James A. Franz - Publications

Affiliations: 
Fundamental & Computational Sciences Pacific Northwest National Laboratory, Richland, WA, United States 
Area:
free radical chemistry and homogeneous catalysis
Website:
http://iic.pnnl.gov/staff/Jim_Franz.stm

52 high-probability publications. We are testing a new system for linking publications to authors. You can help! If you notice any inaccuracies, please sign in and mark papers as correct or incorrect matches. If you identify any major omissions or other inaccuracies in the publication list, please let us know.

Year Citation  Score
2017 Glezakou VA, Rousseau R, Elbert ST, Franz JA. Trends in Homolytic Bond Dissociation Energies of Five- and Six-Coordinate Hydrides of Group 9 Transition Metals: Co, Rh, Ir. The Journal of Physical Chemistry. A. PMID 28139924 DOI: 10.1021/Acs.Jpca.6B11655  0.34
2014 Norton JR, Spataru T, Camaioni DM, Lee SJ, Li G, Choi J, Franz JA. Kinetics and mechanism of the hydrogenation of the CpCr(CO) 3 •/[CpCr(CO)3]2 equilibrium to CpCr(CO)3H Organometallics. 33: 2496-2502. DOI: 10.1021/Om4012399  0.35
2013 Franz JA, O'Hagan M, Ho MH, Liu T, Helm ML, Lense S, Dubois DL, Shaw WJ, Appel AM, Raugei S, Bullock RM. Conformational dynamics and proton relay positioning in nickel catalysts for hydrogen production and oxidation Organometallics. 32: 7034-7042. DOI: 10.1021/Om400695W  0.31
2011 Roberts JA, Franz JA, van der Eide EF, Walter ED, Petersen JL, DuBois DL, Bullock RM. Comproportionation of cationic and anionic tungsten complexes having an N-heterocyclic carbene ligand to give the isolable 17-electron tungsten radical CpW(CO)2(IMes)(•). Journal of the American Chemical Society. 133: 14593-603. PMID 21786753 DOI: 10.1021/Ja202754E  0.407
2010 Cheng TY, Szalda DJ, Franz JA, Morris Bullock R. Structural and computational studies of Cp(CO)2(PCy3)MoFBF3, a complex with a bound BF4 - ligand Inorganica Chimica Acta. 363: 581-585. DOI: 10.1016/J.Ica.2009.02.028  0.327
2009 Franz JA, Lee SJ, Bowden TA, Alnajjar MS, Appel AM, Birnbaum JC, Bitterwolf TE, Dupuis M. Activation of the S-H group in Fe(mu(2)-SH)Fe clusters: S-H bond strengths and free radical reactivity of the Fe(mu(2)-SH)Fe cluster. Journal of the American Chemical Society. 131: 15212-24. PMID 19795866 DOI: 10.1021/Ja904602P  0.331
2009 Appel AM, Lee SJ, Franz JA, DuBois DL, DuBois MR. Free energy landscapes for S-H bonds in Cp*2Mo2S4 complexes. Journal of the American Chemical Society. 131: 5224-32. PMID 19309157 DOI: 10.1021/Ja8093179  0.383
2009 Mader EA, Manner VW, Markle TF, Wu A, Franz JA, Mayer JM. Trends in ground-state entropies for transition metal based hydrogen atom transfer reactions. Journal of the American Chemical Society. 131: 4335-45. PMID 19275235 DOI: 10.1021/Ja8081846  0.358
2009 Appel AM, Lee SJ, Franz JA, DuBois DL, DuBois MR, Twamley B. Determination of S - H bond strengths in dimolybdenum tetrasulfide complexes Organometallics. 28: 749-754. DOI: 10.1021/Om800875N  0.304
2008 Appel AM, Lee SJ, Franz JA, DuBois DL, DuBois MR, Birnbaum JC, Twamley B. Formation and reactivity of a persistent radical in a dinuclear molybdenum complex. Journal of the American Chemical Society. 130: 8940-51. PMID 18564842 DOI: 10.1021/Ja078115R  0.414
2006 DuBois DL, Blake DM, Miedaner A, Curtis CJ, DuBois MR, Franz JA, Linehan JC. Hydride transfer from rhodium complexes to triethylborane Organometallics. 25: 4414-4419. DOI: 10.1021/Om060584Z  0.392
2006 Zhao H, Kwak JH, Wang Y, Franz JA, White JM, Holladay JE. Effects of crystallinity on dilute acid hydrolysis of cellulose by cellulose ball-milling study Energy and Fuels. 20: 807-811. DOI: 10.1021/Ef050319A  0.325
2004 Franz JA, Birnbaum JC, Kolwaite DS, Linehan JC, Camaioni DM, Dupuis M. Activation of the sulfhydryl group by Mo centers: kinetics of reaction of benzyl radical with a binuclear Mo(micro-SH)Mo complex and with arene and alkane thiols. Journal of the American Chemical Society. 126: 6680-91. PMID 15161296 DOI: 10.1021/Ja049321R  0.457
2004 Franz JA, Shaw WJ, Lamb CN, Autrey T, Kolwaite DS, Camaioni DM, Alnajjar MS. Absolute rate constants for reactions of tributylstannyl radicals with bromoalkanes, episulfides, and alpha-halomethyl-episulfides, -cyclopropanes, and -oxiranes: new rate expressions for sulfur and bromine atom abstraction. The Journal of Organic Chemistry. 69: 1020-7. PMID 14961649 DOI: 10.1021/Jo035467H  0.431
2004 Shaw WJ, Kandandarachchi P, Franz JA, Autrey T. Spectroscopic studies of tributylstannyl radical. Rates of formation, termination, and abstraction determined by transient absorption spectroscopy Organometallics. 23: 2080-2086. DOI: 10.1021/Om049933K  0.346
2004 Franz JA, Kolwaite DS, Linehan JC, Rosenberg E. Comparison of hydrogen atom abstraction rates of terminal and bridging hydrides in triosmium clusters: Absolute abstraction rate constants for benzyl radical Organometallics. 23: 441-445. DOI: 10.1021/Om0342255  0.37
2003 Tanner DD, Kandanarachchi P, Das NC, Franz JA. Absolute rates of the solution-phase addition of atomic hydrogen to a vinyl ether and a vinyl ester: Effect of oxygen substitution on hydrogen atom reactivity with olefins Journal of Physical Chemistry A. 107: 3054-3063. DOI: 10.1021/Jp021963I  0.428
2002 Alnajjar MS, Zhang XM, Gleicher GJ, Truksa SV, Franz JA. Equilibrium acidities and homolytic bond dissociation energies of acidic C-H bonds in alpha-arylacetophenones and related compounds. The Journal of Organic Chemistry. 67: 9016-22. PMID 12467424 DOI: 10.1021/Jo020275S  0.375
2002 Kandanarachchi PH, Autrey T, Franz JA. Model compound studies of the beta-O-4 linkage in lignin: absolute rate expressions for beta-scission of phenoxyl radical from 1-phenyl-2-phenoxyethanol-1-yl radical. The Journal of Organic Chemistry. 67: 7937-45. PMID 12423121 DOI: 10.1021/Jo025581K  0.388
2001 Autrey T, Kandanarachchi P, Franz JA. Comparison of diffusion coefficients of aryl carbonyls and aryl alcohols in hydroxylic solvents. Evidence that the diffusion of ketyl radicals in hydrogen-bonding solvents is not anomalous? Journal of Physical Chemistry A. 105: 5948-5953. DOI: 10.1021/Jp004291+  0.329
2001 Tanner DD, Kandanarachchi P, Ding Q, Shao H, Vizitiu D, Franz JA. The Catalytic Conversion of C1−Cn Hydrocarbons to Olefins and Hydrogen: Microwave-Assisted C−C and C−H Bond Activation Energy & Fuels. 15: 197-204. DOI: 10.1021/Ef000167D  0.43
2000 Franz JA, Camaioni DM, Autrey T, Linehan JC, Alnajjar MS. Measurement of select radical processes in hydrocarbon pyrolysis Journal of Analytical and Applied Pyrolysis. 54: 37-64. DOI: 10.1016/S0165-2370(99)00079-0  0.355
1999 Franz JA, Linehan JC, Birnbaum JC, Hicks KW, Alnajjar MS. Absolute rate expressions for hydrogen atom abstraction from molybdenum hydrides by carbon-centered radicals Journal of the American Chemical Society. 121: 9824-9830. DOI: 10.1021/Ja991412E  0.411
1999 Autrey T, Linehan JC, Kaune L, Powers TR, McMillan EF, Stearns C, Franz JA. `FeS'-assisted scission of strong bonds in phenoxydiphenylmethanes. Competition between hydrogen atom transfer and free radical rearrangement pathways Energy and Fuels. 13: 927-933. DOI: 10.1021/Ef990009Q  0.457
1999 Autrey T, Linehan JC, Kaune L, Powers TR, McMillan EF, Stearns C, Franz JA. `FeS'-assisted scission of strong bonds in phenoxydiphenylmethanes. Competition between hydrogen atom transfer and free radical rearrangement pathways Energy and Fuels. 13: 927-933. DOI: 10.1021/ef990009q  0.309
1998 Tanner DD, Kandanarachchi P, Das NC, Brausen M, Vo CT, Camaioni DM, Franz JA. Reactions of Microwave-Generated O(3P) Atoms with Unsaturated Hydrocarbons Journal of Organic Chemistry. 63: 4587-4593. DOI: 10.1021/Jo972083G  0.374
1996 Camaioni DM, Autrey ST, Salinias TB, Franz JA. Calculation of the effects of branching and conjugation on intrinsic barriers for H atom transfer reactions involving hydrocarbons Journal of the American Chemical Society. 118: 2013-2022. DOI: 10.1021/Ja950740L  0.45
1996 Autrey T, Linehan JC, Camaioni DM, Kaune LE, Watrob HM, Franz JA. Mechanistic investigations of iron/sulfur-catalyzed bond scission in aromatic hydrocarbons. a catalytic hydrogen atom transfer step involving a late transition state Catalysis Today. 31: 105-111. DOI: 10.1016/0920-5861(96)00037-5  0.389
1996 Watts JD, Franz JA, Bartlett RJ. Radical hydrogen transfer reactions: benchmark calculations on the C2H4…H…C2H4 transition state Chemical Physics Letters. 249: 496-500. DOI: 10.1016/0009-2614(95)01420-9  0.395
1995 Alnajjar MS, Zhang XM, Franz JA, Bordwell FG. Stereoelectronic effects of divalent sulfur functions on radical stabilities The Journal of Organic Chemistry. 60: 4976-4977. DOI: 10.1021/Jo00121A009  0.321
1995 Autrey T, Devadoss C, Sauerwein B, Franz JA, Schuster GB. Solvent cage recombination of 4-benzoylphenylthiyl radicals: Fast intersystem crossing of triplet sulfur-centered radical pairs Journal of Physical Chemistry. 99: 869-871. DOI: 10.1021/J100003A005  0.413
1995 Autrey T, Alborn EA, Franz JA, Camaioni DM. Solvent-induced scission of diarylmethanes in dihydroarene donor solvents: An experimental and mechanistic modeling study of hydrogen-transfer pathways Energy & Fuels. 9: 420-428. DOI: 10.1021/Ef00051A005  0.41
1995 Autrey T, Powers T, Alborn EA, M Camaioni D, Franz JA. Hydrogen shuttling pathways in thermal hydroliquefaction: Solvent-induced scission of coal model compound structures Coal Science and Technology. 24: 1431-1434. DOI: 10.1016/S0167-9449(06)80074-1  0.399
1995 Franz JA, Autrey T, Camaioni DM, Watts JD, Bartlett RJ. Role of aromatic structure in pathways of hydrogen transfer and bond cleavage in coal liquefaction: Theoretical studies Coal Science and Technology. 24: 1411-1414. DOI: 10.1016/S0167-9449(06)80069-8  0.467
1994 Franz JA, Ferris KF, Camaioni DM, Autrey ST. Are strong bonds cleaved during coal liquefaction via radical hydrogen transfer? An ab initio theoretical study of thermoneutral radical hydrogen transfer Energy & Fuels. 8: 1016-1019. DOI: 10.1021/Ef00047A002  0.428
1993 Camaioni DM, Autrey ST, Franz JA. Comment on "Hydrogen transfer between anthracene structures" Journal of Physical Chemistry. 97: 5791-5792. DOI: 10.1021/J100123A055  0.343
1992 Ferris KF, Franz JA, Sosa C, Bartlett RJ. Alkyl radical displacement reactions at sulfur: On the question of intermediacy in alkylsulfuranyl radicals Journal of Organic Chemistry. 57: 777-778. DOI: 10.1021/Jo00028A076  0.397
1992 Alnajjar MS, Franz JA. A kinetic study of the migration of a phenyl group from sulfur to a carbon radical center: rearrangement of the .alpha.-(phenylthio)benzyl radical Journal of the American Chemical Society. 114: 1052-1058. DOI: 10.1021/Ja00029A038  0.336
1992 Alnajjar MS, Garrossian MS, Autrey ST, Ferris KF, Franz JA. Kinetic and ab initio theoretical study of hydrogen atom abstraction from thiols by thiyl radicals: Basis rate expressions for reactions of sulfur-centered radicals Journal of Physical Chemistry. 96: 7037-7043. DOI: 10.1021/J100196A036  0.353
1992 Alnajjar MS, Garrossian MS, Autrey ST, Ferris KF, Franz JA. Kinetic and ab initio theoretical study of hydrogen atom abstraction from thiols by thiyl radicals: Basis rate expressions for reactions of sulfur-centered radicals Journal of Physical Chemistry. 96: 7037-7043.  0.367
1991 Autrey ST, Alnajjar MS, Nelson DA, Franz JA. Absolute rate constants for the .beta.-scission reaction of the 1-phenyl-2-phenoxypropyl radical: a model for radical reactions of lignin Journal of Organic Chemistry. 56: 2197-2202. DOI: 10.1021/Jo00006A043  0.373
1989 Franz JA, Bushaw BA, Alnajjar MS. Absolute rate expressions for the abstraction of hydrogen by primary, secondary, and tertiary alkyl radicals from thiophenol Journal of the American Chemical Society. 111: 268-275. DOI: 10.1021/Ja00183A040  0.344
1987 Franz JA, Roberts DH, Ferris KF. Absolute rate expressions for intramolecular displacement reactions of primary alkyl radicals at sulfur Journal of Organic Chemistry. 52: 2256-2262. DOI: 10.1021/Jo00387A028  0.374
1986 Franz JA, Alnajjar MS, Barrows RD, Kaisaki DL, Camaioni DM, Suleman NK. Reactions of the 2-allylbenzyl radical: Relative and absolute rate constants for abstraction of hydrogen atom from thiophenol, dicyclohexylphosphine, phenols, and arylalkyl donors Journal of Organic Chemistry. 51: 1446-1456. DOI: 10.1002/Chin.198648128  0.446
1986 Franz JA, Suleman NK, Alnajjar MS. Absolute rate constants for hydrogen atom abstraction by benzyl radical from thiophenol, tributylstannane, tributylstannane-d, and dicyclohexylphosphine and for the cyclization of the 2-allylbenzyl radical Journal of Organic Chemistry. 51: 19-25. DOI: 10.1002/Chin.198625094  0.426
1985 Camaioni DM, Alnajjar MS, Deardurff LA, Franz JA. RADICAL CATION MEDIATED BOND CLEAVAGE REACTIONS OF COAL MODEL COMPOUNDS . 702-705.  0.308
1984 Camaioni DM, Franz JA. Carbon-hydrogen vs. carbon-carbon bond cleavage of 1,2-diarylethane radical cations in acetonitrile-water Journal of Organic Chemistry. 49: 1607-1613. DOI: 10.1021/Jo00183A023  0.417
1984 Franz JA, Barrows RD, Camaioni DM. Arrhenius parameters for rearrangements of the neophyl, 1-indanylmethyl, 2-allylbenzyl, and 2-(2-vinylphenyl)ethyl radicals relative to hydrogen abstraction from tributylstannane Journal of the American Chemical Society. 106: 3964-3967. DOI: 10.1021/Ja00326A013  0.393
1984 Franz JA, Camaioni DM. Study of deuterium transfer, isotope effects and structural distributions of products of reactions of coals in deuterated tetralin using 2H and 13C FT-n.m.r. and solid-state 13C FT-n.m.r. Fuel. 63: 990-1001. DOI: 10.1016/0016-2361(84)90324-7  0.311
1984 Franz JA, Camaioni DM, Beishline RR, Dalling DK. Products, radical intermediates, and hydrogen atom production in the thermal decomposition of 1,2-dihydronaphthalene Journal of Organic Chemistry. 49: 3563-3570. DOI: 10.1002/Chin.198509101  0.413
1980 Franz JA, Camaioni DM. Radical pathways of coal dissolution in hydrogen donor media. 2. β Scission and 1,2 aryl migration reactions of radicals derived from methylindans and tetralin at 327-627°C Journal of Organic Chemistry. 45: 5247-5255. DOI: 10.1021/Jo01314A005  0.396
1980 Franz JA, Camaioni DM. Fragmentations and rearrangments of free radical intermediates during hydroliquefaction of coals in hydrogen donor media Fuel. 59: 803-805. DOI: 10.1016/0016-2361(80)90260-4  0.412
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