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Guy Bertrand, Ph.D. - Publications

Affiliations: 
1975-2005 CNRS-Université Paul Sabatier, Toulouse, Occitanie, France 
 2001-2012 University of California, Riverside, Riverside, CA, United States 
 2012- University of California, San Diego, La Jolla, CA 
Website:
http://www-chem.ucsd.edu/faculty/profiles/bertrand_guy.html
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Year Citation  Score
2023 Loh YK, Melaimi M, Gembicky M, Munz D, Bertrand G. A crystalline doubly oxidized carbene. Nature. PMID 37730995 DOI: 10.1038/s41586-023-06539-x  0.519
2023 Hu L, Meng G, Chen X, Yoon JS, Shan JR, Chekshin N, Strassfeld DA, Sheng T, Zhuang Z, Jazzar R, Bertrand G, Houk KN, Yu JQ. Enhancing Substrate-Metal Catalyst Affinity via Hydrogen Bonding: Pd(II)-Catalyzed β-C(sp)-H Bromination of Free Carboxylic Acids. Journal of the American Chemical Society. PMID 37487009 DOI: 10.1021/jacs.3c04223  0.643
2023 Lorkowski J, Bouetard D, Yorkgitis P, Gembicky M, Roisnel T, Vanthuyne N, Munz D, Favereau L, Bertrand G, Mauduit M, Jazzar R. Circularly Polarized Luminescence from Cyclic (Alkyl)(Amino) Carbene Derived Propellers. Angewandte Chemie (International Ed. in English). e202305404. PMID 37221132 DOI: 10.1002/anie.202305404  0.707
2023 Mulks FF, Melaimi M, Yan X, Baik MH, Bertrand G. How To Enhance the Efficiency of Breslow Intermediates for SET Catalysis. The Journal of Organic Chemistry. PMID 36719963 DOI: 10.1021/acs.joc.2c02978  0.78
2023 Loh YK, Melaimi M, Munz D, Bertrand G. An Air-Stable "Masked" Bis(imino)carbene: A Carbon-Based Dual Ambiphile. Journal of the American Chemical Society. PMID 36649656 DOI: 10.1021/jacs.2c12847  0.531
2022 Gao Y, Kim N, Mendoza SD, Yazdani S, Faria-Vieira A, Liu M, Kendrick A, Grotjahn DB, Bertrand G, Jazzar R, Engle KM. (CAAC)Copper Catalysis Enables Regioselective Three-Component Carboboration of Terminal Alkynes. Acs Catalysis. 12: 7243-7247. PMID 37143933 DOI: 10.1021/acscatal.2c00614  0.663
2022 Schaab J, Hamze R, Shi S, Kapper SC, Muthiah Ravinson DS, Estergreen L, Jung MC, Tadle AC, Haiges R, Djurovich PI, Peltier JL, Jazzar R, Bertrand G, Bradforth SE, Thompson ME. Correction to " 'Quick-Silver' from a Systematic Study of Highly Luminescent, Two-Coordinate, d Coinage Metal Complexes. Journal of the American Chemical Society. PMID 36576490 DOI: 10.1021/jacs.2c12680  0.619
2022 Peltier JL, Serrato MR, Thery V, Pecaut J, Tomás-Mendivil E, Bertrand G, Jazzar R, Martin D. An air-stable radical with a redox-chameleonic amide. Chemical Communications (Cambridge, England). PMID 36524847 DOI: 10.1039/d2cc05404c  0.646
2022 Vermersch F, Oliveira L, Hunter J, Soleilhavoup M, Jazzar R, Bertrand G. Cyclic (Alkyl)(amino)carbenes: Synthesis of Iminium Precursors and Structural Properties. The Journal of Organic Chemistry. PMID 35133152 DOI: 10.1021/acs.joc.1c03075  0.661
2021 Bertrand G, Vermersch F, Yazdani S, Junor GP, Grotjahn DB, Jazzar R. Stable Singlet Carbenes as Organic Superbases. Angewandte Chemie (International Ed. in English). PMID 34729888 DOI: 10.1002/anie.202111588  0.622
2021 Gao Y, Yazdani S, Kendrick A, Junor GP, Kang T, Grotjahn DB, Bertrand G, Jazzar R, Engle KM. Cyclic(Alkyl)(Amino)Carbene Ligands Enable Cu-Catalyzed Markovnikov Protoboration and Protosilylation of Terminal Alkynes: A Versatile Portal to Functionalized Alkenes. Angewandte Chemie (International Ed. in English). PMID 34159696 DOI: 10.1002/anie.202106107  0.666
2020 Morvan J, Vermersch F, Zhang Z, Falivene L, Vives T, Dorcet V, Roisnel T, Crévisy C, Cavallo L, Vanthuyne N, Bertrand G, Jazzar R, Mauduit M. Optically Pure -Symmetric Cyclic(alkyl)(amino)carbene Ruthenium Complexes for Asymmetric Olefin Metathesis. Journal of the American Chemical Society. PMID 33185429 DOI: 10.1021/jacs.0c10705  0.653
2020 Peltier JL, Tomás-Mendivil E, Tolentino DR, Hansmann MM, Jazzar R, Bertrand G. Realizing Metal-Free Carbene-Catalyzed Carbonylation Reactions with CO. Journal of the American Chemical Society. PMID 33054191 DOI: 10.1021/jacs.0c09938  0.645
2020 Peltier JL, Soleilhavoup M, Martin D, Jazzar R, Bertrand G. Absolute Templating of M(111) Cluster Surrogates by Galvanic Exchange. Journal of the American Chemical Society. PMID 32872772 DOI: 10.1021/Jacs.0C07990  0.636
2020 Bertrand G, Junor G, Lorkowski J, Weinstein C, Jazzar R, Pietraszuk C. The influence of C(sp3)H-Selenium Interactions on the 77 Se NMR Quantification of the p -Accepting Properties of Carbenes. Angewandte Chemie (International Ed. in English). PMID 32822513 DOI: 10.1002/Anie.202010744  0.648
2020 Jazzar R, Soleilhavoup M, Bertrand G. Cyclic (Alkyl)- and (Aryl)-(amino)carbene Coinage Metal Complexes and Their Applications. Chemical Reviews. PMID 32239922 DOI: 10.1021/Acs.Chemrev.0C00043  0.708
2020 Mantanona AJ, Tolentino DR, Cay KS, Gembicky M, Jazzar R, Bertrand G, Rinehart JD. Tuning electronic structure through halide modulation of mesoionic carbene cobalt complexes. Dalton Transactions (Cambridge, England : 2003). PMID 32048665 DOI: 10.1039/C9Dt04624K  0.671
2020 Sau SC, Hota PK, Mandal SK, Soleilhavoup M, Bertrand G. Stable abnormal N-heterocyclic carbenes and their applications. Chemical Society Reviews. PMID 31998907 DOI: 10.1039/C9Cs00866G  0.393
2020 Soleilhavoup M, Bertrand G. Stable Carbenes, Nitrenes, Phosphinidenes, and Borylenes: Past and Future Chem. 6: 1275-1282. DOI: 10.1016/J.Chempr.2020.04.015  0.306
2019 Pichon D, Soleilhavoup M, Morvan J, Junor GP, Vives T, Crévisy C, Lavallo V, Campagne JM, Mauduit M, Jazzar R, Bertrand G. The debut of chiral cyclic (alkyl)(amino)carbenes (CAACs) in enantioselective catalysis. Chemical Science. 10: 7807-7811. PMID 31588330 DOI: 10.1039/C9Sc02810B  0.79
2019 Romero EA, Chen G, Gembicky M, Jazzar R, Yu JQ, Bertrand G. Understanding the Activity and Enantioselectivity of Acetyl-Protected Aminoethyl Quinoline ligands in Palladium-Catalyzed β-C(sp3)-H Bond Arylation reactions. Journal of the American Chemical Society. PMID 31565934 DOI: 10.1021/Jacs.9B06746  0.696
2019 Hamze R, Shi S, Kapper SC, Muthiah Ravinson DS, Estergreen L, Jung MC, Tadle AC, Haiges R, Djurovich PI, Peltier JL, Jazzar R, Bertrand G, Bradforth SE, Thompson ME. Correction to " 'Quick-Silver' from a Systematic Study of Highly Luminescent, Two-Coordinate, d Coinage Metal Complexes". Journal of the American Chemical Society. PMID 31199623 DOI: 10.1021/Jacs.9B06147  0.65
2019 Tolentino DR, Neale SE, Isaac CJ, Macgregor SA, Whittlesey MK, Jazzar R, Bertrand G. Reductive Elimination at Carbon under Steric Control. Journal of the American Chemical Society. PMID 31180660 DOI: 10.1021/Jacs.9B04957  0.74
2019 Hamze R, Shi S, Kapper SC, Muthiah Ravinson DS, Estergreen L, Jung MC, Tadle AC, Haiges R, Djurovich PI, Peltier JL, Jazzar R, Bertrand G, Bradforth SE, Thompson ME. "Quick-Silver" from a systematic study of highly luminescent, 2-coordinate, d coinage metal complexes. Journal of the American Chemical Society. PMID 31062972 DOI: 10.1021/Jacs.9B03657  0.651
2019 Schiegerl LJ, Melaimi M, Tolentino DR, Klein W, Bertrand G, Fässler TF. Silylated Ge Clusters as New Ligands for Cyclic (Alkyl)amino and Mesoionic Carbene Copper Complexes. Inorganic Chemistry. PMID 30741546 DOI: 10.1021/Acs.Inorgchem.8B03338  0.354
2019 Hamze R, Peltier JL, Sylvinson D, Jung M, Cardenas J, Haiges R, Soleilhavoup M, Jazzar R, Djurovich PI, Bertrand G, Thompson ME. Eliminating nonradiative decay in Cu(I) emitters: >99% quantum efficiency and microsecond lifetime. Science (New York, N.Y.). 363: 601-606. PMID 30733411 DOI: 10.1126/Science.Aav2865  0.648
2019 Junor G, Romero E, Chen X, Jazzar R, Bertrand G. Readily Available Primary Aminoboranes as Powerful Reagents for Aldimine Synthesis. Angewandte Chemie (International Ed. in English). PMID 30618172 DOI: 10.1002/Anie.201814081  0.658
2019 Liu W, Zhao L, Melaimi M, Cao L, Xu X, Bouffard J, Bertrand G, Yan X. Mesoionic Carbene (MIC)-Catalyzed H/D Exchange at Formyl Groups Chem. 5: 2484-2494. DOI: 10.1016/J.Chempr.2019.08.011  0.38
2018 Regnier V, Romero EA, Molton F, Jazzar R, Bertrand G, Martin D. What are the Radical Intermediates in Oxidative N-Heterocyclic Carbene Organocatalysis? Journal of the American Chemical Society. PMID 30561990 DOI: 10.1021/Jacs.8B11824  0.655
2018 Guisado-Barrios G, Soleilhavoup M, Bertrand G. 1 H-1,2,3-Triazol-5-ylidenes: Readily Available Mesoionic Carbenes. Accounts of Chemical Research. PMID 30417642 DOI: 10.1021/Acs.Accounts.8B00480  0.464
2018 Nakano R, Jazzar R, Bertrand G. A crystalline monosubstituted carbene. Nature Chemistry. PMID 30323332 DOI: 10.1038/S41557-018-0153-1  0.789
2018 Weinstein CM, Junor GP, Tolentino DR, Jazzar R, Melaimi M, Bertrand G. Highly Ambiphilic Room Temperature Stable Six-Membered Cyclic (Alkyl)(amino)carbenes. Journal of the American Chemical Society. PMID 29954178 DOI: 10.1021/Jacs.8B05518  0.708
2018 Goicoechea JM, Hinz A, Hansmann M, Bertrand G. Intercepting a Transient Phosphino-Arsinidene. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 29723432 DOI: 10.1002/Chem.201802175  0.395
2018 Hansmann MM, Melaimi M, Munz D, Bertrand G. A Modular Approach to Kekulé Diradicaloids Derived from Cyclic (Alkyl)(amino)carbenes. Journal of the American Chemical Society. PMID 29382199 DOI: 10.1021/Jacs.7B11183  0.625
2018 Hansmann MM, Melaimi M, Bertrand G. Organic Mixed Valence Compounds Derived from Cyclic (Alkyl)(amino)carbenes. Journal of the American Chemical Society. PMID 29342351 DOI: 10.1021/Jacs.7B11184  0.341
2018 Mahoney JK, Regnier V, Romero EA, Molton F, Royal G, Jazzar R, Martin D, Bertrand G. The serendipitous discovery of a readily available redox-bistable molecule derived from cyclic(alkyl)(amino)carbenes Organic Chemistry Frontiers. 5: 2073-2078. DOI: 10.1039/C8Qo00447A  0.687
2018 Romero EA, Zhao T, Nakano R, Hu X, Wu Y, Jazzar R, Bertrand G. Tandem copper hydride–Lewis pair catalysed reduction of carbon dioxide into formate with dihydrogen Nature Catalysis. 1: 743-747. DOI: 10.1038/s41929-018-0140-3  0.745
2017 Grützmacher H, Li Z, Hou Y, Li Y, Hinz A, Harmer J, Su CY, Bertrand G. L3C3P3: Tricarbontriphosphide Cage Radicals and Cations Stabilized by Cyclic (alkyl)(amino)carbenes. Angewandte Chemie (International Ed. in English). PMID 29106069 DOI: 10.1002/Anie.201710099  0.691
2017 Hansmann MM, Melaimi M, Bertrand G. A Crystalline Monomeric Allenyl/Propargyl Radical. Journal of the American Chemical Society. PMID 29046060 DOI: 10.1021/Jacs.7B09622  0.339
2017 Hamze R, Jazzar R, Soleilhavoup M, Djurovich PI, Bertrand G, Thompson ME. Phosphorescent 2-, 3- and 4-coordinate cyclic (alkyl)(amino)carbene (CAAC) Cu(i) complexes. Chemical Communications (Cambridge, England). PMID 28745735 DOI: 10.1039/C7Cc02638B  0.68
2017 Hansmann MM, Ruiz DA, Liu LL, Jazzar R, Bertrand G. (Phosphanyl)phosphaketenes as building blocks for novel phosphorus heterocycles. Chemical Science. 8: 3720-3725. PMID 28580107 DOI: 10.1039/C7Sc00300E  0.762
2017 Bertrand G, Soleilhavoup M. Borylenes: an Emerging Class of Compounds. Angewandte Chemie (International Ed. in English). PMID 28577325 DOI: 10.1002/Anie.201705153  0.387
2017 Tomás-Mendivil E, Hansmann MM, Weinstein CM, Jazzar R, Melaimi M, Bertrand G. Bicyclic (Alkyl)(amino)carbenes (BICAACs): Stable Carbenes More Ambiphilic than CAACs. Journal of the American Chemical Society. PMID 28541687 DOI: 10.1021/Jacs.7B04640  0.709
2017 Romero EA, Jazzar R, Bertrand G. Copper-catalyzed dehydrogenative borylation of terminal alkynes with pinacolborane. Chemical Science. 8: 165-168. PMID 28451161 DOI: 10.1039/C6Sc02668K  0.698
2017 Bertrand G, Sioleilhavoup M, Melaimi M, Jazzar R. Cyclic (alkyl)(amino)carbenes (CAACs): Recent Developments. Angewandte Chemie (International Ed. in English). PMID 28376253 DOI: 10.1002/Anie.201702148  0.674
2017 Romero EA, Olsen PM, Jazzar R, Soleilhavoup M, Gembicky M, Bertrand G. Spectroscopic Evidence for a Monomeric Copper(I) Hydride and Crystallographic Characterization of a Monomeric Silver(I) Hydride. Angewandte Chemie (International Ed. in English). PMID 28251762 DOI: 10.1002/Anie.201700858  0.677
2017 Mahoney J, Jazzar R, Royal G, Martin D, Bertrand G. On the Advantage of Cyclic over Acyclic Carbenes to Access Isolable Capto-Dative C-Centered Radicals. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 28105672 DOI: 10.1002/Chem.201700144  0.694
2017 Romero EA, Jazzar R, Bertrand G. (CAAC)CuX-catalyzed hydroboration of terminal alkynes with pinacolborane directed by the X-ligand Journal of Organometallic Chemistry. 829: 11-13. DOI: 10.1016/J.Jorganchem.2016.09.025  0.687
2017 Melaimi M, Jazzar R, Soleilhavoup M, Bertrand G. Cyclische Alkylaminocarbene (CAACs): Neues von guten Bekannten Angewandte Chemie. 129: 10180-10203. DOI: 10.1002/Ange.201702148  0.596
2016 Liu L, Ruiz DA, Dahcheh F, Bertrand G, Suter R, Tondreau AM, Grützmacher H. Isolation of Au-, Co-ηPCO and Cu-ηPCO complexes, conversion of an Ir-ηPCO complex into a dimetalladiphosphene, and an interaction-free PCO anion. Chemical Science. 7: 2335-2341. PMID 29997776 DOI: 10.1039/C5Sc04504E  0.807
2016 Jin L, Melaimi M, Kostenko A, Karni M, Apeloig Y, Moore CE, Rheingold AL, Bertrand G. Isolation of cationic and neutral (allenylidene)(carbene) and bis(allenylidene)gold complexes. Chemical Science. 7: 150-154. PMID 28966767 DOI: 10.1039/C5Sc03654B  0.404
2016 Hansmann MM, Bertrand G. Transition-Metal-like Behavior of Main Group Elements: Ligand Exchange at a Phosphinidene. Journal of the American Chemical Society. 138: 15885-15888. PMID 27960331 DOI: 10.1021/Jacs.6B11496  0.377
2016 Kleinhans G, Hansmann MM, Guisado-Barrios G, Liles DC, Bertrand G, Bezuidenhout DI. Nucleophilic T-Shaped (LXL)Au(I)-Pincer Complexes: Protonation and Alkylation. Journal of the American Chemical Society. 138: 15873-15876. PMID 27960301 DOI: 10.1021/Jacs.6B11359  0.391
2016 Munz D, Chu J, Melaimi M, Bertrand G. NHC-CAAC Heterodimers with Three Stable Oxidation States. Angewandte Chemie (International Ed. in English). PMID 27628756 DOI: 10.1002/Anie.201607537  0.811
2016 Martin D, Marx VM, Grubbs RH, Bertrand G. A Ruthenium Catalyst for Olefin Metathesis Featuring an Anti-Bredt N-Heterocyclic Carbene Ligand. Advanced Synthesis & Catalysis. 358: 965-969. PMID 27594819 DOI: 10.1002/Adsc.201501140  0.507
2016 Romero EA, Peltier JL, Jazzar R, Bertrand G. Catalyst-free dehydrocoupling of amines, alcohols, and thiols with pinacol borane and 9-borabicyclononane (9-BBN). Chemical Communications (Cambridge, England). PMID 27498971 DOI: 10.1039/C6Cc06096J  0.632
2016 Hansmann MM, Jazzar R, Bertrand G. Singlet (Phosphino)phosphinidenes are Electrophilic. Journal of the American Chemical Society. PMID 27340902 DOI: 10.1021/Jacs.6B04232  0.667
2016 Chu J, Munz D, Jazzar R, Melaimi M, Bertrand G. Synthesis of Hemilabile Cyclic (Alkyl)(amino)carbenes (CAACs) and Applications in Organometallic Chemistry. Journal of the American Chemical Society. PMID 27304485 DOI: 10.1021/Jacs.6B05221  0.82
2016 Bidal YD, Santoro O, Melaimi M, Cordes DB, Slawin AM, Bertrand G, Cazin CS. Generalization of the Copper to Late-Transition-Metal Transmetallation to Carbenes beyond N-Heterocyclic Carbenes. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 27238837 DOI: 10.1002/Chem.201601254  0.349
2016 Li Z, Chen X, Benkő Z, Liu L, Ruiz DA, Peltier JL, Bertrand G, Su CY, Grützmacher H. N-Heterocyclic Carbenes as Promotors for the Rearrangement of Phosphaketenes to Phosphaheteroallenes: A Case Study for OCP to OPC Constitutional Isomerism. Angewandte Chemie (International Ed. in English). PMID 27060924 DOI: 10.1002/Anie.201600903  0.752
2016 Pranckevicius C, Liu L, Bertrand G, Stephan DW. Synthesis of a Carbodicyclopropenylidene: A Carbodicarbene based Solely on Carbon. Angewandte Chemie (International Ed. in English). PMID 27028936 DOI: 10.1002/Anie.201600765  0.693
2016 Kleinhans G, Guisado-Barrios G, Liles DC, Bertrand G, Bezuidenhout DI. A rhodium(i)-oxygen adduct as a selective catalyst for one-pot sequential alkyne dimerization-hydrothiolation tandem reactions. Chemical Communications (Cambridge, England). PMID 26838677 DOI: 10.1039/C6Cc00029K  0.37
2016 Peltier JL, Jazzar R, Melaimi M, Bertrand G. Ancillary ligand-free copper catalysed hydrohydrazination of terminal alkynes with NH2NH2. Chemical Communications (Cambridge, England). PMID 26757745 DOI: 10.1039/C5Cc10427K  0.656
2016 Hu X, Martin D, Bertrand G. Room temperature hydroamination of alkynes with anilines catalyzed by anti-Bredt di(amino)carbene gold(i) complexes New Journal of Chemistry. 40: 5993-5996. DOI: 10.1039/C6Nj00980H  0.333
2016 Liu L, Ruiz DA, Dahcheh F, Bertrand G, Suter R, Tondreau AM, Grützmacher H. Isolation of Au-, Co-η1PCO and Cu-η2PCO complexes, conversion of an Ir-η1PCO complex into a dimetalladiphosphene, and an interaction-free PCO anion Chemical Science. 7: 2335-2341. DOI: 10.1039/c5sc04504e  0.756
2016 Liu L, Ruiz D, Munz D, Bertrand G. A Singlet Phosphinidene Stable at Room Temperature Chem. 1: 147-153. DOI: 10.1016/J.Chempr.2016.04.001  0.73
2016 Martin D, Marx VM, Grubbs RH, Bertrand G. A Ruthenium Catalyst for Olefin Metathesis Featuring an Anti-Bredt N-Heterocyclic Carbene Ligand Advanced Synthesis and Catalysis. 358: 965-969. DOI: 10.1002/adsc.201501140  0.386
2015 Jin L, Romero EA, Melaimi M, Bertrand G. The Janus Face of the X Ligand in the Copper Catalyzed Azide Alkyne Cycloaddition. Journal of the American Chemical Society. PMID 26611196 DOI: 10.1021/Jacs.5B11028  0.412
2015 Jin L, Tolentino DR, Melaimi M, Bertrand G. Isolation of bis(copper) key intermediates in Cu-catalyzed azide-alkyne "click reaction". Science Advances. 1: e1500304. PMID 26601202 DOI: 10.1126/Sciadv.1500304  0.393
2015 Rao B, Tang H, Zeng X, Liu L, Melaimi M, Bertrand G. Cyclic (Amino)(aryl)carbenes (CAArCs) as Strong σ-Donating and π-Accepting Ligands for Transition Metals. Angewandte Chemie (International Ed. in English). PMID 26457345 DOI: 10.1002/Anie.201507844  0.684
2015 Liu L, Ruiz DA, Dahcheh F, Bertrand G. Isolation of a Lewis base stabilized parent phosphenium (PH2(+)) and related species. Chemical Communications (Cambridge, England). 51: 12732-5. PMID 26166485 DOI: 10.1039/C5Cc05241F  0.582
2015 Mahoney JK, Martin D, Thomas F, Moore CE, Rheingold AL, Bertrand G. Air-Persistent Monomeric (Amino)(carboxy) Radicals Derived from Cyclic (Alkyl)(Amino) Carbenes. Journal of the American Chemical Society. 137: 7519-25. PMID 26011769 DOI: 10.1021/Jacs.5B04414  0.365
2015 Styra S, Melaimi M, Moore CE, Rheingold AL, Augenstein T, Breher F, Bertrand G. Crystalline Cyclic (Alkyl)(amino)carbene-tetrafluoropyridyl Radical. Chemistry (Weinheim An Der Bergstrasse, Germany). 21: 8441-6. PMID 25925367 DOI: 10.1002/Chem.201500740  0.414
2015 Hu X, Soleilhavoup M, Melaimi M, Chu J, Bertrand G. Air-Stable (CAAC)CuCl and (CAAC)CuBH4 Complexes as Catalysts for the Hydrolytic Dehydrogenation of BH3NH3. Angewandte Chemie (International Ed. in English). 54: 6008-11. PMID 25802096 DOI: 10.1002/Anie.201500224  0.772
2015 Bidal YD, Lesieur M, Melaimi M, Cordes DB, Slawin AM, Bertrand G, Cazin CS. A simple access to transition metal cyclopropenylidene complexes. Chemical Communications (Cambridge, England). 51: 4778-81. PMID 25621852 DOI: 10.1039/C4Cc10375K  0.372
2015 Tolentino DR, Jin L, Melaimi M, Bertrand G. Mesoionic Carbene-Gold(I) Catalyzed Bis-Hydrohydrazination of Alkynes with Parent Hydrazine. Chemistry, An Asian Journal. PMID 25597889 DOI: 10.1002/Asia.201403408  0.375
2015 Marx VM, Sullivan AH, Melaimi M, Virgil SC, Keitz BK, Weinberger DS, Bertrand G, Grubbs RH. Cyclic alkyl amino carbene (CAAC) ruthenium complexes as remarkably active catalysts for ethenolysis. Angewandte Chemie (International Ed. in English). 54: 1919-23. PMID 25522160 DOI: 10.1002/Anie.201410797  0.445
2015 Soleilhavoup M, Bertrand G. Cyclic (alkyl)(amino)carbenes (CAACs): stable carbenes on the rise. Accounts of Chemical Research. 48: 256-66. PMID 25515548 DOI: 10.1021/Ar5003494  0.466
2015 Dahcheh F, Stephan DW, Bertrand G. Oxidative addition at a carbene center: synthesis of an iminoboryl-CAAC adduct. Chemistry (Weinheim An Der Bergstrasse, Germany). 21: 199-204. PMID 25414006 DOI: 10.1002/Chem.201405887  0.543
2015 Dielmann F, Bertrand G. Reactivity of a stable phosphinonitrene towards small molecules. Chemistry (Weinheim An Der Bergstrasse, Germany). 21: 191-8. PMID 25395098 DOI: 10.1002/Chem.201405430  0.331
2015 Liu L, Ruiz DA, Dahcheh F, Bertrand G. Isolation of a Lewis base stabilized parent phosphenium (PH2+) and related species Chemical Communications. 51: 12732-12735. DOI: 10.1039/c5cc05241f  0.497
2015 Dahcheh F, Stephan DW, Bertrand G. Oxidative addition at a carbene center: Synthesis of an iminoboryl-CAAC adduct Chemistry - a European Journal. 21: 199-204. DOI: 10.1002/chem.201405887  0.381
2015 Bidal YD, Lesieur M, Melaimi M, Nahra F, Cordes DB, Athukorala Arachchige KS, Slawin AMZ, Bertrand G, Cazin CSJ. Copper(I) Complexes Bearing Carbenes beyond Classical N-Heterocyclic Carbenes: Synthesis and Catalytic Activity in "click Chemistry" Advanced Synthesis and Catalysis. 357: 3155-3161. DOI: 10.1002/Adsc.201500453  0.413
2014 Jerabek P, Roesky HW, Bertrand G, Frenking G. Coinage metals binding as main group elements: structure and bonding of the carbene complexes [TM(cAAC)2] and [TM(cAAC)2](+) (TM = Cu, Ag, Au). Journal of the American Chemical Society. 136: 17123-35. PMID 25394669 DOI: 10.1021/Ja508887S  0.474
2014 Dahcheh F, Martin D, Stephan DW, Bertrand G. Synthesis and reactivity of a CAAC-aminoborylene adduct: a hetero-allene or an organoboron isoelectronic with singlet carbenes. Angewandte Chemie (International Ed. in English). 53: 13159-63. PMID 25267591 DOI: 10.1002/Anie.201408371  0.524
2014 Hu X, Martin D, Melaimi M, Bertrand G. Gold-catalyzed hydroarylation of alkenes with dialkylanilines. Journal of the American Chemical Society. 136: 13594-7. PMID 25222130 DOI: 10.1021/Ja507788R  0.403
2014 Jin L, Weinberger DS, Melaimi M, Moore CE, Rheingold AL, Bertrand G. Trinuclear gold clusters supported by cyclic (alkyl)(amino)carbene ligands: mimics for gold heterogeneous catalysts. Angewandte Chemie (International Ed. in English). 53: 9059-63. PMID 24985149 DOI: 10.1002/Anie.201404665  0.335
2014 Kretschmer R, Ruiz DA, Moore CE, Rheingold AL, Bertrand G. One-, two-, and three-electron reduction of a cyclic alkyl(amino)carbene-SbCl₃ adduct. Angewandte Chemie (International Ed. in English). 53: 8176-9. PMID 24961494 DOI: 10.1002/Anie.201404849  0.351
2014 Ung G, Rittle J, Soleilhavoup M, Bertrand G, Peters JC. Two-coordinate Fe⁰ and Co⁰ complexes supported by cyclic (alkyl)(amino)carbenes. Angewandte Chemie (International Ed. in English). 53: 8427-31. PMID 24953342 DOI: 10.1002/Anie.201404078  0.775
2014 Weinstein CM, Martin CD, Liu L, Bertrand G. Cross-coupling reactions between stable carbenes. Angewandte Chemie (International Ed. in English). 53: 6550-3. PMID 24838590 DOI: 10.1002/Anie.201404199  0.714
2014 Weinberger DS, Amin Sk N, Mondal KC, Melaimi M, Bertrand G, Stückl AC, Roesky HW, Dittrich B, Demeshko S, Schwederski B, Kaim W, Jerabek P, Frenking G. Isolation of neutral mononuclear copper complexes stabilized by two cyclic (alkyl)(amino)carbenes. Journal of the American Chemical Society. 136: 6235-8. PMID 24731250 DOI: 10.1021/Ja502521B  0.47
2014 Martin D, Canac Y, Lavallo V, Bertrand G. Comparative reactivity of different types of stable cyclic and acyclic mono- and diamino carbenes with simple organic substrates. Journal of the American Chemical Society. 136: 5023-30. PMID 24634983 DOI: 10.1021/Ja412981X  0.707
2014 Dielmann F, Andrada DM, Frenking G, Bertrand G. Isolation of bridging and terminal coinage metal-nitrene complexes. Journal of the American Chemical Society. 136: 3800-2. PMID 24559041 DOI: 10.1021/Ja5007355  0.413
2014 Bezuidenhout DI, Kleinhans G, Guisado-Barrios G, Liles DC, Ung G, Bertrand G. Isolation of a potassium bis(1,2,3-triazol-5-ylidene)carbazolide: a stabilizing pincer ligand for reactive late transition metal complexes. Chemical Communications (Cambridge, England). 50: 2431-3. PMID 24448261 DOI: 10.1039/C3Cc49385G  0.721
2014 Jin L, Melaimi M, Liu L, Bertrand G. Singlet carbenes as mimics for transition metals: Synthesis of an air stable organic mixed valence compound [M2(C2)+; M = cyclic(alkyl)(amino)carbene] Organic Chemistry Frontiers. 1: 351-354. DOI: 10.1039/C4Qo00072B  0.63
2014 Bezuidenhout DI, Kleinhans G, Guisado-Barrios G, Liles DC, Ung G, Bertrand G. Isolation of a potassium bis(1,2,3-triazol-5-ylidene)carbazolide: A stabilizing pincer ligand for reactive late transition metal complexes Chemical Communications. 50: 2431-2433. DOI: 10.1039/c3cc49385g  0.689
2014 Weinberger DS, Amin Sk N, Mondal KC, Melaimi M, Bertrand G, Stückl AC, Roesky HW, Dittrich B, Demeshko S, Schwederski B, Kaim W, Jerabek P, Frenking G. Isolation of neutral mononuclear copper complexes stabilized by two cyclic (Alkyl)(amino)carbenes Journal of the American Chemical Society. 136: 6235-6238. DOI: 10.1021/ja502521b  0.399
2014 Dahcheh F, Martin D, Stephan DW, Bertrand G. Synthesis and reactivity of a CAAC-aminoborylene adduct: A hetero-allene or an organoboron isoelectronic with singlet carbenes Angewandte Chemie - International Edition. 53: 13159-13163. DOI: 10.1002/anie.201408371  0.443
2013 Mahoney JK, Martin D, Moore CE, Rheingold AL, Bertrand G. Bottleable (amino)(carboxy) radicals derived from cyclic (alkyl)(amino) carbenes. Journal of the American Chemical Society. 135: 18766-9. PMID 24304381 DOI: 10.1021/Ja4104765  0.39
2013 Ung G, Bertrand G. β- and α-Hydride abstraction in Gold(I) alkyl complexes. Angewandte Chemie (International Ed. in English). 52: 11388-91. PMID 24027200 DOI: 10.1002/Anie.201306550  0.667
2013 Ung G, Bertrand G. β- and α-Hydride abstraction in Gold(I) alkyl complexes. Angewandte Chemie (International Ed. in English). 52: 11388-91. PMID 24027200 DOI: 10.1002/Anie.201306550  0.667
2013 Martin CD, Soleilhavoup M, Bertrand G. Carbene-Stabilized Main Group Radicals and Radical Ions. Chemical Science (Royal Society of Chemistry : 2010). 4: 3020-3030. PMID 23878717 DOI: 10.1039/C3Sc51174J  0.581
2013 Weinberger DS, Melaimi M, Moore CE, Rheingold AL, Frenking G, Jerabek P, Bertrand G. Isolation of neutral mono- and dinuclear gold complexes of cyclic (alkyl)(amino)carbenes. Angewandte Chemie (International Ed. in English). 52: 8964-7. PMID 23861304 DOI: 10.1002/Anie.201304820  0.376
2013 Ruiz DA, Ung G, Melaimi M, Bertrand G. Deprotonation of a borohydride: synthesis of a carbene-stabilized boryl anion. Angewandte Chemie (International Ed. in English). 52: 7590-2. PMID 23765789 DOI: 10.1002/Anie.201303457  0.738
2013 Martin CD, Weinstein CM, Moore CE, Rheingold AL, Bertrand G. Exploring the reactivity of white phosphorus with electrophilic carbenes: synthesis of a P4 cage and P8 clusters. Chemical Communications (Cambridge, England). 49: 4486-8. PMID 23571800 DOI: 10.1039/C3Cc42041H  0.517
2013 Martin CD, Weinstein CM, Moore CE, Rheingold AL, Bertrand G. Exploring the reactivity of white phosphorus with electrophilic carbenes: synthesis of a P4 cage and P8 clusters. Chemical Communications (Cambridge, England). 49: 4486-8. PMID 23571800 DOI: 10.1039/C3Cc42041H  0.517
2013 López-Gómez MJ, Martin D, Bertrand G. Anti-Bredt N-heterocyclic carbene: An efficient ligand for the gold(i)-catalyzed hydroamination of terminal alkynes with parent hydrazine Chemical Communications. 49: 4483-4485. PMID 23552965 DOI: 10.1039/C3Cc41279B  0.359
2013 Back O, Henry-Ellinger M, Martin CD, Martin D, Bertrand G. 31P NMR chemical shifts of carbene-phosphinidene adducts as an indicator of the π-accepting properties of carbenes. Angewandte Chemie (International Ed. in English). 52: 2939-43. PMID 23364832 DOI: 10.1002/Anie.201209109  0.516
2013 Back O, Henry-Ellinger M, Martin CD, Martin D, Bertrand G. 31P NMR chemical shifts of carbene-phosphinidene adducts as an indicator of the π-accepting properties of carbenes. Angewandte Chemie (International Ed. in English). 52: 2939-43. PMID 23364832 DOI: 10.1002/Anie.201209109  0.516
2013 Ung G, Soleilhavoup M, Bertrand G. Gold(III)- versus gold(I)-induced cyclization: synthesis of six-membered mesoionic carbene and acyclic (aryl)(heteroaryl) carbene complexes. Angewandte Chemie (International Ed. in English). 52: 758-61. PMID 23169762 DOI: 10.1002/Anie.201207961  0.717
2013 Giziroglu E, Donnadieu B, Bertrand G. Synthesis and characterization of a pyrazolium bearing N-heterocyclic carbene-palladium(II) complex Journal of Organometallic Chemistry. 724: 251-254. DOI: 10.1016/J.Jorganchem.2012.11.021  0.383
2013 Ung G, Bertrand G. α- und β-Hydridabstraktion in Gold(I)-alkylkomplexen Angewandte Chemie. 125: 11599-11602. DOI: 10.1002/Ange.201306550  0.634
2013 Weinberger DS, Melaimi M, Moore CE, Rheingold AL, Frenking G, Jerabek P, Bertrand G. Isolierung neutraler mono- und dinuklearer Goldkomplexe von cyclischen Alkyl(amino)carbenen Angewandte Chemie. 125: 9134-9137. DOI: 10.1002/Ange.201304820  0.311
2013 Ruiz DA, Ung G, Melaimi M, Bertrand G. Deprotonierung eines Borhydrids und Synthese eines Carben- stabilisierten Borylanions Angewandte Chemie. 125: 7739-7742. DOI: 10.1002/Ange.201303457  0.71
2012 Yan X, Bouffard J, Guisado-Barrios G, Donnadieu B, Bertrand G. Anionic 1,2,3-triazole-4,5-diylidene: a 1,2-dihapto ligand for the construction of bimetallic complexes. Chemistry (Weinheim An Der Bergstrasse, Germany). 18: 14627-31. PMID 23042507 DOI: 10.1002/Chem.201202862  0.404
2012 Dielmann F, Back O, Henry-Ellinger M, Jerabek P, Frenking G, Bertrand G. A crystalline singlet phosphinonitrene: a nitrogen atom-transfer agent. Science (New York, N.Y.). 337: 1526-8. PMID 22997335 DOI: 10.1126/Science.1226022  0.377
2012 Ung G, Bertrand G. C-F bond activation with an apparently benign ethynyl dithiocarbamate, and subsequent fluoride transfer reactions. Chemistry (Weinheim An Der Bergstrasse, Germany). 18: 12955-7. PMID 22961643 DOI: 10.1002/Chem.201202292  0.677
2012 Ung G, Mendoza-Espinosa D, Bertrand G. Ynamides: stable ligand equivalents of unstable oxazol-4-ylidenes (novel mesoionic carbenes). Chemical Communications (Cambridge, England). 48: 7088-90. PMID 22684100 DOI: 10.1039/C2Cc33319H  0.734
2012 Martin D, Lassauque N, Donnadieu B, Bertrand G. A cyclic diaminocarbene with a pyramidalized nitrogen atom: a stable N-heterocyclic carbene with enhanced electrophilicity. Angewandte Chemie (International Ed. in English). 51: 6172-5. PMID 22565863 DOI: 10.1002/Anie.201202137  0.423
2012 Celik MA, Sure R, Klein S, Kinjo R, Bertrand G, Frenking G. Borylene complexes (BH)L2 and nitrogen cation complexes (N+)L2: isoelectronic homologues of carbones CL2. Chemistry (Weinheim An Der Bergstrasse, Germany). 18: 5676-92. PMID 22434609 DOI: 10.1002/Chem.201103965  0.633
2012 Ung G, Soleilhavoup M, Bertrand G. Gold-vermittelte Cyclisierung: ob sechsgliedriges mesoionisches Carben oder acyclischer (Aryl)(heteroaryl)-Carbenkomplex - entscheidend ist die Oxidationsstufe Angewandte Chemie. 125: 787-790. DOI: 10.1002/Ange.201207961  0.684
2011 Ung G, Frey GD, Schoeller WW, Bertrand G. Bond activation with an apparently benign ethynyl dithiocarbamate Ar-C≡C-S-C(S)NR2. Angewandte Chemie (International Ed. in English). 50: 9923-5. PMID 23210141 DOI: 10.1002/Anie.201104303  0.682
2011 Dehope A, Mendoza-Espinosa D, Donnadieu B, Bertrand G. A persistent (amino)(ferrocenyl)carbene(). New Journal of Chemistry = Nouveau Journal De Chimie. 35: 2037-2042. PMID 22707878 DOI: 10.1039/C1Nj20170K  0.807
2011 Martin D, Melaimi M, Soleilhavoup M, Bertrand G. A Brief Survey of our Contribution to Stable Carbene Chemistry. Organometallics. 30: 5304-5313. PMID 22707843 DOI: 10.1021/Om200650X  0.33
2011 Guisado-Barrios G, Bouffard J, Donnadieu B, Bertrand G. Bis(1,2,3-triazol-5-ylidenes) (i-bitz) as Stable 1,4-Bidentate Ligands Based on Mesoionic Carbenes (MICs). Organometallics. 30: 6017-6021. PMID 22096269 DOI: 10.1021/Om200844B  0.394
2011 Mendoza-Espinosa D, Ung G, Donnadieu B, Bertrand G. Mesoionic thiazol-5-ylidenes as ligands for transition metal complexes. Chemical Communications (Cambridge, England). 47: 10614-6. PMID 21879048 DOI: 10.1039/C1Cc14165A  0.702
2011 Kinjo R, Donnadieu B, Celik MA, Frenking G, Bertrand G. Synthesis and characterization of a neutral tricoordinate organoboron isoelectronic with amines. Science (New York, N.Y.). 333: 610-3. PMID 21798945 DOI: 10.1126/Science.1207573  0.662
2011 Dehope A, Donnadieu B, Bertrand G. Grubbs and Hoveyda-Type Ruthenium Complexes Bearing a Cyclic Bent-Allene. Journal of Organometallic Chemistry. 696: 2899-2903. PMID 21765542 DOI: 10.1016/J.Jorganchem.2011.03.010  0.808
2011 Martin D, Soleilhavoup M, Bertrand G. Stable singlet carbenes as mimics for transition metal centers. Chemical Science (Royal Society of Chemistry : 2010). 2: 389-399. PMID 21743834 DOI: 10.1039/C0Sc00388C  0.342
2011 Ung G, Bertrand G. Stability and electronic properties of imidazole-based mesoionic carbenes. Chemistry (Weinheim An Der Bergstrasse, Germany). 17: 8269-72. PMID 21656597 DOI: 10.1002/Chem.201101130  0.671
2011 Keitz BK, Bouffard J, Bertrand G, Grubbs RH. Protonolysis of a ruthenium-carbene bond and applications in olefin metathesis. Journal of the American Chemical Society. 133: 8498-501. PMID 21574621 DOI: 10.1021/Ja203070R  0.495
2011 Kinjo R, Donnadieu B, Bertrand G. Gold-catalyzed hydroamination of alkynes and allenes with parent hydrazine. Angewandte Chemie (International Ed. in English). 50: 5560-3. PMID 21574224 DOI: 10.1002/Anie.201100740  0.588
2011 Bouffard J, Keitz BK, Tonner R, Lavallo V, Guisado-Barrios G, Frenking G, Grubbs RH, Bertrand G. Synthesis of Highly Stable 1,3-Diaryl-1H-1,2,3-triazol-5-ylidenes and their Applications in Ruthenium-Catalyzed Olefin Metathesis. Organometallics. 30: 2617-2627. PMID 21572542 DOI: 10.1021/Om200272M  0.747
2011 Ung G, Mendoza-Espinosa D, Bouffard J, Bertrand G. A stable acyclic ligand equivalent of an unstable 1,3-dithiol-5-ylidene. Angewandte Chemie (International Ed. in English). 50: 4215-8. PMID 21472947 DOI: 10.1002/Anie.201100420  0.756
2011 Mendoza-Espinosa D, Donnadieu B, Bertrand G. Facile preparation of homo- and hetero-dimetallic complexes with a 4-phosphino-substituted NHC ligand. Toward the design of multifunctional catalysts. Chemistry, An Asian Journal. 6: 1099-103. PMID 21322115 DOI: 10.1002/Asia.201000856  0.403
2011 Lavallo V, El-Batta A, Bertrand G, Grubbs RH. Insights into the carbene-initiated aggregation of [Fe(cot)(2)]. Angewandte Chemie (International Ed. in English). 50: 268-71. PMID 21110365 DOI: 10.1002/Anie.201005212  0.682
2011 Frey GD, Donnadieu B, Soleilhavoup M, Bertrand G. Synthesis of a room-temperature-stable dimeric copper(I) hydride. Chemistry, An Asian Journal. 6: 402-5. PMID 20945453 DOI: 10.1002/Asia.201000576  0.432
2011 Back O, Donnadieu B, von Hopffgarten M, Klein S, Tonner R, Frenking G, Bertrand G. N-Heterocyclic carbenes versus transition metals for stabilizing phosphinyl radicals Chemical Science. 2: 858-861. DOI: 10.1039/C1Sc00027F  0.347
2011 Ung G, Frey GD, Schoeller WW, Bertrand G. Cover Picture: Bond Activation with an Apparently Benign Ethynyl Dithiocarbamate ArCCSC(S)NR2 (Angew. Chem. Int. Ed. 42/2011) Angewandte Chemie International Edition. 50: 9759-9759. DOI: 10.1002/Anie.201105306  0.662
2011 Ung G, Frey GD, Schoeller WW, Bertrand G. Titelbild: Bond Activation with an Apparently Benign Ethynyl Dithiocarbamate ArCCSC(S)NR2 (Angew. Chem. 42/2011) Angewandte Chemie. 123: 9933-9933. DOI: 10.1002/Ange.201105306  0.663
2010 Frey GD, Masuda JD, Donnadieu B, Bertrand G. Activation of Si-H, B-H, and P-H bonds at a single nonmetal center. Angewandte Chemie (International Ed. in English). 49: 9444-7. PMID 21031393 DOI: 10.1002/Anie.201005698  0.57
2010 Melaimi M, Soleilhavoup M, Bertrand G. Stable cyclic carbenes and related species beyond diaminocarbenes. Angewandte Chemie (International Ed. in English). 49: 8810-49. PMID 20836099 DOI: 10.1002/Anie.201000165  0.405
2010 Back O, Celik MA, Frenking G, Melaimi M, Donnadieu B, Bertrand G. A crystalline phosphinyl radical cation. Journal of the American Chemical Society. 132: 10262-3. PMID 20662507 DOI: 10.1021/Ja1046846  0.354
2010 Kinjo R, Donnadieu B, Bertrand G. Isolation of a carbene-stabilized phosphorus mononitride and its radical cation (PN+*). Angewandte Chemie (International Ed. in English). 49: 5930-3. PMID 20632430 DOI: 10.1002/Anie.201002889  0.62
2010 Guisado-Barrios G, Bouffard J, Donnadieu B, Bertrand G. Crystalline 1H-1,2,3-triazol-5-ylidenes: new stable mesoionic carbenes (MICs). Angewandte Chemie (International Ed. in English). 49: 4759-62. PMID 20509134 DOI: 10.1002/Anie.201001864  0.449
2010 Mendoza-Espinosa D, Donnadieu B, Bertrand G. Synthesis of 4- and 4,5-functionalized imidazol-2-ylidenes from a single 4,5-unsubstituted imidazol-2-ylidene. Journal of the American Chemical Society. 132: 7264-5. PMID 20443633 DOI: 10.1021/Ja102639A  0.342
2010 Back O, Donnadieu B, Parameswaran P, Frenking G, Bertrand G. Isolation of crystalline carbene-stabilized P(2)-radical cations and P(2)-dications. Nature Chemistry. 2: 369-73. PMID 20414236 DOI: 10.1038/Nchem.617  0.351
2010 Zeng X, Kinjo R, Donnadieu B, Bertrand G. Serendipitous discovery of the catalytic hydroammoniumation and methylamination of alkynes. Angewandte Chemie (International Ed. in English). 49: 942-5. PMID 20058283 DOI: 10.1002/Anie.200905341  0.686
2010 Fuks G, Donnadieu B, Sacquet A, Maron L, Bourissou D, Bertrand G. Oxidation of a stable 1,3-diborata-2,4-diphosphonio-cyclobutane-1,3-diyl Main Group Chemistry. 9: 101-109. DOI: 10.3233/Mgc-2010-0009  0.467
2010 Zeng X, Kinjo R, Donnadieu B, Bertrand G. Gold(I)-Catalyzed Hydroammoniumation and Methylaminationof Alkynes to Indoles Synfacts. 2010: 401-401. DOI: 10.1055/S-0029-1219498  0.325
2010 Huy NHT, Donnadieu B, Bertrand G, Mathey F. The phosphorus version of the oxaspiropentene-cyclobutenone rearrangement Organometallics. 29: 1302-1304. DOI: 10.1021/Om900983K  0.338
2010 BOURISSOU D, DUPUCH C, DAHAN F, BERTRAND G. ChemInform Abstract: One-Pot Synthesis and Reactivity of New Tetrazoles, 1,3,4-Oxa- and 1,2,3-Thiadiazoles. Cheminform. 29: no-no. DOI: 10.1002/chin.199812109  0.481
2010 Majoral J, Bertrand G, Ocando-Mavarez E, Baceiredo A. XIIth European Colloquium on Heterocyclic Chemistry “Phosphorus azides, powerful reagents in heterocyclic chemistry” Bulletin Des SociéTéS Chimiques Belges. 95: 945-957. DOI: 10.1002/Bscb.19860951102  0.375
2010 Melaimi M, Soleilhavoup M, Bertrand G. Stabile cyclische Carbene und verwandte Spezies jenseits der Diaminocarbene Angewandte Chemie. 122: 8992-9032. DOI: 10.1002/Ange.201000165  0.304
2009 Aldeco-Perez E, Rosenthal AJ, Donnadieu B, Parameswaran P, Frenking G, Bertrand G. Isolation of a C5-deprotonated imidazolium, a crystalline "abnormal" N-heterocyclic carbene. Science (New York, N.Y.). 326: 556-9. PMID 19900893 DOI: 10.1126/Science.1178206  0.417
2009 Kuchenbeiser G, Soleilhavoup M, Donnadieu B, Bertrand G. Reactivity of cyclic (alkyl)(amino)carbenes (CAACs) and bis(amino)cyclopropenylidenes (BACs) with heteroallenes: comparisons with their N-heterocyclic carbene (NHCs) counterparts. Chemistry, An Asian Journal. 4: 1745-50. PMID 19780080 DOI: 10.1002/Asia.200900338  0.811
2009 Fuks G, Saffon N, Maron L, Bertrand G, Bourissou D. Ionic-type reactivity of 1,3-dibora-2,4-diphosphoniocyclobutane-1,3-diyls: regio- and stereoselective addition of hydracids. Journal of the American Chemical Society. 131: 13681-9. PMID 19772363 DOI: 10.1021/Ja903746P  0.57
2009 Zeng X, Soleilhavoup M, Bertrand G. Gold-catalyzed intermolecular Markovnikov hydroamination of allenes with secondary amines. Organic Letters. 11: 3166-9. PMID 19719176 DOI: 10.1021/Ol901418C  0.421
2009 Fernández I, Dyker CA, DeHope A, Donnadieu B, Frenking G, Bertrand G. Exocyclic delocalization at the expense of aromaticity in 3,5-bis(pi-donor) substituted pyrazolium ions and corresponding cyclic bent allenes. Journal of the American Chemical Society. 131: 11875-81. PMID 19645451 DOI: 10.1021/Ja903396E  0.79
2009 Tran HN, Donnadieu B, Bertrand G, Mathey F. Umpolung of electrophilic terminal phosphinidene complexes by interaction with nucleophilic carbenes. Chemistry, An Asian Journal. 4: 1225-8. PMID 19557786 DOI: 10.1002/Asia.200900177  0.32
2009 Back O, Kuchenbeiser G, Donnadieu B, Bertrand G. Nonmetal-mediated fragmentation of P4: isolation of P1 and P2 bis(carbene) adducts. Angewandte Chemie (International Ed. in English). 48: 5530-3. PMID 19544519 DOI: 10.1002/Anie.200902344  0.761
2009 Asay M, Donnadieu B, Schoeller WW, Bertrand G. Synthesis of allenylidene lithium and silver complexes, and subsequent transmetalation reactions. Angewandte Chemie (International Ed. in English). 48: 4796-9. PMID 19472245 DOI: 10.1002/Anie.200901319  0.753
2009 Melaimi M, Parameswaran P, Donnadieu B, Frenking G, Bertrand G. Synthesis and ligand properties of a persistent, all-carbon four-membered-ring allene. Angewandte Chemie (International Ed. in English). 48: 4792-5. PMID 19472243 DOI: 10.1002/Anie.200901117  0.37
2009 Zeng X, Frey GD, Kinjo R, Donnadieu B, Bertrand G. Synthesis of a simplified version of stable bulky and rigid cyclic (alkyl)(amino)carbenes, and catalytic activity of the ensuing gold(I) complex in the three-component preparation of 1,2-dihydroquinoline derivatives. Journal of the American Chemical Society. 131: 8690-6. PMID 19456108 DOI: 10.1021/Ja902051M  0.694
2009 Zeng X, Frey GD, Kousar S, Bertrand G. A cationic gold(I) complex as a general catalyst for the intermolecular hydroamination of alkynes: application to the one-pot synthesis of allenes from two alkynes and a sacrificial amine. Chemistry (Weinheim An Der Bergstrasse, Germany). 15: 3056-60. PMID 19219866 DOI: 10.1002/Chem.200802626  0.374
2009 Kinjo R, Ishida Y, Donnadieu B, Bertrand G. Isolation of bicyclopropenylidenes: derivatives of the smallest member of the fulvalene family. Angewandte Chemie (International Ed. in English). 48: 517-20. PMID 19072812 DOI: 10.1002/Anie.200804372  0.576
2009 Fuks G, Saffon N, Maron L, Bertrand G, Bourissou D. Ionic-type reactivity of 1,3-dibora-2,4-diphosphoniocyclobutane-1,3-diyls: Regio- and stereoselective addition of hydracids Journal of the American Chemical Society. 131: 13681-13689. DOI: 10.1021/ja903746p  0.448
2009 Lavallo V, Dyker CA, Donnadieu B, Bertrand G. Are allenes with zwitterionic character still allenes? of course! Angewandte Chemie - International Edition. 48: 1540-1542. DOI: 10.1002/Anie.200804909  0.617
2008 Frey GD, Dewhurst RD, Kousar S, Donnadieu B, Bertrand G. Cyclic (Alkyl)(amino)carbene Gold(I) complexes: A Synthetic and Structural Investigation. Journal of Organometallic Chemistry. 693: 1674-1682. PMID 19343084 DOI: 10.1016/J.Jorganchem.2008.01.026  0.372
2008 Kuchenbeiser G, Donnadieu B, Bertrand G. Stable Bis(diisopropylamino)cyclopropenylidene (BAC) as Ligand for Transition Metal Complexes. Journal of Organometallic Chemistry. 693: 899-904. PMID 19255609 DOI: 10.1016/J.Jorganchem.2007.11.056  0.806
2008 Giziroglu E, Donnadieu B, Bertrand G. Reluctance of 4-chloro-5-metalla-1,3,2-diazaborolines to undergo metal halide beta-elimination: an opportunity for C-functionalization of 1,3,2-diazaborolines. Inorganic Chemistry. 47: 9751-3. PMID 18841958 DOI: 10.1021/Ic801424K  0.374
2008 Frey GD, Song M, Bourg JB, Donnadieu B, Soleilhavoup M, Bertrand G. A persistent P,N-heterocyclic carbene. Chemical Communications (Cambridge, England). 4711-3. PMID 18830468 DOI: 10.1039/B812333K  0.516
2008 Vignolle J, Asay M, Miqueu K, Bourissou D, Bertrand G. Rearrangement of biaryl monoaminocarbenes via concerted asynchronous insertion into aromatic C-H bonds Organic Letters. 10: 4299-4302. PMID 18763790 DOI: 10.1021/Ol801670Z  0.79
2008 Asay M, Kato T, Saffon-Merceron N, Cossío FP, Baceiredo A, Bertrand G. Synthesis and ligand properties of a stable five-membered-ring vinylidenephosphorane. Angewandte Chemie (International Ed. in English). 47: 7530-3. PMID 18704912 DOI: 10.1002/Anie.200802741  0.755
2008 Rodriguez A, Fuks G, Bourg JB, Bourissou D, Tham FS, Bertrand G. 1,3-Diborata-2,4-diphosphoniocyclobutane-1,3-diyls communicate through a para-phenylene linker. Dalton Transactions (Cambridge, England : 2003). 4482-7. PMID 18698452 DOI: 10.1039/B718631B  0.515
2008 Anderson DR, Ung T, Mkrtumyan G, Bertrand G, Grubbs RH, Schrodi Y. Kinetic Selectivity of Olefin Metathesis Catalysts Bearing Cyclic (Alkyl)(Amino)Carbenes. Organometallics. 27: 563-566. PMID 18584055 DOI: 10.1021/Om7008028  0.521
2008 Lavallo V, Dyker CA, Donnadieu B, Bertrand G. Synthesis and ligand properties of stable five-membered-ring allenes containing only second-row elements. Angewandte Chemie (International Ed. in English). 47: 5411-4. PMID 18551494 DOI: 10.1002/Anie.200801176  0.683
2008 Lavallo V, Frey GD, Donnadieu B, Soleilhavoup M, Bertrand G. Homogeneous catalytic hydroamination of alkynes and allenes with ammonia. Angewandte Chemie (International Ed. in English). 47: 5224-8. PMID 18528830 DOI: 10.1002/Anie.200801136  0.726
2008 Asay M, Donnadieu B, Baceiredo A, Soleilhavoup M, Bertrand G. Cyclic (amino)[bis(ylide)]carbene as an anionic bidentate ligand for transition-metal complexes. Inorganic Chemistry. 47: 3949-51. PMID 18422308 DOI: 10.1021/Ic800459P  0.786
2008 Schoeller WW, Frey GD, Bertrand G. Tuning the nucleophilicity in cyclopropenylidenes. Chemistry (Weinheim An Der Bergstrasse, Germany). 14: 4711-8. PMID 18404754 DOI: 10.1002/Chem.200701926  0.322
2008 Dyker CA, Lavallo V, Donnadieu B, Bertrand G. Synthesis of an extremely bent acyclic allene (a "carbodicarbene"): a strong donor ligand. Angewandte Chemie (International Ed. in English). 47: 3206-9. PMID 18311741 DOI: 10.1002/Anie.200705620  0.682
2008 Vignolle J, Gornitzka H, Donnadieu B, Bourissou D, Bertrand G. Palladium-oxygen and palladium-arene interactions in complexes derived from biaryl aminocarbenes: Comparison with biaryl phosphanes Angewandte Chemie - International Edition. 47: 2271-2274. PMID 18273845 DOI: 10.1002/Anie.200704927  0.614
2008 Gandon V, Bourg JB, Tham FS, Schoeller WW, Bertrand G. The existence of two short-bond isomers for bicyclo[1.1.0]butane derivatives based on boron and phosphorus. Angewandte Chemie (International Ed. in English). 47: 155-9. PMID 18022990 DOI: 10.1002/Anie.200704008  0.336
2008 Rodriguez A, Fuks G, Bourg JB, Bourissou D, Tham FS, Bertrand G. 1,3-Diborata-2,4-diphosphoniocyclobutane-1,3-diyls communicate through a para-phenylene linker Dalton Transactions. 4482-4487. DOI: 10.1039/b718631b  0.375
2007 Vignolle J, Donnadieu B, Bourissou D, Bertrand G. An unusual norcaradiene/tropylium rearrangement from a persistent amino-phosphonio-carbene. Tetrahedron Letters. 48: 685-687. PMID 19513183 DOI: 10.1016/J.Tetlet.2006.11.099  0.562
2007 Masuda JD, Schoeller WW, Donnadieu B, Bertrand G. NHC-mediated aggregation of P4: isolation of a P12 cluster. Journal of the American Chemical Society. 129: 14180-1. PMID 17973395 DOI: 10.1021/Ja077296U  0.541
2007 Pascual S, Asay M, Illa O, Kato T, Bertrand G, Saffon-Merceron N, Branchadell V, Baceiredo A. Synthesis of a mixed phosphonium-sulfonium bisylide R3P=C=SR2. Angewandte Chemie (International Ed. in English). 46: 9078-80. PMID 17960549 DOI: 10.1002/Anie.200704071  0.729
2007 Masuda JD, Schoeller WW, Donnadieu B, Bertrand G. Carbene activation of P4 and subsequent derivatization. Angewandte Chemie (International Ed. in English). 46: 7052-5. PMID 17705209 DOI: 10.1002/Anie.200703055  0.5
2007 Lavallo V, Frey GD, Kousar S, Donnadieu B, Bertrand G. Allene formation by gold catalyzed cross-coupling of masked carbenes and vinylidenes. Proceedings of the National Academy of Sciences of the United States of America. 104: 13569-73. PMID 17698808 DOI: 10.1073/Pnas.0705809104  0.705
2007 DeHope A, Lavallo V, Donnadieu B, Schoeller WW, Bertrand G. Recently reported crystalline isothiazole carbenes: myth or reality. Angewandte Chemie (International Ed. in English). 46: 6922-5; discussion 6. PMID 17661300 DOI: 10.1002/Anie.200702272  0.759
2007 Anderson DR, Lavallo V, O'Leary DJ, Bertrand G, Grubbs RH. Synthesis and reactivity of olefin metathesis catalysts bearing cyclic (alkyl)(amino)carbenes. Angewandte Chemie (International Ed. in English). 46: 7262-5. PMID 17623287 DOI: 10.1002/Anie.200702085  0.703
2007 Bourg JB, Rodriguez A, Scheschkewitz D, Gornitzka H, Bourissou D, Bertrand G. Thermal valence isomerization of 2,3-diborata-1,4-diphosphoniabuta-1,3-dienes to bicyclo[1.1.0]butanes and cyclobutane-1,3-diyls. Angewandte Chemie (International Ed. in English). 46: 5741-5. PMID 17592605 DOI: 10.1002/Anie.200701578  0.739
2007 Song M, Donnadieu B, Soleilhavoup M, Bertrand G. Synthesis of phosphaformamidines and phosphaformamidinates. Chemistry, An Asian Journal. 2: 904-8. PMID 17551916 DOI: 10.1002/Asia.200700103  0.532
2007 Frey GD, Lavallo V, Donnadieu B, Schoeller WW, Bertrand G. Facile splitting of hydrogen and ammonia by nucleophilic activation at a single carbon center. Science (New York, N.Y.). 316: 439-41. PMID 17446400 DOI: 10.1126/Science.1141474  0.686
2007 Masuda JD, Martin D, Lyon-Saunier C, Baceiredo A, Gornitzka H, Donnadieu B, Bertrand G. Stable P-heterocyclic carbenes: scope and limitations. Chemistry, An Asian Journal. 2: 178-87. PMID 17441152 DOI: 10.1002/Asia.200600300  0.613
2007 Jazzar R, Bourg JB, Dewhurst RD, Donnadieu B, Bertrand G. Intramolecular "hydroiminiumation and -amidiniumation" of alkenes: a convenient, flexible, and scalable route to cyclic iminium and imidazolinium salts. The Journal of Organic Chemistry. 72: 3492-9. PMID 17408289 DOI: 10.1021/Jo0703909  0.715
2007 Jazzar R, Dewhurst RD, Bourg JB, Donnadieu B, Canac Y, Bertrand G. Intramolecular "hydroiminiumation" of alkenes: application to the synthesis of conjugate acids of cyclic alkyl amino carbenes (CAACs). Angewandte Chemie (International Ed. in English). 46: 2899-902. PMID 17352445 DOI: 10.1002/Anie.200605083  0.7
2007 Vignolle J, Gornitzka H, Maron L, Schoeller WW, Bourissou D, Bertrand G. Transient palladadiphosphanylcarbenes: singlet carbenes with an "inverse" electronic configuration (p(pi)2 instead of sigma2) and unusual transannular metal-carbene interactions (piC-->Pd donation and sigmaPd-->C back-donation). Journal of the American Chemical Society. 129: 978-85. PMID 17243835 DOI: 10.1021/Ja066738J  0.588
2007 Soleilhavoup M, Bertrand G. Let's Play with Valence Isomers : The Influence of Different Main Group Elements on Their Relative Stability Bulletin of the Chemical Society of Japan. 80: 1241-1252. DOI: 10.1246/Bcsj.80.1241  0.359
2007 Fuks G, Saffon N, Bourissou D, Bertrand G. 2,2,4,4-Tetrabromo-1,1,3,3-tetramethyl-cyclodiborazane Acta Crystallographica Section E: Structure Reports Online. 63: o4476. DOI: 10.1107/S1600536807052385  0.521
2007 Cattoën X, Gornitzka H, Tham FS, Miqueu K, Bourissou D, Bertrand G. Transient amino-hydrazino-carbenes: A radical pathway for intramolecular 1,2-migration reactions European Journal of Organic Chemistry. 912-917. DOI: 10.1002/Ejoc.200600901  0.688
2006 Canac Y, Aniol GE, Conejero S, Donnadieu B, Bertrand G. A Facile Synthesis of Carbamoylsilanes, -boranes and -phosphane Oxides - Isolation of the First Uncomplexed Carbamoylborane. European Journal of Inorganic Chemistry. 2006: 5076-5080. PMID 19763185 DOI: 10.1002/Ejic.200600799  0.686
2006 Jazzar R, Liang H, Donnadieu B, Bertrand G. A New Synthetic Method for the Preparation of Protonated-NHCs and Related Compounds. Journal of Organometallic Chemistry. 691: 3201-3205. PMID 19543436 DOI: 10.1016/J.Jorganchem.2006.04.008  0.692
2006 Cattoën X, Bourissou D, Bertrand G. Toward phenanthridin-2-ylidene: electrophilicity versus acidity in planar-constrained C-aryl iminium salts. Tetrahedron Letters. 47: 531-534. PMID 18776944 DOI: 10.1016/J.Tetlet.2005.11.052  0.582
2006 Conejero S, Song M, Martin D, Canac Y, Soleilhavoup M, Bertrand G. New synthetic routes to C-amino phosphorus ylides and their subsequent fragmentation into carbenes and phosphines. Chemistry, An Asian Journal. 1: 155-60. PMID 17441050 DOI: 10.1002/Asia.200600075  0.769
2006 Vignolle J, Donnadieu B, Bourissou D, Soleilhavoup M, Bertrand G. Cyclic C-amino phosphorus ylides as a source of bidentate heteroditopic ligands (phosphine/aminocarbene) for transition metals. Journal of the American Chemical Society. 128: 14810-1. PMID 17105283 DOI: 10.1021/Ja0662725  0.576
2006 Martin D, Tham FS, Baceiredo A, Bertrand G. Synthesis of extended polyphosphacumulenes. Chemistry (Weinheim An Der Bergstrasse, Germany). 12: 8444-50. PMID 17009365 DOI: 10.1002/Chem.200600829  0.357
2006 Lavallo V, Ishida Y, Donnadieu B, Bertrand G. Isolation of cyclopropenylidene-lithium adducts: the Weiss-Yoshida reagent. Angewandte Chemie (International Ed. in English). 45: 6652-5. PMID 16986195 DOI: 10.1002/Anie.200602701  0.73
2006 Ishida Y, Donnadieu B, Bertrand G. Stable four-pi-electron, four-membered heterocyclic cations and carbenes. Proceedings of the National Academy of Sciences of the United States of America. 103: 13585-8. PMID 16950877 DOI: 10.1073/Pnas.0604761103  0.366
2006 Lavallo V, Canac Y, Donnadieu B, Schoeller WW, Bertrand G. CO fixation to stable acyclic and cyclic alkyl amino carbenes: stable amino ketenes with a small HOMO-LUMO gap. Angewandte Chemie (International Ed. in English). 45: 3488-91. PMID 16637087 DOI: 10.1002/Anie.200600987  0.703
2006 Lavallo V, Canac Y, Donnadieu B, Schoeller WW, Bertrand G. Cyclopropenylidenes: from interstellar space to an isolated derivative in the laboratory. Science (New York, N.Y.). 312: 722-4. PMID 16614171 DOI: 10.1126/Science.1126675  0.682
2006 Canac Y, Conejero S, Soleilhavoup M, Donnadieu B, Bertrand G. Synthesis of transient and stable C-amino phosphorus ylides and their fragmentation into transient and stable carbenes. Journal of the American Chemical Society. 128: 459-64. PMID 16402832 DOI: 10.1021/Ja055863C  0.706
2005 Teuma E, Lyon-Saunier C, Gornitzka H, Mignani G, Baceiredo A, Bertrand G. A Stable (Amino)(Phosphino)Carbene as bidentate ligand for Palladium and Nickel Complexes: Synthesis, Structure, and Catalytic Activity. Journal of Organometallic Chemistry. 690: 5541-5545. PMID 19543437 DOI: 10.1016/J.Jorganchem.2005.06.036  0.449
2005 Lavallo V, Canac Y, DeHope A, Donnadieu B, Bertrand G. A rigid cyclic (alkyl)(amino)carbene ligand leads to isolation of low-coordinate transition-metal complexes. Angewandte Chemie (International Ed. in English). 44: 7236-9. PMID 16229037 DOI: 10.1002/Anie.200502566  0.824
2005 Lavallo V, Canac Y, Präsang C, Donnadieu B, Bertrand G. Stable cyclic (alkyl)(amino)carbenes as rigid or flexible, bulky, electron-rich ligands for transition-metal catalysts: a quaternary carbon atom makes the difference. Angewandte Chemie (International Ed. in English). 44: 5705-9. PMID 16059961 DOI: 10.1002/Anie.200501841  0.703
2005 Kato T, Gornitzka H, Schoeller WW, Baceiredo A, Bertrand G. Dimerization of a cyclo-1sigma4,3sigma2,4sigma2-triphosphapentadienyl radical: evidence for phosphorus-phosphorus odd-electron bonds. Angewandte Chemie (International Ed. in English). 44: 5497-500. PMID 16052642 DOI: 10.1002/Anie.200501369  0.308
2005 Präsang C, Donnadieu B, Bertrand G. Stable planar six-pi-electron six-membered N-heterocyclic carbenes with tunable electronic properties. Journal of the American Chemical Society. 127: 10182-3. PMID 16028925 DOI: 10.1021/Ja052987G  0.327
2005 Martin D, Illa O, Baceiredo A, Bertrand G, Ortuño RM, Branchadell V. Theoretical and experimental investigation of the basicity of phosphino(silyl)carbenes. The Journal of Organic Chemistry. 70: 5671-7. PMID 15989352 DOI: 10.1021/Jo0508447  0.332
2005 Canac Y, Conejero S, Donnadieu B, Schoeller WW, Bertrand G. Persistent (amino)(silyl)carbenes. Journal of the American Chemical Society. 127: 7312-3. PMID 15898770 DOI: 10.1021/Ja051109F  0.709
2005 Cattoën X, Miqueu K, Gornitzka H, Bourissou D, Bertrand G. Evidence for radical fragmentations from persistent singlet carbenes. Journal of the American Chemical Society. 127: 3292-3. PMID 15755142 DOI: 10.1021/Ja050028G  0.662
2005 Martin D, Gornitzka H, Baceiredo A, Bertrand G. C-phosphoniophosphaalkenes as precursors of Iσ4, 3σ2-diphosphaallenes: Scope and limitations European Journal of Inorganic Chemistry. 2619-2624. DOI: 10.1002/Ejic.200500014  0.389
2005 Kato T, Gornitzka H, Schoeller WW, Baceiredo A, Bertrand G. Dimerization of a Cyclo-1σ4,3σ2,4σ2-Triphosphapentadienyl Radical: Evidence for Phosphorus-Phosphorus Odd-Electron Bonds Angewandte Chemie. 117: 5633-5636. DOI: 10.1002/Ange.200501369  0.313
2004 Dumitrescu A, Rudzevich VL, Romanenko VD, Mari A, Schoeller WW, Bourissou D, Bertrand G. Persistent phosphinyl radicals featuring a bulky amino substituent and the 2,6-bis(trifluoromethyl)phenyl group. Inorganic Chemistry. 43: 6546-8. PMID 15476350 DOI: 10.1021/Ic049152B  0.564
2004 Rodriguez A, Tham FS, Schoeller WW, Bertrand G. Catenation of two singlet diradicals: synthesis of a stable tetraradical (tetraradicaloid). Angewandte Chemie (International Ed. in English). 43: 4876-80. PMID 15372559 DOI: 10.1002/Anie.200460473  0.333
2004 Rodriguez A, Olsen RA, Ghaderi N, Scheschkewitz D, Tham FS, Mueller LJ, Bertrand G. Evidence for the coexistence of two bond-stretch isomers in solution. Angewandte Chemie (International Ed. in English). 43: 4880-3. PMID 15372558 DOI: 10.1002/Anie.200460475  0.698
2004 Conejero S, Canac Y, Tham FS, Bertrand G. Readily available onio-substituted methyleneiminium salts: single precursors for a variety of aminocarbenes. Angewandte Chemie (International Ed. in English). 43: 4089-93. PMID 15300703 DOI: 10.1002/Anie.200460045  0.687
2004 Bertrand G. Chemistry. The modest undressing of a silicon center. Science (New York, N.Y.). 305: 783-5. PMID 15297652 DOI: 10.1126/Science.1102270  0.334
2004 Lavallo V, Mafhouz J, Canac Y, Donnadieu B, Schoeller WW, Bertrand G. Synthesis, reactivity, and ligand properties of a stable alkyl carbene. Journal of the American Chemical Society. 126: 8670-1. PMID 15250717 DOI: 10.1021/Ja047503F  0.709
2004 Amii H, Vranicar L, Gornitzka H, Bourissou D, Bertrand G. Radical-type reactivity of the 1,3-dibora-2,4-diphosphoniocyclobutane-1,3-diyl. Journal of the American Chemical Society. 126: 1344-5. PMID 14759184 DOI: 10.1021/Ja039920I  0.513
2004 Cattoën X, Gornitzka H, Bourissou D, Bertrand G. Amino-aryl-carbenes: alternative ligands for transition metals? Journal of the American Chemical Society. 126: 1342-3. PMID 14759183 DOI: 10.1021/Ja0396854  0.578
2004 Otto M, Conejero S, Canac Y, Romanenko VD, Rudzevitch V, Bertrand G. Mono- and diaminocarbenes from chloroiminium and -amidinium salts: synthesis of metal-free bis(dimethylamino)carbene. Journal of the American Chemical Society. 126: 1016-7. PMID 14746458 DOI: 10.1021/Ja0393325  0.705
2004 Scheschkewitz D, Amii H, Gornitzka H, Schoeller WW, Bourissou D, Bertrand G. Sigma-bond stretching: a static approach for a dynamic process. Angewandte Chemie (International Ed. in English). 43: 585-7. PMID 14743410 DOI: 10.1002/Anie.200352944  0.737
2004 Solé S, Cattoën X, Gornitzka H, Bourissou D, Bertrand G. Reaction of a stable aminoarylcarbene with 2-chloroacrylonitrile: Dearomatizing cyclization rather than cyclopropanation Tetrahedron Letters. 45: 5391-5393. DOI: 10.1016/J.Tetlet.2004.05.082  0.558
2004 Canac Y, Soleilhavoup M, Conejero S, Bertrand G. Stable non-N-heterocyclic carbenes (non-NHC): recent progress Journal of Organometallic Chemistry. 689: 3857-3865. DOI: 10.1016/J.Jorganchem.2004.02.005  0.393
2004 Merceron-Saffon N, Gornitzka H, Baceiredo A, Bertrand G. α,β-(Phosphino)(aminocarbene) and α,ω-(phosphino)(oxyaminocarbene): new bidentate ligands for transition metal complexes Journal of Organometallic Chemistry. 689: 1431-1435. DOI: 10.1016/J.Jorganchem.2004.02.002  0.418
2004 Martin D, Baceiredo A, Bertrand G. Synthesis of a persistent 1σ3,3σ3- diphosphaallyl cation featuring a localized phosphorus-carbon double bond European Journal of Inorganic Chemistry. 3533-3537. DOI: 10.1002/Ejic.200400181  0.403
2004 Miqueu K, Sotiropoulos J, Pfister-Guillouzo G, Rudzevich V, Romanenko V, Bertrand G. Role of the 2,6-Bis(trifluoromethyl)phenyl Group on the Acidity of the Corresponding Phosphane European Journal of Inorganic Chemistry. 2004: 381-387. DOI: 10.1002/Ejic.200300313  0.614
2004 Scheschkewitz D, Amii H, Gornitzka H, Schoeller WW, Bourissou D, Bertrand G. Cover Picture:σ-Bond Stretching: A Static Approach for a Dynamic Process (Angew. Chem. Int. Ed. 5/2004) Angewandte Chemie International Edition. 43: 531-531. DOI: 10.1002/Anie.200490004  0.739
2004 Scheschkewitz D, Amii H, Gornitzka H, Schoeller WW, Bourissou D, Bertrand G. Titelbild:σ-Bond Stretching: A Static Approach for a Dynamic Process (Angew. Chem. 5/2004) Angewandte Chemie. 116: 537-537. DOI: 10.1002/Ange.200490004  0.739
2003 Miqueu K, Despagnet-Ayoub E, Dyer PW, Bourissou D, Bertrand G. Theoretical study of rhodium(I) carbene complexes: the structural versatility of phosphino- compared with aminocarbenes. Chemistry (Weinheim An Der Bergstrasse, Germany). 9: 5858-64. PMID 14673857 DOI: 10.1002/Chem.200304928  0.712
2003 Illa O, Gornitzka H, Baceiredo A, Bertrand G, Branchadell V, Ortuño RM. Stereoselective synthesis of phosphoranyl aryloxiranes through the addition of a nucleophilic stable carbene to aromatic aldehydes. The Journal of Organic Chemistry. 68: 7707-10. PMID 14510546 DOI: 10.1021/Jo0350460  0.393
2003 Merceron-Saffon N, Baceiredo A, Gornitzka H, Bertrand G. Synthesis of carbenes through substitution reactions at a carbene center. Science (New York, N.Y.). 301: 1223-5. PMID 12947194 DOI: 10.1126/Science.1086860  0.429
2003 Schoeller WW, Rozhenko A, Bourissou D, Bertrand G. On the electronic structures of the 1,3-diboracyclobutane-1,3-diyls and their valence isomers with a B2E2 skeleton (E=N, P, As). Chemistry (Weinheim An Der Bergstrasse, Germany). 9: 3611-7. PMID 12898688 DOI: 10.1002/Chem.200204508  0.53
2003 Cattoën X, Solé S, Pradel C, Gornitzka H, Miqueu K, Bourissou D, Bertrand G. Transient azomethine-ylides from a stable amino-carbene and an aldiminium salt. The Journal of Organic Chemistry. 68: 911-4. PMID 12558415 DOI: 10.1021/Jo026214B  0.698
2003 Despagnet-Ayoub E, Solé S, Gornitzka H, Rozhenko AB, Schoeller WW, Bourissou D, Bertrand G. (Phosphino)(aryl)carbenes: effect of aryl substituents on their stabilization mode. Journal of the American Chemical Society. 125: 124-30. PMID 12515513 DOI: 10.1021/Ja0281986  0.56
2003 Romanenko VD, Thoumazet C, Lavallo V, Tham FS, Bertrand G. Synthesis and reactivity of a stable crystalline diastereomerically pure trifluoromethanesulfinic acid derivative: (S)-(−)-1-trifluoromethylsulfinyl-(R)-4-phenyloxazolidin-2-one Chemical Communications. 1680-1681. DOI: 10.1039/B303574C  0.653
2003 Despagnet-Ayoub E, Gornitzka H, Fawcett J, Dyer PW, Bourissou D, Bertrand G. The first coordination of an (α-diazo)phosphine to a transition-metal center Organometallics. 22: 1358-1360. DOI: 10.1021/Om0210558  0.591
2003 Martín-Vaca B, Dumitrescu A, Gornitzka H, Bourissou D, Bertrand G. Synthesis and structural characterization of unusual amido samarium(III) complexes Journal of Organometallic Chemistry. 682: 263-266. DOI: 10.1016/J.Jorganchem.2003.08.001  0.558
2003 Despagnet-Ayoub E, Gornitzka H, Bourissou D, Bertrand G. Cover Picture: (Aryl)(phosphanyl)Carbene: Ground- and Excited-State Reactions (Eur. J. Org. Chem. 11/2003) European Journal of Organic Chemistry. 2003: 2011-2011. DOI: 10.1002/Ejoc.200390223  0.515
2003 Illa O, Gornitzka H, Branchadell V, Baceiredo A, Bertrand G, Ortuño RM. Reactions of a Stable (Phosphanyl)(silyl)carbene with Aliphatic Aldehydes: [2+1] versus [2+2] Addition to a Carbonyl Group European Journal of Organic Chemistry. 2003: 3147-3152. DOI: 10.1002/Ejoc.200300226  0.383
2003 Despagnet-Ayoub E, Gornitzka H, Bourissou D, Bertrand G. (Aryl)(phosphanyl)Carbene: Ground- and Excited-State Reactions European Journal of Organic Chemistry. 2003: 2039-2042. DOI: 10.1002/Ejoc.200200657  0.556
2002 Rudzevich VL, Gornitzka H, Miqueu K, Sotiropoulos JM, Pfister-Guillouzo G, Romanenko VD, Bertrand G. The first "naked" primary phosphanide anion [ArPH](-). Angewandte Chemie (International Ed. in English). 41: 1193-5. PMID 12491256 DOI: 10.1002/1521-3773(20020402)41:7<1193::Aid-Anie1193>3.0.Co;2-X  0.739
2002 Amsallem D, Mazières S, Piquet-Fauré V, Gornitzka H, Baceiredo A, Bertrand G. A rare example of a rearrangement involving four structural isomers: alpha-phosphinonitrile/C-phosphinoketenimine/1-aza-4- phosphabutadiene/1,2-dihydro-1,2-azaphosphete. Chemistry (Weinheim An Der Bergstrasse, Germany). 8: 5305-11. PMID 12432498 DOI: 10.1002/1521-3765(20021202)8:23<5305::Aid-Chem5305>3.0.Co;2-6  0.369
2002 Despagnet E, Miqueu K, Gornitzka H, Dyer PW, Bourissou D, Bertrand G. Stable (aryl)(phosphino)carbenes: new ligands for transition metals. Journal of the American Chemical Society. 124: 11834-5. PMID 12358511 DOI: 10.1021/Ja027201I  0.707
2002 Otto M, Scheschkewitz D, Kato T, Midland MM, Lambert JB, Bertrand G. The stable pentamethylcyclopentadienyl cation remains unknown. Angewandte Chemie (International Ed. in English). 41: 2275-6. PMID 12203563 DOI: 10.1002/1521-3773(20020703)41:13<2275::Aid-Anie2275>3.0.Co;2-1  0.712
2002 Despagnet E, Gornitzka H, Rozhenko AB, Schoeller WW, Bourissou D, Bertrand G. Stable non-push-pull phosphanylcarbenes: NMR spectroscopic characterization of a methylcarbene. Angewandte Chemie (International Ed. in English). 41: 2835-7. PMID 12203501 DOI: 10.1002/1521-3773(20020802)41:15<2835::Aid-Anie2835>3.0.Co;2-8  0.511
2002 Merceron N, Miqueu K, Baceiredo A, Bertrand G. Stable (amino)(phosphino)carbenes: difunctional molecules. Journal of the American Chemical Society. 124: 6806-7. PMID 12059184 DOI: 10.1021/Ja026556Z  0.623
2002 Kato T, Gornitzka H, Baceiredo A, Schoeller WW, Bertrand G. Synthesis and rearrangement of diphosphorus analogues of amidinium salts. Journal of the American Chemical Society. 124: 2506-12. PMID 11890799 DOI: 10.1021/Ja010347H  0.414
2002 Scheschkewitz D, Amii H, Gornitzka H, Schoeller WW, Bourissou D, Bertrand G. Singlet diradicals: from transition states to crystalline compounds. Science (New York, N.Y.). 295: 1880-1. PMID 11884750 DOI: 10.1126/Science.1068167  0.763
2002 Krysiak J, Kato T, Gornitzka H, Baceiredo A, Mikolajczyk M, Bertrand G. The first asymmetric cyclopropanation reactions involving a stable carbene. The Journal of Organic Chemistry. 66: 8240-2. PMID 11722233 DOI: 10.1021/Jo010586N  0.336
2002 Buron C, Stelzig L, Guerret O, Gornitzka H, Romanenko V, Bertrand G. Synthesis and structure of 1,2,4-triazol-2-ium-5-ylidene complexes of Hg(II), Pd(II), Ni(II), Ni(0), Rh(I) and Ir(I) Journal of Organometallic Chemistry. 664: 70-76. DOI: 10.1016/S0022-328X(02)01924-1  0.32
2002 Bourissou D, Bertrand G. Diphosphorus-Containing Unsaturated Three-Membered Rings: Comparison of Carbon, Nitrogen, and Phosphorus Chemistry Topics in Current Chemistry. 220: 1-25. DOI: 10.1007/3-540-45731-3_1  0.579
2002 Dumitrescu A, Gornitzka H, Schoeller W, Bourissou D, Bertrand G. A Crystalline Phosphenium Salt Featuring the Electron-Withdrawing 2,6-Bis(trifluoromethyl)phenyl Group European Journal of Inorganic Chemistry. 2002: 1953-1956. DOI: 10.1002/1099-0682(200208)2002:8<1953::Aid-Ejic1953>3.0.Co;2-Y  0.56
2002 Dumitrescu A, Martin-Vaca B, Gornitzka H, Cazaux J, Bourissou D, Bertrand G. Zinc(II), Samarium(III) and Tin(II) Complexes Featuring a Tridentate Nitrogen Donor for the Ring-Opening Copolymerization of (D,L)-Lactide and Glycolide European Journal of Inorganic Chemistry. 2002: 1948-1951. DOI: 10.1002/1099-0682(200208)2002:8<1948::Aid-Ejic1948>3.0.Co;2-6  0.59
2001 Rudzevich VL, Gornitzka H, Romanenko VD, Bertrand G. Formation of the monoanion[Ar*P(BH3)(μ-BH2)2H]−with a symmetrically bridging hydride from the attempted synthesis of thedianion [Ar*P(BH3)3]2− Chemical Communications. 1634-1635. PMID 12240418 DOI: 10.1039/B105030N  0.317
2001 Solé S, Gornitzka H, Schoeller WW, Bourissou D, Bertrand G. (Amino)(aryl)carbenes: stable singlet carbenes featuring a spectator substituent. Science (New York, N.Y.). 292: 1901-3. PMID 11397943 DOI: 10.1126/Science.292.5523.1901  0.57
2001 Baceiredo A, Bertrand G, Dyer PW, Fawcett J, Griep-Raming N, Guerret O, Hanton MJ, Russell DR, Williamson A. The ‘one-pot’ syntheses of α,α′-diphosphino-substituted imines: a unique reaction of bulky bis(dialkylamino)chlorophosphines New Journal of Chemistry. 25: 591-596. DOI: 10.1039/B009867L  0.399
2001 Chaumonnot A, Donnadieu B, Sabo-Etienne S, Chaudret B, Buron C, Bertrand G, Metivier P. Ruthenium Carbene Complexes Containing a Triazolidene Cationic Ligand Organometallics. 20: 5614-5618. DOI: 10.1021/Om010699X  0.423
2000 Bourissou D, Guerret O, Gabbaï FP, Bertrand G. Stable Carbenes. Chemical Reviews. 100: 39-92. PMID 11749234  0.51
2000 Kato T, Gornitzka H, Baceiredo A, Schoeller WW, Bertrand G. A cyclic carbanionic valence isomer of a carbocation: diphosphino analogs of diaminocarbocations Science. 289: 754-756. PMID 10926532 DOI: 10.1126/Science.289.5480.754  0.37
2000 Buron C, Gornitzka H, Romanenko V, Bertrand G. Stable versions of transient push-pull carbenes: extending lifetimes from nanoseconds to weeks Science. 288: 834-836. PMID 10796999 DOI: 10.1126/Science.288.5467.834  0.308
2000 Bertrand G, Eisfeld W, Nyulászi L, Reau R, Regitz M, Szieberth D. Diphosphetes—substituent stabilized ring systems Journal of the Chemical Society-Perkin Transactions 1. 2324-2327. DOI: 10.1039/B002003F  0.35
2000 Gornitzka H, Hemmert C, Bertrand G, Pfeiffer M, Stalke D. Transmetalation Reaction of Dimethylzinc and (Bis(2-pyridyl)methyl)lithium Organometallics. 19: 112-114. DOI: 10.1021/Om990815K  0.399
2000 Goumri-Magnet S, Kato T, Gornitzka H, Baceiredo A, Bertrand G. Stereoselectivity and Stereospecificity of Cyclopropanation Reactions with Stable (Phosphanyl)(silyl)carbenes Journal of the American Chemical Society. 122: 4464-4470. DOI: 10.1021/Ja994408B  0.335
2000 Bertrand G, Cazaux J, Baceiredo A, Guerret O, Palacios F, Aparicio D, De Los Santos JM. Free and supported phosphorus ylides: efficient, neutral non-nucleophilic Brønsted bases with a wide utility in organic synthesis Comptes Rendus De L'AcadéMie Des Sciences - Series Iic - Chemistry. 3: 261-265. DOI: 10.1016/S1387-1609(00)00122-5  0.378
2000 Palacios F, Aparicio D, Santos JMdl, Baceiredo A, Bertrand G. Easy and Efficient Generation of Reactive Anions with Free and Supported Ylides as Neutral Brønsted Bases Tetrahedron. 56: 663-669. DOI: 10.1016/S0040-4020(99)01039-X  0.383
2000 Kato T, Polishchuk O, Gornitzka H, Baceiredo A, Bertrand G. The peculiar behavior of a diphosphirenium salt towards sodium η5-cyclopentadienyl(dicarbonyl)ferrate Journal of Organometallic Chemistry. 613: 33-36. DOI: 10.1016/S0022-328X(00)00466-6  0.348
2000 Guerret O, Solé S, Gornitzka H, Trinquier G, Bertrand G. 1,2,4-Triazolium-5-ylidene and 1,2,4-triazol-3,5-diylidene as new ligands for transition metals Journal of Organometallic Chemistry. 600: 112-117. DOI: 10.1016/S0022-328X(00)00037-1  0.308
1999 Goumri-Magnet S, Gornitzka H, Baceiredo A, Bertrand G. Synthetic Utility of Stable Phosphanylcarbenes: Synthesis and Crystal Structure of an α-(Lithiomethylene)phosphorane. Angewandte Chemie (International Ed. in English). 38: 678-680. PMID 29711539 DOI: 10.1002/(Sici)1521-3773(19990301)38:5<678::Aid-Anie678>3.0.Co;2-L  0.329
1999 Goumri-Magnet S, Polishchuk O, Gornitzka H, Marsden CJ, Baceiredo A, Bertrand G. The Electrophilic Behavior of Stable Phosphanylcarbenes Towards Phosphorus Lone Pairs Angewandte Chemie. 38: 3727-3729. PMID 10649339 DOI: 10.1002/(Sici)1521-3773(19991216)38:24<3727::Aid-Anie3727>3.0.Co;2-A  0.37
1999 Amsallem D, Gornitzka H, Baceiredo A, Bertrand G. New Types of Stable Aldehydes: Formylphosphane and Formylphosphane Oxide. Angewandte Chemie. 38: 2201-2203. PMID 10425481 DOI: 10.1002/(Sici)1521-3773(19990802)38:15<2201::Aid-Anie2201>3.0.Co;2-E  0.311
1999 Canac Y, Bourissou D, Gornitzka H, Schoeller WW, Baceiredo A, Bertrand G. 2-Π- and 3-Π-Electron Diphosphorus-Containing 3-Membered Heterocycles Phosphorus, Sulfur, and Silicon and the Related Elements. 144: 37-40. DOI: 10.1080/10426509908546176  0.563
1999 Bourissou D, Canac Y, Gornitzka H, Baceiredo A, Bertrand G. Ligand properties of 1H-diphosphirenes and diphosphirenylium salts towards iron carbonyl fragments Chemical Communications. 1535-1536. DOI: 10.1039/A904747F  0.517
1999 Bourissou D, Bertrand G. The quest for diphosphirenium and diphosphirenylium salts, diheteroatom- containing cyclopropenium analogues Accounts of Chemical Research. 32: 561-570. DOI: 10.1021/Ar9800237  0.539
1999 Bourissou D, Le Floch P, Mathey F, Bertrand G. On the way to phosphino-phosphaalkynes Comptes Rendus De L'AcadéMie Des Sciences - Series Iic - Chemistry. 2: 351-357. DOI: 10.1016/S1387-1609(00)88545-X  0.548
1999 Bourissou D, Bertrand G. The Chemistry of Phosphinocarbenes Advances in Organometallic Chemistry. 44: 175-219. DOI: 10.1016/S0065-3055(08)60622-X  0.621
1999 Bourissou D, Bertrand G. Effect of lithiation on the reactivity of diazo derivatives with sulfonylalkynes: Application to the synthesis of three isomeric trisubstituted pyrazoles Tetrahedron Letters. 40: 883-886. DOI: 10.1016/S0040-4039(98)02582-9  0.564
1999 Fauré J, Gornitzka H, Réau R, Stalke D, Bertrand G. The Dramatic Influence of Diamidoamine Ligands on the Structure and Reactivity of Low-Valent Tin and Bismuth Derivatives European Journal of Inorganic Chemistry. 1999: 2295-2299. DOI: 10.1002/(Sici)1099-0682(199912)1999:12<2295::Aid-Ejic2295>3.0.Co;2-F  0.36
1999 Bertrand G, Díez-Barra E, Fernández-Baeza J, Gornitzka H, Moreno A, Otero A, Rodríguez-Curiel RI, Tejeda J. Synthesis, Characterization and Dynamic Behavior of Mono- and Dinuclear Palladium(II) Carbene Complexes Derived From 1,1′-Methylenebis(4-alkyl-1,2,4-triazolium) Diiodides European Journal of Inorganic Chemistry. 1999: 1965-1971. DOI: 10.1002/(Sici)1099-0682(199911)1999:11<1965::Aid-Ejic1965>3.0.Co;2-K  0.413
1999 Bourissou D, Canac Y, Gornitzka H, Marsden CJ, Baceiredo A, Bertrand G. Tungsten Carbonyl Complexes of 1H-Diphosphirenes and Diphosphirenylium Salts European Journal of Inorganic Chemistry. 1999: 1479-1488. DOI: 10.1002/(Sici)1099-0682(199909)1999:9<1479::Aid-Ejic1479>3.0.Co;2-Z  0.54
1999 Wingerter S, Gornitzka H, Bertrand G, Stalke D. The Deprotonated Iminophosphoraneo-C6H4PPh2P=NSiMe3 as a Novel Chelating Ligand in Organocopper(I) and -zinc(II) Chemistry European Journal of Inorganic Chemistry. 1999: 173-178. DOI: 10.1002/(Sici)1099-0682(199901)1999:1<173::Aid-Ejic173>3.0.Co;2-T  0.406
1998 Emig N, Gabbaï FP, Krautscheid H, Réau R, Bertrand G. The Azide-Nitrilimine Analogy in Aluminum Chemistry. Angewandte Chemie (International Ed. in English). 37: 989-992. PMID 29711487 DOI: 10.1002/(Sici)1521-3773(19980420)37:7<989::Aid-Anie989>3.0.Co;2-1  0.301
1998 Canac Y, Bourissou D, Baceiredo A, Gornitzka H, Schoeller WW, Bertrand G. Isolation of a benzene valence isomer with one-electron phosphorus-phosphorus bonds Science (New York, N.Y.). 279: 2080-2. PMID 9516102 DOI: 10.1126/Science.279.5359.2080  0.543
1998 Emig N, Nguyen H, Krautscheid H, Réau R, Cazaux J, Bertrand G. Neutral and Cationic Tetracoordinated Aluminum Complexes Featuring Tridentate Nitrogen Donors:  Synthesis, Structure, and Catalytic Activity for the Ring-Opening Polymerization of Propylene Oxide and (d,l)-Lactide Organometallics. 17: 3599-3608. DOI: 10.1021/Om980401B  0.394
1998 Solé, S, Gornitzka H, Guerret O, Bertrand G. Apparent 1,2-Silyl Migrations in Aromatic Carbenes Occur by Intermolecular Silyl Exchanges Journal of the American Chemical Society. 120: 9100-9101. DOI: 10.1021/Ja980797I  0.34
1998 Piquet V, Baceiredo A, Dahan F, Bertrand G. Oxidation-induced ring expansion of a 2-phosphino-2H-azirine Comptes Rendus De L'AcadéMie Des Sciences - Series Iic - Chemistry. 1: 123-128. DOI: 10.1016/S1251-8069(97)86271-9  0.372
1998 Dahrouch M, Rivière-Baudet M, Gornitzka H, Bertrand G. Synthesis and X-ray crystal structure of bis(germyl)carbodiimides. Spectroscopic characterization of (hydrogeno)(germyl)cyanamides Journal of Organometallic Chemistry. 562: 191-195. DOI: 10.1016/S0022-328X(98)00546-4  0.332
1998 Lentz D, Anibarro M, Preugschat D, Bertrand G. Transition metal complexes and cycloaddition products of pentafluorophenyl isocyanide Journal of Fluorine Chemistry. 89: 73-81. DOI: 10.1016/S0022-1139(98)00089-X  0.376
1998 Goumri S, Leriche Y, Gornitzka H, Baceiredo A, Bertrand G. The Inferior p-Donor Ability of Phosphanyl versus Amino Substituents: Consequences on the Stability and Reactivity of Phosphanyl- and Aminocarbenes European Journal of Inorganic Chemistry. 1998: 1539-1542. DOI: 10.1002/(Sici)1099-0682(199810)1998:10<1539::Aid-Ejic1539>3.0.Co;2-W  0.391
1997 Palacios F, Pagalday J, Piquet V, Dahan F, Baceiredo A, Bertrand G. N-Phosphino- and N-Phosphonionitrilimines: From Nucleophilic to Electrophilic 1,3-Dipoles. The Journal of Organic Chemistry. 62: 292-296. PMID 11671401 DOI: 10.1021/Jo961443H  0.354
1997 Soleilhavoup M, Guerret O, Faure J, Baceiredo A, Bertrand G. EVIDENCE FOR A TRANSIENT ACYLPHOSPHENIUM ION Phosphorus, Sulfur, and Silicon and the Related Elements. 123: 161-167. DOI: 10.1080/10426509708044205  0.308
1997 Bourissou D, Canac Y, Collado MI, Baceiredo A, Bertrand G. New routes to free and coordinated 1H-diphosphirenes Chemical Communications. 2399-2400. DOI: 10.1039/A706688K  0.549
1997 Bourissou D, Canac Y, Collado MI, Baceiredo A, Bertrand G. Synthesis and reactivity of a stable η2-(diphosphirenylium)(W(CO)5 complex Journal of the American Chemical Society. 119: 9923-9924. DOI: 10.1021/Ja971973A  0.583
1997 Sanchez M, Réau R, Gornitzka H, Dahan F, Regitz M, Bertrand G. 1σ4,2σ(x)-diphosphetes (x = 2-6): On the persistence of the P-P bond Journal of the American Chemical Society. 119: 9720-9728. DOI: 10.1021/Ja971821F  0.316
1997 Fauré J, Réau R, Wong MW, Koch R, Wentrup C, Bertrand G. Nitrilimines:  Evidence for the Allenic Structure in Solution, Experimental andAb InitioStudies of the Barrier to Racemization, and First Diastereoselective [3 + 2]-Cycloaddition Journal of the American Chemical Society. 119: 2819-2824. DOI: 10.1021/Ja9637661  0.38
1997 and OG, Bertrand G. Trigonal Planar Phosphorus Cations Accounts of Chemical Research. 30: 486-493. DOI: 10.1021/Ar970061A  0.334
1997 Piquet V, Baceiredo A, Gornitzka H, Dahan F, Bertrand G. The Stable (Phosphino)(Silyl)Carbene As A Useful Building Block: Synthesis And Reactivity of 2-Phosphorus-Substituted 2H-Azirines Chemistry - a European Journal. 3: 1757-1764. DOI: 10.1002/Chem.19970031106  0.318
1996 Alcaraz G, Baceiredo A, Nieger M, Schoeller WW, Bertrand G. X-ray Crystal Structure, ab Initio Calculations, and Reactivity of 1,3,2lambda(5)-Diazaphosphetes: A New Type of 4-pi-Electron 4-Membered Heterocycle. Inorganic Chemistry. 35: 2458-2462. PMID 11666457 DOI: 10.1021/Ic951474F  0.305
1996 Dyer P, Baceiredo A, Bertrand G. Synthesis of Stable Multifunctional C-Phosphonio Phosphorus Vinyl Ylides. Inorganic Chemistry. 35: 46-50. PMID 11666162 DOI: 10.1021/Ic950628O  0.334
1996 Dubau-Assibat N, Baceiredo A, Bertrand G. Synthesis and Reactivity of the First Spectroscopically Observed 1H-Diazirine Journal of the American Chemical Society. 118: 5216-5220. DOI: 10.1021/Ja960491G  0.367
1996 Emig N, Réau R, Krautscheid H, Fenske D, Bertrand G. Synthesis and Structure of the First Chiral Tetracoordinated Aluminum Cation Journal of the American Chemical Society. 118: 5822-5823. DOI: 10.1021/Ja953700Q  0.326
1996 Alcaraz G, Piquet V, Baceiredo A, Dahan F, and WWS,, Bertrand G. Mechanism of the exchange reaction of halodiazirines with nucleophiles revisited. Synthesis of neutral, mono- or dicationic 4-16-membered phosphorus heterocycles Journal of the American Chemical Society. 118: 1060-1065. DOI: 10.1021/Ja9532143  0.401
1996 Bieger K, Bouhadir G, Réau R, Dahan F, Bertrand G. Ligand Behavior of a (Z)-Phosphazide (a 1,2,3,4λ5-Triazaphosphinine) and of the Corresponding Phosphazene (a 1,2λ5-Azaphosphete) Journal of the American Chemical Society. 118: 1038-1044. DOI: 10.1021/Ja9531440  0.414
1996 Canac Y, Baceiredo A, Gornitzka H, Stalke D, Bertrand G. Synthesis of a Cationic 1,3-Diphospha-2,4-dipallada(II)tricyclo[1.1.1]pentane Derivative: The First Structurally Characterized Pyramidalμ2-Phosphinidene Angewandte Chemie International Edition in English. 34: 2677-2679. DOI: 10.1002/Anie.199526771  0.318
1996 Goumri S, Lacassin F, Baceiredo A, Bertrand G. Synthesis and multinuclear NMR characterization of iminophosphoranyl phosphines and silanes Heteroatom Chemistry. 7: 403-408. DOI: 10.1002/(Sici)1098-1071(199611)7:6<403::Aid-Hc1>3.0.Co;2-9  0.359
1995 Canac Y, Soleilhavoup M, Ricard L, Baceiredo A, Bertrand G. Addition of a Diphosphirenium Salt to Palladium(0) Complexes: The First Examples of Diphosphametallacyclobutenes Organometallics. 14: 3614-3616. DOI: 10.1021/Om00008A003  0.371
1995 Cowley AH, Gabbaï FP, Bertrand G, Carrano CJ, Bond MR. Structural investigation into the suprising stability of free and complexed bis(amino) phosphine azides Journal of Organometallic Chemistry. 493: 95-99. DOI: 10.1016/0022-328X(95)91149-E  0.351
1995 Bouhadir G, Reed RW, Réau R, Bertrand G. Synthesis of onio‐, dionio‐, and trionio‐substituted phosphines; the nucleophilic behavior of DBN and DBU toward main group electrophiles Heteroatom Chemistry. 6: 371-375. DOI: 10.1002/Hc.520060415  0.388
1995 Alcaraz G, Wecker U, Baceiredo A, Dahan F, Bertrand G. Synthesis of a 2H-Azirine by[1+ 2] Cycloaddition of a Phosphinocarbene with a Nitrile and Its Ring-Expansion to a 1,2λ5-Azaphosphete Angewandte Chemie International Edition in English. 34: 1246-1248. DOI: 10.1002/Anie.199512461  0.305
1994 Reau R, Baceiredo A, Bertrand G. Synthesis and Reactivity of Cyclic 4-π Electron Ylides: Non-Antiaromatic Inorganic Ring Systems Phosphorus, Sulfur, and Silicon and the Related Elements. 93: 1-12. DOI: 10.1080/10426509408021795  0.365
1994 Dubau N, Arthur M, Dahan F, Baceiredo A, Bertrand G. Effects of a Strong Electron-Withdrawing N-Boryl Substituent on the Stability of Nitrilimines: Surprising Dimerization Involving the Nitrilimine Heteroatom Substituents with Formation of (Fused) Bicyclic [3.3.0] and [4.3.0] Derivatives Organometallics. 13: 2913-2916. DOI: 10.1021/Om00019A059  0.353
1994 Leue C, Reau R, Neumann B, Stammler H, Jutzi P, Bertrand G. Preparation of Mono- and Bis(germyl)nitrilimines from Germylenes and Stannyl Diazo Derivatives Organometallics. 13: 436-438. DOI: 10.1021/Om00014A014  0.348
1994 Bieger K, Tejeda J, Reau R, Dahan F, Bertrand G. Synthesis and Reactivity of Cyclic 6-Membered Six-.pi.- and Four-Membered Four-.pi. Electron Ylides Journal of the American Chemical Society. 116: 8087-8094. DOI: 10.1021/Ja00097A015  0.313
1994 Soleilhavoup M, Canac Y, Polozov AM, Baceiredo A, Bertrand G. Synthesis and Rearrangement of Intramolecularly Stabilized 1.sigma.2,3.sigma.2-Diphosphaallylic Cations into Intramolecularly Stabilized 1.sigma.1,3.sigma.3-Diphosphaallylic Cations Journal of the American Chemical Society. 116: 6149-6152. DOI: 10.1021/Ja00093A012  0.321
1994 Alcaraz G, Baceiredo A, Nieger M, Bertrand G. Evidence for Imidoylnitrene Intermediates in the Reaction of Bromophenyldiazirine with Phosphines: First Ring-Expansion Reaction of a Diazirine Journal of the American Chemical Society. 116: 2159-2160. DOI: 10.1021/Ja00084A072  0.315
1994 Bertrand G. Phosphorous Chemistry: Introduction Chemical Reviews. 94: 1161-1162. DOI: 10.1021/Cr00029A600  0.302
1994 Bertrand G, Reed R. λ3-Phosphinocarbenes λ5-phosphaacetylenes Coordination Chemistry Reviews. 137: 323-355. DOI: 10.1016/0010-8545(94)03005-B  0.324
1994 Cowley AH, Gabbaï FP, Carrano CJ, Mokry LM, Bond MR, Bertrand G. Reactivity of a Phosphanylcarbene(λ5-Phosphaacetylene) with Lewis Acids: X-Ray Crystal Structures of the First Carbene-Gallane Complex andC-Gallyl-Substituted Phosphorus Ylide Angewandte Chemie International Edition in English. 33: 578-580. DOI: 10.1002/Anie.199405781  0.321
1993 Rolland H, Potin P, Majoral J, Bertrand G. Use of Tin Derivatives for the Synthesis of Polyphosphazenes Featuring Phosphorus-Carbon Bonds Phosphorus, Sulfur, and Silicon and the Related Elements. 76: 211-214. DOI: 10.1080/10426509308032396  0.377
1993 Soleilhavoup M, Alcaraz G, Reau R, Bachredo A, Bertrand G. Phosphanylcarbenes: From Unstable Intermediates to X-Ray Characterized Compounds Phosphorus, Sulfur, and Silicon and the Related Elements. 76: 49-52. DOI: 10.1080/10426509308032355  0.309
1993 Alcaraz G, Reed R, Baceiredo A, Bertrand G. Synthesis and evolution of phosphanylcarbene–borane adducts Journal of the Chemical Society, Chemical Communications. 1354-1355. DOI: 10.1039/C39930001354  0.367
1993 Reau R, Reed RW, Dahan F, Bertrand G. Transition metal complexes featuring a diazo group on a ligand: x-ray crystal structure of manganese complex [exo-(Me3SiCN2)-.eta.5-C6H6]Mn (CO)3 Organometallics. 12: 1501-1502. DOI: 10.1021/Om00029A006  0.342
1992 Arthur M, Baceiredo A, Fischer J, Cian AD, Bertrand G. Substitution Reactions at Nitrilimine Skeletons Synthesis. 1992: 43-45. DOI: 10.1055/S-1992-34175  0.356
1992 Soleilhavoup M, Baceiredo A, Dahan F, Bertrand G. Photochemical behavior of thioxophosphoranyl diazo compounds: evidence for transient .lambda.5-phosphathiirenes and for structural isomerizations of the diazo group Inorganic Chemistry. 31: 1500-1504. DOI: 10.1021/Ic00034A034  0.329
1992 Réau R, Veneziani G, Dahan F, Bertrand G. Eine einfache Synthese von Nitriliminen; Röntgenstrukturanalyse eines nicht durch Heteroatomsubstituenten stabilisierten Nitrilimins Angewandte Chemie. 104: 481-482. DOI: 10.1002/Ange.19921040430  0.317
1991 Castan F, Baceiredo A, Bigg D, Bertrand G. Synthesis and reactivity of stable silyl-substituted nitrilimines Journal of Organic Chemistry. 56: 1801-1807. DOI: 10.1021/Jo00005A026  0.398
1991 Locquenghien KHv, Baceiredo A, Boese R, Bertrand G. New synthesis and first x-ray crystal study of a C-borylated phosphorus ylide Journal of the American Chemical Society. 113: 5062-5063. DOI: 10.1021/Ja00013A053  0.334
1991 Rolland H, Ocando-Mavarez E, Potin P, Majoral JP, Bertrand G. Preparation of novel low-coordinate chloro and azido phosphorus-nitrogen compounds. Attempted synthesis of cyclodiphosphazenes Inorganic Chemistry. 30: 4095-4098. DOI: 10.1021/Ic00021A025  0.338
1991 Castan F, Granier M, Baceiredo A, Bertrand G, Straw TA, Dillon KB. Stable N‐Phosphanyl Nitrilimines: Reactivity on the Periphery of the Nitrilimine Skeleton Chemische Berichte. 124: 1739-1746. DOI: 10.1002/Cber.19911240812  0.396
1990 Bertrand G, Igau A, Baceireco A, Grutzmacher H. Synthesis and Reactivity of the First Stable λ5-Phosphaacetylene Phosphorus Sulfur and Silicon and the Related Elements. 301-304. DOI: 10.1080/10426509008038965  0.67
1990 Baceiredq A, Granier M, Castan F, Sotiropoulos JM, Bertrand G. Use of Phosphorus for Stabilizing Highly Reactive Organic Species: Nitrileimines and Pseudo-Diazoalkenes Phosphorus Sulfur and Silicon and the Related Elements. 131-134. DOI: 10.1080/10426509008038924  0.326
1990 Menu M, Dartiguenave Y, Dartiguenave M, Baceiredo A, Bertrand G. STEREOSPECIFIC FORMATION OF A 1,2λ3 -AZAPHOSPETANE IN THE THERMOLYSIS OF BIS[BIS(DIISOPROPYLAMINO)PHOSPHANYL] DIAZOMETHANE Phosphorus, Sulfur, and Silicon and the Related Elements. 47: 327-334. DOI: 10.1080/10426509008037986  0.364
1990 Granier M, Baceiredo A, Dartiguenave Y, Dartiguenave M, Menu MJ, Bertrand G. Synthesis and reactivity of stable phosphorus-substituted nitrilimines. X-ray crystal structure of C-[bis(diisopropylamino)thioxophosphoranyl]-N-[bis(diisopropylamino)phosphanyl]nitrilimine Journal of the American Chemical Society. 112: 6277-6285. DOI: 10.1021/Ja00173A014  0.363
1990 Granier M, Baceiredo A, Grützmacher H, Pritzkow H, Bertrand G. Nachweis einer Nitrilimin-Imidoylnitren-Umlagerung: Röntgenstrukturanalyse eines ungewöhnlichen Nitren-Komplexes Angewandte Chemie. 102: 671-672. DOI: 10.1002/Ange.19901020608  0.621
1989 Sicard G, Gruetzmacher H, Baceiredo A, Fischer J, Bertrand G. Evidence for .alpha.-phosphanyl-.alpha.'-sulfinylcarbene to .alpha.-phosphoranyl-.alpha.'-sulfanylcarbene rearrangement. Synthesis of 2-oxo- and 2-thioxo-1,2-.lambda.5-azaphosphetanes The Journal of Organic Chemistry. 54: 4426-4430. DOI: 10.1021/Jo00279A035  0.301
1989 Igau A, Baceiredo A, Gruetzmacher H, Pritzkow H, Bertrand G. Synthesis, reactivity, and crystal structure of the first methylenephosphonium ion: a severely twisted valence isoelectronic olefin Journal of the American Chemical Society. 111: 6853-6854. DOI: 10.1021/Ja00199A062  0.339
1989 Boeske J, Niecke E, Nieger M, Ocando E, Majoral JP, Bertrand G. Reactivity of phosphonitriles with low-coordinated phosphorus double-bonded compounds Inorganic Chemistry. 28: 499-504. DOI: 10.1021/Ic00302A024  0.344
1989 Castan F, Baceiredo A, Bertrand G. A DistillableC- andN-Silylated Nitrile Imine Angewandte Chemie International Edition in English. 28: 1250-1251. DOI: 10.1002/Anie.198912501  0.375
1989 Igau A, Baceiredo A, Trinquier G, Bertrand G. [Bis(diisopropylamino)phosphino]trimethylsilylcarbene: A Stable Nucleophilic Carbene Angewandte Chemie International Edition in English. 28: 621-622. DOI: 10.1002/Anie.198906211  0.428
1989 Igau A, Baceiredo A, Trinquier G, Bertrand G. [Bis(diisopropylamino)phosphino]trimethylsilyl-carben: Ein stabiles nucleophiles Carben Angewandte Chemie. 101: 617-618. DOI: 10.1002/Ange.19891010513  0.352
1988 Menu MJ, Crocco G, Dartiguenave M, Dartiguenave Y, Bertrand G. Reactivity of Rh(PMe3)4Cl with lithium derivatives of phosphorus-substituted diazomethanes. First evidence for a transient nitrogen-transition-metal nitrile imine. X-ray structure of [cyclic] (PMe3)2RhNBuNCHP(N-iso-Pr2)2 Organometallics. 7: 2231-2233. DOI: 10.1021/Om00100A025  0.36
1988 Igau A, Grutzmacher H, Baceiredo A, Bertrand G. Analogous .alpha.,.alpha.'-bis-carbenoid, triply bonded species: synthesis of a stable .lambda.3-phosphino carbene-.lambda.5-phosphaacetylene Journal of the American Chemical Society. 110: 6463-6466. DOI: 10.1021/Ja00227A028  0.63
1988 Sicard G, Baceiredo A, Bertrand G. Synthesis and reactivity of a stable nitrile imine Journal of the American Chemical Society. 110: 2663-2664. DOI: 10.1021/Ja00216A058  0.358
1988 Granier M, Baceiredo A, Bertrand G. First Direct Evidence for Nitrile Imine-Diazo Isomerization. Synthesis of Relatively StableN-Silylated Nitrile Imines Angewandte Chemie International Edition in English. 27: 1350-1351. DOI: 10.1002/Anie.198813501  0.353
1988 Granier M, Baceiredo A, Bertrand G. Erster direkter Nachweis einer Nitrilimin-Diazo-Isomerisierung und Synthese relativ stabilerN-silylierter Nitrilimine Angewandte Chemie. 100: 1397-1398. DOI: 10.1002/Ange.19881001020  0.335
1987 Bertrand G, Brceiredo A, Sicard G, Granier M. Triple-Bonded-Like Tricoordinated Phosphorus Species P= Phosphorous and Sulfur and the Related Elements. 30: 353-356. DOI: 10.1080/03086648708080593  0.31
1987 Menu MJ, Desrosiers P, Dartiguenave M, Dartiguenave Y, Bertrand G. Reaction of the (trimethylsilyl)diazomethane anion with metal complexes: synthesis and x-ray study of iodomethyltris(trimethylphosphine)rhodium(III) (trimethylsilyl)diazomethane, RhICH3(PMe3)3{C(N2)SiMe3} Organometallics. 6: 1822-1824. DOI: 10.1021/Om00151A039  0.39
1987 Sotiropoulos JM, Baceiredo A, Bertrand G. Synthesis and reactivity of diazomethylenephosphoranes (P=C=N2). New phosphacumulene ylides and first stable pseudo-unsaturated diazo derivatives Journal of the American Chemical Society. 109: 4711-4712. DOI: 10.1021/Ja00249A039  0.337
1987 Boeske J, Ocando-Mavarez E, Niecke E, Majoral JP, Bertrand G. Synthesis and electrocyclic ring opening of 1,3,2.lambda.3,4.lambda.5-diazadiphosphetenes Journal of the American Chemical Society. 109: 2822-2823. DOI: 10.1021/Ja00243A044  0.303
1986 Baceiredo A, Igau A, Bertrand G, Menu MJ, Dartiguenave Y, Bonnet JJ. Phosphinocarbene-phosphaalkene rearrangement and intramolecular Wittig-like reaction involving a phosphorus vinyl ylide. Journal of the American Chemical Society. 108: 7868-7869. PMID 22283319 DOI: 10.1021/Ja00284A081  0.328
1986 Majoral J, Bertrand G, Baceiredo A, Mavarez EO. PHOSPHORUS-NITROGEN TRIPLE-BONDED SPECIES Phosphorous and Sulfur and the Related Elements. 27: 75-80. DOI: 10.1080/03086648608072760  0.302
1986 Boeske J, Niecke E, Ocando-Mavarez E, Majoral JP, Bertrand G. Phosphonitriles: versatile intermediates Inorganic Chemistry. 25: 2695-2698. DOI: 10.1002/Chin.198649241  0.326
1986 Caminade AM, Ocando E, Majoral JP, Cristante M, Bertrand G. First example of prototropism in iminobis(phosphines) induced by phosphorus alkylation Inorganic Chemistry. 25: 712-714. DOI: 10.1002/Chin.198628255  0.303
1986 WEBER WP, KAZOURA SA, MANUEL G, BERTRAND G. ChemInform Abstract: Unsaturated Reactive Intermediates in Organosilicon Chemistry - Recent Results Chemischer Informationsdienst. 17. DOI: 10.1002/Chin.198626351  0.34
1985 Baceiredo A, Bertrand G, Majoral J, Dillon KB. The reactions of some azides with an anionic phosphorus(III) complex Journal of the Chemical Society, Chemical Communications. 562-563. DOI: 10.1039/C39850000562  0.352
1985 Ocando E, Majid S, Pierre Majoral J, Baceiredo A, Bertrand G. Azides of heavier main group elements: The reluctance of phosphine azides to undergo a curtius-type rearrangement Polyhedron. 4: 1667-1668. DOI: 10.1016/S0277-5387(00)87245-9  0.338
1985 Baceiredo A, Bertrand G, Majoral J-, Dillon KB. The Reactions Of Some Azides With An Anionic Phosphorus(Iii) Complex Cheminform. 16. DOI: 10.1002/Chin.198533298  0.364
1985 NAKAZAWA H, BUHRO WE, BERTRAND G, GLADYSZ JA. ChemInform Abstract: REACTIONS OF PHOSPHORUS ELECTROPHILES WITH ((η5-C5ME5)FE(CO)2)-; SPECTROSCOPIC EVIDENCE FOR A PHOSPHINIDENE COMPLEX Chemischer Informationsdienst. 16. DOI: 10.1002/Chin.198507295  0.319
1983 Veith M, Huch V, Majoral J, Bertrand G, Manuel G. Stannylene and germylene as powerful dechlorinated reagents. New route to diphosphene. Tetrahedron Letters. 24: 4219-4222. DOI: 10.1016/S0040-4039(00)88305-7  0.313
1982 Bertrand G, Couret C, Escudie J, Majid S, Majoral J. A new route to bis(2,4,6-tri-tert-butylphenyl)diphosphene via silylated compound Tetrahedron Letters. 23: 3567-3570. DOI: 10.1016/S0040-4039(00)87671-6  0.322
1982 BERTRAND G, DUBAC J, MAZEROLLES P, ANCELLE J. ChemInform Abstract: FIRST ASYMMETRIC SYNTHESIS OF FUNCTIONALIZED MONOAROMATIC OR NONAROMATIC SILANES FROM PROCHIRAL SILAETHYLENES Chemischer Informationsdienst. 13. DOI: 10.1002/Chin.198252273  0.57
1982 BERTRAND G, TRINQUIER G, MAZEROLLES P. ChemInform Abstract: THE SILICON-CARBON DOUBLE BOND. A SURVEY OF RECENT EXPERIMENTAL AND THEORETICAL RESULTS Chemischer Informationsdienst. 13. DOI: 10.1002/Chin.198223263  0.507
1982 Baceiredo A, Bertrand G, Mazerolles P, Majoral J-. Surprising Reactivity Of Very Crowded Phosphinic Derivatives Cheminform. 13. DOI: 10.1002/Chin.198213257  0.583
1981 Baceiredo A, Bertrand G, Mazerolles P, Majoral J. Surprising reactivity of very crowded phosphinic derivatives Journal of the Chemical Society, Chemical Communications. 1197-1198. DOI: 10.1039/C39810001197  0.595
1981 Baceiredo A, Bertrand G, Mazerolles P. Photolytic rearrangement of germanium azides. Evidence for transient germa-imines Tetrahedron Letters. 22: 2553-2556. DOI: 10.1016/S0040-4039(01)90518-0  0.577
1981 Bertrand G, Manuel G, Mazerolles P, Trinquier G. Le probleme de la conjugaison a travers un atome de silicium π-lie dans les systemes sila-2 butadieniques Tetrahedron. 37: 2875-2880. DOI: 10.1016/S0040-4020(01)92358-0  0.517
1981 Bertrand G, Mazerolles P, Ancelle J. Le rearrangement de claisen en series siliciee et germaniee: silaethylene et germaethylene Tetrahedron. 37: 2459-2466. DOI: 10.1016/S0040-4020(01)88902-X  0.552
1981 Manuel G, Bertrand G, Mazerolles P, Ancelle J. Isomerisations thermiques originales de composes β-chlores du silicium induites par un groupe β′-ethylenique Journal of Organometallic Chemistry. 212: 311-323. DOI: 10.1016/S0022-328X(00)85657-0  0.576
1981 MANUEL G, BERTRAND G, MAZEROLLES P, ANCELLE J. ChemInform Abstract: FIRST THERMAL ISOMERIZATIONS OF β-CHLORO SILICON COMPOUNDS INDUCED BY A β-VINYL GROUP Chemischer Informationsdienst. 12. DOI: 10.1002/Chin.198141241  0.531
1980 Bertrand G, Dubac J, Mazerolles P, Ancelle J. Asymmetric induction at silicon from prochiral silaethylenes Journal of the Chemical Society, Chemical Communications. 382-383. DOI: 10.1039/C39800000382  0.55
1979 Ancelle J, Bertrand G, Joanny M, Mazerolles P. Glaisen rearrangement in the silicon series. Tetrahedron Letters. 20: 3153-3156. DOI: 10.1016/S0040-4039(01)95346-8  0.582
1978 Bertrand G, Manuel G, Mazerolles P. Delocalisation a travers un atome de silicum. Formation d'un ion silicenium au cours du piegeage du methyl-2 sila-2butadiene-1,3 Tetrahedron Letters. 19: 2149-2152. DOI: 10.1016/S0040-4039(01)86830-1  0.53
1978 Bertrand G, Manuel G, Mazerolles P. Syntheses et rearrangements thermiques de sila-1 et sila-2 dichloro-6,6 bicyclo[3.1.0]hexanes Journal of Organometallic Chemistry. 144: 303-315. DOI: 10.1016/S0022-328X(00)84089-9  0.607
1978 Manuel G, Bertrand G, Mazerolles P. Synthese et rearrangements de cycles α-fonctionnels du germanium: oxa-6 diphenyl-2,2 germa-2 bicyclo[3.1.0] hexane et diphenyl-1,1 germa-1 cyclopentanol-2. etude comparative avec les derives isologues du silicium Journal of Organometallic Chemistry. 146: 7-16. DOI: 10.1016/S0022-328X(00)83746-8  0.584
1978 Bertrand G, Manuel G, Mazerolles P. Hypotheses sur la formation par pyrolyse du premier intermediaire a silicium digonal Tetrahedron. 34: 1951-1956. DOI: 10.1016/0040-4020(78)80102-1  0.52
1978 BERTRAND G, MANUEL G, MAZEROLLES P. ChemInform Abstract: DELOCALIZATION ACROSS A SILICON ATOM. FORMATION OF A SILICENIUM ION IN THE TRAPPING OF 2-METHYL-2-SILA-1,3-BUTADIENE Chemischer Informationsdienst. 9. DOI: 10.1002/Chin.197846290  0.535
1978 MANUEL G, BERTRAND G, MAZEROLLES P. ChemInform Abstract: SYNTHESIS AND REARRANGEMENTS OF α-FUNCTIONAL RINGS OF GERMANIUM- 6-OXA-2,2-DIPHENYL-2-GERMABICYCLO(3.1.0)HEXANE AND 1,1-DIPHENYL-1-GERMACYCLOPENTAN-2-OL. COMPARATIVE STUDY WITH ISOLOGOUS DERIVATIVES OF SILICON Chemischer Informationsdienst. 9. DOI: 10.1002/Chin.197823271  0.581
1978 BERTRAND G, MANUEL G, MAZEROLLES P. ChemInform Abstract: SYNTHESES AND THERMAL REARRANGEMENTS OF 2-SILA- AND 3-SILA-6,6-DICHLOROBICYCLO(3.1.0)HEXANES Chemischer Informationsdienst. 9. DOI: 10.1002/Chin.197817247  0.558
Low-probability matches (unlikely to be authored by this person)
1993 Auner N, Weingartner AW, Bertrand G. Silaheterocyclen, XXIII. Synthese und Thermolyseverhalten von Si-funktionellen 2-Silaazetidinen Chemische Berichte. 126: 581-589. DOI: 10.1002/Cber.19931260306  0.3
1995 Armbrust R, Sanchez M, Reau R, Bergstraesser U, Regitz M, Bertrand G. Synthesis of a Stable 1.lambda.5,2.lambda.3-Diphosphete: the First Codimer of a .lambda.3-Phosphaalkyne with a .lambda.5-Phosphaalkyne Journal of the American Chemical Society. 117: 10785-10786. DOI: 10.1021/Ja00148A038  0.299
2009 Dyker CA, Bertrand G. Chemical bonding: Rethinking carbon. Nature Chemistry. 1: 265-6. PMID 21378867 DOI: 10.1038/Nchem.265  0.298
1989 Menu M, Dartiguenave M, Dartiguenave Y, Bonnet J, Bertrand G, Baceiredo A. First structural characterization of an α-diazophosphane: crystal structure of bis[bis(diisopropylamino)phosphanyl]diazomethane [(i-Pr2N)2P]2CN2 Journal of Organometallic Chemistry. 372: 201-206. DOI: 10.1016/0022-328X(89)87094-9  0.298
2013 Martin D, Lassauque N, Steinmann F, Manuel G, Bertrand G. Experimental and computational studies of anti-Bredt amidinium salts. Chemistry (Weinheim An Der Bergstrasse, Germany). 19: 14895-901. PMID 24105742 DOI: 10.1002/Chem.201302474  0.298
1984 Nakazawa H, Buhro WE, Bertrand G, Gladysz JA. Reactions of phosphorus electrophiles with [(.eta.5-C5Me5)Fe(CO)2]-; spectroscopic evidence for a phosphinidene complex Inorganic Chemistry. 23: 3431-3433. DOI: 10.1021/Ic00190A001  0.297
1991 Sotiropoulos J, Baceiredo A, von Locquenghien KH, Dahan F, Bertrand G. Reactivity of a(Diazomethylene)phosphorane with Alkylating Agents and Lewis Acids; Synthesis of the Firstα-Diazoalkylborates Angewandte Chemie International Edition in English. 30: 1154-1156. DOI: 10.1002/Anie.199111541  0.297
1991 Locquenghien KHv, Réau R, Bertrand G. The first nitrogen NMR spectroscopic study of nitrile imides (nitrilimines) Journal of the Chemical Society, Chemical Communications. 12: 1192-1193. DOI: 10.1039/C39910001192  0.296
1998 Bertrand G. Ylidische viergliedrige Vier-π-Elektronen-λ5-Phosphorheterocyclen: elektronische Heterocyclobutadien-Isomere Angewandte Chemie. 110: 282-293. DOI: 10.1002/(Sici)1521-3757(19980202)110:3<282::Aid-Ange282>3.0.Co;2-R  0.296
1983 Manuel G, Bertrand G, El Anba F. An improved synthesis of key intermediates in metallole Group IVB chemistry Organometallics. 2: 391-394. DOI: 10.1021/Om00075A007  0.295
2000 Kato T, Gornitzka H, Baceiredo A, Bertrand G. Synthesis, Structure, and Reactivity of a 1σ4,3σ2‐Diphosphaallene Angewandte Chemie. 39: 3319-3321. PMID 11028090 DOI: 10.1002/1521-3773(20000915)39:18<3319::Aid-Anie3319>3.0.Co;2-M  0.295
2004 Krysiak J, Lyon C, Baceiredo A, Gornitzka H, Mikolajczyk M, Bertrand G. Stable optically pure phosphino(silyl)carbenes: reagents for highly enantioselective cyclopropanation reactions. Chemistry (Weinheim An Der Bergstrasse, Germany). 10: 1982-6. PMID 15079838 DOI: 10.1002/Chem.200305722  0.295
2002 Merceron N, Baceiredo A, Gornitzka H, Bertrand G. C-phosphanyl-C-chloroiminium salts as electrophilic carbene synthetic equivalents. Chemical Communications (Cambridge, England). 2250-1. PMID 12398001 DOI: 10.1039/B206641F  0.294
2014 Ruiz DA, Melaimi M, Bertrand G. An efficient synthetic route to stable bis(carbene)borylenes [(L1)(L2)BH]. Chemical Communications (Cambridge, England). 50: 7837-9. PMID 24909943 DOI: 10.1039/C4Cc03497J  0.292
1988 Menu MJ, Crocco G, Dartiguenave M, Dartiguenave Y, Bertrand G. Synthesis of N-bonded diazoalkane complexes via the reaction of the trimethylsilyldiazomethane anion with M(CO)5PPh3(M = Cr; W): X-ray structure of W(CO)4(PPh3)[N2C(SiMe3)2] Journal of the Chemical Society, Chemical Communications. 1598-1599. DOI: 10.1039/C39880001598  0.291
1987 Ocando-mavarez E, Böske J, Niecke E, Majoral J, Bertrand G. Phosphonitriles: Powerful Intermediates in Heterocyclic Chemistry Phosphorus and Sulfur and the Related Elements. 30: 797-797. DOI: 10.1080/03086648708079289  0.29
1985 Baceiredo A, Bertrand G, Sicard G. Synthesis of the first .alpha.-diazophosphines. Phosphorous-carbon multiple-bond character of phosphinocarbenes Journal of the American Chemical Society. 107: 4781-4783. DOI: 10.1021/Ja00302A032  0.29
1996 Sanchez M, Réau R, Dahan F, Regitz M, Bertrand G. From 1σ4, 2σ2 to 1σ4, 2σn-Diphosphetes (n= 3–6): The Surprising Persistence of the PP bond Angewandte Chemie International Edition in English. 35: 2228-2230. DOI: 10.1002/Anie.199622281  0.289
1993 Rolland H, Potin P, Majoral JP, Bertrand G. Straightforward synthesis of polyallylphosphazenes from poly(dichlorophosphazene) Inorganic Chemistry. 32: 4679-4680. DOI: 10.1021/Ic00074A005  0.289
2022 Serrato MR, Melaimi M, Bertrand G. Cyclic (amino)(barrelene)carbenes: an original family of CAACs through a novel synthetic pathway. Chemical Communications (Cambridge, England). 58: 7519-7521. PMID 35699417 DOI: 10.1039/d2cc02565e  0.288
1984 Mulliez M, Majoral J, Bertrand G. First evidence for a curtius type rearrangement involving a charged atom. An easy synthesis of an iminophosphonium salt Journal of the Chemical Society, Chemical Communications. 284-285. DOI: 10.1039/C39840000284  0.288
1992 Soleilhavoup M, Baceiredo A, Treutler O, Ahlrichs R, Nieger M, Bertrand G. Synthesis and x-ray crystal structure of [(iso-Pr2N)2P(H)CP(N-iso-Pr2)2]+CF3SO3-: a carbene, a cumulene, or a phosphaacetylene? Journal of the American Chemical Society. 114: 10959-10961. DOI: 10.1021/Ja00053A042  0.288
1990 Granier M, Baceiredo A, Nieger M, Bertrand G. AnN-PhosphinoC-ThiophosphinoyI Nitrilimine as a Formal 1,4 Dipole: Synthesis of 1,2,3λ5-Diaza- and 1,2,4,3λ5-Triazaphosphinines Angewandte Chemie International Edition in English. 29: 1123-1125. DOI: 10.1002/Anie.199011231  0.283
1990 Granier M, Baceiredo A, Grüzmacher H, Pritzkow H, Bertrand G. Direct Evidence for a Nitrile Imine–Imidoylnitrene Rearrangement: X-Ray Crystal Structure of an Unusual Nitrene Complex Angewandte Chemie International Edition in English. 29: 659-661. DOI: 10.1002/Anie.199006591  0.282
2004 Bertrand G. Modern Arene Chemistry: Concepts, Synthesis and Applications. Edited by Didier Astruc Advanced Synthesis & Catalysis. 346: 584-584. DOI: 10.1002/Adsc.200404083  0.281
1992 Réau R, Veneziani G, Dahan F, Bertrand G. A Straightforward Synthesis of Nitrilimines; X-Ray Crystal Structure of a Nitrilimine Stabilized by Non-Heteroatom Substituents Angewandte Chemie International Edition in English. 31: 439-440. DOI: 10.1002/Anie.199204391  0.28
1986 Baceiredo A, Bertrand G. α-Diazophosphines Stables Analogie γ3-Phosphinocarbene/γ5-Phosphaacetylene Phosphorous and Sulfur and the Related Elements. 26: 57-62. DOI: 10.1080/03086648608084570  0.278
2005 Martin D, Baceiredo A, Gornitzka H, Schoeller WW, Bertrand G. A stable P-heterocyclic carbene. Angewandte Chemie (International Ed. in English). 44: 1700-3. PMID 15712311 DOI: 10.1055/S-2005-865379  0.277
1984 Mulliez M, Majoral J‐, Bertrand G. First Evidence For A Curtius-Type Rearrangement Involving A Charged Atom. An Easy Synthesis Of An Iminophosphonium Salt Cheminform. 15. DOI: 10.1002/Chin.198427098  0.277
1991 Granier M, Baceiredo A, Huch V, Veith M, Bertrand G. X-ray crystal structure and reactivity of an N-phosphonio-substituted nitrilimine: a stable electrophilic nitrilimine Inorganic Chemistry. 30: 1161-1162. DOI: 10.1021/Ic00006A001  0.275
1995 Alcaraz G, Wecker U, Baceiredo A, Dahan F, Bertrand G. Synthese eines 2H-Azirins durch [1 + 2]-Cycloaddition eines Phosphinocarbens an ein Nitril und Anschließende Ringerweiterung zu einem 1,2λ5-Azaphosphet Angewandte Chemie. 107: 1358-1359. DOI: 10.1002/Ange.19951071126  0.274
1986 Garrigues B, Bertrand G, Maffrand J. Synthese De LaD,1-(Acetoxy-3 Octadecylthio-1) Propyl-2 Phosphorylcholine: Un Isomere Geometrique Du Thia-Paf Phosphorous and Sulfur and the Related Elements. 26: 53-56. DOI: 10.1080/03086648608084569  0.273
1984 Baceiredo A, Bertrand G, Majoral JP, Sicard G, Jaud J, Galy J. Synthesis and structure of the first cyclodiphosphazene. Dimerization of a phosphonitrile :P.tplbond.N Journal of the American Chemical Society. 106: 6088-6089. DOI: 10.1021/Ja00332A061  0.273
1994 Alcaraz G, Baceiredo A, Dahan F, Bertrand G. .lambda.5-Phosphonitriles and .lambda.3-Phosphinonitrenes: Evidence for Nitrene-Lewis Acid Adducts Journal of the American Chemical Society. 116: 1225-1229. DOI: 10.1021/Ja00083A008  0.27
2008 Dyker CA, Bertrand G. Chemistry. Soluble allotropes of main-group elements. Science (New York, N.Y.). 321: 1050-1. PMID 18719272 DOI: 10.1126/Science.1162926  0.268
1994 Veneziani G, Dyer P, Reau R, Bertrand G. N-Cyano-P-hydrogenoiminophosphorane-Trimethylchlorostannane Adducts [R2P(H):N-C.tplbond.N.cntdot.Me3SnCl] and Related Species: Building Blocks for Bis(carbodiimides) of Phosphorus Inorganic Chemistry. 33: 5639-5642. DOI: 10.1021/Ic00103A007  0.268
1984 Sicard G, Baceiredo A, Bertrand G, Majoral J. Erster Hinweis auf ein intermediäres Nitrilo-λ5-phosphan Angewandte Chemie. 96: 450-451. DOI: 10.1002/Ange.19840960629  0.267
1993 Soleilhavoup M, Baceiredo A, Bertrand G. The ?Phosphonioyl(phosphoranediyl)carbene? [(iPr2N)2P(H)CP(NiPr2)2]+ as a Source of New 1,3-Diphosphaallene Ylides: The First Carbodiphosphoranes with P?H Bonds Angewandte Chemie International Edition in English. 32: 1167-1169. DOI: 10.1002/Anie.199311671  0.267
1990 Gillette GR, Baceiredo A, Bertrand G. Spontane Bildung stabiler Phosphino(silyl)carbene aus instabilen Diazoverbindungen Angewandte Chemie. 102: 1486-1488. DOI: 10.1002/Ange.19901021233  0.266
2013 Ruiz DA, Melaimi M, Bertrand G. Carbodicarbenes, carbon(0) derivatives, can dimerize. Chemistry, An Asian Journal. 8: 2940-2. PMID 23960023 DOI: 10.1002/Asia.201300887  0.264
2003 Bertrand G. Group 13 Chemistry III: Industrial Applications Edited by Herbert W. Roesky (University of Göttingen, Germany) and David A. Atwood (University of Kentucky, Lexington). From the Series, Structure & Bonding, 105. Edited by D. M. P. Mingos. Springer-Verlag: Berlin, Heidelberg, New York. 2003. x + 208 pp. $169.00. ISBN 3-540-44105-0. Journal of the American Chemical Society. 125: 13908-13908. DOI: 10.1021/Ja033573V  0.264
1996 Heim U, Pritzkow H, Fleischer U, Grützmacher H, Sanchez M, Réau R, Bertrand G. λ5-Phosphetes, Benzo-λ5-Phosphetes, Naphtho-λ5-Phosphetes: Four-π-, Eight-π-, and Twelve-π-Electron Systems Chemistry - a European Journal. 2: 68-74. DOI: 10.1002/Chem.19960020113  0.264
2013 Martin D, Moore CE, Rheingold AL, Bertrand G. An air-stable oxyallyl radical cation. Angewandte Chemie (International Ed. in English). 52: 7014-7. PMID 23720417 DOI: 10.1002/Anie.201302841  0.263
2023 Liu C, Zhang Z, Zhao LL, Bertrand G, Yan X. Mesoionic Carbene-Catalyzed Formyl Alkylation of Aldehydes. Angewandte Chemie (International Ed. in English). e202303478. PMID 37070460 DOI: 10.1002/anie.202303478  0.262
1999 Amsallem D, Gornitzka H, Baceiredo A, Bertrand G. Neuartige stabile Aldehyde: Formylphosphane und Formylphosphanoxide Angewandte Chemie. 111: 2338-2340. DOI: 10.1002/(Sici)1521-3757(19990802)111:15<2338::Aid-Ange2338>3.0.Co;2-E  0.262
1983 Majoral JP, Bertrand G, Baceiredo A, Mulliez M, Schmutzler R. Photolysis of Phosphoniums and Phosphoranes Azides Phosphorus and Sulfur and the Related Elements. 18: 221-224. DOI: 10.1080/03086648308076006  0.262
1984 Sicard G, Baceiredo A, Bertrand G, Majoral J. First Evidence for an Intermediate Nitrilo-?5-phosphane Angewandte Chemie International Edition in English. 23: 459-460. DOI: 10.1002/Anie.198404591  0.262
2013 Dielmann F, Moore CE, Rheingold AL, Bertrand G. Crystalline, Lewis base-free, cationic phosphoranimines (iminophosphonium salts). Journal of the American Chemical Society. 135: 14071-3. PMID 24007472 DOI: 10.1021/Ja4080979  0.262
2013 Dielmann F, Moore CE, Rheingold AL, Bertrand G. Crystalline, Lewis base-free, cationic phosphoranimines (iminophosphonium salts). Journal of the American Chemical Society. 135: 14071-3. PMID 24007472 DOI: 10.1021/Ja4080979  0.262
1994 Cowley AH, Gabbaï FP, Carrano CJ, Mokry LM, Bond MR, Bertrand G. Reaktivität eines Phosphanylcarbens (λ5-Phosphaacetylens) gegenüber Lewis-Säuren: Strukturen des ersten Carben-Gallan-Komplexes und einesC-Gallyl-substituierten Phosphor-Ylids Angewandte Chemie. 106: 584-586. DOI: 10.1002/Ange.19941060511  0.262
2013 Ung G, Soleilhavoup M, Bertrand G. Gold(III)- versus gold(I)-induced cyclization: Synthesis of six-membered mesoionic carbene and acyclic (aryl)(heteroaryl) carbene complexes Angewandte Chemie - International Edition. 52: 758-761. PMID 23169762 DOI: 10.1002/anie.201207961  0.26
1999 Goumri-Magnet S, Gornitzka H, Baceiredo A, Bertrand G. Präparativer Nutzen stabiler Phosphanylcarbene: Synthese und Kristallstruktur eines α-(Lithiomethylen)phosphorans Angewandte Chemie. 111: 710-712. DOI: 10.1002/(Sici)1521-3757(19990301)111:5<710::Aid-Ange710>3.0.Co;2-2  0.259
2015 Soleilhavoup M, Bertrand G. Cyclic (alkyl)(amino)carbenes (CAACs): Stable carbenes on the rise Accounts of Chemical Research. 48: 256-266. DOI: 10.1021/ar5003494  0.259
1992 Romanenko VD, Gudima AO, Chernega AN, Bertrand G. Reaction of a stable phosphinocarbene with germane- and stannanediyls: evidence for C-phosphinogerma and C-phosphinostannaethene to C-germyl- and C-stannylphosphaalkene rearrangements Inorganic Chemistry. 31: 3493-3494. DOI: 10.1021/Ic00042A030  0.259
1991 Dixon DA, Dobbs KD, Arduengo AJ, Bertrand G. Electronic structure of .lambda.5-phosphaacetylene and corresponding triplet methylenes Journal of the American Chemical Society. 113: 8782-8785. DOI: 10.1021/Ja00023A027  0.258
1994 Bon E, Biggs DCH, Bertrand G, Bigg DCH. Aluminum Chloride-Promoted Aminolysis of N-Tosyl Lactams Journal of Organic Chemistry. 59: 1904-1906. DOI: 10.1021/Jo00086A051  0.258
1993 Reed R, Réau R, Dahan F, Bertrand G. DBU and DBN are Strong Nucleophiles: X-Ray Crystal Structures of Onio- and Dionio-Substituted Phosphanes Angewandte Chemie International Edition in English. 32: 399-401. DOI: 10.1002/Anie.199303991  0.257
1991 Castan F, Baceiredo A, Fischer J, Cian AD, Commenges G, Bertrand G. Synthesis and X-ray crystal structure of the first diphosphirenium salt Journal of the American Chemical Society. 113: 8160-8161. DOI: 10.1021/Ja00021A048  0.257
2003 Bertrand G. Group 13 Chemistry I: Fundamental New Develop-ments. Structure & Bonding, Volume 103 Edited by Herbert W. Roesky (University of Göttingen, Germany) and David A. Atwood (University of Kentucky, Lexing-ton). Springer-Verlag: Berlin, Heidelberg, New York. 2002. x + 172 pp. $129.00. ISBN 3-540-43615-4. Journal of the American Chemical Society. 125: 3399-3399. DOI: 10.1021/Ja025331L  0.256
1988 Sicard G, Baceiredo A, Crocco G, Bertrand G. A New Route to Nitrile Oxides via ?-Nitrosodiazo Derivatives Angewandte Chemie International Edition in English. 27: 301-302. DOI: 10.1002/Anie.198803011  0.256
1985 Davidson IMT, Fenton A, Manuel G, Bertrand G. Kinetics and mechanism of the pyrolysis of 6-oxa-3,3-dimethyl-3-silabicyclo[3.1.0]hexane, a dimethylsilanone precursor Organometallics. 4: 1324-1327. DOI: 10.1021/Om00127A002  0.256
1991 Sotiropoulos J, Baceiredo A, von Locquenghien KH, Dahan F, Bertrand G. Reaktivität eines (Diazomethylen)phosphorans gegenüber Alkylierungsmitteln und Lewis-Säuren; Synthese der ersten α-Diazoalkylborate Angewandte Chemie. 103: 1174-1175. DOI: 10.1002/Ange.19911030928  0.256
1999 Goumri-Magnet S, Guerret O, Gornitzka H, Cazaux JB, Bigg D, Palacios F, Bertrand G. Free and Supported Phosphorus Ylides as Strong Neutral Brønsted Bases. The Journal of Organic Chemistry. 64: 3741-3744. PMID 11674508 DOI: 10.1021/Jo9822030  0.254
1990 Granier M, Baceiredo A, Nieger M, Bertrand G. EinN-Phosphino-C-thiophosphinoylnitrilimin als formaler 1,4-Dipol: Synthese von 1,2,3λ5-Diaza- und 1,2,4,3λ5-Triazaphosphininen Angewandte Chemie. 102: 1185-1187. DOI: 10.1002/Ange.19901021024  0.253
1985 Baceiredo A, Bertrand G, Majoral JP, Anba FE, Manuel G. Versatile photochemical behavior of phosphorus azides: Curtius-type rearrangement and diverse fates of .alpha.-phosphorus nitrenes Journal of the American Chemical Society. 107: 3945-3949. DOI: 10.1021/Ja00299A033  0.252
1991 Arthur MP, Baceiredo A, Bertrand G. Synthesis of the first distillable .alpha.-boranyldiazomethane. Direct evidence for a lithioboranyldiazomethane-lithioboranylisodiazomethane [(>BCNN-,Li+)-(>BNNC-,Li+)] rearrangement Journal of the American Chemical Society. 113: 5856-5857. DOI: 10.1021/Ja00015A046  0.249
2000 Kato T, Gornitzka H, Baceiredo A, Savin A, Bertrand G. On the Electronic Structure of (Phosphino)(silyl)carbenes:  Single-Crystal X-ray Diffraction and ELF Analyses Journal of the American Chemical Society. 122: 998-999. DOI: 10.1021/Ja9939542  0.247
2010 GILLETTE GR, IGAU A, BACEIREDO A, BERTRAND G. ChemInform Abstract: Stable Phosphanyl Silyl Carbenes: Synthesis and Reactivity. Cheminform. 23: no-no. DOI: 10.1002/chin.199221223  0.246
2017 Soleilhavoup M, Bertrand G. Borylene: eine aufstrebende Verbindungsklasse Angewandte Chemie. 129: 10416-10426. DOI: 10.1002/Ange.201705153  0.245
1979 Barthelat JC, Trinquier G, Bertrand G. Theoretical investigations on some C2SiH4 isomers Journal of the American Chemical Society. 101: 3785-3789. DOI: 10.1021/Ja00508A015  0.245
1985 Trinquier G, Bertrand G. Binding phosphinidenes to transition-metal fragments Inorganic Chemistry. 24: 3842-3856. DOI: 10.1021/Ic00217A029  0.243
1996 Sanchez M, Réau R, Dahan F, Regitz M, Bertrand G. Von 1σ4, 2σ2- zu 1σ4, 2σn-Diphospheten (n = 3–6): die überraschende Beständigkeit der P-P-Bindung Angewandte Chemie. 108: 2386-2388. DOI: 10.1002/Ange.19961081923  0.243
2013 Giziroglu E, Donnadieu B, Bertrand G. Synthesis and characterization of a pyrazolium bearing N-heterocyclic carbene-palladium(II) complex Journal of Organometallic Chemistry. 724: 251-254. DOI: 10.1016/j.jorganchem.2012.11.021  0.24
1988 Sicard G, Baceredo A, Crocco G, Bertrand G. Ein neuer Weg zu Nitriloxiden über α-Nitroso-diazo-Derivate Angewandte Chemie. 100: 289-290. DOI: 10.1002/Ange.19881000222  0.239
1984 Garrigues B, Bertrand G, Maffrand J. An Efficient Synthesis of Azathia Analogs of Platelet-Activating Factor Synthesis. 1984: 870-872. DOI: 10.1055/S-1984-31003  0.237
1998 Emig N, Gabbaï F, Krautscheid H, Réau R, Bertrand G. Die Azid-Nitrilimin-Analogie in der Aluminium-Chemie Angewandte Chemie. 110: 1037-1040. DOI: 10.1002/(Sici)1521-3757(19980403)110:7<1037::Aid-Ange1037>3.0.Co;2-8  0.236
2015 Jin L, Melaimi M, Kostenko A, Karni M, Apeloig Y, Moore CE, Rheingold AL, Bertrand G. Isolation of cationic and neutral (allenylidene)(carbene) and bis(allenylidene)gold complexes Chemical Science. 7: 150-154. DOI: 10.1039/c5sc03654b  0.234
2010 VENEZIANI G, REAU R, BERTRAND G. ChemInform Abstract: Thermal and Metal-Catalyzed Rearrangements of Bis(stannyl)diazo Derivatives into Carbodiimides: Carbodiimide-Transfer Reactions. Cheminform. 25: no-no. DOI: 10.1002/chin.199407242  0.232
1995 Cowley AH, Gabbaï FP, Bertrand G, Carrano CJ, Bond MR. Structural investigation into the suprising stability of free and complexed bis(amino) phosphine azides Journal of Organometallic Chemistry. 493: 95-99. DOI: 10.1016/0022-328X(95)91149-E  0.232
1986 Bertrand G, Majoral JP, Baceiredo A. Photochemical and thermal rearrangement of heavier main-group element azides Accounts of Chemical Research. 19: 17-23. DOI: 10.1021/Ar00121A003  0.231
1984 Garrigues B, Bertrand G, Frehel D, Maffrand J. SYNTHESE DE LA d,l-(ACETOXY-2 OCTADECYLTHIO-1) PROPYL-3 PHOSPHORYLCHOLINE OU THIA-PAF Phosphorus and Sulfur and the Related Elements. 21: 171-176. DOI: 10.1080/03086648408077653  0.23
1984 Baceiredo A, Bertrand G, Majoral JP, Wermuth U, Schmutzler R. First evidence for a Curtius-type rearrangement involving a pentacoordinated atom Journal of the American Chemical Society. 106: 7065-7068. DOI: 10.1002/Chin.198510302  0.23
2011 Martin D, Melaimi M, Soleilhavoup M, Bertrand G. ChemInform Abstract: Our Contribution to Stable Carbene Chemistry Cheminform. 43: no-no. DOI: 10.1002/chin.201201251  0.229
2010 Bertrand G. Introduction to main group chemistry. Chemical Reviews. 110: 3851. PMID 20672857 DOI: 10.1021/Cr1001657  0.229
2009 Arduengo AJ, Bertrand G. Carbenes introduction. Chemical Reviews. 109: 3209-10. PMID 19642638 DOI: 10.1021/cr900241h  0.228
1986 Bertrand G, Majoral JP, Baceiredo A. Photochemical and Thermal Rearrangement of Heavier Main‐Group Element Azides Cheminform. 17. DOI: 10.1002/Chin.198626353  0.227
2023 Haimerl M, Schwarzmaier C, Riesinger C, Timoshkin A, Melaimi M, Bertrand G, Scheer M. Reactivity of Yellow Arsenic towards Cyclic (Alkyl)(Amino) Carbenes (CAACs). Chemistry (Weinheim An Der Bergstrasse, Germany). e202300280. PMID 37015017 DOI: 10.1002/chem.202300280  0.226
2004 Bertrand G. Main group chemistry – 2002 ICMGC award Journal of Organometallic Chemistry. 689: 1329-1330. DOI: 10.1016/J.Jorganchem.2004.02.017  0.225
1999 Goumri-Magnet S, Polishchuk O, Gornitzka H, Marsden C, Baceiredo A, Bertrand G. Das elektrophile Verhalten von stabilen Phosphanylcarbenen gegenüber den freien Elektronenpaaren des Phosphoratoms Angewandte Chemie. 111: 3938-3941. DOI: 10.1002/(Sici)1521-3757(19991216)111:24<3938::Aid-Ange3938>3.0.Co;2-F  0.225
1997 Guerret O, Solé S, Gornitzka H, Teichert M, Trinquier G, Bertrand G. 1,2,4-Triazole-3,5-diylidene:  A Building Block for Organometallic Polymer Synthesis Journal of the American Chemical Society. 119: 6668-6669. DOI: 10.1021/Ja964191A  0.223
1993 Soleilhavoup M, Baceiredo A, Bertrand G. Das „Phosphonioyl(phosphorandiyl)carben” [(iPr2N)2P(H)CP(NiPr2)2]+ als Quelle neuartiger Diphosphaallene mit Ylid-Struktur: die ersten Car-bodiphosphorane mit H-substituiertem Phosphor Angewandte Chemie. 105: 1245-1247. DOI: 10.1002/Ange.19931050833  0.222
2014 Kretschmer R, Ruiz DA, Moore CE, Rheingold AL, Bertrand G. Ein-, Zwei- und Drei-Elektronen-Reduktion eines CAAC-SbCl3- Addukts Angewandte Chemie. 126: 8315-8318. DOI: 10.1002/Ange.201404849  0.219
1980 Bertrand G, Majoral J, Baceiredo A. Photolytic rearrangement of phosphorus azide : evidence for a transient metaphosphonimidate. Tetrahedron Letters. 21: 5015-5018. DOI: 10.1016/S0040-4039(00)71119-1  0.219
1984 Manuel G, Bertrand G, Weber WP, Kazoura SA. Thermolysis Of 6‐Oxa‐3‐Silabicyclo(3.1.0)Hexanes: A New Convenient Route To Silicon‐Oxygen Π‐Bonded Species Organometallics. 15: 1340-1343. DOI: 10.1002/Chin.198452267  0.218
2010 VENEZIANI G, REAU R, DAHAN F, BERTRAND G. ChemInform Abstract: Bis(phosphino)carbodiimide: A Bis(1,3)-dipole. Cheminform. 26: no-no. DOI: 10.1002/chin.199517174  0.215
1993 Reed R, Réau R, Dahan F, Bertrand G. DBU und DBN als starke Nucleophile: Kristallstrukturen onio- und dioniosubstituierter Phosphane Angewandte Chemie. 105: 464-465. DOI: 10.1002/Ange.19931050336  0.213
1999 Sanchez M, Réau R, Marsden CJ, Regitz M, Bertrand G. From 2-Phosphino-2H-Phosphirene to 1-Phosphino-1H-Phosphirene, 1λ5,2λ3-Diphosphete, and 1,2-Dihydro-1λ3,2λ3-Diphosphete: an Experimental and Theoretical Study Chemistry - a European Journal. 5: 274-279. DOI: 10.1002/(Sici)1521-3765(19990104)5:1<274::Aid-Chem274>3.0.Co;2-P  0.211
1995 Canac Y, Baceiredo A, Gornitzka H, Stalke D, Bertrand G. Ein kationisches 1,3-Diphospha-2,4-dipallada(II)-tricyclo[1.1.1]pentan-Derivat: das erste strukturell charakterisierte pyramidale μ2-Phosphiniden Angewandte Chemie. 107: 2904-2906. DOI: 10.1002/Ange.19951072326  0.209
1994 Bertrand G, Wentrup C. Nitrilimine: von der Charakterisierung in Matrix zu stabilen Verbindungen Angewandte Chemie. 106: 549-568. DOI: 10.1002/Ange.19941060505  0.209
2003 Canac Y, Bertrand G. nido-Five-vertex clusters: in and out of boron chemistry. Angewandte Chemie (International Ed. in English). 42: 3578-80. PMID 12916028 DOI: 10.1002/Anie.200301648  0.208
1995 Dubau-Assibat N, Baceiredo A, Bertrand G. Lawesson's Reagent: An Efficient 1,3-Dipole Trapping Agent The Journal of Organic Chemistry. 60: 3904-3906. DOI: 10.1021/Jo00117A050  0.208
2020 Proetto MT, Alexander K, Melaimi M, Bertrand G, Gianneschi NC. Cyclic (Alkyl)(Amino)Carbene (CAAC) Gold(I) Complexes as Chemotherapeutic Agents. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 33090571 DOI: 10.1002/chem.202004317  0.205
2013 Bertrand GH, Michaelis VK, Ong TC, Griffin RG, Dincă M. Thiophene-based covalent organic frameworks. Proceedings of the National Academy of Sciences of the United States of America. 110: 4923-8. PMID 23479656 DOI: 10.1073/Pnas.1221824110  0.202
2014 Bertrand GH, Tortech L, Gandon V, Aubert C, Fichou D. Synthesis and photovoltaic performances in solution-processed BHJs of oligothiophene-substituted organocobalt complexes [(η⁴-C₄(nT)₄)Co(η⁵-C₅H₅)]. Chemical Communications (Cambridge, England). 50: 8663-6. PMID 24942914 DOI: 10.1039/C4Cc03530E  0.198
2013 Martin D, Moore CE, Rheingold AL, Bertrand G. Ein luftstabiles Oxyallyl-Radikalkation Angewandte Chemie. 125: 7152-7155. DOI: 10.1002/Ange.201302841  0.198
1989 Castan F, Baceiredo A, Bertrand G. Ein destillierbaresC- undN-silyliertes Nitrilimin Angewandte Chemie. 101: 1253-1254. DOI: 10.1002/Ange.19891010914  0.198
2012 Bertrand G, Tortech L, Fichou D, Malacria M, Aubert C, Gandon V. An improved protocol for the synthesis of [(ν 4-C 4R 4)Co(ν 5-C 5H 5)] complexes Organometallics. 31: 126-132. DOI: 10.1021/Om200662G  0.198
2003 Canac Y, Bertrand G. nido-Cluster mit fünf Ecken: ein allgemeines Konzept aus der Borchemie Angewandte Chemie. 115: 3702-3704. DOI: 10.1002/Ange.200301648  0.193
2002 Bertrand G. Main Group Chemistry—1999 ICMGC Award Journal of Organometallic Chemistry. 646: 2-3. DOI: 10.1016/S0022-328X(01)01485-1  0.192
2012 Gladysz JA, Ball ZT, Bertrand G, Blum SA, Dong VM, Dorta R, Hahn FE, Humphrey MG, Jones WD, Klosin J, Manners I, Marks TJ, Mayer JM, Rieger B, Ritter JC, et al. Organometallics roundtable 2011 Organometallics. 31: 1-18. DOI: 10.1021/Om201234X  0.191
2010 TEJEDA J, REAU R, DAHAN F, BERTRAND G. ChemInform Abstract: Synthesis and Molecular Structure of a 1,2λ5-Azaphosphete: A Cyclic 4-π-Electron Ylide. Cheminform. 24: no-no. DOI: 10.1002/chin.199351230  0.187
2014 Bertrand GHV, Tortech L, Gandon V, Aubert C, Fichou D. Synthesis and photovoltaic performances in solution-processed BHJs of oligothiophene-substituted organocobalt complexes [(η4-C 4(nT)4)Co(η5-C5H5)] Chemical Communications. 50: 8663-8666. DOI: 10.1039/c4cc03530e  0.187
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