Igor Larrosa - Publications

Affiliations: 
School of Chemistry University of Manchester, Manchester, England, United Kingdom 

70 high-probability publications. We are testing a new system for linking publications to authors. You can help! If you notice any inaccuracies, please sign in and mark papers as correct or incorrect matches. If you identify any major omissions or other inaccuracies in the publication list, please let us know.

Year Citation  Score
2023 Docherty JH, Lister TM, Mcarthur G, Findlay MT, Domingo-Legarda P, Kenyon J, Choudhary S, Larrosa I. Transition-Metal-Catalyzed C-H Bond Activation for the Formation of C-C Bonds in Complex Molecules. Chemical Reviews. PMID 37163671 DOI: 10.1021/acs.chemrev.2c00888  0.372
2023 Findlay MT, Hogg AS, Douglas JJ, Larrosa I. Improving the sustainability of the ruthenium-catalysed -directed C-H arylation of arenes with aryl halides. Green Chemistry : An International Journal and Green Chemistry Resource : Gc. 25: 2394-2400. PMID 36960441 DOI: 10.1039/d2gc03860a  0.321
2020 Spencer ARA, Korde R, Font M, Larrosa I. -Selective olefination of fluoroarenes with alkynes using CO as a traceless directing group. Chemical Science. 11: 4204-4208. PMID 34122883 DOI: 10.1039/d0sc01138j  0.738
2020 Just-Baringo X, Shin Y, Panigrahi A, Zarattini M, Nagyte V, Zhao L, Kostarelos K, Casiraghi C, Larrosa I. Palladium catalysed C-H arylation of pyrenes: access to a new class of exfoliating agents for water-based graphene dispersions. Chemical Science. 11: 2472-2478. PMID 34084412 DOI: 10.1039/c9sc05101e  0.317
2020 Spencer ARA, Grainger R, Panigrahi A, Lepper TJ, Bentkowska K, Larrosa I. Transition metal-free cross-dehydrogenative arylation of unactivated benzylic C-H bonds. Chemical Communications (Cambridge, England). PMID 33150344 DOI: 10.1039/d0cc06212j  0.397
2020 Panigrahi A, Whitaker D, Vitorica-Yrezabal IJ, Larrosa I. Ag/Pd Cocatalyzed Direct Arylation of Fluoroarene Derivatives with Aryl Bromides. Acs Catalysis. 10: 2100-2107. PMID 32201633 DOI: 10.1021/Acscatal.9B05334  0.409
2020 Spencer ARA, Korde R, Font M, Larrosa I. meta-Selective olefination of fluoroarenes with alkynes using CO2 as a traceless directing group Chemical Science. 11: 4204-4208. DOI: 10.1039/D0Sc01138J  0.691
2020 Wang G, Wheatley M, Simonetti M, Cannas DM, Larrosa I. Cyclometalated Ruthenium Catalyst Enables Ortho-Selective C–H Alkylation with Secondary Alkyl Bromides Chem. 6: 1459-1468. DOI: 10.1016/J.Chempr.2020.04.006  0.425
2019 Batuecas M, Luo J, Gergelitsová I, Krämer K, Whitaker D, Vitorica-Yrezabal IJ, Larrosa I. Catalytic Asymmetric C-H Arylation of (η-Arene)Chromium Complexes: Facile Access to Planar-Chiral Phosphines. Acs Catalysis. 9: 5268-5278. PMID 32064145 DOI: 10.1021/Acscatal.9B00918  0.456
2019 Quibell JM, Duan G, Perry GJP, Larrosa I. Decarboxylative Suzuki-Miyaura coupling of (hetero)aromatic carboxylic acids using iodine as the terminal oxidant. Chemical Communications (Cambridge, England). PMID 31099348 DOI: 10.1039/C9Cc01817D  0.405
2018 Font M, Spencer ARA, Larrosa I. -C-H arylation of fluoroarenes traceless directing group relay strategy. Chemical Science. 9: 7133-7137. PMID 30310635 DOI: 10.1039/C8Sc02417K  0.735
2018 Simonetti M, Kuniyil R, Macgregor SA, Larrosa I. Benzoate cyclometallation enables oxidative addition of haloarenes at a Ru(II) center. Journal of the American Chemical Society. PMID 30134657 DOI: 10.1021/Jacs.8B08150  0.408
2018 Colletto C, Panigrahi A, Fernández-Casado J, Larrosa I. Ag(I)-C-H Activation Enables Near-Room-Temperature Direct α-Arylation of Benzo[ b]thiophenes. Journal of the American Chemical Society. 140: 9638-9643. PMID 29983049 DOI: 10.1021/Jacs.8B05361  0.375
2018 Simonetti M, Cannas DM, Just-Baringo X, Vitorica-Yrezabal IJ, Larrosa I. Cyclometallated ruthenium catalyst enables late-stage directed arylation of pharmaceuticals. Nature Chemistry. 10: 724-731. PMID 29930274 DOI: 10.1055/S-0037-1609800  0.442
2018 Quibell JM, Perry GJP, Cannas DM, Larrosa I. Transition-metal-free decarboxylative bromination of aromatic carboxylic acids. Chemical Science. 9: 3860-3865. PMID 29780518 DOI: 10.1039/C8Sc01016A  0.407
2018 Just-Baringo X, Larrosa I. Ketone C–C Bond Activation Meets the Suzuki-Miyaura Cross-coupling Chem. 4: 1203-1204. DOI: 10.1016/J.Chempr.2018.05.012  0.362
2017 Colletto C, Whitaker D, Larrosa I. Determination of H KIEs from Competition Experiments: Increased Accuracy via Isotopic Enrichment. Topics in Catalysis. 60: 589-593. PMID 32025177 DOI: 10.1007/S11244-017-0740-1  0.332
2017 Perry GJP, Larrosa I. Recent Progress in Decarboxylative Oxidative Cross-Coupling for Biaryl Synthesis. European Journal of Organic Chemistry. 2017: 3517-3527. PMID 29354019 DOI: 10.1002/Ejoc.201700121  0.349
2017 Colletto C, Burés J, Larrosa I. Reaction monitoring reveals poisoning mechanism of Pd(dba) and guides catalyst selection. Chemical Communications (Cambridge, England). 53: 12890-12893. PMID 29143032 DOI: 10.1039/C7Cc08018B  0.414
2017 Whitaker D, Batuecas M, Ricci P, Larrosa I. A Direct Arylation-Cyclization Reaction for the Construction of Medium-Sized Rings. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 28758702 DOI: 10.1002/Chem.201703527  0.426
2017 Perry GJP, Quibell JM, Panigrahi A, Larrosa I. Transition Metal-Free Decarboxylative Iodination: New Routes for Decarboxylative Oxidative Cross-Couplings. Journal of the American Chemical Society. PMID 28735532 DOI: 10.1021/Jacs.7B05155  0.416
2017 Luo J, Larrosa I. C-H carboxylation of aromatic compounds via CO2 fixation. Chemsuschem. PMID 28722818 DOI: 10.1002/Cssc.201701058  0.413
2017 Font M, Quibell JM, Perry GJP, Larrosa I. The use of carboxylic acids as traceless directing groups for regioselective C-H bond functionalisation. Chemical Communications (Cambridge, England). PMID 28492623 DOI: 10.1039/C7Cc01755C  0.731
2017 Simonetti M, Cannas DM, Larrosa I. Chapter Four - Biaryl Synthesis via C–H Bond Activation: Strategies and Methods Advances in Organometallic Chemistry. 67: 299-399. DOI: 10.1016/Bs.Adomc.2017.03.002  0.397
2016 Johnston AJ, Ling KB, Sale D, Lebrasseur N, Larrosa I. Direct ortho-Arylation of Pyridinecarboxylic Acids: Overcoming the Deactivating Effect of sp(2)-Nitrogen. Organic Letters. 18: 6094-6097. PMID 27934340 DOI: 10.1021/Acs.Orglett.6B03085  0.531
2016 Simonetti M, Larrosa I. C-H activation: Good things come in threes. Nature Chemistry. 8: 1086-1088. PMID 27874874 DOI: 10.1038/Nchem.2679  0.462
2016 Simonetti M, Cannas DM, Panigrahi A, Kujawa S, Kryjewski M, Xie P, Larrosa I. Ruthenium-Catalyzed C-H Arylation of Benzoic Acids and Indole Carboxylic Acids with Aryl Halides. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 27798824 DOI: 10.1002/Chem.201605068  0.469
2016 Whitaker D, Burés J, Larrosa I. Ag(I)-catalyzed C-H activation: the role of the Ag(I) salt in Pd/Ag mediated C-H arylation of electron-deficient arenes. Journal of the American Chemical Society. PMID 27303956 DOI: 10.1021/Jacs.6B04726  0.426
2016 Simonetti M, Perry GJ, Cambeiro XC, Juliá-Hernández F, Arokianathar JN, Larrosa I. Ru-Catalyzed C-H Arylation of Fluoroarenes with Aryl Halides. Journal of the American Chemical Society. 138: 3596-606. PMID 26942551 DOI: 10.1021/Jacs.6B01615  0.521
2016 Colletto C, Islam S, Julia-Hernandez F, Larrosa I. Room Temperature Direct β-Arylation of Thiophenes and Benzo[b]thiophenes and Kinetic Evidence for a Heck-type Pathway. Journal of the American Chemical Society. PMID 26788885 DOI: 10.1021/Jacs.5B12242  0.416
2015 Cambeiro XC, Ahlsten N, Larrosa I. Au-Catalyzed Cross-Coupling of Arenes via Double C-H Activation. Journal of the American Chemical Society. 137: 15636-9. PMID 26645996 DOI: 10.1021/Jacs.5B10593  0.473
2015 Luo J, Preciado S, Araromi SO, Larrosa I. A Domino Oxidation/Arylation/Protodecarboxylation Reaction of Salicylaldehydes: Expanded Access to meta-Arylphenols. Chemistry, An Asian Journal. PMID 26097094 DOI: 10.1002/Asia.201500506  0.432
2015 Groombridge BJ, Goldup SM, Larrosa I. Selective and general exhaustive cross-coupling of di-chloroarenes with a deficit of nucleophiles mediated by a Pd-NHC complex. Chemical Communications (Cambridge, England). 51: 3832-4. PMID 25648472 DOI: 10.1039/C4Cc08920K  0.357
2015 Luo J, Preciado S, Larrosa I. Salicylic acids as readily available starting materials for the synthesis of meta-substituted biaryls. Chemical Communications (Cambridge, England). 51: 3127-30. PMID 25600238 DOI: 10.1039/C4Cc09674F  0.375
2014 Ricci P, Krämer K, Larrosa I. Tuning reactivity and site selectivity of simple arenes in C-H activation: ortho-arylation of anisoles via arene-metal π-complexation. Journal of the American Chemical Society. 136: 18082-6. PMID 25510851 DOI: 10.1021/Ja510260J  0.451
2014 Grainger R, Cornella J, Blakemore DC, Larrosa I, Campanera JM. The ortho-substituent effect on the Ag-catalysed decarboxylation of benzoic acids. Chemistry (Weinheim An Der Bergstrasse, Germany). 20: 16680-7. PMID 25336158 DOI: 10.1002/Chem.201402931  0.348
2014 Luo J, Preciado S, Larrosa I. Overriding ortho-para selectivity via a traceless directing group relay strategy: the meta-selective arylation of phenols. Journal of the American Chemical Society. 136: 4109-12. PMID 24612008 DOI: 10.1021/Ja500457S  0.471
2014 Lacerda AM, Larrosa I, Dunn S. Highly Efficient Plasmonic Palladium-Titanium Dioxide Co-Catalyst in the Photodegradation of Rhodamine B Dye Advances in Science and Technology. 93: 184-189. DOI: 10.4028/Www.Scientific.Net/Ast.93.184  0.301
2014 Arroniz C, Denis JG, Ironmonger A, Rassias G, Larrosa I. An organic cation as a silver(i) analogue for the arylation of sp 2 and sp3 C-H bonds with iodoarenes Chemical Science. 5: 3509-3514. DOI: 10.1039/C4Sc01215A  0.433
2013 Islam S, Larrosa I. "On water", phosphine-free palladium-catalyzed room temperature C-H arylation of indoles. Chemistry (Weinheim An Der Bergstrasse, Germany). 19: 15093-6. PMID 24123582 DOI: 10.1002/Chem.201302838  0.386
2013 Juliá-Hernández F, Simonetti M, Larrosa I. Metalation dictates remote regioselectivity: ruthenium-catalyzed functionalization of meta C(Ar)-H Bonds. Angewandte Chemie (International Ed. in English). 52: 11458-60. PMID 24030678 DOI: 10.1002/Anie.201306425  0.466
2013 Ricci P, Krämer K, Cambeiro XC, Larrosa I. Arene-metal π-complexation as a traceless reactivity enhancer for C-H arylation. Journal of the American Chemical Society. 135: 13258-61. PMID 23962336 DOI: 10.1021/Ja405936S  0.421
2013 Arroniz C, Ironmonger A, Rassias G, Larrosa I. Direct ortho-arylation of ortho-substituted benzoic acids: overriding Pd-catalyzed protodecarboxylation. Organic Letters. 15: 910-3. PMID 23373630 DOI: 10.1021/Ol400065J  0.409
2013 Cambeiro XC, Boorman TC, Lu P, Larrosa I. Redox-controlled selectivity of C-H activation in the oxidative cross-coupling of arenes. Angewandte Chemie (International Ed. in English). 52: 1781-4. PMID 23280825 DOI: 10.1002/Anie.201209007  0.387
2013 Ahlsten N, Perry GJP, Cambeiro XC, Boorman TC, Larrosa I. A silver-free system for the direct C–H auration of arenes and heteroarenes from gold chloride complexes Catalysis Science & Technology. 3: 2892. DOI: 10.1039/C3Cy00240C  0.308
2013 Juliá-Hernández F, Simonetti M, Larrosa I. Ferngesteuerte Regioselektivität durch Metallierung: Ruthenium-katalysiertemeta-C-H-Funktionalisierung von Arenen Angewandte Chemie. 125: 11670-11672. DOI: 10.1002/Ange.201306425  0.366
2012 Grainger R, Nikmal A, Cornella J, Larrosa I. Selective deuteration of (hetero)aromatic compounds via deutero-decarboxylation of carboxylic acids. Organic & Biomolecular Chemistry. 10: 3172-4. PMID 22418863 DOI: 10.1039/C2Ob25157D  0.392
2012 Jacques SA, Michaelis S, Gebhardt B, Blum A, Lebrasseur N, Larrosa I, White AJP, Barrett AGM. Studies on the total synthesis of lactonamycin: Synthesis of the fused pentacyclic B-F ring unit European Journal of Organic Chemistry. 107-113. DOI: 10.1002/Ejoc.201101317  0.383
2011 Cornella J, Righi M, Larrosa I. Carboxylic acids as traceless directing groups for formal meta-selective direct arylation. Angewandte Chemie (International Ed. in English). 50: 9429-32. PMID 21948440 DOI: 10.1002/Anie.201103720  0.459
2011 Larrosa I, Somoza C, Banquy A, Goldup SM. Two flavors of PEPPSI-IPr: activation and diffusion control in a single NHC-ligated Pd catalyst? Organic Letters. 13: 146-9. PMID 21133362 DOI: 10.1021/Ol1027283  0.371
2011 Boorman TC, Larrosa I. Gold-mediated C-H bond functionalisation. Chemical Society Reviews. 40: 1910-25. PMID 21103517 DOI: 10.1039/C0Cs00098A  0.442
2011 Boorman TC, Larrosa I. Chapter 1 – Recent Advances in the C-2 Regioselective Direct Arylation of Indoles Progress in Heterocyclic Chemistry. 22: 1-20. DOI: 10.1016/S0959-6380(11)22001-4  0.466
2011 Boorman TC, Larrosa I. Recent Advances in the C-2 Regioselective Direct Arylation of Indoles Advances in Heterocyclic Chemistry. 105: 1-20. DOI: 10.1016/B978-0-12-396530-1.00004-8  0.466
2011 Cornella J, Rosillo-Lopez M, Larrosa I. A Novel Mode of Reactivity for Gold(I): The Decarboxylative Activation of (Hetero)Aromatic Carboxylic Acids Advanced Synthesis & Catalysis. 353: 1359-1366. DOI: 10.1002/Adsc.201100109  0.391
2010 Cornella J, Lahlali H, Larrosa I. Decarboxylative homocoupling of (hetero)aromatic carboxylic acids. Chemical Communications (Cambridge, England). 46: 8276-8. PMID 20882244 DOI: 10.1039/C0Cc01943G  0.389
2010 Lu P, Boorman TC, Slawin AM, Larrosa I. Gold(I)-mediated C-H activation of arenes. Journal of the American Chemical Society. 132: 5580-1. PMID 20364835 DOI: 10.1021/Ja101525W  0.352
2010 Lu P, Sanchez C, Cornella J, Larrosa I. Silver(I)-Catalyzed Decarboxylation of Aromatic CarboxylicAcids Synfacts. 2010: 338-338. DOI: 10.1055/S-0029-1219302  0.374
2009 Lu P, Sanchez C, Cornella J, Larrosa I. Silver-catalyzed protodecarboxylation of heteroaromatic carboxylic acids. Organic Letters. 11: 5710-3. PMID 19924891 DOI: 10.1021/Ol902482P  0.387
2009 Cornella J, Sanchez C, Banawa D, Larrosa I. Silver-catalysed protodecarboxylation of ortho-substituted benzoic acids. Chemical Communications (Cambridge, England). 7176-8. PMID 19921021 DOI: 10.1039/B916646G  0.39
2009 Cornella J, Lu P, Larrosa I. Intermolecular decarboxylative direct C-3 arylation of indoles with benzoic acids. Organic Letters. 11: 5506-9. PMID 19877661 DOI: 10.1021/Ol902304N  0.478
2009 Gálvez E, Larrosa I, Romea P, Urpí F. Stereoselective Synthesis of α-and β-C-Glycosides by Additionof Titanium Enolates to Glycals Synlett. 2009: 2982-2986. DOI: 10.1055/S-0029-1218279  0.32
2008 Lebrasseur N, Larrosa I. Room temperature and phosphine free palladium catalyzed direct C-2 arylation of indoles. Journal of the American Chemical Society. 130: 2926-7. PMID 18278918 DOI: 10.1021/Ja710731A  0.445
2008 Larrosa I, Romea P, Urpí F. Synthesis of six-membered oxygenated heterocycles through carbon–oxygen bond-forming reactions Tetrahedron. 64: 2683-2723. DOI: 10.1016/J.Tet.2007.11.092  0.334
2006 Larrosa I, Da Silva MI, Gómez PM, Hannen P, Ko E, Lenger SR, Linke SR, White AJ, Wilton D, Barrett AG. Highly convergent three component benzyne coupling: the total synthesis of ent-clavilactone B. Journal of the American Chemical Society. 128: 14042-3. PMID 17061883 DOI: 10.1021/Ja0662671  0.385
2006 Larrosa I, Romea P, Urpí F. Stereoselective synthesis of the western hemisphere of salinomycin. Organic Letters. 8: 527-30. PMID 16435876 DOI: 10.1021/Ol052900W  0.396
2005 Bonvin Y, Callens E, Larrosa I, Henderson DA, Oldham J, Burton AJ, Barrett AG. Bismuth-catalyzed benzylic oxidations with tert-butyl hydroperoxide. Organic Letters. 7: 4549-52. PMID 16209476 DOI: 10.1021/Ol051765K  0.353
2004 Ritter T, Stanek K, Larrosa I, Carreira EM. Mild cleavage of aryl mesylates: methanesulfonate as potent protecting group for phenols. Organic Letters. 6: 1513-4. PMID 15101780 DOI: 10.1021/Ol049514J  0.427
2003 Cosp A, Larrosa I, Anglada JM, Bofill JM, Romea P, Urpí F. Studies on the intramolecular C[bond]H...X (X = O, S) interactions in (S)-N-acyl- 4-isopropyl-1,3-thiazolidine-2-thiones and related 1,3-oxazolidin-2-ones. Organic Letters. 5: 2809-12. PMID 12889880 DOI: 10.1021/Ol0347848  0.306
2003 Cosp A, Larrosa I, Vilasis I, Romea P, Urpi F, Vilarrasa J. Synthesis of O-Benzyl Protected anti Aldols Through the Cross-Coupling Reaction of Dibenzyl Acetals with a Chiral Titanium Enolate. Cheminform. 34. DOI: 10.1055/S-2003-39891  0.396
2002 Larrosa I, Romea P, Urpí F, Balsells D, Vilarrasa J, Font-Bardia M, Solans X. Unprecedented highly stereoselective alpha- and beta-C-glycosidation with chiral titanium enolates. Organic Letters. 4: 4651-4. PMID 12489952 DOI: 10.1021/Ol0270226  0.339
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