Tom D Sheppard - Publications

Affiliations: 
2007- Chemistry University College London (UCL) 
Area:
Organic Chemistry
Website:
www.tomsheppard.info

65 high-probability publications. We are testing a new system for linking publications to authors. You can help! If you notice any inaccuracies, please sign in and mark papers as correct or incorrect matches. If you identify any major omissions or other inaccuracies in the publication list, please let us know.

Year Citation  Score
2021 Carter EM, Subrizi F, Ward JM, Sheppard TD, Hailes HC. Direct Conversion of Hydrazones to Amines using Transaminases. Chemcatchem. 13: 4520-4523. PMID 35874927 DOI: 10.1002/cctc.202101008  0.427
2021 Szpara R, Goyder A, Porter MJ, Hailes HC, Sheppard TD. Regioselective Dehydration of Sugar Thioacetals under Mild Conditions. Organic Letters. PMID 33729808 DOI: 10.1021/acs.orglett.1c00424  0.353
2020 Takeuchi K, Murata Y, Hirata G, Sheppard TD, Nishikata T. Hybrid Reaction Systems for the Synthesis of Alkylated Compounds Based upon Cu-Catalyzed Coupling of Radicals and Organometallic Species. Chemical Record (New York, N.Y.). 20: 403-412. PMID 31556485 DOI: 10.1002/tcr.201900053  0.397
2020 Nakashima Y, Hirata G, Sheppard TD, Nishikata T. The Mizoroki‐Heck Reaction with Internal Olefins: Reactivities and Stereoselectivities Asian Journal of Organic Chemistry. 9: 480-491. DOI: 10.1002/ajoc.201900741  0.386
2019 Laserna V, Porter MJ, Sheppard TD. Gold-Catalyzed Hydroamination of Propargylic Alcohols: Controlling Divergent Catalytic Reaction Pathways to Access 1,3-Aminoalcohols, 3-Hydroxyketones or 3-Aminoketones. The Journal of Organic Chemistry. PMID 31418573 DOI: 10.1021/Acs.Joc.9B00988  0.327
2019 Coomber CE, Laserna V, Martin LT, Smith PD, Hailes HC, Porter MJ, Sheppard TD. Catalytic direct amidations in tert-butyl acetate using B(OCHCF). Organic & Biomolecular Chemistry. PMID 31225568 DOI: 10.1039/C9Ob01012B  0.418
2019 Laserna V, Jeapes Rojas C, Sheppard TD. Gold-Catalyzed Hydrophenoxylation of Propargylic Alcohols and Amines: Synthesis of Phenyl Enol Ethers. Organic Letters. 21: 4443-4447. PMID 31184177 DOI: 10.1021/acs.orglett.9b01208  0.371
2019 Subrizi F, Benhamou L, Ward JM, Sheppard TD, Hailes HC. Aminopolyols from Carbohydrates: Amination of Sugars and Sugar-Derived Tetrahydrofurans with Transaminases. Angewandte Chemie (International Ed. in English). 58: 3854-3858. PMID 30690839 DOI: 10.1002/anie.201813712  0.384
2019 Benhamou L, Foster RW, Ward DP, Wheelhouse K, Sloan L, Tame CJ, Bučar D, Lye GJ, Hailes HC, Sheppard TD. Functionalised tetrahydrofuran fragments from carbohydrates or sugar beet pulp biomass Green Chemistry. 21: 2035-2042. DOI: 10.1039/C9Gc00448C  0.306
2018 Gibson SM, D'Oyley JM, Higham JI, Sanders K, Laserna V, Aliev AE, Sheppard TD. Dihalohydration of Alkynols: A Versatile Approach to Diverse Halogenated Molecules. European Journal of Organic Chemistry. 2018: 4018-4028. PMID 30147439 DOI: 10.1002/ejoc.201800668  0.332
2018 Arkhipenko S, Sabatini MT, Batsanov AS, Karaluka V, Sheppard TD, Rzepa HS, Whiting A. Mechanistic insights into boron-catalysed direct amidation reactions. Chemical Science. 9: 1058-1072. PMID 29675153 DOI: 10.1039/c7sc03595k  0.445
2017 Coomber CE, Benhamou L, Bučar DK, Smith PD, Porter MJ, Sheppard TD. Silver-Free Palladium-Catalyzed C(sp3)-H Arylation of Saturated Bicyclic Amine Scaffolds. The Journal of Organic Chemistry. PMID 29241011 DOI: 10.1021/Acs.Joc.7B02665  0.388
2017 Sabatini MT, Boulton LT, Sheppard TD. Borate esters: Simple catalysts for the sustainable synthesis of complex amides. Science Advances. 3: e1701028. PMID 28948222 DOI: 10.1126/sciadv.1701028  0.369
2017 Gibson SM, Macmillan D, Sheppard TD. Synthesis of Boronocysteine Synlett. 29: 314-317. DOI: 10.1055/S-0036-1591491  0.418
2016 Pennell MN, Kyle MP, Gibson SM, Male L, Turner PG, Grainger RS, Sheppard TD. Intercepting the Gold-Catalysed Meyer-Schuster Rearrangement by Controlled Protodemetallation: A Regioselective Hydration of Propargylic Alcohols. Advanced Synthesis & Catalysis. 358: 1519-1525. PMID 29200990 DOI: 10.1002/adsc.201600101  0.402
2016 Benhamou L, Walker DW, Bučar DK, Aliev AE, Sheppard TD. Synthesis of substituted benzooxaborinin-1-ols via palladium-catalysed cyclisation of alkenyl- and alkynyl-boronic acids. Organic & Biomolecular Chemistry. PMID 27506186 DOI: 10.1039/C6Ob01419D  0.509
2016 Lanigan RM, Karaluka V, Sabatini MT, Starkov P, Badland M, Boulton L, Sheppard TD. Direct amidation of unprotected amino acids using B(OCH2CF3)3. Chemical Communications (Cambridge, England). 52: 8846-9. PMID 27346362 DOI: 10.1039/c6cc05147b  0.345
2016 Pennell MN, Kyle MP, Gibson SM, Male L, Turner PG, Grainger RS, Sheppard TD. Intercepting the Gold-Catalysed Meyer-Schuster Rearrangement by Controlled Protodemetallation: A Regioselective Hydration of Propargylic Alcohols Advanced Synthesis and Catalysis. 358: 1519-1525. DOI: 10.1002/adsc.201600101  0.412
2015 Barreiro E, Sanz-Vidal A, Tan E, Lau SH, Sheppard TD, Díez-González S. HBF4-Catalysed Nucleophilic Substitutions of Propargylic Alcohols. European Journal of Organic Chemistry. 2015: 7544-7549. PMID 26693210 DOI: 10.1002/ejoc.201501249  0.663
2015 Karaluka V, Lanigan RM, Murray PM, Badland M, Sheppard TD. B(OCH2CF3)3-mediated direct amidation of pharmaceutically relevant building blocks in cyclopentyl methyl ether. Organic & Biomolecular Chemistry. 13: 10888-94. PMID 26366853 DOI: 10.1039/c5ob01801c  0.448
2015 Gibson SM, Lanigan RM, Benhamou L, Aliev AE, Sheppard TD. A lactate-derived chiral aldehyde for determining the enantiopurity of enantioenriched primary amines. Organic & Biomolecular Chemistry. 13: 9050-4. PMID 26219531 DOI: 10.1039/c5ob01398d  0.352
2015 Foster RW, Benhamou L, Porter MJ, Bu?ar DK, Hailes HC, Tame CJ, Sheppard TD. Irreversible endo-selective diels-alder reactions of substituted alkoxyfurans: a general synthesis of endo-cantharimides. Chemistry (Weinheim An Der Bergstrasse, Germany). 21: 6107-14. PMID 25756502 DOI: 10.1002/Chem.201406286  0.432
2015 Gibson SM, Lanigan RM, Benhamou L, Aliev AE, Sheppard TD. A lactate-derived chiral aldehyde for determining the enantiopurity of enantioenriched primary amines Organic and Biomolecular Chemistry. 13: 9050-9054. DOI: 10.1039/c5ob01398d  0.357
2014 Dhankher P, Benhamou L, Sheppard TD. Rapid assembly of functionalised spirocyclic indolines by palladium-catalysed dearomatising diallylation of indoles with allyl acetate. Chemistry (Weinheim An Der Bergstrasse, Germany). 20: 13375-81. PMID 25171550 DOI: 10.1002/chem.201403940  0.511
2014 D'Oyley JM, Aliev AE, Sheppard TD. Regioselective dihalohydration reactions of propargylic alcohols: gold-catalyzed and noncatalyzed reactions. Angewandte Chemie (International Ed. in English). 53: 10747-50. PMID 25147077 DOI: 10.1002/anie.201405348  0.396
2014 Dhankher P, Sheppard TD. ChemInform Abstract: A Convenient Synthesis of Tri- and Tetramethylbenzaldehydes from Readily Available Phenols. Cheminform. 45: no-no. DOI: 10.1002/CHIN.201430079  0.337
2014 Lanigan RM, Sheppard TD. ChemInform Abstract: Recent Developments in Amide Synthesis: Direct Amidation of Carboxylic Acids and Transamidation Reactions Cheminform. 45: no-no. DOI: 10.1002/CHIN.201406249  0.492
2013 Foster RW, Tame CJ, Hailes HC, Sheppard TD. Highly Regioselective Synthesis of Substituted Isoindolinones via Ruthenium-Catalyzed Alkyne Cyclotrimerizations. Advanced Synthesis & Catalysis. 355: 2353-2360. PMID 24124414 DOI: 10.1002/adsc.201300055  0.416
2013 Ishikawa S, Sheppard TD, D'Oyley JM, Kamimura A, Motherwell WB. A rapid route to aminocyclopropanes via carbamatoorganozinc carbenoids. Angewandte Chemie (International Ed. in English). 52: 10060-3. PMID 23913871 DOI: 10.1002/Anie.201304720  0.579
2013 Lanigan RM, Starkov P, Sheppard TD. Direct synthesis of amides from carboxylic acids and amines using B(OCH2CF3)3. The Journal of Organic Chemistry. 78: 4512-23. PMID 23586467 DOI: 10.1021/jo400509n  0.372
2013 Sheppard T, Dhankher P. A Convenient Synthesis of Tri- and Tetramethylbenzaldehydes from Readily Available Phenols Synlett. 25: 381-384. DOI: 10.1055/S-0033-1340302  0.34
2013 Lanigan RM, Sheppard TD. Recent Developments in Amide Synthesis: Direct Amidation of Carboxylic Acids and Transamidation Reactions European Journal of Organic Chemistry. 2013: 7453-7465. DOI: 10.1002/EJOC.201300573  0.488
2013 Sheppard TD. ChemInform Abstract: Complexity-Generating Hydration Reactions via Gold-Catalyzed Addition of Boronic Acids to Alkynes Cheminform. 44: no-no. DOI: 10.1002/CHIN.201343256  0.422
2013 Lanigan RM, Starkov P, Sheppard TD. ChemInform Abstract: Direct Synthesis of Amides from Carboxylic Acids and Amines Using B(OCH2CF3)3. Cheminform. 44: no-no. DOI: 10.1002/CHIN.201336039  0.34
2013 Starkov P, Rota F, D'Oyley JM, Sheppard TD. ChemInform Abstract: Catalytic Electrophilic Halogenation of Silyl-Protected and Terminal Alkynes: Trapping Gold(I) Acetylides vs. a Broensted Acid-Promoted Reaction. Cheminform. 44: no-no. DOI: 10.1002/CHIN.201319053  0.44
2012 Pennell MN, Turner PG, Sheppard TD. Gold- and silver-catalyzed reactions of propargylic alcohols in the presence of protic additives. Chemistry (Weinheim An Der Bergstrasse, Germany). 18: 4748-58. PMID 22374879 DOI: 10.1002/chem.201102830  0.352
2012 Bachman M, Mann SE, Sheppard TD. Rapid synthesis of highly functionalised α-amino amides and medium ring lactones using multicomponent reactions of amino alcohols and isocyanides. Organic & Biomolecular Chemistry. 10: 162-70. PMID 22076284 DOI: 10.1039/c1ob06534c  0.449
2012 Sheppard TD. Complexity-generating hydration reactions via gold-catalyzed addition of boronic acids to alkynes Pure and Applied Chemistry. 84: 2431-2441. DOI: 10.1351/PAC-CON-12-01-08  0.497
2012 Sheppard TD, Snaddon TN. Highlights from the 47th EUCHEM conference on stereochemistry, Bürgenstock, Switzerland, May 2012 Chemical Communications. 48: 11597-11600. DOI: 10.1039/C2Cc90366K  0.585
2012 Starkov P, Rota F, D'Oyley JM, Sheppard TD. Catalytic Electrophilic Halogenation of Silyl-Protected and Terminal Alkynes: Trapping Gold(I) Acetylidesvs. a Brønsted Acid-Promoted Reaction Advanced Synthesis & Catalysis. 354: 3217-3224. DOI: 10.1002/ADSC.201200491  0.437
2011 Starkov P, Sheppard TD. Borate esters as convenient reagents for direct amidation of carboxylic acids and transamidation of primary amides. Organic & Biomolecular Chemistry. 9: 1320-3. PMID 21212879 DOI: 10.1039/c0ob01069c  0.38
2010 Körner C, Starkov P, Sheppard TD. An alternative approach to aldol reactions: gold-catalyzed formation of boron enolates from alkynes. Journal of the American Chemical Society. 132: 5968-9. PMID 20380452 DOI: 10.1021/ja102129c  0.495
2010 Waller RW, Diorazio LJ, Taylor BA, Motherwell WB, Sheppard TD. Isocyanide based multicomponent reactions of oxazolidines and related systems Tetrahedron. 66: 6496-6507. DOI: 10.1016/J.Tet.2010.05.083  0.648
2010 Dixon DJ, Ley SV, Polara A, Sheppard T. ChemInform Abstract: Highly Diastereoselective Lithium Enolate Aldol Reactions of Butane-2,3-diacetal Desymmetrized Glycolic Acid and Deprotection to Enantiopure anti-2,3-Dihydroxy Esters. Cheminform. 33: no-no. DOI: 10.1002/chin.200217143  0.692
2009 Sheppard TD. Metal-catalysed halogen exchange reactions of aryl halides. Organic & Biomolecular Chemistry. 7: 1043-52. PMID 19262919 DOI: 10.1039/b818155a  0.374
2009 Jerome L, Sheppard TD, Aliev AE, Motherwell WB. Intramolecular amidocyclopropanation reactions using diethoxymethyl-functionalised lactams as organozinc carbenoid precursors Tetrahedron Letters. 50: 3709-3712. DOI: 10.1016/J.Tetlet.2009.03.224  0.607
2009 Bégis G, Cladingboel DE, Jerome L, Motherwell WB, Sheppard TD. Asymmetric synthesis of amlnocyclopropanes and N-cyclopropylamino alcohols through direct amidocyclopropanation of alkenes using chiral organozinc carbenoids European Journal of Organic Chemistry. 1532-1548. DOI: 10.1002/Ejoc.200801033  0.641
2009 Jerome L, Sheppard TD, Aliev AE, Motherwell WB. ChemInform Abstract: Intramolecular Amidocyclopropanation Reactions Using Diethoxymethyl-Functionalized Lactams as Organozinc Carbenoid Precursors. Cheminform. 40. DOI: 10.1002/CHIN.200941161  0.384
2009 Begis G, Cladingboel DE, Jerome L, Motherwell WB, Sheppard TD. ChemInform Abstract: Asymmetric Synthesis of Aminocyclopropanes and N-Cyclopropylamino Alcohols Through Direct Amidocyclopropanation of Alkenes Using Chiral Organozinc Carbenoids. Cheminform. 40. DOI: 10.1002/CHIN.200929053  0.3
2008 Gray PJ, Motherwell WB, Sheppard TD, Whitehead AJ. Observations on the synthesis and carbocyclisation reactions of 6-oxohexa-2,3-dienoates Synlett. 2097-2100. DOI: 10.1055/S-2008-1078028  0.639
2008 Gray PJ, Motherwell WB, Sheppard TD, Whitehead AJ. ChemInform Abstract: Observations on the Synthesis and Carbocyclization Reactions of 6-Oxohexa-2,3-dienoates. Cheminform. 39. DOI: 10.1002/CHIN.200852058  0.44
2007 Ley SV, Sheppard TD, Myers RM, Chorghade MS. Chiral glycolate equivalents for the asymmetric synthesis of α-hydroxycarbonyl compounds Bulletin of the Chemical Society of Japan. 80: 1451-1472. DOI: 10.1246/Bcsj.80.1451  0.725
2007 Motherwell WB, Bégis G, Cladingboel DE, Jerome L, Sheppard TD. Direct Amidocyclopropanation of Alkenes Using Organozinc Carbenoids Synfacts. 2007: 861-861. DOI: 10.1055/S-2007-968739  0.478
2007 Ramos SS, Almeida P, Santos L, Motherwell WB, Sheppard TD, Costa MdC. Functionalisation of terpenoids at C-4 via organopalladium dimers: cyclopropane formation during oxidation of homoallylic σ-organopalladium intermediates with lead tetraacetate Tetrahedron. 63: 12608-12615. DOI: 10.1016/J.Tet.2007.10.016  0.549
2007 Motherwell WB, Bégis G, Cladingboel DE, Jerome L, Sheppard TD. Observations on the direct amidocyclopropanation of alkenes using organozinc carbenoids Tetrahedron. 63: 6462-6476. DOI: 10.1016/J.Tet.2007.03.027  0.624
2007 Ley SV, Sheppard TD, Myers RM, Chorghade MS. Chiral Glycolate Equivalents for the Asymmetric Synthesis of α-Hydroxycarbonyl Compounds. Cheminform. 38. DOI: 10.1002/CHIN.200744250  0.671
2006 Diorazio LJ, Motherwell WB, Sheppard TD, Waller RW. Observations on the reaction of N-alkyloxazolidines, isocyanides and carboxylic acids: A novel three-component reaction leading to N-acyloxyethylamino acid amides Synlett. 2281-2283. DOI: 10.1055/S-2006-950413  0.629
2006 Diorazio LJ, Motherwell WB, Sheppard TD, Waller RW. Observations on the Reaction of N-Alkyloxazolidines, Isocyanides and Carboxylic Acids: A Novel Three-Component Reaction Leading to N-Acyloxyethylamino Acid Amides. Cheminform. 37. DOI: 10.1002/CHIN.200652081  0.403
2006 Begis G, Sheppard TD, Cladingboel DE, Motherwell WB, Tocher DA. Synthesis of Enantiopure Aminocyclopropanes by Diastereoselective Addition of a Chiral Amino Substituted Organozinc Carbenoid to Alkenes. Cheminform. 37. DOI: 10.1002/CHIN.200616077  0.428
2005 Ley SV, Dixon DJ, Guy RT, Rodríguez F, Sheppard TD. Michael, Michael-aldol and Michael-Michael reactions of enolate equivalents of butane-2,3-diacetal protected glycolic acid derivatives. Organic & Biomolecular Chemistry. 3: 4095-107. PMID 16267589 DOI: 10.1039/B512410G  0.699
2005 Bégis G, Sheppard TD, Cladingboel DE, Motherwell WB, Tocher DA. Synthesis of enantiopure aminocyclopropanes by diastereoselective addition of a chiral amino substituted organozinc carbenoid to alkenes Synthesis. 3186-3188. DOI: 10.1055/S-2005-918469  0.602
2005 Dixon DJ, Ley SV, Lohmann S, Sheppard TD. Synthesis of a ceramide sphingolipid as a potential sex pheromone of the hair crab Erimacrus isenbeckii using butane-2,3-diacetal desymmetrised glycolic acid building blocks Synlett. 481-484. DOI: 10.1055/S-2005-862361  0.663
2004 Ley SV, Dixon DJ, Guy RT, Palomero MA, Polara A, Rodriguez F, Sheppard TD. Studies on the generation of enolate anions from butane-2,3-diacetal protected glycolic acid derivatives and subsequent highly diastereoselective coupling reactions with aldehydes and acid chlorides. Organic & Biomolecular Chemistry. 2: 3618-27. PMID 15592620 DOI: 10.1039/B412790K  0.684
2004 Ley SV, Diez E, Dixon DJ, Guy RT, Michel P, Nattrass GL, Sheppard TD. Preparation of enantiopure butane-2,3-diacetals of glycolic acid and alkylation reactions leading to alpha-hydroxyacid and amide derivatives. Organic & Biomolecular Chemistry. 2: 3608-17. PMID 15592619 DOI: 10.1039/B412788A  0.597
2002 Dixon DJ, Ley SV, Polara A, Sheppard T. Highly diastereoselective lithium enolate aldol reactions of butane-2,3-diacetal desymmetrized glycolic acid and deprotection to enantiopure anti-2,3-dihydroxy esters. Organic Letters. 3: 3749-52. PMID 11700129 DOI: 10.1021/Ol016707N  0.707
Show low-probability matches.