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Claude F. Bernasconi - Publications

Affiliations: 
Chemistry & Biochemistry University of California, Santa Cruz, Santa Cruz, CA, United States 
Area:
Physical and Mechanistic Organic Chemistry and Organometallic Chemistry, Chemical Reactivity, Kinetics, Ab Initio Calculations
Website:
http://www.chemistry.ucsc.edu/faculty/singleton.php?&singleton=true&cruz_id=cbernasc

199 high-probability publications. We are testing a new system for linking publications to authors. You can help! If you notice any inaccuracies, please sign in and mark papers as correct or incorrect matches. If you identify any major omissions or other inaccuracies in the publication list, please let us know.

Year Citation  Score
2013 Bernasconi CF. The role of solvent reorganization in proton transfer and nucleophilic addition reactions Pure and Applied Chemistry. 54: 2335-2348. DOI: 10.1351/Pac198254122335  1
2011 Bernasconi CF. Happy birthday to Joe Bunnett Accounts of Chemical Research. 44: 1253-1254. DOI: 10.1021/Ar2002914  1
2010 Bernasconi CF, Wenzel PJ. Effect of transition state aromaticity and antiaromaticity on intrinsic barriers of proton transfers in aromatic and antiaromatic heterocyclic systems; An ab initio study Journal of Organic Chemistry. 75: 8422-8434. DOI: 10.1021/jo101719z  1
2009 Bernasconi CF, Rappoport Z. Recent advances in our mechanistic understanding of S(N)V reactions. Accounts of Chemical Research. 42: 993-1003. PMID 19522460 DOI: 10.1021/Ar900048Q  0.56
2009 Bernasconi CF, Yamataka H, Yoshimura N, Sato M. Deprotonation of 3(2H)-furanone and 3(2H)-thiophenone by carbanions in the gas phase: Disproportionately high aromaticity of the transition state: An ab initio study Journal of Organic Chemistry. 74: 188-196. PMID 19053588 DOI: 10.1021/Jo8018076  1
2009 Bernasconi CF. Proton transfers in aromatic systems: How aromatic is the transition state? Pure and Applied Chemistry. 81: 649-665. DOI: 10.1351/Pac-Con-08-08-27  1
2009 Bernasconi CF, Rappoport Z. Recent advances in our mechanistic understanding of S NV reactions Accounts of Chemical Research. 42: 993-1003. DOI: 10.1021/ar900048q  1
2008 Karni M, Bernasconi CF, Rappoport Z. Role of negative hyperconjugation and anomeric effects in the stabilization of the intermediate in SNV reactions. The Journal of Organic Chemistry. 73: 2980-94. PMID 18376875 DOI: 10.1021/Jo7017476  0.56
2008 Karni M, Bernasconi CF, Rappoport Z. Role of negative hyperconjugation and anomeric effects in the stabilization of the intermediate in SNV reactions Journal of Organic Chemistry. 73: 2980-2994. DOI: 10.1021/jo7017476  1
2008 Bernasconi CF, Wenzel PJ, Ragains ML. Proton transfers in aromatic and antiaromatic systems. How aromatic or antiaromatic is the transition state? An ab initio study Journal of the American Chemical Society. 130: 4934-4944. DOI: 10.1021/ja078185y  1
2007 Bernasconi CF, Pérez-Lorenzo M, Codding SJ. Reactions of [aryloxy(phenyl)carbene]pentacarbonylchromium(0) complexes with thiolate ions. Decreasing reactivity with increasing basicity of the nucleophile Journal of Organic Chemistry. 72: 9456-9463. PMID 18001091 DOI: 10.1021/Jo701422Z  1
2007 Bernasconi CF, Pérez-Lorenzo M, Brown SD. Kinetics of the deprotonation of methylnitroacetate by amines: unusually high intrinsic rate constants for a nitroalkane. The Journal of Organic Chemistry. 72: 4416-23. PMID 17500569 DOI: 10.1021/Jo070372R  1
2007 Bernasconi CF, Brown SD, Eventova I, Rappoport Z. Spectroscopic and kinetic evidence for an accumulating intermediate in an SNV reaction with amine nucleophiles. Reaction of methyl beta-methylthio-alpha-nitrocinnamate with piperidine and morpholine. The Journal of Organic Chemistry. 72: 3302-10. PMID 17407355 DOI: 10.1021/Jo062602S  1
2007 Bernasconi CF, Michoff MEZ, De Rossi RH, Granados AM. Kinetics of the reactions of [p-nitrophenoxy(phenyl)carbene] pentacarbonylchromium(0) with aryloxide ions, hydroxide ion, and water in aqueous acetonitrile. Concerted or stepwise? Journal of Organic Chemistry. 72: 1285-1293. DOI: 10.1021/jo062138r  1
2007 Bernasconi CF, Pérez-Lorenzo M. Does aromaticity in a reaction product increase or decrease the intrinsic barrier? Kinetics of the reversible deprotonation of benzofuran-3(2H)-one and benzothiophene-3(2H)-one Journal of the American Chemical Society. 129: 2704-2712. DOI: 10.1021/ja067118l  1
2006 Bernasconi CF, Zheng H. Kinetics of proton transfer from benzo[b]-2,3-dihydrofuran-2-one and benzo[b]-2,3-dihydrothiophene-2-one. Effect of anion aromaticity on intrinsic barriers. The Journal of Organic Chemistry. 71: 8203-11. PMID 17025313 DOI: 10.1021/Jo0615899  1
2006 Bernasconi CF, Brown SD, Ali M, Rappoport Z, Yamataka H, Salim H. Hydrolysis of α-alkyl-α-(methylthio)methylene Meldrum's acids. A kinetic and computational investigation of steric effects Journal of Organic Chemistry. 71: 4795-4802. PMID 16776504 DOI: 10.1021/Jo060254O  1
2006 Bernasconi CF, Bhattacharya S, Wenzel PJ, Olmstead MM. Kinetic and thermodynamic acidity of [Cp(NO)(PPh 3)Re(2,5- dimethyl-3-thienyl) carbene] +. Transition state imbalance and intrinsic barriers Organometallics. 25: 4322-4330. DOI: 10.1021/Om0604369  1
2006 Bernasconi CF, Zheng H. Kinetics of proton transfer from benzo[b]-2,3-dihydrofuran-2-one and benzo[b]-2,3-dihydrothiophene-2-one. Effect of anion aromaticity on intrinsic barriers Journal of Organic Chemistry. 71: 8203-8211. DOI: 10.1021/jo0615899  1
2006 Ali M, Bernasconi CF, Biswas S. Transition metal carbene chemistry 6: Kinetic studies of the reactions of hydroxide ion with (CO)5Mo{double bond, long}C(XCH2CH2OH)(C6H5) (X = O and S) and (CO)5W{double bond, long}C(OCH2CH2OH)(C6H4-Z) Journal of Organometallic Chemistry. 691: 3477-3483. DOI: 10.1016/J.Jorganchem.2006.04.032  1
2006 Ali M, Biswas S, Rappoport Z, Bernasconi CF. Kinetics and mechanism of reactions of substituted (methylthio)benzylidene Meldrum's acids with primary amines in aqueous DMSO Journal of Physical Organic Chemistry. 19: 647-653. DOI: 10.1002/Poc.1109  1
2005 Bernasconi CF, Fairchild DE, Montañez RL, Aleshi P, Zheng H, Lorance E. Kinetics of proton transfer from cationic carbon acids in water and aqueous DMSO. Effect of activating groups and solvent on intrinsic rate constants. The Journal of Organic Chemistry. 70: 7721-30. PMID 16149805 DOI: 10.1021/Jo051166R  1
2005 Bernasconi CF, Fairchild DE, Montañez RL, Aleshi P, Zheng H, Lorance E. Kinetics of proton transfer from cationic carbon acids in water and aqueous DMSO. Effect of activating groups and solvent on intrinsic rate constants Journal of Organic Chemistry. 70: 7721-7730. DOI: 10.1021/jo051166r  1
2005 Bernasconi CF, Ragains ML. Factors that affect the kinetic and thermodynamic acidities of Fischer carbene complexes: New insights from the study of the cationic (methoxymethylcarbene)dicarbonylpentamethylcyclopentadienyl iron ([Cp*(CO)2FeC(OMe)Me]+) in aqueous acetonitrile Journal of Organometallic Chemistry. 690: 5616-5624. DOI: 10.1016/J.Jorganchem.2005.07.011  1
2004 Bernasconi CF, Ali M, Nguyen K, Ruddat V, Rappoport Z. Reactions of substituted (methylthio)benzylidene Meldrum's acids with secondary alicyclic amines in aqueous DMSO. Evidence for rate-limiting proton transfer. The Journal of Organic Chemistry. 69: 9248-54. PMID 15609963 DOI: 10.1021/Jo040244S  0.56
2004 Ruddat VC, Mogul R, Chorny I, Chen C, Perrin N, Whitman S, Kenyon V, Jacobson MP, Bernasconi CF, Holman TR. Tryptophan 500 and arginine 707 define product and substrate active site binding in soybean lipoxygenase-1 Biochemistry. 43: 13063-13071. PMID 15476400 DOI: 10.1021/Bi0489098  1
2004 Bernasconi CF, Ali M. Physical organic chemistry of transition metal complexes. 31.† nucleophilic attachment of the malononitrile anion to fischer carbene complexes Organometallics. 23: 6134-6139. DOI: 10.1021/Om0401051  1
2004 Bernasconi CF, Bhattacharya S. Physical Organic Chemistry of Transition Metal Carbene Complexes. 29. Kinetics of Reactions of [Ethoxy(phenyl)carbene]pentacarbonylchromium(0) and [Ethoxy(phenyl)(Cr(CO) 3)carbene]pentacarbonylchromium(0) with Water, OH -, and Amines. Mechanistic Changes Induced by the Cr(CO) 3 Group Organometallics. 23: 1722-1729. DOI: 10.1021/Om030696F  1
2004 Bernasconi CF, Ali M, Nguyen K, Ruddat V, Rappoport Z. Reactions of substituted (methylthio)benzylidene Meldrum's acids with secondary alicyclic amines in aqueous DMSO. Evidence for rate-limiting proton transfer Journal of Organic Chemistry. 69: 9248-9254. DOI: 10.1021/jo040244s  1
2004 Bernasconi CF, Ruddat V, Wenzel PJ, Fischer H. Kinetic and thermodynamic acidities of pentacarbonyl(cyclobutenylidene) chromium complexes. Effect of antiaromaticity in the conjugate anion. An experimental and computational study Journal of Organic Chemistry. 69: 5232-5239. DOI: 10.1021/jo040168t  1
2004 Bernasconi CF. The principle of nonperfect synchronization: How does it apply to aromatic systems? Journal of Physical Organic Chemistry. 17: 951-956. DOI: 10.1002/Poc.810  1
2003 Ruddat VC, Whitman S, Holman TR, Bernasconi CF. Stopped-flow kinetic investigations of the activation of soybean lipoxygenase-1 and the influence of inhibitors on the allosteric site Biochemistry. 42: 4172-4178. PMID 12680771 DOI: 10.1021/Bi020698O  1
2003 Bernasconi CF, Ali M, Gunter JC. Kinetic and thermodynamic acidities of substituted 1-benzyl-1-methoxy-2-nitroethylenes. Strong reduction of the transition state imbalance compared to other nitroalkanes Journal of the American Chemical Society. 125: 151-157. PMID 12515516 DOI: 10.1021/Ja0211398  1
2003 Bernasconi CF, Bhattacharya S. Physical organic chemistry of transition metal carbene complexes. 27. Substituent effects on the nucleophilic substitution of [aryl(thiomethyl)carbene]pentacarbonylchromium(0) complexes by amines in aqueous acetonitrile Organometallics. 22: 1310-1313. DOI: 10.1021/om020955l  1
2003 Bernasconi CF, Bhattacharya S. Physical organic chemistry of transition metal carbene complexes. 26. Kinetics and mechanism of the reactions of [phenyl(thiomethyl)carbene]pentacarbonylchromium(0) with amines in aqueous acetonitrile Organometallics. 22: 426-433. DOI: 10.1021/Om020748L  1
2003 Bernasconi CF, Wenzel PJ. Proton transfers from carbon acids activated by π-acceptors. Changes in intrinsic barriers and transition state imbalances induced by a cyano group. An ab initio study Journal of Organic Chemistry. 68: 6870-6879. DOI: 10.1021/jo030117g  1
2003 Bernasconi CF, Ragains ML, Bhattacharya S. Reactions that generate aromatic molecules: Is aromatic stabilization less or more advanced than bond changes at the transition state? Kinetic and thermodynamic acidities of rhenium carbene complexes Journal of the American Chemical Society. 125: 12328-12336. DOI: 10.1021/ja030229p  1
2002 Bernasconi CF, Ruddat V. Physical organic chemistry of transition metal carbene complexes. 25. Kinetic and thermodynamic acidities of substituted (methylthiophenylcarbene)pentacarbonyl tungsten(0) and (benzoxymethylcarbene)pentacarbonyl tungsten(0) in aqueous acetonitrile. Evidence for transition state imbalances Journal of the American Chemical Society. 124: 14968-14976. PMID 12475339 DOI: 10.1021/Ja020665W  1
2002 Bernasconi CF, Sun W. Physical organic chemistry of transition metal carbene complexes. 24. Thermodynamic and kinetic acidities of phenyl-substituted (benzylmethoxycarbene)pentacarbonylchromium(0) complexes. Is there a transition-state imbalance? Journal of the American Chemical Society. 124: 2299-2304. PMID 11878984 DOI: 10.1021/Ja012000K  1
2002 Bernasconi CF. The Physical Organic Chemistry of Fischer Carbene Complexes Advances in Physical Organic Chemistry. 37: 137-237. DOI: 10.1016/S0065-3160(02)37003-5  1
2001 Bernasconi CF, Ragains ML. Physical organic chemistry of transition metal carbene complexes. 23. Kinetic and thermodynamic acidities of cationic benzothienyl- and selenylcarbene complexes of rhenium in aqueous acetonitrile Journal of the American Chemical Society. 123: 11890-11898. PMID 11724595 DOI: 10.1021/Ja011568Q  1
2001 Bernasconi CF, Wenzel PJ. Carbon-to-carbon identity proton transfer from allene, ketene, ketenimine, and thioketene to their respective conjugate anions in the gas phase. An ab initio study Journal of the American Chemical Society. 123: 7146-7153. PMID 11459495 DOI: 10.1021/ja010368b  1
2001 Bernasconi CF, Wenzel PJ. Ab initio study of the carbon-to-carbon identity proton transfer from ketene to its anion in the gas phase Journal of the American Chemical Society. 123: 2430-2431. PMID 11456895 DOI: 10.1021/Ja003858X  1
2001 Bernasconi CF, Ketner RJ, Ragains ML, Chen X, Rappoport Z. Unraveling structure-reactivity relationships in SNV reactions: Kinetics of the reactions of methoxybenzylidenemalononitrile, 2-(methylthiobenzylidene)- 1,3-indandione, 2-(benzylthiobenzylidene)-1,3-indandione, and methyl β-methylthio-α-nitrocinnamate with OH- and thiolate ions in aqueous DMSO Journal of the American Chemical Society. 123: 2155-2164. PMID 11456860 DOI: 10.1021/Ja003536T  1
2001 Bernasconi CF, Wenzel PJ. Carbon-to-carbon identity proton transfers from propyne, acetimide, thioacetaldehyde, and nitrosomethane to their respective conjugate anions in the gas phase. An ab initio study Journal of Organic Chemistry. 66: 968-979. PMID 11430120 DOI: 10.1021/jo001543u  1
2001 Bernasconi CF, Ketner RJ, Chen X, Rappoport Z. Reactions of substituted benzylidene Meldrum's acids and methylthiobenzylidene Meldrum's acids with OH-, CF3CH 2O- and HOCH2CH2S- in 50% DMSO-50% water. π-Donor effects, soft acid-base interactions and transition state imbalances Arkivoc. 2001: 161-178. DOI: 10.3998/Ark.5550190.0002.C16  1
2001 Bernasconi CF, Ali M. Physical organic chemistry of transition metal carbene complexes. 22. Substituent effects on the reversible cyclization of fischer carbene complexes (CO)5W=C(SCH2CH2OH)C6H4Z in aqueous acetonitrile Organometallics. 20: 3383-3389. DOI: 10.1021/Om010364F  1
2000 Bernasconi CF, García-Río L. Physical organic chemistry of transition metal carbene complexes. 19. Kinetics of reversible alkoxide ion addition to substituted (methoxyphenylcarbene)pentacarbonylchromium(0) and (methoxyphenylcarbene)pentacarbonyltungsten(0) in methanol and aqueous acetonitrile Journal of the American Chemical Society. 122: 3821-3829. DOI: 10.1021/ja994174w  1
2000 Bernasconi CF, Ali M, Lu F. Physical organic chemistry of transition metal carbene complexes. 18. Kinetics of reversible cyclization of the Fischer carbene complexes (CO)5M=C(SCH2CH2OH)Ph and (CO)5M=C(OCH2CH2OH)Ph (M = Cr, W) in aqueous acetonitrile Journal of the American Chemical Society. 122: 1352-1359. DOI: 10.1021/Ja993418+  1
2000 Bernasconi CF, Perez GS. Physical organic chemistry of transition metal carbene complexes. 21.1 Kinetics and mechanism of hydrolysis of (CO)5m=C(SR)AR (M = CR and W; R = CH3 and CH3CH2CH2; AR = C6H5 and 3-CIC6H4) in Aqueous Acetonitrile. Important differences relative to complexes with alkoxy leaving groups Journal of the American Chemical Society. 122: 12441-12446. DOI: 10.1021/ja002371l  1
2000 Bernasconi CF, Whitesell C, Johnson RA. Physical organic chemistry of transition metal carbene complexes. Part 20: Kinetics and mechanism of reactions of (CO)5M=C(OMe)C6H4X (M=Cr and W) with primary aliphatic amines in aqueous acetonitrile. Substituent effects Tetrahedron. 56: 4917-4924. DOI: 10.1016/S0040-4020(00)00206-4  1
1999 Bernasconi CF, Ketner RJ, Brown SD, Chen X, Rappoport Z. Acid-Catalyzed Breakdown of Alkoxide and Thiolate Ion Adducts of Benzylidene Meldrum's Acid, Methoxybenzylidene Meldrum's Acid and Thiomethoxybenzylidene Meldrum's Acid. The Journal of Organic Chemistry. 64: 8829-8839. PMID 11674786 DOI: 10.1021/Jo991041K  0.56
1999 Bernasconi CF, Leyes AE, Rappoport Z. Kinetics of the Reaction of beta-Methoxy-alpha-nitrostilbene with Cyanamide in 50 DMSO-50 Water. Failure to Detect the S(N)V Intermediate. The Journal of Organic Chemistry. 64: 2897-2902. PMID 11674363 DOI: 10.1021/Jo990044U  0.56
1999 Bernasconi CF, Ketner RJ, Chen X, Rappoport Z. Detection and kinetic characterization of S(N)V intermediates. Reactions of thiomethoxybenzylidene Meldrum's acid with thiolate ions, alkoxide ions, OH-, and water in aqueous DMSO Canadian Journal of Chemistry. 77: 584-594. DOI: 10.1139/V99-009  1
1999 Bernasconi CF, Ketner RJ, Brown SD, Chen X, Rappoport Z. Acid-catalyzed breakdown of alkoxide and thiolate ion adducts of benzylidene Meldrum's acid, methoxybenzylidene Meldrum's acid and thiomethoxybenzylidene Meldrum's acid Journal of Organic Chemistry. 64: 8829-8839. DOI: 10.1021/jo991041k  1
1999 Bernasconi CF, Leyes AE, Rappoport Z. Kinetics of the reaction of β-methoxy-α-nitrostilbene with cyanamide in 50% DMSO-50% water. Failure to detect the S(N)V intermediate Journal of Organic Chemistry. 64: 2897-2902. DOI: 10.1021/jo990044u  1
1999 Bernasconi CF, Kittredge IW. Carbanion stabilization by adjacent sulfur: Polarizability, resonance, or negative hyperconjugation? Experimental distinction based on intrinsic rate constants of proton transfer from (phenylthio)nitromethane and I-nitro-2-phenylethane Chemtracts. 12: 492-493. DOI: 10.1021/Jo9719463  1
1999 Bernasconi CF, Ali M. Physical organic chemistry of transition metal carbene complexes. 17. Kinetics of the reactions of (arylthioalkoxycarbene)pentacarbonyl complexes of chromium(0) and tungsten(0) with thiolate ions in aqueous acetonitrile: pK(a) values of the metal-protonated tetrahedral adducts formed between carbene complexes and thiolate ion Journal of the American Chemical Society. 121: 11384-11394. DOI: 10.1021/ja992741+  1
1999 Bernasconi CF, Kittredge KW, Flores FX. Physical organic chemistry of transition metal carbene complexes. 16. Reactions of (CO)5M=C(OR)Ph (M = Cr or W; R = Me or Et) with thiolate ions in aqueous acetonitrile. Complete kinetic dissection of the two-step mechanism Journal of the American Chemical Society. 121: 6630-6639. DOI: 10.1021/Ja9908265  1
1999 Bernasconi CF, Ali M. Physical organic chemistry of transition metal carbene complexes. 15. Kinetic and thermodynamic acidities of (methylthiomethoxycarbene)pentacarbonyl complexes of chromium and tungsten in aqueous acetonitrile Journal of the American Chemical Society. 121: 3039-3045. DOI: 10.1021/Ja984274M  1
1999 Bernasconi CF, Moreira JA, Huang LL, Kittredge KW. Intrinsic rate constants for proton transfer from a monoketone to amine bases and electrostatic effects on the intrinsic rate constants for the deprotonation of cationic ketones by OH- Journal of the American Chemical Society. 121: 1674-1680. DOI: 10.1021/Ja983304I  1
1998 Bernasconi CF, Leyes AE, García-Río L. Physical organic chemistry of transition metal carbene complexes. 13.1 kinetics of proton transfer from (5-methyl-2-oxacyclopentylidene)pentacarbonylchromium(0) and hydrolysis of its conjugate anion in aqueous acetonitrile Organometallics. 17: 4940-4945. DOI: 10.1021/Om980444S  1
1998 Bernasconi CF, Flores FX, Kittredge KW. Physical organic chemistry of transition metal carbene complexes. 12. Spectroscopic detection and kinetic characterization of the intermediate in the nucleophilic substitution reaction of (CO)5Cr=C(OCH3)Ph with thiolate ions in aqueous acetonitrile [6] Journal of the American Chemical Society. 120: 7983-7984. DOI: 10.1021/Ja9812655  1
1998 Kanavarioti A, Bernasconi CF, Baird EE. Effects of monomer and template concentration on the kinetics of nonenzymatic template-directed oligoguanylate synthesis Journal of the American Chemical Society. 120: 8575-8581. DOI: 10.1021/ja9807237  1
1998 Bernasconi CF, Leyes AE, Ragains ML, Shi Y, Wang H, Wulff WD. Physical organic chemistry of transition metal carbene complexes. 14. Thermodynamic acidity measurements of Fischer carbene complexes in acetonitrile Journal of the American Chemical Society. 120: 8632-8639. DOI: 10.1021/Ja980608W  1
1998 Bernasconi CF, Ketner RJ, Chen X, Rappoport Z. Kinetics of the reactions of methoxybenzylidene Meldrum's acid with thiolate ions, alkoxide ions, OH-, and water in aqueous DMSO. Detection and kinetic characterization of the S(N)V intermediate Journal of the American Chemical Society. 120: 7461-7468. DOI: 10.1021/Ja9743102  1
1998 Bernasconi CF, Ketner RJ. Kinetics of the Reactions of Benzylidene Meldrum's Acid with Thiolate and Alkoxide Ions in Aqueous Dimethyl Sulfoxide Journal of Organic Chemistry. 63: 6266-6272.  1
1998 Bernasconi CF, Kittredge KW. Carbanion Stabilization by Adjacent Sulfur: Polarizability, Resonance, or Negative Hyperconjugation? Experimental Distinction Based on Intrinsic Rate Constants of Proton Transfer from (Phenylthio)nitromethane and 1-Nitro-2-phenylethane Journal of Organic Chemistry. 63: 1944-1953.  1
1997 Bernasconi CF, Montañez RL. Kinetics of Proton Transfer from Benzoylnitromethane and 1,2-Diphenyl-2-nitroethanone to Various Bases. Resonance, Inductive, Solvation, Steric, and Transition State Hydrogen-Bonding Effects on Intrinsic Rate Constants. The Journal of Organic Chemistry. 62: 8162-8170. PMID 11671926 DOI: 10.1021/Jo971259B  0.6
1997 Bernasconi CF, Leyes AE. Physical organic chemistry of transition metal carbene complexes. Part II.1 Kinetics and mechanism of the hydrolysis of (2-oxacyclopentylidene)pentacarbonylchromium(0) in aqueous acetonitrile Journal of the Chemical Society. Perkin Transactions 2. 1641-1647. DOI: 10.1039/A702286G  1
1997 Bernasconi CF, Sun W. Physical organic chemistry of transition metal carbene complexes. 8.1 kinetic and thermodynamic acidities of alkoxyalkylcarbene pentacarbonyl complexes of Cr, Mo, and W in aqueous acetonitrile. Dependence on metal, alkyl group, and alkoxy group Organometallics. 16: 1926-1932. DOI: 10.1021/Om960936+  1
1997 Bernasconi CF, Sun W, Garcia-Río L, Yan K, Kittredge K. Physical organic chemistry of transition metal carbene complexes. 10. Opposing effects of α-alkyl groups on the thermodynamic and kinetic acidities of (CO)5Cr = C(OMe)CHR'R''-type fischer carbene complexes in aqueous acetonitrile. Analogy to the nitroalkane anomaly Journal of the American Chemical Society. 119: 5583-5590. DOI: 10.1021/Ja970193Z  1
1997 Bernasconi CF, Leyes AE. Physical organic chemistry of transition metal carbene complexes. 9. Thermodynamic and kinetic acidity of (2- oxacyclopentylidene)pentacarbonylchromium(0) in aqueous acetonitrile Journal of the American Chemical Society. 119: 5169-5175. DOI: 10.1021/Ja964069B  1
1997 Bernasconi CF, Flores FX, Kittredge KW. Physical organic chemistry of transition metal carbene complexes. 7. Kinetics of hydrolysis of (CO)5M = C(OR)Ph (M = Cr, W; R = Me, Et) and (CO)5Cr = (OMe)CH = CHPh in aqueous acetonitrile Journal of the American Chemical Society. 119: 2103-2110. DOI: 10.1021/Ja963617I  1
1997 Bernasconi CF, Wenzel PJ, Keeffe JR, Gronert S. Intrinsic barriers and transition state structures in the gas phase carbon-to-carbon identity proton transfers from nitromethane to nitromethide anion and from protonated nitromethane to aci-nitromethane. An ab Initio study Journal of the American Chemical Society. 119: 4008-4020. DOI: 10.1021/Ja963492H  1
1997 Bernasconi CF, Montañez RL. Kinetics of Proton Transfer from Benzoylnitromethane and 1,2-Diphenyl-2-nitroethanone to Various Bases. Resonance, Inductive, Solvation, Steric, and Transition State Hydrogen-Bonding Effects on Intrinsic Rate Constants Journal of Organic Chemistry. 62: 8162-8170.  1
1996 Bernasconi CF, Wenzel PJ. Kinetics of proton transfer from 2-nitro-4-X-phenylacetonitriles to piperidine and morpholine in aqueous Me2SO. Solvent and substituent effects on intrinsic rate constants. Transition state imbalances Journal of the American Chemical Society. 118: 11446-11453. DOI: 10.1021/Ja961837Q  1
1996 Bernasconi CF, Wenzel PJ. Transition state imbalances in gas phase proton transfers. Ab initio study of the carbon-to-carbon proton transfer from the protonated acetaldehyde cation to acetaldehyde enol Journal of the American Chemical Society. 118: 10494-10504. DOI: 10.1021/Ja960233J  1
1995 Bernasconi CF, Sun W. Physical organic chemistry of transition metal carbene complexes. 6. Kinetics and mechanism of the thermal and photochemical hydrolysis of (CO)5M=C(OMe)CH2Ph (M = Cr, W) in aqueous acetonitrile Organometallics. 14: 5615-5621. DOI: 10.1021/Om00012A030  1
1995 Bernasconi CF, Flores FX, Sun W. Physical organic chemistry of transition metal carbene complexes. 5.1 kinetics and mechanism of hydrolysis of (CO)5Cr=C(OCH3)CH3 and (CO)5Cr=C(OCH2CH3)CH3 in aqueous acetonitrile Journal of the American Chemical Society. 117: 4875-4880. DOI: 10.1021/Ja00122A019  1
1995 Bernasconi CF, Panda M, Stronach MW. Kinetics of reversible carbon deprotonation of 2-nitroethanol and 2-nitro-1,3-propanediol by hydroxide ion, water, amines, and carboxylate ions. A normal brønsted α despite an imbalanced transition state Journal of the American Chemical Society. 117: 9206-9212.  1
1995 Bernasconi CF, Schuck DF, Ketner RJ, Eventova I, Rappoport Z. The CF3CH2O- adducts of α-nitro-β-(2,2,2-trifluoroethoxy)stilbene and β-methoxy-α-nitrostilbene, and the MeO- adduct of β-methoxy-α-nitrostilbene. Kinetics of competition between protonation and acid catalyzed alkoxide ion departure Journal of the American Chemical Society. 117: 2719-2725.  1
1995 Bernasconi CF, Leyes AE, Eventova I, Rappoport Z. Kinetics of the reactions of β-methoxy-α-nitrostilbene with methoxyamine and N-methylmethoxyamine. Direct observation of the intermediate in nucleophilic vinylic substitution Journal of the American Chemical Society. 117: 1703-1711.  1
1994 Bernasconi CF, Flores FX, Gandler JR, Leyes AE. Physical organic chemistry of transition metal carbene complexes. 4. Kinetics and equilibria of methoxide ion addition to [methoxy(phenyl)carbene]pentacarbonylchromium(0) and [methoxy(phenyl)carbene]pentacarbonyltungsten(0) Organometallics. 13: 2186-2193. DOI: 10.1021/Om00018A011  1
1994 Bernasconi CF, Flores FX, Claus JJ, Dvořák D. Kinetics of the reactions of phenyl-substituted benzylidenemalonodialdehydes with water and hydroxide ion Journal of Organic Chemistry. 59: 4917-4924. DOI: 10.1021/Jo00096A039  1
1994 Bernasconi CF, Ni JX. Proton transfer from carbon acids to carbanions. 2. Reaction of phenylnitromethane with carbanions, enolate, and nitronate ions in 90% Me2SO-10% water. Carbon to carbon or carbon to oxygen proton transfer? Test of the Marcus equation Journal of Organic Chemistry. 59: 4910-4916. DOI: 10.1021/Jo00096A038  1
1994 Bernasconi CF, Kanavarioti A, Stronach MW. Kinetics of hydrolysis of benzylideneacetylacetone Journal of Organic Chemistry. 59: 3806-3813. DOI: 10.1021/Jo00093A012  1
1994 Bernasconi CF, Wenzel PJ. Is there a transition-state imbalance for proton transfers in the gas phase? Ab initio study of the carbon-to-carbon proton transfer from acetaldehyde to its enolate ion Journal of the American Chemical Society. 116: 5405-5413. DOI: 10.1021/Ja00091A052  1
1994 Bernasconi CF, Fassberg J. Hydrolysis of substituted α-nitrostilbenes: Dissection of rate coefficients for individual steps in the four-step mechanism. Estimates of intrinsic rate constants and transition-state imbalances Journal of the American Chemical Society. 116: 514-522. DOI: 10.1021/Ja00081A011  1
1994 Bernasconi CF, Schuck DF, Ketner RJ, Weiss M, Rappoport Z. Kinetic analysis of elementary steps in nucleophilic vinylic substitution reactions of α-nitro-β-X-stilbenes (X = OCH2CF3, OCH3, NO2) with various nucleophiles. Journal of the American Chemical Society. 116: 11764-11774.  1
1994 Bernasconi CF, Renfrow RA. Large transition state imbalance in the expulsion of arylnitromethane anions from aniline adducts of α-nitrostilbenes Journal of Organic Chemistry. 59: 5404-5413.  1
1993 Kanavarioti A, Bernasconi CF, Alberas DJ, Baird EE. Kinetic dissection of individual steps in the poly(C)-directed oligoguanylate synthesis from guanosine 5′-monophosphate 2-methylimidazolide Journal of the American Chemical Society. 115: 8537-8546. PMID 11539864 DOI: 10.1021/Ja00072A003  1
1993 Bernasconi CF, Wiersema D, Stronach MW. Deprotonation of arylnitromethanes. Higher intrinsic rate constants with thiolate ions than with oxyanions or amines as the proton acceptors. Hydrogen bonding in the transition state and desolvation of the base as competing factors in proton transfer at carbon Journal of Organic Chemistry. 58: 217-223. DOI: 10.1021/Jo00053A039  1
1993 Bernasconi CF, Sun W. Physical organic chemistry of transition metal carbene complexes. 3. Thermodynamic and kinetic acidities of chromium carbenes (CO)5Cr:C(OCH3)CH3 and (CO)5Cr:C(OCH3)CH2Ph in aqueous acetonitrile Journal of the American Chemical Society. 115: 12526-12532. DOI: 10.1021/Ja00079A036  0.36
1993 Bernasconi CF, Ni JX. Proton transfer from carbon acids to carbanions. 1. Reactions of various carbon acids with the anions of substituted benzylmalononitriles in 90% Me2SO-10% water. determination of intrinsic barriers of identity reactions from the marcus relationship Journal of the American Chemical Society. 115: 5060-5066. DOI: 10.1021/Ja00065A016  1
1993 Bernasconi CF, Stronach MW. Physical organic chemistry of transition metal carbene complexes. 2.1 Kinetics and mechanism of reactions of [methoxy(phenyl)carbene]pentacarbonylchromium(0) with primary aliphatic amines in aqueous acetonitrile Journal of the American Chemical Society. 115: 1341-1346. DOI: 10.1021/Ja00057A017  1
1993 Bernasconi CF, Sun W. Physical organic chemistry of transition metal carbene complexes.1 Thermodynamic and kinetic acidities of (CO)5Cr=C(OCH3)CH3 and (CO)5Cr=C(OCH3)CH2Ph in aqueous acetonitrile Journal of the American Chemical Society. 115: 12526-12532.  1
1993 Bernasconi CF, Leyes AE, Rappoport Z, Eventova I. Reaction of N-methylmethoxyamine with β-methoxy-α-nitrostilbene. First direct observation of the intermediate in a nucleophilic vinylic substitution with an amine nucleophile Journal of the American Chemical Society. 115: 7513-7514.  1
1992 Bernasconi CF, Schuck DF. Kinetics of reversible thiolate ion addition to substituted β-nitrostyrenes in water. Radicaloid transition state or principle of nonperfect synchronization? Journal of Organic Chemistry. 57: 2365-2373. DOI: 10.1021/Jo00034A032  1
1992 Bernasconi CF, Zitomer JL, Schuck DF. Kinetics of hydroxide and nitromethide ion addition to substituted .beta.-nitrostyrenes in dimethyl sulfoxide-water mixtures. Solvent dependence of .pi.-donor substituent effects and of intrinsic rate constants Journal of Organic Chemistry. 57: 1132-1139. DOI: 10.1021/Jo00030A019  0.52
1992 Gandler JR, Bernasconi CF. Kinetics of deprotonation of arylnitromethanes by benzoate ions in acetonitrile solution. Effect of equilibrium and nonequilibrium transition-state solvation on intrinsic rate constants of proton transfers Journal of the American Chemical Society. 114: 631-637. DOI: 10.1021/Ja00028A032  1
1992 Bernasconi CF. The principle of nonperfect synchronization: More than a qualitative concept? Accounts of Chemical Research. 25: 9-16. DOI: 10.1021/Ar00013A002  1
1992 Bernasconi CF, Zitomer JL, Schuck DF. Kinetics of hydroxide and nitromethide ion addition to substituted β-nitrostyrenes in Me2SO-water mixtures. Solvent dependence of π-donor substituent effects and of intrinsic rate constants Journal of Organic Chemistry. 57: 1132-1139.  1
1991 Bernasconi CF, Stronach MW. Kinetics of Amine Addition to Benzylidene-1,3-indandione and Other Vinylic β-Diketones. Effect of Cyclic Structure and Steric Strain on Intrinsic Rate Constants Journal of the American Chemical Society. 113: 2222-2227. DOI: 10.1021/Ja00006A046  1
1991 Bernasconi CF. The Principle of Non-perfect Synchronization Advances in Physical Organic Chemistry. 27: 119-238. DOI: 10.1016/S0065-3160(08)60065-9  1
1991 Bernasconi CF, Fassberg J, Killion RB, Schuck DF, Rappoport Z. Kinetics of reactions of hydroxide ion and water with β-X-substituted α-nitrostilbenes (X = Cl, I, SEt, OMe, SCH2CH2OH) in 50% Me2SO-50% water. Search for the intermediate in nucleophilic vinylic substitution Journal of the American Chemical Society. 113: 4937-4946.  1
1991 Bernasconi CF, Ohlberg DAA, Stronach MW. Kinetics of proton transfer of 3,5-heptanedione, 2,6-dimethyl-3,5-heptanedione, and dibenzoylmethane with amines in 50% Me2SO-50% water. Effect of steric crowding and π-overlap on intrinsic rate constants Journal of Organic Chemistry. 56: 3016-3020.  1
1991 Bernasconi CF, Stronach MW. Kinetics of amine addition to benzylidenemalonodialdehyde in 50% Me2SO-50% water Journal of Organic Chemistry. 56: 1993-2001.  1
1990 Kanavarioti A, Bernasconi CF. Computer simulation in template-directed oligonucleotide synthesis. Journal of Molecular Evolution. 31: 470-7. PMID 2176695 DOI: 10.1007/Bf02102073  1
1990 Bernasconi CF, Stronach MW, DePuy CH, Gronert S. Reaction of anions with activated olefins in the gas phase. A flowing afterglow-selected ion flow tube study Journal of the American Chemical Society. 112: 9044-9052. DOI: 10.1021/Ja00181A003  1
1990 Bernasconi CF, Stronach MW. Kinetic behavior of tetrachlorocyclopentadienyl-type anions. Deprotonation of 1,2,3,4-tetrachloro-1,3-cyclopentadiene and nucleophilic addition to 1,2,3,4-tetrachloro-6-phenylfulvene in 50% Me2SO/50% water Journal of the American Chemical Society. 112: 8448-8454. DOI: 10.1021/Ja00179A032  1
1990 Bernasconi CF, Stronach MW, Depuy CH, Gronert S. Gas‐phase acidities of acrolein and methyl acrylate Journal of Physical Organic Chemistry. 3: 346-348. DOI: 10.1002/Poc.610030512  1
1990 Bernasconi CF, Fassberg J, Killion RB, Rappoport Z. Kinetics of reactions of amines with α-nitro-β-substituted-stilbenes in 50% Me2SO-50% water. Search for the intermediate in nucleophilic vinylic substitution reactions Journal of Organic Chemistry. 55: 4568-4575.  1
1990 Bernasconi CF, Fassberg J, Killion RB, Rappoport Z. Kinetics of reactions of thiolate ions with α-nitro β-substituted stilbenes in 50% Me2SO-50% water. Observation of the intermediate in nucleophilic vinylic substitution reactions Journal of the American Chemical Society. 112: 3169-3177.  1
1989 Kanavarioti A, Bernasconi CF, Doodokyan DL, Alberas DJ. Magnesium ion catalyzed P-N bond hydrolysis in imidazolide-activated nucleotides. Relevance to template-directed synthesis of polynucleotides. Journal of the American Chemical Society. 111: 7247-57. PMID 11542186 DOI: 10.1007/Bf02388889  1
1989 Gandler JR, Bernasconi CF. Proton transfer from (methoxymethylcarbene)pentacarbonylchromium(0) in aqueous solution Organometallics. 8: 2282-2284. DOI: 10.1021/Om00111A035  1
1989 Bernasconi CF, Killion RB. Nucleophilic addition to olefins. Part 24. Is there a transition-state imbalance in malononitrile anion forming reactions? Kinetics of piperidine and morpholine addition to substituted benzylidenemalononitriles in various Me2SO-water mixtures Journal of Organic Chemistry. 54: 2878-2885. DOI: 10.1021/Jo00273A021  1
1989 Bernasconi CF. Nucleophilic addition to olefins. Kinetics and mechanism Tetrahedron. 45: 4017-4090. DOI: 10.1016/S0040-4020(01)81304-1  1
1989 Kanavarioti A, Bernasconi CF, Doodokyan DL, Alberas D. Magnesium ion catalyzed P-N bond hydrolysis in imidazolide activated nucleotides. Relevance to template-directed synthesis of polynucleotides Origins of Life and Evolution of the Biosphere. 19: 353-353. DOI: 10.1007/BF02388889  1
1989 Bernasconi CF, Killion RB, Fassberg J, Rappoport Z. Kinetics of the reaction of β-methoxy-α-nitrostilbene with thiolate ions. First direct observation of the intermediate in a nucleophilic vinylic substitution Journal of the American Chemical Society. 111: 6862-6864.  1
1989 Bernasconi CF, Paschalis P. Kinetics of hydrolysis of substituted β-nitrostyrenes. Transition-state imbalances and intrinsic rate constants for three different types of nitronate ion forming processes. Relevance to the nitroalkane anomaly Journal of the American Chemical Society. 111: 5893-5902.  1
1989 Bernasconi CF, Killion RB. Is there a transition-state imbalance in malononitrile anion forming reactions? kinetics of piperidine and morpholine addition to substituted benzylidenemalononitriles in various Me2SO-water mixtures Journal of Organic Chemistry. 54: 2878-2885.  1
1988 Bernasconi CF, Kliner DAV, Mullin AS, Ni JX. Kinetics of ionization of nitromethane and phenylnitromethane by amines and carboxylate ions in Me2SO-water mixtures. Evidence of ammonium ion-nitronate ion hydrogen bonded complex formation in Me2SO-rich solvent mixtures Journal of Organic Chemistry. 53: 3342-3351. DOI: 10.1021/Jo00249A040  1
1988 Bernasconi CF, Killion RB. Nucleophilic addition to olefins. Part 23. High intrinsic rate constant and large imbalances in the thiolate ion addition to substituted .alpha.-nitrostilbenes Journal of the American Chemical Society. 110: 7506-7512. DOI: 10.1021/Ja00230A038  1
1988 Bernasconi CF, Fairchild DE. Intermediates in nucleophilic aromatic substitution. Part 23. Kinetics of spiro meisenheimer complex formation from 3,6-dimethylcatechol 2,4,6-trinitrophenyl ether. Competition between a trapping and a preassociation mechanism Journal of the American Chemical Society. 110: 5498-5505. DOI: 10.1021/Ja00224A038  0.6
1988 Bernasconi CF, Bunnell RD, Terrier F. Rate and equilibrium constants of ionization of (α-cyanodiphenylmethane)bis(tricarbonylchromium(0)) in Me2SO-water mixtures. Unusual solvent effect on the intrinsic rate constant Journal of the American Chemical Society. 110: 6514-6521.  1
1988 Bernasconi CF, Fairchild DE. Kinetics of spiro Meisenheimer complex formation from 3,6-dimethylcatechol 2,4,6-trinitrophenyl ether. Competition between a trapping and a preassociation mechanism Journal of the American Chemical Society. 110: 5498-5505.  1
1988 Bernasconi CF, Bunnell RD. Free energies of transfer of carbon acids and their conjugate carbanions from water to Me2SO-water mixtures Journal of the American Chemical Society. 110: 2900-2903.  1
1988 Bernasconi CF, Bunnell RD. Nucleophilic addition to olefins. 22. Kinetics of hydrolysis of the piperidine and morpholine adducts of benzylideneacetylacetone in 50% Me2SO-50% water Journal of Organic Chemistry. 53: 2001-2008.  1
1988 Bernasconi CF, Killion RB. High intrinsic rate constant and large imbalances in the thiolate ion addition to substituted α-nitrostilbenes Journal of the American Chemical Society. 110: 7506-7512.  1
1987 Bernasconi CF, Panda M. Nucleophilic addition to olefins. 21. Substituent and solvent effects on the reaction of benzylidene Meldrum's acids with piperidine and morpholine Journal of Organic Chemistry. 52: 3042-3050. DOI: 10.1021/Jo00390A016  1
1987 Bernasconi CF, Terrier F. Ionization of 9-cyano- and 9-(carbomethoxy)fluorene in dimethyl sulfoxide-water mixtures. How important is solvent reorganization? Journal of the American Chemical Society. 109: 7115-7121. DOI: 10.1021/Ja00257A035  1
1987 Bernasconi CF, Fairchild DE, Murray CJ. Kinetic solvent isotope effect and proton inventory study of the carbon protonation of amine adducts of benzylidene Meldrum's acid and other Meldrum's acid derivatives. Evidence for concerted intramolecular proton transfer Journal of the American Chemical Society. 109: 3409-3415. DOI: 10.1021/Ja00245A036  1
1987 Bernasconi CF. Intrinsic barriers of reactions and the principle of nonperfect synchronization Accounts of Chemical Research. 20: 301-308. DOI: 10.1021/Ar00140A006  1
1987 Bernasconi CF, Renfrow RA. Nucleophilic addition to olefins. 20. Large transition-state imbalances in the reaction of α-nitrostilbenes with amines Journal of Organic Chemistry. 52: 3035-3041.  1
1986 Bernasconi CF, Kanavarioti A. Nucleophilic additions to olefins. 19. Abnormally high intrinsic barrier in the reaction of piperidine and morpholine with benzylideneacetylacetone. Journal of the American Chemical Society. 108: 7744-51. PMID 22283281 DOI: 10.1021/Ja00284A043  0.52
1986 Bernasconi CF, Fox JP, Kanavarioti A, Panda M. Nucleophilic addition to olefins. 15. Solvent and substituent effects on the hydrolysis of benzylidenemalononitriles in basic dimethyl sulfoxide-water solutions. Journal of the American Chemical Society. 108: 2372-81. PMID 22175586 DOI: 10.1021/Ja00269A039  0.52
1986 Bernasconi CF, Terrier F. Ionization of 9-cyanofluorene in Me2SO-water mixtures. The role of solvent reorientation in proton tranfers Canadian Journal of Chemistry. 64: 1273-1275. DOI: 10.1139/V86-210  1
1986 Bernasconi CF, Murray CJ. Brønsted coefficients for intramolecularly assisted carbon protonation of amine adducts of benzylidene Meldrum's acid Journal of the American Chemical Society. 108: 5257-5264. DOI: 10.1021/Ja00277A033  1
1986 Bernasconi CF, Renfrow RA, Tia PR. Nucleophilic addition to olefins. 16. Unusual substituent effects in the reaction of amines with β-nitrostyrenes. Solvent effect on intrinsic rate constants Journal of the American Chemical Society. 108: 4541-4549. DOI: 10.1021/Ja00275A047  1
1986 Bernasconi CF, Kanavarioti A. Nucleophilic addition to olefins. 19. Abnormally high intrinsic barrier in the reaction of piperidine and morpholine with benzylideneacetylacetone Journal of the American Chemical Society. 108: 7744-7751.  1
1986 Bernasconi CF, Murray CJ. Nucleophilic addition to olefins. 18. Kinetics of the addition of primary amines and α-effect nucleophiles to benzylidene Meldrum's acid Journal of the American Chemical Society. 108: 5251-5257.  1
1986 Bernasconi CF, Paschalis P. Kinetics of ionization of 1,3-indandione in Me2SO-water mixtures. Solvent effect on intrinsic rates and Brønsted coefficients Journal of the American Chemical Society. 108: 2969-2977.  1
1986 Bernasconi CF, Stronach MW. Reaction of benzylidenemalonaldehyde with water and hydroxide ion Journal of Organic Chemistry. 51: 2144-2145.  1
1986 Bernasconi CF, Fox JP, Kanavarioti A, Panda M. Nucleophilic addition to olefins. 15. Solvent and substituent effects on the hydrolysis of benzylidenemalononitriles in basic Me2SO-water solutions Journal of the American Chemical Society. 108: 2372-2381.  1
1985 Bernasconi CF, Laibelman A, Zitomer JL. Nucleophilic addition to olefins. 13. Kinetics of hydrolysis of benzylidene-1,3-indandione Journal of the American Chemical Society. 107: 6563-6570. DOI: 10.1021/Ja00309A023  1
1985 Bernasconi CF, Kanavarioti A, Killion RB. Nucleophilic addition to olefins. 12. Solvent-induced change in the rate-limiting step of the hydrolysis of benzylidenemalononitrile in acidic dimethyl sulfoxide-water solution Journal of the American Chemical Society. 107: 3612-3620. DOI: 10.1021/Ja00298A035  1
1985 Bernasconi CF. The principle of imperfect synchronization. I. Ionization of carbon acids Tetrahedron. 41: 3219-3234. DOI: 10.1016/S0040-4020(01)96673-6  1
1985 Bernasconi CF, Laibelman A, Zitomer JL. Nucleophilic addition to olefins. 14. Kinetics of the reaction of 1,3-indandione anion with benzylidene-1,3-indandione Journal of the American Chemical Society. 107: 6570-6575. DOI: 10.1002/Chin.198610140  1
1985 Bernasconi CF, Kanavarioti A, Killion RB. Nucleophilic addition to olefins. 12. Solvent-induced change in the rate-limiting step of the hydrolysis of benzylidenemalononitrile in acidic Me2SO - water solution Journal of the American Chemical Society. 107: 3612-3620.  1
1984 Bernasconi CF, Howard KA, Kanavarioti A. Nucleophilic addition to olefins. 11. Kinetics of the reversible hydrolysis of benzylidenemalononitrile in water Journal of the American Chemical Society. 106: 6827-6835. DOI: 10.1021/Ja00334A058  1
1984 Bernasconi CF, Zitomer JL, Fox JP, Howard KA. Nucleophilic addition to olefins. 9. Kinetics of the reaction of benzylidenemalononitrile with malononitrile anion Journal of Organic Chemistry. 49: 482-486. DOI: 10.1002/Chin.198431094  1
1984 Bernasconi CF, Murray CJ. Nucleophilic addition to olefins. 10. Kinetics of cleavage of the piperidine and morpholine adducts of α-cyano-4-nitrostilbene and α-cyano-2,4-dinitrostilbene Journal of the American Chemical Society. 106: 3257-3264.  1
1983 Bernasconi CF, Howard KA. Kinetics of acid-catalyzed breakdown of spiro Meisenheimer complexes Journal of the American Chemical Society. 105: 4690-4697.  1
1982 Bernasconi CF, Howard KA. Stereoelectronic and conformational effects in Meisenheimer complexes. Intrinsic reactivities of spiro vs. 1,1-dimethoxy and 1-methoxy-1-phenoxy complexes Journal of the American Chemical Society. 104: 7248-7257. DOI: 10.1021/Ja00389A057  1
1982 Bernasconi CF, Leonarduzzi GD. Nucleophilic addition to olefins. 7. Kinetic deuterium isotope effects as criterion for an enforced preassociation mechanism in the hydrolysis of substituted benzylidene meldrum's acids Journal of the American Chemical Society. 104: 5143-5153. DOI: 10.1021/Ja00383A025  1
1982 Bernasconi CF, Leonarduzzi GD. Nucleophilic addition to olefins. 6. Structure-reactivity relationships in the reactions of substituted benzylidene Meldrum's acids with water, hydroxide ion, and aryl oxide ions Journal of the American Chemical Society. 104: 5133-5142. DOI: 10.1021/Ja00383A024  1
1982 Bernasconi CF, Hibdon SA, McMurry SE. When is intramolecular proton transfer between carbon and nitrogen or oxygen observable? Journal of the American Chemical Society. 104: 3459-3471. DOI: 10.1021/Ja00376A036  1
1981 Bernasconi CF, Carre DJ, Kanavarioti A. Nucleophilic addition to olefins. 5. Reaction of 1,1-dinitro-2,2-diphenylethylene with water and hydroxide ion in 50% dimethyl sulfoxide-50% water. Complete kinetic analysis of hydrolytic cleavage of the C:C double bond in acidic and basic solution Journal of the American Chemical Society. 103: 4850-4860. DOI: 10.1021/Ja00406A030  0.52
1981 Bernasconi CF, Carré DJ, Kanavarioti A. Nucleophilic addition to olefins. 5. Reaction of 1,1-dinitro-2,2-diphenylethylene with water and hydroxide ion in 50% Me2SO-50% water. Complete kinetic analysis of hydrolytic cleavage of the C=C double bond in acidic and basic solution Journal of the American Chemical Society. 103: 4850-4860.  1
1980 Bernasconi CF, Fornarini S. Nucleophilic addition to olefins. 4. Structure-reactivity relationships in the reactions of amines with substituted benzylidene meldrum's acids. Evidence for intramolecular proton transfer to carbon Journal of the American Chemical Society. 102: 5329-5336. DOI: 10.1021/Ja00536A035  1
1980 Bernasconi CF, Fox JP, Fornarini S. Nucleophilic addition to activated olefins. 3. Reactions of piperidine and morpholine with benzylidenemalononitrile in 50% dimethyl sulfoxide-50% Water. Intrinsic barriers in nucleophilic additions Journal of the American Chemical Society. 102: 2810-2816. DOI: 10.1021/Ja00528A049  1
1980 Bernasconi CF, Leonarduzzi GD. Nucleophilic addition to olefins. 2. Reaction of benzylidene Meldrum's acid with water, hydroxide ion, and aryloxide ions. Complete kinetic analysis of the hydrolytic cleavage of the C=C double bond Journal of the American Chemical Society. 102: 1361-1366.  1
1979 Bernasconi CF, Kanavarioti A. Rates of ionization of 1,1-dinitroethane in 50% dimethyl sulfoxide-50% water. Solvent effect on proton transfer Journal of Organic Chemistry. 44: 4829-4832. DOI: 10.1021/Jo00394A018  1
1979 Bernasconi CF, Carré DJ. Rate of protonation of 2,6-di-tert-butylpyridine by the hydronium ion. Steric hindrance to proton transfer Journal of the American Chemical Society. 101: 2707-2709. DOI: 10.1021/Ja00504A035  1
1979 Bernasconi CF, Carré DJ. Anomalous rates of proton transfer to and from nitrogen and carbon in the reactions of amines with 1,1-dinitro-2,2-diphenylethylene Journal of the American Chemical Society. 101: 2698-2707. DOI: 10.1021/Ja00504A034  1
1979 Bernasconi CF, Muller MC, Schmid P. Rate-limiting proton transfer in the formation of Meisenheimer complexes between 1,3,5-trinitrobenzene and amines. The effect of dimethyl sulfoxide on proton-transfer rates. Relative leaving-group abilities of amines and alkoxide ions Journal of Organic Chemistry. 44: 3189-3196.  1
1978 Bernasconi CF, Muller MC. The elusive 1,1-Meisenheimer complex from 2,4,6-Trinitroanisole and aryloxide ions. A stopped-flow temperature-jump study Journal of the American Chemical Society. 100: 5530-5533.  1
1978 Bernasconi CF. Kinetic behavior of short-lived anionic σ complexes Accounts of Chemical Research. 11: 147-152.  1
1978 Bernasconi CF, Gandler JR. Multiple structure-reactivity relationships in the acid-catalyzed breakdown of Meisenheimer complexes Journal of the American Chemical Society. 100: 8117-8124.  1
1977 Bernasconi CF, Gandler JR. Intermediates in nucleophilic aromatic substitution. 17. Kinetics of spiro Meisenheimer complexes. Effect of ring size Journal of Organic Chemistry. 42: 3387-3393. DOI: 10.1021/Jo00441A014  1
1977 Bernasconi CF, De Rossi RH, Schmid P. Changing views on the mechanism of base catalysis in nucleophilic aromatic substitution. Kinetics of reactions of nitroaryl ethers with piperidine and with n-butylamine in aqueous dioxane Journal of the American Chemical Society. 99: 4090-4101. DOI: 10.1021/Ja00454A030  1
1977 Bernasconi CF, Wang HC. Kinetics of the electron-transfer reactions of azaviolene radical ions. 2. Correlation with the Marcus theory. The question of concerted acid-base catalysis Journal of the American Chemical Society. 99: 2214-2221. DOI: 10.1021/Ja00449A031  1
1976 Bernasconi CF, De Rossi RH. Influence of the o-nitro group on base catalysis in nucleophilic aromatic substitution. Reactions in benzene solution Journal of Organic Chemistry. 41: 44-49. DOI: 10.1021/Jo00863A010  1
1976 Bernasconi CF, Wang HC. Spiro Meisenheimer complex from catechol 2,4,6-trinitrophenyl ether. Rate-limiting proton transfer as a consequence of a very fast intramolecular nucleophilic attack Journal of the American Chemical Society. 98: 6265-6270.  1
1976 Bernasconi CF, Gehriger CL, De Rossi RH. Toward a complete characterization of the mechanism of nucleophilic aromatic substitution by an amine. Kinetics of spiro Meisenheimer complexes derived from N-methylethanolamine Journal of the American Chemical Society. 98: 8451-8459.  1
1975 Bernasconi CF, Terrier F. Intermediates in nucleophilic aromatic substitution. XIV. Spiro Meisenheimer complexes derived from N,N′-dimethylethylenediamine. Kinetics in aqueous dimethyl sulfoxide Journal of the American Chemical Society. 97: 7458-7466. DOI: 10.1021/Ja00859A013  1
1974 Bernasconi CF, Cross HS. Intermediates in nucleophilic aromatic substitution. XII. Kinetic and equilibrium study of the spiro Meisenheimer complex of 1-(β-hydroxyethoxy)-2,4-dinitrobenzene Journal of Organic Chemistry. 39: 1054-1058. DOI: 10.1021/Jo00922A008  1
1974 Bernasconi CF, Boyle WJ. A complete kinetic analysis of the A-SE2 mechanism of acid-catalyzed addition of methanol to an olefinic double bond Journal of the American Chemical Society. 96: 6070-6077. DOI: 10.1021/Ja00826A019  1
1974 Bernasconi CF, Bergstrom RG, Boyle WJ. Kinetics of the electron transfer reactions of azaviolene radical ions. I Journal of the American Chemical Society. 96: 4643-4650. DOI: 10.1021/Ja00821A046  1
1974 Bernasconi CF, Gehriger CL. Intermediates in nucleophilic aromatic substitution. XI. Spiro Meisenheimer complex of N,N′-dimethyl-N-picrylethylenediamine. Partially rate-limiting proton transfer of complex formation. A temperature-jump study Journal of the American Chemical Society. 96: 1092-1099. DOI: 10.1021/Ja00811A025  1
1974 Bernasconi CF, Bergstrom RG. Normal coordinate analysis of coupled reactions. Application to anionic σ complexes of 1,3,5-trinitrobenzene with hydroxide and alkoxide ions in water, methanol-water, and ethanol-water mixtures Journal of the American Chemical Society. 96: 2397-2403.  1
1973 Bernasconi CF, DeRossi RH. Intermediates in nucleophilic aromatic substitution. VIII. Temperature-jump and equilibrium study of the spiro Meisenheimer complex of N-2-hydroxyethyl-N-methyl-2,4-dinitroaniline Journal of Organic Chemistry. 38: 500-507. DOI: 10.1021/Jo00943A020  1
1973 Bernasconi CF, Bergstrom RG. Intermediates in nucleophilic aromatic substitution. IX. 1:1 and 1:2 sulfite complexes of 1,3,5-trinitrobenzene. Cis-trans isomerism in the 1:2 complex Journal of the American Chemical Society. 95: 3603-3608. DOI: 10.1021/Ja00792A023  1
1971 Bernasconi CF, Bergstrom RG, Hünig S. Temperature-jump study of the reversible disproportionation of an azaviolene radical ion Journal of the Chemical Society D: Chemical Communications. 1485-1486. DOI: 10.1039/C29710001485  1
1971 Bernasconi CF. Kinetic and spectral study of some reactions of 2,4,6-trinitrotoluene in basic solution. I. Deprotonation and Janovsky complex formation Journal of Organic Chemistry. 36: 1671-1679. DOI: 10.1021/Jo00811A022  1
1971 Bernasconi CF, Bergstrom RG. Intermediates in nucleophilic aromatic substitution. V. Kinetic study of Meisenheimer complexes of 1,3,5-trinitrobenzene with hydroxide and alkoxide ions in ethanol-water and methanol-water mixtures Journal of Organic Chemistry. 36: 1325-1330. DOI: 10.1021/Jo00809A001  1
1971 Bernasconi CF. Intermediates in nucleophilic aromatic substitution. VII. Stopped-flow temperature-jump study of the transient 1,3-methoxide ion adduct of 2,4,6-trinitroanisole in methanol Journal of the American Chemical Society. 93: 6975-6977. DOI: 10.1021/Ja00754A047  1
1971 Bernasconi CF. Intermediates in nucleophilic aromatic substitution. VI. Kinetic evidence of intramolecular hydrogen bonding in meisenheimer complexes Journal of Physical Chemistry. 75: 3636-3639.  1
1970 Bernasconi CF. Intermediates in nucleophilic aromatic substitution. III. Visible absorption spectra of the acid and basic form of the 1,3,5-trinitrobenzene-piperidine meisenheimer complex in 10% dioxane-90% water Journal of Organic Chemistry. 35: 1214-1216. DOI: 10.1021/Jo00829A091  1
1970 Bunnett JF, Bernasconi CF. Kinetics of reactions of piperidine with substituted phenyl ethers of 2,4-dinitrophenol in 60% dioxane-40% water. Base catalysis as a function of the group displaced Journal of Organic Chemistry. 35: 70-75. DOI: 10.1021/Jo00826A017  1
1970 Bernasconi CF. Intermediates in nucleophilic aromatic substitution. IV. Kinetic study of the interaction of 1,3,5-trinitrobenzene with the lyate ions of water, methanol, and ethanol in the respective solvents Journal of the American Chemical Society. 92: 4682-4688. DOI: 10.1021/Ja00718A035  1
1970 Bernasconi CF. Intermediates in nucleophilic aromatic substitution. II. Temperature-jump study of the interaction of 1,3,5-trinitrobenzene with aliphatic amines in 10% dioxane-90% water. Concurrent nucleophilic attack on the aromatic carbon and on the nitro group? Journal of the American Chemical Society. 92: 129-137. DOI: 10.1021/Ja00704A021  1
1968 Bernasconi CF. Intermediates in nucleophilic aromatic substitution. I. Temperature-jump study of the decomposition of 1,1-dimethoxy-2,4-dinitrocyclohexadienate in methanol Journal of the American Chemical Society. 90: 4982-4988. DOI: 10.1021/Ja01020A036  1
1967 Becker G, Bernasconi CF, Zollinger H. [Catalytic effect in the reaction of 2,4-dinitrofluorobenzene with morpholine in benzene. 7. Communication on nucleophile aromatic substitution reactions]. Helvetica Chimica Acta. 50: 10-5. PMID 5593203 DOI: 10.1002/hlca.19670500104  0.6
1967 Bernasconi CF, Schmid P. Base catalysis of the reaction of morpholine with 2,4-dinitrophenyl phenyl ether in 10% dioxane-90% water Journal of Organic Chemistry. 32: 2953-2956.  1
1967 Bernasconi CF. Kinetics of reactions of amines with ethers of 2,4-dinitrophenol in 10% dioxane-90% water. Dependence of base catalysis on the entering amine and on the leaving group Journal of Organic Chemistry. 32: 2947-2952.  1
1965 Bunnett JF, Bernasconi C. Kinetics of reactions of piperidine with ethers of 2,4-dinitrophenol in 10% dioxane-90% water. Dependence of base catalysis on the group displaced Journal of the American Chemical Society. 87: 5209-5218. DOI: 10.1021/Ja00950A040  1
1965 Bernasconi C, Zollinger H. Zum problem der elektrophil und basen-katalysierten aromatischen nukleophilen substitutionsreaktionen in benzol Tetrahedron Letters. 6: 1083-1090.  0.6
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