Claude F. Bernasconi
Affiliations: | Chemistry & Biochemistry | University of California, Santa Cruz, Santa Cruz, CA, United States |
Area:
Physical and Mechanistic Organic Chemistry and Organometallic Chemistry, Chemical Reactivity, Kinetics, Ab Initio CalculationsWebsite:
https://news.ucsc.edu/2021/01/bernasconi-in-memoriam.htmlGoogle:
"Claude F. Bernasconi"Bio:
(1939 - 2021)
Bernasconi, Claude, Beitrag zur Aufklärung des Mechanismus der aromatischen nukleophilen Substitution, Zürich (1965)
Bernasconi, Claude F., The principle of nonperfect synchronization: more than a qualitative concept?, Acc. Chem. Res., 1992, 25 (1), pp 9–16, January 1992
Mean distance: 8.66
Parents
Sign in to add mentor| Heinrich Zollinger | grad student | 1965 | ETH Zürich | |
| (Beitrag zur Aufklärung des Mechanismus der aromatischen nukleophilen Substitution) | ||||
| Manfred Eigen | post-doc | 1967 | Max-Planck-Institut für Physikalische Chemie, Göttingen | |
Children
Sign in to add trainee| Robert B Killion | grad student | 1988 | UC Santa Cruz |
| Kevin W. Kittredge | grad student | 1998 | UC Santa Cruz |
| Viola C. Ruddat | grad student | 2002 | UC Santa Cruz |
| Jeffrey T. Gautschi | grad student | 2006 | UC Santa Cruz |
| Huaiben Zheng | grad student | 2006 | UC Santa Cruz |
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Publications
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| Bernasconi CF. (2013) The role of solvent reorganization in proton transfer and nucleophilic addition reactions Pure and Applied Chemistry. 54: 2335-2348 |
| Bernasconi CF, Wenzel PJ. (2010) Effect of transition state aromaticity and antiaromaticity on intrinsic barriers of proton transfers in aromatic and antiaromatic heterocyclic systems; an ab initio study. The Journal of Organic Chemistry. 75: 8422-34 |
| Bernasconi CF. (2010) The principle of nonperfect synchronization: recent developments Advances in Physical Organic Chemistry. 44: 223-324 |
| Bernasconi CF, Rappoport Z. (2009) Recent advances in our mechanistic understanding of S(N)V reactions. Accounts of Chemical Research. 42: 993-1003 |
| Bernasconi CF, Yamataka H, Yoshimura N, et al. (2009) Deprotonation of 3(2H)-furanone and 3(2H)-thiophenone by carbanions in the gas phase: Disproportionately high aromaticity of the transition state: An ab initio study Journal of Organic Chemistry. 74: 188-196 |
| Bernasconi CF. (2009) Proton transfers in aromatic systems: How aromatic is the transition state? Pure and Applied Chemistry. 81: 649-665 |
| Karni M, Bernasconi CF, Rappoport Z. (2008) Role of negative hyperconjugation and anomeric effects in the stabilization of the intermediate in SNV reactions. The Journal of Organic Chemistry. 73: 2980-94 |
| Bernasconi CF, Wenzel PJ, Ragains ML. (2008) Proton transfers in aromatic and antiaromatic systems. How aromatic or antiaromatic is the transition state? An ab initio study. Journal of the American Chemical Society. 130: 4934-44 |
| Bernasconi CF, Pérez-Lorenzo M, Codding SJ. (2007) Reactions of [aryloxy(phenyl)carbene]pentacarbonylchromium(0) complexes with thiolate ions. Decreasing reactivity with increasing basicity of the nucleophile Journal of Organic Chemistry. 72: 9456-9463 |
| Bernasconi CF, Pérez-Lorenzo M, Brown SD. (2007) Kinetics of the deprotonation of methylnitroacetate by amines: unusually high intrinsic rate constants for a nitroalkane. The Journal of Organic Chemistry. 72: 4416-23 |