Alan S. Goldman, Ph.D. - Publications

Affiliations: 
1987- Chemistry Rutgers University, New Brunswick, NJ, United States 
Website:
http://rutchem.rutgers.edu/goldman-alan

108 high-probability publications. We are testing a new system for linking publications to authors. You can help! If you notice any inaccuracies, please sign in and mark papers as correct or incorrect matches. If you identify any major omissions or other inaccuracies in the publication list, please let us know.

Year Citation  Score
2019 Zhou T, Malakar S, Webb SL, Krogh-Jespersen K, Goldman AS. Polar molecules catalyze CO insertion into metal-alkyl bonds through the displacement of an agostic C-H bond. Proceedings of the National Academy of Sciences of the United States of America. PMID 30755529 DOI: 10.1073/pnas.1816339116  1
2018 Omar BS, Mallah J, Ataya M, Li B, Zhou X, Malakar S, Goldman AS, Hasanayn F. H Addition to Pincer Iridium Complexes Yielding trans-Dihydride Products: Unexpected Correlations of Bond Strength with Bond Length and Vibrational Frequencies. Inorganic Chemistry. PMID 29894175 DOI: 10.1021/acs.inorgchem.7b03086  1
2018 Goldman AS, Landis CR, Sen A. Jack Halpern (1925-2018). Angewandte Chemie (International Ed. in English). PMID 29570933 DOI: 10.1002/anie.201802390  1
2018 Gao Y, Emge TJ, Krogh-Jespersen K, Goldman AS. Selective Dehydrogenative Coupling of Ethylene to Butadiene via an Iridacyclopentane Complex. Journal of the American Chemical Society. PMID 29338213 DOI: 10.1021/jacs.7b11689  1
2017 Connor GP, Lease N, Casuras A, Goldman AS, Holland PL, Mayer JM. Protonation and electrochemical reduction of rhodium- and iridium-dinitrogen complexes in organic solution. Dalton Transactions (Cambridge, England : 2003). PMID 29019358 DOI: 10.1039/c7dt03476h  1
2017 Kumar A, Bhatti TM, Goldman AS. Dehydrogenation of Alkanes and Aliphatic Groups by Pincer-Ligated Metal Complexes. Chemical Reviews. PMID 28952312 DOI: 10.1021/acs.chemrev.7b00247  1
2017 Goldberg KI, Goldman AS. Large-Scale Selective Functionalization of Alkanes. Accounts of Chemical Research. 50: 620-626. PMID 28945401 DOI: 10.1021/acs.accounts.6b00621  1
2017 Wilklow-Marnell M, Li B, Zhou T, Krogh-Jespersen K, Brennessel WW, Emge TJ, Goldman AS, Jones WD. Catalytic Dehydrogenative C-C Coupling by a Pincer-Ligated Iridium Complex. Journal of the American Chemical Society. PMID 28594178 DOI: 10.1021/jacs.7b03433  1
2017 Gao Y, Guan C, Zhou M, Kumar A, Emge TJ, Wright AM, Goldberg KI, Krogh-Jespersen K, Goldman AS. β-Hydride Elimination and C-H Activation by an Iridium Acetate Complex, Catalyzed by Lewis Acids. Alkane Dehydrogenation Co-Catalyzed by Lewis Acids and (Phebox)Ir. Journal of the American Chemical Society. PMID 28418249 DOI: 10.1021/jacs.6b12995  1
2016 Bézier D, Guan C, Krogh-Jespersen K, Goldman AS, Brookhart M. Experimental and computational study of alkane dehydrogenation catalyzed by a carbazolide-based rhodium PNP pincer complex. Chemical Science. 7: 2579-2586. PMID 28660029 DOI: 10.1039/c5sc04794c  1
2016 Kulkarni A, Kumar A, Goldman AS, Celik FE. Selectivity for dimers in pentene oligomerization over acid zeolites Catalysis Communications. 75: 98-102. DOI: 10.1016/j.catcom.2015.11.012  1
2015 Wang DY, Choliy Y, Haibach MC, Hartwig JF, Krogh-Jespersen K, Goldman AS. Assessment of the Electronic Factors Determining the Thermodynamics of 'Oxidative Addition' of C-H and N-H Bonds to Ir(I) Complexes. Journal of the American Chemical Society. PMID 26652221 DOI: 10.1021/jacs.5b09522  1
2015 Kumar A, Zhou T, Emge TJ, Mironov O, Saxton RJ, Krogh-Jespersen K, Goldman AS. Dehydrogenation of n-Alkanes by Solid-Phase Molecular Pincer-Iridium Catalysts. High Yields of α-Olefin Product. Journal of the American Chemical Society. PMID 26200219 DOI: 10.1021/jacs.5b05313  1
2015 Zhou M, Goldman AS. Chlorination of (Phebox)Ir(mesityl)(OAc) by Thionyl Chloride. Molecules (Basel, Switzerland). 20: 10122-30. PMID 26039335 DOI: 10.3390/molecules200610122  1
2015 Fujita E, Goldman AS. Preface for small-molecule activation: carbon-containing fuels. Inorganic Chemistry. 54: 5040-2. PMID 26027480 DOI: 10.1021/acs.inorgchem.5b00790  1
2015 Zhou M, Johnson SI, Gao Y, Emge TJ, Nielsen RJ, Goddard WA, Goldman AS. Activation and Oxidation of Mesitylene C-H Bonds by (Phebox)Iridium(III) Complexes Organometallics. 34: 2879-2888. DOI: 10.1021/acs.organomet.5b00200  1
2015 Kumar A, Goldman AS. Recent advances in alkane dehydrogenation catalyzed by pincer complexes Topics in Organometallic Chemistry. 54: 307-334. DOI: 10.1007/3418_2015_113  1
2014 Baroudi A, El-Hellani A, Bengali AA, Goldman AS, Hasanayn F. Calculation of ionization energy, electron affinity, and hydride affinity trends in pincer-ligated d(8)-Ir((tBu4)PXCXP) complexes: implications for the thermodynamics of oxidative H2 addition. Inorganic Chemistry. 53: 12348-59. PMID 25406031 DOI: 10.1021/ic5015829  1
2014 Laviska DA, Guan C, Emge TJ, Wilklow-Marnell M, Brennessel WW, Jones WD, Krogh-Jespersen K, Goldman AS. Addition of C-C and C-H bonds by pincer-iridium complexes: a combined experimental and computational study. Dalton Transactions (Cambridge, England : 2003). 43: 16354-65. PMID 25250874 DOI: 10.1039/c4dt02043j  1
2014 Haibach MC, Lease N, Goldman AS. Catalytic cleavage of ether C-O bonds by pincer iridium complexes. Angewandte Chemie (International Ed. in English). 53: 10160-3. PMID 25060043 DOI: 10.1002/anie.201402576  1
2014 Hackenberg JD, Kundu S, Emge TJ, Krogh-Jespersen K, Goldman AS. Acid-catalyzed oxidative addition of a C-H bond to a square planar d⁸ iridium complex. Journal of the American Chemical Society. 136: 8891-4. PMID 24896665 DOI: 10.1021/ja503953v  1
2014 Goldman AS, Chen X, Fan M, Frencken JE. Methods and preliminary findings of a cost-effectiveness study of glass-ionomer-based and composite resin sealant materials after 2 yr. European Journal of Oral Sciences. 122: 230-7. PMID 24799118 DOI: 10.1111/eos.12129  0.4
2014 Cheng C, Kim BG, Guironnet D, Brookhart M, Guan C, Wang DY, Krogh-Jespersen K, Goldman AS. Synthesis and characterization of carbazolide-based iridium PNP pincer complexes. Mechanistic and computational investigation of alkene hydrogenation: evidence for an Ir(III)/Ir(V)/Ir(III) catalytic cycle. Journal of the American Chemical Society. 136: 6672-83. PMID 24746026 DOI: 10.1021/ja501572g  1
2014 Allen KE, Heinekey DM, Goldman AS, Goldberg KI. Regeneration of an Iridium(III) complex active for alkane dehydrogenation using molecular oxygen Organometallics. 33: 1337-1340. DOI: 10.1021/om401241e  1
2014 Laviska DA, Field KD, Sparks SM, Goldman AS. The LEEDAR program: Learning Enhanced through Experimental Design and Analysis with Rutgers Acs Symposium Series. 1177: 209-228.  1
2013 Haibach MC, Guan C, Wang DY, Li B, Lease N, Steffens AM, Krogh-Jespersen K, Goldman AS. Olefin hydroaryloxylation catalyzed by pincer-iridium complexes. Journal of the American Chemical Society. 135: 15062-70. PMID 24028199 DOI: 10.1021/ja404566v  1
2013 Dobereiner GE, Yuan J, Schrock RR, Goldman AS, Hackenberg JD. Catalytic synthesis of n-alkyl arenes through alkyl group cross-metathesis. Journal of the American Chemical Society. 135: 12572-5. PMID 23909821 DOI: 10.1021/ja4066392  1
2013 Kundu S, Choi J, Wang DY, Choliy Y, Emge TJ, Krogh-Jespersen K, Goldman AS. Cleavage of ether, ester, and tosylate C(sp3)-O bonds by an iridium complex, initiated by oxidative addition of C-H bonds. Experimental and computational studies. Journal of the American Chemical Society. 135: 5127-43. PMID 23469859 DOI: 10.1021/ja312464b  1
2013 Haibach MC, Wang DY, Emge TJ, Krogh-Jespersen K, Goldman AS. (POP)Rh pincer hydride complexes: Unusual reactivity and selectivity in oxidative addition and olefin insertion reactions Chemical Science. 4: 3683-3692. DOI: 10.1039/c3sc50380a  1
2013 Hasanayn F, Baroudi A, Bengali AA, Goldman AS. Hydrogenation of dimethyl carbonate to methanol by trans -[Ru(H) 2(PNN)(CO)] catalysts: DFT evidence for ion-pair-mediated metathesis paths for C-OMe bond cleavage Organometallics. 32: 6969-6985. DOI: 10.1021/om4005127  1
2013 Allen KE, Heinekey DM, Goldman AS, Goldberg KI. Alkane dehydrogenation by C-H activation at iridium(III) Organometallics. 32: 1579-1582. DOI: 10.1021/om301267c  1
2013 Nawara-Hultzsch AJ, Hackenberg JD, Punji B, Supplee C, Emge TJ, Bailey BC, Schrock RR, Brookhart M, Goldman AS. Rational design of highly active "hybrid" phosphine-phosphinite pincer iridium catalysts for alkane metathesis Acs Catalysis. 3: 2505-2514. DOI: 10.1021/cs400624c  1
2012 Biswas S, Huang Z, Choliy Y, Wang DY, Brookhart M, Krogh-Jespersen K, Goldman AS. Olefin isomerization by iridium pincer catalysts. Experimental evidence for an η3-allyl pathway and an unconventional mechanism predicted by DFT calculations. Journal of the American Chemical Society. 134: 13276-95. PMID 22765770 DOI: 10.1021/ja301464c  1
2012 Haibach MC, Kundu S, Brookhart M, Goldman AS. Alkane metathesis by tandem alkane-dehydrogenation-olefin-metathesis catalysis and related chemistry. Accounts of Chemical Research. 45: 947-58. PMID 22584036 DOI: 10.1021/ar3000713  1
2012 Hasanayn F, Achord P, Braunstein P, Magnier HJ, Krogh-Jespersen K, Goldman AS. Theoretical structure-reactivity study of ethylene insertion into nickel-alkyl bonds. A kinetically significant and unanticipated role of trans influence in determining agostic bond strengths Organometallics. 31: 4680-4692. DOI: 10.1021/om300001n  1
2011 Choi J, Wang DY, Kundu S, Choliy Y, Emge TJ, Krogh-Jespersen K, Goldman AS. Net oxidative addition of C(sp3)-F bonds to iridium via initial C-H bond activation. Science (New York, N.Y.). 332: 1545-8. PMID 21700870 DOI: 10.1126/science.1200514  1
2011 Choi J, MacArthur AH, Brookhart M, Goldman AS. Dehydrogenation and related reactions catalyzed by iridium pincer complexes. Chemical Reviews. 111: 1761-79. PMID 21391566 DOI: 10.1021/cr1003503  1
2011 Vicente BC, Huang Z, Brookhart M, Goldman AS, Scott SL. Reactions of phosphinites with oxide surfaces: a new method for anchoring organic and organometallic complexes. Dalton Transactions (Cambridge, England : 2003). 40: 4268-74. PMID 21384048 DOI: 10.1039/c0dt01369b  1
2011 Ahuja R, Punji B, Findlater M, Supplee C, Schinski W, Brookhart M, Goldman AS. Catalytic dehydroaromatization of n-alkanes by pincer-ligated iridium complexes. Nature Chemistry. 3: 167-71. PMID 21258391 DOI: 10.1038/nchem.946  1
2011 Touzani R, Haibach M, Nawara-Hultzsch AJ, El Kadiri S, Emge TJ, Goldman AS. Synthesis and structural characterization of new polynuclear complexes of 1-hydroxymethyl-3,5-dimethylpyrazole with Ni(II) and Fe(II) Polyhedron. 30: 2530-2534. DOI: 10.1016/j.poly.2011.06.038  1
2011 Zhang X, Wang DY, Emge TJ, Goldman AS. Dehydrogenation of ketones by pincer-ligated iridium: Formation and reactivity of novel enone complexes Inorganica Chimica Acta. 369: 253-259. DOI: 10.1016/j.ica.2010.11.016  1
2011 Choi J, Goldman AS. Ir-catalyzed functionalization of C-H bonds Topics in Organometallic Chemistry. 34: 139-167. DOI: 10.1007/978-3-642-15334-1_6  1
2011 Yuan J, Townsend EM, Schrock RR, Goldman AS, Müller P, Takase MK. Preparation of tungsten-based olefin metathesis catalysts supported on alumina Advanced Synthesis and Catalysis. 353: 1985-1992. DOI: 10.1002/adsc.201100200  1
2011 Goldman AS, Krogh-Jespersen K, Brookhart M. Dehydrogenation and related reactions of alkanes catalyzed by pincerâ-iridium complexes Acs National Meeting Book of Abstracts 1
2010 Goldman AS. Organometallic chemistry: Carbon-carbon bonds get a break. Nature. 463: 435-6. PMID 20110980 DOI: 10.1038/463435a  1
2010 Hebden TJ, Goldberg KI, Heinekey DM, Zhang X, Emge TJ, Goldman AS, Krogh-Jespersen K. Dihydrogen/dihydride or tetrahydride? An experimental and computational investigation of pincer iridium polyhydrides. Inorganic Chemistry. 49: 1733-42. PMID 20095648 DOI: 10.1021/ic902163w  1
2010 Punji B, Emge TJ, Goldman AS. A highly stable adamantyl-substituted pincer-ligated iridium catalyst for alkane dehydrogenation Organometallics. 29: 2702-2709. DOI: 10.1021/om100145q  1
2010 Huang Z, Rolfe E, Carson EC, Brookhart M, Goldman AS, El-Khalafy SH, Roy MacArthur AH. Efficient heterogeneous dual catalyst systems for alkane metathesis Advanced Synthesis and Catalysis. 352: 125-135. DOI: 10.1002/adsc.200900539  1
2009 Goldman AS. Bioinorganic chemistry: Bond breaking bacteria-style. Nature Chemistry. 1: 109-10. PMID 21378820 DOI: 10.1038/nchem.191  1
2009 Choi J, Choliy Y, Zhang X, Emge TJ, Krogh-Jespersen K, Goldman AS. Cleavage of sp3 C-O bonds via oxidative addition of C-H bonds. Journal of the American Chemical Society. 131: 15627-9. PMID 19827768 DOI: 10.1021/ja906930u  1
2009 Kundu S, Choliy Y, Zhuo G, Ahuja R, Emge TJ, Warmuth R, Brookhart M, Krogh-Jespersen K, Goldman AS. Rational design and synthesis of highly active pincer-iridium catalysts for alkane dehydrogenation Organometallics. 28: 5432-5444. DOI: 10.1021/om900568f  1
2009 Bailey BC, Schrock RR, Kundu S, Goldman AS, Huang Z, Brookhart M. Evaluation of molybdenum and tungsten metathesis catalysts for homogeneous tandem alkane metathesis Organometallics. 28: 355-360. DOI: 10.1021/om800877q  1
2009 Huang Z, Brookhart M, Goldman AS, Kundu S, Ray A, Scott SL, Vicente BC. Highly active and recyclable heterogeneous iridium pincer catalysts for transfer dehydrogenation of alkanes Advanced Synthesis and Catalysis. 351: 188-206. DOI: 10.1002/adsc.200800615  1
2009 Decker L, Goldman AS. Alkane metathesis by tandem alkane dehydrogenation and olefin metathesis: Modeling the selectivity for carbon-number Acs National Meeting Book of Abstracts 1
2009 Goldman AS, Brookhart M, Huang Z, Krogh-Jespersen K, Kundu S, Scott SL. Transition-metal-based catalytic systems for the dehydrogenation and metathesis of alkanes: Solution-phase and solid-supported iridium-based pincer catalysts Acs National Meeting Book of Abstracts 1
2009 Biswas S, Choliy Y, Krogh-Jespersen K, Brookhart M, Goldman AS. Regioselectivity in the transfer-dehydrogenation of alkanes by two pincer-iridium-based catalysts Acs National Meeting Book of Abstracts 1
2009 Hebden TJ, Piccoli PMB, Koetzle TF, Schultz AJ, Goldberg KI, Heinekey DM, Emge TJ, Krogh-Jespersen K, Goldman AS. Structural investigations of Ir pincer complexes relevant to catalytic H2 release from the chemical hydrogen storage material H3BNH3 Acs National Meeting Book of Abstracts 1
2008 Ghosh R, Emge TJ, Krogh-Jespersen K, Goldman AS. Combined experimental and computational studies on carbon-carbon reductive elimination from Bis(hydrocarbyl) complexes of (PCP)Ir. Journal of the American Chemical Society. 130: 11317-27. PMID 18680287 DOI: 10.1021/ja800434r  1
2008 Ahuja R, Kundu S, Goldman AS, Brookhart M, Vicente BC, Scott SL. Catalytic ring expansion, contraction, and metathesis-polymerization of cycloalkanes. Chemical Communications (Cambridge, England). 253-5. PMID 18092104 DOI: 10.1039/b712197k  1
2008 Hasanayn F, Nsouli NH, Al-Ayoubi A, Goldman AS. Addition of alkyl radicals to transition-metal-coordinated CO: calculation of the reaction of [Ru(CO)5] and related complexes and relevance to alkane carbonylation. Journal of the American Chemical Society. 130: 511-21. PMID 18081278 DOI: 10.1021/ja072704f  1
2008 Pelczar EM, Emge TJ, Krogh-Jespersen K, Goldman AS. Unusual structural and spectroscopic features of some PNP-pincer complexes of iron Organometallics. 27: 5759-5767. DOI: 10.1021/om800425p  1
2008 Stavropoulos P, Çelenligil-Çetin R, Kiani S, Tapper A, Pinnapareddy D, Paraskevopoulou P, Adam W, Zhao CG, Bühler B, Schmid A, Bhalla G, Mironov O, Jones CJ, Tenn WJ, Nakamura S, ... ... Goldman AS, et al. C-H Transformation at Unfunctionalized Alkanes Handbook of C-H Transformations: Applications in Organic Synthesis. 2: 497-651. DOI: 10.1002/9783527619450.ch9  1
2008 Biswas S, Ahuja R, Ray A, Choliy Y, Krogh-Jespersen K, Brookhart M, Goldman AS. A tale of two ligands. Subtle differences in sterics exert major differences in the energetics of alkane dehydrogenation catalyzed by pincer complexes (tBuPCP)Ir vs. (tBuPOCOP)Ir Acs National Meeting Book of Abstracts 1
2007 Pelczar EM, Emge TJ, Goldman AS. A mixed-valence chloride-bridged (pincer)Ir(III)-(diene)Ir(I) complex. Acta Crystallographica. Section C, Crystal Structure Communications. 63: m323-6. PMID 17609557 DOI: 10.1107/S0108270107022378  1
2007 Ghosh R, Zhang X, Achord P, Emge TJ, Krogh-Jespersen K, Goldman AS. Dimerization of alkynes promoted by a pincer-ligated iridium complex. C-C reductive elimination inhibited by steric crowding. Journal of the American Chemical Society. 129: 853-66. PMID 17243822 DOI: 10.1021/ja0647194  1
2006 Goldman AS, Roy AH, Huang Z, Ahuja R, Schinski W, Brookhart M. Catalytic alkane metathesis by tandem alkane dehydrogenation-olefin metathesis. Science (New York, N.Y.). 312: 257-61. PMID 16614220 DOI: 10.1126/science.1123787  1
2006 Ghosh R, Kanzelberger M, Emge TJ, Hall GS, Goldman AS. Dinitrogen complexes of pincer-ligated iridium Organometallics. 25: 5668-5671. DOI: 10.1021/om0607043  1
2006 Zhang X, Emge TJ, Ghosh R, Krogh-Jespersen K, Goldman AS. Reaction of nitromethane with an iridium pincer complex. Multiple binding modes of the nitromethanate anion Organometallics. 25: 1303-1309. DOI: 10.1021/om050659j  1
2006 Ray A, Kissin YV, Zhu K, Goldman AS, Cherian AE, Coates GW. Catalytic post-modification of alkene polymers. Chemistry and kinetics of dehydrogenation of alkene polymers and oligomers with pincer Ir complexes Journal of Molecular Catalysis a: Chemical. 256: 200-207. DOI: 10.1016/j.molcata.2006.04.017  1
2005 Ray A, Zhu K, Kissin YV, Cherian AE, Coates GW, Goldman AS. Dehydrogenation of aliphatic polyolefins catalyzed by pincer-ligated iridium complexes. Chemical Communications (Cambridge, England). 3388-90. PMID 15997273 DOI: 10.1039/b502120k  1
2005 Zhang X, Emge TJ, Ghosh R, Goldman AS. Selective cleavage of the C-C bonds of aminoethyl groups, via a multistep pathway, by a pincer iridium complex. Journal of the American Chemical Society. 127: 8250-1. PMID 15941235 DOI: 10.1021/ja051300p  1
2005 Zhao J, Goldman AS, Hartwig JF. Oxidative addition of ammonia to form a stable monomeric amido hydride complex. Science (New York, N.Y.). 307: 1080-2. PMID 15718464 DOI: 10.1126/science.1109389  1
2004 Zhang X, Kanzelberger M, Emge TJ, Goldman AS. Selective addition to iridium of aryl C-H bonds ortho to coordinating groups. Not chelation-assisted. Journal of the American Chemical Society. 126: 13192-3. PMID 15479051 DOI: 10.1021/ja046476q  1
2004 Zhu K, Achord PD, Zhang X, Krogh-Jespersen K, Goldman AS. Highly effective pincer-ligated iridium catalysts for alkane dehydrogenation. DFT calculations of relevant thermodynamic, kinetic, and spectroscopic properties. Journal of the American Chemical Society. 126: 13044-53. PMID 15469303 DOI: 10.1021/ja047356l  1
2004 Fang JB, Sanghi R, Kohn J, Goldman AS. Tantalum pentachloride as a coupling agent for stereohindered amide bond formation Inorganica Chimica Acta. 357: 2415-2426. DOI: 10.1016/j.ica.2004.03.007  1
2004 Zhang X, Emge TJ, Goldman AS. A hexanuclear iridium complex with a novel binding mode of a PCP-pincer ligand Inorganica Chimica Acta. 357: 3014-3018. DOI: 10.1016/j.ica.2004.02.026  1
2003 Kanzelberger M, Zhang X, Emge TJ, Goldman AS, Zhao J, Incarvito C, Hartwig JF. Distinct thermodynamics for the formation and cleavage of N-H bonds in aniline and ammonia. Directly-observed reductive elimination of ammonia from an isolated amido hydride complex. Journal of the American Chemical Society. 125: 13644-5. PMID 14599186 DOI: 10.1021/ja037363u  1
2003 Zhang X, Fried A, Knapp S, Goldman AS. Novel synthesis of enamines by iridium-catalyzed dehydrogenation of tertiary amines. Chemical Communications (Cambridge, England). 2060-1. PMID 12934911  1
2003 Renkema KB, Kissin YV, Goldman AS. Mechanism of alkane transfer-dehydrogenation catalyzed by a pincer-ligated iridium complex. Journal of the American Chemical Society. 125: 7770-1. PMID 12822973 DOI: 10.1021/ja0289200  1
2003 Zhang X, Emge TJ, Goldman AS. Synthesis and crystal structure of a coordinatively unsaturated organomercury iridium complex (PCP)Ir(HgPh)Cl (PCP = η3-2,6- (tBu2PCH2)2C6H 3) Journal of Chemical Crystallography. 33: 613-617. DOI: 10.1023/A:1024997827607  1
2002 Krogh-Jespersen K, Czerw M, Summa N, Renkema KB, Achord PD, Goldman AS. On the mechanism of (PCP)Ir-catalyzed acceptorless dehydrogenation of alkanes: a combined computational and experimental study. Journal of the American Chemical Society. 124: 11404-16. PMID 12236755 DOI: 10.1021/ja012460d  1
2002 Krogh-Jespersen K, Czerw M, Zhu K, Singh B, Kanzelberger M, Darji N, Achord PD, Renkema KB, Goldman AS. Combined computational and experimental study of substituent effects on the thermodynamics of H(2), CO, arene, and alkane addition to iridium. Journal of the American Chemical Society. 124: 10797-809. PMID 12207536 DOI: 10.1021/ja010547t  1
2002 Krogh-Jespersen K, Czerw M, Goldman AS. Computational and experimental studies of the mechanism of (PCP)Ir-catalyzed acceptorless dehydrogenation of alkanes Journal of Molecular Catalysis a: Chemical. 189: 95-110. DOI: 10.1016/S1381-1169(02)00199-1  1
2001 Krogh-Jespersen K, Czerw M, Kanzelberger M, Goldman AS. DFT/ECP study of C-H activation by (PCP)Ir and (PCP)Ir(H)2(PCP=eta3-1,3-C6H3(CH2PR2)2). Enthalpies and free energies of associative and dissociative pathways. Journal of Chemical Information and Computer Sciences. 41: 56-63. PMID 11206383 DOI: 10.1021/ci000061g  1
2000 Czerw M, Goldman AS, Krogh-Jespersen K. Addition of ammonia to AlH3 and BH3. Why does only aluminum form 2:1 adducts? Inorganic Chemistry. 39: 363-9. PMID 11272548 DOI: 10.1021/ic990961i  1
2000 Kanzelberger M, Singh B, Czerw M, Krogh-Jespersen K, Goldman AS. Addition of C-H bonds to the catalytically active complex (PCP)Ir (PCP = η3-2,6-((t)Bu2PCH2)2C6H3) [7] Journal of the American Chemical Society. 122: 11017-11018. DOI: 10.1021/ja001626s  1
1999 Liu F, Pak EB, Singh B, Jensen CM, Goldman AS. Dehydrogenation of n-alkanes catalyzed by iridium 'pincer' complexes: Regioselective formation of α-olefins Journal of the American Chemical Society. 121: 4086-4087. DOI: 10.1021/ja983460p  1
1999 Krogh-Jespersen K, Goldman AS. Transition states for oxidative addition to three-coordinate Ir(I): H-H, C-H, C-C, and C-F bond activation processes Acs Symposium Series. 721: 151-162.  1
1999 Liu F, Goldman AS. Efficient thermochemical alkane dehydrogenation and isomerization catalyzed by an iridium pincer complex Chemical Communications. 655-656.  1
1998 Rosini GP, Liu F, Krogh-Jespersen K, Goldman AS, Li C, Nolan SP. Thermodynamics of addition of H2, Co, N2, and C-H bonds to M(P(i)Pr3)2Cl (M = Ir, Rh). An unprecedented metal-carbonyl bond strength Journal of the American Chemical Society. 120: 9256-9266. DOI: 10.1021/ja974100p  1
1998 Rosini GP, Wang K, Patel B, Goldman AS. A mechanistic study of thermal C-H reductive elimination from a six-coordinate d6 indium complex Inorganica Chimica Acta. 270: 537-542.  1
1998 Rosini GP, Soubra S, Vixamar M, Wang S, Goldman AS. Kinetics of photochemical alkane dehydrogenation catalyzed by Rh(PMe3)2(CO)Cl: Implications concerning the C-H bond activation step Journal of Organometallic Chemistry. 554: 41-47.  1
1997 Kelly AM, Rosini GP, Goldman AS. Oxygen transfer from organoelement oxides to carbon monoxide catalyzed by transition metal carbonyls Journal of the American Chemical Society. 119: 6115-6125. DOI: 10.1021/ja970158s  1
1997 Xu WW, Rosini GP, Gupta M, Jensen CM, Kaska WC, Krogh-Jespersen K, Goldman AS. Thermochemical alkane dehydrogenation catalyzed in solution without the use of a hydrogen acceptor Chemical Communications. 2273-2274.  1
1997 Wang K, Emge TJ, Goldman AS. Crystal and molecular structure of a novel coordinatively unsaturated rhodium (II) dimer Inorganica Chimica Acta. 255: 395-398.  1
1996 Goldman AS, Krogh-Jespersen K. Why do cationic carbon monoxide complexes have high C-O stretching force constants and short C-O bonds? Electrostatic effects, not σ-bonding Journal of the American Chemical Society. 118: 12159-12166. DOI: 10.1021/ja960876z  1
1996 Wang K, Goldman ME, Emge TJ, Goldman AS. Transfer-dehydrogenation of alkanes catalyzed by rhodium(I) phosphine complexes Journal of Organometallic Chemistry. 518: 55-68.  1
1995 Wang K, Emge TJ, Goldman AS, Li C, Nolan SP. Addition of aldehydes and acyl chlorides to [Rh(PiPr3)2Cl]2. Thermodynamics and molecular and crystal structures of Rh(PiPr3)2ClX[C(O)Ph] (X = H, Cl) Organometallics. 14: 4929-4936.  1
1995 Wang K, Goldman AS, Li C, Nolan SP. Thermodynamic studies of the addition of N2, C2H4, and alkynes to [Rh(PiPr3)2Cl]2 Organometallics. 14: 4010-4013.  1
1995 Rosini GP, Zhu K, Goldman AS. On the mechanism and regioselectivity of alkane photocarbonylation catalyzed by Rh(PMe3)2(CO)Cl Journal of Organometallic Chemistry. 504: 115-121.  1
1995 Wang K, Rosini GP, Nolan SP, Goldman AS. Thermodynamics of addition of CO, isocyanide, and H2 to Rh(PR3)2Cl Journal of the American Chemical Society. 117: 5082-5088.  1
1994 Abu-Hasanayn F, Goldman AS, Krogh-Jespersen K. Ab initio molecular orbital study of substituent effects in Vaska type complexes (trans-IrL2(CO)X): Electron affinities, ionization potentials, carbonyl stretch frequencies, and the thermodynamics of H2 dissociative addition Inorganic Chemistry. 33: 5122-5130.  1
1994 Abu-Hasanayn F, Emge TJ, Maguire JA, Krogh-Jespersen K, Goldman AS. Computational, spectroscopic, and crystallographic determination of the molecular structures of CO adducts of Vaska-type complexes trans-IrL2(CO)2X Organometallics. 13: 5177-5180.  1
1994 Rosini GP, Boese WT, Goldman AS. Study of the mechanism of photochemical carbonylation of benzene catalyzed by Rh(PMe3)2(CO)Cl Journal of the American Chemical Society. 116: 9498-9505.  1
1994 Abu-Hasanayn F, Krogh-Jespersen K, Goldman AS. Carbon monoxide addition to transition metal complexes: Bent metal carbonyl transition states Journal of the American Chemical Society. 116: 5979-5980.  1
1994 Wang K, Emge TJ, Goldman AS. Synthesis and structure of a (diphosphoxane)rhodium(I) complex. Novel reaction with CO to liberate phosphinidene oxide Organometallics. 13: 2135-2137.  1
1993 Abu-Hasanayn F, Goldman AS, Krogh-Jespersen K. Computational study of the transition state for H2 addition to Vaska-type complexes (trans-Ir(L)2(CO)X): Substituent effects on the energy barrier and the origin of the small H2/D2 kinetic isotope effect Journal of Physical Chemistry. 97: 5890-5896.  1
1993 Shih KC, Goldman AS. Alkane dehydrogenation catalyzed by rhodium(I) phosphine complexes: Observation of the stoichiometric alkane-to-rhodium hydrogen-transfer step Organometallics. 12: 3390-3392.  1
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