Claude Spino, Ph. D. - Publications

Affiliations: 
Chemistry Université de Sherbrooke, Sherbrooke, Québec, Canada 

70 high-probability publications. We are testing a new system for linking publications to authors. You can help! If you notice any inaccuracies, please sign in and mark papers as correct or incorrect matches. If you identify any major omissions or other inaccuracies in the publication list, please let us know.

Year Citation  Score
2019 Spino C, Aubert-Nicol S, Heinrich N, Lessard J. [Bis(trifluoroacetoxy)iodo]p-nitrobenzene and [Bis(trifluoroacetoxy)iodo]pentafluorobenzene as Lead Reagents for the Direct Ring Contraction of Lactams to Pyrrolidines Heterocycles. 99: 484. DOI: 10.3987/Com-18-S(F)43  0.394
2018 Croisetière JP, Spino C. O-Heterocycles from Unsaturated Carbonyls and Dimethoxycarbene. The Journal of Organic Chemistry. PMID 29682963 DOI: 10.1021/Acs.Joc.8B00613  0.314
2018 Aubert-Nicol S, Lessard J, Spino C. A Photorearrangement To Construct the ABDE Tetracyclic Core of Palau'amine. Organic Letters. PMID 29667828 DOI: 10.1021/Acs.Orglett.8B00819  0.404
2018 Gund M, Déry M, Spino C. Synthesis of carotol using a formal (4+1)-cycloaddition of chiral dialkoxycarbenes Canadian Journal of Chemistry. 96: 311-327. DOI: 10.1139/Cjc-2017-0594  0.45
2016 Gund M, Déry M, Amzallag V, Spino C. Dialkoxycarbenes in (4 + 1) Cycloadditions: Application to the Synthesis of Carotol. Organic Letters. PMID 27540758 DOI: 10.1021/Acs.Orglett.6B02023  0.475
2015 Déry M, Assouvie K, Heinrich N, Rajotte I, Lefebvre LP, Legault MA, Spino C. N-Heterocycles from chromium aminocarbenes. Organic Letters. 17: 1312-5. PMID 25702700 DOI: 10.1021/Acs.Orglett.5B00313  0.392
2014 Spino C. Modern Methods in Stereoselective Aldol Reactions. Edited by Rainer Mahrwald. Angewandte Chemie International Edition. 53: 5498-5498. DOI: 10.1002/Anie.201400982  0.355
2014 Spino C. Modern Methods in Stereoselective Aldol Reactions. Herausgegeben von Rainer Mahrwald. Angewandte Chemie. 126: 5602-5603. DOI: 10.1002/Ange.201400982  0.356
2013 Pichette S, Winter DK, Lessard J, Spino C. Converting cycloalkanones into N-heterocycles: formal synthesis of (-)-gephyrotoxin 287C. The Journal of Organic Chemistry. 78: 12532-44. PMID 24188015 DOI: 10.1021/Jo402217E  0.766
2013 Déry M, Lefebvre LP, Aissa K, Spino C. N-Heteropolycyclic compounds from the formal intramolecular (4 + 1)-cycloaddition of chromium aminocarbenes. Organic Letters. 15: 5456-9. PMID 24117372 DOI: 10.1021/Ol4025887  0.412
2012 Pichette S, Aubert-Nicol S, Lessard J, Spino C. Photochemical and thermal ring-contraction of cyclic hydroxamic acid derivatives. The Journal of Organic Chemistry. 77: 11216-26. PMID 23198744 DOI: 10.1021/Jo3023507  0.769
2012 Beaumier F, Dupuis M, Spino C, Legault CY. Formal intramolecular (4 + 1)-cycloaddition of dialkoxycarbenes: control of the stereoselectivity and a mechanistic portrait. Journal of the American Chemical Society. 134: 5938-53. PMID 22404454 DOI: 10.1021/Ja211927B  0.776
2012 Pichette S, Aubert-Nicol S, Lessard J, Spino C. Photochemical and thermal ring-contraction of cyclic hydroxamic acid derivatives Journal of Organic Chemistry. 77: 11216-11226. DOI: 10.1021/jo3023507  0.73
2012 Beaumier F, Dupuis M, Spino C, Legault CY. Formal intramolecular (4 + 1)-cycloaddition of dialkoxycarbenes: Control of the stereoselectivity and a mechanistic portrait Journal of the American Chemical Society. 134: 5938-5953. DOI: 10.1021/ja211927b  0.757
2012 Pichette S, Aubert-Nicol S, Lessard J, Spino C. Regioselective photochemical rearrangement of N-mesyloxylactams European Journal of Organic Chemistry. 1328-1335. DOI: 10.1002/Ejoc.201101222  0.727
2011 Spino C. Menthone and p-menthyl-3-carboxaldehyde as chiral auxiliaries. Chemical Communications (Cambridge, England). 47: 4872-83. PMID 21387050 DOI: 10.1039/C0Cc05543C  0.434
2011 Drouin A, Winter DK, Pichette S, Aubert-Nicol S, Lessard J, Spino C. Photochemical rearrangement of N-mesyloxylactams: stereospecific formation of N-heterocycles. The Journal of Organic Chemistry. 76: 164-9. PMID 21128634 DOI: 10.1021/Jo101805Q  0.769
2011 Spino C. Copper-Mediated Asymmetric Allylic Alkylations Patai's Chemistry of Functional Groups. DOI: 10.1002/9780470682531.Pat0446  0.389
2010 Winter DK, Drouin A, Lessard J, Spino C. Photochemical rearrangement of N-chlorolactams: a route to N-heterocycles through concerted ring contraction. The Journal of Organic Chemistry. 75: 2610-8. PMID 20230016 DOI: 10.1021/Jo100181H  0.411
2010 SPINO C, MAYES N, DESFOSSES H, SOTHEESWARAN S. ChemInform Abstract: Enantioselective Synthesis of (+)- and (-)-Dihydrokawain. Cheminform. 27: no-no. DOI: 10.1002/CHIN.199652267  0.329
2010 LAVALLEE J, SPINO C, RUEL R, HOGAN KT, DESLONGCHAMPS P. ChemInform Abstract: Stereoselective Synthesis of cis-Decalins via Diels-Alder and Double Michael Addition of Substituted Nazarov Reagents. Cheminform. 24: no-no. DOI: 10.1002/chin.199305158  0.313
2009 Gagnon D, Spino C. Stereoselective synthesis of (+)-aspidofractinine Journal of Organic Chemistry. 74: 6035-6041. PMID 19603751 DOI: 10.1021/Jo9009497  0.476
2009 Arbour M, Roy S, Godbout C, Spino C. Stereoselective synthesis of (+)-euphococcinine and (-)-adaline Journal of Organic Chemistry. 74: 3806-3814. PMID 19371091 DOI: 10.1021/Jo9001992  0.445
2008 Perreault S, Poirier M, Léveillé P, René O, Joly P, Dory Y, Spino C. Mechanism and regioselectivity of the cycloaddition of thiones derived from Meldrum's acid, malonates, or other dicarbonyls. The Journal of Organic Chemistry. 73: 7457-66. PMID 18771325 DOI: 10.1021/Jo800945Y  0.364
2008 Lauzon S, Tremblay F, Gagnon D, Godbout C, Chabot C, Mercier-Shanks C, Perreault S, DeSève H, Spino C. Sterically biased 3,3-sigmatropic rearrangement of chiral allylic azides: Application to the total syntheses of alkaloids Journal of Organic Chemistry. 73: 6239-6250. PMID 18642871 DOI: 10.1021/Jo800817P  0.491
2008 Lauzon S, Tremblay F, Gagnon D, Godbout C, Chabot C, Mercier-Shanks C, Perreault S, DeSeve H, Spino C. ChemInform Abstract: Sterically Biased 3,3-Sigmatropic Rearrangement of Chiral Allylic Azides: Application to the Total Syntheses of Alkaloids. Cheminform. 39. DOI: 10.1002/chin.200852060  0.319
2007 Boisvert L, Beaumier F, Spino C. Evidence for a concerted [4 + 1]- cycloaddition between electron-rich carbenes and electron-deficient dienes. Organic Letters. 9: 5361-3. PMID 18027955 DOI: 10.1021/Ol702172T  0.757
2007 Minville J, Girardin M, Spino C. Efficient preparation of chiral non-racemic sulfur compounds Canadian Journal of Chemistry. 85: 603-618. DOI: 10.1139/V07-091  0.424
2007 Boisvert L, Beaumier F, Spino C. Evidence for a concerted [4 + 1]-cycloaddition between electron-rich carbenes and electron-deficient dienes Organic Letters. 9: 5361-5363. DOI: 10.1021/ol702172t  0.736
2007 Spino C, Boisvert L, Douville J, Roy S, Lauzon S, Minville J, Gagnon D, Beaumier F, Chabot C. Cleavage of a Chiral Auxiliary Using RCM on an Especially Sterically Crowded Alkene: Syntheses of Chiral Carbo- and Heterocycles. Cheminform. 38. DOI: 10.1002/chin.200720044  0.324
2006 Perreault S, Spino C. Meldrum's acid-derived thione dienophile in a convergent and stereoselective synthesis of a tetracyclic quassinoid intermediate Organic Letters. 8: 4385-4388. PMID 16986906 DOI: 10.1021/Ol060892T  0.459
2006 Roy S, Spino C. Stereocontrolled formation of amino acids and N-heterocycles bearing a quaternary chiral carbon Organic Letters. 8: 939-942. PMID 16494479 DOI: 10.1021/Ol053061G  0.377
2006 Boisvert L, Beaumier F, Spino C. A chiral auxiliary cleavable by ring-closing alkene metathesis - Efficient synthesis of chiral nonracemic cycloalkenes Canadian Journal of Chemistry. 84: 1290-1293. DOI: 10.1139/V06-095  0.791
2006 Spino C, Boisvert L, Douville J, Roy S, Lauzon S, Minville J, Gagnon D, Beaumier F, Chabot C. Cleavage of a chiral auxiliary using RCM on an especially sterically crowded alkene: Syntheses of chiral carbo- and heterocycles Journal of Organometallic Chemistry. 691: 5336-5355. DOI: 10.1016/J.Jorganchem.2006.07.028  0.762
2005 Dion A, Dubé P, Spino C. A triple diene-transmissive Diels-Alder strategy to build the quassinoid framework Organic Letters. 7: 5601-5604. PMID 16321001 DOI: 10.1021/Ol0522236  0.442
2005 Gagnon D, Lauzon S, Godbout C, Spino C. Sterically biased 3,3-sigmatropic rearrangement of azides: efficient preparation of nonracemic alpha-amino acids and heterocycles. Organic Letters. 7: 4769-71. PMID 16209531 DOI: 10.1021/Ol052034N  0.376
2005 Spino C, Gund VG, Nadeau C. A chiral cyclohexanone linked to polystyrene for solid-phase synthesis of chiral α-carbonyls Journal of Combinatorial Chemistry. 7: 345-352. PMID 15762765 DOI: 10.1021/Cc049859T  0.389
2004 Spino C, Godbout C, Beaulieu C, Harter M, Mwene-Mbeja TM, Boisvert L. p-Menthane-3-carboxaldehyde: a useful chiral auxiliary for the synthesis of chiral quaternary carbons of high enantiomeric purity. Journal of the American Chemical Society. 126: 13312-9. PMID 15479086 DOI: 10.1021/Ja046084J  0.433
2004 Spino C, Rezaei H, Dupont-Gaudet K, Bélanger F. Inter- and intramolecular [4 + 1]-cycloadditions between electron-poor dienes and electron-rich carbenes. Journal of the American Chemical Society. 126: 9926-7. PMID 15303859 DOI: 10.1021/Ja046344X  0.405
2004 Spino C, Tremblay MC, Gobdout C. A stereodivergent approach to amino acids, amino alcohols, or oxazolidinones of high enantiomeric purity Organic Letters. 6: 2801-2804. PMID 15281773 DOI: 10.1021/Ol048936Q  0.303
2004 Spino C, Rezaei H, Dory YL. Characteristics of the two frontier orbital interactions in the Diels-Alder cycloaddition. The Journal of Organic Chemistry. 69: 757-64. PMID 14750802 DOI: 10.1021/Jo0353740  0.351
2004 Spino C, Allan M. An iterative approach to three fragments of ionomycin Canadian Journal of Chemistry. 82: 177-184. DOI: 10.1139/V03-182  0.382
2003 Spino C, Gobdout C. A stereodivergent approach to chiral nonracemic N-protected α,α-dialkylated amino acids Journal of the American Chemical Society. 125: 12106-12107. PMID 14518992 DOI: 10.1021/Ja037078A  0.35
2003 Spino C, Hill B, Dubé P, Gingras S. A diene-transmissive approach to the quassinoid skeleton Canadian Journal of Chemistry. 81: 81-108. DOI: 10.1139/V02-196  0.326
2003 Spino C. Chiral enolate equivalents. A review Organic Preparations and Procedures International. 35: 1-140. DOI: 10.1080/00304940309355794  0.335
2002 Spino C, Granger MC, Tremblay MC. Increased Felkin-Anh selectivity using AlMe(3) in the addition of vinyllithiums to alpha-chiral aldehydes: do "ate" complexes play any role? Organic Letters. 4: 4735-7. PMID 12489974 DOI: 10.1021/Ol027236N  0.333
2002 Spino C, Granger MC, Boisvert L, Beaulieu C. Increased Felkin-Anh selectivity in nucleophilic additions to α-chiral aldehydes using vinylalanes Tetrahedron Letters. 43: 4183-4185. DOI: 10.1016/S0040-4039(02)00753-0  0.408
2000 Spino C, Beaulieu C, Lafreniere J. Chiral alpha-substituted carbonyls and alcohols from the S(N)2' displacement of cuprates on chiral carbonates: An alternative to the alkylation of chiral enolates The Journal of Organic Chemistry. 65: 7091-7. PMID 11031033 DOI: 10.1021/Jo000810T  0.448
2000 Spino C, Beaulieu C. A Novel Method To Generate Chiral Quaternary Carbon Centers of High Enantiomeric Purity Using a Highly Stereoselective Addition of Vinylalanes to a Chiral Aldehyde We acknowledge the Natural Sciences and Engineering Council of Canada and Merck-Frosst for financial support. Angewandte Chemie (International Ed. in English). 39: 1930-1932. PMID 10940984 DOI: 10.1002/1521-3773(20000602)39:11<1930::Aid-Anie1930>3.0.Co;2-J  0.384
2000 Spino C, Frechette S. Synthesis of non-racemic unsymmetrical tetrasubstituted vinylallenes Tetrahedron Letters. 41: 8033-8036. DOI: 10.1016/S0040-4039(00)01406-4  0.448
1999 Spino C, Barriault N. Radical cyclization of polyenes initiated by attack of trialkyltin or germanium radical on an ynone Journal of Organic Chemistry. 64: 5292-5298. DOI: 10.1021/Jo9905524  0.34
1999 Beaulieu C, Spino C. Efficient syntheses of optically active 2-arylalkanoic acids Tetrahedron Letters. 40: 1637-1640. DOI: 10.1016/S0040-4039(99)00055-6  0.4
1998 Spino C, Crawford J, Cui Y, Gugelchuk M. The dimerisation of 2-methoxycarbonylbuta-1,3-diene: the importance of paralocalisation energy in assessing diene reactivity Journal of the Chemical Society-Perkin Transactions 1. 1499-1506. DOI: 10.1039/A708199E  0.314
1998 Spino C, Thibault C, Gingras S. Stereoselective Construction of Tetrasubstituted Exocyclic Alkenes from the [4 + 2]-Cycloaddition of Vinylallenes The Journal of Organic Chemistry. 63: 5283-5287. DOI: 10.1021/Jo980482L  0.405
1998 Spino C, Pesant M, Dory Y. Neues vom Diels-Alder-Übergangszustand Angewandte Chemie. 110: 3454-3457. DOI: 10.1002/(Sici)1521-3757(19981204)110:23<3454::Aid-Ange3454>3.0.Co;2-5  0.302
1997 Spino C, Clouston LL, Berg DJ. Lanthanide catalysts for the hetero Diels-Alder reaction: Effect of ligand structure and acidity Canadian Journal of Chemistry. 75: 1047-1054. DOI: 10.1139/V97-125  0.327
1996 Spino C, Clouston L, Berg D. Novel, air-stable, lanthanide catalysts for the hetero Diels-Alder reaction Canadian Journal of Chemistry. 74: 1762-1764. DOI: 10.1139/V96-195  0.307
1996 Spino C, Mayes N, Desfossés H. Enantioselective synthesis of (+)- and (-)-dihydrokawain Tetrahedron Letters. 37: 6503-6506. DOI: 10.1016/0040-4039(96)01429-3  0.361
1995 Spino C, Crawford J, Bishop J. Sequential Diels-Alder Reactions on a 1,3,7,9-Tetraene: An Efficient and Stereoselective Route to the Perhydrophenanthrene Skeleton Journal of Organic Chemistry. 60: 844-851. DOI: 10.1021/Jo00109A014  0.4
1995 Spino C, Lal J, Sotheeswaran S, Aalbersberg W. Three prenylated phenolic benzophenones from Garcinia myrtifolia Phytochemistry. 38: 233-236. DOI: 10.1016/0031-9422(94)00589-L  0.315
1994 Spino C, Liu G, Tu N, Girard S. The diene - transmissive [4 + 2]-cycloaddition strategy: Stereoselective synthesis of advanced intermediates to quassinoids Journal of Organic Chemistry. 59: 5596-5608. DOI: 10.1021/Jo00098A017  0.421
1994 Spino C, Crawford J. An expedient and stereoselective route to the perhydrophenanthrene skeleton via sequential Diels-Alder reactions Tetrahedron Letters. 35: 5559-5562. DOI: 10.1016/S0040-4039(00)77246-7  0.473
1994 Spino C, Tu N. Enantioselective synthesis of an advanced intermediate to quassinoids Tetrahedron Letters. 35: 3683-3686. DOI: 10.1016/S0040-4039(00)73071-1  0.379
1993 Alderdice M, Spino C, Weiler L. The synthesis of the isomeric components of San Jose scale pheromone - An illustration of a stereospecific synthesis of trisubstituted alkenes Canadian Journal of Chemistry. 71: 1955-1963. DOI: 10.1139/V93-242  0.689
1993 Spino C, Crawford J. 2-Carbomethoxy-1,3-butadiene: an electronically activated diene in [4 + 2] cycloadditions with electron-deficient dienophiles Canadian Journal of Chemistry. 71: 1094-1097. DOI: 10.1139/V93-145  0.392
1993 Spino C, Liu G. A stereoselective diene-transmissive [4 + 2]-cycloaddition strategy for the construction of the tetracyclic quassinoid framework Journal of Organic Chemistry. 58: 817-819. DOI: 10.1021/Jo00056A008  0.42
1992 Lavallée J, Spino C, Ruel R, Hogan KT, Deslongchamps P. Stereoselective synthesis of cis-decalins via Diels–Alder and double Michael addition of substituted Nazarov reagents Canadian Journal of Chemistry. 70: 1406-1426. DOI: 10.1139/V92-179  0.357
1990 Spino C, Deslongchamps P. Highly stereoselective double michael cyclization of 1-phenylsulfinyl and sulfonyl analogues of the nazarov reagent Tetrahedron Letters. 31: 3969-3972. DOI: 10.1016/S0040-4039(00)94474-5  0.432
1987 Spino C, Weiler L. A stereoselective synthesis of the tetrahydrofuran unit in ionomycin Tetrahedron Letters. 28: 731-734. DOI: 10.1016/S0040-4039(01)80974-6  0.638
1984 Alderdice M, Spino C, Weiler L. Synthesis of the three isomeric components of San Jose scale pheromone Tetrahedron Letters. 25: 1643-1646. DOI: 10.1016/S0040-4039(01)81133-3  0.607
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