Armin R. Ofial - Publications

Affiliations: 
1992-1996 physical organic chemistry Technische Universität Darmstadt 

53 high-probability publications. We are testing a new system for linking publications to authors. You can help! If you notice any inaccuracies, please sign in and mark papers as correct or incorrect matches. If you identify any major omissions or other inaccuracies in the publication list, please let us know.

Year Citation  Score
2023 Sun Q, Eitzinger A, Esken R, Antoni PW, Mayer RJ, Ofial AR, Hansmann MM. Pyridinium-Derived Mesoionic N-Heterocyclic Olefins (py-mNHOs). Angewandte Chemie (International Ed. in English). e202318283. PMID 38153170 DOI: 10.1002/anie.202318283  0.345
2023 Hensinger MJ, Eitzinger A, Trapp O, Ofial AR. Nucleophilicity of 4-(Alkylthio)-3-imidazoline Derived Enamines. Chemistry (Weinheim An Der Bergstrasse, Germany). e202302764. PMID 37850416 DOI: 10.1002/chem.202302764  0.453
2023 Eitzinger A, Reitz J, Antoni PW, Mayr H, Ofial AR, Hansmann MM. Pushing the Upper Limit of Nucleophilicity Scales by Mesoionic N-Heterocyclic Olefins. Angewandte Chemie (International Ed. in English). e202309790. PMID 37540606 DOI: 10.1002/anie.202309790  0.732
2023 Hensinger MJ, Closs AC, Trapp O, Ofial AR. The effect of -alkylation on organocatalytic enamine activation through imidazolidine-4-thiones. Chemical Communications (Cambridge, England). 59: 8091-8094. PMID 37293771 DOI: 10.1039/d3cc01912h  0.304
2023 Eitzinger A, Ofial AR. Reactivity of electrophilic cyclopropanes. Pure and Applied Chemistry. Chimie Pure Et Appliquee. 95: 389-400. PMID 37252340 DOI: 10.1515/pac-2023-0209  0.404
2023 Li L, Mayer RJ, Ofial AR, Mayr H. One-Bond-Nucleophilicity and -Electrophilicity Parameters: An Efficient Ordering System for 1,3-Dipolar Cycloadditions. Journal of the American Chemical Society. PMID 36952671 DOI: 10.1021/jacs.2c13872  0.786
2022 Li L, Mayer RJ, Stephenson DS, Mayer P, Ofial AR, Mayr H. Quantification of the Electrophilicities of Diazoalkanes: Kinetics and Mechanism of Azo Couplings with Enamines and Sulfonium Ylides. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 35758555 DOI: 10.1002/chem.202201376  0.819
2022 Macchia A, Summa FF, Monaco G, Eitzinger A, Ofial AR, Di Mola A, Massa A. Access to β-Alkylated γ-Functionalized Ketones via Conjugate Additions to Arylideneisoxazol-5-ones and Mo(CO)-Mediated Reductive Cascade Reactions. Acs Omega. 7: 8808-8818. PMID 35309475 DOI: 10.1021/acsomega.1c07081  0.39
2022 Traube FR, Brás NF, Roos WP, Sommermann CC, Diehl T, Mayer RJ, Ofial AR, Müller M, Zipse H, Carell T. Epigenetic Anti-Cancer Treatment With a Stabilized Carbocyclic Decitabine Analogue. Chemistry (Weinheim An Der Bergstrasse, Germany). e202200640. PMID 35285586 DOI: 10.1002/chem.202200640  0.599
2022 An F, Jangra H, Wei Y, Shi M, Zipse H, Ofial AR. Reactivities of allenic and olefinic Michael acceptors towards phosphines. Chemical Communications (Cambridge, England). PMID 35188503 DOI: 10.1039/d1cc06786a  0.398
2022 Li L, Mayer P, Stephenson DS, Ofial AR, Mayer RJ, Mayr H. An Overlooked Pathway in 1,3-Dipolar Cycloadditions of Diazoalkanes with Enamines. Angewandte Chemie (International Ed. in English). PMID 35023245 DOI: 10.1002/anie.202117047  0.781
2021 Macchia A, Summa FF, Di Mola A, Tedesco C, Pierri G, Ofial AR, Monaco G, Massa A. Base-Promoted Cascade Reactions for the Synthesis of 3,3-Dialkylated Isoindolin-1-ones and 3-Methyleneisoindolin-1-ones. The Journal of Organic Chemistry. 86: 15128-15138. PMID 34613731 DOI: 10.1021/acs.joc.1c01794  0.347
2021 Jüstel PM, Stan A, Pignot CD, Ofial AR. Inherent Reactivity of Spiro-Activated Electrophilic Cyclopropanes. Chemistry (Weinheim An Der Bergstrasse, Germany). 27: 15928-15935. PMID 34569669 DOI: 10.1002/chem.202103027  0.431
2021 Mayer RJ, Allihn PWA, Hampel N, Mayer P, Sieber SA, Ofial AR. Electrophilic reactivities of cyclic enones and α,β-unsaturated lactones. Chemical Science. 12: 4850-4865. PMID 34163736 DOI: 10.1039/d0sc06628a  0.705
2021 Maji B, Duan XH, Jüstel PM, Byrne PA, Ofial AR, Mayr H. Nucleophilicities and Nucleofugalities of Thio- and Selenoethers. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 34002899 DOI: 10.1002/chem.202100977  0.772
2021 Jüstel PM, Pignot CD, Ofial AR. Nucleophilic Reactivities of Thiophenolates. The Journal of Organic Chemistry. 86: 5965-5972. PMID 33797263 DOI: 10.1021/acs.joc.1c00025  0.496
2020 Mayer RJ, Hampel N, Ofial AR. Lewis Acidic Boranes, Lewis Bases, and Equilibrium Constants: A Reliable Scaffold for a Quantitative Lewis Acidity/Basicity Scale. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 33215760 DOI: 10.1002/chem.202003916  0.681
2020 Li Z, Mayer RJ, Ofial AR, Mayr H. From Carbodiimides to Carbon Dioxide: Quantification of the Electrophilic Reactivities of Heteroallenes. Journal of the American Chemical Society. PMID 32338511 DOI: 10.1021/Jacs.0C01960  0.779
2020 Zhang J, Chen Q, Mayer RJ, Yang JD, Ofial AR, Cheng JP, Mayr H. Predicting Absolute Rate Constants for Huisgen Reactions of Unsaturated Iminium Ions with Diazoalkanes. Angewandte Chemie (International Ed. in English). PMID 32259362 DOI: 10.1002/Anie.202003029  0.823
2020 Mayer RJ, Ofial AR, Mayr H, Legault CY. Lewis Acidity Scale of Diaryliodonium Ions toward Oxygen, Nitrogen, and Halogen Lewis Bases. Journal of the American Chemical Society. 142: 5221-5233. PMID 32125154 DOI: 10.1021/Jacs.9B12998  0.776
2020 Eitzinger A, Mayer RJ, Hampel N, Mayer P, Waser M, Ofial AR. Electrophilic Reactivities of Vinyl -Quinone Methides. Organic Letters. PMID 32118449 DOI: 10.1021/Acs.Orglett.0C00338  0.748
2020 An F, Maji B, Min E, Ofial AR, Mayr H. Basicities and Nucleophilicities of Pyrrolidines and Imidazolidinones Used as Organocatalysts. Journal of the American Chemical Society. PMID 31913030 DOI: 10.1021/Jacs.9B11877  0.791
2019 Mayer RJ, Ofial AR. Nucleophilicity of Glutathione: A Link to Michael Acceptor Reactivities. Angewandte Chemie (International Ed. in English). PMID 31560405 DOI: 10.1002/anie.201909803  0.72
2019 Mayer RJ, Breugst M, Hampel N, Ofial AR, Mayr H. Ambident Reactivity of Phenolate Anions Revisited: A Quantitative Approach to Phenolate Reactivities. The Journal of Organic Chemistry. PMID 31241938 DOI: 10.1021/Acs.Joc.9B01485  0.81
2018 Jangra H, Chen Q, Fuks E, Zenz I, Mayer P, Ofial AR, Zipse H, Mayr H. Nucleophilicity and Electrophilicity Parameters for Predicting Absolute Rate Constants of Highly Asynchronous 1,3-Dipolar Cycloadditions of Aryldiazomethanes. Journal of the American Chemical Society. PMID 30444361 DOI: 10.1021/Jacs.8B09995  0.734
2018 Timofeeva DS, Ofial AR, Mayr H. Kinetics of Electrophilic Fluorinations of Enamines and Carbanions: Comparison of the Fluorinating Power of N-F Reagents. Journal of the American Chemical Society. PMID 30156412 DOI: 10.1021/Jacs.8B07147  0.737
2018 Mayer RJ, Ofial AR. Nucleophilic Reactivities of Bleach Reagents. Organic Letters. PMID 29741385 DOI: 10.1021/acs.orglett.8b00645  0.761
2018 Li Z, Jangra H, Chen Q, Mayer P, Ofial AR, Zipse H, Mayr H. Kinetics and Mechanism of Oxirane Formation by Darzens Condensation of Ketones: Quantification of the Electrophilicities of Ketones. Journal of the American Chemical Society. PMID 29659264 DOI: 10.1021/Jacs.8B01657  0.707
2018 Timofeeva DS, Mayer R, Mayer P, Ofial A, Mayr H. Which Factors Control the Nucleophilic Reactivities of Enamines? Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 29388720 DOI: 10.1002/Chem.201705962  0.775
2017 Allgäuer DS, Jangra H, Asahara H, Li Z, Chen Q, Zipse H, Ofial AR, Mayr H. Quantification and Theoretical Analysis of the Electrophilicities of Michael Acceptors. Journal of the American Chemical Society. PMID 28921959 DOI: 10.1021/Jacs.7B05106  0.738
2017 Mayer R, Tokuyasu T, Mayer P, Gomar J, Sabelle S, Mennucci B, Mayr H, Ofial AR. Solvation Accounts for the Counter-Intuitive Nucleophilicity Ordering of Peroxide Anions. Angewandte Chemie (International Ed. in English). PMID 28815833 DOI: 10.1002/Anie.201707086  0.83
2017 Follet E, Mayer P, Stephenson DS, Ofial AR, Berionni G. Reactivity-Tuning in Frustrated Lewis Pairs: Nucleophilicity and Lewis Basicity of Sterically Hindered Phosphines. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 28370848 DOI: 10.1002/Chem.201701080  0.709
2016 Chelli S, Troshin K, Mayer P, Lakhdar S, Ofial AR, Mayr H. Nucleophilicity Parameters of Stabilized Iodonium Ylides for Characterizing their Synthetic Potential. Journal of the American Chemical Society. PMID 27428876 DOI: 10.1021/Jacs.6B05768  0.822
2016 Mayr H, Ofial AR. Philicities, Fugalities, and Equilibrium Constants. Accounts of Chemical Research. PMID 27108991 DOI: 10.1021/Acs.Accounts.6B00071  0.714
2015 Berionni G, Leonov AI, Mayer P, Ofial AR, Mayr H. Fine-tuning the nucleophilic reactivities of boron ate complexes derived from aryl and heteroaryl boronic esters. Angewandte Chemie (International Ed. in English). 54: 2780-3. PMID 25604646 DOI: 10.1002/Anie.201410562  0.797
2015 Mayr H, Ammer J, Baidya M, Maji B, Nigst TA, Ofial AR, Singer T. Scales of Lewis basicities toward C-centered Lewis acids (carbocations). Journal of the American Chemical Society. 137: 2580-99. PMID 25555037 DOI: 10.1021/Ja511639B  0.763
2014 Erdmann H, An F, Mayer P, Ofial AR, Lakhdar S, Mayr H. Structures and reactivities of 2-Trityl- and 2-(Triphenylsilyl)pyrrolidine-derived enamines: evidence for negative hyperconjugation with the trityl group. Journal of the American Chemical Society. 136: 14263-9. PMID 25220171 DOI: 10.1021/Ja508065E  0.718
2014 Chen X, Tan Y, Berionni G, Ofial AR, Mayr H. Di- and triarylmethylium ions as probes for the ambident reactivities of carbanions derived from 5-benzylated Meldrum's acid. Chemistry (Weinheim An Der Bergstrasse, Germany). 20: 11069-77. PMID 25099696 DOI: 10.1002/Chem.201403161  0.811
2013 Horn M, Schappele LH, Lang-Wittkowski G, Mayr H, Ofial AR. Towards a comprehensive hydride donor ability scale. Chemistry (Weinheim An Der Bergstrasse, Germany). 19: 249-63. PMID 23203839 DOI: 10.1002/Chem.201202839  0.671
2012 Mayr H, Lakhdar S, Maji B, Ofial AR. A quantitative approach to nucleophilic organocatalysis. Beilstein Journal of Organic Chemistry. 8: 1458-78. PMID 23019481 DOI: 10.3762/Bjoc.8.166  0.846
2011 Mayr H, Breugst M, Ofial AR. Farewell to the HSAB treatment of ambident reactivity. Angewandte Chemie (International Ed. in English). 50: 6470-505. PMID 21726020 DOI: 10.1002/Anie.201007100  0.578
2010 Kanzian T, Nicolini S, De Crescentini L, Attanasi OA, Ofial AR, Mayr H. Electrophilic reactivities of 1,2-diaza-1,3-dienes. Chemistry (Weinheim An Der Bergstrasse, Germany). 16: 12008-16. PMID 20836093 DOI: 10.1002/Chem.201000828  0.723
2009 Hampel N, Richter D, Ofial AR, Mayr H, Mayer P. 4-[4-(Dimethyl-amino)benzyl-idene]-2,6-dimethyl-cyclo-hexa-2,5-dienone. Acta Crystallographica. Section E, Structure Reports Online. 65: o2102. PMID 21577517 DOI: 10.1107/S1600536809030748  0.514
2009 Phan TB, Nolte C, Kobayashi S, Ofial AR, Mayr H. Can one predict changes from S(N)1 to S(N)2 mechanisms? Journal of the American Chemical Society. 131: 11392-401. PMID 19634906 DOI: 10.1021/Ja903207B  0.698
2007 Berger ST, Ofial AR, Mayr H. Inverse solvent effects in carbocation carbanion combination reactions: the unique behavior of trifluoromethylsulfonyl stabilized carbanions. Journal of the American Chemical Society. 129: 9753-61. PMID 17636911 DOI: 10.1021/Ja072135B  0.695
2007 Mayr H, Ofial AR. The reactivity-selectivity principle: an imperishable myth in organic chemistry. Angewandte Chemie (International Ed. in English). 45: 1844-54. PMID 16470749 DOI: 10.1002/Anie.200503273  0.505
2007 Denegri B, Ofial AR, Jurić S, Streiter A, Kronja O, Mayr H. How fast do R-X bonds ionize? A semiquantitative approach. Chemistry (Weinheim An Der Bergstrasse, Germany). 12: 1657-66. PMID 16331713 DOI: 10.1002/Chem.200500847  0.552
2007 Denegri B, Streiter A, Jurić S, Ofial AR, Kronja O, Mayr H. Kinetics of the solvolyses of benzhydryl derivatives: basis for the construction of a comprehensive nucleofugality scale. Chemistry (Weinheim An Der Bergstrasse, Germany). 12: 1648-56. PMID 16320366 DOI: 10.1002/Chem.200500845  0.632
2006 Lakhdar S, Westermaier M, Terrier F, Goumont R, Boubaker T, Ofial AR, Mayr H. Nucleophilic reactivities of indoles. The Journal of Organic Chemistry. 71: 9088-95. PMID 17109534 DOI: 10.1021/Jo0614339  0.789
2004 Ofial AR, Ohkubo K, Fukuzumi S, Lucius R, Mayr H. Role of electron-transfer processes in reactions of diarylcarbenium ions and related quinone methides with nucleophiles. Journal of the American Chemical Society. 125: 10906-12. PMID 12952471 DOI: 10.1021/Ja035191V  0.652
2003 Kempf B, Hampel N, Ofial AR, Mayr H. Structure-nucleophilicity relationships for enamines. Chemistry (Weinheim An Der Bergstrasse, Germany). 9: 2209-18. PMID 12772295 DOI: 10.1002/Chem.200204666  0.733
2003 Mayr H, Kempf B, Ofial AR. Pi-nucleophilicity in carbon-carbon bond-forming reactions. Accounts of Chemical Research. 36: 66-77. PMID 12534306 DOI: 10.1021/Ar020094C  0.696
2002 Mayr H, Lang G, Ofial AR. Reactions of carbocations with unsaturated hydrocarbons: electrophilic alkylation or hydride abstraction? Journal of the American Chemical Society. 124: 4076-83. PMID 11942846 DOI: 10.1021/Ja0121538  0.74
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