Takeshi Nakai - Publications

Affiliations: 
Department of Applied Chemistry Tokyo Institute of Technology 

164 high-probability publications. We are testing a new system for linking publications to authors. You can help! If you notice any inaccuracies, please sign in and mark papers as correct or incorrect matches. If you identify any major omissions or other inaccuracies in the publication list, please let us know.

Year Citation  Score
2005 Tomooka K, Komine N, Fujiki D, Nakai T, Yanagitsuru S. Planar chiral cyclic ether: asymmetric resolution and chirality transformation. Journal of the American Chemical Society. 127: 12182-3. PMID 16131170 DOI: 10.1021/Ja053347G  0.367
2005 Tayama E, Tanaka H, Nakai T. Kinetic Resolution via the [2,3] Stevens Rearrangement of Epimeric Six-Membered Ammonium Ylides : A New Entry to Enantio-enriched α-Amino Acid Derivatives Heterocycles. 66: 95-99. DOI: 10.3987/Com-05-S(K)39  0.426
2005 Tomooka K, Komine N, Fujiki D, Nakai T, Yanagitsuru S. Planar Chiral Cyclic Ether Synfacts. 2005: 303-303. DOI: 10.1055/S-2005-921611  0.364
2004 Harada M, Nakai T, Tomooka K. Stevens rearrangement of a cyclic hemiacetal system: Diastereoselective approach to chiral α-amino ketone Synlett. 2004: 365-367. DOI: 10.1055/S-2003-44998  0.421
2004 Hanyuda K, Hirai K, Nakai T. Unique Molecular Discrimination in Europium Complex-Catalyzed Reactions of Saturated and α,β-Unsaturated Ketones with Ketene Silyl Acetals Synlett. 1: 31-32. DOI: 10.1055/S-1997-716  0.375
2004 NakaI T, MikamI K. The [2,3]‐Wittig Rearrangement Organic Reactions. 105-209. DOI: 10.1002/0471264180.Or046.02  0.408
2003 Mikami K, Terada M, Narisawa S, Nakai T. Asymmetric Catalytic Glyoxylate‐Ene Reaction: Methyl (2R)‐2‐Hydroxy‐4‐Phenyl‐4‐Pentenoate Organic Syntheses. 14-14. DOI: 10.1002/0471264180.Os071.02  0.406
2001 Nakai T, Mikoshiba H, Mikami K. Diastereocontrol in the Reaction of (R)-2,2-Dimethyl-4-acyl-1,3-dioxolanes with Alkylmetals: A Facile Entry to Enantiopure Terpenetriols Heterocycles. 54: 585-588. DOI: 10.3987/Com-00-S(I)76  0.331
2000 Tomooka K, Kikuchi M, Igawa K, Suzuki M, Keong PH, Nakai T. Stereoselective Total Synthesis of Zaragozic Acid A based on an Acetal Angewandte Chemie (International Ed. in English). 39: 4502-4505. PMID 11169650 DOI: 10.1002/1521-3773(20001215)39:24<4502::Aid-Anie4502>3.0.Co;2-K  0.35
2000 Tomooka K, Yamamoto H, Nakai T. Stereoselective Synthesis of Highly Functionalized C-Glycosides based on Acetal Angewandte Chemie (International Ed. in English). 39: 4500-4502. PMID 11169649 DOI: 10.1002/1521-3773(20001215)39:24<4500::Aid-Anie4500>3.3.Co;2-N  0.333
1998 Sugiura M, Yagi Y, Wei SY, Nakai T. Chiral dienolate-based remote asymmetric induction: The asymmetric α-oxylation/Pd(0)-catalyzed allylic substitution sequence leading to γ-chiral α, β-unsaturated acid derivatives Tetrahedron Letters. 39: 4351-4354. DOI: 10.1016/S0040-4039(98)00770-9  0.396
1997 Nakai T, Tomooka K. Asymmetric (2,3)-Wittig rearrangement as a general tool for asymmetric synthesis Pure and Applied Chemistry. 69: 595-600. DOI: 10.1351/Pac199769030595  0.417
1997 Tomooka K, Komine N, Nakai T. Wittig Rearrangement of α-(Propargyloxy)alkyllithiums: Periselectivity and Steric Course at the Lithium-Bearing Terminus Synlett. 1997: 1045-1046. DOI: 10.1055/S-1997-1551  0.353
1997 Tomooka K, Komine N, Nakai T. Cyclization of enantio-enriched α-(homoallyloxy)alkyllithiums: Evidence for retention of configuration at the carbanion center Tetrahedron Letters. 38: 8939-8942. DOI: 10.1016/S0040-4039(97)10327-6  0.379
1997 Mori M, Nakai T. Asymmetric Catalytic Alkylation of Aldehydes with Diethylzinc Using a Chiral Binaphthol-Titanium Complex Tetrahedron Letters. 38: 6233-6236. DOI: 10.1016/S0040-4039(97)01433-0  0.365
1997 Mori M, Imma H, Nakai T. Asymmetric Catalytic Cyanosilylation of Aldehydes Using a Chiral Binaphthol-Titanium Complex Tetrahedron Letters. 38: 6229-6232. DOI: 10.1016/S0040-4039(97)01432-9  0.363
1997 Sugiura M, Nakai T. Asymmetric Catalytic Protonation of Silyl Enol Ethers with Chiral Palladium Complexes Angewandte Chemie. 36: 2366-2368. DOI: 10.1002/Anie.199723661  0.354
1996 Tomooka K, Nakai T. [1, 2] -Wittig Rearrangement Stereochemical Features and Synthetic Utilities Journal of Synthetic Organic Chemistry Japan. 54: 1000-1008. DOI: 10.5059/Yukigoseikyokaishi.54.1000  0.41
1996 Nishiuchi M, Honda K, Nakai T. Stereocontrol by Lewis Acids in the Hetero-Diels-Alder Reaction Leading to a Key 1β-Methylcarbapenem Intermediate Chemistry Letters. 1996: 321-322. DOI: 10.1246/Cl.1996.321  0.405
1996 Imma H, Mori M, Nakai T. Asymmetric Catalytic Hydrosilylation of Ketones with Triethoxysilane Using a Chiral Binaphthol-Titanium Complex Synlett. 1996: 1229-1230. DOI: 10.1055/S-1996-5726  0.371
1996 Tomooka K, Nagasawa A, Wei SY, Nakai T. Chiral dienolate chemistry in remote asymmetric induction: The asymmetric aldol / oxycope strategy for asymmetric synthesis of γ,δ-dichiral α, β-unsaturated acid derivatives Tetrahedron Letters. 37: 8899-8900. DOI: 10.1016/S0040-4039(96)02078-3  0.396
1996 Tomooka K, Nagasawa A, Wei S, Nakai T. Chiral dienolate chemistry in remote asymmetric induction: the allylation / cope rearrangement sequence leading to γ-chiral α, β-unsaturated acid derivatives Tetrahedron Letters. 37: 8895-8898. DOI: 10.1016/S0040-4039(96)02077-1  0.416
1996 Sugiura M, Nakai T. Regiochemical control in the Pd(II)-catalyzed claisen rearrangement via in situ enol ether exchange Tetrahedron Letters. 37: 7991-7994. DOI: 10.1016/0040-4039(96)01790-X  0.386
1996 Kobayashi M, Masumoto K, Nakai E, Nakai T. Stereochemical control in the silyl triflate-mediated Claisen rearrangement of allylic esters Tetrahedron Letters. 37: 3005-3008. DOI: 10.1016/0040-4039(96)00485-6  0.401
1995 Sugiura M, Nakai T. Stereochemical Feature of Palladium(II)-Catalyzed Claisen Rearrangement Chemistry Letters. 1995: 697-698. DOI: 10.1246/Cl.1995.697  0.339
1995 Tomooka K, Ishikawa K, Nakai T. Asymmetric [2,3]-Wittig Rearrangement Approach to the Formal Synthesis of (+)-Brefeldin A Synlett. 1995: 901-902. DOI: 10.1055/S-1995-5152  0.36
1995 Sugiura M, Yanagisawa M, Nakai T. An Improved Procedure for the Pd(II)-Catalyzed Claisen Rearrangement via In Situ Enol Ether Exchange Synlett. 1995: 447-448. DOI: 10.1055/S-1995-5005  0.327
1995 Narita T, Hagiwara T, Hamana H, Tomooka K, Liu Y, Nakai T. Unique radical addition reactions onto perfluoro-enol esters Tetrahedron Letters. 36: 6091-6094. DOI: 10.1016/0040-4039(95)01211-Y  0.371
1995 Kitamoto D, Imma H, Nakai T. Asymmetric catalysis by a new type of chiral binaphthol-titanium complex Tetrahedron Letters. 36: 1861-1864. DOI: 10.1016/0040-4039(95)00134-X  0.368
1995 Otera J, Fujita Y, Fukuzumi S, Hirai K, Gu J, Nakai T. Diastereocontrol in Lewis acid-catalyzed Michael reactions of 4-siloxycyclopentenone with ketene silyl acetals: Stereoelectronic vs. steric effect Tetrahedron Letters. 36: 95-98. DOI: 10.1016/0040-4039(94)02174-A  0.423
1994 Bégué J, Bonnet-Delpon D, Wu S, M'Bida A, Shintani T, Nakai T. Claisen rearrangement of α-(F-alkyl)enol ethers prepared via Wittig olefination of allyl perfluoroalkanoates Tetrahedron Letters. 35: 2907-2910. DOI: 10.1016/S0040-4039(00)76656-1  0.374
1993 Tomooka K, Ishikawa K, Nakai T. A New Cyclic Version of [2,3]Wittig Rearrangement: A Simple Approach to the Stereocontrolled Introduction of an α-Chiral Side Chain onto Cyclopentane Ring Systems Synlett. 1993: 527-528. DOI: 10.1055/S-1993-22517  0.376
1993 Mikami K, Matsueda H, Nakai T. Intramolecular Ene-Based Approach to Furofuran Lignans: Total Synthesis of Neopaulownin Synlett. 1993: 235-236. DOI: 10.1055/S-1993-22416  0.343
1993 Mikami K, Terada M, Nakai T. Control of chelation/nonchelation stereoselections in lanthanide-catalysed aldol reactions Journal of the Chemical Society, Chemical Communications. 343-345. DOI: 10.1039/C39930000343  0.389
1993 Nakazawa M, Sakamoto Y, Takahashi T, Tomooka K, Ishikawa K, Nakai T. A new approach to asymmetric synthesis of Stork's prostaglandin intermediate Tetrahedron Letters. 34: 5923-5926. DOI: 10.1016/S0040-4039(00)73815-9  0.381
1993 Mikami K, Matsueda H, Nakai T. Intramolecular 11-(3,4) ene approach to the bicyclic core of enediyne antibiotics: Dynemicin, calicheamicin, and esperamicin Tetrahedron Letters. 34: 3571-3572. DOI: 10.1016/S0040-4039(00)73638-0  0.336
1993 Wei SY, Tomooka K, Nakai T. Acyclic diastereocontrol and asymmetric transmission via anionic oxy-Cope rearrangement. Synthesis of key precursors of (+)-faranal and (−)-antirhine Tetrahedron. 49: 1025-1042. DOI: 10.1016/S0040-4020(01)86283-9  0.357
1992 Terada M, Gu J, Deka DC, Mikami K, Nakai T. Stereo-modulating catalysis by europium(III) complexes in aldol reactions of chiral α-alkoxy aldehydes with ketene silyl acetals Chemistry Letters. 1992: 29-32. DOI: 10.1246/Cl.1992.29  0.412
1992 Kishi N, Imma H, Mikami K, Nakai T. Novel SN2′-Type Reaction of β-(Silyl)allylic Ethers with Alkyllithiums: A Stereoselective Entry to (E)-Vinylic Silanes Synlett. 1992: 189-190. DOI: 10.1055/S-1992-21308  0.382
1992 Kishi N, Maeda T, Mikami K, Nakai T. [2,3]Wittig rearrangement-peterson olefination sequence: a stereocontrolled entry to terminal conjugated trienes Tetrahedron. 48: 4087-4098. DOI: 10.1016/S0040-4020(01)92188-X  0.397
1991 Mikami K, Nakai T. Acyclic Stereocontrol via [2,3]-Wittig Sigmatropic Rearrangement Synthesis. 1991: 594-604. DOI: 10.1055/S-1991-26523  0.35
1991 Wei SY, Tomooka K, Nakai T. Acyclic diastereocontrol and asymmetric transmission via anionic oxy-Cope rearrangement: a synthetic application of sequential [2,3]Wittig-oxy-Cope rearrangements Journal of Organic Chemistry. 56: 5973-5974. DOI: 10.1021/Jo00021A002  0.336
1991 Mikami K, Wakabayashi H, Nakai T. A new vinylsilane substitution reaction with glyoxylate: asymmetric synthesis of .alpha.-hydroxy .beta.,.gamma.-unsaturated esters Journal of Organic Chemistry. 56: 4337-4339. DOI: 10.1021/Jo00014A002  0.447
1991 Nakai T, Qian C-, Kobayashi M, Hirasa T. Claisen rearrangements of fluorinated enol ethers: new entries to α-monofluoro and α, α-difluoro carboxylic acids Journal of Fluorine Chemistry. 54: 68. DOI: 10.1016/S0022-1139(00)83578-2  0.386
1990 Mikami K, Terada M, Nakai T. “Chemzyme” for Carbonyl-Ene Reactions Journal of Japan Oil Chemists Society. 39: 837-845. DOI: 10.5650/Jos1956.39.10_837  0.326
1990 Murata Y, Nakai T. Feasibility Studies on Amino-[2,3]Wittig Rearrangement. Silyl Triflate-Mediated [2,3]-Sigmatropic Rearrangement of α-Allylamino Esters Chemistry Letters. 19: 2069-2072. DOI: 10.1246/Cl.1990.2069  0.414
1990 Terada M, Mikami K, Nakai T. Remarkable positive nonlinear effect in the enantioselective glyoxylate–ene reaction catalysed by a chiral titanium complex Journal of the Chemical Society, Chemical Communications. 1623-1624. DOI: 10.1039/C39900001623  0.387
1990 Qian CP, Nakai T, Dixon DA, Smart BE. Ketone perfluoro enolates: regioselective and stereoselective synthesis, unique reactivities, and electronic properties Journal of the American Chemical Society. 112: 4602-4604. DOI: 10.1021/Ja00167A101  0.356
1990 Qian C, Nakai T. Perfluoro-enolate chemistry: An “electrophile-coexisting” procedure for carbon-carbon bond forming reactions with an ester lithium f-enolate Tetrahedron Letters. 31: 7043-7046. DOI: 10.1016/S0040-4039(00)97238-1  0.317
1990 Tomooka K, Watanabe M, Nakai T. Highly periselective [2,3]wittig rearrangements on dihydrofuran and dihydropyran rings Tetrahedron Letters. 31: 7353-7354. DOI: 10.1016/S0040-4039(00)88564-0  0.347
1989 Shirai F, Nakai T. A New Synthetic Route to the Key Precursor of 1β-Methylcarbapenem Antibiotics from (S)-Methyl 3-Hydroxy-2-methylpropanoate Chemistry Letters. 18: 445-448. DOI: 10.1246/Cl.1989.445  0.4
1989 Mikami K, Kishi N, Nakai T. Silicon-Directed Regiocontrol in Wittig Rearrangements of Bis-Allyl Ethers and Allyl Propargyl Ethers Chemistry Letters. 18: 1683-1686. DOI: 10.1246/Cl.1989.1683  0.371
1989 Mikami K, Takahashi K, Nakai T. Intramolecular Ene Approach to Carbocyclization with Stereocontrol over Four Contiguous Chiral Centers: An Efficient Access to Iridoids Synlett. 1989: 45-46. DOI: 10.1055/S-1989-34689  0.342
1989 Mikami K, Terada M, Nakai T. Asymmetric glyoxylate-ene reaction catalyzed by chiral titanium complexes: a practical access to .alpha.-hydroxy esters in high enantiomeric purities Journal of the American Chemical Society. 111: 1940-1941. DOI: 10.1021/Ja00187A093  0.373
1988 Mikami K, Loh T, Nakai T. Ene approach for concurrent control over the chiral centres at C-20 and C-22 of steroid side chains: a highly stereocontrolled synthesis of (20S,22R)-(erythro-)22-hydroxy-23,24-acetylenic steroid side chains Journal of the Chemical Society, Chemical Communications. 1430-1431. DOI: 10.1039/C39880001430  0.367
1988 Nakai E, Nakai T. Siloxy-[2,3]Wittig rearrangement: A new method for diastereoselective preparations of 1,2-diol systems Tetrahedron Letters. 29: 5409-5412. DOI: 10.1016/S0040-4039(00)82881-6  0.312
1988 Shirai F, Nakai T. A novel, double-asymmetric aldol approach to the synthesis of a 1β-methyl carbapenem antibiotic precursor Tetrahedron Letters. 29: 6461-6463. DOI: 10.1016/S0040-4039(00)82373-4  0.414
1988 Mikami K, Loh T, Nakai T. Diastereocontrol via Lewis acid-promoted ene reaction with glyoxylates and its application to stereocontrolled synthesis of a 22R-hydroxy-23-carboxylate steroid side chain Tetrahedron Letters. 29: 6305-6308. DOI: 10.1016/S0040-4039(00)82332-1  0.406
1988 Nakai E, Nakai T. Asymmetric induction in the [2,3]Wittig rearrangement of allylic ethers with a chiral substituent. New entries to stereocontrol over three contiguous chiral centers Tetrahedron Letters. 29: 4587-4590. DOI: 10.1016/S0040-4039(00)80554-7  0.421
1987 Mikami K, Takahashi K, Nakai T. Stereochemical Control in Intramolecular Ene Reactions of Crotyl Propargyl Ether Systems Chemistry Letters. 16: 2347-2350. DOI: 10.1246/Cl.1987.2347  0.403
1987 Chiba T, Nakai T. A new synthetic approach to the carbapenem antibiotic PS-5 from ethyl (S)-3-hydroxybutanoate. Chemistry Letters. 16: 2187-2188. DOI: 10.1246/Cl.1987.2187  0.329
1987 Yokozawa T, Ishikawa N, Nakai T. Reformatsky reaction of methyl 2-bromo-3,3,3-trifluoropropanoate. A synthetic method for α-trifluoromethyl-β-hydroxy esters Chemistry Letters. 16: 1971-1974. DOI: 10.1246/Cl.1987.1971  0.434
1987 Shirai F, Nakai T. A new approach to the chiral synthesis of the 1-.beta.-methylcarbapenem key precursor using an achiral ketone Sn(II) enolate Journal of Organic Chemistry. 52: 5491-5492. DOI: 10.1021/Jo00233A044  0.341
1986 Takahashi O, Saka T, Mikami K, Nakai T. [2,3]Wittig Rearrangements of “Lithium Enolates” Generated from α-Allyloxy Esters, Ketones, and Oximes. Some Implications of the Enolate Structures Chemistry Letters. 15: 1599-1602. DOI: 10.1246/Cl.1986.1599  0.357
1986 Takahashi O, Maeda T, Mikami K, Nakai T. [3,3]Claisen vs. [2,3]Wittig Shift in Thermal and Fluolide Ion-Promoted Rearrangements of the O- and C-Silylated Forms of α-Allyloxy Esters Chemistry Letters. 15: 1355-1358. DOI: 10.1246/Cl.1986.1355  0.354
1986 Nakai T, Mikami K. [2,3]-Wittig sigmatropic rearrangements in organic synthesis Chemical Reviews. 86: 885-902. DOI: 10.1021/Cr00075A011  0.326
1986 Mikami K, Kawamoto K, Nakai T. Application of [2,3]Wittig and [3,3]Claisen rearrangements in steroid side chain synthesis. A highly stereocontrolled entry to either (22 S)- or (22 R)-hydroxy-23-carboxylic acid Tetrahedron Letters. 27: 4899-4902. DOI: 10.1016/S0040-4039(00)85092-3  0.352
1986 Mikami K, Kishi N, Nakai T, Fujita Y. New sigmatropic sequences based on the [2,3]-wittig rearrangement of the bis-allylic ether system : A general approach to regiocontrolled c—c bond formation of allylic moieties leading to unsaturated carbonyl compounds Tetrahedron. 42: 2911-2918. DOI: 10.1016/S0040-4020(01)90580-0  0.368
1986 Mikami K, Kawamoto K, Nakai T. Application of [2,3]Wittig Rearrangement in Steroid Side Chain Synthesis. Cheminform. 17. DOI: 10.1002/Chin.198620312  0.302
1985 Chiba T, Nakai T. A Synthetic Approach To (+)-Thienamycin From Methyl (R)-3-Hydroxybutanoate. A New Entry To (3R, 4R)-3-[(R)-1-Hydroxyethyl]-4-Acetoxy-2-Azetidinone Chemistry Letters. 14: 651-654. DOI: 10.1246/Cl.1985.651  0.311
1985 Nakai E, Kitahara E, Sayo N, Ueno Y, Nakai T. [2,3]Wittig Rearrangement-Based Approaches To Stereocontrol Over Three Contiguous Chiral Centers. New Entries To The (±)-Prelog-Djerassi Lactone Chemistry Letters. 14: 1725-1728. DOI: 10.1246/Cl.1985.1725  0.384
1985 Sayo N, Nakai E, Nakai T. Application Of Asymmetric [2,3]Wittig Rearrangement To Stereocontrol Over Three Contiguous Chiral Centers. A New Synthesis Of (+)-Blastmycinone Chemistry Letters. 14: 1723-1724. DOI: 10.1246/Cl.1985.1723  0.445
1985 Mikami K, Kawamoto K, Nakai T. APPLICATION OF [2,3]WITTIG REARRANGEMENT IN STEROID SIDE CHAIN SYNTHESIS. A NEW ENTRY TO (22R)-HYDROXY-23-ACETYLENIC SIDE CHAINS VIA THE β-FACE REARRANGEMENT Chemistry Letters. 14: 1719-1722. DOI: 10.1246/Cl.1985.1719  0.362
1985 Chiba T, Nagatsuma M, Nakai T. A facile, stereocontrolled entry to key intermediates for thienamycin synthesis from ethyl (S)-3-hydroxybutanoate. Chemistry Letters. 14: 1343-1346. DOI: 10.1246/Cl.1985.1343  0.383
1985 Mikami K, Kawamoto K, Nakai T. Stereocontrolled synthesis of either (22S)- or (22R)-hydroxy-23-acetylenic steroid side chains via [2,3]-Wittig sigmatropic rearrangement Tetrahedron Letters. 26: 5799-5802. DOI: 10.1016/S0040-4039(00)98930-5  0.333
1985 Chiba T, Nakai T. An improved entry to a key intermediate for thienamycin synthesis from methyl (R)-3-hydroxybutanoate via direct epimerization at C-3 on 2-azetidinone rings Tetrahedron Letters. 26: 4647-4648. DOI: 10.1016/S0040-4039(00)98775-6  0.35
1985 Yokozawa T, Yamaguchi M, Nakai T, Ishikawa N. The Enol Silyl Ether of 3,3,3-Trifluoropropiophenone Preparation and Carbon-Carbon Bond Forming Reactions. Cheminform. 17: 2202-2204. DOI: 10.1002/Chin.198631266  0.379
1985 Nagatsuma M, Shirai F, Sayo N, Nakai T. 1,4-Chirality Transfer Via The Ester Enolate Claisen Rearrangement Cheminform. 16. DOI: 10.1002/Chin.198507099  0.343
1984 Sayo N, Kitahara E, Nakai T. HIGHLY ENANTIOSPECIFIC AND ERYTHRO-SELECTIVE [2,3]-WITTIG REARRANGEMENT OF ENANTIOMERICALLY-ENRICHED ALLYLIC BENZYL ETHERS. A NEW, FORMAL CHIRAL SYNTHESIS OF l-EPHEDRINE Chemistry Letters. 13: 259-262. DOI: 10.1246/Cl.1984.259  0.392
1984 Sayo N, Shirai F, Nakai T. 1,4-Chirality Transfer Via The [2,3]-Wittig Rearrangement Of Chiral Allylic Propargyl Ether System. A New, Practical Entry To Chiral Propargylic Alcohols Chemistry Letters. 13: 255-258. DOI: 10.1246/Cl.1984.255  0.356
1984 Chiba T, Nagatsuma M, Nakai T. A Facile Entry To 3-(1-Hydroxyethyl)-2-Azetidinones From Methyl (R)-3-Hydroxybutanoate Based On The Ester Enolate-Aldimine Condensation Chemistry Letters. 13: 1927-1930. DOI: 10.1246/Cl.1984.1927  0.324
1984 Nagatsuma M, Shirai F, Sayo N, Nakai T. 1,4-Chirality transfer via the ester enolate Claisen rearrangement Chemistry Letters. 13: 1393-1396. DOI: 10.1246/Cl.1984.1393  0.351
1984 Mikami K, Fujimoto K, Kasuga T, Nakai T. Asymmetric [2,3]Wittig sigmatropic rearrangement involving a chiral azaenolate as the migrating terminus. A simple synthesis of (+)-verrucarinolactone Tetrahedron Letters. 25: 6011-6014. DOI: 10.1016/S0040-4039(01)81746-9  0.434
1984 Mikami K, Maeda T, Kishi N, Nakai T. Asymmetric allylsilane-mediated carbocyclization: a highly enantiospecific synthesis of (1S, 2S)-(+)-2-methyl-3-cyclopenten-1-ol Tetrahedron Letters. 25: 5151-5154. DOI: 10.1016/S0040-4039(01)81549-5  0.422
1984 Sayo N, Azuma K, Mikami K, Nakai T. Acyclic stereocontrol via asymmetric [2,3]-Wittig rearrangement with high enantio- and erythro-selectivity and its use in the chiral synthesis of insect pheromones Tetrahedron Letters. 25: 565-568. DOI: 10.1016/S0040-4039(00)99939-8  0.384
1984 Yokozawa T, Nakai T, Ishikawa N. Alpha-Acylation and -allylation of β,β,β-trifluoropropionic esters via the ketene silyl acetals Tetrahedron Letters. 25: 3991-3994. DOI: 10.1016/0040-4039(84)80048-9  0.336
1984 Yokozawa T, Nakai T, Ishikawa N. (Trifluoromethyl)ketene silyl acetal as an equivalent to the trifluoropropionic ester enolate: preparation and aldol-type reactions with acetals Tetrahedron Letters. 25: 3987-3990. DOI: 10.1016/0040-4039(84)80047-7  0.387
1984 Mikami K, Azuma K, Nakai T. [2,3]-Wittig sigmatropic rearrangement of crotyl propargyl ether system. An emerging tool for control of acyclic stereochemistry Tetrahedron. 40: 2303-2308. DOI: 10.1016/0040-4020(84)80013-7  0.396
1984 Sayo N, Kitahara E, Nakai T. Highly Enantiospecific And Erythro-Selective (2,3)-Wittig Rearrangement Of Enantiomerically Enriched Allylic Benzyl Ethers. A New, Formal Chiral Synthesis Of L-Ephedrine Cheminform. 15. DOI: 10.1002/Chin.198431184  0.389
1984 Sayo N, Shirai F, Nakai T. 1,4-Chirality Transfer Via The (2,3)-Wittig Rearrangement Of The Chiral Allylic Propargyl Ether System. A New, Practical Entry To Chiral Propargylic Alcohols Cheminform. 15. DOI: 10.1002/Chin.198431159  0.331
1983 Nakai T, Mikami K, Sayo N. Stereochemical Control Through Sigmatropic Rearrangements Journal of Synthetic Organic Chemistry Japan. 41: 100-116. DOI: 10.5059/Yukigoseikyokaishi.41.100  0.388
1983 Mikami K, Kishi N, Nakai T. Intramolecular acylation of vinylic silanes. A novel, general approach for the synthesis of four- to six-membered carbocyclic systems and its regiochemical features Tetrahedron Letters. 24: 795-798. DOI: 10.1016/S0040-4039(00)81530-0  0.329
1983 Kōichi M, Fujimoto K, Nakai T. Enhancement of erythro-selectivity in the [2,3]-wittig rearrangement via meyers' azenolates. A facile entry to erythro-α-hydroxy-β-methyl carboxylic acid derivatives Tetrahedron Letters. 24: 513-516. DOI: 10.1016/S0040-4039(00)81451-3  0.392
1983 Mikami K, Nakai T. APPLICATIONS OF THE TANDEM (2,3)-WITTIG-OXY-COPE REARRANGEMENT TO SYNTHESES OF EXO-BREVICOMIN AND OXOCRINOL. THE SCOPE AND LIMITATION OF THE SIGMATROPIC SEQUENCES AS A SYNTHETIC METHOD FOR Δ,ε-UNSATURATED KETONES Cheminform. 14. DOI: 10.1002/Chin.198310153  0.34
1982 Mikami K, Kishi N, Nakai T. Sigmatropic rearrangements of 2-(trimethylsilyl)allyl alcohol derivatives: Facile and general entries to functionalized vinylsilanes. Chemistry Letters. 11: 1643-1646. DOI: 10.1246/Cl.1982.1643  0.308
1982 Mikami K, Nakai T. APPLICATIONS OF THE TANDEM [2,3]-WITTIG-OXY-COPE REARRANGEMENT TO SYNTHESES OF exo-BREVICOMIN AND OXOCRINOL. THE SCOPE AND LIMITATION OF THE SIGMATROPIC SEQUENCES AS A SYNTHETIC METHOD FOR δ,ε-UNSATURATED KETONES Chemistry Letters. 11: 1349-1352. DOI: 10.1246/Cl.1982.1349  0.32
1982 Sayo N, Kimura Y, Nakai T. Chirality transmission via tandem sigmatropic rearrangement: Regio- and stereochemical outcome in the tandem Wittig—oxy-Cope sequence of allyl cis-5-methyl-2-cyclohexenyl ether Tetrahedron Letters. 23: 3931-3934. DOI: 10.1016/S0040-4039(00)87746-1  0.317
1982 Mikami K, Kishi N, Nakai T. Sequential (2,3)Wittig And Claisen Rearrangement: A Facile Synthetic Method For (E,E)-4,7-Alkadienals And -Alkadienoic Acids. A New Formal Synthesis Of (.+-.)-Cerulenin Cheminform. 13. DOI: 10.1002/Chin.198221192  0.32
1981 Mikami K, Kishi N, Nakai T. Sequential [2,3]Wittig And Claisen Rearrangement: A Facile Synthetic Method For (E,E)-4,7-Alkadienals And -Alkadienoic Acids. A New Formal Synthesis Of (±)-Cerulenin Chemistry Letters. 10: 1721-1724. DOI: 10.1246/Cl.1981.1721  0.326
1981 Mimura T, Nakai T. A NEW APPROACH TO REGIOCONTROLLED ENONE TRANSPOSITIONS BASED ON THE FACILE CONVERSION OF α,β-ENONE TOSYLHYDRAZONES TO THE TRANSPOSED ALLYLIC SULFIDES Chemistry Letters. 10: 1579-1582. DOI: 10.1246/Cl.1981.1579  0.383
1981 Nakai T, Tanaka K, Ogasawara K, Ishikawa N. Synthetic Utility Of A Fluorine-Facilitated Claisen Rearrangement: A Novel Synthetic Method For 2,4-Alkadienoic Acids Using 2,2,2-Trifluoroethyl Phenyl Sulfoxide Chemistry Letters. 10: 1289-1292. DOI: 10.1246/Cl.1981.1289  0.365
1981 Mikami K, Taya S, Nakai T, Fujita Y. New sigmatropic sequences based on the [2,3] Wittig rearrangement of bis(allylic) ethers. Regiocontrolled joining reactions of two or three allylic moieties leading to unsaturated carbonyl compounds Journal of Organic Chemistry. 13: 5447-5449. DOI: 10.1021/Jo00339A051  0.396
1981 Nakai T, Setoi H, Kageyama Y. Stereocontrolled synthesis of conjugated dienamides via the ynamine-claisen rearrangement with (arylthio)ynamine Tetrahedron Letters. 22: 4097-4100. DOI: 10.1016/S0040-4039(01)82075-X  0.383
1981 Nakai T, Mikami K, Taya S, Kimura Y, Mimura T. The [2,3]Wittig rearrangement of 2-alkenyloxyacetic acids and its applications to the stereocontrolled synthesis of β, γ-unsaturated aldehydes and conjugated dienoic acids Tetrahedron Letters. 22: 69-72. DOI: 10.1016/0040-4039(81)80043-3  0.373
1981 Nakai T, Mikami K, Taya S, Kimura Y, Mimura T. APPLICATIONS OF (2,3)SIGMATROPIC REARRANGEMENTS IN ORGANIC SYNTHESIS. III. THE (2,3)WITTIG REARRANGEMENT OF 2-ALKENYLOXYACETIC ACIDS AND ITS APPLICATIONS TO THE STEREOCONTROLLED SYNTHESIS OF β,Γ-UNSATURATED ALDEHYDES AND CONJUGATED DI Cheminform. 12. DOI: 10.1002/Chin.198117176  0.397
1981 Hayashi S, Nakai T, Ishikawa N. Applications Of Organofluorine Reagents In Organic Synthesis. Part Viii. Defluorinative Coupling Reactions Of Gem-Difluoroolefins With Organolithium Reagents. Novel, Facile Methods For Chain Elongations Of Aldehydes Leading To Amides, Cheminform. 12. DOI: 10.1002/Chin.198104158  0.385
1980 Nakai T, Mikami K. Synthesis of Medium Ring Compounds via Sigmatropic Rearrangements Journal of Synthetic Organic Chemistry Japan. 38: 381-394. DOI: 10.5059/Yukigoseikyokaishi.38.381  0.339
1980 Hayashi S, Nakai T, Ishikawa N. DEFLUORINATIVE COUPLING REACTIONS OF gem-DIFLUOROOLEFINS WITH ORGANOLITHIUM REAGENTS. NOVEL, FACILE METHODS FOR CHAIN ELONGATIONS OF ALDEHYDES LEADING TO AMIDES, ACETYLENES, AND KETONES Chemistry Letters. 9: 935-938. DOI: 10.1246/Cl.1980.935  0.411
1980 Hayashi S, Nakai T, Ishikawa N. DEFLUORINATION REACTIONS OF gem-DIFLUORO- AND MONOFLUOROOLEFINS. NOVEL METHODS FOR ONE-CARBON HOMOLOGATIONS OF CARBONYL COMPOUNDS LEADING TO ALDEHYDES, CARBOXYLIC ACIDS, AND ESTERS Chemistry Letters. 9: 651-654. DOI: 10.1246/Cl.1980.651  0.399
1980 Mimura T, Nakai T. A Facile Method For Regioselective 1,2-Carbonyl Transposition Of Δ2-Cyclohexenone Systems Leading To The Positionally Isomeric Δ2-Cyclohexenones Chemistry Letters. 9: 1099-1102. DOI: 10.1246/Cl.1980.1099  0.32
1980 Hayashi S, Nakai T, Ishikawa N. Application Of Organofluorine Reagents In Organic Synthesis. Vii. Defluorination Reactions Of Gem-Difluoro- And Monofluoroolefins. Novel Methods For One-Carbon Homologations Of Carbonyl Compounds Leading To Aldehydes Carboxylic Acids, Cheminform. 11. DOI: 10.1002/Chin.198048096  0.387
1980 Tanaka K, Nakai T, Ishikawa N. PREPARATION AND SYNTHETIC UTILITY OF DIFLUOROKETENE THIOACETAL. A NOVEL SYNTHETIC ROUTE TO α-MONOFLUOROALKANOIC ACIDS. PART 5 ON NEW APPLICATIONS OF ORGANOFLUORINE REAGENTS IN ORGANIC SYNTHESIS Cheminform. 11. DOI: 10.1002/Chin.198005171  0.413
1979 Hayashi S, Nakai T, Ishikawa N, Burton DJ, Naae DG, Kesling HS. CONVENIENT PROCEDURES FOR CONVERSION OF CARBONYL COMPOUNDS TO gem-DIFLUOROOLEFINS AND THEIR SELECTIVE REDUCTIONS TO MONOFLUOROOLEFINS Chemistry Letters. 8: 983-986. DOI: 10.1246/Cl.1979.983  0.394
1979 Tanaka K, Nakai T, Ishikawa N. PREPARATION AND SYNTHETIC UTILITY OF DIFLUOROKETENE THIOACETAL. A NOVEL SYNTHETIC ROUTE TOα-MONOFLUOROALKANOIC ACIDS Chemistry Letters. 8: 175-178. DOI: 10.1246/Cl.1979.175  0.415
1979 Mimura T, Kimura Y, Nakai T. SYNTHETIC UTILITY OF ALLYLIC THIOLCARBAMATES. STEREOSELECTIVE SYNTHESIS OF SIMPLE NATURAL PRODUCTS INCLUDING OPTICALLY ACTIVE MANICONE AND β-SINENSAL Chemistry Letters. 8: 1361-1364. DOI: 10.1246/Cl.1979.1361  0.364
1979 Nakai T, Mimura T. A facile procedure for regioselective 1,2-carbonyl transposition. One-pot conversion of ketone tosylhydrazones to enol thioethers of transposed ketones Tetrahedron Letters. 20: 531-534. DOI: 10.1016/S0040-4039(01)85992-X  0.377
1979 Tanaka K, Nakai T, Ishikawa N. NEW APPLICATIONS OF ORGANOFLUORINE REAGENTS IN ORGANIC SYNTHESIS. PART IV. 2,2-DIFLUORO-1-TOLYLSULFONYLOXYVINYLLITHIUM: A NOVEL, EFFECTIVE REAGENT FOR THE PREPARATION OF α-KETO ACIDS FROM CARBONYL COMPOUNDS Cheminform. 10. DOI: 10.1002/Chin.197913202  0.41
1978 Nakai T, Mikami K. A New Synthetic Route To 1,1-Bis(Methylthio)-1,3-Butadienes Via The [2,3]Sigmatropic Rearrangement Of Dithiocarbenes Chemistry Letters. 7: 1243-1244. DOI: 10.1246/Cl.1978.1243  0.421
1978 Tanaka K, Shiraishi S, Nakai T, Ishikawa N. New applications of organofluorine reagents in organic synthesis. III. A convenient synthetic method for acetylenic ethers and thioethers Tetrahedron Letters. 19: 3103-3106. DOI: 10.1016/S0040-4039(01)94954-8  0.361
1978 Nakai T, Mimura T, Kurokawa T. General synthetic routes to α,β-unsaturated carboxylic esters and ketones via the [3,3]sigmatropic rearrangement of allylic thioncarbamates. Stereospecific syntheses of two ant mandibular gland secretions☆ Tetrahedron Letters. 19: 2895-2898. DOI: 10.1016/S0040-4039(01)94892-0  0.408
1978 Tanaka K, Nakai T, Ishikawa N. 2,2-difluoro-1-tosyloxyvinyllithium: a novel, effective reagent for the preparation of α-keto acids from carbonyl compounds☆ Tetrahedron Letters. 19: 4809-4810. DOI: 10.1016/S0040-4039(01)85738-5  0.372
1978 Wada E, Nakai T, Okawara M. Synthesis and polymerization of acrylates containing azulene structure Journal of Polymer Science Part A. 16: 2085-2087. DOI: 10.1002/Pol.1978.170160824  0.324
1978 Nakai T, Mimura T, Kurokawa T. General Synthetic Routes to α,β-Unsaturated Carboxylic Esters and Ketones via the(3,3)Sigmatropic Rearrangement of Allylic Thioncarbamates. Stereospecific Syntheses of Two Ant Mandibular Gland Secretions. Part 7 on Dithiocarbamates in Cheminform. 9. DOI: 10.1002/Chin.197845150  0.404
1978 Nakai T, Mimura T. Carbonyl Transpositions And Related Synthetic Reactions Cheminform. 9. DOI: 10.1002/Chin.197822348  0.342
1978 Tanaka K, Nakai T, Ishikawa N. Applications Of Organofluorine Reagents In Organic Synthesis. Part Ii. 2,2-Difluoro-1-Phenoxyvinyllithium- A New Reagent For The Preparation Of 2-Phenoxy-2-Alkenoic Acids From Carbonyl Compounds Cheminform. 9. DOI: 10.1002/Chin.197817163  0.359
1978 Wada E, Nakai T, Okawara M. A New Synthesis Of 2-(6-Carboxyhexyl)Cyclopent-2-En-1-One, A Prostanoid Synthon Cheminform. 9. DOI: 10.1002/Chin.197812155  0.376
1978 Nakai T, Tanaka K, Setoi H, Ishikawa N. A Convenient Preparation Of Arylthioynamines Cheminform. 9. DOI: 10.1002/Chin.197804160  0.324
1978 Nakai T, Hassan NM, Ishikawa N. Competitive Cyclization In The Reaction Of Hexafluoropropene With 2-Aminobenzamide Cheminform. 9. DOI: 10.1002/Chin.197803155  0.344
1977 Nakai T, Mimura T. Carbonyl Transpositions and Related Synthetic Reactions Journal of Synthetic Organic Chemistry Japan. 35: 964-978. DOI: 10.5059/Yukigoseikyokaishi.35.964  0.409
1977 Wada E, Nakai T, Okawara M. A New Synthesis Of 2-(6-Carboxyhexyl)Cyclopent-2-En-1-One, A Prostanoid Synthon Chemistry Letters. 6: 1121-1124. DOI: 10.1246/Cl.1977.1121  0.438
1977 Nakai T, Tanaka K, Setoi H, Ishikawa N. A Convenient Preparation of Arylthioynamines Bulletin of the Chemical Society of Japan. 50: 3069-3070. DOI: 10.1246/Bcsj.50.3069  0.356
1977 Nakai T, Hassan NM, Ishikawa N. Competitive Cyclization in the Reaction of Hexafluoropropene with 2-Aminobenzamide Bulletin of the Chemical Society of Japan. 50: 3014-3017. DOI: 10.1246/Bcsj.50.3014  0.354
1977 Nakai T, Mimura T, Ari-Izumi A. A new method for the bishomologation of carbonyl compounds to α,β-unsaturated aldehydes via the [3,3]sigmatropic rearrangement of allylic thionocarbamates Tetrahedron Letters. 18: 2425-2428. DOI: 10.1016/S0040-4039(01)83783-7  0.373
1977 Nakai T, Tanaka K, Ishikawa N. The reaction of 2,2,2-trifluoroethyl iodide with sodium phenolate. A novel competition between substitution and elimination reactions Journal of Fluorine Chemistry. 9: 89-93. DOI: 10.1016/S0022-1139(00)82560-9  0.34
1977 Nakai T, Mimura T, Ari-Izumi A. DITHIOCARBAMATES IN ORGANIC SYNTHESIS. PART VI. A NEW METHOD FOR THE BISHOMOLOGATION OF CARBONYL COMPOUNDS TO α,β-UNSATURATED ALDEHYDES VIA THE (3,3)SIGMATROPIC REARRANGEMENT OF ALLYLIC THIONOCARBAMATES Cheminform. 8. DOI: 10.1002/Chin.197744159  0.4
1977 Nakai T, Tanaka K, Ishikawa N. Reaction Of 2,2,2-Trifluoroethoxy- And 2,2,2-Trifluoroethylthiobenzene With Lithium Dialkylamides. The Formation Of Phenylthioynamines Cheminform. 8. DOI: 10.1002/Chin.197718195  0.332
1977 Nakai T, Tanaka K, Ishikawa N. Preparations Of Nmr (Proton And Fluorine-19) Studies Of Aryl 2,2,2-Trifluoroethyl Ethers And Sulfides, And N-(2,2,2-Trifluoroethyl)Anilines Cheminform. 8. DOI: 10.1002/Chin.197718176  0.339
1977 Wada E, Nakai T, Okawara M. A New Method For Cyclopentenone Annelation Via The Rearrangement Of Bicyclic Cyclopropyl Ketones. Syntheses Of Bicyclo(4.3.0)Non-6-En-8-One And Bicyclo(5.3.0)Dec-7-En-9-One Cheminform. 8. DOI: 10.1002/Chin.197711187  0.371
1976 Nakai T, Tanaka K, Ishikawa N. Reactions of 2,2,2-trifluoroethoxy- and 2,2,2-trifluoroethylthiobenzene with lithium dialkylamides. The formation of phenylthioynamines. Chemistry Letters. 5: 1263-1266. DOI: 10.1246/Cl.1976.1263  0.358
1976 Wada E, Nakai T, Okawara M. A New Method For Cyclopentenone Annelation Via The Rearrangement Of Bicyclic Cyclopropyl Ketones. Syntheses Of Bicyclo[4.3.0] Non-6-En-8-One And Bicyclo[5.3.0]Dec-7-En-9-One Chemistry Letters. 5: 1025-1028. DOI: 10.1246/Cl.1976.1025  0.425
1976 Nakai T, Hiratani K, Okawara M. Tri(hetero)substituted Carbonium Ions. XI. A Novel Synthetic Route to 2-Dialkylamino-4-alkyl-1,3-dithiolium Salts Bulletin of the Chemical Society of Japan. 49: 827-828. DOI: 10.1246/Bcsj.49.827  0.434
1976 Hiratani K, Nakai T, Okawara M. Tri(hetero)substituted Carbonium Ions. XII. A Novel Ring Expansion of 1,3-Dithiolanyiium Salts into 1,3-Dithia-4-cyclohexene (1,3-Dithiine) System Bulletin of the Chemical Society of Japan. 49: 2339-2340. DOI: 10.1246/Bcsj.49.2339  0.379
1976 Hiratani K, Nakai T, Okawara M. Tri(Hetero)Substituted Carbonium Ions. Xii. A Novel Ring Expansion Of 1,3-Dithiolanylium Salts Into 1,3-Dithia-4-Cyclohexene (1,3-Dithiine) Systems Cheminform. 7. DOI: 10.1002/Chin.197648236  0.312
1976 Nakai T, Shiono H, Okawara M. Dithiocarbamates In Organic Synthesis. Iv. Lithiated S-(2-Methoxyallyl) N,N-Dimethyldithiocarbamate, A New, Versatile Reagent For The Introduction Of The Acetonyl Functional Group Into Organic Substrates Cheminform. 7. DOI: 10.1002/Chin.197606131  0.306
1975 Nakai T, Shiono H, Okawara M. Selective carbon-carbon bond forming reactions via S-allyl dithiocarbamates. Reductive desulfurization of allylic dithiocarbamates. Chemistry Letters. 4: 249-252. DOI: 10.1246/Cl.1975.249  0.371
1975 Nakai T, Wada E, Okawara M. A new synthetic route to 1,4-dicarbonyl compounds based on the utility of the rearrangement of protonated cyclopropyl ketones. A simple synthesis of dihydrojasmone Tetrahedron Letters. 16: 1531-1534. DOI: 10.1016/S0040-4039(00)72189-7  0.395
1975 Nakai T, Shiono H, Okawara M. Dithiocarbamates In Organic Synthesis Part 3, Selective Carbon‐Carbon Bond Forming Reactions Via S‐Allyl Dithiocarbamates. Reductive Desulfurization Of Allylic Dithiocarbamates Cheminform. 6. DOI: 10.1002/Chin.197545197  0.375
1974 Hiratani K, Nakai T, Okawara M. REGIOSPECIFIC NEIGHBORING-GROUP PARTICIPATION BY DITHIOCARBAMATE FUNCTION DURING BROMINATION OF γ-SUBSTITUTED S -ALLYL N , N -DIMETHYLDITHIOCARBAMATES Chemistry Letters. 3: 1041-1044. DOI: 10.1246/Cl.1974.1041  0.334
1974 Nakai T, Hiratani K, Okawara M. Tri(hetero)substituted Carbonium Ions. VII. Effect of the Ring System on the Ambident Reactivity of Cyclic Dithiocarbamidium Ions Bulletin of the Chemical Society of Japan. 47: 398-403. DOI: 10.1246/Bcsj.47.398  0.317
1974 Nakai T, Shiono H, Okawara M. Potential synthetic utility of [3,3]-sigmatropic rearrangement of s-allyl dithiocarbamates. New routes to α,β-unsaturated aldehydes Tetrahedron Letters. 15: 3625-3628. DOI: 10.1016/S0040-4039(01)91984-7  0.382
1974 Hiratani K, Nakai T, Okawara M. Trihetero Substituted Carbonium Ions Part 8, The Hydride Reduction Of Cyclic And Open-Chain Dithiocarbamidium Salts Cheminform. 5. DOI: 10.1002/Chin.197410216  0.3
1973 Hiratani K, Nakai T, Okawara M. Tri(hetero)substituted Carbonium Ions. VIII. The Hydride Reduction of Cyclic and Open-chain Dithiocarbamidium Salts Bulletin of the Chemical Society of Japan. 46: 3872-3876. DOI: 10.1246/Bcsj.46.3872  0.317
1971 Ueno Y, Nakai T, Okawara M. Iminodithiocarbonates. III. Reactions with Some Electrophiles and the Structural Effect on Nucleophilic Reactivities and Basicities Bulletin of the Chemical Society of Japan. 44: 1933-1938. DOI: 10.1246/Bcsj.44.1933  0.387
1970 Nakai T, Okawara M. Tri(hetero) substituted Carbonium Ions. VI. An Anomalous Reaction of 2-Methylthio-1,3-dithiolanylium Ion with N,N-Dimethyldithiocarbamate Anion Bulletin of the Chemical Society of Japan. 43: 3882-3886. DOI: 10.1246/Bcsj.43.3882  0.331
1970 Nakai T, Okawara M. Tri(hetero)substituted Carbonium Ions. IV. Reactions of N , N ′-Dimethyl- S , S ′-dimethyldithiocarbamidium Ion with Various Nucleophiles Bulletin of the Chemical Society of Japan. 43: 3528-3534. DOI: 10.1246/Bcsj.43.3528  0.372
1970 Nakai T, Okawara M. Tri(hetero)substituted Carbonium Ions. II. 2-Dialkylamino-1,3-dithiolanylium Ions. Reactions with Nucleophiles and Ambident Behaviors Bulletin of the Chemical Society of Japan. 43: 1864-1869. DOI: 10.1246/Bcsj.43.1864  0.346
1970 Ueno Y, Nakai T, Okawara M. Reactions of Various Thione-compounds with Epoxides. A New Method for the Transformation of the C=S Bond into the C=O Bulletin of the Chemical Society of Japan. 43: 168-172. DOI: 10.1246/Bcsj.43.168  0.365
1970 Ueno Y, Nakai T, Okawara M. 2-Substituted Imino-1,3-dithiolanes. Their Thermal Ring-isomerizations and Reactions with Epoxides Bulletin of the Chemical Society of Japan. 43: 162-167. DOI: 10.1246/Bcsj.43.162  0.392
1970 Nakai T, Ueno Y, Okawara M. Tri(hetero)substituted Carbonium Ions. I. Neighboring-Group Participation of the N,N-Dimethyldithiocarbamate Function Involving the Intermediacy of 2-Dimethylamino-1,3-dithiolanylium Ion Bulletin of the Chemical Society of Japan. 43: 156-162. DOI: 10.1246/Bcsj.43.156  0.308
1970 Nakai T, Okawara M. Formation of α-dimethylamino-α-methylthio-carbene. Carbene-induced isomerization of dimethyl maleate Journal of the Chemical Society D: Chemical Communications. 907-908. DOI: 10.1039/C29700000907  0.364
1969 Nakai T, Kawaoka H, Okawara M. Syntheses and Reactions of Functional Polymers. XL. Enhanced Reactivity of Poly(vinyl chloride) by Neighboring-Group Participation of the N,N-Disubstituted Dithiocarbamate Function Bulletin of the Chemical Society of Japan. 42: 508-512. DOI: 10.1246/Bcsj.42.508  0.319
1968 Nakai T, Okawara M. Synthesis and Reactions of Functional Polymers. XXXIV. Low Polymerization of Ethylene Oxide with Sodium N , N -Dimethyldithiocarbamate in Dipolar Aprotic Solvents Bulletin of the Chemical Society of Japan. 41: 707-712. DOI: 10.1246/Bcsj.41.707  0.358
1967 Nakai T, Okawara M. A new ambident cation. Reactions of 2-dialkylamino-1,3-dithiolanylium salts with various nucleophiles☆ Tetrahedron Letters. 8: 3835-3838. DOI: 10.1016/S0040-4039(00)71634-0  0.351
1966 Okawara M, Ori M, Nakai T, Imoto E. Synthesis and Reaction of Polyethylenimine Containing Dithiocarbamoyl Group Nippon Kagaku Kaishi. 69: 766-771. DOI: 10.1246/Nikkashi1898.69.4_766  0.328
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