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Donald Allen Watson - Publications

Affiliations: 
2009- Chemistry and Biochemistry University of Delaware, Newark, DE, United States 
Area:
transition metal catalysts
Website:
http://www.chem.udel.edu/chemistry/faculty/donald-watson-assistant-professor
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59 high-probability publications. We are testing a new system for linking publications to authors. You can help! If you notice any inaccuracies, please sign in and mark papers as correct or incorrect matches. If you identify any major omissions or other inaccuracies in the publication list, please let us know.

Year Citation  Score
2024 Kim RS, Kgoadi LO, Hayes JC, Rainboth DP, Mudd CM, Yap GPA, Watson DA. Nickel-Catalyzed Atroposelective Cross-Electrophile Coupling of Aryl Halides: A General and Practical Route to Diverse MOP-Type Ligands. Journal of the American Chemical Society. PMID 38780663 DOI: 10.1021/jacs.4c04608  0.39
2023 Rezazadeh S, Martin MI, Kim RS, Yap GPA, Rosenthal J, Watson DA. Photoredox-Nickel Dual-Catalyzed -Alkylation of Secondary Nitroalkanes: Access to Sterically Hindered α-Tertiary Amines. Journal of the American Chemical Society. PMID 36795911 DOI: 10.1021/jacs.2c13174  0.383
2022 Pawley SB, Conner AM, Omer HM, Watson DA. Development of a General Method for the Hiyama-Denmark Cross-Coupling of Tetrasubstituted Vinyl Silanes. Acs Catalysis. 12: 13108-13115. PMID 36817085 DOI: 10.1021/acscatal.2c03981  0.392
2021 Korch KM, Watson DA. Total Synthesis of (±)-Impatien A via Aza-Heck Cyclization. Organic Letters. PMID 34460273 DOI: 10.1021/acs.orglett.1c02767  0.352
2021 Gao RD, Shuler SA, Watson DA. Tandem aza-Heck Suzuki and carbonylation reactions of -phenyl hydroxamic ethers: complex lactams carboamination. Chemical Science. 12: 8859-8864. PMID 34257886 DOI: 10.1039/d1sc02075g  0.5
2021 Idowu OO, Hayes JC, Reid WB, Watson DA. Synthesis of 1,1-Diboryl Alkenes Using the Boryl-Heck Reaction. Organic Letters. PMID 34043367 DOI: 10.1021/acs.orglett.1c01567  0.481
2021 Zuo Z, Kim RS, Watson DA. Synthesis of Axially Chiral 2,2'-Bisphosphobiarenes via a Nickel-Catalyzed Asymmetric Ullmann Coupling: General Access to Privileged Chiral Ligands without Optical Resolution. Journal of the American Chemical Society. PMID 33439640 DOI: 10.1021/jacs.0c12843  0.304
2020 Kim RS, Dinh-Nguyen LV, Shimkin KW, Watson DA. Copper-Catalyzed Propargylation of Nitroalkanes. Organic Letters. PMID 33006901 DOI: 10.1021/acs.orglett.0c03061  0.416
2020 Xu F, Duke OM, Rojas D, Eichelberger HM, Kim RS, Clark TB, Watson DA. Arylphosphonate-Directed Ortho C-H Borylation: Rapid Entry into Highly-Substituted Phosphoarenes. Journal of the American Chemical Society. PMID 32594742 DOI: 10.1021/Jacs.0C04159  0.468
2020 Wisthoff MF, Pawley SB, Cinderella AP, Watson DA. Stereoselective Synthesis of - and -Tetrasubstituted Vinyl Silanes Using a Silyl-Heck Strategy and Hiyama Conditions for Their Cross-Coupling. Journal of the American Chemical Society. PMID 32579845 DOI: 10.1021/Jacs.0C05382  0.516
2019 Reid WB, McAtee JR, Watson DA. Synthesis of Unsaturated Silyl Heterocycles an Intramolecular Silyl-Heck Reaction. Organometallics. 38: 3796-3803. PMID 32431470 DOI: 10.1021/Acs.Organomet.9B00498  0.56
2019 Xu F, Korch K, Watson D. Synthesis of Indolines and Derivatives via Aza-Heck Cyclization. Angewandte Chemie (International Ed. in English). PMID 31310448 DOI: 10.1002/Anie.201907758  0.49
2019 Korch KM, Watson DA. Cross-Coupling of Heteroatomic Electrophiles. Chemical Reviews. PMID 31184483 DOI: 10.1021/Acs.Chemrev.8B00628  0.431
2019 Devannah V, Sharma R, Watson DA. Nickel-Catalyzed Asymmetric C-Alkylation of Nitroalkanes: Synthesis of Enantioenriched β-Nitroamides. Journal of the American Chemical Society. PMID 31082224 DOI: 10.1021/Jacs.9B04175  0.595
2018 Reid WB, Watson DA. Synthesis of Trisubstituted Alkenyl Boronic Esters from Alkenes Using the Boryl-Heck Reaction. Organic Letters. PMID 30350673 DOI: 10.1021/Acs.Orglett.8B02949  0.573
2018 Xu F, Shuler SA, Watson DA. Synthesis of N-H Bearing Imidazolidinones and Dihydroimidazolones Using Aza-Heck Cyclizations. Angewandte Chemie (International Ed. in English). PMID 30125443 DOI: 10.1002/Anie.201806295  0.564
2017 Vulovic B, Cinderella AP, Watson DA. Palladium-Catalyzed Cross-Coupling of Monochlorosilanes And Grignard Reagents. Acs Catalysis. 7: 8113-8117. PMID 29868244 DOI: 10.1021/Acscatal.7B03465  0.531
2017 Vulovic B, Watson DA. Heck-like Reactions Involving Heteroatomic Electrophiles. European Journal of Organic Chemistry. 2017: 4996-5009. PMID 29104453 DOI: 10.1002/Ejoc.201700485  0.496
2017 Krause SB, McAtee JR, Yap GPA, Watson DA. A Bench-Stable, Single-Component Precatalyst for Silyl-Heck Reactions. Organic Letters. PMID 28960083 DOI: 10.1021/Acs.Orglett.7B02807  0.453
2017 Rezazadeh S, Devannah V, Watson DA. Nickel-Catalyzed C-Alkylation of Nitroalkanes with Unactivated Alkyl Iodides. Journal of the American Chemical Society. PMID 28594543 DOI: 10.1021/Jacs.7B04312  0.516
2017 Cinderella AP, Vulovic B, Watson DA. Palladium-Catalyzed Cross-Coupling of Silyl Electrophiles with Alkylzinc Halides: A Silyl-Negishi Reaction. Journal of the American Chemical Society. PMID 28570065 DOI: 10.1021/Jacs.7B04364  0.533
2017 Gietter-Burch AAS, Devannah V, Watson DA. Trifluoromethylation of Secondary Nitroalkanes. Organic Letters. PMID 28535057 DOI: 10.1021/Acs.Orglett.7B01196  0.428
2017 Knochel P, Lutter FH, Cinderella AP, Vulovic B, Watson DA. Palladium-Catalyzed Cross-Coupling of Silyl Electrophiles with Alkylzinc Halides Synfacts. 13: 861-7744. DOI: 10.1055/S-0036-1590641  0.426
2016 Shuler SA, Yin G, Krause SB, Vesper CM, Watson DA. Synthesis of Secondary Unsaturated Lactams via an Aza-Heck Reaction. Journal of the American Chemical Society. PMID 27754648 DOI: 10.1021/Jacs.6B08932  0.536
2016 Mori-Quiroz LM, Shimkin KW, Rezazadeh S, Kozlowski RA, Watson DA. Copper-Catalyzed Amidation of Primary and Secondary Alkyl Boronic Esters. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 27654642 DOI: 10.1002/Chem.201603677  0.472
2016 Reid WB, Spillane JJ, Krause SB, Watson DA. Direct Synthesis of Alkenyl Boronic Esters from Unfunctionalized Alkenes: A Boryl-Heck Reaction. Journal of the American Chemical Society. PMID 27104749 DOI: 10.1021/Jacs.6B02914  0.797
2016 Shimkin KW, Gildner PG, Watson DA. Copper-Catalyzed Alkylation of Nitroalkanes with α-Bromonitriles: Synthesis of β-Cyanonitroalkanes. Organic Letters. PMID 26866576 DOI: 10.1021/Acs.Orglett.6B00093  0.802
2016 Watson DA. Legacy of Richard Heck Organometallics. 35: 1177-1178. DOI: 10.1021/Acs.Organomet.6B00261  0.375
2015 McAtee JR, Krause SB, Watson DA. Simplified Preparation of Trialkylvinylsilanes via the Silyl-Heck Reaction Utilizing a Second Generation Catalyst. Advanced Synthesis & Catalysis. 357: 2317-2321. PMID 27325912 DOI: 10.1002/Adsc.201500436  0.555
2015 Shimkin KW, Watson DA. Recent developments in copper-catalyzed radical alkylations of electron-rich π-systems. Beilstein Journal of Organic Chemistry. 11: 2278-88. PMID 26734076 DOI: 10.3762/Bjoc.11.248  0.489
2015 Gietter-Burch AA, Mitrut RE, Watson DA. Highly Diastereoselective Michael Reactions Using β-Nitrocarbonyl Nucleophiles. Organic Letters. 17: 5468-71. PMID 26502157 DOI: 10.1021/Acs.Orglett.5B02832  0.718
2015 McAtee JR, Krause SB, Watson DA. Simplified Preparation of Trialkylvinylsilanes via the Silyl-Heck Reaction Utilizing a Second Generation Catalyst Advanced Synthesis and Catalysis. 357: 2317-2321. DOI: 10.1002/adsc.201500436  0.395
2014 McAtee JR, Yap GP, Watson DA. Rational design of a second generation catalyst for preparation of allylsilanes using the silyl-Heck reaction. Journal of the American Chemical Society. 136: 10166-72. PMID 25003502 DOI: 10.1021/Ja505446Y  0.491
2014 McAtee JR, Martin SE, Cinderella AP, Reid WB, Johnson KA, Watson DA. The First Example of Nickel-Catalyzed Silyl-Heck Reactions: Direct Activation of Silyl Triflates Without Iodide Additives. Tetrahedron. 70: 4250-4256. PMID 24914247 DOI: 10.1016/J.Tet.2014.03.021  0.541
2014 Gietter AA, Gildner PG, Cinderella AP, Watson DA. General route for preparing β-nitrocarbonyl compounds using copper thermal redox catalysis. Organic Letters. 16: 3166-9. PMID 24870052 DOI: 10.1021/Ol5014153  0.812
2014 Mahmoud E, Watson DA, Lobo RF. Renewable production of phthalic anhydride from biomass-derived furan and maleic anhydride Green Chemistry. 16: 167-175. DOI: 10.1039/C3Gc41655K  0.504
2013 Martin SES, Watson DA. Silyl-Heck Reactions for the Preparation of Unsaturated Organosilanes. Synlett : Accounts and Rapid Communications in Synthetic Organic Chemistry. 24: 2177-2182. PMID 29104371 DOI: 10.1055/S-0033-1339795  0.53
2013 Gietter AA, Pupillo RC, Yap GP, Beebe TP, Rosenthal J, Watson DA. On-Surface Cross Coupling Methods for the Construction of Modified Electrode Assemblies with Tailored Morphologies. Chemical Science (Royal Society of Chemistry : 2010). 4: 437-443. PMID 25520772 DOI: 10.1039/C2Sc21413J  0.305
2013 Martin SE, Watson DA. Preparation of vinyl silyl ethers and disiloxanes via the silyl-Heck reaction of silyl ditriflates. Journal of the American Chemical Society. 135: 13330-3. PMID 23984876 DOI: 10.1021/Ja407748Z  0.579
2013 Rossi SA, Shimkin KW, Xu Q, Mori-Quiroz LM, Watson DA. Selective formation of secondary amides via the copper-catalyzed cross-coupling of alkylboronic acids with primary amides. Organic Letters. 15: 2314-7. PMID 23611591 DOI: 10.1021/Ol401004R  0.542
2013 Do PT, McAtee JR, Watson DA, Lobo RF. Elucidation of Diels-Alder Reaction Network of 2,5-Dimethylfuran and Ethylene on HY Zeolite Catalyst. Acs Catalysis. 3: 41-46. PMID 23316419 DOI: 10.1021/Cs300673B  0.498
2013 Martin SES, Watson DA. Silyl-heck reactions for the preparation of unsaturated organosilanes Synlett. 24: 2177-2182. DOI: 10.1055/s-0033-1339795  0.428
2012 Gildner PG, Gietter AA, Cui D, Watson DA. Benzylation of nitroalkanes using copper-catalyzed thermal redox catalysis: toward the facile C-alkylation of nitroalkanes. Journal of the American Chemical Society. 134: 9942-5. PMID 22691127 DOI: 10.1021/Ja304561C  0.804
2012 McAtee JR, Martin SE, Ahneman DT, Johnson KA, Watson DA. Preparation of allyl and vinyl silanes by the palladium-catalyzed silylation of terminal olefins: a silyl-Heck reaction. Angewandte Chemie (International Ed. in English). 51: 3663-7. PMID 22383447 DOI: 10.1002/Anie.201200060  0.555
2012 Watson DA. 2.22 Selected Diastereoselective Reactions: Heck Type Cyclizations Comprehensive Chirality. 2: 648-684. DOI: 10.1016/B978-0-08-095167-6.00217-2  0.355
2010 Shen X, Jones GO, Watson DA, Bhayana B, Buchwald SL. Enantioselective synthesis of axially chiral biaryls by the Pd-catalyzed Suzuki-Miyaura reaction: substrate scope and quantum mechanical investigations. Journal of the American Chemical Society. 132: 11278-87. PMID 20698695 DOI: 10.1021/Ja104297G  0.754
2010 Cho EJ, Senecal TD, Kinzel T, Zhang Y, Watson DA, Buchwald SL. The palladium-catalyzed trifluoromethylation of aryl chlorides. Science (New York, N.Y.). 328: 1679-81. PMID 20576888 DOI: 10.1126/Science.1190524  0.798
2010 Watson DA, Su M, Teverovskiy G, Zhang Y, García-Fortanet J, Kinzel T, Buchwald SL. Palladium-Catalyzed Conversion of Aryl Triflates to ArylFluorides Synfacts. 2010: 85-85. DOI: 10.1055/S-0029-1218434  0.817
2009 Watson DA, Su M, Teverovskiy G, Zhang Y, García-Fortanet J, Kinzel T, Buchwald SL. Formation of ArF from LPdAr(F): catalytic conversion of aryl triflates to aryl fluorides. Science (New York, N.Y.). 325: 1661-4. PMID 19679769 DOI: 10.1126/Science.1178239  0.783
2008 Fors BP, Watson DA, Biscoe MR, Buchwald SL. A highly active catalyst for Pd-catalyzed amination reactions: cross-coupling reactions using aryl mesylates and the highly selective monoarylation of primary amines using aryl chlorides. Journal of the American Chemical Society. 130: 13552-4. PMID 18798626 DOI: 10.1021/Ja8055358  0.82
2008 Watson DA, Fan X, Buchwald SL. Carbonylation of aryl chlorides with oxygen nucleophiles at atmospheric pressure. Preparation of phenyl esters as acyl transfer agents and the direct preparation of alkyl esters and carboxylic acids. The Journal of Organic Chemistry. 73: 7096-101. PMID 18720992 DOI: 10.1021/Jo800907E  0.607
2008 Martinelli JR, Watson DA, Freckmann DM, Barder TE, Buchwald SL. Palladium-catalyzed carbonylation reactions of aryl bromides at atmospheric pressure: a general system based on Xantphos. The Journal of Organic Chemistry. 73: 7102-7. PMID 18720970 DOI: 10.1021/Jo801279R  0.803
2008 Martinelli JR, Watson DA, Freckmann DMM, Barder TE, Buchwald SL. Pd-Catalyzed Carbonylation of Aryl Bromides at AtmosphericPressure Synfacts. 2008: 1312-1312. DOI: 10.1055/S-0028-1083588  0.766
2007 Martinelli JR, Clark TP, Watson DA, Munday RH, Buchwald SL. Palladium-catalyzed aminocarbonylation of aryl chlorides at atmospheric pressure: the dual role of sodium phenoxide. Angewandte Chemie (International Ed. in English). 46: 8460-3. PMID 17902084 DOI: 10.1002/Anie.200702943  0.714
2006 Watson DA, Chiu M, Bergman RG. Zirconium Bis(Amido) Catalysts for Asymmetric Intramolecular Alkene Hydroamination. Organometallics. 25: 4731-4733. PMID 19079735 DOI: 10.1021/Om0606791  0.693
2006 Overman LE, Watson DA. Diastereoselection in the formation of contiguous quaternary carbon stereocenters by the intramolecular Heck reaction. The Journal of Organic Chemistry. 71: 2600-8. PMID 16555810 DOI: 10.1021/Jo0523363  0.63
2006 Overman LE, Watson DA. Diastereoselection in the formation of spirocyclic oxindoles by the intramolecular Heck reaction. The Journal of Organic Chemistry. 71: 2587-99. PMID 16555809 DOI: 10.1021/Jo052335A  0.606
2002 Hynes J, Nasser T, Overman LE, Watson DA. Preparation of alpha-sulfenyl enones by thermal fragmentation of beta-sulfenyl enol triflates. Organic Letters. 4: 929-31. PMID 11893188 DOI: 10.1021/Ol017303Y  0.695
1998 Xiang AX, Watson DA, Ling T, Theodorakis EA. Total Synthesis of Clerocidin via a Novel, Enantioselective Homoallenylboration Methodology. The Journal of Organic Chemistry. 63: 6774-6775. PMID 11672290 DOI: 10.1021/Jo981331L  0.576
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