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Ekambaram Balaraman - Publications

Affiliations: 
2012-2013 SRM University, Kattankulathur, India 
 2013-2018 CSIR-NCL 
 2018- IISER Tirupati 
Area:
Organometallics, sustainable catalysis
Website:
https://sites.google.com/view/balaramansresearchgroup/dr-e-balaraman
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76 high-probability publications. We are testing a new system for linking publications to authors. You can help! If you notice any inaccuracies, please sign in and mark papers as correct or incorrect matches. If you identify any major omissions or other inaccuracies in the publication list, please let us know.

Year Citation  Score
2023 Nallagangula M, Subaramanian M, Kumar R, Balaraman E. Transition metal-catalysis in interrupted borrowing hydrogen strategy. Chemical Communications (Cambridge, England). PMID 37259885 DOI: 10.1039/d3cc01517c  0.342
2023 Goyal V, Bhatt T, Dewangan C, Narani A, Naik G, Balaraman E, Natte K, Jagadeesh RV. Methanol as a Potential Hydrogen Source for Reduction Reactions Enabled by a Commercial Pt/C Catalyst. The Journal of Organic Chemistry. 88: 2245-2259. PMID 36753730 DOI: 10.1021/acs.joc.2c02657  0.41
2022 Yadav V, Jagtap SG, Balaraman E, Mhaske SB. Nickel-Catalyzed Direct Synthesis of -Substituted Indoles from Amino Alcohols and Alcohols. Organic Letters. 24: 9054-9059. PMID 36468976 DOI: 10.1021/acs.orglett.2c03617  0.778
2022 Mondal A, Karattil Suresh A, Sivakumar G, Balaraman E. Sustainable and Affordable Synthesis of (Deuterated) -Methyl/Ethyl Amines from Nitroarenes. Organic Letters. 24: 8990-8995. PMID 36468910 DOI: 10.1021/acs.orglett.2c03595  0.352
2022 Shaik S, Reddy Sirigireddy RM, Godugu K, Vemula V, Kakarla RR, Balaraman E, Nallagondu CGR, Aminabhavi TM. SiO-supported HClO catalyzed synthesis of (Z)-thiazolylhydrazonoindolin-2-ones and their electrochemical properties. Chemosphere. 309: 136667. PMID 36202369 DOI: 10.1016/j.chemosphere.2022.136667  0.329
2021 Subaramanian M, Sivakumar G, Balaraman E. First-Row Transition-Metal Catalyzed Acceptorless Dehydrogenation and Related Reactions: A Personal Account. Chemical Record (New York, N.Y.). PMID 34415674 DOI: 10.1002/tcr.202100165  0.453
2021 Sahoo MK, Sivakumar G, Jadhav S, Shaikh S, Balaraman E. Convenient semihydrogenation of azoarenes to hydrazoarenes using H. Organic & Biomolecular Chemistry. 19: 5289-5293. PMID 34076020 DOI: 10.1039/d1ob00850a  0.726
2021 Midya SP, Subaramanian M, Babu R, Yadav V, Balaraman E. Tandem Acceptorless Dehydrogenative Coupling-Decyanation under Nickel Catalysis. The Journal of Organic Chemistry. 86: 7552-7562. PMID 34032425 DOI: 10.1021/acs.joc.1c00592  0.821
2021 Babu R, Subaramanian M, Midya SP, Balaraman E. Nickel-Catalyzed Guerbet Type Reaction: C-Alkylation of Secondary Alcohols Double (de)Hydrogenation. Organic Letters. 23: 3320-3325. PMID 33881325 DOI: 10.1021/acs.orglett.1c00782  0.809
2021 Subaramanian M, Sivakumar G, Balaraman E. Recent advances in nickel-catalyzed C-C and C-N bond formation HA and ADC reactions. Organic & Biomolecular Chemistry. PMID 33881121 DOI: 10.1039/d1ob00080b  0.365
2021 Rana J, Nagarasu P, Subaramanian M, Mondal A, Madhu V, Balaraman E. Manganese-Catalyzed C(α)-Alkylation of Oxindoles with Secondary Alcohols via Borrowing Hydrogen Organometallics. 40: 627-634. DOI: 10.1021/ACS.ORGANOMET.1C00009  0.665
2020 Subaramanian M, Sivakumar G, Babu JK, Balaraman E. Selective hydrogenation of primary amides and cyclic di-peptides under Ru-catalysis. Chemical Communications (Cambridge, England). PMID 32936149 DOI: 10.1039/D0Cc04550K  0.471
2020 Subaramanian M, Ramar PM, Rana J, Gupta VK, Balaraman E. Catalytic conversion of ketones to esters via C(O)-C bond cleavage under transition-metal free conditions. Chemical Communications (Cambridge, England). 56: 8143-8146. PMID 32691781 DOI: 10.1039/D0Cc03312J  0.675
2020 Landge VG, Babu R, Yadav V, Subaramanian M, Gupta VK, Balaraman E. Iron-Catalyzed Direct Julia-type Olefination of Alcohols. The Journal of Organic Chemistry. PMID 32600041 DOI: 10.1021/Acs.Joc.0C01173  0.819
2020 Mondal A, Sahoo MK, Subaramanian M, Balaraman E. Manganese(I)-Catalyzed Sustainable Synthesis of Quinoxaline and Quinazoline Derivatives with the Liberation of Dihydrogen. The Journal of Organic Chemistry. PMID 32400155 DOI: 10.1021/Acs.Joc.0C00561  0.761
2020 Jaiswal G, Landge VG, Subaramanian M, Kadam RG, Zbořil R, Gawande MB, Balaraman E. N‑Graphitic Modified Cobalt Nanoparticles Supportedon Graphene for Tandem Dehydrogenation of Ammonia–Borane andSemihydrogenation of Alkynes Acs Sustainable Chemistry & Engineering. 8: 11058-11068. DOI: 10.1021/Acssuschemeng.9B07211  0.748
2020 Yadav V, Landge VG, Subaramanian M, Balaraman E. Manganese-Catalyzed α-Olefination of Nitriles with Secondary Alcohols Acs Catalysis. 10: 947-954. DOI: 10.1021/Acscatal.9B02811  0.466
2019 Subaramanian M, Midya SP, Ramar PM, Balaraman E. General Synthesis of -Alkylation of Amines with Secondary Alcohols via Hydrogen Autotransfer. Organic Letters. 21: 8899-8903. PMID 31691555 DOI: 10.1021/Acs.Orglett.9B02990  0.565
2019 Sahoo MK, Jaiswal G, Rana J, Balaraman E. Corrigendum: Organo-Photoredox Catalyzed Oxidative Dehydrogenation of N-Heterocycles. Chemistry (Weinheim An Der Bergstrasse, Germany). 25: 7038. PMID 31099104 DOI: 10.1002/Chem.201901351  0.753
2019 Landge VG, Yadav V, Subaramanian M, Dangarh P, Balaraman E. Nickel(ii)-catalyzed direct olefination of benzyl alcohols with sulfones with the liberation of H. Chemical Communications (Cambridge, England). 55: 6130-6133. PMID 31070623 DOI: 10.1039/C9Cc02603G  0.783
2019 Bhadra M, Kandambeth S, Sahoo MK, Addicoat M, Balaraman E, Banerjee R. Triazine Functionalized Porous Covalent Organic Framework for Photo-organocatalytic E- Z Isomerization of Olefins. Journal of the American Chemical Society. PMID 30945862 DOI: 10.1021/Jacs.9B01891  0.702
2019 Rana J, Gupta V, Balaraman E. Manganese-catalyzed direct C-C coupling of α-C-H bonds of amides and esters with alcohols via hydrogen autotransfer. Dalton Transactions (Cambridge, England : 2003). PMID 30916073 DOI: 10.1039/C8Dt05020A  0.708
2019 Sahoo MK, Balaraman E. Room temperature catalytic dehydrogenation of cyclic amines with the liberation of H2 using water as a solvent Green Chemistry. 21: 2119-2128. DOI: 10.1039/C9Gc00201D  0.758
2019 Jaiswal G, Subaramanian M, Sahoo MK, Balaraman E. A Reusable Cobalt Catalyst for Reversible Acceptorless Dehydrogenation and Hydrogenation of N‐Heterocycles Chemcatchem. 11: 2449-2457. DOI: 10.1002/Cctc.201900367  0.787
2018 Landge VG, Mondal A, Kumar V, Nandakumar A, Balaraman E. Manganese catalyzed N-alkylation of anilines with alcohols: ligand enabled selectivity. Organic & Biomolecular Chemistry. PMID 30350840 DOI: 10.1039/C8Ob01886C  0.493
2018 Landge VG, Parveen A, Nandakumar A, Balaraman E. Pd(ii)-Catalyzed gamma-C(sp)-H alkynylation of amides: selective functionalization of R chains of amides RC(O)NHR. Chemical Communications (Cambridge, England). 54: 7483-7486. PMID 29915835 DOI: 10.1039/C8Cc03445A  0.393
2018 Mondal A, Subaramanian M, Nandakumar A, Balaraman E. Manganese-Catalyzed Direct Conversion of Ester to Amide with Liberation of H. Organic Letters. PMID 29791162 DOI: 10.1021/Acs.Orglett.8B01305  0.453
2018 Rana J, Babu R, Subaramanian M, Balaraman E. Ni-Catalyzed dehydrogenative coupling of primary and secondary alcohols with methyl-N-heteroaromatics Organic Chemistry Frontiers. 5: 3250-3255. DOI: 10.1039/C8Qo00764K  0.822
2018 Midya SP, Pitchaimani J, Landge VG, Madhu V, Balaraman E. Direct access to N-alkylated amines and imines via acceptorless dehydrogenative coupling catalyzed by a cobalt(II)-NNN pincer complex Catalysis Science & Technology. 8: 3469-3473. DOI: 10.1039/C8Cy00859K  0.522
2018 Karthik P, Balaraman E, Neppolian B. Efficient solar light-driven H2 production: post-synthetic encapsulation of a Cu2O co-catalyst in a metal–organic framework (MOF) for boosting the effective charge carrier separation Catalysis Science & Technology. 8: 3286-3294. DOI: 10.1039/C8Cy00604K  0.306
2018 Landge VG, Pitchaimani J, Midya SP, Subaramanian M, Madhu V, Balaraman E. Phosphine-free cobalt pincer complex catalyzed Z-selective semi-hydrogenation of unbiased alkynes Catalysis Science & Technology. 8: 428-433. DOI: 10.1039/C7Cy01994G  0.429
2018 Sahoo MK, Saravanakumar K, Jaiswal G, Balaraman E. Photocatalysis Enabling Acceptorless Dehydrogenation of Diaryl Hydrazines at Room Temperature Acs Catalysis. 8: 7727-7733. DOI: 10.1021/Acscatal.8B01579  0.804
2017 Jaiswal G, Landge VG, Jagadeesan D, Balaraman E. Iron-based nanocatalyst for the acceptorless dehydrogenation reactions. Nature Communications. 8: 2147. PMID 29247179 DOI: 10.1038/S41467-017-01603-3  0.813
2017 Midya SP, Landge VG, Sahoo MK, Rana J, Balaraman E. Cobalt-catalyzed acceptorless dehydrogenative coupling of aminoalcohols with alcohols: direct access to pyrrole, pyridine and pyrazine derivatives. Chemical Communications (Cambridge, England). 54: 90-93. PMID 29211066 DOI: 10.1039/C7Cc07427A  0.812
2017 Landge VG, Rana J, Subaramanian M, Balaraman E. Nickel-catalyzed N-vinylation of heteroaromatic amines via C-H bond activation. Organic & Biomolecular Chemistry. PMID 28786460 DOI: 10.1039/C7Ob01791J  0.686
2017 Midya SP, Rana J, Abraham T, Aswin B, Balaraman E. Metal-free radical trifluoromethylation of β-nitroalkenes through visible-light photoredox catalysis. Chemical Communications (Cambridge, England). PMID 28597876 DOI: 10.1039/C7Cc02589K  0.631
2017 Bhadra M, Sasmal HS, Basu A, Midya SP, Kandambeth S, Pachfule P, Balaraman E, Banerjee R. Predesigned Metal Anchored Building Block for In Situ Generation of Pd Nanoparticles in Porous Covalent Organic Framework: Application in Heterogeneous Tandem Catalysis. Acs Applied Materials & Interfaces. PMID 28368103 DOI: 10.1021/Acsami.7B02355  0.365
2017 Midya SP, Mondal A, Begum A, Balaraman E. A Simple Cobalt(II) Chloride Catalyzed N-Alkylation of Amines with Alcohols Synthesis. 49: 3957-3961. DOI: 10.1055/S-0036-1589064  0.541
2017 Balaraman E, Nandakumar A, Jaiswal G, Sahoo MK. Iron-catalyzed dehydrogenation reactions and their applications in sustainable energy and catalysis Catalysis Science & Technology. 7: 3177-3195. DOI: 10.1039/C7Cy00879A  0.789
2017 Sahoo MK, Midya SP, Landge VG, Balaraman E. A unified strategy for silver-, base-, and oxidant-free direct arylation of C–H bonds Green Chemistry. 19: 2111-2117. DOI: 10.1039/C6Gc03438A  0.748
2017 Subaramanian M, Bera A, Prasad BLV, Balaraman E. Nickel-catalyzed direct synthesis of dialkoxymethane ethers Journal of Chemical Sciences. 129: 1153-1159. DOI: 10.1007/S12039-017-1339-6  0.525
2017 Sahoo MK, Rana J, Subaramanian M, Balaraman E. Room-Temperature Direct Arylation of Anilides under External Oxidant-Free Conditions Using CO2-Derived Dimethyl Carbonate (DMC) as a ′Green′ Solvent Chemistryselect. 2: 7565-7569. DOI: 10.1002/SLCT.201701108  0.736
2016 Landge VG, Midya SP, Rana J, Shinde DR, Balaraman E. Expedient Cobalt-Catalyzed C-H Alkynylation of (Enantiopure) Benzylamines. Organic Letters. PMID 27700123 DOI: 10.1021/Acs.Orglett.6B02549  0.675
2016 Landge VG, Jaiswal G, Balaraman E. Cobalt-Catalyzed Bis-alkynylation of Amides via Double C-H Bond Activation. Organic Letters. 18: 812-5. PMID 26863522 DOI: 10.1021/Acs.Orglett.6B00095  0.797
2016 Jaiswal G, Landge VG, Jagadeesan D, Balaraman E. Sustainable iron-catalyzed direct imine formation by acceptorless dehydrogenative coupling of alcohols with amines Green Chemistry. 18: 3232-3238. DOI: 10.1039/C6Gc00565A  0.813
2016 Landge VG, Shewale CH, Jaiswal G, Sahoo MK, Midya SP, Balaraman E. Nickel-catalyzed direct alkynylation of C(sp2)–H bonds of amides: an “inverse Sonogashira strategy” to ortho-alkynylbenzoic acids Catalysis Science & Technology. 6: 1946-1951. DOI: 10.1039/C5Cy01299F  0.791
2015 Midya SP, Sahoo MK, Landge VG, Rajamohanan PR, Balaraman E. Reversed reactivity of anilines with alkynes in the rhodium-catalysed C-H activation/carbonylation tandem. Nature Communications. 6: 8591. PMID 26486182 DOI: 10.1038/Ncomms9591  0.751
2015 Nandakumar A, Midya SP, Landge VG, Balaraman E. Transition-metal-catalyzed hydrogen-transfer annulations: access to heterocyclic scaffolds. Angewandte Chemie (International Ed. in English). 54: 11022-34. PMID 26269420 DOI: 10.1002/Anie.201503247  0.469
2015 Landge VG, Sahoo MK, Midya SP, Jaiswal G, Balaraman E. Well-defined palladium(ii) complexes for ligand-enabled C(sp(3))-alkynylation. Dalton Transactions (Cambridge, England : 2003). 44: 15382-6. PMID 26243558 DOI: 10.1039/C5Dt02772A  0.777
2015 Nandakumar A, Sahoo MK, Balaraman E. Reverse-hydroformylation: a missing reaction explored Organic Chemistry Frontiers. 2: 1422-1424. DOI: 10.1039/C5Qo00229J  0.717
2014 Balaraman E, Srimani D, Diskin-Posner Y, Milstein D. Direct Synthesis of Secondary Amines From Alcohols and Ammonia Catalyzed by a Ruthenium Pincer Complex Catalysis Letters. 145: 139-144. DOI: 10.1007/S10562-014-1422-2  0.792
2014 Balaraman E, Milstein D. Hydrogenation of polar bonds catalysed by ruthenium-pincer complexes Topics in Organometallic Chemistry. 48: 19-44. DOI: 10.1007/3418_2014_77  0.637
2014 Srimani D, Balaraman E, Hu P, Ben-David Y, Milstein D. ChemInform Abstract: Formation of Tertiary Amides and Dihydrogen by Dehydrogenative Coupling of Primary Alcohols with Secondary Amines Catalyzed by Ruthenium Bipyridine-Based Pincer Complexes. Cheminform. 45: no-no. DOI: 10.1002/CHIN.201415054  0.741
2013 Zell T, Langer R, Iron MA, Konstantinovski L, Shimon LJW, Diskin-Posner Y, Leitus G, Balaraman E, Ben-David Y, Milstein D. Synthesis, structures, and dearomatization by deprotonation of iron complexes featuring bipyridine-based PNN pincer ligands Inorganic Chemistry. 52: 9636-9649. PMID 23902514 DOI: 10.1021/Ic401432M  0.487
2013 Langer R, Fuchs I, Vogt M, Balaraman E, Diskin-Posner Y, Shimon LJ, Ben-David Y, Milstein D. Stepwise metal-ligand cooperation by a reversible aromatization/deconjugation sequence in ruthenium complexes with a tetradentate phenanthroline-based ligand. Chemistry (Weinheim An Der Bergstrasse, Germany). 19: 3407-14. PMID 23362113 DOI: 10.1002/Chem.201204003  0.563
2013 Balaraman E, Khaskin E, Leitus G, Milstein D. Catalytic transformation of alcohols to carboxylic acid salts and H2 using water as the oxygen atom source. Nature Chemistry. 5: 122-5. PMID 23344447 DOI: 10.1038/Nchem.1536  0.607
2013 Barrios-Francisco R, Balaraman E, Diskin-Posner Y, Leitus G, Shimon LJW, Milstein D. PNN ruthenium pincer complexes based on phosphinated 2,2′- dipyridinemethane and 2,2′-oxobispyridine. metal-ligand cooperation in cyclometalation and catalysis Organometallics. 32: 2973-2982. DOI: 10.1021/Om400194W  0.503
2013 Srimani D, Balaraman E, Gnanaprasam B, Ben-David Y, Milstein D. ChemInform Abstract: Ruthenium Pincer-Catalyzed Cross-Dehydrogenative Coupling of Primary Alcohols with Secondary Alcohols under Neutral Conditions. Cheminform. 44: no-no. DOI: 10.1002/CHIN.201309055  0.721
2013 Srimani D, Balaraman E, Hu P, Ben-David Y, Milstein D. Formation of tertiary amides and dihydrogen by dehydrogenative coupling of primary alcohols with secondary amines catalyzed by ruthenium bipyridine-based pincer complexes Advanced Synthesis and Catalysis. 355: 2525-2530. DOI: 10.1002/Adsc.201300620  0.784
2012 Balaraman E, Fogler E, Milstein D. Efficient hydrogenation of biomass-derived cyclic di-esters to 1,2-diols. Chemical Communications (Cambridge, England). 48: 1111-3. PMID 22038098 DOI: 10.1039/C1Cc15778G  0.582
2012 Gnanaprakasam B, Balaraman E, Gunanathan C, Milstein D. Synthesis of polyamides from diols and diamines with liberation of H 2 Journal of Polymer Science, Part a: Polymer Chemistry. 50: 1755-1765. DOI: 10.1002/Pola.25943  0.587
2012 Srimani D, Balaraman E, Gnanaprakasam B, Ben-David Y, Milstein D. Ruthenium pincer-catalyzed cross-dehydrogenative coupling of primary alcohols with secondary alcohols under neutral conditions Advanced Synthesis and Catalysis. 354: 2403-2406. DOI: 10.1002/Adsc.201200438  0.79
2011 Balaraman E, Ben-David Y, Milstein D. Unprecedented catalytic hydrogenation of urea derivatives to amines and methanol. Angewandte Chemie (International Ed. in English). 50: 11702-5. PMID 22052711 DOI: 10.1002/Anie.201106612  0.59
2011 Gnanaprakasam B, Balaraman E, Ben-David Y, Milstein D. Synthesis of peptides and pyrazines from β-amino alcohols through extrusion of H2 catalyzed by ruthenium pincer complexes: ligand-controlled selectivity. Angewandte Chemie (International Ed. in English). 50: 12240-4. PMID 22031234 DOI: 10.1002/Anie.201105876  0.553
2011 Livanov K, Madhu V, Balaraman E, Shimon LJ, Diskin-Posner Y, Neumann R. Photocatalytic splitting of CS2 to S8 and a carbon-sulfur polymer catalyzed by a bimetallic ruthenium(II) compound with a tertiary amine binding site: toward photocatalytic splitting of CO2? Inorganic Chemistry. 50: 11273-5. PMID 22029376 DOI: 10.1021/Ic2008045  0.345
2011 Balaraman E, Gunanathan C, Zhang J, Shimon LJ, Milstein D. Efficient hydrogenation of organic carbonates, carbamates and formates indicates alternative routes to methanol based on CO2 and CO. Nature Chemistry. 3: 609-14. PMID 21778980 DOI: 10.1038/Nchem.1089  0.624
2011 Zhang J, Balaraman E, Leitus G, Milstein D. Electron-rich PNP-and PNN-type ruthenium(ii) hydrido borohydride pincer complexes. synthesis, structure, and catalytic dehydrogenation of alcohols and hydrogenation of esters Organometallics. 30: 5716-5724. DOI: 10.1021/Om200595M  0.572
2011 Fogler E, Balaraman E, Ben-David Y, Leitus G, Shimon LJW, Milstein D. New CNN-type ruthenium pincer NHC complexes. Mild, efficient catalytic hydrogenation of esters Organometallics. 30: 3826-3833. DOI: 10.1021/Om200367J  0.57
2011 Kumara Swamy KC, Allu S, Srinivas V, Balaraman E, Kumar KVPP. Alkynyl and phosphonyl substituted nucleobases: A case of thermally induced conformational polymorphism Crystal Growth and Design. 11: 2302-2310. DOI: 10.1021/Cg101737X  0.317
2011 Srinivas V, Balaraman E, Sajna KV, Swamy KCK. Catalyst‐Free and Catalysed Addition of P(O)–H Bonds to Allenyl/Alkynyl‐Phosphonates and ‐Phosphane Oxides: Use of a Robust, Recoverable Dinuclear Palladium(I) Catalyst European Journal of Organic Chemistry. 2011: 4222-4230. DOI: 10.1002/Ejoc.201100197  0.34
2010 Balaraman E, Gnanaprakasam B, Shimon LJ, Milstein D. Direct hydrogenation of amides to alcohols and amines under mild conditions. Journal of the American Chemical Society. 132: 16756-8. PMID 21049928 DOI: 10.1021/Ja1080019  0.689
2009 Swamy KC, Kumar NN, Balaraman E, Kumar KV. Mitsunobu and related reactions: advances and applications. Chemical Reviews. 109: 2551-651. PMID 19382806 DOI: 10.1021/Cr800278Z  0.346
2009 Balaraman E, Srinivas V, Swamy KCK. Hydrophosphonylation of activated alkenes and alkynes via fluoride ion activation in ionic liquid medium Tetrahedron. 65: 7603-7610. DOI: 10.1016/J.Tet.2009.06.096  0.328
2007 Balaraman E, Swamy KCK. A convenient chromatography-free access to enantiopure 6,6′-di-tert-butyl-1,1′-binaphthalene-2,2′-diol and its 3,3′-dibromo, di-tert-butyl and phosphorus derivatives: utility in asymmetric synthesis Tetrahedron-Asymmetry. 18: 2037-2048. DOI: 10.1016/J.Tetasy.2007.06.028  0.366
2006 Swamy KCK, Balaraman E, Kumar NS. Synthesis and utility of new amine/nucleobase addition products of allenylphosphonates Tetrahedron. 62: 10152-10161. DOI: 10.1016/J.Tet.2006.08.034  0.379
2006 Swamy KCK, Balaraman E, Pavan MP, Kumar NNB, Kumar KP, Kumar NS. Unusual products in the reactions of phosphorus(III) compounds with N=N, C≡C or conjugated double-bonded systems Journal of Chemical Sciences. 118: 495-501. DOI: 10.1007/Bf02703946  0.33
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