A. Stephen K. Hashmi, Ph.D. - Publications

Affiliations: 
1991-1993 Stanford University, Palo Alto, CA 
 2007- Heidelberg University, Tiffin, OH, United States 
Website:
https://www.uni-heidelberg.de/institutions/rectorate/stephen_hashmi.html

138 high-probability publications. We are testing a new system for linking publications to authors. You can help! If you notice any inaccuracies, please sign in and mark papers as correct or incorrect matches. If you identify any major omissions or other inaccuracies in the publication list, please let us know.

Year Citation  Score
2017 Zeng Z, Jin H, Song X, Wang Q, Rudolph M, Rominger F, Hashmi AS. Gold-catalyzed intermolecular cyclocarboamination of ynamides with 1,3,5-triazinanes: en route to tetrahydropyrimidines. Chemical Communications (Cambridge, England). PMID 28288220 DOI: 10.1039/C7Cc00789B  0.422
2017 Wurm T, Hornung J, O'Neil M, Rudolph M, Rominger F, Hashmi AS. Synthesis of Ester- and Phosphonate-Functionalized Imidazolylidene Au(I) Chlorides via the Isonitrile Route. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 28236328 DOI: 10.1002/Chem.201700214  0.462
2017 Zeng Z, Jin H, Xie J, Tian B, Rudolph M, Rominger F, Hashmi AS. α-Imino Gold Carbenes from 1,2,4-Oxadiazoles: Atom-Economical Access to Fully Substituted 4-Aminoimidazoles. Organic Letters. PMID 28218539 DOI: 10.1021/Acs.Orglett.7B00001  0.411
2017 Wurm T, Bucher J, Duckworth SB, Rudolph M, Rominger F, Hashmi AS. On the Gold-Catalyzed Generation of Vinyl Cations from 1,5-Diynes. Angewandte Chemie (International Ed. in English). 56: 3364-3368. PMID 28194865 DOI: 10.1002/Anie.201700057  0.48
2016 Hossein Bagi A, Khaledi Y, Ghari H, Arndt S, Hashmi AS, Yates BF, Ariafard A. A Mechanistic Investigation of the Gold(III)-Catalyzed Hydrofurylation of C-C Multiple Bonds. Journal of the American Chemical Society. 138: 14599-14608. PMID 27750414 DOI: 10.1021/Jacs.6B05742  0.451
2016 Tšupova S, Hansmann MM, Rudolph M, Rominger F, Hashmi AS. New Pathways for the Dual Gold-Catalyzed Cyclization of Diynes. Chemistry (Weinheim An Der Bergstrasse, Germany). 22: 16286-16291. PMID 27689676 DOI: 10.1002/Chem.201602873  0.485
2016 Bürki C, Whyte A, Arndt S, Hashmi AS, Lautens M. Expanding the Scope of the Gold(I)-Catalyzed Rautenstrauch Rearrangement: Protic Additives. Organic Letters. PMID 27661092 DOI: 10.1021/Acs.Orglett.6B02505  0.575
2016 Jin MS, Tian MS, Song MS, Xie J, Rudolph M, Rominger F, Hashmi AS. Gold-Catalyzed Synthesis of Quinolines from Propargyl Silyl Ethers and Anthranils through the Umpolung of a Gold Carbene Carbon. Angewandte Chemie (International Ed. in English). PMID 27629266 DOI: 10.1002/Anie.201606043  0.462
2016 Wilkins LC, Lawson JR, Wieneke P, Rominger F, Hashmi AS, Hansmann MM, Melen RL. The Propargyl Rearrangement to Functionalised Allyl-Boron and Borocation Compounds. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 27538742 DOI: 10.1002/Chem.201602719  0.367
2016 Asiri AM, Hashmi AS. Gold-catalysed reactions of diynes. Chemical Society Reviews. PMID 27385433 DOI: 10.1039/C6Cs00023A  0.446
2016 Xie J, Yu J, Rudolph M, Rominger F, Hashmi AS. Monofluoroalkenylation of Dimethylamino Compounds through Radical-Radical Cross-Coupling. Angewandte Chemie (International Ed. in English). PMID 27351709 DOI: 10.1002/Anie.201602347  0.355
2016 Hashmi AS. Intermolecular Photocatalyzed Heck-like Coupling of Unactivated Alkyl Bromides by a Dinuclear Gold Complex. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 27348503 DOI: 10.1002/Chem.201602939  0.491
2016 Chen F, Hashmi AS. Silver-Catalyzed Decarboxylative Alkynylation of α,α-Difluoroarylacetic Acids with Ethynylbenziodoxolone Reagents. Organic Letters. PMID 27267868 DOI: 10.1021/Acs.Orglett.6B01188  0.324
2016 Huang L, Rominger F, Rudolph M, Hashmi AS. A general access to organogold(iii) complexes by oxidative addition of diazonium salts. Chemical Communications (Cambridge, England). PMID 27094217 DOI: 10.1039/C6Cc02199A  0.322
2016 Huang L, Rudolph M, Rominger F, Hashmi AS. Photosensitizer-Free Visible-Light-Mediated Gold-Catalyzed 1,2-Difunctionalization of Alkynes. Angewandte Chemie (International Ed. in English). PMID 26969831 DOI: 10.1002/Anie.201511487  0.509
2016 Xie J, Zhang T, Chen F, Mehrkens N, Rominger F, Rudolph M, Hashmi AS. Gold-Catalyzed Highly Selective Photoredox C(sp(2) )-H Difluoroalkylation and Perfluoroalkylation of Hydrazones. Angewandte Chemie (International Ed. in English). PMID 26800002 DOI: 10.1002/Anie.201508622  0.382
2015 Hashmi AS. Gold(I) vinylidene complexes as reactive intermediates and their tendency to π-backbond. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 26711532 DOI: 10.1002/Chem.201504511  0.378
2015 Pflästerer D, Hashmi AS. Gold catalysis in total synthesis - recent achievements. Chemical Society Reviews. PMID 26673389 DOI: 10.1039/C5Cs00721F  0.349
2015 Jin H, Huang L, Xie J, Rudolph M, Rominger F, Hashmi AS. Gold-Catalyzed CH Annulation of Anthranils with Alkynes: A Facile, Flexible, and Atom-Economical Synthesis of Unprotected 7-Acyl Indoles. Angewandte Chemie (International Ed. in English). PMID 26610069 DOI: 10.1002/Anie.201508309  0.468
2015 Hansmann MM, Melen RL, Rudolph M, Rominger F, Wadepohl H, Stephan DW, Hashmi AS. Cyclopropanation / Carboboration Reactions of Enynes with B(C6F5)3. Journal of the American Chemical Society. PMID 26580316 DOI: 10.1021/Jacs.5B09311  0.402
2015 Wilkins LC, Hamilton HB, Kariuki BM, Hashmi AS, Hansmann MM, Melen RL. Lewis acid-base 1,2-addition reactions: synthesis of pyrylium borates from en-ynoate precursors. Dalton Transactions (Cambridge, England : 2003). PMID 26435394 DOI: 10.1039/C5Dt03340C  0.422
2015 Rettenmeier E, Hansmann MM, Ahrens A, Rübenacker K, Saboo T, Massholder J, Meier C, Rudolph M, Rominger F, Hashmi AS. Insights into the Gold-Catalyzed Propargyl Ester Rearrangement/Tandem Cyclization Sequence: Radical versus Gold Catalysis-Myers-Saito- versus Schmittel-Type Cyclization. Chemistry (Weinheim An Der Bergstrasse, Germany). 21: 14401-9. PMID 26291466 DOI: 10.1002/Chem.201501725  0.479
2015 Larsen MH, Houk KN, Hashmi AS. Dual Gold Catalysis: Stepwise Catalyst Transfer via Dinuclear Clusters. Journal of the American Chemical Society. PMID 26258807 DOI: 10.1021/Jacs.5B05773  0.37
2015 Pflästerer D, Schumacher S, Rudolph M, Hashmi AS. Mechanistic Insights into the Post-Cyclization Isomerization in Gold-Catalyzed 7-exo-dig-Hydroarylations. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 26118364 DOI: 10.1002/Chem.201501075  0.472
2015 Zeiler A, Rudolph M, Rominger F, Hashmi AS. An Alternative Approach to PEPPSI Catalysts: From Palladium Isonitriles to Highly Active Unsymmetrically Substituted PEPPSI Catalysts. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 26096141 DOI: 10.1002/Chem.201500025  0.456
2015 Lothschütz C, Wurm T, Zeiler A, Freiherr V Falkenhausen A, Rudolph M, Rominger F, Hashmi AS. Facile Synthesis of Functionalized Carbene Metal Complexes from Coordinated Isonitriles. Chemistry, An Asian Journal. PMID 26033484 DOI: 10.1002/Asia.201500353  0.458
2015 Nunes Dos Santos Comprido L, Klein JE, Knizia G, Kästner J, Hashmi AS. The Stabilizing Effects in Gold Carbene Complexes. Angewandte Chemie (International Ed. in English). PMID 25951142 DOI: 10.1002/Anie.201412401  0.364
2015 Xie J, Shi S, Zhang T, Mehrkens N, Rudolph M, Hashmi AS. A Highly Efficient Gold-Catalyzed Photoredox α-C(sp(3))-H Alkynylation of Tertiary Aliphatic Amines with Sunlight. Angewandte Chemie (International Ed. in English). 54: 6046-50. PMID 25823756 DOI: 10.1002/Anie.201412399  0.366
2015 Mader S, Molinari L, Rudolph M, Rominger F, Hashmi AS. Dual gold-catalyzed head-to-tail coupling of iodoalkynes. Chemistry (Weinheim An Der Bergstrasse, Germany). 21: 3910-3. PMID 25620322 DOI: 10.1002/Chem.201406594  0.386
2015 Tokimizu Y, Wieteck M, Rudolph M, Oishi S, Fujii N, Hashmi AS, Ohno H. Dual gold catalysis: a novel synthesis of bicyclic and tricyclic pyrroles from N-propargyl ynamides. Organic Letters. 17: 604-7. PMID 25611870 DOI: 10.1021/Ol503623M  0.51
2015 Bucher J, Stößer T, Rudolph M, Rominger F, Hashmi AS. CO extrusion in homogeneous gold catalysis: reactivity of gold acyl species generated through water addition to gold vinylidenes. Angewandte Chemie (International Ed. in English). 54: 1666-70. PMID 25510651 DOI: 10.1002/Anie.201409859  0.433
2015 Blanco Jaimes MC, Ahrens A, Pflästerer D, Rudolph M, Hashmi AS. Synthesis of highly substituted γ-butyrolactones by a gold-catalyzed cascade reaction of benzyl esters. Chemistry (Weinheim An Der Bergstrasse, Germany). 21: 427-33. PMID 25352382 DOI: 10.1002/Chem.201402524  0.519
2014 Wieteck M, Tokimizu Y, Rudolph M, Rominger F, Ohno H, Fujii N, Hashmi AS. Dual gold catalysis: synthesis of polycyclic compounds via C-H insertion of gold vinylidenes. Chemistry (Weinheim An Der Bergstrasse, Germany). 20: 16331-6. PMID 25298270 DOI: 10.1002/Chem.201404987  0.374
2014 Wang T, Huang L, Shi S, Rudolph M, Hashmi AS. Synthesis of highly substituted N-(furan-3-ylmethylene)benzenesulfonamides by a gold(I)-catalyzed oxidation/1,2-alkynyl migration/cyclization cascade. Chemistry (Weinheim An Der Bergstrasse, Germany). 20: 14868-71. PMID 25236914 DOI: 10.1002/Chem.201404229  0.482
2014 Hansmann MM, Melen RL, Rominger F, Hashmi AS, Stephan DW. B(C₆F₅)₃ promoted cyclisation of internal propargyl esters: structural characterisation of 1,3-dioxolium compounds. Chemical Communications (Cambridge, England). 50: 7243-5. PMID 24817134 DOI: 10.1039/C4Cc01370K  0.327
2014 Pflästerer D, Rettenmeier E, Schneider S, de Las Heras Ruiz E, Rudolph M, Hashmi AS. Highly efficient gold-catalyzed synthesis of dibenzocycloheptatrienes. Chemistry (Weinheim An Der Bergstrasse, Germany). 20: 6752-5. PMID 24771698 DOI: 10.1002/Chem.201402015  0.464
2014 Manzano R, Wurm T, Rominger F, Hashmi AS. Room-temperature hydrohydrazination of terminal alkynes catalyzed by saturated abnormal N-heterocyclic carbene-gold(I) complexes. Chemistry (Weinheim An Der Bergstrasse, Germany). 20: 6844-8. PMID 24771293 DOI: 10.1002/Chem.201402560  0.459
2014 Blanco Jaimes MC, Rominger F, Pereira MM, Carrilho RM, Carabineiro SA, Hashmi AS. Highly active phosphite gold(I) catalysts for intramolecular hydroalkoxylation, enyne cyclization and furanyne cyclization. Chemical Communications (Cambridge, England). 50: 4937-40. PMID 24700111 DOI: 10.1039/C4Cc00839A  0.448
2014 Yang W, Hashmi AS. Mechanistic insights into the gold chemistry of allenes. Chemical Society Reviews. 43: 2941-55. PMID 24671183 DOI: 10.1039/C3Cs60441A  0.455
2014 Wang T, Shi S, Hansmann MM, Rettenmeier E, Rudolph M, Hashmi AS. Synthesis of highly substituted 3-formylfurans by a gold(I)-catalyzed oxidation/1,2-alkynyl migration/cyclization cascade. Angewandte Chemie (International Ed. in English). 53: 3715-9. PMID 24616030 DOI: 10.1002/Anie.201310146  0.475
2014 Bucher J, Wurm T, Nalivela KS, Rudolph M, Rominger F, Hashmi AS. Cyclization of gold acetylides: synthesis of vinyl sulfonates via gold vinylidene complexes. Angewandte Chemie (International Ed. in English). 53: 3854-8. PMID 24596326 DOI: 10.1002/Anie.201310280  0.481
2014 Yang W, Huang L, Yu Y, Pflästerer D, Rominger F, Hashmi AS. Highly diastereoselective and regioselective copper-catalyzed nitrosoformate dearomatization reaction under aerobic-oxidation conditions. Chemistry (Weinheim An Der Bergstrasse, Germany). 20: 3927-31. PMID 24590772 DOI: 10.1002/Chem.201400321  0.459
2014 Hashmi AS. Dual gold catalysis. Accounts of Chemical Research. 47: 864-76. PMID 24533563 DOI: 10.1021/Ar500015K  0.445
2014 Vilhelmsen MH, Hashmi AS. Reaction mechanism for the dual gold-catalyzed synthesis of dibenzopentalene: a DFT study. Chemistry (Weinheim An Der Bergstrasse, Germany). 20: 1901-8. PMID 24443140 DOI: 10.1002/Chem.201303636  0.466
2014 Hansmann MM, Tšupova S, Rudolph M, Rominger F, Hashmi AS. Gold-catalyzed cyclization of diynes: controlling the mode of 5-endo versus 6-endo cyclization--an experimental and theoretical study by utilizing diethynylthiophenes. Chemistry (Weinheim An Der Bergstrasse, Germany). 20: 2215-23. PMID 24436306 DOI: 10.1002/Chem.201302967  0.384
2014 Wang T, Shi S, Pflästerer D, Rettenmeier E, Rudolph M, Rominger F, Hashmi AS. Synthesis of polycyclic indole skeletons by a gold(I)-catalyzed cascade reaction. Chemistry (Weinheim An Der Bergstrasse, Germany). 20: 292-6. PMID 24375591 DOI: 10.1002/Chem.201303539  0.521
2014 Hansmann MM, Melen RL, Rominger F, Hashmi AS, Stephan DW. Activation of alkynes with B(C₆F₅)₃--boron allylation reagents derived from propargyl esters. Journal of the American Chemical Society. 136: 777-82. PMID 24354408 DOI: 10.1021/Ja4110842  0.442
2014 Shi S, Wang T, Weingand V, Rudolph M, Hashmi AS. Gold(I)-catalyzed diastereoselective hydroacylation of terminal alkynes with glyoxals. Angewandte Chemie (International Ed. in English). 53: 1148-51. PMID 24339019 DOI: 10.1002/Anie.201307685  0.454
2014 Yu Y, Yang W, Pflästerer D, Hashmi AS. Dehydrogenative Meyer-Schuster-like rearrangement: a gold-catalyzed reaction generating an alkyne. Angewandte Chemie (International Ed. in English). 53: 1144-7. PMID 24338996 DOI: 10.1002/Anie.201307647  0.519
2013 Hansmann MM, Pernpointner M, Döpp R, Hashmi AS. A theoretical DFT-based and experimental study of the transmetalation step in Au/Pd-mediated cross-coupling reactions. Chemistry (Weinheim An Der Bergstrasse, Germany). 19: 15290-303. PMID 24115258 DOI: 10.1002/Chem.201301840  0.373
2013 Nösel P, dos Santos Comprido LN, Lauterbach T, Rudolph M, Rominger F, Hashmi AS. 1,6-Carbene transfer: gold-catalyzed oxidative diyne cyclizations. Journal of the American Chemical Society. 135: 15662-6. PMID 24050384 DOI: 10.1021/Ja4085385  0.438
2013 Melen RL, Hansmann MM, Lough AJ, Hashmi AS, Stephan DW. Cyclisation versus 1,1-Carboboration: Reactions of B(C6F5)3 with Propargyl Amides. Chemistry (Weinheim An Der Bergstrasse, Germany). 19: 11928-38. PMID 23922200 DOI: 10.1002/Chem.201301899  0.432
2013 Blanco Jaimes MC, Weingand V, Rominger F, Hashmi AS. From ynamides to highly substituted benzo[b]furans: gold(I)-catalyzed 5-endo-dig-cyclization/rearrangement of alkylic oxonium intermediates. Chemistry (Weinheim An Der Bergstrasse, Germany). 19: 12504-11. PMID 23922052 DOI: 10.1002/Chem.201301595  0.42
2013 Wang T, Shi S, Vilhelmsen MH, Zhang T, Rudolph M, Rominger F, Hashmi AS. Chemoselectivity control: gold(I)-catalyzed synthesis of 6,7-dihydrobenzofuran-4(5H)-ones and benzofurans from 1-(alkynyl)-7-oxabicyclo[4.1.0]heptan-2-ones. Chemistry (Weinheim An Der Bergstrasse, Germany). 19: 12512-6. PMID 23881797 DOI: 10.1002/Chem.201301698  0.418
2013 Yu Y, Yang W, Rominger F, Hashmi AS. In situ generation of nucleophilic allenes by the gold-catalyzed rearrangement of propargylic esters for the highly diastereoselective formation of intermolecular C(sp3)-C(sp2) bonds. Angewandte Chemie (International Ed. in English). 52: 7586-9. PMID 23843175 DOI: 10.1002/Anie.201302402  0.475
2013 Cauteruccio S, Loos A, Bossi A, Blanco Jaimes MC, Dova D, Rominger F, Prager S, Dreuw A, Licandro E, Hashmi AS. Gold(I) complexes of tetrathiaheterohelicene phosphanes. Inorganic Chemistry. 52: 7995-8004. PMID 23815095 DOI: 10.1021/Ic4005533  0.345
2013 Blanco Jaimes MC, Böhling CR, Serrano-Becerra JM, Hashmi AS. Highly active mononuclear NAC-gold(I) catalysts. Angewandte Chemie (International Ed. in English). 52: 7963-6. PMID 23788434 DOI: 10.1002/Anie.201210351  0.344
2013 Hansmann MM, Hashmi AS, Lautens M. Gold meets rhodium: tandem one-pot synthesis of β-disubstituted ketones via Meyer-Schuster rearrangement and asymmetric 1,4-addition. Organic Letters. 15: 3226-9. PMID 23777565 DOI: 10.1021/Ol4011739  0.531
2013 Ackermann M, Bucher J, Rappold M, Graf K, Rominger F, Hashmi AS. [3,3]-Sigmatropic rearrangement step in the gold-catalyzed cyclization of allyl-(ortho-alkinylphenyl)methyl ethers. Chemistry, An Asian Journal. 8: 1786-94. PMID 23729410 DOI: 10.1002/Asia.201300324  0.484
2013 Nösel P, Lauterbach T, Rudolph M, Rominger F, Hashmi AS. Gold-catalyzed synthesis of iodofulvenes. Chemistry (Weinheim An Der Bergstrasse, Germany). 19: 8634-41. PMID 23653259 DOI: 10.1002/Chem.201300507  0.513
2013 Rettenmeier E, Schuster AM, Rudolph M, Rominger F, Gade CA, Hashmi AS. Gold catalysis: highly functionalized cyclopentadienes prepared by intermolecular cyclization of ynamides and propargylic carboxylates. Angewandte Chemie (International Ed. in English). 52: 5880-4. PMID 23616262 DOI: 10.1002/Anie.201301382  0.434
2013 Shi S, Wang T, Yang W, Rudolph M, Hashmi AS. Gold-catalyzed synthesis of glyoxals by oxidation of terminal alkynes: one-pot synthesis of quinoxalines. Chemistry (Weinheim An Der Bergstrasse, Germany). 19: 6576-80. PMID 23576273 DOI: 10.1002/Chem.201300518  0.403
2013 Klatt G, Xu R, Pernpointner M, Molinari L, Quang Hung T, Rominger F, Hashmi AS, Köppel H. Are β-H eliminations or alkene insertions feasible elementary steps in catalytic cycles involving gold(I) alkyl species or gold(I) hydrides? Chemistry (Weinheim An Der Bergstrasse, Germany). 19: 3954-61. PMID 23401385 DOI: 10.1002/Chem.201203043  0.321
2013 Hansmann MM, Rudolph M, Rominger F, Hashmi AS. Mechanistic switch in dual gold catalysis of diynes: C(sp(3))-H activation through bifurcation--vinylidene versus carbene pathways. Angewandte Chemie (International Ed. in English). 52: 2593-8. PMID 23362151 DOI: 10.1002/Anie.201208777  0.401
2013 Hashmi AS, Lauterbach T, Nösel P, Vilhelmsen MH, Rudolph M, Rominger F. Dual gold catalysis: σ,π-propyne acetylide and hydroxyl-bridged digold complexes as easy-to-prepare and easy-to-handle precatalysts. Chemistry (Weinheim An Der Bergstrasse, Germany). 19: 1058-65. PMID 23255064 DOI: 10.1002/Chem.201203010  0.435
2013 Hashmi AS, Yang W, Yu Y, Hansmann MM, Rudolph M, Rominger F. Gold-catalyzed formal 1,6-acyloxy migration leading to 3,4-disubstituted pyrrolidin-2-ones. Angewandte Chemie (International Ed. in English). 52: 1329-32. PMID 23212940 DOI: 10.1002/Anie.201207287  0.434
2013 Hashmi AS, Hofmann J, Shi S, Schütz A, Rudolph M, Lothschütz C, Wieteck M, Bührle M, Wölfle M, Rominger F. Gold catalysis: catalyst oxidation state dependent dichotomy in the cyclization of furan-yne systems with aromatic tethers. Chemistry (Weinheim An Der Bergstrasse, Germany). 19: 382-9. PMID 23150272 DOI: 10.1002/Chem.201202004  0.498
2012 Hashmi AS. Chemistry. Sub-nanosized gold catalysts. Science (New York, N.Y.). 338: 1434. PMID 23239727 DOI: 10.1126/Science.1231901  0.408
2012 Hashmi AS. Fire and ice: a gold(III) monohydride. Angewandte Chemie (International Ed. in English). 51: 12935-6. PMID 23184856 DOI: 10.1002/Anie.201208603  0.381
2012 Hashmi AS, Wieteck M, Braun I, Rudolph M, Rominger F. Gold vinylidene complexes: intermolecular C(sp3)-H insertions and cyclopropanations pathways. Angewandte Chemie (International Ed. in English). 51: 10633-7. PMID 22987629 DOI: 10.1002/Anie.201204015  0.362
2012 Hashmi AS, Wang T, Shi S, Rudolph M. Regioselectivity switch: gold(I)-catalyzed oxidative rearrangement of propargyl alcohols to 1,3-diketones. The Journal of Organic Chemistry. 77: 7761-7. PMID 22877083 DOI: 10.1021/Jo301381Z  0.331
2012 Hashmi AS, Häffner T, Yang W, Pankajakshan S, Schäfer S, Schultes L, Rominger F, Frey W. Gold catalysis: non-spirocyclic intermediates in the conversion of furanynes by the formal insertion of an alkyne into an aryl-alkyl C-C single bond. Chemistry (Weinheim An Der Bergstrasse, Germany). 18: 10480-6. PMID 22807391 DOI: 10.1002/Chem.201200306  0.374
2012 Hashmi AS, Blanco Jaimes MC, Schuster AM, Rominger F. From propargylic amides to functionalized oxazoles: domino gold catalysis/oxidation by dioxygen. The Journal of Organic Chemistry. 77: 6394-408. PMID 22800562 DOI: 10.1021/Jo301288W  0.463
2012 Hashmi AS, Ghanbari M, Rudolph M, Rominger F. Combining gold and palladium catalysis: one-pot access to pentasubstituted arenes from furan-yne and en-diyne substrates. Chemistry (Weinheim An Der Bergstrasse, Germany). 18: 8113-9. PMID 22615003 DOI: 10.1002/Chem.201200091  0.52
2012 Hashmi AS, Yang W, Rominger F. Gold(I)-catalyzed rearrangement of 3-silyloxy-1,5-enynes: an efficient synthesis of benzo[b]thiophenes, dibenzothiophenes, dibenzofurans, and indole derivatives. Chemistry (Weinheim An Der Bergstrasse, Germany). 18: 6576-80. PMID 22517669 DOI: 10.1002/Chem.201200314  0.459
2012 Hashmi AS, Littmann A. Gold catalysis: one-pot alkylideneoxazoline synthesis/Alder-ene reaction. Chemistry, An Asian Journal. 7: 1435-42. PMID 22434782 DOI: 10.1002/Asia.201200046  0.509
2012 Hashmi AS, Braun I, Nösel P, Schädlich J, Wieteck M, Rudolph M, Rominger F. Simple gold-catalyzed synthesis of benzofulvenes--gem-diaurated species as "instant dual-activation" precatalysts. Angewandte Chemie (International Ed. in English). 51: 4456-60. PMID 22431399 DOI: 10.1002/Anie.201109183  0.381
2012 Hashmi AS, Riedel D, Rudolph M, Rominger F, Oeser T. Regioselective formation of saturated abnormal NHC-gold(I) complexes by [3+2] cycloaddition of azomethine ylides and isonitrile gold(I) complexes. Chemistry (Weinheim An Der Bergstrasse, Germany). 18: 3827-30. PMID 22378616 DOI: 10.1002/Chem.201200217  0.347
2012 Rudolph M, Hashmi AS. Gold catalysis in total synthesis--an update. Chemical Society Reviews. 41: 2448-62. PMID 22182942 DOI: 10.1039/C1Cs15279C  0.4
2011 Hashmi AS, Pernpointner M, Hansmann MM. Theoretical insights into the superior activity of gold catalysts and reactions of organogold intermediates with electrophiles. Faraday Discussions. 152: 179-84; discussion 2. PMID 22455045 DOI: 10.1039/C1Fd00029B  0.507
2011 Rudolph M, McCreery MQ, Frey W, Hashmi AS. High chemoselectivity in the phenol synthesis. Beilstein Journal of Organic Chemistry. 7: 794-801. PMID 21804874 DOI: 10.3762/Bjoc.7.90  0.481
2011 Hashmi AS, Häffner T, Rudolph M, Rominger F. Gold catalysis: domino reaction of en-diynes to highly substituted phenols. Chemistry (Weinheim An Der Bergstrasse, Germany). 17: 8195-201. PMID 21656584 DOI: 10.1002/Chem.201100305  0.471
2011 Hashmi AS, Yang W, Rominger F. Gold(I)-catalyzed formation of benzo[b]furans from 3-silyloxy-1,5-enynes. Angewandte Chemie (International Ed. in English). 50: 5762-5. PMID 21557422 DOI: 10.1002/Anie.201100989  0.36
2011 Hashmi AS, Riedel D, Grundl MA, Wittel BC, Föll A, Lubkoll J, Traut T, Hewer R, Rominger F, Frey W, Bats JW. Bioconjugates of enantiomerically pure organopalladium compounds by metal-assisted positional selective transesterifications at palladium enolates. Chemistry (Weinheim An Der Bergstrasse, Germany). 17: 6407-14. PMID 21520303 DOI: 10.1002/Chem.201003308  0.442
2011 Hashmi AS, Schuster AM, Zimmer M, Rominger F. Synthesis of 5-halo-4H-1,3-oxazine-6-amines by a copper-mediated domino reaction. Chemistry (Weinheim An Der Bergstrasse, Germany). 17: 5511-5. PMID 21491523 DOI: 10.1002/Chem.201100423  0.414
2011 Hashmi AS, Schuster AM, Litters S, Rominger F, Pernpointner M. Gold catalysis: 1,3-oxazines by cyclisation of allene amides. Chemistry (Weinheim An Der Bergstrasse, Germany). 17: 5661-7. PMID 21488108 DOI: 10.1002/Chem.201100132  0.447
2011 Rudolph M, Hashmi AS. Heterocycles from gold catalysis. Chemical Communications (Cambridge, England). 47: 6536-44. PMID 21451867 DOI: 10.1039/C1Cc10780A  0.467
2010 Hashmi AS, Bührle M, Wölfle M, Rudolph M, Wieteck M, Rominger F, Frey W. Gold catalysis: tandem reactions of diyne-diols and external nucleophiles as an easy access to tricyclic cage-like structures. Chemistry (Weinheim An Der Bergstrasse, Germany). 16: 9846-54. PMID 20632335 DOI: 10.1002/Chem.201001322  0.518
2010 Hashmi AS, Lothschütz C, Ackermann M, Doepp R, Anantharaman S, Marchetti B, Bertagnolli H, Rominger F. Gold catalysis: in situ EXAFS study of homogeneous oxidative esterification. Chemistry (Weinheim An Der Bergstrasse, Germany). 16: 8012-9. PMID 20602364 DOI: 10.1002/Chem.200903450  0.457
2010 Hashmi AS. Homogeneous gold catalysis beyond assumptions and proposals--characterized intermediates. Angewandte Chemie (International Ed. in English). 49: 5232-41. PMID 20572216 DOI: 10.1002/Anie.200907078  0.43
2010 Bechem B, Patman RL, Hashmi AS, Krische MJ. Enantioselective carbonyl allylation, crotylation, and tert-prenylation of furan methanols and furfurals via iridium-catalyzed transfer hydrogenation. The Journal of Organic Chemistry. 75: 1795-8. PMID 20131774 DOI: 10.1021/Jo902697G  0.53
2010 Hashmi AS, Hubbert C. Gold and organocatalysis combined. Angewandte Chemie (International Ed. in English). 49: 1010-2. PMID 20041466 DOI: 10.1002/Anie.200906609  0.321
2010 Weyrauch JP, Hashmi AS, Schuster A, Hengst T, Schetter S, Littmann A, Rudolph M, Hamzic M, Visus J, Rominger F, Frey W, Bats JW. Cyclization of propargylic amides: mild access to oxazole derivatives. Chemistry (Weinheim An Der Bergstrasse, Germany). 16: 956-63. PMID 19938017 DOI: 10.1002/Chem.200902472  0.454
2010 Hashmi A, Wölfle M, Ata F, Frey W, Rominger F. Gold Catalysis: Desymmetrization in the Furan-Yne Reaction Synthesis. 2010: 2297-2307. DOI: 10.1055/S-0029-1218800  0.411
2010 Hashmi AS, Döpp R, Lothschütz C, Rudolph M, Riedel D, Rominger F. Scope and Limitations of Palladium-Catalyzed Cross-Coupling Reactions with Organogold Compounds Advanced Synthesis & Catalysis. 352: 1307-1314. DOI: 10.1002/Adsc.201000159  0.397
2010 Hashmi AS, Hengst T, Lothschütz C, Rominger F. New and Easily Accessible Nitrogen Acyclic Gold(I) Carbenes: Structure and Application in the Gold-Catalyzed Phenol Synthesis as well as the Hydration of Alkynes Advanced Synthesis & Catalysis. 352: 1315-1337. DOI: 10.1002/Adsc.201000126  0.485
2010 Hashmi AS, Ramamurthi TD, Rominger F. On the Trapping of Vinylgold Intermediates Advanced Synthesis & Catalysis. 352: 971-975. DOI: 10.1002/Adsc.201000011  0.444
2009 Pernpointner M, Hashmi AS. Fully Relativistic, Comparative Investigation of Gold and Platinum Alkyne Complexes of Relevance for the Catalysis of Nucleophilic Additions to Alkynes. Journal of Chemical Theory and Computation. 5: 2717-25. PMID 26631784 DOI: 10.1021/Ct900441F  0.395
2009 Hashmi AS, Hamzi? M, Rominger F, Bats JW. Gold catalysis: enantiotopos selection. Chemistry (Weinheim An Der Bergstrasse, Germany). 15: 13318-22. PMID 19899092 DOI: 10.1002/Chem.200901695  0.318
2009 Hashmi AS, Lothschütz C, Döpp R, Rudolph M, Ramamurthi TD, Rominger F. Gold and palladium combined for cross-coupling. Angewandte Chemie (International Ed. in English). 48: 8243-6. PMID 19790218 DOI: 10.1002/Anie.200902942  0.309
2009 Hashmi AS, Schuster AM, Rominger F. Gold catalysis: isolation of vinylgold complexes derived from alkynes. Angewandte Chemie (International Ed. in English). 48: 8247-9. PMID 19768822 DOI: 10.1002/Anie.200903134  0.339
2009 Hashmi AS, Rudolph M, Huck J, Frey W, Bats JW, Hamzi? M. Gold catalysis: switching the pathway of the furan-yne cyclization. Angewandte Chemie (International Ed. in English). 48: 5848-52. PMID 19562808 DOI: 10.1002/Anie.200900887  0.334
2009 Hashmi A, Schuster A, Rominger F. Gold-Katalyse: Isolierung von Vinylgold-Komplexen ausgehend von Alkinen Angewandte Chemie. 121: 8396-8398. DOI: 10.1002/Ange.200903134  0.325
2009 Hashmi A, Lothschütz C, Döpp R, Rudolph M, Ramamurthi T, Rominger F. Gold trifft Palladium für Kreuzkupplungen Angewandte Chemie. 121: 8392-8395. DOI: 10.1002/Ange.200902942  0.424
2009 Hashmi A, Rudolph M, Huck J, Frey W, Bats J, Hamzić M. Gold-Katalyse: Umlenken des Reaktionspfades der Furan-Alkin- Cyclisierung Angewandte Chemie. 121: 5962-5966. DOI: 10.1002/Ange.200900887  0.313
2009 Hashmi AS, Pankajakshan S, Rudolph M, Enns E, Bander T, Rominger F, Frey W. Gold Catalysis: Anellated Heterocycles and Dependency of the Reaction Pathway on the Tether Length Advanced Synthesis & Catalysis. 351: 2855-2875. DOI: 10.1002/Adsc.200900614  0.401
2009 Hashmi AS, Hamzić M, Rudolph M, Ackermann M, Rominger F. Gold Catalysis: Efficient 1,3-Induction with Diastereotopic Homopropargyl Alcohols in the Phenol Synthesis Advanced Synthesis & Catalysis. 351: 2469-2481. DOI: 10.1002/Adsc.200900402  0.465
2009 Hashmi AS, Loos A, Littmann A, Braun I, Knight J, Doherty S, Rominger F. Gold(I) Complexes of KITPHOS Monophosphines: Efficient Cycloisomerisation Catalysts Advanced Synthesis & Catalysis. 351: 576-582. DOI: 10.1002/Adsc.200800681  0.378
2008 Hashmi AS, Rudolph M. Gold catalysis in total synthesis. Chemical Society Reviews. 37: 1766-75. PMID 18762826 DOI: 10.1039/B615629K  0.423
2008 Hashmi AS. "High noon" in gold catalysis: carbene versus carbocation intermediates. Angewandte Chemie (International Ed. in English). 47: 6754-6. PMID 18683174 DOI: 10.1002/Anie.200802517  0.41
2008 Hashmi AS, Rudolph M, Bats JW, Frey W, Rominger F, Oeser T. Gold-catalyzed synthesis of chroman, dihydrobenzofuran, dihydroindole, and tetrahydroquinoline derivatives. Chemistry (Weinheim An Der Bergstrasse, Germany). 14: 6672-8. PMID 18576410 DOI: 10.1002/Chem.200800210  0.485
2008 Hashmi AS, Rudolph M, Siehl HU, Tanaka M, Bats JW, Frey W. Gold catalysis: deuterated substrates as the key for an experimental insight into the mechanism and selectivity of the phenol synthesis. Chemistry (Weinheim An Der Bergstrasse, Germany). 14: 3703-8. PMID 18318022 DOI: 10.1002/Chem.200701795  0.465
2008 Hashmi AS, Bührle M, Salathé R, Bats J. Gold Catalysis: Synthesis of 3-Acylindenes from 2-Alkynylaryl Epoxides Advanced Synthesis & Catalysis. 350: 2059-2064. DOI: 10.1002/Adsc.200800385  0.433
2007 Hashmi AS. Catalysis: raising the gold standard. Nature. 449: 292-3. PMID 17882208 DOI: 10.1038/449292A  0.379
2007 Hashmi AS. Gold-catalyzed organic reactions. Chemical Reviews. 107: 3180-211. PMID 17580975 DOI: 10.1021/Cr000436X  0.431
2007 Hashmi AS, Teles J, Wölfle M, Frey W. Bisphenols from Furfurals by Organocatalysis and Gold Catalysis Synlett. 2007: 1747-1752. DOI: 10.1055/S-2007-982569  0.469
2007 Hashmi AS, Kurpejović E, Wölfle M, Frey W, Bats J. Gold Catalysis: Oxepines from γ-Alkynylfurans Advanced Synthesis & Catalysis. 349: 1743-1750. DOI: 10.1002/Adsc.200600653  0.467
2006 Hashmi AS, Hutchings GJ. Gold catalysis. Angewandte Chemie (International Ed. in English). 45: 7896-936. PMID 17131371 DOI: 10.1002/anie.200602454  0.358
2006 Hashmi AS, Salathé R, Frey W. Gold catalysis: no steric limitations in the phenol synthesis. Chemistry (Weinheim An Der Bergstrasse, Germany). 12: 6991-6. PMID 16823790 DOI: 10.1002/Chem.200600533  0.499
2006 Hashmi AS, Weyrauch JP, Kurpejovi? E, Frost TM, Miehlich B, Frey W, Bats JW. Gold catalysis: phenol synthesis in the presence of functional groups. Chemistry (Weinheim An Der Bergstrasse, Germany). 12: 5806-14. PMID 16718723 DOI: 10.1002/Chem.200501268  0.522
2006 Hashmi AS, Haufe P, Schmid C, Rivas Nass A, Frey W. Asymmetric rhodium-catalyzed hydrogenation meets gold-catalyzed cyclization: Enantioselective synthesis of 8-hydroxytetrahydroisoquinolines. Chemistry (Weinheim An Der Bergstrasse, Germany). 12: 5376-82. PMID 16683280 DOI: 10.1002/Chem.200600192  0.494
2006 Hashmi A, Blanco M, Kurpejović E, Frey W, Bats J. Gold Catalysis: First Applications of Cationic Binuclear Gold(I) Complexes and the First Intermolecular Reaction of an Alkyne with a Furan Advanced Synthesis & Catalysis. 348: 709-713. DOI: 10.1002/Adsc.200606012  0.489
2006 Hashmi AS, Wölfle M, Ata F, Hamzic M, Salathé R, Frey W. Gold Catalysis: Dihydroisobenzofurans and Isochromanes by the Intramolecular Furan/Alkyne Reaction Advanced Synthesis & Catalysis. 348: 2501-2508. DOI: 10.1002/Adsc.200600367  0.465
2006 Hashmi A, Schwarz L, Rubenbauer P, Blanco M. The Condensation of Carbonyl Compounds with Electron-Rich Arenes: Mercury, Thallium, Gold or a Proton? Advanced Synthesis & Catalysis. 348: 705-708. DOI: 10.1002/Adsc.200505464  0.378
2005 Hashmi AS. The catalysis gold rush: new claims. Angewandte Chemie (International Ed. in English). 44: 6990-3. PMID 16259021 DOI: 10.1002/Anie.200502735  0.333
2005 Hashmi AS, Rudolph M, Weyrauch JP, Wölfle M, Frey W, Bats JW. Gold catalysis: proof of arene oxides as intermediates in the phenol synthesis. Angewandte Chemie (International Ed. in English). 44: 2798-801. PMID 15806608 DOI: 10.1002/Anie.200462672  0.391
2004 Hashmi AS, Weyrauch JP, Frey W, Bats JW. Gold catalysis: mild conditions for the synthesis of oxazoles from N-propargylcarboxamides and mechanistic aspects. Organic Letters. 6: 4391-4. PMID 15524491 DOI: 10.1021/Ol0480067  0.465
2004 Hashmi A, Schwarz L, Bolte M. Synthesis of 2,4-Furanophanes by Palladium-Catalyzed Macrocyclization Reactions of 1,n-Diallenyl Diketones European Journal of Organic Chemistry. 2004: 1923-1935. DOI: 10.1002/Ejoc.200300792  0.446
2004 Hashmi A, Haufe P, Rivas Nass A, Bats J. The Absolute Configuration of the Products of the Enantioselective Rhodium(I)/BINAP-Catalyzed Enyne Cyclization Advanced Synthesis & Catalysis. 346: 421-424. DOI: 10.1002/Adsc.200303225  0.342
2004 Hashmi A, Sinha P. Gold Catalysis: Mild Conditions for the Transformation of Alkynyl Epoxides to Furans Advanced Synthesis & Catalysis. 346: 432-438. DOI: 10.1002/Adsc.200303201  0.406
2003 Hashmi AS, Ding L, Bats JW, Fischer P, Frey W. Gold catalysis: efficient synthesis and structural assignment of jungianol and epi-jungianol. Chemistry (Weinheim An Der Bergstrasse, Germany). 9: 4339-45. PMID 14502619 DOI: 10.1002/Chem.200305092  0.413
2003 Hashmi A, Haufe P, Rivas Nass A. On the Enantioselective Rhodium-Catalyzed Enyne Cyclization Advanced Synthesis & Catalysis. 345: 1237-1241. DOI: 10.1002/Adsc.200303086  0.435
2002 Hashmi A, Grundl M, Bats J, Bolte M. Different Diastereoselectivities in the Stereoselective Oxidative Cyclization of Two Cyclopropenes at Palladium(0) European Journal of Organic Chemistry. 2002: 1263-1270. DOI: 10.1002/1099-0690(200204)2002:7<1263::Aid-Ejoc1263>3.0.Co;2-6  0.339
2001 Hashmi AS, Frost TM, Bats JW. Gold catalysis: on the phenol synthesis. Organic Letters. 3: 3769-71. PMID 11700134 DOI: 10.1021/Ol016734D  0.48
2001 Trost B, Hashmi A, Ball R. Chemoselectivity in the Pd-Catalyzed Cyclization of 1,6-Enynes and Proof of the Relative Configuration of the New Stereogenic Centers Advanced Synthesis & Catalysis. 343: 490-494. DOI: 10.1002/1615-4169(200107)343:5<490::Aid-Adsc490>3.0.Co;2-S  0.52
2001 Hashmi A, Grundl M, Nass A, Naumann F, Bats J, Bolte M. Photochemical Synthesis of Prochiral Dialkyl 3,3-Dialkylcyclopropene-1,2-dicarboxylates with Facial Shielding Substituents and Related Substrates European Journal of Organic Chemistry. 2001: 4705. DOI: 10.1002/1099-0690(200112)2001:24<4705::Aid-Ejoc4705>3.0.Co;2-J  0.393
2000 Hashmi AS, Schwarz L, Choi JH, Frost TM. A New Gold-Catalyzed C-C Bond Formation This work was supported by the Deutsche Forschungsgemeinschaft (Ha 1932/5-1, Ha 1932/6-1) and the Fonds der Chemischen Industrie. Gold salts were donated by Degussa-Hüls AG. A.S.K.H. is indebted to Prof. M. Göbel for laboratory space. Angewandte Chemie (International Ed. in English). 39: 2285-2288. PMID 10941065 DOI: 10.1002/1521-3773(20000703)39:13<2285::Aid-Anie2285>3.0.Co;2-F  0.305
1997 Hashmi AS, Ruppert TL, Knöfel T, Bats JW. C-C-Bond Formation by the Palladium-Catalyzed Cycloisomerization/Dimerization of Terminal Allenyl Ketones: Selectivity and Mechanistic Aspects. The Journal of Organic Chemistry. 62: 7295-7304. PMID 11671843 DOI: 10.1021/jo970837l  0.335
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