Year |
Citation |
Score |
2023 |
Krämer T, Gyton MR, Bustos I, Sinclair MJG, Tan SY, Wedge CJ, Macgregor SA, Chaplin AB. Stability and C-H Bond Activation Reactions of Palladium(I) and Platinum(I) Metalloradicals: Carbon-to-Metal H-Atom Transfer and an Organometallic Radical Rebound Mechanism. Journal of the American Chemical Society. PMID 37318758 DOI: 10.1021/jacs.3c04167 |
0.408 |
|
2023 |
Emerson-King J, Chaplin AB. Template synthesis of an intermediate in silver salt metathesis using a calix[4]arene-based diphosphine ligand. Dalton Transactions (Cambridge, England : 2003). 52: 5044-5046. PMID 37066625 DOI: 10.1039/d3dt00567d |
0.325 |
|
2023 |
Emerson-King J, Pan S, Gyton MR, Tonner-Zech R, Chaplin AB. Synthesis of a rhodium(III) dinitrogen complex using a calix[4]arene-based diphosphine ligand. Chemical Communications (Cambridge, England). PMID 36727440 DOI: 10.1039/d2cc06837k |
0.303 |
|
2023 |
Poole EW, Bustos I, Hood TM, Smart JE, Chaplin AB. Iridium complexes of an -trifluoromethylphenyl substituted PONOP pincer ligand. Dalton Transactions (Cambridge, England : 2003). PMID 36602231 DOI: 10.1039/d2dt03608h |
0.406 |
|
2022 |
Longcake A, Lees MR, Senn MS, Chaplin AB. Oxidative Addition of C-Cl Bonds to a Rh(PONOP) Pincer Complex. Organometallics. 41: 3557-3567. PMID 36533115 DOI: 10.1021/acs.organomet.2c00400 |
0.382 |
|
2021 |
Hood TM, Chaplin AB. Synthesis and reactivity of iridium complexes of a macrocyclic PNP pincer ligand. Dalton Transactions (Cambridge, England : 2003). PMID 33511383 DOI: 10.1039/d0dt04303f |
0.483 |
|
2020 |
Kynman AE, Lau S, Dowd SO, Krämer T, Chaplin AB. Oxidative Addition of Biphenylene and Chlorobenzene to a Rh(CNC) Complex. European Journal of Inorganic Chemistry. 2020: 3899-3906. PMID 33328794 DOI: 10.1002/ejic.202000780 |
0.406 |
|
2020 |
Storey CM, Gyton MR, Andrew RE, Chaplin AB. Terminal alkyne coupling reactions through a ring: effect of ring size on rate and regioselectivity. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 32677713 DOI: 10.1002/chem.202002962 |
0.343 |
|
2020 |
Gyton MR, Kynman AE, Leforestier B, Gallo A, Lewandowski JR, Chaplin AB. Isolation and structural characterisation of rhodium(iii) η-fluoroarene complexes: experimental verification of predicted regioselectivity. Dalton Transactions (Cambridge, England : 2003). 49: 5791-5793. PMID 32314773 DOI: 10.1039/d0dt01137a |
0.309 |
|
2020 |
Leforestier B, Gyton MR, Chaplin AB. Synthesis and group 9 complexes of macrocyclic PCP and POCOP pincer ligands. Dalton Transactions (Cambridge, England : 2003). 49: 2087-2101. PMID 32031194 DOI: 10.1039/c9dt04835a |
0.318 |
|
2020 |
Hood TM, Gyton MR, Chaplin AB. Synthesis and rhodium complexes of macrocyclic PNP and PONOP pincer ligands. Dalton Transactions (Cambridge, England : 2003). 49: 2077-2086. PMID 31912067 DOI: 10.1039/c9dt04474d |
0.335 |
|
2019 |
Parker GL, Lau S, Leforestier B, Chaplin AB. Probing the Donor Properties of Pincer Ligands Using Rhodium Carbonyl Fragments: An Experimental and Computational Case Study. European Journal of Inorganic Chemistry. 2019: 3791-3798. PMID 31598095 DOI: 10.1002/ejic.201900727 |
0.328 |
|
2019 |
Hood TM, Leforestier B, Gyton MR, Chaplin AB. Synthesis and Structural Dynamics of Five-Coordinate Rh(III) and Ir(III) PNP and PONOP Pincer Complexes. Inorganic Chemistry. 58: 7593-7601. PMID 31117634 DOI: 10.1021/acs.inorgchem.9b00957 |
0.339 |
|
2019 |
Emerson-King J, Prokes I, Chaplin AB. Rhodium(III) Complexes Featuring Coordinated CF Appendages. Chemistry (Weinheim An Der Bergstrasse, Germany). 25: 6317-6319. PMID 30875135 DOI: 10.1002/chem.201901184 |
0.318 |
|
2019 |
Gyton MR, Hood TM, Chaplin AB. A convenient method for the generation of {Rh(PNP)} and {Rh(PONOP)} fragments: reversible formation of vinylidene derivatives. Dalton Transactions (Cambridge, England : 2003). 48: 2877-2880. PMID 30729961 DOI: 10.1039/c8dt05049j |
0.379 |
|
2018 |
Gyton MR, Leforestier B, Chaplin AB. Rhodium(III) and Iridium(III) Complexes of a NHC-Based Macrocycle: Persistent Weak Agostic Interactions and Reactions with Dihydrogen. Organometallics. 37: 3963-3971. PMID 30449914 DOI: 10.1021/acs.organomet.8b00595 |
0.41 |
|
2018 |
Knighton RC, Emerson-King J, Rourke JP, Ohlin CA, Chaplin AB. Solution, Solid-State, and Computational Analysis of Agostic Interactions in a Coherent Set of Low-Coordinate Rhodium(III) and Iridium(III) Complexes. Chemistry (Weinheim An Der Bergstrasse, Germany). 24: 4927-4938. PMID 29377308 DOI: 10.1002/chem.201705990 |
0.342 |
|
2018 |
Emerson-King J, Knighton RC, Gyton MR, Chaplin AB. Rotaxane synthesis exploiting the M(i)/M(iii) redox couple. Dalton Transactions (Cambridge, England : 2003). 46: 11645-11655. PMID 28835957 DOI: 10.1039/c7dt02648j |
0.362 |
|
2017 |
Patchett R, Knighton RC, Mattock JD, Vargas A, Chaplin AB. Potassium Binding Adjacent to Cationic Transition-Metal Fragments: Unusual Heterobimetallic Adducts of a Calix[4]arene-Based Thione Ligand. Inorganic Chemistry. PMID 29094927 DOI: 10.1021/acs.inorgchem.7b02441 |
0.349 |
|
2017 |
Hauser SA, Emerson-King J, Habershon S, Chaplin AB. UV-light promoted C-H bond activation of benzene and fluorobenzenes by an iridium(i) pincer complex. Chemical Communications (Cambridge, England). 53: 3634-3636. PMID 28304407 DOI: 10.1039/C6Cc09807J |
0.444 |
|
2017 |
Pike SD, Crimmin MR, Chaplin AB. Organometallic chemistry using partially fluorinated benzenes. Chemical Communications (Cambridge, England). 53: 3615-3633. PMID 28304406 DOI: 10.1039/c6cc09575e |
0.694 |
|
2016 |
Patchett R, Chaplin AB. Coordination chemistry of a calix[4]arene-based NHC ligand: dinuclear complexes and comparison to I(i)Pr2Me2. Dalton Transactions (Cambridge, England : 2003). 45: 8945-55. PMID 27160544 DOI: 10.1039/c6dt01001f |
0.37 |
|
2015 |
Hauser SA, Prokes I, Chaplin AB. Low-coordinate iridium NHC complexes derived from selective and reversible C-H bond activation of fluoroarenes. Chemical Communications (Cambridge, England). 51: 4425-8. PMID 25679455 DOI: 10.1039/c5cc00529a |
0.436 |
|
2014 |
Wheatley JE, Ohlin CA, Chaplin AB. Solvent promoted reversible cyclometalation in a tethered NHC iridium complex. Chemical Communications (Cambridge, England). 50: 685-7. PMID 24281774 DOI: 10.1039/c3cc48015a |
0.377 |
|
2013 |
Andrew RE, Chaplin AB. Synthesis, structure and dynamics of NHC-based palladium macrocycles. Dalton Transactions (Cambridge, England : 2003). 43: 1413-23. PMID 24201818 DOI: 10.1039/c3dt52578c |
0.376 |
|
2012 |
Chaplin AB, Hooper JF, Weller AS, Willis MC. Intermolecular hydroacylation: high activity rhodium catalysts containing small-bite-angle diphosphine ligands. Journal of the American Chemical Society. 134: 4885-97. PMID 22324763 DOI: 10.1021/Ja211649A |
0.636 |
|
2012 |
Hooper JF, Chaplin AB, González-RodrÃguez C, Thompson AL, Weller AS, Willis MC. Aryl methyl sulfides as substrates for rhodium-catalyzed alkyne carbothiolation: arene functionalization with activating group recycling. Journal of the American Chemical Society. 134: 2906-9. PMID 22296656 DOI: 10.1021/Ja2108992 |
0.476 |
|
2011 |
Chaplin AB, Weller AS. A rhodium(III) complex of the linear diborazine H3B·NMe2BH2·NMe2H: an intermediate in the dehydrocoupling of H3B·NMe2H. Acta Crystallographica. Section C, Crystal Structure Communications. 67: m355-8. PMID 22051952 DOI: 10.1107/S0108270111043447 |
0.659 |
|
2011 |
Chaplin AB, Green JC, Weller AS. C-C activation in the solid state in an organometallic σ-complex. Journal of the American Chemical Society. 133: 13162-8. PMID 21736363 DOI: 10.1021/Ja2047599 |
0.566 |
|
2011 |
Sewell LJ, Chaplin AB, Weller AS. Hydroboration of an alkene by amine-boranes catalysed by a [Rh(PR3)2]+ fragment. Mechanistic insight and tandem hydroboration/dehydrogenation. Dalton Transactions (Cambridge, England : 2003). 40: 7499-501. PMID 21713289 DOI: 10.1039/C1Dt10819K |
0.567 |
|
2011 |
Johnson HC, Robertson AP, Chaplin AB, Sewell LJ, Thompson AL, Haddow MF, Manners I, Weller AS. Catching the first oligomerization event in the catalytic formation of polyaminoboranes: H3B·NMeHBH2·NMeH2 bound to iridium. Journal of the American Chemical Society. 133: 11076-9. PMID 21699193 DOI: 10.1021/Ja2040738 |
0.621 |
|
2011 |
Dallanegra R, Pilgrim BS, Chaplin AB, Donohoe TJ, Weller AS. Dehydrogenation of cyclic thioethers bound to a [Rh(diphosphine)]+ fragment. Dalton Transactions (Cambridge, England : 2003). 40: 6626-8. PMID 21611674 DOI: 10.1039/C1Dt10503E |
0.574 |
|
2011 |
González-Rodríguez C, Pawley RJ, Chaplin AB, Thompson AL, Weller AS, Willis MC. Rhodium-catalyzed branched-selective alkyne hydroacylation: a ligand-controlled regioselectivity switch. Angewandte Chemie (International Ed. in English). 50: 5134-8. PMID 21506226 DOI: 10.1002/Anie.201100956 |
0.507 |
|
2011 |
Stevens CJ, Dallanegra R, Chaplin AB, Weller AS, Macgregor SA, Ward B, McKay D, Alcaraz G, Sabo-Etienne S. [Ir(PCy3)2(H)2(H2B-NMe2)]+ as a latent source of aminoborane: probing the role of metal in the dehydrocoupling of H3B⋅NMe2H and retrodimerisation of [H2BNMe2]2. Chemistry (Weinheim An Der Bergstrasse, Germany). 17: 3011-20. PMID 21322070 DOI: 10.1002/Chem.201002517 |
0.655 |
|
2011 |
Dallanegra R, Robertson AP, Chaplin AB, Manners I, Weller AS. Tuning the [L2Rh···H3B·NR3]+ interaction using phosphine bite angle. Demonstration by the catalytic formation of polyaminoboranes. Chemical Communications (Cambridge, England). 47: 3763-5. PMID 21293798 DOI: 10.1039/C0Cc05460G |
0.544 |
|
2010 |
Sparkes HA, Chaplin AB, Weller AS, Howard JA. Bond catastrophes in rhodium complexes: experimental charge-density studies of [Rh(C7H8)(P(t)Bu3)Cl] and [Rh(C7H8)(PCy3)Cl]. Acta Crystallographica. Section B, Structural Science. 66: 503-14. PMID 20841918 DOI: 10.1107/S0108768110031496 |
0.532 |
|
2010 |
Sewell LJ, Chaplin AB, Abdalla JA, Weller AS. Reversible C-H activation of a P(t)Bu(i)Bu2 ligand to reveal a masked 12 electron [Rh(PR3)2]+ cation. Dalton Transactions (Cambridge, England : 2003). 39: 7437-9. PMID 20623070 DOI: 10.1039/C0Dt00449A |
0.611 |
|
2010 |
Townsend NS, Chaplin AB, Abu Naser M, Thompson AL, Rees NH, Macgregor SA, Weller AS. Reactivity of the latent 12-electron fragment [Rh(PiBu3)2]+ with aryl bromides: aryl-Br and phosphine ligand C-H activation. Chemistry (Weinheim An Der Bergstrasse, Germany). 16: 8376-89. PMID 20572181 DOI: 10.1002/Chem.201000554 |
0.674 |
|
2010 |
Hiney RM, Chaplin AB, Harmer J, Green JC, Weller AS. Using EPR to follow reversible dihydrogen addition to paramagnetic clusters of high hydride count: [Rh(6)(PCy(3))(6)H(12)](+) and [Rh(6)(PCy(3))(6)H(14)](+). Dalton Transactions (Cambridge, England : 2003). 39: 1726-33. PMID 20449414 DOI: 10.1039/B919209C |
0.594 |
|
2010 |
Dallanegra R, Chaplin AB, Tsim J, Weller AS. Amino-borane oligomers bound to a Rh(I) metal fragment. Chemical Communications (Cambridge, England). 46: 3092-4. PMID 20424747 DOI: 10.1039/C003055D |
0.636 |
|
2010 |
Chaplin AB, Weller AS. Amine- and dimeric amino-borane complexes of the {Rh(P(i)Pr3)2}+ fragment and their relevance to the transition-metal-mediated dehydrocoupling of amine-boranes. Inorganic Chemistry. 49: 1111-21. PMID 20052982 DOI: 10.1021/Ic9020542 |
0.669 |
|
2010 |
Chaplin AB, Weller AS. B-H activation at a rhodium(I) center: isolation of a bimetallic complex relevant to the transition-metal-catalyzed dehydrocoupling of amine-boranes. Angewandte Chemie (International Ed. in English). 49: 581-4. PMID 19937888 DOI: 10.1002/Anie.200905185 |
0.589 |
|
2009 |
Douglas TM, Chaplin AB, Weller AS, Yang X, Hall MB. Monomeric and oligomeric amine-borane sigma-complexes of rhodium. intermediates in the catalytic dehydrogenation of amine-boranes. Journal of the American Chemical Society. 131: 15440-56. PMID 19785431 DOI: 10.1021/Ja906070R |
0.66 |
|
2009 |
Dallanegra R, Chaplin AB, Weller AS. Bis(sigma-amine-borane) complexes: an unusual binding mode at a transition-metal center. Angewandte Chemie (International Ed. in English). 48: 6875-8. PMID 19688804 DOI: 10.1002/Anie.200903121 |
0.565 |
|
2009 |
Chaplin AB, Poblador-Bahamonde AI, Sparkes HA, Howard JA, Macgregor SA, Weller AS. Alkyl dehydrogenation in a Rh(I) complex via an isolated agostic intermediate. Chemical Communications (Cambridge, England). 244-6. PMID 19099083 DOI: 10.1039/B816739G |
0.516 |
|
2008 |
Douglas TM, Chaplin AB, Weller AS. Amine-borane sigma-complexes of rhodium. relevance to the catalytic dehydrogenation of amine-boranes. Journal of the American Chemical Society. 130: 14432-3. PMID 18844358 DOI: 10.1021/Ja806582N |
0.553 |
|
2007 |
Chaplin AB, Dyson PJ. Reactivity and catalytic activity of a robust ruthenium(II)-triphos complex. Inorganic Chemistry. 47: 381-90. PMID 18044884 DOI: 10.1021/IC701773A |
0.372 |
|
2007 |
Scolaro C, Chaplin AB, Hartinger CG, Bergamo A, Cocchietto M, Keppler BK, Sava G, Dyson PJ. Tuning the hydrophobicity of ruthenium(II)-arene (RAPTA) drugs to modify uptake, biomolecular interactions and efficacy. Dalton Transactions (Cambridge, England : 2003). 5065-72. PMID 17992291 DOI: 10.1039/B705449A |
0.33 |
|
2004 |
Chaplin AB, Harrison JA, Nielson AJ, Shen C, Waters JM. A case for linear agostic interactions: identification by DFT calculation in a complex of Ta containing a uniquely caged triphenylmethyl C-H hydrogen. Dalton Transactions (Cambridge, England : 2003). 2643-8. PMID 15514746 DOI: 10.1039/b405918b |
0.375 |
|
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