Robert B. Grossman, Ph.D. - Publications

Affiliations: 
University of Kentucky, Lexington, KY 
Area:
Synthetic Organic Chemistry
Website:
https://chem.as.uky.edu/users/rbgros1

44 high-probability publications. We are testing a new system for linking publications to authors. You can help! If you notice any inaccuracies, please sign in and mark papers as correct or incorrect matches. If you identify any major omissions or other inaccuracies in the publication list, please let us know.

Year Citation  Score
2020 Bhardwaj M, Ai Q, Parkin SR, Grossman RB. An unusually short inter-molecular N-H⋯N hydrogen bond in crystals of the hemi-hydro-chloride salt of 1--acetamido-pyrrolizidine. Acta Crystallographica. Section E, Crystallographic Communications. 76: 77-81. PMID 31921456 DOI: 10.1107/S2056989019016517  0.491
2019 Pan J, Wenger ES, Matthews ML, Pollock CJ, Bhardwaj M, Kim AJ, Allen BD, Grossman RB, Krebs C, Bollinger JM. Evidence for Modulation of Oxygen-Rebound Rate in Control of Outcome by Iron(II)- and 2-Oxoglutarate-Dependent Oxygenases. Journal of the American Chemical Society. PMID 31475820 DOI: 10.1021/Jacs.9B06689  0.496
2018 Kearney SE, Zahoránszky-Kőhalmi G, Brimacombe KR, Henderson MJ, Lynch C, Zhao T, Wan KK, Itkin Z, Dillon C, Shen M, Cheff DM, Lee TD, Bougie D, Cheng K, Coussens NP, ... ... Grossman RB, et al. Canvass: A Crowd-Sourced, Natural-Product Screening Library for Exploring Biological Space. Acs Central Science. 4: 1727-1741. PMID 30648156 DOI: 10.1021/Acscentsci.8B00747  0.676
2018 Pan J, Bhardwaj M, Zhang B, Chang WC, Schardl CL, Krebs C, Grossman RB, Bollinger JM. Installation of the ether bridge of lolines by the iron- and 2-oxoglutarate-dependent oxygenase, LolO: regio- and stereochemistry of sequential hydroxylation and oxacyclization reactions. Biochemistry. PMID 29537853 DOI: 10.1021/Acs.Biochem.8B00157  0.556
2018 Yang XW, Grossman RB, Xu G. Research Progress of Polycyclic Polyprenylated Acylphloroglucinols. Chemical Reviews. PMID 29461053 DOI: 10.1021/Acs.Chemrev.7B00551  0.314
2014 Pan J, Bhardwaj M, Nagabhyru P, Grossman RB, Schardl CL. Enzymes from fungal and plant origin required for chemical diversification of insecticidal loline alkaloids in grass-Epichloë symbiota. Plos One. 9: e115590. PMID 25531527 DOI: 10.1371/Journal.Pone.0115590  0.499
2014 Pan J, Bhardwaj M, Faulkner JR, Nagabhyru P, Charlton ND, Higashi RM, Miller AF, Young CA, Grossman RB, Schardl CL. Ether bridge formation in loline alkaloid biosynthesis. Phytochemistry. 98: 60-8. PMID 24374065 DOI: 10.1016/J.Phytochem.2013.11.015  0.514
2010 Roy S, Ernst J, Kharchenko PV, Kheradpour P, Negre N, Eaton ML, Landolin JM, Bristow CA, Ma L, Lin MF, Washietl S, Arshinoff BI, Ay F, Meyer PE, ... ... Grossman R, et al. Identification of functional elements and regulatory circuits by Drosophila modENCODE. Science (New York, N.Y.). 330: 1787-97. PMID 21177974 DOI: 10.1126/Science.1198374  0.5
2010 DE LA PUENTE ML, GROSSMAN RB, LEY SV, SIMMONDS MSJ, BLANEY WM. ChemInform Abstract: Chemistry of Insect Antifeedants from Azadirachta indica. Part 20. Synthesis of Biologically Active, Simple Analogues of Azadirachtin, Containing the Hydroxytetrahydrofurancarboxylate Hemiketal Moiety. Cheminform. 27: no-no. DOI: 10.1002/chin.199640104  0.413
2010 GROSSMAN RB, LEY SV. ChemInform Abstract: Chemistry of Insect Antifeedants from Azadirachta indica. Part 17. Synthesis of Model Compounds of Azadirachtin. Unusual Effect of Remote Substituents on the Course of the Oxidative Ring Contraction Reaction. Cheminform. 26: no-no. DOI: 10.1002/chin.199511231  0.439
2010 BERK SC, GROSSMAN RB, BUCHWALD SL. ChemInform Abstract: Titanocene-Catalyzed Conversion of Enynes to Bicyclic Cyclopentenones. Cheminform. 24: no-no. DOI: 10.1002/chin.199340158  0.716
2010 GROSSMAN RB, BUCHWALD SL. ChemInform Abstract: Reductive Cyclization of Ester-Containing Enynes with a Practical Titanocene Reagent. Synthesis of Bicyclic Cyclopentenones and Iminocyclopentenes. Cheminform. 24: no-no. DOI: 10.1002/chin.199309065  0.453
2010 GROSSMAN RB, DAVIS WM, BUCHWALD SL. ChemInform Abstract: Enantioselective, Zirconium-Mediated Synthesis of Allylic Amines. Cheminform. 22: no-no. DOI: 10.1002/chin.199130134  0.476
2007 Schardl CL, Grossman RB, Nagabhyru P, Faulkner JR, Mallik UP. Loline alkaloids: Currencies of mutualism. Phytochemistry. 68: 980-96. PMID 17346759 DOI: 10.1016/J.Phytochem.2007.01.010  0.364
2006 Faulkner JR, Hussaini SR, Blankenship JD, Pal S, Branan BM, Grossman RB, Schardl CL. On the sequence of bond formation in loline alkaloid biosynthesis. Chembiochem : a European Journal of Chemical Biology. 7: 1078-88. PMID 16755627 DOI: 10.1002/Cbic.200600066  0.321
2006 Chamala RR, Ciochina R, Grossman RB, Finkel RA, Kannan S, Ramachandran P. EPOCH: An organic chemistry homework program that offers response-specific feedback to students Journal of Chemical Education. 83: 164-169. DOI: 10.1021/Ed083P164  0.682
2004 Grossman RB, Rasne RM. Chapter 1 Methodology validation and structure correction by total synthesis: The case of the clerodane diterpenoid, sacacarin Strategies and Tactics in Organic Synthesis. 4: 1-18. DOI: 10.1016/S1874-6004(04)80005-4  0.416
2003 Ciochina R, Grossman RB. A new synthetic approach to the polycyclic polyprenylated acylphloroglucinols. Organic Letters. 5: 4619-21. PMID 14627398 DOI: 10.1021/Ol0357907  0.357
2003 Grossman RB, Comesse S, Rasne RM, Hattori K, Delong MN. Phosphoramidites are efficient, green organocatalysts for the Michael reaction. Mechanistic insights into the phosphorus-catalyzed Michael reaction of alkynones and implications for asymmetric catalysis. The Journal of Organic Chemistry. 68: 871-4. PMID 12558409 DOI: 10.1021/Jo026425G  0.423
2002 Holeman DS, Rasne RM, Grossman RB. Trimethylsilylethynyl ketones as surrogates for ethynyl ketones in the double Michael reaction. The Journal of Organic Chemistry. 67: 3149-51. PMID 11975585 DOI: 10.1021/Jo0163086  0.427
2001 Grossman RB, Rasne RM. Short total syntheses of both the putative and actual structures of the clerodane diterpenoid (+/-)-sacacarin by double annulation. Organic Letters. 3: 4027-30. PMID 11735576 DOI: 10.1021/Ol016748J  0.412
2001 Hughes F, Grossman RB. A heterocycle-forming double michael reaction. [5 + 1] annulation route to highly substituted and functionalized piperidines. Organic Letters. 3: 2911-4. PMID 11529788 DOI: 10.1021/Ol016395O  0.461
2001 Nisbet AJ, Mordue Luntz AJ, Grossman RB, Jennens L, Ley SV, Mordue W. Characterization of azadirachtin binding to Sf9 nuclei in vitro. Archives of Insect Biochemistry and Physiology. 46: 78-86. PMID 11276064 DOI: 10.1002/Arch.11  0.329
2000 Grossman RB, Pendharkar DS, Rasne RM, Varner MA. Double annulation route to highly substituted and functionalized cis bicyclic and tricyclic delta-lactams and imides The Journal of Organic Chemistry. 65: 3255-8. PMID 10814230 DOI: 10.1021/Jo0000978  0.307
1999 Grossman RB, Skaggs AJ, Kray AE, Patrick BO. Double annulation route to fused bicyclic compounds with three contiguous quaternary centers Organic Letters. 1: 1583-1586. DOI: 10.1021/Ol990935O  0.369
1999 Grossman RB, Rasne RM, Patrick BO. Nitro compounds in the double annulation route to trans-fused bicyclic compounds Journal of Organic Chemistry. 64: 7173-7177. DOI: 10.1021/Jo9907888  0.387
1999 Grossman RB, Pendharkar DS, Patrick BO. [n + 1] Annulation route to highly substituted cyclic ketones with pendant ketone, nitrile, and ester functionality Journal of Organic Chemistry. 64: 7178-7183. DOI: 10.1021/Jo9907787  0.45
1999 Grossman RB, Varner MA, Skaggs AJ. Double annulation route to highly substituted and functionalized trans- fused bicyclic compounds Journal of Organic Chemistry. 64: 340-341. DOI: 10.1021/Jo9822737  0.332
1999 Grossman RB. Pauson-Khand approach to chiral, diastereomerically pure group 4 ansa- metallocene complexes Tetrahedron. 55: 919-934. DOI: 10.1016/S0040-4020(98)01099-0  0.356
1996 Puente MLdl, Grossman RB, Ley SV, Simmonds MSJ, Blaney WM. Chemistry of insect antifeedants from Azadirachta indica(part 20): synthesis of biologically active, simple analogues of azadirachtin, containing the hydroxytetrahydrofurancarboxylate hemiketal moiety Journal of the Chemical Society-Perkin Transactions 1. 1517-1521. DOI: 10.1039/P19960001517  0.455
1995 Simmonds MSJ, Blaney WM, Ley SV, Anderson JC, Banteli R, Denholm AA, Green PCW, Grossman RB, Gutteridge C, Jennens L, Smith SC, Toogood PL, Wood A. Behavioural and neurophysiological responses of Spodoptera littoralis to azadirachtin and a range of synthetic analogues Entomologia Experimentalis Et Applicata. 77: 69-80. DOI: 10.1111/J.1570-7458.1995.Tb01987.X  0.537
1995 Simmonds M, Blaney W, Grossman R, Ley S. Behavioural responses of locusts and Spodoptera littoralis to azadirachtin and azadirachtin analogues containing fluorescent and immunogenic reporter groups Journal of Insect Physiology. 41: 555-564. DOI: 10.1016/0022-1910(95)00014-L  0.382
1995 BERK SC, GROSSMAN RB, BUCHWALD SL. ChemInform Abstract: Development of a Titanocene-Catalyzed Enyne Cyclization/Isocyanide Insertion Reaction. Cheminform. 26: no-no. DOI: 10.1002/chin.199516102  0.723
1994 Grossman RB, Tsai J, Davis WM, Gutierrez A, Buchwald SL. Synthesis and Structure of a C2-Symmetric, Doubly Bridged ansa-Titanocene Complex Organometallics. 13: 3892-3896. DOI: 10.1021/Om00022A026  0.448
1994 Berk SC, Grossman RB, Buchwald SL. Development of a Titanocene-Catalyzed Enyne Cyclization/Isocyanide Insertion Reaction Journal of the American Chemical Society. 116: 8593-8601. DOI: 10.1021/Ja00098A020  0.728
1994 Grossman RB, Ley SV. Chemistry of insect antifeedants from Azadirachta indica (Part 16): Synthesis of several derivatives of azadirachtin containing fluorescent or immunogenic reporter groups Tetrahedron. 50: 8871-8884. DOI: 10.1016/S0040-4020(01)85360-6  0.41
1994 Berk SC, Grossman RB, Buchwald SL. Development of a titanocene-catalyzed enyne cyclization/isocyanide insertion reaction Journal of the American Chemical Society. 116: 8593-8601.  0.695
1993 Berk SC, Grossman RB, Buchwald SL. Titanocene-catalyzed conversion of enynes to bicyclic cyclopentenones Journal of the American Chemical Society. 115: 4912-4913. DOI: 10.1021/Ja00064A071  0.729
1993 Berk SC, Grossman RB, Buchwald SL. Titanocene-catalyzed conversion of enynes to bicyclic cyclopentenones Journal of the American Chemical Society. 115: 4912-4913.  0.696
1992 Grossman RB, Buchwald SL. Reductive cyclization of ester-containing enynes with a practical titanocene reagent. Synthesis of bicyclic cyclopentenones and iminocyclopentenes The Journal of Organic Chemistry. 57: 5803-5805. DOI: 10.1021/Jo00048A001  0.554
1991 Grossman RB, Doyle RA, Buchwald SL. Syntheses of [ethylene-1,2-bis(.eta.5-4,5,6,7-tetrahydro-1-indenyl)]zirconium and -hafnium hydride complexes. Improved syntheses of the corresponding dichlorides Organometallics. 10: 1501-1505. DOI: 10.1021/Om00051A047  0.401
1991 Grossman RB, Davis WM, Buchwald SL. Enantioselective, zirconium-mediated synthesis of allylic amines Journal of the American Chemical Society. 113: 2321-2322. DOI: 10.1021/Ja00006A071  0.531
1987 Pascal RA, Grossman RB, Van Engen D. Synthesis of in-[34,10][7]metacyclophane: Projection of an aliphatic hydrogen toward the center of an aromatic ring Journal of the American Chemical Society. 109: 6878-6880. DOI: 10.1021/Ja00256A067  0.307
1987 Horn KA, Grossman RB, Whitenack AA. The palladium catalyzed synthesis of substituted phenylethynylpentamethyldisilanes and phenylethynylheptamethyltrisilanes Journal of Organometallic Chemistry. 332: 271-278. DOI: 10.1016/0022-328X(87)85094-5  0.428
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