153 high-probability publications. We are testing a new system for linking publications to authors. You can help! If you notice any inaccuracies, please sign in and mark papers as correct or incorrect matches. If you identify any major omissions or other inaccuracies in the publication list, please let us know.

Year Citation  Score
2020 Dunn PL, Cook BJ, Johnson SI, Appel AM, Bullock RM. Oxidation of Ammonia with Molecular Complexes. Journal of the American Chemical Society. PMID 32977718 DOI: 10.1021/jacs.0c08269  0.56
2020 Bullock RM, Chen JG, Gagliardi L, Chirik PJ, Farha OK, Hendon CH, Jones CW, Keith JA, Klosin J, Minteer SD, Morris RH, Radosevich AT, Rauchfuss TB, Strotman NA, Vojvodic A, et al. Using nature's blueprint to expand catalysis with Earth-abundant metals. Science (New York, N.Y.). 369. PMID 32792370 DOI: 10.1126/science.abc3183  0.44
2020 Dunn P, Johnson SI, Kaminsky W, Bullock RM. Diversion of Catalytic C-N Bond Formation to Catalytic Oxidation of NH3 Through Modification of the Hydrogen Atom Abstractor. Journal of the American Chemical Society. PMID 32009401 DOI: 10.1021/jacs.9b13706  0.56
2019 Cook BJ, Johnson SI, Chambers GM, Kaminsky W, Bullock RM. Triple hydrogen atom abstraction from Mn-NH complexes results in cyclophosphazenium cations. Chemical Communications (Cambridge, England). PMID 31691686 DOI: 10.1039/c9cc06915a  0.64
2019 Bhattacharya P, Heiden ZM, Chambers GM, Johnson SI, Bullock RM, Mock MT. Catalytic Ammonia Oxidation to Dinitrogen by Hydrogen Atom Abstraction. Angewandte Chemie (International Ed. in English). PMID 31115120 DOI: 10.1002/anie.201903221  0.64
2019 Johnson SI, Heins SP, Klug CM, Wiedner ES, Bullock RM, Raugei S. Design and reactivity of pentapyridyl metal complexes for ammonia oxidation. Chemical Communications (Cambridge, England). PMID 30977481 DOI: 10.1039/c9cc01249d  0.56
2019 Chambers GM, Johnson SI, Raugei S, Bullock RM. Anion control of tautomeric equilibria: Fe-H N-H influenced by NH···F hydrogen bonding. Chemical Science. 10: 1410-1418. PMID 30842818 DOI: 10.1039/c8sc04239j  0.64
2019 Prokopchuk DE, Chambers GM, Walter ED, Mock MT, Bullock RM. H2 Binding, Splitting, and Net Hydrogen Atom Transfer at a Paramagnetic Iron Complex. Journal of the American Chemical Society. PMID 30669844 DOI: 10.1021/jacs.8b12823  0.64
2018 Chambers GM, Wiedner ES, Bullock RM. H2 Oxidation Electrocatalysis Enabled by Metal-to-Metal Hydrogen Atom Transfer: A Homolytic Approach to a Heterolytic Reaction. Angewandte Chemie (International Ed. in English). PMID 30117247 DOI: 10.1002/anie.201807510  0.64
2018 Kendall AJ, Johnson SI, Bullock RM, Mock MT. Catalytic Silylation of N2 and Synthesis of NH3 and N2H4 by Net Hydrogen Atom Transfer Reactions using a Chromium P4 Macrocycle. Journal of the American Chemical Society. PMID 29384664 DOI: 10.1021/jacs.7b11132  0.64
2017 Bullock RM, Chambers GM. Frustration across the periodic table: heterolytic cleavage of dihydrogen by metal complexes. Philosophical Transactions. Series a, Mathematical, Physical, and Engineering Sciences. 375. PMID 28739961 DOI: 10.1098/rsta.2017.0002  0.64
2017 Prokopchuk DE, Wiedner ES, Walter ED, Popescu CV, Piro NA, Kassel WS, Bullock RM, Mock MT. Catalytic N2 Reduction into Silylamines and Thermodynamics of N2 Binding at Square Planar Fe. Journal of the American Chemical Society. PMID 28613896 DOI: 10.1021/jacs.7b04552  0.64
2017 Zhang S, Appel AM, Bullock RM. Reversible Heterolytic Cleavage of the H-H Bond by Molybdenum Complexes: Controlling the Dynamics of Exchange Between Proton and Hydride. Journal of the American Chemical Society. PMID 28467854 DOI: 10.1021/jacs.7b03053  0.48
2017 Bhattacharya P, Heiden ZM, Wiedner ES, Raugei S, Piro NA, Kassel WS, Bullock RM, Mock MT. Ammonia Oxidation by Abstraction of Three Hydrogen Atoms from a Mo-NH3 Complex. Journal of the American Chemical Society. PMID 28166403 DOI: 10.1021/jacs.7b00002  0.64
2016 Cardenas AJ, Ginovska B, Kumar N, Hou J, Raugei S, Helm ML, Appel AM, Bullock RM, O'Hagan M. Controlling Proton Delivery through Catalyst Structural Dynamics. Angewandte Chemie (International Ed. in English). PMID 27677094 DOI: 10.1002/anie.201607460  0.64
2016 Wiedner ES, Chambers MB, Pitman CL, Bullock RM, Miller AJ, Appel AM. Thermodynamic Hydricity of Transition Metal Hydrides. Chemical Reviews. PMID 27483171 DOI: 10.1021/acs.chemrev.6b00168  0.48
2016 Egbert JD, O'Hagan M, Wiedner ES, Bullock RM, Piro NA, Kassel WS, Mock MT. Putting chromium on the map for N2 reduction: production of hydrazine and ammonia. A study of cis-M(N2)2 (M = Cr, Mo, W) bis(diphosphine) complexes. Chemical Communications (Cambridge, England). PMID 27331373 DOI: 10.1039/c6cc03449g  1
2016 Wiedner ES, Bullock RM. Electrochemical Detection of Transient Cobalt Hydride Intermediates of Electrocatalytic Hydrogen Production. Journal of the American Chemical Society. PMID 27300721 DOI: 10.1021/jacs.6b04779  1
2016 Zhang S, Li H, Appel AM, Hall MB, Bullock M. Facile P-C/C-H Bond Cleavage Reactivity of Nickel Bis(diphosphine) Complexes. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 27189413 DOI: 10.1002/chem.201601469  1
2016 Pruski M, Sadow AD, Slowing II, Marshall CL, Stair P, Rodriguez J, Harris A, Somorjai GA, Biener J, Matranga C, Wang C, Schaidle JA, Beckham GT, Ruddy DA, Deutsch T, ... ... Bullock RM, et al. Virtual Special Issue on Catalysis at the U.S. Department of Energy's National Laboratories Acs Catalysis. 6: 3227-3235. DOI: 10.1021/acscatal.6b00823  1
2015 Raugei S, Helm ML, Hammes-Schiffer S, Appel AM, O'Hagan M, Wiedner ES, Bullock RM. Experimental and Computational Mechanistic Studies Guiding the Rational Design of Molecular Electrocatalysts for Production and Oxidation of Hydrogen. Inorganic Chemistry. PMID 26653114 DOI: 10.1021/acs.inorgchem.5b02262  1
2015 Bullock RM, Helm ML. Molecular Electrocatalysts for Oxidation of Hydrogen Using Earth-Abundant Metals: Shoving Protons Around with Proton Relays. Accounts of Chemical Research. PMID 26079983 DOI: 10.1021/acs.accounts.5b00069  1
2015 Zhang S, Bullock RM. Molybdenum Hydride and Dihydride Complexes Bearing Diphosphine Ligands with a Pendant Amine: Formation of Complexes with Bound Amines. Inorganic Chemistry. 54: 6397-409. PMID 26054002 DOI: 10.1021/acs.inorgchem.5b00728  1
2015 Ho MH, O'Hagan M, Dupuis M, DuBois DL, Bullock RM, Shaw WJ, Raugei S. Water-assisted proton delivery and removal in bio-inspired hydrogen production catalysts. Dalton Transactions (Cambridge, England : 2003). 44: 10969-79. PMID 25999141 DOI: 10.1039/c5dt00782h  1
2015 Mock MT, Pierpont AW, Egbert JD, O'Hagan M, Chen S, Bullock RM, Dougherty WG, Kassel WS, Rousseau R. Protonation studies of a mono-dinitrogen complex of chromium supported by a 12-membered phosphorus macrocycle containing pendant amines. Inorganic Chemistry. 54: 4827-39. PMID 25933172 DOI: 10.1021/acs.inorgchem.5b00351  1
2015 Das AK, Engelhard MH, Lense S, Roberts JA, Bullock RM. Covalent attachment of diphosphine ligands to glassy carbon electrodes via Cu-catalyzed alkyne-azide cycloaddition. Metallation with Ni(ii). Dalton Transactions (Cambridge, England : 2003). 44: 12225-33. PMID 25811536 DOI: 10.1039/c5dt00162e  1
2015 Raugei S, DuBois DL, Rousseau R, Chen S, Ho MH, Bullock RM, Dupuis M. Toward molecular catalysts by computer. Accounts of Chemical Research. 48: 248-55. PMID 25574854 DOI: 10.1021/ar500342g  1
2015 Darmon JM, Kumar N, Hulley EB, Weiss CJ, Raugei S, Bullock RM, Helm ML. Increasing the rate of hydrogen oxidation without increasing the overpotential: A bio-inspired iron molecular electrocatalyst with an outer coordination sphere proton relay Chemical Science. 6: 2737-2745. DOI: 10.1039/c5sc00398a  1
2015 Liu T, Liao Q, O'Hagan M, Hulley EB, DuBois DL, Bullock RM. Iron Complexes Bearing Diphosphine Ligands with Positioned Pendant Amines as Electrocatalysts for the Oxidation of H2 Organometallics. 34: 2747-2764. DOI: 10.1021/om501289f  1
2015 Brown HJS, Wiese S, Roberts JAS, Bullock RM, Helm ML. Electrocatalytic hydrogen production by [Ni(7PPh 2NH)2]2+: Removing the Distinction between endo- and exo-protonation sites Acs Catalysis. 5: 2116-2123. DOI: 10.1021/cs502132y  1
2015 Hulley EB, Kumar N, Raugei S, Bullock RM. Manganese-Based Molecular Electrocatalysts for Oxidation of Hydrogen Acs Catalysis. 5: 6838-6847. DOI: 10.1021/acscatal.5b01751  1
2015 Ho MH, Rousseau R, Roberts JAS, Wiedner ES, Dupuis M, Dubois DL, Bullock RM, Raugei S. Ab Initio-Based Kinetic Modeling for the Design of Molecular Catalysts: The Case of H2 Production Electrocatalysts Acs Catalysis. 5: 5436-5452. DOI: 10.1021/acscatal.5b01152  1
2015 Labios LA, Weiss CJ, Egbert JD, Lense S, Bullock RM, Dougherty WG, Kassel WS, Mock MT. Synthesis and Protonation studies of molybdenum(0) bis(dinitrogen) complexes supported by diphosphine ligands containing pendant amines Zeitschrift Fur Anorganische Und Allgemeine Chemie. 641: 105-117. DOI: 10.1002/zaac.201400119  1
2014 Das AK, Engelhard MH, Bullock RM, Roberts JA. A hydrogen-evolving Ni(P2N2)2 electrocatalyst covalently attached to a glassy carbon electrode: preparation, characterization, and catalysis. comparisons with the homogeneous analogue. Inorganic Chemistry. 53: 6875-85. PMID 24971843 DOI: 10.1021/ic500701a  1
2014 Liu T, Wang X, Hoffmann C, DuBois DL, Bullock RM. Heterolytic cleavage of hydrogen by an iron hydrogenase model: an Fe-Hâ‹…â‹…â‹…H-N dihydrogen bond characterized by neutron diffraction. Angewandte Chemie (International Ed. in English). 53: 5300-4. PMID 24757087 DOI: 10.1002/anie.201402090  1
2014 Bullock RM, Appel AM, Helm ML. Production of hydrogen by electrocatalysis: making the H-H bond by combining protons and hydrides. Chemical Communications (Cambridge, England). 50: 3125-43. PMID 24448464 DOI: 10.1039/c3cc46135a  0.64
2014 Hulley EB, Helm ML, Bullock RM. Heterolytic cleavage of H2 by bifunctional manganese(i) complexes: Impact of ligand dynamics, electrophilicity, and base positioning Chemical Science. 5: 4729-4741. DOI: 10.1039/c4sc01801j  1
2014 Hou J, Fang M, Cardenas AJP, Shaw WJ, Helm ML, Bullock RM, Roberts JAS, O'Hagan M. Electrocatalytic H2 production with a turnover frequency >107 s-1: The medium provides an increase in rate but not overpotential Energy and Environmental Science. 7: 4013-4017. DOI: 10.1039/c4ee01899k  1
2014 Liu T, Dubois MR, Dubois DL, Bullock RM. Electrochemical oxidation of H2 catalyzed by ruthenium hydride complexes bearing P2N2 ligands with pendant amines as proton relays Energy and Environmental Science. 7: 3630-3639. DOI: 10.1039/c4ee01262c  1
2014 Bullock RM, Appel AM, Helm ML. Production of hydrogen by electrocatalysis: Making the H-H bond by combining protons and hydrides Chemical Communications. 50: 3125-3143. DOI: 10.1039/c3cc46135a  1
2014 Fang M, Wiedner ES, Dougherty WG, Kassel WS, Liu T, Dubois DL, Bullock RM. Cobalt complexes containing pendant amines in the second coordination sphere as electrocatalysts for H2 production Organometallics. 33: 5820-5833. DOI: 10.1021/om5004607  1
2014 Laws DR, Bullock RM, Lee R, Huang KW, Geiger WE. Comparison of the one-electron oxidations of CO-bridged vs unbridged bimetallic complexes: Electron-transfer chemistry of Os2Cp2(CO)4 and Os2Cp2(μ-CO)2(CO)2 (Cp = η5-C5H5, Cp = η5-C5Me5) Organometallics. 33: 4716-4728. DOI: 10.1021/om401213y  1
2014 Weiss CJ, Egbert JD, Chen S, Helm ML, Bullock RM, Mock MT. Protonation studies of a tungsten dinitrogen complex supported by a diphosphine ligand containing a pendant amine Organometallics. 33: 2189-2200. DOI: 10.1021/om401127v  1
2014 Heiden ZM, Chen S, Labios LA, Bullock RM, Walter ED, Tyson EL, Mock MT. Proton and electron additions to Iron(II) dinitrogen complexes containing pendant amines Organometallics. 33: 1333-1336. DOI: 10.1021/om401089d  1
2014 Lewandowska-Andralojc A, Grills DC, Zhang J, Bullock RM, Miyazawa A, Kawanishi Y, Fujita E. Kinetic and mechanistic studies of carbon-to-metal hydrogen atom transfer involving os-centered radicals: Evidence for tunneling Journal of the American Chemical Society. 136: 3572-3578. DOI: 10.1021/ja4123076  1
2014 Darmon JM, Raugei S, Liu T, Hulley EB, Weiss CJ, Bullock RM, Helm ML. Iron complexes for the electrocatalytic oxidation of hydrogen: Tuning primary and secondary coordination spheres Acs Catalysis. 4: 1246-1260. DOI: 10.1021/cs500290w  1
2014 Chen S, Ho MH, Bullock RM, Dubois DL, Dupuis M, Rousseau R, Raugei S. Computing free energy landscapes: Application to Ni-based electrocatalysts with pendant amines for H2 production and oxidation Acs Catalysis. 4: 229-242. DOI: 10.1021/cs401104w  1
2013 Ho MH, Raugei S, Rousseau R, Dupuis M, Bullock RM. Evaluation of the Role of Water in the H2 Bond Formation by Ni(II)-Based Electrocatalysts. Journal of Chemical Theory and Computation. 9: 3505-14. PMID 26584107 DOI: 10.1021/ct400396s  0.44
2013 Bullock RM. Chemistry. Abundant metals give precious hydrogenation performance. Science (New York, N.Y.). 342: 1054-5. PMID 24288322 DOI: 10.1126/science.1247240  1
2013 Wiedner ES, Appel AM, DuBois DL, Bullock RM. Thermochemical and mechanistic studies of electrocatalytic hydrogen production by cobalt complexes containing pendant amines. Inorganic Chemistry. 52: 14391-403. PMID 24261463 DOI: 10.1021/ic4025475  1
2013 Das AK, Engelhard MH, Liu F, Bullock RM, Roberts JAS. The electrode as organolithium reagent: Catalyst-free covalent attachment of electrochemically active species to an azide-terminated glassy carbon electrode surface Inorganic Chemistry. 52: 13674-13684. PMID 24228741 DOI: 10.1021/ic402247n  1
2013 Wiedner ES, Roberts JA, Dougherty WG, Kassel WS, DuBois DL, Bullock RM. Synthesis and electrochemical studies of cobalt(III) monohydride complexes containing pendant amines. Inorganic Chemistry. 52: 9975-88. PMID 23945020 DOI: 10.1021/ic401232g  1
2013 van der Eide EF, Yang P, Bullock RM. Isolation of two agostic isomers of an organometallic cation: different structures and colors. Angewandte Chemie (International Ed. in English). 52: 10190-4. PMID 23897712 DOI: 10.1002/anie.201305032  0.32
2013 Hulley EB, Welch KD, Appel AM, DuBois DL, Bullock RM. Rapid, reversible heterolytic cleavage of bound H2. Journal of the American Chemical Society. 135: 11736-9. PMID 23889300 DOI: 10.1021/ja405755j  1
2013 Mock MT, Chen S, O'Hagan M, Rousseau R, Dougherty WG, Kassel WS, Bullock RM. Dinitrogen reduction by a chromium(0) complex supported by a 16-membered phosphorus macrocycle. Journal of the American Chemical Society. 135: 11493-6. PMID 23865433 DOI: 10.1021/ja405668u  0.36
2013 Yang JY, Smith SE, Liu T, Dougherty WG, Hoffert WA, Kassel WS, Rakowski DuBois M, DuBois DL, Bullock RM. Two pathways for electrocatalytic oxidation of hydrogen by a nickel bis(diphosphine) complex with pendant amines in the second coordination sphere. Journal of the American Chemical Society. 135: 9700-12. PMID 23631473 DOI: 10.1021/ja400705a  1
2013 Heiden ZM, Chen S, Mock MT, Dougherty WG, Kassel WS, Rousseau R, Bullock RM. Protonation of ferrous dinitrogen complexes containing a diphosphine ligand with a pendent amine. Inorganic Chemistry. 52: 4026-39. PMID 23506204 DOI: 10.1021/ic4000704  0.64
2013 Liu T, Dubois DL, Bullock RM. An iron complex with pendent amines as a molecular electrocatalyst for oxidation of hydrogen. Nature Chemistry. 5: 228-233. PMID 23422565 DOI: 10.1038/nchem.1571  1
2013 Stewart MP, Ho MH, Wiese S, Lindstrom ML, Thogerson CE, Raugei S, Bullock RM, Helm ML. High catalytic rates for hydrogen production using nickel electrocatalysts with seven-membered cyclic diphosphine ligands containing one pendant amine. Journal of the American Chemical Society. 135: 6033-46. PMID 23384205 DOI: 10.1021/ja400181a  0.64
2013 van der Eide EF, Helm ML, Walter ED, Bullock RM. Structural and spectroscopic characterization of 17- and 18-electron piano-stool complexes of chromium. Thermochemical analyses of weak Cr-H bonds. Inorganic Chemistry. 52: 1591-603. PMID 23343354 DOI: 10.1021/ic302460y  1
2013 Franz JA, O'Hagan M, Ho MH, Liu T, Helm ML, Lense S, Dubois DL, Shaw WJ, Appel AM, Raugei S, Bullock RM. Conformational dynamics and proton relay positioning in nickel catalysts for hydrogen production and oxidation Organometallics. 32: 7034-7042. DOI: 10.1021/om400695w  1
2013 Van Der Eide EF, Hou GL, Deng SHM, Wen H, Yang P, Bullock RM, Wang XB. Metal-centered 17-electron radicals CpM(CO)3 • (M = Cr, Mo, W): A combined negative ion photoelectron spectroscopic and theoretical study Organometallics. 32: 2084-2091. DOI: 10.1021/om3011454  1
2013 Stewart MP, Ho MH, Wiese S, Lindstrom ML, Thogerson CE, Raugei S, Bullock RM, Helm ML. High catalytic rates for hydrogen production using nickel electrocatalysts with seven-membered cyclic diphosphine ligands containing one pendant amine Journal of the American Chemical Society. 135: 6033-6046. DOI: 10.1021/ja400181a  1
2013 Heiden ZM, Chen S, Mock MT, Dougherty WG, Kassel WS, Rousseau R, Bullock RM. Protonation of ferrous dinitrogen complexes containing a diphosphine ligand with a pendent amine Inorganic Chemistry. 52: 4026-4039. DOI: 10.1021/ic4000704  1
2013 Roberts JAS, Bullock RM. Direct determination of equilibrium potentials for hydrogen oxidation/production by open circuit potential measurements in acetonitrile Inorganic Chemistry. 52: 3823-3835. DOI: 10.1021/ic302461q  1
2013 Ho MH, Raugei S, Rousseau R, Dupuis M, Bullock RM. Evaluation of the role of water in the H2 bond formation by Ni(II)-based electrocatalysts Journal of Chemical Theory and Computation. 9: 3505-3514. DOI: 10.1021/ct400396s  1
2013 Wiese S, Kilgore UJ, Ho MH, Raugei S, Dubois DL, Bullock RM, Helm ML. Hydrogen production using nickel electrocatalysts with pendant amines: Ligand effects on rates and overpotentials Acs Catalysis. 3: 2527-2535. DOI: 10.1021/cs400638f  1
2013 Ho MH, Chen S, Rousseau R, Dupuis M, Bullock RM, Raugei S. Bio-inspired molecular catalysts for hydrogen oxidation and hydrogen production Acs Symposium Series. 1133: 89-111. DOI: 10.1021/bk-2013-1133.ch006  1
2013 Van Der Eide EF, Yang P, Bullock RM. Isolation of two agostic isomers of an organometallic cation: Different structures and colors Angewandte Chemie - International Edition. 52: 10190-10194. DOI: 10.1002/anie.201305032  1
2012 O'Hagan M, Ho MH, Yang JY, Appel AM, Rakowski DuBois M, Raugei S, Shaw WJ, DuBois DL, Bullock RM. Proton delivery and removal in [Ni(P(R)2N(R')2)2]2+ hydrogen production and oxidation catalysts. Journal of the American Chemical Society. 134: 19409-24. PMID 23072436 DOI: 10.1021/ja307413x  1
2012 van der Eide EF, Yang P, Walter ED, Liu T, Bullock RM. Dinuclear metalloradicals featuring unsupported metal-metal bonds. Angewandte Chemie (International Ed. in English). 51: 8361-4. PMID 22821475 DOI: 10.1002/anie.201203531  1
2012 Pool DH, Stewart MP, O'Hagan M, Shaw WJ, Roberts JA, Bullock RM, DuBois DL. Acidic ionic liquid/water solution as both medium and proton source for electrocatalytic H2 evolution by [Ni(P2N2)2]2+ complexes. Proceedings of the National Academy of Sciences of the United States of America. 109: 15634-9. PMID 22685211 DOI: 10.1073/pnas.1120208109  1
2012 Raugei S, Chen S, Ho MH, Ginovska-Pangovska B, Rousseau RJ, Dupuis M, DuBois DL, Bullock RM. The role of pendant amines in the breaking and forming of molecular hydrogen catalyzed by nickel complexes. Chemistry (Weinheim An Der Bergstrasse, Germany). 18: 6493-506. PMID 22532421 DOI: 10.1002/chem.201103346  1
2012 Liu T, Chen S, O'Hagan MJ, Rakowski DuBois M, Bullock RM, DuBois DL. Synthesis, characterization, and reactivity of Fe complexes containing cyclic diazadiphosphine ligands: the role of the pendant base in heterolytic cleavage of H2. Journal of the American Chemical Society. 134: 6257-72. PMID 22394350 DOI: 10.1021/ja211193j  1
2012 Weiss CJ, Groves AN, Mock MT, Dougherty WG, Kassel WS, Helm ML, DuBois DL, Bullock RM. Synthesis and reactivity of molybdenum and tungsten bis(dinitrogen) complexes supported by diphosphine chelates containing pendant amines. Dalton Transactions (Cambridge, England : 2003). 41: 4517-29. PMID 22344347 DOI: 10.1039/c2dt12224c  1
2012 Smith SE, Yang JY, DuBois DL, Bullock RM. Reversible electrocatalytic production and oxidation of hydrogen at low overpotentials by a functional hydrogenase mimic. Angewandte Chemie (International Ed. in English). 51: 3152-5. PMID 22334352 DOI: 10.1002/anie.201108461  1
2012 Van Der Eide EF, Liu T, Camaioni DM, Walter ED, Bullock RM. Facile thermal W-W bond homolysis in the N-heterocyclic carbene containing tungsten dimer [CpW(CO) 2(IMe)] 2 Organometallics. 31: 1775-1789. DOI: 10.1021/om201162g  1
2012 Wiedner ES, Yang JY, Chen S, Raugei S, Dougherty WG, Kassel WS, Helm ML, Bullock RM, DuBois MR, DuBois DL. Stabilization of nickel complexes with Ni 0H-N bonding interactions using sterically demanding cyclic diphosphine ligands Organometallics. 31: 144-156. DOI: 10.1021/om200709z  1
2012 Wiese S, Kilgore UJ, Dubois DL, Bullock RM. [Ni(P Me 2N Ph 2) 2] (BF 4) 2 as an electrocatalyst for H 2 production Acs Catalysis. 2: 720-727. DOI: 10.1021/cs300019h  1
2011 Kilgore UJ, Stewart MP, Helm ML, Dougherty WG, Kassel WS, DuBois MR, DuBois DL, Bullock RM. Studies of a series of [Ni(P(R)2N(Ph)2)2(CH3CN)]2+ complexes as electrocatalysts for H2 production: substituent variation at the phosphorus atom of the P2N2 ligand. Inorganic Chemistry. 50: 10908-18. PMID 21999814 DOI: 10.1021/ic201461a  1
2011 Mock MT, Chen S, Rousseau R, O'Hagan MJ, Dougherty WG, Kassel WS, DuBois DL, Bullock RM. A rare terminal dinitrogen complex of chromium. Chemical Communications (Cambridge, England). 47: 12212-4. PMID 21993453 DOI: 10.1039/c1cc15430c  1
2011 Helm ML, Stewart MP, Bullock RM, DuBois MR, DuBois DL. A synthetic nickel electrocatalyst with a turnover frequency above 100,000 s⁻¹ for H₂ production. Science (New York, N.Y.). 333: 863-6. PMID 21836012 DOI: 10.1126/science.1205864  1
2011 Roberts JA, Franz JA, van der Eide EF, Walter ED, Petersen JL, DuBois DL, Bullock RM. Comproportionation of cationic and anionic tungsten complexes having an N-heterocyclic carbene ligand to give the isolable 17-electron tungsten radical CpW(CO)2(IMes)(•). Journal of the American Chemical Society. 133: 14593-603. PMID 21786753 DOI: 10.1021/ja202754e  1
2011 Roberts JA, Appel AM, DuBois DL, Bullock RM. Comprehensive thermochemistry of W-H bonding in the metal hydrides CpW(CO)2(IMes)H, [CpW(CO)2(IMes)H](•+), and [CpW(CO)2(IMes)(H)2]+. Influence of an N-heterocyclic carbene ligand on metal hydride bond energies. Journal of the American Chemical Society. 133: 14604-13. PMID 21780811 DOI: 10.1021/ja202830w  1
2011 O'Hagan M, Shaw WJ, Raugei S, Chen S, Yang JY, Kilgore UJ, DuBois DL, Bullock RM. Moving protons with pendant amines: proton mobility in a nickel catalyst for oxidation of hydrogen. Journal of the American Chemical Society. 133: 14301-12. PMID 21595478 DOI: 10.1021/ja201838x  1
2011 Dupuis M, Chen S, Raugei S, DuBois DL, Bullock RM. Comment on "New insights in the electrocatalytic proton reduction and hydrogen oxidation by bioinspired catalysts: a DFT investigation". The Journal of Physical Chemistry. A. 115: 4861-5. PMID 21504191 DOI: 10.1021/jp111479z  1
2011 Bullock RM. A mercurial route to a cobalt dihydrogen complex. Angewandte Chemie (International Ed. in English). 50: 4050-2. PMID 21452184 DOI: 10.1002/anie.201006731  1
2011 Kilgore UJ, Roberts JA, Pool DH, Appel AM, Stewart MP, DuBois MR, Dougherty WG, Kassel WS, Bullock RM, DuBois DL. [Ni(P(Ph)2N(C6H4X)2)2]2+ complexes as electrocatalysts for H2 production: effect of substituents, acids, and water on catalytic rates. Journal of the American Chemical Society. 133: 5861-72. PMID 21438562 DOI: 10.1021/ja109755f  1
2011 Yang JY, Bullock RM, DuBois MR, DuBois DL. Fast and efficient molecular electrocatalysts for H2 production: Using hydrogenase enzymes as guides Mrs Bulletin. 36: 39-47. DOI: 10.1557/mrs.2010.8  1
2011 Chen S, Rousseau R, Raugei S, Dupuis M, DuBois DL, Bullock RM. Comprehensive thermodynamics of nickel hydride bis(diphosphine) complexes: A predictive model through computations Organometallics. 30: 6108-6118. DOI: 10.1021/om200645x  1
2011 Roberts JAS, Dubois DL, Bullock RM. Experimental and digital simulation studies of the electrochemical oxidation of the metal anion [CpW(CO)2(IMes)]- and the 17-electron metal radical CpW(CO)2(IMes)•. Kinetics and thermodynamics of capture and release of MeCN by a metal radical and a metal cation Organometallics. 30: 4555-4563. DOI: 10.1021/om2002816  1
2011 Appel AM, Pool DH, O'Hagan M, Shaw WJ, Yang JY, Rakowski Dubois M, Dubois DL, Bullock RM. [Ni(PPh 2NBn 2) 2(CH3CN)]2+ as an electrocatalyst for H 2 production: Dependence on acid strength and isomer distribution Acs Catalysis. 1: 777-785. DOI: 10.1021/cs2000939  1
2011 DuBois DL, Morris Bullock R. Molecular electrocatalysts for the oxidation of hydrogen and the production of hydrogen - The role of pendant amines as proton relays European Journal of Inorganic Chemistry. 1017-1027. DOI: 10.1002/ejic.201001081  0.76
2011 Raugei S, Chen S, Ho M, Rousseau R, Dupuis M, Dubois DL, Bullock RM. Ni(II) complexes for hydrogen oxidation and hydrogen production: An ab-initio molecular dynamics investigation Acs National Meeting Book of Abstracts 1
2011 Yang J, Smith SE, O'Hagan M, Kilgore UJ, Dubois MR, Bullock RM, Dubois DL. Molecular nickel diphosphine electrocatalysts for hydrogen oxidation and production: The function of proton relays in the secondary coordination sphere Acs National Meeting Book of Abstracts 1
2011 Bullock RM, Yang JY, Roberts JAS, Kilgore UJ, Helm ML, Smith SE, Stewart MP, Dubois DL. Nickel(II) electrocatalysts with pendant amines as proton relays for production of hydrogen and oxidation of hydrogen Acs National Meeting Book of Abstracts 1
2011 Bullock RM, Yang JY, Roberts JAS, Kilgore UJ, Wiedner ES, Liu T, Dubois DL. Nickel and cobalt catalysts for production of H2 and oxidation of H2: Shoving protons around with pendant amines Acs National Meeting Book of Abstracts 1
2011 Mock MT, Groves AN, Weiss CJ, Chen S, Rousseau R, Dubois DL, Bullock RM. Group 6 dinitrogen complexes supported by diphosphine ligands containing proton relays: Toward the reduction of dinitrogen to ammonia Acs National Meeting Book of Abstracts 1
2011 Yang JY, O'Hagan M, Shaw W, Appel A, Smith S, Bullock RM, DuBois MR, DuBois DL. Role of proton relays in molecular electrocatalysts for hydrogen oxidation and production Acs National Meeting Book of Abstracts 1
2010 Chen S, Raugei S, Rousseau R, Dupuis M, Bullock RM. Homogeneous Ni catalysts for H2 oxidation and production: an assessment of theoretical methods, from density functional theory to post Hartree-Fock correlated wave-function theory. The Journal of Physical Chemistry. A. 114: 12716-24. PMID 21070021 DOI: 10.1021/jp106800n  1
2010 Yang JY, Chen S, Dougherty WG, Kassel WS, Bullock RM, DuBois DL, Raugei S, Rousseau R, Dupuis M, Rakowski DuBois M. Hydrogen oxidation catalysis by a nickel diphosphine complex with pendant tert-butyl amines. Chemical Communications (Cambridge, England). 46: 8618-20. PMID 20938535 DOI: 10.1039/c0cc03246h  1
2010 Yang JY, Bullock RM, Dougherty WG, Kassel WS, Twamley B, DuBois DL, Rakowski DuBois M. Reduction of oxygen catalyzed by nickel diphosphine complexes with positioned pendant amines. Dalton Transactions (Cambridge, England : 2003). 39: 3001-10. PMID 20221533 DOI: 10.1039/b921245k  1
2010 Welch KD, Dougherty WG, Kassel WS, Dubois DL, Bullock RM. Synthesis, structures, and reactions of manganese complexes containing diphosphine ligands with pendant amines Organometallics. 29: 4532-4540. DOI: 10.1021/om100668e  1
2010 Wiedner ES, Yang JY, Dougherty WG, Kassel WS, Bullock RM, Dubois MR, Dubois DL. Comparison of cobalt and nickel complexes with sterically demanding cyclic diphosphine ligands: Electrocatalytic H2 production by [Co(P tBu 2NPh 2)(CH3CN) 3](BF4)2 Organometallics. 29: 5390-5401. DOI: 10.1021/om100395r  1
2010 Bullock RM. Molybdenum and Tungsten Catalysts for Hydrogenation, Hydrosilylation and Hydrolysis Catalysis Without Precious Metals. 51-81. DOI: 10.1002/9783527631582.ch3  1
2010 Bullock RM. Catalysis without Precious Metals Catalysis Without Precious Metals. DOI: 10.1002/9783527631582  1
2010 Dubois DL, Dubois MCR, Bullock RM. Modular approach to molecular electrocatalysts for H2 production and oxidation Acs National Meeting Book of Abstracts 1
2010 Bullock RM, Yang JY, Wiedner ES, Welch KD, Dubois DL. Molecular catalysts for oxidation of hydrogen and production of hydrogen: Shoving protons around with pendant amines Acs National Meeting Book of Abstracts 1
2010 Rakowski-DuBois M, Dubois D, Bullock RM. Nickel catalysts for hydrogen oxidation and production containing diphosphine ligands with pendant amine bases Acs National Meeting Book of Abstracts 1
2009 Ghosh P, Fagan PJ, Marshall WJ, Hauptman E, Bullock RM. Synthesis of ruthenium carbonyl complexes with phosphine or substituted Cp ligands, and their activity in the catalytic deoxygenation of 1,2-propanediol. Inorganic Chemistry. 48: 6490-500. PMID 19548688 DOI: 10.1021/ic900413y  1
2009 Yang JY, Bullock RM, Shaw WJ, Twamley B, Fraze K, DuBois MR, DuBois DL. Mechanistic insights into catalytic h(2) oxidation by ni complexes containing a diphosphine ligand with a positioned amine base. Journal of the American Chemical Society. 131: 5935-45. PMID 19341269 DOI: 10.1021/ja900483x  1
2008 Jacobsen GM, Yang JY, Twamley B, Wilson AD, Bullock RM, Rakowski Dubois M, Dubois DL. Hydrogen production using cobalt-based molecular catalysts containing a proton relay in the second coordination sphere Energy and Environmental Science. 1: 167-174. DOI: 10.1039/b805309j  1
2008 Cheng TY, Szalda DJ, Hanson JC, Muckerman JT, Bullock RM. Four-electron-donor hemilabile η3-PPh3 ligand that binds through a C=C bond rather than an agostic C-H interaction, and displacement of the C=C by methyl iodide or water Organometallics. 27: 3785-3795. DOI: 10.1021/om800401d  1
2008 Bullock RM. Ionic Hydrogenations The Handbook of Homogeneous Hydrogenation. 153-197. DOI: 10.1002/9783527619382.ch7  1
2007 Bullock RM. An iron catalyst for ketone hydrogenations under mild conditions. Angewandte Chemie (International Ed. in English). 46: 7360-3. PMID 17847139 DOI: 10.1002/anie.200703053  1
2007 Wu F, Dioumaev VK, Szalda DJ, Hanson J, Bullock RM. A tungsten complex with a bidentate, hemilabile N-heterocyclic carbene ligand, facile displacement of the weakly bound W-(C=C) bond, and the vulnerability of the NHC ligand toward catalyst deactivation during ketone hydrogenation Organometallics. 26: 5079-5090. DOI: 10.1021/om700694e  1
2007 Egbert JD, Bullock RM, Heinekey DM. Cationic dihydrogen/dihydride complexes of osmium: Structure and dynamics Organometallics. 26: 2291-2295. DOI: 10.1021/om0700718  1
2006 Cheng TY, Szalda DJ, Zhang J, Bullock RM. Synthesis and structure of CpMo(CO)(dppe)H and its oxidation by Ph3C+. Inorganic Chemistry. 45: 4712-20. PMID 16749835 DOI: 10.1021/ic060111k  1
2006 Zhang J, Huang KW, Szalda DJ, Bullock RM. Efficient synthesis of the Os-Os dimers [Cp(CO) 2Os] 2, [Cp*(CO) 2Os] 2, and [ iPr 4C 5H(CO) 2Os] 2and computational studies on the relative stabilities of their geometrical isomers Organometallics. 25: 2209-2215. DOI: 10.1021/om060075x  1
2005 Zhang J, Grills DC, Huang KW, Fujita E, Bullock RM. Carbon-to-metal hydrogen atom transfer: direct observation using time-resolved infrared spectroscopy. Journal of the American Chemical Society. 127: 15684-5. PMID 16277493 DOI: 10.1021/ja0555724  1
2005 Kimmich BFM, Fagan PJ, Hauptman E, Marshall WJ, Bullock RM. Molybdenum carbonyl complexes in the solvent-free catalytic hydrogenation of ketones Organometallics. 24: 6220-6229. DOI: 10.1021/om050564h  1
2004 Bullock RM. Catalytic ionic hydrogenations. Chemistry (Weinheim An Der Bergstrasse, Germany). 10: 2366-74. PMID 15146510 DOI: 10.1002/chem.200305639  1
2004 Kimmich BF, Fagan PJ, Hauptman E, Bullock RM. Solvent-free ketone hydrogenations catalyzed by molybdenum complexes. Chemical Communications (Cambridge, England). 1014-5. PMID 15069521 DOI: 10.1039/b401760a  0.4
2003 Dioumaev VK, Bullock RM. A recyclable catalyst that precipitates at the end of the reaction. Nature. 424: 530-2. PMID 12891351 DOI: 10.1038/nature01856  1
2002 Voges MH, Bullock RM. Catalytic ionic hydrogenations of ketones using molybdenum and tungsten complexes Journal of the Chemical Society, Dalton Transactions. 759-770. DOI: 10.1039/b107754f  1
2002 Cheng TY, Bullock RM. Hydride transfer from (η5-C5Me5)(CO)2MH (M = Fe, Ru, Os) to trityl cation: Different products from different metals and the kinetics of hydride transfer Organometallics. 21: 2325-2331. DOI: 10.1021/om020012o  1
2002 Kimmich BFM, Bullock RM. Protonation of (PCP)PtH to give a dihydrogen complex Organometallics. 21: 1504-1507. DOI: 10.1021/om0108651  1
2001 Schlaf M, Ghosh P, Fagan PJ, Hauptman E, Bullock RM. Metal-Catalyzed Selective Deoxygenation of Diols to Alcohols We thank the U.S. Department of Energy, Office of Science, Laboratory Technology Research Program for support. Research at Brookhaven National Laboratory was carried out under contract DE-AC02-98CH10886 with the U.S. Department of Energy and was additionally supported by its Division of Chemical Sciences, Office of Basic Energy Sciences. We thank Dupont Central Research and Development for additional funding. M.S. thanks the NSERC (Canada) for a postdoctoral fellowship. Angewandte Chemie (International Ed. in English). 40: 3887-3890. PMID 11668564 DOI: 10.1002/1521-3773(20011015)40:20<3887::AID-ANIE3887>3.0.CO;2-Q  0.4
2001 Song JS, Szalda DJ, Bullock RM. Alcohol complexes of tungsten prepared by ionic hydrogenations of ketones Organometallics. 20: 3337-3346. DOI: 10.1021/om010222l  1
2001 Cabelli DE, Shafiq F, Creutz C, Bullock RM. Pulse radiolysis studies of water-soluble tungsten hydride complexes: One-electron reduction of metal hydrides and hydrogen atom transfer reactions Organometallics. 20: 3729-3737. DOI: 10.1021/om0102089  1
2000 Bullock RM, Voges MH. Homogeneous catalysis with inexpensive metals: Ionic hydrogenation of ketones with molybdenum and tungsten catalysts Journal of the American Chemical Society. 122: 12594-12595. DOI: 10.1021/ja0010599  1
1999 Cheng TY, Bullock RM. Isotope effects on hydride transfer reactions from transition metal hydrides to trityl cation. An inverse isotope effect for a hydride transfer Journal of the American Chemical Society. 121: 3150-3155. DOI: 10.1021/ja983448x  1
1998 Cheng TY, Brunschwig BS, Bullock RM. Hydride transfer reactions of transition metal hydrides: Kinetic hydricity of metal carbonyl hydrides Journal of the American Chemical Society. 120: 13121-13137. DOI: 10.1021/ja9820036  1
1996 Song JS, Szalda DJ, Bullock RM. Ether complexes of tungsten with two different binding modes: An O-bound ether and an η 2-(C=C) vinyl ether. Evidence for C-H···O hydrogen bonding of vinylic C-H groups Journal of the American Chemical Society. 118: 11134-11141. DOI: 10.1021/ja962193p  1
1995 Creutz C, Song JS, Bullock RM. Photoinduced atom-transfer reactions between transition-metal centres Pure and Applied Chemistry. 67: 47-54. DOI: 10.1351/pac199567010047  1
1992 Bullock RM, Rappoli BJ. Formation of a manganese alkyl complex as an intermediate in the ring-opening hydroformylation of α-cyclopropylstyrene by HMn(CO)5 Journal of Organometallic Chemistry. 429: 345-368. DOI: 10.1016/0022-328X(92)83184-J  1
1992 Song JS, Szalda DJ, Bullock RM, Lawrie CJC, Rodkin MA, Norton JR. Hydride transfer by hydrido transition-metal complexes. Ionic hydrogenation of aldehydes and ketones, and structural characterization of an alcohol complex Angewandte Chemie (International Edition in English). 31: 1233-1235.  1
1992 Bullock RM, Brammer L, Schultz AJ, Albinati A, Koetzle TF. Low-temperature neutron diffraction study of HMn2Re(CO)14 and studies of a metal metal exchange equilibrium that converts HMn2Re(CO)14 into HMnRe2(CO)14 Journal of the American Chemical Society. 114: 5125-5130.  1
1991 Bullock RM. Metal-Hydrogen Bond Cleavage Reactions of Transition Metal Hydrides: Hydrogen Atom, Hydride, and Proton Transfer Reactions Comments On Inorganic Chemistry. 12: 1-33. DOI: 10.1080/02603599108018617  1
1991 Albinati A, Bullock RM, Rappoli BJ, Koetzle TF. X-ray diffraction study of pentacarbonyl(μ-hydrido)(nonacarbonyldimanganese)rhenium, HMn2Re(CO)14 Inorganic Chemistry. 30: 1414-1417.  1
1989 Bullock RM, Rappoli BJ. Ionic hydrogenations using transition metal hydrides. Rapid hydrogenation of hindered alkenes at low temperature Journal of the Chemical Society, Chemical Communications. 1447-1448. DOI: 10.1039/C39890001447  1
1989 Masnovi J, Samsel EG, Bullock RM. Cyclopropylbenzyl radical clocks Journal of the Chemical Society, Chemical Communications. 1044-1045. DOI: 10.1039/C39890001044  1
1989 Anson CE, Johnson BFG, Lewis J, Powell DB, Sheppard N, Bhattacharyya AK, Bender BR, Bullock RM, Hembre RT, Norton JR. [Os2(CO)822-C 2H4)] as a vibrational model for 1,2-di-σ chemisorbed ethylene on metal surfaces Journal of the Chemical Society, Chemical Communications. 703-705. DOI: 10.1039/C39890000703  1
1989 Bullock RM, Rappoli BJ, Samsel EG, Rheingold AL. Ring-opening hydroformylation of α-cyclopropylstyrene by HMn(CO) <inf>5</inf>, and structure of a novel Mn<inf>2</inf>(CO)<inf>9</inf>(η <sup>1</sup>-aldehyde) complex Journal of the Chemical Society, Chemical Communications. 261-263. DOI: 10.1039/C39890000261  1
1989 Bullock RM. Rearrangement of a metal (η<sup>2</sup>-alkyne) complex to a metal vinylidene and subsequent reaction of the metal vinylidene to regenerate the alkyne Journal of the Chemical Society, Chemical Communications. 165-167. DOI: 10.1039/C39890000165  1
1989 Bullock RM, Headford CEL, Hennessy KM, Kegley SE, Norton JR. Intramolecular hydrogen exchange among the coordinated methane fragments of Cp2W(H)CH3. Evidence for the formation of a σ complex of methane prior to elimination Journal of the American Chemical Society. 111: 3897-3908.  1
1988 Bullock RM, Hembre RT, Norton JR. Synthesis of Os2(CO)8(μ-CHCH3) from a geminal ditriflate and its reversible carbonylation to a ketene-bridged diosmacycle Journal of the American Chemical Society. 110: 7868-7870. DOI: 10.1021/JA00231A043  1
1987 Bullock RM, Casey CP. Heterobimetallic compounds linked by heterodifunctional ligands Accounts of Chemical Research. 20: 167-173.  1
1983 Casey CP, Bullock RM. Protonation of metalmetal bonds in heterobimetallic compounds linked by a heterodifunctional ligand Journal of Organometallic Chemistry. 251: 245-248. DOI: 10.1016/S0022-328X(00)99507-X  1
1983 Casey CP, Bullock RM, Nief F. Synthesis of molybdenum-rhodium and molybdenum-iridium compounds linked by a heterodifunctional ligand and formation of molybdenum-iridium dihydrides by reaction with molecular hydrogen Journal of the American Chemical Society. 105: 7574-7580.  1
1982 Casey CP, Morris Bullock R. Search for heterobimetallic dihydrides from the reaction of H2 with metal-metal bonds Journal of Molecular Catalysis. 14: 283-292. DOI: 10.1016/0304-5102(82)80088-6  0.92
1982 Casey CP, Morris Bullock R, Fultz WC, Rheingold AL. Heterobimetallic compounds linked by heterodifunctional ligands: Synthesis and X-ray crystal structure of (CO)4MnMo(CO)3[η5-C5H 4P(C6H5)2] Organometallics. 1: 1591-1596.  0.48
1981 Casey CP, Bullock RM. Fluxional behavior of (CO)4Fe(u-AsMe2)Mo(CO)2(C5H5) Journal of Organometallic Chemistry. 218. DOI: 10.1016/S0022-328X(00)81015-3  1
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