John M. Brown - Publications

Chemistry University of Oxford, Oxford, United Kingdom 
enantioselective synthesis

72 high-probability publications. We are testing a new system for linking publications to authors. You can help! If you notice any inaccuracies, please sign in and mark papers as correct or incorrect matches. If you identify any major omissions or other inaccuracies in the publication list, please let us know.

Year Citation  Score
2020 Ibba F, Pupo G, Thompson AL, Brown JM, Claridge TDW, Gouverneur V. Impact of Multiple Hydrogen Bonds with Fluoride on Catalysis: Insight from NMR Spectroscopy. Journal of the American Chemical Society. PMID 33166450 DOI: 10.1021/jacs.0c09832  1
2019 Pupo G, Vicini AC, Ascough DMH, Ibba F, Christensen KE, Thompson AL, Brown JM, Paton RS, Gouverneur V. Hydrogen Bonding Phase-Transfer Catalysis with Potassium Fluoride: Enantioselective Synthesis of β-Fluoroamines. Journal of the American Chemical Society. PMID 30689372 DOI: 10.1021/jacs.8b12568  1
2018 Pupo G, Ibba F, Ascough DMH, Vicini AC, Ricci P, Christensen KE, Pfeifer L, Morphy JR, Brown JM, Paton RS, Gouverneur V. Asymmetric nucleophilic fluorination under hydrogen bonding phase-transfer catalysis. Science (New York, N.Y.). 360: 638-642. PMID 29748281 DOI: 10.1126/science.aar7941  1
2017 Rauf W, Brown JM. Mechanisms for C(sp(2))-Si activation of aryltrimethylsilyl groups in palladium-catalysed couplings. Organic & Biomolecular Chemistry. PMID 28926074 DOI: 10.1039/c7ob01675a  1
2016 Pfeifer L, Engle KM, Pidgeon GW, Sparkes HA, Thompson AL, Brown JM, Gouverneur VE. Hydrogen-Bonded Homoleptic Fluoride-Diarylurea Complexes: Structure, Reactivity and Coordinating Power. Journal of the American Chemical Society. PMID 27608274 DOI: 10.1021/jacs.6b07501  1
2016 Rauf W, Brown JM. Palladium-catalysed directed C-H activation by anilides and ureas; water participation in a general base mechanism. Organic & Biomolecular Chemistry. PMID 27184358 DOI: 10.1039/c6ob00897f  1
2015 Engle KM, Pfeifer L, Pidgeon GW, Giuffredi GT, Thompson AL, Paton RS, Brown JM, Gouverneur V. Coordination diversity in hydrogen-bonded homoleptic fluoride-alcohol complexes modulates reactivity. Chemical Science. 6: 5293-5302. PMID 29449931 DOI: 10.1039/c5sc01812a  1
2015 Pubill-Ulldemolins C, Fernánez E, Bo C, Brown JM. Origins of observed reactivity and specificity in the addition of B2Cl4 and analogues to unsaturated compounds. Organic & Biomolecular Chemistry. 13: 9619-28. PMID 26260922 DOI: 10.1039/c5ob01280e  1
2014 Fernández E, Guiry PJ, Connole KP, Brown JM. Quinap and congeners: atropos PN ligands for asymmetric catalysis. The Journal of Organic Chemistry. 79: 5391-400. PMID 24806741 DOI: 10.1021/jo500512s  0.68
2014 Emer E, Pfeifer L, Brown JM, Gouverneur V. cis-Specific hydrofluorination of alkenylarenes under palladium catalysis through an ionic pathway. Angewandte Chemie (International Ed. in English). 53: 4181-5. PMID 24644083 DOI: 10.1002/anie.201310056  1
2014 Kurbangalieva A, Carmichael D, Hii KK, Jutand A, Brown JM. Oxidative addition to palladium(0) diphosphine complexes: observations of mechanistic complexity with iodobenzene as reactant. Chemistry (Weinheim An Der Bergstrasse, Germany). 20: 1116-25. PMID 24375651 DOI: 10.1002/chem.201301937  1
2013 Rauf W, Brown JM. Reactive intermediates in catalytic alkenylation; pathways for Mizoroki-Heck, oxidative Heck and Fujiwara-Moritani reactions. Chemical Communications (Cambridge, England). 49: 8430-40. PMID 23949625 DOI: 10.1039/c3cc44842h  1
2013 Carroll MP, Guiry PJ, Brown JM. Meta-analysis in asymmetric catalysis. Influence of chelate geometry on the roles of PN chelating ligands. Organic & Biomolecular Chemistry. 11: 4591-601. PMID 23636132 DOI: 10.1039/c3ob40360b  1
2013 Raskatov JA, Thompson AL, Cowley AR, Claridge TDW, Brown JM. Chiral recognition in contact ion-pairs; Observation, characterization and analysis Chemical Science. 4: 3140-3147. DOI: 10.1039/c3sc51096d  1
2013 Benedetto E, Tredwell M, Hollingworth C, Khotavivattana T, Brown JM, Gouverneur V. Regio- and stereoretentive synthesis of branched, linear (E)- and (Z)-allyl fluorides from allyl carbonates under Ir-catalysis Chemical Science. 4: 89-96. DOI: 10.1039/c2sc21789a  1
2012 Paton RS, Brown JM. Dinuclear palladium complexes--precursors or catalysts? Angewandte Chemie (International Ed. in English). 51: 10448-50. PMID 22968902 DOI: 10.1002/anie.201205417  1
2012 Gehring T, Quaranta M, Odell B, Blackmond DG, Brown JM. Observation of a transient intermediate in Soai's asymmetric autocatalysis: insights from 1H NMR turnover in real time. Angewandte Chemie (International Ed. in English). 51: 9539-42. PMID 22936384 DOI: 10.1002/anie.201203398  1
2012 Blessley G, Holden P, Walker M, Brown JM, Gouverneur V. Palladium-catalyzed substitution and cross-coupling of benzylic fluorides. Organic Letters. 14: 2754-7. PMID 22594918 DOI: 10.1021/ol300977f  1
2012 Gosiewska S, Raskatov JA, Shintani R, Hayashi T, Brown JM. The origins of enantioselectivity in Rh-diene complex catalysed arylation of cyclohex-2-enones. Chemistry (Weinheim An Der Bergstrasse, Germany). 18: 80-4. PMID 22161767 DOI: 10.1002/chem.201102421  1
2012 Benedetto E, Keita M, Tredwell M, Hollingworth C, Brown JM, Gouverneur V. Platinum-catalyzed substitution of allylic fluorides Organometallics. 31: 1408-1416. DOI: 10.1021/om201029m  1
2011 Hollingworth C, Hazari A, Hopkinson MN, Tredwell M, Benedetto E, Huiban M, Gee AD, Brown JM, Gouverneur V. Palladium-catalyzed allylic fluorination. Angewandte Chemie (International Ed. in English). 50: 2613-7. PMID 21370349 DOI: 10.1002/anie.201007307  1
2011 Raskatov JA, Brown JM, Thompson AL. Chiral selection in the formation of borates from racemic binaphthols and related diols Crystengcomm. 13: 2923-2929. DOI: 10.1039/c0ce00709a  1
2010 Quaranta M, Gehring T, Odell B, Brown JM, Blackmond DG. Unusual inverse temperature dependence on reaction rate in the asymmetric autocatalytic alkylation of pyrimidyl aldehydes. Journal of the American Chemical Society. 132: 15104-7. PMID 20942400 DOI: 10.1021/ja103204w  1
2010 Rauf W, Thompson AL, Brown JM. Anilide activation of adjacent C-H bonds in the palladium-catalysed Fujiwara-Moritani reaction. Dalton Transactions (Cambridge, England : 2003). 39: 10414-21. PMID 20936231 DOI: 10.1039/c0dt00378f  1
2010 Rauf W, Hazari A, Gouverneur V, Brown JM. Catalytic activation of hydrogen, silicon, and fluorine by transition-metal complexes Pure and Applied Chemistry. 82: 1415-1428. DOI: 10.1351/PAC-CON-09-10-37  1
2010 Raskatov JA, Thompson AL, Brown JM. Asymmetric catalysis with 7-ring chelate diphosphines: DIOP, BINAP and conformational mobility Tetrahedron Asymmetry. 21: 1737-1744. DOI: 10.1016/j.tetasy.2010.04.030  1
2009 Brown JM, Gouverneur V. Transition-metal-mediated reactions for C(sp2)-F bond construction: the state of play. Angewandte Chemie (International Ed. in English). 48: 8610-4. PMID 19827068 DOI: 10.1002/anie.200902121  1
2009 Rauf W, Thompson AL, Brown JM. Comparative catalytic C-H vs. C-Si activation of arenes with Pd complexes directed by urea or amide groups. Chemical Communications (Cambridge, England). 3874-6. PMID 19662237 DOI: 10.1039/b905717j  1
2009 Hübers HW, Evenson KM, Hill C, Brown JM. The rotational spectrum of the NH+ radical in its X 2Pi and a 4Sigma- states. The Journal of Chemical Physics. 131: 034311. PMID 19624201 DOI: 10.1063/1.3160964  1
2009 Ma T, Butler C, Brown JM, Linton C, Steimle TC. Optical Zeeman spectroscopy of ytterbium monofluoride, YbF. The Journal of Physical Chemistry. A. 113: 8038-44. PMID 19555112 DOI: 10.1021/jp903596g  1
2009 Halfen DT, Ziurys LM, Brown JM. Fine structure and hyperfine perturbations in the pure rotational spectrum of the VCl radical in its X 5Delta(r) state. The Journal of Chemical Physics. 130: 164301. PMID 19405573 DOI: 10.1063/1.3108538  1
2009 Jackson M, Zink LR, Towle JP, Riley N, Brown JM. The rotational spectrum of the FeD radical in its X (4)Delta state, measured by far-infrared laser magnetic resonance. The Journal of Chemical Physics. 130: 154311. PMID 19388750 DOI: 10.1063/1.3117182  1
2009 Hazari A, Gouverneur V, Brown JM. Palladium-catalyzed substitution of allylic fluorides. Angewandte Chemie (International Ed. in English). 48: 1296-9. PMID 19142916 DOI: 10.1002/anie.200804310  1
2009 Xu Y, Celik MA, Thompson AL, Cai H, Yurtsever M, Odell B, Green JC, Mingos DM, Brown JM. Tetrameric iridium hydride-rich clusters formed under hydrogenation conditions. Angewandte Chemie (International Ed. in English). 48: 582-5. PMID 19067451 DOI: 10.1002/anie.200804484  1
2009 Brown JM, Deeth RJ. Is enantioselectivity predictable in asymmetric catalysis Angewandte Chemie - International Edition. 48: 4476-4479. DOI: 10.1002/anie.200900697  1
2008 Punniyamurthy T, Mayr M, Dorofeev AS, Bataille CJ, Gosiewska S, Nguyen B, Cowley AR, Brown JM. Enantiomerically pure bicyclo[3.3.1]nona-2,6-diene as the sole source of enantioselectivity in BIPHEP-Rh asymmetric hydrogenation. Chemical Communications (Cambridge, England). 5092-4. PMID 18956032 DOI: 10.1039/b807669c  0.32
2008 Rauf W, Brown JM. Catalytic amide-mediated methyl transfer from silanes to alkenes in Fujiwara-Moritani oxidative coupling. Angewandte Chemie (International Ed. in English). 47: 4228-30. PMID 18431728 DOI: 10.1002/anie.200800815  1
2008 Flemming JP, Berry MB, Brown JM. Sequential ortho-lithiations; the sulfoxide group as a relay to enable meta-substitution. Organic & Biomolecular Chemistry. 6: 1215-21. PMID 18362961 DOI: 10.1039/b716954j  1
2008 Mayr M, Bataille CJR, Gosiewska S, Raskatov JA, Brown JM. Synthesis and rhodium complexation of enantiomerically enriched bicyclo[3.3.1]nona-2,6-diene Tetrahedron Asymmetry. 19: 1328-1332. DOI: 10.1016/j.tetasy.2008.05.009  1
2007 Harrison JJ, Brown JM, Flory MA, Sheridan PM, McLamarrah SK, Ziurys LM. The rotational spectrum of CoF in all three spin-orbit components of the X3Phi i state. The Journal of Chemical Physics. 127: 194308. PMID 18035884 DOI: 10.1063/1.2789427  1
2007 Klankermayer J, Gridnev ID, Brown JM. Role of the isopropyl group in asymmetric autocatalytic zinc alkylations. Chemical Communications (Cambridge, England). 3151-3. PMID 17653371 DOI: 10.1039/b705978g  0.6
2006 Brown JM, Körsgen H, Beaton SP, Evenson KM. The rotational and fine-structure spectrum of FeH, studied by far-infrared laser magnetic resonance. The Journal of Chemical Physics. 124: 234309. PMID 16821920 DOI: 10.1063/1.2198843  1
2006 Hodges PJ, Beattie IR, Brown JM. The observation of the electronic spectrum of Fe2Cl6 in the gas phase. Physical Chemistry Chemical Physics : Pccp. 8: 2696-9. PMID 16763699 DOI: 10.1039/b605200b  1
2006 Steimle TC, Chen J, Harrison JJ, Brown JM. A molecular-beam optical Stark study of lines in the (1,0) band of the F4delta(7/2)-X4delta(7/2) transition of iron monohydride, FeH. The Journal of Chemical Physics. 124: 184307. PMID 16709106 DOI: 10.1063/1.2194551  1
2005 Rainville S, Thompson JK, Myers EG, Brown JM, Dewey MS, Kessler EG, Deslattes RD, Börner HG, Jentschel M, Mutti P, Pritchard DE. World Year of Physics: a direct test of E=mc2. Nature. 438: 1096-7. PMID 16371997 DOI: 10.1038/4381096a  1
2005 Capito E, Brown JM, Ricci A. Directed palladation: fine tuning permits the catalytic 2-alkenylation of indoles. Chemical Communications (Cambridge, England). 1854-6. PMID 15795765 DOI: 10.1039/b417035k  1
2004 Gridnev ID, Serafimov JM, Brown JM. Solution structure and reagent binding of the zinc alkoxide catalyst in the Soai asymmetric autocatalytic reaction. Angewandte Chemie (International Ed. in English). 43: 4884-7. PMID 15372571 DOI: 10.1002/anie.200353572  0.6
2004 Gridnev ID, Brown JM. Asymmetric autocatalysis: novel structures, novel mechanism? Proceedings of the National Academy of Sciences of the United States of America. 101: 5727-31. PMID 15060283 DOI: 10.1073/pnas.0308178101  0.6
2004 Deeth RJ, Smith A, Brown JM. Electronic control of the regiochemistry in palladium-phosphine catalyzed intermolecular heck reactions Journal of the American Chemical Society. 126: 7144-7151. DOI: 10.1021/ja0315098  1
2003 Gridnev ID, Serafimov JM, Quiney H, Brown JM. Reflections on spontaneous asymmetric synthesis by amplifying autocatalysis. Organic & Biomolecular Chemistry. 1: 3811-9. PMID 14649913  0.6
2003 Lim CW, Tissot O, Mattison A, Hooper MW, Brown JM, Cowley AR, Hulmes DI, Blacker AJ. Practical preparation and resolution of 1-(2′-diphenylphosphino-1′-naphthyl)isoquinoline: A useful ligand for catalytic asymmetric synthesis Organic Process Research and Development. 7: 379-384. DOI: 10.1021/op034007n  1
2002 Galardon E, Ramdeehul S, Brown JM, Cowley A, Hii KK, Jutand A. Profound steric control of reactivity in aryl halide addition to bisphosphane palladium(0) complexes. Angewandte Chemie (International Ed. in English). 41: 1760-3. PMID 19750708 DOI: 10.1002/1521-3773(20020517)41:10<1760::AID-ANIE1760>3.0.CO;2-3  1
2002 Farrington EJ, Martinez Viviente E, Williams BS, van Koten G, Brown JM. Synthesis and reactivity of a ferrocene-derived PCP-pincer ligand. Chemical Communications (Cambridge, England). 308-9. PMID 12120048  1
2002 Sheridan PM, Xin J, Ziurys LM, Beaton SA, Kermode SM, Brown JM. The pure rotational spectrum of NaC in its X 4Σ- state: Observation and interpretation Journal of Chemical Physics. 116: 5544-5550. DOI: 10.1063/1.1457441  1
2001 Wilson C, Cook HM, Brown JM. Complete characterization of the a6Δ state of the FeH radical Journal of Chemical Physics. 115: 5943-5956. DOI: 10.1063/1.1399300  1
2001 Hii KK, Claridge TDW, Brown JM, Smith A, Deeth RJ. The intermolecular asymmetric Heck reaction: Mechanistic and computational studies Helvetica Chimica Acta. 84: 3043-3056. DOI: 10.1002/1522-2675(20011017)84:10<3043::AID-HLCA3043>3.0.CO;2-V  1
2001 Adams NJ, Bargon J, Brown JM, Farrington EJ, Galardon E, Giernoth R, Heinrich H, John BD, Maeda K. Interplay of synthesis and mechanism in asymmetric homogeneous catalysis Pure and Applied Chemistry. 73: 343-346.  1
2000 Giernoth R, Heinrich H, Adams NJ, Deeth RJ, Bargon J, Brown JM. PHIP detection of a transient rhodium dihydride intermediate in the homogeneous hydrogenation of dehydroamino acids Journal of the American Chemical Society. 122: 12381-12382. DOI: 10.1021/ja002516o  1
1998 Deeth RJ, Smith A, Hii KKM, Brown JM. The Heck olefination reaction; a DFT study of the elimination pathway Tetrahedron Letters. 39: 3229-3232. DOI: 10.1016/S0040-4039(98)00398-0  1
1995 Valk JM, Whitlock GA, Layzell TP, Brown JM. Catalytic asymmetric hydroboration with heterotopic P-N ligands: Trends in enantioselectivity with increased steric demand Tetrahedron: Asymmetry. 6: 2593-2596. DOI: 10.1016/0957-4166(95)00340-U  1
1994 Lakin NM, Brown JM, Beattie IR, Jones PJ. The identification of InOH in the gas phase and determination of its geometric structure The Journal of Chemical Physics. 100: 8546-8549.  1
1993 Barnes MP, Carter RT, Lakin NM, Brown JM. Observation and analysis of rotational and nuclear hyperfine structure in bands of the red system of copper dichloride Journal of the Chemical Society, Faraday Transactions. 89: 3205-3215. DOI: 10.1039/FT9938903205  1
1987 Vasconcellos ECC, Davidson SA, Brown JM, Leopold KR, Evenson KM. Rotational and hyperfine constants of vibrationally excited NH (a1Δ; v = 1) Journal of Molecular Spectroscopy. 122: 242-245. DOI: 10.1016/0022-2852(87)90233-5  0.64
1986 Brown JM, Cutting I, Evans PL, Maddox PJ. Factors affecting stereochemical control in directed homogeneous hydrogenation of α-hydroxyalkylacrylates Tetrahedron Letters. 27: 3307-3310. DOI: 10.1016/S0040-4039(00)84783-8  0.64
1985 Steimle TC, Brazier CR, Brown JM. Studies of copper monofluoride in the b3Π state by microwave-optical double resonance and intermodulated fluorescence Journal of Molecular Spectroscopy. 110: 39-52. DOI: 10.1016/0022-2852(85)90210-3  1
1984 Brown JM, Curl RF, Evenson KM. The far-infrared laser magnetic resonance spectrum of the SiH radical and determination of ground state parameters The Journal of Chemical Physics. 81: 2884-2890.  1
1983 Brazier CR, Brown JM, Steimle TC. The identification of the b3Π state of copper monofluoride Journal of Molecular Spectroscopy. 97: 449-453. DOI: 10.1016/0022-2852(83)90282-5  0.64
1982 Steimle TC, Brazier CR, Brown JM. Rotational and hyperfine structure in the yellow system of CuF Journal of Molecular Spectroscopy. 91: 137-149. DOI: 10.1016/0022-2852(82)90037-6  0.64
1979 Brown JM, Carrington A, Sears TJ. The infra-red L.M.R. spectrum of SeH in the X2П state a direct determination of the spin-orbit coupling constant Molecular Physics. 37: 1837-1848. DOI: 10.1080/00268977900101361  0.96
1978 Barnes CE, Brown JM, Carrington A, Pinkstone J, Sears TJ, Thistlethwaite PJ. The EPR spectrum of the HO2 radical and determination of ground state parameters Journal of Molecular Spectroscopy. 72: 86-101. DOI: 10.1016/0022-2852(78)90045-0  1
1975 Brown JM. K-type doubling parameters for linear molecules in Π electronic states Journal of Molecular Spectroscopy. 56: 159-162. DOI: 10.1016/0022-2852(75)90212-X  1
1968 Brown JM. Chapter 11. Alicyclic compounds Annual Reports On the Progress of Chemistry - Section B. 65: 379-407. DOI: 10.1039/OC9686500379  1
Show low-probability matches.