. Lewis acid-catalyzed hydrogenation: B(C6F5)3-mediated reduction of imines and nitriles with H2. Chemical Communications (Cambridge, England). 1701-3. PMID 18368170 DOI: 10.1039/b718598g  1
2008 Welch GC, Holtrichter-Roessmann T, Stephan DW. Thermal rearrangement of phosphine-B(C6F5)3 adducts. Inorganic Chemistry. 47: 1904-6. PMID 18284195 DOI: 10.1021/ic702485r  0.76
2008 Gall BT, McCahill J, Stephan DW, Mülhaupt R. Novel polyolefins containing crystallizable isotactic polystyrene side chains Macromolecular Rapid Communications. 29: 1549-1553. DOI: 10.1002/marc.200800350  1
2007 Chase PA, Welch GC, Jurca T, Stephan DW. Metal-free catalytic hydrogenation. Angewandte Chemie (International Ed. in English). 46: 8050-3. PMID 17696181 DOI: 10.1002/anie.200702908  1
2007 Welch GC, Cabrera L, Chase PA, Hollink E, Masuda JD, Wei P, Stephan DW. Tuning Lewis acidity using the reactivity of "frustrated Lewis pairs": facile formation of phosphine-boranes and cationic phosphonium-boranes. Dalton Transactions (Cambridge, England : 2003). 3407-14. PMID 17664977 DOI: 10.1039/b704417h  1
2007 McCahill JS, Welch GC, Stephan DW. Reactivity of "frustrated Lewis pairs": three-component reactions of phosphines, a borane, and olefins. Angewandte Chemie (International Ed. in English). 46: 4968-71. PMID 17526043 DOI: 10.1002/anie.200701215  0.76
2007 Welch GC, Stephan DW. Facile heterolytic cleavage of dihydrogen by phosphines and boranes. Journal of the American Chemical Society. 129: 1880-1. PMID 17260994 DOI: 10.1021/ja067961j  0.76
2007 Bai G, Stephan DW. Formation of C-C and C-N bonds in NiII ketimide complexes via transient NiIII aryl imides Angewandte Chemie - International Edition. 46: 1856-1859. DOI: 10.1002/anie.200604547  1
2006 Welch GC, San Juan RR, Masuda JD, Stephan DW. Reversible, metal-free hydrogen activation. Science (New York, N.Y.). 314: 1124-6. PMID 17110572 DOI: 10.1126/science.1134230  1
2006 Masuda JD, Hoskin AJ, Graham TW, Beddie C, Fermin MC, Etkin N, Stephan DW. Catalytic P--H activation by Ti and Zr catalysts. Chemistry (Weinheim An Der Bergstrasse, Germany). 12: 8696-707. PMID 16952126 DOI: 10.1002/chem.200600429  1
2006 Masuda JD, Stephan DW. Neutral and cationic aluminium complexes of a sterically demanding N-imidoylamidine ligand. Dalton Transactions (Cambridge, England : 2003). 2089-97. PMID 16625253 DOI: 10.1039/b513531a  1
2006 Welch GC, Masuda JD, Stephan DW. Phosphonium-borate zwitterions, anionic phosphines, and dianionic phosphonium-dialkoxides via tetrahydrofuran ring-opening reactions. Inorganic Chemistry. 45: 478-80. PMID 16411674 DOI: 10.1021/ic051713r  1
2006 Heiser DE, Pelascini F, Kramer D, Scott J, Gambarotta S, McCahill J, Stephan DW, Okuda J, Mülhaupt R. Ethylene/1,3-cyclohexadiene copolymerization by means of methylaluminoxane activated half-sandwich complexes Macromolecular Symposia. 236: 156-160. DOI: 10.1002/masy.200690050  1
2005 Hawkeswood S, Wei P, Gauld JW, Stephan DW. Steric effects in metathesis and reduction reactions of phosphinimines with catechol- and pinacolboranes. Inorganic Chemistry. 44: 4301-8. PMID 15934760 DOI: 10.1021/ic050230k  1
2004 Zhao X, Ramsey KE, Stephan DA, Russell P. Gene and protein expression changes in human trabecular meshwork cells treated with transforming growth factor-beta. Investigative Ophthalmology & Visual Science. 45: 4023-34. PMID 15505052 DOI: 10.1167/iovs.04-0535  1
2004 Smith SB, Stephan DW. Titanium Comprehensive Coordination Chemistry Ii. 4: 31-104. DOI: 10.1016/B0-08-043748-6/03028-0  1
2003 Zhao X, Pearson KE, Stephan DA, Russell P. Effects of prostaglandin analogues on human ciliary muscle and trabecular meshwork cells. Investigative Ophthalmology & Visual Science. 44: 1945-52. PMID 12714628 DOI: 10.1167/IOVS.02-0920  1
2003 Wei P, Stephan DW. Cationic and neutral phosphido-bridged pentamethylcyclopentadienyl-chromium dimers Organometallics. 22: 1712-1717. DOI: 10.1021/om0209881  1
2003 Wei P, Stephan DW. Magnesium complexes of bis(phosphinimine)methane and -methanide ligands Organometallics. 22: 601-604. DOI: 10.1021/om0207818  1
2002 Courtenay S, Mutus JY, Schurko RW, Stephan DW. The extended borinium cation: [(tBu(3)PN)(2)B](+). Angewandte Chemie (International Ed. in English). 41: 498-501. PMID 12491392 DOI: 10.1002/1521-3773(20020201)41:3<498::AID-ANIE498>3.0.CO;2-C  1
2002 Wei P, Stephan DW. Structural isomers of the chromium bis(phosphoranimine)methanide complex [(HC(PPh2NSiMe3)2)Cr(μ-Cl)]2 Organometallics. 21: 1308-1310. DOI: 10.1021/om0108494  1
2000 Sung RC, Courtenay S, McGarvey BR, Stephan DW. Synthesis, structure, and single-crystal EPR study of [Cp(t-Bu3PN)Ti(mu-Cl)]2. Inorganic Chemistry. 39: 2542-6. PMID 11197008 DOI: 10.1021/ic991305l  1
1990 Baidya N, Mascharak PK, Stephan DW, Campagna CF. Mononuclear nickel(II) thiolates of square-planar geometry: syntheses, spectral and redox properties of [Ni(SCH2CH2S)2]2- and [Ni(SCH(CH3)CH(CH3)S)2]2- and the structure of (Ph4P)2[Ni(SCH2CH2S)2]·4H2O Inorganica Chimica Acta. 177: 233-238. DOI: 10.1016/S0020-1693(00)85981-2  1
1986 Konefal E, Loeb SJ, Willis CJ, Stephan DW. Coordination modes of polydentate ligands. 4. The crystal and molecular structure of an oxo-bridged iron(III) complex containing a pentadentate imino-alkoxy ligand Inorganica Chimica Acta. 115: 147-151. DOI: 10.1016/S0020-1693(00)84406-0  1
1985 Gelmini L, Stephan DW, Loeb SJ. The molecular structure of Rh2Cl2(μ-CO)(μ-(C6H52PCH2P(C6H5)2)·2C6H6: A rhodium 'a-frame' complex Inorganica Chimica Acta. 98. DOI: 10.1016/S0020-1693(00)90736-9  1
1981 Payne NC, Stephan DW. Studies in enantiomeric discrimination. I. Chiral phosphine complexes of platinum Journal of Organometallic Chemistry. 221: 223-230. DOI: 10.1016/S0022-328X(00)89057-9  1
1981 Payne NC, Stephan DW. Preparation and 31P NMR studies of platinum complexes of some chiral, bidentate phosphines Journal of Organometallic Chemistry. 221: 203-221. DOI: 10.1016/S0022-328X(00)89056-7  1
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