Matthew T. Kieber-Emmons, Ph.D. - Publications

Chemistry University of Utah, Salt Lake City, UT 
metalloprotein mechanism and bioinspired catalysis

28 high-probability publications. We are testing a new system for linking publications to authors. You can help! If you notice any inaccuracies, please sign in and mark papers as correct or incorrect matches. If you identify any major omissions or other inaccuracies in the publication list, please let us know.

Year Citation  Score
2020 VanNatta PE, Ramirez DA, Velarde A, Ali G, Kieber-Emmons MT. Exceptionally High O-H Bond Dissociation Free Energy of a Dicopper(II) µ-Hydroxo Complex and Insights into the Geometric and Electronic Structure Origins Thereof. Journal of the American Chemical Society. PMID 32867475 DOI: 10.1021/jacs.0c06425  1
2020 Ahlburg NL, Velarde AR, Kieber-Emmons MT, Jones PG, Werz DB. Substituted Benzothietes: Synthesis and a Quantum Chemical Investigation of Their Cycloreversion Properties. Organic Letters. PMID 32401521 DOI: 10.1021/acs.orglett.0c01261  0.01
2019 Nimens WJ, Lefave SJ, Flannery L, Ogle J, Smilgies DM, Kieber-Emmons MT, Whittaker Brooks L. Understanding hydrogen bonding interactions in crosslinked methylammonium lead iodide crystals: towards reducing moisture and light degradation pathways. Angewandte Chemie (International Ed. in English). PMID 31369693 DOI: 10.1002/anie.201906017  0.04
2018 Cook BJ, Di Francesco GN, Kieber-Emmons MT, Murray LJ. A Tricopper(I) Complex Competent for O Atom Transfer, C-H Bond Activation, and Multiple O Activation Steps. Inorganic Chemistry. PMID 29791149 DOI: 10.1021/acs.inorgchem.8b00921  0.01
2017 Ali G, VanNatta PE, Ramirez DA, Light KM, Kieber-Emmons MT. Thermodynamics of a μ-oxo Dicopper(II) Complex for Hydrogen Atom Abstraction. Journal of the American Chemical Society. PMID 29207870 DOI: 10.1021/jacs.7b10833  1
2017 Koepke SJ, Light KM, VanNatta PE, Wiley KM, Kieber-Emmons MT. Electrocatalytic Water Oxidation by a Homogeneous Copper Catalyst Disfavors Single-Site Mechanisms. Journal of the American Chemical Society. PMID 28558469 DOI: 10.1021/jacs.7b03278  1
2017 Schaefer AW, Kieber-Emmons MT, Adam SM, Karlin KD, Solomon EI. Phenol-Induced O-O Bond Cleavage in a Low-Spin Heme-Peroxo-Copper Complex: Implications for O2 Reduction in Heme-Copper Oxidases. Journal of the American Chemical Society. PMID 28521498 DOI: 10.1021/jacs.7b03292  1
2016 Light KM, Wisniewski JA, Vinyard WA, Kieber-Emmons MT. Perception of the plant hormone ethylene: known-knowns and known-unknowns. Journal of Biological Inorganic Chemistry : Jbic : a Publication of the Society of Biological Inorganic Chemistry. PMID 27456611 DOI: 10.1007/s00775-016-1378-3  1
2016 Cao R, Saracini C, Ginsbach JW, Kieber-Emmons MT, Siegler MA, Solomon EI, Fukuzumi S, Karlin KD. Peroxo and Superoxo Moieties Bound to Copper Ion: Electron-Transfer Equilibrium with a Small Reorganization Energy. Journal of the American Chemical Society. PMID 27228314 DOI: 10.1021/jacs.6b02404  1
2014 Kieber-Emmons MT, Ginsbach JW, Wick PK, Lucas HR, Helton ME, Lucchese B, Suzuki M, Zuberbühler AD, Karlin KD, Solomon EI. Observation of a Cu(II)(2) (μ-1,2-peroxo)/Cu(III)(2) (μ-oxo)(2) equilibrium and its implications for copper-dioxygen reactivity. Angewandte Chemie (International Ed. in English). 53: 4935-9. PMID 24700427 DOI: 10.1002/anie.201402166  1
2014 Solomon EI, Heppner DE, Johnston EM, Ginsbach JW, Cirera J, Qayyum M, Kieber-Emmons MT, Kjaergaard CH, Hadt RG, Tian L. Copper active sites in biology. Chemical Reviews. 114: 3659-853. PMID 24588098 DOI: 10.1021/cr400327t  1
2012 Ginsbach JW, Kieber-Emmons MT, Nomoto R, Noguchi A, Ohnishi Y, Solomon EI. Structure/function correlations among coupled binuclear copper proteins through spectroscopic and reactivity studies of NspF. Proceedings of the National Academy of Sciences of the United States of America. 109: 10793-7. PMID 22711806 DOI: 10.1073/pnas.1208718109  1
2012 Kieber-Emmons MT, Qayyum MF, Li Y, Halime Z, Hodgson KO, Hedman B, Karlin KD, Solomon EI. Spectroscopic elucidation of a new heme/copper dioxygen structure type: implications for O···O bond rupture in cytochrome c oxidase. Angewandte Chemie (International Ed. in English). 51: 168-72. PMID 22095556 DOI: 10.1002/anie.201104080  1
2011 Kieber-Emmons MT, Li Y, Halime Z, Karlin KD, Solomon EI. Electronic structure of a low-spin heme/Cu peroxide complex: spin-state and spin-topology contributions to reactivity. Inorganic Chemistry. 50: 11777-86. PMID 22007669 DOI: 10.1021/ic2018727  1
2011 Solomon EI, Ginsbach JW, Heppner DE, Kieber-Emmons MT, Kjaergaard CH, Smeets PJ, Tian L, Woertink JS. Copper dioxygen (bio)inorganic chemistry. Faraday Discussions. 148: 11-39; discussion 97. PMID 21322475 DOI: 10.1039/c005500j  1
2010 Lee Y, Lee DH, Park GY, Lucas HR, Narducci Sarjeant AA, Kieber-Emmons MT, Vance MA, Milligan AE, Solomon EI, Karlin KD. Sulfur donor atom effects on copper(I)/O(2) chemistry with thioanisole containing tetradentate N(3)S ligand leading to μ-1,2-peroxo-dicopper(II) species. Inorganic Chemistry. 49: 8873-85. PMID 20822156 DOI: 10.1021/ic101041m  1
2010 Halime Z, Kieber-Emmons MT, Qayyum MF, Mondal B, Gandhi T, Puiu SC, Chufán EE, Sarjeant AA, Hodgson KO, Hedman B, Solomon EI, Karlin KD. Heme-copper-dioxygen complexes: toward understanding ligand-environmental effects on the coordination geometry, electronic structure, and reactivity. Inorganic Chemistry. 49: 3629-45. PMID 20380465 DOI: 10.1021/ic9020993  1
2010 Van Heuvelen KM, Kieber-Emmons MT, Riordan CG, Brunold TC. Spectroscopic and computational studies of a trans-mu-1,2-disulfido-bridged dinickel species, [{(tmc)Ni}(2)(S(2))](OTf)(2): comparison of end-on disulfido and peroxo bonding in (Ni(II))(2) and (Cu(II))(2) species. Inorganic Chemistry. 49: 3104-12. PMID 20199095 DOI: 10.1021/ic901733h  1
2009 Mock MT, Kieber-Emmons MT, Popescu CV, Gasda P, Yap GP, Riordan CG. A Series of Cyanide-Bridged Binuclear Complexes. Inorganica Chimica Acta. 362: 4553-4562. PMID 20161111 DOI: 10.1016/j.ica.2009.05.042  1
2009 Ariyananda PW, Kieber-Emmons MT, Yap GP, Riordan CG. Synthetic analogs for evaluating the influence of N-H...S hydrogen bonds on the formation of thioester in acetyl coenzyme A synthase. Dalton Transactions (Cambridge, England : 2003). 4359-69. PMID 19662314 DOI: 10.1039/b901192g  1
2009 Kieber-Emmons MT, Van Heuvelen KM, Brunold TC, Riordan CG. Synthesis and spectroscopic identification of a mu-1,2-disulfidodinickel complex. Journal of the American Chemical Society. 131: 440-1. PMID 19099477 DOI: 10.1021/ja807735a  1
2007 Kieber-Emmons MT, Riordan CG. Dioxygen activation at monovalent nickel. Accounts of Chemical Research. 40: 618-25. PMID 17518438 DOI: 10.1021/ar700043n  1
2006 Kieber-Emmons MT, Annaraj J, Seo MS, Van Heuvelen KM, Tosha T, Kitagawa T, Brunold TC, Nam W, Riordan CG. Identification of an "end-on" nickel-superoxo adduct, [Ni(tmc)(O2)]+. Journal of the American Chemical Society. 128: 14230-1. PMID 17076476 DOI: 10.1021/ja0644879  1
2005 Schenker R, Mock MT, Kieber-Emmons MT, Riordan CG, Brunold TC. Spectroscopic and computational studies on [Ni(tmc)CH3]OTf: implications for Ni-methyl bonding in the A cluster of acetyl-CoA synthase. Inorganic Chemistry. 44: 3605-17. PMID 15877445 DOI: 10.1021/ic0483996  1
2005 Schenker R, Kieber-Emmons MT, Riordan CG, Brunold TC. Spectroscopic and computational studies on the trans-mu-1,2-peroxo-bridged dinickel(II) species [{Ni(tmc)}2 (O2)](OTf)2: nature of end-on peroxo-nickel(II) bonding and comparison with peroxo-copper(II) bonding. Inorganic Chemistry. 44: 1752-62. PMID 15762702 DOI: 10.1021/ic048584j  1
2004 Kieber-Emmons MT, Schenker R, Yap GP, Brunold TC, Riordan CG. Spectroscopic elucidation of a peroxo Ni2(mu-O2) intermediate derived from a nickel(I) complex and dioxygen. Angewandte Chemie (International Ed. in English). 43: 6716-8. PMID 15558642 DOI: 10.1002/anie.200460747  1
2003 Hammes BS, Kieber-Emmons MT, Letizia JA, Shirin Z, Carrano CJ, Zakharov LN, Rheingold AL. Synthesis and characterization of several zinc(II) complexes containing the bulky heteroscorpionate ligand bis(5-tert-butyl-3-methylpyrazol-2-yl)acetate: Relevance to the resting states of the zinc(II) enzymes thermolysin and carboxypeptidase A Inorganica Chimica Acta. 346: 227-238. DOI: 10.1016/S0020-1693(02)01338-5  1
2002 Hammes BS, Kieber-Emmons MT, Sommer R, Rheingold AL. Modulating the reduction potential of mononuclear cobalt(II) complexes via selective deprotonation of tris[(2-benzimidazolyl)methyl]amine. Inorganic Chemistry. 41: 1351-3. PMID 11896700 DOI: 10.1021/ic0155885  1
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