Sandro Gambarotta - Publications

Affiliations: 
Chemistry University of Ottawa, Ottawa, ON, Canada 
Area:
Organic Chemistry

266 high-probability publications. We are testing a new system for linking publications to authors. You can help! If you notice any inaccuracies, please sign in and mark papers as correct or incorrect matches. If you identify any major omissions or other inaccuracies in the publication list, please let us know.

Year Citation  Score
2019 Gambarotta S, Viasus CJ, Gabidullin B. Linear and Bridging End-On coordination modes of CO2 on vanadium(II) and (III) aryloxides. Angewandte Chemie (International Ed. in English). PMID 31329324 DOI: 10.1002/Ange.201907651  0.373
2019 Alderman NP, Peneau V, Viasus CJ, Korobkov I, Vidjayacoumar B, Albahily K, Gambarotta S. Efficient reduction of formic acid to formaldehyde by zinc Canadian Journal of Chemistry. 97: 42-45. DOI: 10.1139/Cjc-2018-0284  0.693
2019 Alderman NP, Peneau V, Viasus CJ, Korobkov I, Vidjayacoumar B, Albahily K, Gambarotta S. Syn-gas from waste: the reduction of CO2 with H2S Reaction Chemistry & Engineering. 4: 763-771. DOI: 10.1039/C8Re00334C  0.687
2019 Viasus CJ, Alderman NP, Peneau V, Gabidullin B, Vidjayacoumar B, Albahily K, Gambarotta S. Two-step catalytic dehydrogenation of formic acid to CO2 via formaldehyde International Journal of Hydrogen Energy. 44: 1534-1543. DOI: 10.1016/J.Ijhydene.2018.11.178  0.709
2018 Gambarotta S, Peres-Viasus CX, Alderman N, Gabidullin B. Reaction of CO2 with a Vanadium(II) Aryloxide: Synergistic Activation of CO2/-oxo Groups towards H-Atom Radical Extraction. Angewandte Chemie (International Ed. in English). PMID 29949678 DOI: 10.1002/Anie.201805569  0.373
2018 Afzali SH, Alzamly A, Firouzi R, Korobkov I, Gambarotta S. Radical chemistry of alkyl aluminum with quinoxaline ligands Journal of Coordination Chemistry. 71: 1234-1249. DOI: 10.1080/00958972.2018.1450977  0.33
2017 Gambarotta S, Viasus C, Alderman N, Korobkov I, Licciulli S. Radical behavior of CO2 versus its deoxygenation promoted by vanadium aryloxide complexes: how the geometry of intermediate CO2-adducts determines the reactivity. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 29030892 DOI: 10.1002/Chem.201702943  0.354
2015 Kulangara SV, Haveman D, Vidjayacoumar B, Korobkov I, Gambarotta S, Duchateau R. Effect of Cocatalysts and Solvent on Selective Ethylene Oligomerization Organometallics. 34: 1203-1210. DOI: 10.1021/Om501013M  0.386
2014 Alzamly A, Gorelsky SI, Gambarotta S, Korobkov I, Le Roy J, Murugesu M. Chromium-chromium interaction in a binuclear mixed-valent Cr(I)-Cr(II) complex. Inorganic Chemistry. 53: 11492-7. PMID 25310604 DOI: 10.1021/Ic501404V  0.397
2014 Alzamly A, Gambarotta S, Korobkov I, Murugesu M, Le Roy JJ, Budzelaar PH. Isolation of a hexanuclear chromium cluster with a tetrahedral hydridic core and its catalytic behavior for ethylene oligomerization. Inorganic Chemistry. 53: 6073-81. PMID 24874446 DOI: 10.1021/Ic500445B  0.446
2014 Yang Y, Gurnham J, Liu B, Duchateau R, Gambarotta S, Korobkov I. Selective ethylene oligomerization with chromium complexes bearing pyridine-phosphine ligands: Influence of ligand structure on catalytic behavior Organometallics. 33: 5749-5757. DOI: 10.1021/Om5003683  0.403
2014 Alzamly A, Gambarotta S, Korobkov I. Reactivity with alkylaluminum of a chromium complex of a pyridine-containing PNP ligand: Redox N-P bond cleavage Organometallics. 33: 1602-1607. DOI: 10.1021/Om401129W  0.467
2013 Alzamly A, Gambarotta S, Korobkov I. Polymer-free ethylene oligomerization using a pyridine-based pincer PNP-type of ligand Organometallics. 32: 7204-7212. DOI: 10.1021/Om4008828  0.477
2013 Alzamly A, Gambarotta S, Korobkov I. Synthesis, structures, and ethylene oligomerization activity of bis(phosphanylamine)pyridine chromium/aluminate complexes Organometallics. 32: 7107-7115. DOI: 10.1021/Om4008289  0.472
2013 Shuster V, Gambarotta S, Nikiforov GB, Budzelaar PHM. Heterometallic aluminum-chromium phenazine and thiophenazine complexes. formation of a tetranuclear chromium(I) sandwich complex Organometallics. 32: 2329-2335. DOI: 10.1021/Om3012097  0.472
2012 Shaikh Y, Albahily K, Sutcliffe M, Fomitcheva V, Gambarotta S, Korobkov I, Duchateau R. A highly selective ethylene tetramerization catalyst. Angewandte Chemie (International Ed. in English). 51: 1366-9. PMID 22223188 DOI: 10.1002/Anie.201106517  0.736
2012 Shuster V, Gambarotta S, Nikiforov GB, Korobkov I, Budzelaar PHM. Radical cleavage of Al-C bonds promoted by phenazine: From noninnocent ligand to radical abstractor Organometallics. 31: 7011-7019. DOI: 10.1021/Om300889M  0.393
2012 Shaikh Y, Gurnham J, Albahily K, Gambarotta S, Korobkov I. Aminophosphine-based chromium catalysts for selective ethylene tetramerization Organometallics. 31: 7427-7433. DOI: 10.1021/Om3007135  0.759
2012 Kulangara SV, Mason C, Juba M, Yang Y, Thapa I, Gambarotta S, Korobkov I, Duchateau R. Synthesis and catalytic oligomerization activity of chromium catalysts of ligand systems with switchable connectivity Organometallics. 31: 6438-6449. DOI: 10.1021/Om300673U  0.757
2012 Kulangara SV, Jabri A, Yang Y, Korobkov I, Gambarotta S, Duchateau R. Synthesis, X-ray structural analysis, and ethylene polymerization studies of group IV metal heterobimetallic aluminum-pyrrolyl complexes Organometallics. 31: 6085-6094. DOI: 10.1021/Om300453A  0.435
2012 Thapa I, Gambarotta S, Korobkov I, Murugesu M, Budzelaar P. Isolation and characterization of a class II mixed-valence chromium(I)/(II) self-activating ethylene trimerization catalyst Organometallics. 31: 486-494. DOI: 10.1021/Om201181N  0.739
2011 Zhu D, Thapa I, Korobkov I, Gambarotta S, Budzelaar PH. Redox-active ligands and organic radical chemistry. Inorganic Chemistry. 50: 9879-87. PMID 21520927 DOI: 10.1021/Ic2002145  0.744
2011 Albahily K, Shaikh Y, Sebastiao E, Gambarotta S, Korobkov I, Gorelsky SI. Vinyl oxidative coupling as a synthetic route to catalytically active monovalent chromium. Journal of the American Chemical Society. 133: 6388-95. PMID 21469645 DOI: 10.1021/Ja201003J  0.754
2011 Albahily K, Fomitcheva V, Gambarotta S, Korobkov I, Murugesu M, Gorelsky SI. Preparation and characterization of a reduced chromium complex via vinyl oxidative coupling: formation of a self-activating catalyst for selective ethylene trimerization. Journal of the American Chemical Society. 133: 6380-7. PMID 21469643 DOI: 10.1021/Ja200593K  0.781
2011 Licciulli S, Albahily K, Fomitcheva V, Korobkov I, Gambarotta S, Duchateau R. A chromium ethylidene complex as a potent catalyst for selective ethylene trimerization. Angewandte Chemie (International Ed. in English). 50: 2346-9. PMID 21351351 DOI: 10.1002/Anie.201006953  0.761
2011 Albahily K, Ahmed Z, Gambarotta S, Koc E, Duchateau R, Korobkov I. New iminophosphonamide chromium(II) complexes as highly active polymer-free ethylene oligomerization catalysts Organometallics. 30: 6022-6027. DOI: 10.1021/Om2008474  0.757
2011 Albahily K, Fomitcheva V, Shaikh Y, Sebastiao E, Gorelsky SI, Gambarotta S, Korobkov I, Duchateau R. New self-activating organochromium catalyst precursor for selective ethylene trimerization Organometallics. 30: 4201-4210. DOI: 10.1021/Om200560E  0.753
2011 Albahily K, Gambarotta S, Duchateau R. Ethylene oligomerization promoted by a silylated-SNS chromium system Organometallics. 30: 4655-4664. DOI: 10.1021/Om200505A  0.74
2011 Albahily K, Shaikh Y, Ahmed Z, Korobkov I, Gambarotta S, Duchateau R. Isolation of a self-activating ethylene trimerization catalyst of a Cr-SNS system Organometallics. 30: 4159-4164. DOI: 10.1021/Om2004699  0.742
2011 Albahily K, Licciulli S, Gambarotta S, Korobkov I, Chevalier R, Schuhen K, Duchateau R. Highly active ethylene oligomerization catalysts Organometallics. 30: 3346-3352. DOI: 10.1021/Om2002359  0.744
2010 Licciulli S, Thapa I, Albahily K, Korobkov I, Gambarotta S, Duchateau R, Chevalier R, Schuhen K. Towards selective ethylene tetramerization. Angewandte Chemie (International Ed. in English). 49: 9225-8. PMID 20963738 DOI: 10.1002/Anie.201003465  0.767
2010 Ilango S, Vidjayacoumar B, Gambarotta S. Samarium complexes of a sigma-/pi-pyrrolide/arene based macrocyclic ligand. Dalton Transactions (Cambridge, England : 2003). 39: 6853-7. PMID 20495730 DOI: 10.1039/C002514N  0.451
2010 Korobkov I, Gambarotta S. Ligand metalation in the reactivity of a tetravalent uranium amides. Inorganic Chemistry. 49: 3409-18. PMID 20201603 DOI: 10.1021/Ic902567M  0.45
2010 Korobkov I, Vidjayacoumar B, Gorelsky SI, Bilione P, Gambarotta S. Attempting to reduce the irreducible: Preparation of a rare paramagnetic thorium species Organometallics. 29: 692-702. DOI: 10.1021/Om900996N  0.428
2010 Thapa I, Gambarotta S, Korobkov I, Duchateau R, Kulangara SV, Chevalier R. Switchable chromium(II) complexes of a chelating amidophosphine (N-P) for selective and nonselective ethylene oligomerization Organometallics. 29: 4080-4089. DOI: 10.1021/Om1006006  0.757
2009 Vidyaratne I, Nikiforov GB, Gorelsky SI, Gambarotta S, Duchateau R, Korobkov I. Isolation of a self-activating ethylene trimerization catalyst. Angewandte Chemie (International Ed. in English). 48: 6552-6. PMID 19637172 DOI: 10.1002/Anie.200900957  0.329
2009 Korobkov I, Gorelsky S, Gambarotta S. Reduced uranium complexes: synthetic and DFT study of the role of pi ligation in the stabilization of uranium species in a formal low-valent state. Journal of the American Chemical Society. 131: 10406-20. PMID 19588963 DOI: 10.1021/Ja9002525  0.453
2009 Korobkov I, Gambarotta S. Unusual reactivity of a Tm-pyrrolide/aluminate complex with a metallocene-type structural motif Organometallics. 28: 5560-5567. DOI: 10.1021/Om900604H  0.428
2009 Korobkov I, Gambarotta S. Aluminate samarium(II) and samarium(III) aryloxides. Isolation of a single-component ethylene polymerization catalyst Organometallics. 28: 4009-4019. DOI: 10.1021/Om900172N  0.469
2008 Horvath S, Gorelsky SI, Gambarotta S, Korobkov I. Breaking the 1.80 A barrier of the Cr-Cr multiple bond between Cr(II) atoms. Angewandte Chemie (International Ed. in English). 47: 9937-40. PMID 19003840 DOI: 10.1002/Anie.200804048  0.308
2008 Albahily K, Koç E, Al-Baldawi D, Savard D, Gambarotta S, Burchell TJ, Duchateau R. Chromium catalysts supported by a nonspectator NPN ligand: isolation of single-component chromium polymerization catalysts. Angewandte Chemie (International Ed. in English). 47: 5816-9. PMID 18576438 DOI: 10.1002/Anie.200800845  0.709
2008 Ilango S, Vidjayacoumar B, Gambarotta S, Gorelsky SI. Low-valent vanadium complexes of a pyrrolide-based ligand. Electronic structure of a dimeric V(I) complex with a short and weak metal-metal bond. Inorganic Chemistry. 47: 3265-73. PMID 18311887 DOI: 10.1021/Ic702280G  0.42
2008 Scott J, Vidyaratne I, Korobkov I, Gambarotta S, Budzelaar PH. Multiple pathways for dinitrogen activation during the reduction of an Fe Bis(iminepyridine) complex. Inorganic Chemistry. 47: 896-911. PMID 18173261 DOI: 10.1021/Ic701643D  0.46
2008 Albahily K, Al-Baldawi D, Gambarotta S, Koç E, Duchateau R. Isolation of a chromium hydride single-component ethylene polymerization catalyst Organometallics. 27: 5943-5947. DOI: 10.1021/Om800773K  0.762
2008 Albahily K, Al-Baldawi D, Gambarotta S, Duchateau R, Koç E, Burchell TJ. Preparation and characterization of a switchable single-component chromium trimerization catalyst Organometallics. 27: 5708-5711. DOI: 10.1021/Om800563W  0.76
2007 Vidyaratne I, Crewdson P, Lefebvre E, Gambarotta S. Dinitrogen coordination and cleavage promoted by a vanadium complex of a sigma,pi,sigma-donor ligand. Inorganic Chemistry. 46: 8836-42. PMID 17883267 DOI: 10.1021/Ic701219H  0.468
2007 Vidyaratne I, Scott J, Gambarotta S, Budzelaar PH. Dinitrogen activation, partial reduction, and formation of coordinated imide promoted by a chromium diiminepyridine complex. Inorganic Chemistry. 46: 7040-9. PMID 17649991 DOI: 10.1021/Ic700810F  0.425
2007 Jabri A, Korobkov I, Gambarotta S, Duchateau R. Single-site, single-component catalysts for very high molecular weight polyethylene: a robust "ready-to-go" vanadium pi-bonded complex without a preformed V-C bond. Angewandte Chemie (International Ed. in English). 46: 6119-22. PMID 17628472 DOI: 10.1002/Anie.200701703  0.36
2007 Cozzi PG, Gambarotta S, Monari M, Zoli L. Convenient preparation of chiral dipyrrolylmethanes containing a chiral moiety Collection of Czechoslovak Chemical Communications. 72: 1046-1056. DOI: 10.1135/Cccc20071046  0.535
2007 Temple CN, Gambarotta S, Korobkov I, Duchateau R. New insight into the role of the metal oxidation state in controlling the selectivity of the Cr-(SNS) ethylene trimerization catalyst Organometallics. 26: 4598-4603. DOI: 10.1021/Om700452U  0.375
2007 Vidyaratne I, Scott J, Gambarotta S, Duchateau R. Reactivity of chromium complexes of a bis(imino)pyridine ligand: Highly active ethylene polymerization catalysts carrying the metal in a formally low oxidation state Organometallics. 26: 3201-3211. DOI: 10.1021/Om0701423  0.45
2007 Nikiforov GB, Crewdson P, Gambarotta S, Korobkov I, Budzelaar PHM. Reduction of titanium supported by a σ-/π-bonded tripyrrole ligand: Ligand C-N bond cleavage and coordination of olefin and arene with an inverse sandwich structure Organometallics. 26: 48-55. DOI: 10.1021/Om060908J  0.432
2007 Johnson AR, Cummins CC, Gambarotta S. N‐Tert‐Alkyl‐anilides as Bulky Anciliary Ligands Inorganic Syntheses. 32: 123-132. DOI: 10.1002/9780470132630.Ch20  0.32
2006 Knijnenburg Q, Gambarotta S, Budzelaar PH. Ligand-centred reactivity in diiminepyridine complexes. Dalton Transactions (Cambridge, England : 2003). 5442-8. PMID 17117213 DOI: 10.1039/B612251E  0.4
2006 Jabri A, Temple C, Crewdson P, Gambarotta S, Korobkov I, Duchateau R. Role of the metal oxidation state in the SNS-Cr catalyst for ethylene trimerization: isolation of di- and trivalent cationic intermediates. Journal of the American Chemical Society. 128: 9238-47. PMID 16834398 DOI: 10.1021/Ja0623717  0.444
2006 Arunachalampillai A, Crewdson P, Korobkov I, Gambarotta S. Ring opening and C-O and C-N bond cleavage by transient reduced thorium species Organometallics. 25: 3856-3866. DOI: 10.1021/Om060454Q  0.434
2006 Jabri A, Crewdson P, Gambarotta S, Korobkov I, Duchateau R. Isolation of a cationic chromium(II) species in a catalytic system for ethylene tri- and tetramerization Organometallics. 25: 715-718. DOI: 10.1021/Om050886L  0.384
2006 Heiser DE, Pelascini F, Kramer D, Scott J, Gambarotta S, McCahill J, Stephan DW, Okuda J, Mülhaupt R. Ethylene/1,3-cyclohexadiene copolymerization by means of methylaluminoxane activated half-sandwich complexes Macromolecular Symposia. 236: 156-160. DOI: 10.1002/Masy.200690050  0.372
2005 Scott J, Gambarotta S, Korobkov I, Knijnenburg Q, de Bruin B, Budzelaar PH. Formation of a paramagnetic Al complex and extrusion of Fe during the reaction of (diiminepyridine)Fe with AlR3 (R = Me, Et). Journal of the American Chemical Society. 127: 17204-6. PMID 16332066 DOI: 10.1021/Ja056135S  0.379
2005 Scott J, Gambarotta S, Korobkov I, Budzelaar PH. Metal versus ligand alkylation in the reactivity of the (bis-iminopyridinato)Fe catalyst. Journal of the American Chemical Society. 127: 13019-29. PMID 16159297 DOI: 10.1021/Ja054152B  0.423
2005 Vidyaratne I, Gambarotta S, Korobkov I, Budzelaar PH. Dinitrogen partial reduction by formally zero- and divalent vanadium complexes supported by the bis-iminopyridine system. Inorganic Chemistry. 44: 1187-9. PMID 15732953 DOI: 10.1021/Ic048358+  0.433
2005 Athimoolam A, Gambarotta S, Korobkov I. Preparation, characterization, and structure of two dipyrrolide thorium homoleptic complexes - Isolation of a dipyrrolide dipotassium salt with an inverted-sandwich type of structure Canadian Journal of Chemistry. 83: 832-837. DOI: 10.1139/V05-086  0.388
2005 Scott J, Gambarotta S, Korobkov I. Ligand-assisted reduction of Co(II) to Co(I) and subsequent coordination of dinitrogen Canadian Journal of Chemistry. 83: 279-285. DOI: 10.1139/V05-010  0.445
2005 Crewdson P, Gambarotta S, Djoman MC, Korobkov I, Duchateau R. Switchable chromium(II) ethylene oligomerization/polymerization catalyst Organometallics. 24: 5214-5216. DOI: 10.1021/Om050699N  0.443
2005 Athimoolam A, Gambarotta S, Korobkov I. Ligand metallation during the reduction of a thorium(IV) amide complex Organometallics. 24: 1996-1999. DOI: 10.1021/Om049120W  0.44
2005 Heiser DE, Okuda J, Gambarotta S, Mülhaupt R. Catalytic 1,3-cyclohexadiene homopolymerization and regioselective copolymerization with ethylene Macromolecular Chemistry and Physics. 206: 195-202. DOI: 10.1002/Macp.200400384  0.412
2004 Sugiyama H, Korobkov I, Gambarotta S, Möller A, Budzelaar PH. Preparation, characterization, and magnetic behavior of the ln derivatives (ln = nd, la) of a 2,6-diiminepyridine ligand and corresponding dianion. Inorganic Chemistry. 43: 5771-9. PMID 15332830 DOI: 10.1021/Ic049820T  0.419
2004 Gao G, Korobkov I, Gambarotta S. Divalent molybdenum complexes of the dipyrrolide ligand system. Isolation of a Mo2 unit with a 45 degree twist angle. Inorganic Chemistry. 43: 1108-15. PMID 14753834 DOI: 10.1021/Ic0350739  0.409
2004 Sugiyama H, Gambarotta S, Yap GPA, Wilson DR, Thiele SKH. Preparation of an active neodymium catalyst for regioselective butadiene cis-polymerization supported by a dianionic modification of the 2,6-diiminopyridine ligand Organometallics. 23: 5054-5061. DOI: 10.1021/Om0496434  0.405
2004 Korobkov I, Gambarotta S. Cis double addition of CO2 to a coordinated arene of a thorium complex Organometallics. 23: 5379-5381. DOI: 10.1021/Om049470I  0.368
2004 Korobkov I, Arunachalampillai A, Gambarotta S. Cyclometalation and solvent deoxygenation during reduction of a homoleptic Th(OAr)4 complex: Serendipitous formation of a terminally bonded Th-OH function Organometallics. 23: 6248-6252. DOI: 10.1021/Om049369D  0.347
2003 Crewdson P, Gambarotta S, Yap GP, Thompson LK. Dinuclear and octanuclear Mn(II) complexes with mu2-C, mu2-N(pyrrolide), and mu-eta1:eta5-(pyrrolide) bridges: a structural and magnetic study. Inorganic Chemistry. 42: 8579-84. PMID 14658916 DOI: 10.1021/Ic0349205  0.424
2003 Korobkov I, Gambarotta S, Yap GP. The first thorium arene complex: a divalent synthon. Angewandte Chemie (International Ed. in English). 42: 814-8. PMID 12596209 DOI: 10.1002/Anie.200390217  0.368
2003 Bérubé CD, Yazdanbakhsh M, Gambarotta S, Yap GPA. Serendipitous Isolation of the First Example of a Mixed-Valence Samarium Tripyrrole Complex Organometallics. 22: 3742-3747. DOI: 10.1021/Om030155Q  0.42
2003 Scott J, Gambarotta S, Yap G, Rancourt DG. Labile tetranuclear Fe(II) and Co(II) clusters of a dipyrrolide dianion with two diamagnetic ferrous links Organometallics. 22: 2325-2330. DOI: 10.1021/Om030111H  0.396
2003 Bérubé CD, Gambarotta S, Yap GPA, Cozzi PG. Di- and trivalent dinuclear samarium complexes supported by pyrrole-based tetradentate Schiff bases Organometallics. 22: 434-439. DOI: 10.1021/Om020773R  0.643
2003 Gambarotta S. Vanadium-based Ziegler-Natta: Challenges, promises, problems Coordination Chemistry Reviews. 237: 229-243. DOI: 10.1016/S0010-8545(02)00298-9  0.374
2002 Sugiyama H, Aharonian G, Gambarotta S, Yap GP, Budzelaar PH. Participation of the alpha,alpha'-diiminopyridine ligand system in reduction of the metal center during alkylation. Journal of the American Chemical Society. 124: 12268-74. PMID 12371869 DOI: 10.1021/Ja020485M  0.413
2002 Korobkov I, Gambarotta S, Yap GP. A highly reactive uranium complex supported by the calix[4]tetrapyrrole tetraanion affording dinitrogen cleavage, solvent deoxygenation, and polysilanol depolymerization. Angewandte Chemie (International Ed. in English). 41: 3433-6. PMID 12298055 DOI: 10.1002/1521-3773(20020916)41:18<3433::Aid-Anie3433>3.0.Co;2-V  0.386
2002 Korobkov I, Aharonian G, Gambarotta S, Yap GPA. Ligand fragmentation promoted by a transient low-valent thulium Organometallics. 21: 4899-4901. DOI: 10.1021/Om0204843  0.379
2002 Reardon D, Guan J, Gambarotta S, Yap GPA, Wilson DR. Vanadium-promoted aldol condensation and pinacolic coupling of acetylpyrrole: Formation of two new potent dinuclear catalysts for olefin copolymerization Organometallics. 21: 4390-4397. DOI: 10.1021/Om0204585  0.813
2002 Aharonian G, Gambarotta S, Yag GPA. Tantalum complexes of diphenyldipyrrolide dianion: Partial hydrogenation of a phenyl ring Organometallics. 21: 4257-4263. DOI: 10.1021/Om020406F  0.469
2002 Schulzke C, Enright D, Sugiyama H, LeBlanc G, Gambarotta S, Yap GPA, Thompson LK, Wilson DR, Duchateau R. The unusual stability of homoleptic di- and tetravalent chromium alkyls Organometallics. 21: 3810-3816. DOI: 10.1021/Om020237Z  0.541
2002 Feghali K, Harding DJ, Reardon D, Gambarotta S, Yap G, Wang Q. Stability of metal-carbon bond versus metal reduction during ethylene polymerization promoted by a vanadium complex: The role of the aluminum cocatalyst Organometallics. 21: 968-976. DOI: 10.1021/Om011040U  0.832
2002 Reardon D, Aharonian G, Gambarotta S, Yap GPA. Mono- and zerovalent manganese alkyl complexes supported by the α,α′-diiminato pyridine ligand: Alkyl stabilization at the expense of catalytic performance Organometallics. 21: 786-788. DOI: 10.1021/Om0110078  0.807
2002 Ganesan M, Bérubé CD, Gambarotta S, Yap GPA. Effect of the alkali-metal cation on the bonding mode of 2,5-dimethylpyrrole in divalent samarium and ytterbium complexes Organometallics. 21: 1707-1713. DOI: 10.1021/Om0109915  0.387
2002 Freckmann DMM, Dubé T, Bérubé CD, Gambarotta S, Yap GPA. Cyclic Di- and mixed-valent ytterbium complexes supported by dipyrrolide ligands Organometallics. 21: 1240-1246. DOI: 10.1021/Om010928F  0.796
2001 Tayebani M, Aharonian G, Feghali K, Gambarotta S, Yap GP. Preparation and characterization of a tetranuclear and mixed-valence Nb(II)/Nb(III) diamagnetic Nb(4)Cl(12)Li(2)(THF)(8) cluster. Inorganic Chemistry. 40: 2442-5. PMID 11327929 DOI: 10.1021/Ic001253W  0.77
2001 Tayebani M, Feghali K, Gambarotta S, Yap GP. Insensitivity of the Nb-Nb distance in a paddle-wheel compound to bond multiplicity and axial ligation. Inorganic Chemistry. 40: 1399-401. PMID 11300851 DOI: 10.1021/Ic001110+  0.757
2001 Dubé T, Guan J, Gambarotta S, Yap GP. Reactivity of calix-tetrapyrrole SmII and SmIII complexes with acetylene: isolation of an "N-confused" calix-tetrapyrrole ring. Chemistry (Weinheim An Der Bergstrasse, Germany). 7: 374-81. PMID 11271523 DOI: 10.1002/1521-3765(20010119)7:2<374::Aid-Chem374>3.0.Co;2-E  0.798
2001 Korobkov I, Gambarotta S, Yap GPA. Highly reactive uranium(III) polypyrrolide complexes: Intramolecular C-H bond activation, ligand isomerization, and solvent deoxygenation and fragmentation Organometallics. 20: 2552-2559. DOI: 10.1021/om010166o  0.369
2001 Dubé T, Guan J, Gambarotta S, Yap GPA. Reactivity of calix-tetrapyrrole SmII and SmIII complexes with acetylene: Isolation of an "N-confused" calix-tetrapyrrole ring Chemistry - a European Journal. 7: 374-381.  0.322
2000 Dube T, Freckmann D, Conoci S, Gambarotta S, Yap GPA. Monomeric and octameric divalent ytterbium complexes of diphenylmethyl dipyrrolyl dianion Organometallics. 19: 209-211. DOI: 10.1021/Om990798Z  0.804
2000 Guan J, Dube T, Gambarotta S, Yap GPA. Dinitrogen labile coordination versus four-electron reduction, THF cleavage, and fragmentation promoted by a (calix-tetrapyrrole)Sm(II) complex Organometallics. 19: 4820-4827. DOI: 10.1021/Om000698P  0.799
2000 Gambarotta S. Tetrametallic divalent samarium cluster hydride and dinitrogen complexes Organometallics. 19: 3716-3721. DOI: 10.1021/Om000502L  0.376
2000 Dubé T, Gambarotta S, Yap GPA. Dinuclear Complexes of Di-, Tri-, and Mixed-Valent Samarium Supported by the Calix-tetrapyrrole Ligand Organometallics. 19: 817-823.  0.307
1999 Dubé T, Gambarotta S, Yap GPA. Reversible Fixation of Ethylene on a Sm Calix-Pyrrole Complex. Angewandte Chemie (International Ed. in English). 38: 1432-1435. PMID 29711581 DOI: 10.1002/(Sici)1521-3773(19990517)38:10<1432::Aid-Anie1432>3.0.Co;2-T  0.788
1999 Tayebani M, Feghali K, Gambarotta S, Yap GP, Thompson LK. A Paramagnetic Diniobium Complex with a Very Short Nb-Nb Distance: Evidence for a Pseudo Nb-Nb Triple Bond? Angewandte Chemie (International Ed. in English). 38: 3659-3661. PMID 10649315 DOI: 10.1002/(Sici)1521-3773(19991216)38:24<3659::Aid-Anie3659>3.0.Co;2-Z  0.787
1999 Ma Y, Reardon D, Gambarotta S, Yap G, Zahalka H, Lemay C. Vanadium-Catalyzed Ethylene−Propylene Copolymerization:  The Question of the Metal Oxidation State in Ziegler−Natta Polymerization Promoted by (β-diketonate)3V Organometallics. 18: 2773-2781. DOI: 10.1021/Om9808763  0.791
1999 Reardon D, Conan F, Gambarotta S, Yap G, Wang Q. Life and death of an active ethylene polymerization catalyst. Ligand involvement in catalyst activation and deactivation. Isolation and characterization of two unprecedented neutral and anionic vanadium(I) alkyls Journal of the American Chemical Society. 121: 9318-9325. DOI: 10.1021/Ja990263X  0.804
1999 Dubé T, Conoci S, Gambarotta S, Yap GPA, Vasapollo G. Tetrametallic reduction of dinitrogen: Formation of a tetranuclear samarium dinitrogen complex Angewandte Chemie - International Edition. 38: 3657-3659. DOI: 10.1002/(Sici)1521-3773(19991216)38:24<3657::Aid-Anie3657>3.0.Co;2-A  0.786
1999 Kasani A, Babu RPK, Feghali K, Gambarotta S, Yap GPA, Thompson LK, Herbst-Irmer R. Di‐ and Trimanganese N,N′‐Dicyclohexylformamidinate Complexes Chemistry: a European Journal. 5: 577-586. DOI: 10.1002/(Sici)1521-3765(19990201)5:2<577::Aid-Chem577>3.0.Co;2-2  0.394
1999 Tayebani M, Feghali K, Gambarotta S, Yap G, Thompson L. Ein paramagnetischer Diniobkomplex mit sehr kurzem Nb-Nb-Abstand: Hinweis auf eine Nb-Nb-Pseudo-Dreifachbindung? Angewandte Chemie. 111: 3893-3895. DOI: 10.1002/(Sici)1521-3757(19991216)111:24<3893::Aid-Ange3893>3.0.Co;2-2  0.736
1999 Dubé T, Conoci S, Gambarotta S, Yap G, Vasapollo G. Stickstoffixierung: Reduktion von N2 durch vier Metallfragmente unter Bildung eines vierkernigen Samarium-Distickstoffkomplexes Angewandte Chemie. 111: 3890-3892. DOI: 10.1002/(Sici)1521-3757(19991216)111:24<3890::Aid-Ange3890>3.0.Co;2-K  0.757
1999 Dubé T, Gambarotta S, Yap GPA. Reversible Fixierung von Ethylen an einem Calixpyrrol-Samarium(II)-Komplex Angewandte Chemie. 111: 1507-1510. DOI: 10.1002/(Sici)1521-3757(19990517)111:10<1507::Aid-Ange1507>3.0.Co;2-E  0.752
1999 Kasani A, Kamalesh Babu RP, Feghali K, Gambarotta S, Yap GPA, Thompson LK, Herbst-Irmer R. Di- and trimanganese N,N′-dicyclohexylformamidinate complexes Chemistry - a European Journal. 5: 577-586.  0.346
1998 Tayebani M, Gambarotta S, Yap GPA. Pyrrole Denitrogenation and Fragmentation of Tetramethylethylenediamine Promoted by a Nb Cluster. Angewandte Chemie (International Ed. in English). 37: 3002-3005. PMID 29711137 DOI: 10.1002/(Sici)1521-3773(19981116)37:21<3002::Aid-Anie3002>3.0.Co;2-K  0.809
1998 Ruppa KBP, Feghali K, Kovacs I, Aparna K, Gambarotta S, Yap GPA, Bensimon C. Reaction of di- and tri-valent chromium amides with O2† Journal of the Chemical Society-Dalton Transactions. 1595-1606. DOI: 10.1039/A708229K  0.335
1998 Tayebani M, Feghali K, Gambarotta S, Yap G. Molecular rearrangements of a low-valent niobium amide: Ligand C-H bond oxidative addition and reductive elimination Organometallics. 17: 4282-4290. DOI: 10.1021/Om980302Y  0.817
1998 Tayebani M, Gambarotta S, Yap G. C−H versus C−N Bond Cleavage Promoted by Niobium(II) Amide Organometallics. 17: 3639-3641. DOI: 10.1021/Om980298Q  0.801
1998 Desmangles N, Gambarotta S, Bensimon C, Davis S, Zahalka H. Preparation and characterization of (R2N)2VCl2 [R=Cy, i-Pr] and its activity as olefin polymerization catalyst Journal of Organometallic Chemistry. 562: 53-60. DOI: 10.1016/S0022-328X(98)00366-0  0.39
1998 Ruppa KBP, Gambarotta S, Yap GPA. Tetravalent niobium alkyls and enolate stabilized by anionic organic amides Inorganica Chimica Acta. 280: 143-149. DOI: 10.1016/S0020-1693(98)00059-0  0.314
1998 Tayebani M, Gambarotta S, Yap GPA. Pyrrole denitrogenation and fragmentation of tetramethylethylenediamine promoted by a Nb(II) cluster Angewandte Chemie - International Edition. 37: 3002-3005. DOI: 10.1002/(SICI)1521-3773(19981116)37:21<3002::AID-ANIE3002>3.0.CO;2-K  0.8
1998 Tayebani M, Gambarotta S, Yap GPA. NbII-Cluster-vermittelte Stickstoffabspaltung aus Pyrrol und Fragmentierung von tmeda Angewandte Chemie. 110: 3222-3225. DOI: 10.1002/(Sici)1521-3757(19981102)110:21<3222::Aid-Ange3222>3.0.Co;2-9  0.738
1998 Dubé T, Gambarotta S, Yap G. Preparation and reactivity of a compartmental Schiff-base samarium dinuclear complex Organometallics. 17: 3967-3973.  0.354
1998 Tayebani M, Gambarotta S, Yap G. C-H versus C-N bond cleavage promoted by niobium(II) amide Organometallics. 17: 3639-3641.  0.79
1997 Fryzuk MD, Hoffman V, Kickham JE, Rettig SJ, Gambarotta S. Synthesis and Structure of a New Lithium Amide Ligand Precursor: A Tridentate Nitrogen-Based Donor Set of the Formula N(SiMe(2)CH(2)NMe(2))(2). Synthesis and Structure of the Group 4 Amides MCl(3)[N(SiMe(2)CH(2)NMe(2))(2)] (M = Ti, Zr, Hf). Inorganic Chemistry. 36: 3480-3484. PMID 11670025 DOI: 10.1021/Ic970168U  0.423
1997 Moore M, Feghali K, Gambarotta S. Preparation and Characterization of a Diamagnetic Sulfido-Bridged Divanadium Amide Complex. Inorganic Chemistry. 36: 2191-2194. PMID 11669843 DOI: 10.1021/Ic961471I  0.411
1997 Hao S, Feghali K, Gambarotta S. Preparation and Characterization of a Diamagnetic and Dinuclear Titanium(III) Formamidinate Complex. Evidence for the Existence of a Ti-Ti Bond? Inorganic Chemistry. 36: 1745-1748. PMID 11669774 DOI: 10.1021/Ic961358S  0.41
1997 Ruppa KB, Desmangles N, Gambarotta S, Yap G, Rheingold AL. Preparation and Characterization of a Homoleptic Vanadium(III) Amide Complex and Its Transformation into Terminal Chalcogenide Derivatives [(3,5-Me(2)Ph)AdN](3)V=E (E = S, Se; Ad = Adamantyl). Inorganic Chemistry. 36: 1194-1197. PMID 11669687 DOI: 10.1021/Ic961168H  0.341
1997 Kasani A, Gambarotta S, Bensimon C. Zirconium alkyl and borohydride complexes stabilized by a sterically demanding anionic organic amide. the crystal structures of ZrMeL3 (2) Zr(BH4)L3 (3) (L = (3,5-Me2Ph)N(Ad); Ad = adamantyl) Canadian Journal of Chemistry. 75: 1494-1499. DOI: 10.1139/V97-179  0.334
1997 Tayebani M, Kasani A, Feghali K, Gambarotta S, Bensimon C. The reduction of Nb2Cl6(tmeda)2 by R2NLi. Formation of a diamagnetic niobium(II) cluster with short Nb-Nb triple bond and amide C-N bond cleavage Chemical Communications. 2001-2002. DOI: 10.1039/A703280C  0.778
1997 Moore M, Gambarotta S, Yap G, Liable-Sands LM, Rheingold AL. Formation of a vanadium(v) bicyclic carbene–amide complexvia insertion of alkyne into a V–C bond Chemical Communications. 643-644. DOI: 10.1039/A606904E  0.397
1997 Tayebani M, Feghali K, Gambarotta S, Bensimon C. Amide C-N bond cleavage and formation of nitride promoted by a niobium(II) cluster Organometallics. 16: 5084-5088. DOI: 10.1021/Om970427N  0.786
1997 Moore M, Gambarotta S, Bensimon C. Serendipitous Formation of a Dinuclear Vanadium(III) Amide Complex Containing a Vanadaazacyclobutane Ring. Potassium−Hydrogen Agostic Interactions Holding Together a V2K2Tetrametallic Framework Organometallics. 16: 1086-1088. DOI: 10.1021/Om960792Z  0.41
1997 Reardon D, Kovacs I, Ruppa KBP, Feghali K, Gambarotta S, Petersen J. Reactivity of coordinatively unsaturated trivalent chromium complexes with sulfur: Preparation of novel sulfide-bridged dinuclear Cr(IV) derivatives Chemistry - a European Journal. 3: 1482-1488. DOI: 10.1002/Chem.19970030915  0.797
1996 Berno P, Moore M, Minhas R, Gambarotta S. Monomeric and dimeric V(III) complexes supported by organic amides Canadian Journal of Chemistry. 74: 1930-1935. DOI: 10.1139/V96-219  0.455
1996 Berno P, Gambarotta S, Kotila S, Erker G. Novel vanadium and titanium phosphorus ylide complexes Chemical Communications. 779-780. DOI: 10.1039/Cc9960000779  0.343
1996 Minhas RK, Scoles L, Wong S, Gambarotta S. Tri- and tetravalent titanium alkyls supported by organic amides Organometallics. 15: 1113-1121. DOI: 10.1021/Om9508288  0.459
1996 Scoles L, Ruppa KBP, Gambarotta S. Preparation of the first ditantalum(III) complex containing a Ta-Ta bond without bridging ligands Journal of the American Chemical Society. 118: 2529-2530. DOI: 10.1021/Ja953807D  0.438
1996 Minhas RK, Ma Y, Song JI, Gambarotta S. Synthesis, Reactivity, and Stability of Di- and Trivalent Samarium Amides Inorganic Chemistry. 35: 1866-1873. DOI: 10.1021/Ic951253+  0.344
1996 Dionne M, Jubb J, Jenkins H, Wong S, Gambarotta S. One- vs Two-Electron Reduction of N2O Promoted by a Divalent Chromium Macrocyclic Complex Inorganic Chemistry. 35: 1874-1879. DOI: 10.1021/Ic9510728  0.375
1996 Desmangles N, Jenkins H, Ruppa KB, Gambarotta S. Preparation and characterization of a vanadium (III) dinitrogen complex supported by a tripodal anionic amide ligand Inorganica Chimica Acta. 250: 1-4. DOI: 10.1016/S0020-1693(96)05323-6  0.454
1996 Hao S, Berno P, Minhas RK, Gambarotta S. The role of ligand steric hindrance in determining the stability of very short V-V contacts. Preparation and characterization of a series of V(II) and V(III) amidinates Inorganica Chimica Acta. 244: 37-49. DOI: 10.1016/0020-1693(95)04757-3  0.36
1996 Song JI, Gambarotta S. Preparation, characterization, and reactivity of a diamagnetic vanadium nitride Angewandte Chemie - International Edition in English. 35: 1258-1263. DOI: 10.1002/Chem.19960021012  0.398
1996 Jubb J, Scoles L, Jenkins H, Gambarotta S. Formation of bridging nitride versus terminal oxovanadium promoted by a vanadium(II) macrocyclic complex Chemistry - a European Journal. 2: 767-771. DOI: 10.1002/Chem.19960020707  0.432
1995 Dionne M, Hao S, Gambarotta S. Preparation and characterization of a new series of Cr(II) hydroborates Canadian Journal of Chemistry. 73: 1126-1134. DOI: 10.1139/V95-139  0.385
1995 Berno P, Gambarotta S. Formation of a metallaaziridine ring and dinitrogen fixation promoted by a niobium amide complex Organometallics. 14: 2159-2161. DOI: 10.1021/Om00005A012  0.414
1995 Goerdt B, Duchateau R, Gambarotta S, Tuczek F. Spectroscopic studies of side-on and end-on bonding of dinitrogen in low-valent binuclear titanium amide complexes Journal of Inorganic Biochemistry. 59: 352. DOI: 10.1016/0162-0134(95)97451-U  0.593
1995 Scoles L, Gambarotta S. Preparation and characterization of a new series of Ti(III) hydroborates supported by silazanate ligands Inorganica Chimica Acta. 235: 375-380. DOI: 10.1016/0020-1693(95)90079-L  0.422
1995 Berno P, Jenkins H, Gambarotta S, Blixt J, Facey GA, Detellier C. [{Ti(μ‐CH3)5(μ‐CH2)}{(tmeda)Li}3] · THF: An Unusual and Highly Fluxional Titanium Organometallic Compound Angewandte Chemie International Edition in English. 34: 2264-2266. DOI: 10.1002/Anie.199522641  0.351
1995 Song J‐, Gambarotta S. The First Dinuclear Low‐Valent Samarium Complex with a Short Sm–Sm Contact Angewandte Chemie International Edition in English. 34: 2141-2143. DOI: 10.1002/Anie.199521411  0.405
1995 Berno P, Gambarotta S. Reaction of a Vanadium(III) Amide with H2: Isolation and Characterization of a Polynuclear Mixed‐Valence Polyhydrido–Nitrido Complex Angewandte Chemie International Edition in English. 34: 822-824. DOI: 10.1002/Anie.199508221  0.432
1995 Berno P, Jenkins H, Gambarotta S, Blixt J, Facey GA, Detellier C. [{Ti(μ-CH3)5(μ-CH2)}{(tmeda)Li}3] · THF: eine Titanverbindung mit stark fluktuierendem Verhalten Angewandte Chemie. 107: 2457-2458. DOI: 10.1002/Ange.19951072027  0.323
1994 Spek AL, Edema JJH, Gambarotta S. Chlorobis{2-[(dimethylamino)methyl]phenyl-C1,N}(pyridine)vanadium(III) Acta Crystallographica Section C Crystal Structure Communications. 50: 1209-1211. DOI: 10.1107/S0108270194004257  0.47
1994 Jubb J, Gambarotta S, Duchateau R, Teuben JH. Preparation and reactivity of the first yttrium porphyrinogen complex Journal of the Chemical Society, Chemical Communications. 2641-2642. DOI: 10.1039/C39940002641  0.41
1994 Berno P, Gambarotta S. Insertion versus elimination in the reaction of ButNC with a azasilavanadacyclobutane ring supported by hexamethylsilazanate ligand Journal of the Chemical Society, Chemical Communications. 2419-2421. DOI: 10.1039/C39940002419  0.381
1994 Hao S, Song JI, Aghabozorg H, Gambarotta S. Diphenylphosphinomethanide complexes of chromium(II) and samarium(III): Preparation and characterization of the dinuclear [Cr{Ph2PC(H) PPh2}2](μ-Cl)[μ-C(H)(PPh2) 2][Cr{Ph2PC(H)PPh2}] and mononuclear pseudo-allylic Sm[η3-Ph2PC(H)PPh2] 3 Journal of the Chemical Society, Chemical Communications. 157-158. DOI: 10.1039/C39940000157  0.385
1994 Scoles L, Minhas R, Duchateau R, Jubb J, Gambarotta S. Synthesis and Characterization of Novel Titanium(III) and -(IV) Alkyls and Carbenes Supported by Amide Ligands. Crystal Structure of [(Cy2N)2Ti(.mu.-CH2)]2 Organometallics. 13: 4978-4983. DOI: 10.1021/Om00024A047  0.398
1994 Berno P, Gambarotta S. Reactivity of a four-membered vanadacycle ring supported by bulky silazanate. Regioselective hydrogenation of pyridine Organometallics. 13: 2569-2571. DOI: 10.1021/Om00019A011  0.445
1994 Hao S, Song JI, Berno P, Gambarotta S. Chromium(II) organochromates. Preparation, characterization, and stability Organometallics. 13: 1326-1335. DOI: 10.1021/Om00016A040  0.429
1994 Berno P, Minhas R, Hao S, Gambarotta S. Preparation, Characterization, and Reactivity of the Binuclear Vanadium(III) Compound {[Me3Si)2N]V[.mu.-CH2SiMe2N(SiMe3)]}2.C-H .sigma.-Bond Metathesis Promoted by an Amido Function Organometallics. 13: 1052-1054. DOI: 10.1021/Om00016A002  0.402
1994 Berno P, Hao S, Minhas R, Gambarotta S. Dinitrogen fixation versus metal-metal bond formation in the chemistry of vanadium(II) amidinates Journal of the American Chemical Society. 116: 7417-7418. DOI: 10.1021/Ja00095A059  0.331
1994 Song JI, Berno P, Gambarotta S. Dinitrogen fixation, ligand dehydrogenation, and cyclometalation in the chemistry of vanadium(III) amides Journal of the American Chemical Society. 116: 6927-6928. DOI: 10.1021/Ja00094A054  0.388
1994 Jubb J, Gambarotta S. Dinitrogen reduction operated by a samarium macrocyclic complex. Encapsulation of dinitrogen into a Sm2Li4 metallic cage Journal of the American Chemical Society. 116: 4477-4478. DOI: 10.1021/Ja00089A047  0.338
1994 Jubb J, Gambarotta S. The surprising role of THF in vanadium macrocyclic chemistry Inorganic Chemistry. 33: 2503-2504. DOI: 10.1021/Ic00090A004  0.449
1994 Berno P, Minhas R, Hao S, Gambarotta S. Preparation, characterization, and reactivity of the binuclear vanadium(III) compound {[(Me3Si)2N]V[μ-CH2SiMe 2N(SiMe3)]}2 C-H σ-bond metathesis promoted by an amido function Organometallics. 13: 1052-1054.  0.338
1994 Scoles L, Minhas R, Duchateau R, Jubb J, Gambarotta S. Synthesis and characterization of novel titanium(III) and -(IV) alkyls and carbenes supported by amide ligands. Crystal structure of [(Cy2N)2Ti(μ-CH2)]2 Organometallics. 13: 4978-4983.  0.316
1993 Edema JJH, Gambarotta S, Meetsma A, Spek AL, Smeets WJJ, Chiang MY. Chromium(II) amides: Synthesis and structures Journal of the Chemical Society, Dalton Transactions. 789-797. DOI: 10.1039/Dt9930000789  0.37
1993 Gambarotta S, Edema JJH, Minhas RK. Isolation and characterization of a vanadium ethylidyne complex. The crystal structure of [(Cy2N)2Li(μ3-O) (μ211CMe) an unusual V 2LiO cluster Journal of the Chemical Society, Chemical Communications. 1503-1504. DOI: 10.1039/C39930001503  0.429
1993 Jubb J, Gambarotta S. Preparation and characterization of the first vanadium ynolate complex Journal of the American Chemical Society. 115: 10410-10411. DOI: 10.1021/Ja00075A087  0.376
1993 Minhas RK, Edema JJH, Gambarotta S, Meetsma A. Stability of vanadium(II) aryloxides: Synthesis and characterization of sterically protected, neutral and monomeric vanadium(II) aryloxides. Reactivity with the N-N bond of (Me3Si)CH=N=N Journal of the American Chemical Society. 115: 6710-6717. DOI: 10.1021/Ja00068A031  0.392
1993 Dick DG, Edema JJH, Duchateau R, Gambarotta S. Novel bis((trimethylsilyl)benzamidinato)titanium(III) complexes. Preparation and crystal structures of {PhC[(Me3Si)N]2}2Ti(.mu.-Cl)2Li(TMEDA), {PhC[(Me3Si)N]2}2Ti(BH4), and {PhC[(Me3Si)N]2}2Ti(.eta.3-allyl) Inorganic Chemistry. 32: 1959-1962. DOI: 10.1021/Ic00062A014  0.387
1993 Shoukang H, Gambarotta S, Bensimon C, Edema JJH. Ligand steric bulk: A neglected factor in the formation of CrCr supershort contacts Inorganica Chimica Acta. 213: 65-74. DOI: 10.1016/S0020-1693(00)83815-3  0.393
1992 Beydoun N, Duchateau R, Gambarotta S. Synthesis and characterization of a thermally robust titanium dinitrogen complex. The crystal structure of [{[(Me3Si)2N] TiCl(pyridine)2}2(μ-η:η′-N2)] Journal of the Chemical Society, Chemical Communications. 244-246. DOI: 10.1039/C39920000244  0.415
1992 Edema JJH, Gambarotta S, Meetsma A, Spek AL. Dimeric and monomeric chromium(II) and monomeric chromium(III) aryls. Crystal structure of pyramidal Mz2Cr(py) (Mz = o-Me2NCH2C6H4, py = pyridine), dimeric [(Me2NC6H4)2Cr]2, and octahedral (Me2NC6H4)3Cr Organometallics. 11: 2452-2457. DOI: 10.1021/Om00043A029  0.369
1992 Hao S, Gambarotta S, Bensimon C. Reversible cleavage of chromium-chromium quadruple bond of [Me8Cr2][Li(THF)]4 via modification of the coordination sphere of the alkali cation. Preparation and crystal structure of monomeric [Me4Cr][Li(TMEDA)]2 Journal of the American Chemical Society. 114: 3556-3557. DOI: 10.1021/Ja00035A061  0.362
1992 Minhas R, Duchateau R, Gambarotta S, Bensimon C. Linear trimeric, dimeric, and monomeric titanium(III) aryloxides Inorganic Chemistry. 31: 4933-4938. DOI: 10.1021/Ic00050A008  0.401
1992 Hao S, Edema JHH, Gambarotta S, Bensimon C. Reversible cleavage of the chromium-chromium multiple bond in [(TAA)Cr]2 (TAA = tetramethyldibenzotetraaza[14]annulene) Inorganic Chemistry. 31: 2676-2678. DOI: 10.1021/Ic00039A003  0.313
1991 Edema JJH, Gambarotta S. Short and Supershort Cr-Cr Distances: A Vanishing Borderline Between Metal-Metal Bonds, Magnetic Couplings and Ligand Artifacts Comments On Inorganic Chemistry. 11: 195-214. DOI: 10.1080/02603599108035825  0.364
1991 Duchateau R, Gambarotta S, Beydoun N, Bensimon C. Side-on versus end-on coordination of dinitrogen to titanium(II) and mixed-valence titanium(I)/titanium(II) amido complexes Journal of the American Chemical Society. 113: 8986-8988. DOI: 10.1021/Ja00023A080  0.349
1991 Duchateau R, Williams AJ, Gambarotta S, Chiang MY. Carbon-carbon double-bond formation in the intermolecular acetonitrile reductive coupling promoted by a mononuclear titanium(II) compound. Preparation and characterization of two titanium(IV) imido derivatives Inorganic Chemistry. 30: 4863-4866. DOI: 10.1021/Ic00025A036  0.321
1991 Edema JJH, Meetsma A, Gambarotta S, Khan SI, Smeets WJJ, Spek AL. Ligand and alkali metal cation control on the molecular complexity of anionic chromium(II) aryloxides. Preparation and crystal structure of dimeric (PhO)10Cr2Li6(THF)6 and (2,6-Me2C6H3O)6Cr2Li2(THF)4 and trimeric (GuO)14Cr3Na9Cl [GuO = (o-CH3O)C6H4O] with an encapsulated chloride ion Inorganic Chemistry. 30: 3639-3646. DOI: 10.1021/Ic00019A014  0.419
1991 Edema JJH, Gambarotta S, Hao S, Bensimon C. Linear trimeric and monomeric octahedral vanadium(II) diphenylacetate complexes Inorganic Chemistry. 30: 2584-2586. DOI: 10.1021/Ic00012A004  0.354
1991 Edema JJH, Gambarotta S, Meetsma A, Spek AL, Veldman N. Synthesis And Structural Features Of Novel Vanadium(Ii) Amides - X-Ray Structures Of Octahedral [(2-C5H4N)(Ch3)N]2V(Tmeda) (Tmeda=N,N,N',N'-Tetramethylethylenediamine) And Square-Pyramidal [2,5-(Ch3)2C4H2N]2V(Py)3 (Py=Pyridine) Inorganic Chemistry. 30: 2062-2066. DOI: 10.1021/Ic00009A023  0.417
1991 Edema J, Meetsma A, Vanbolhuis F, Gambarotta S. Role Of The Ligand In The Formation Of Short Vanadium Vanadium Contacts - Preparation And Crystal-Structure Of Monomeric ([(Ph2P)2Ch]3V)[Li(Thf)4](Thf)2 And [Phnc(H)Nph]2V(Tmeda) And Dimeric ([Phnc(Me)O]2V)2(Tmeda) (Tmeda=N,N,N',N'-Tetramethylethylenediamine) Inorganic Chemistry. 30: 2056-2061. DOI: 10.1021/Ic00009A022  0.407
1991 Edema JJH, Gambarotta S, Smeets WJJ, Spek AL. Polymetallic chromium alkoxides: synthesis and crystal structures of (iso-PrO)8Cr2Na4(THF)4 and (.mu.3-OPh)10Cr4(.mu.3-O)3Na4(TMEDA)4 Inorganic Chemistry. 30: 1380-1384. DOI: 10.1021/Ic00006A040  0.354
1991 Edema JJH, Duchateau R, Gambarotta S, Hynes R, Gabe E. Novel titanium(II) amine complexes L4TiCl2 [L = 1/2 N,N,N′,N′-tetramethylethylenediamine (TMEDA), 1/2 N,N,N′-trimethylethylenediamine, pyridine, 1/2 2,2′-bipyridine]: Synthesis and crystal structure of monomeric trans-(TMEDA)2TiCl2 Inorganic Chemistry. 30: 154-156. DOI: 10.1021/Ic00002A002  0.385
1991 Wielstra Y, Duchateau R, Gambarotta S, Bensimon C, Gabe E. A binuclear zirconium fulvalene tetraallyl complex. The preparation and the molecular structure of [η5 : η5-C10H8][CpZr(η1-CH2CHCH2)(η3-CH2CHCH2)]2 Journal of Organometallic Chemistry. 418: 183-190. DOI: 10.1016/0022-328X(91)86365-W  0.395
1991 Edema JJH, Gambarotta S, Meetsma A, Spek AL, Veldman N. Synthesis and structural features of novel vanadium(II) amides. X-ray structures of octahedral [(2-C5H4N)(CH3)N]2V(TMEDA) (TMEDA = N,N,N′,N′-tetramethylethylenediamine) and square-pyramidal [2,5-(CH3)2C4H2N] 2V(Py)3 (Py = pyridine) Inorganic Chemistry. 30: 2062-2066.  0.325
1991 Edema JJH, Meetsma A, Gambarotta S, Khan SI, Smeets WJJ, Spek AL. Ligand and alkali metal cation control on the molecular complexity of anionic chromium(II) aryloxides. Preparation and crystal structure of dimeric (PhO)10Cr2Li6(THF)6 and (2,6-Me2C6H3O)6Cr2Li 2(THF)4 and trimeric (GuO)14Cr3Na .. Inorganic Chemistry. 30: 3639-3646.  0.316
1990 Edema JJH, Meetsma A, Gambarotta S. Preparation and characterization of [V3Cl5(tmeda) 3][V(NPh2)4] (tmeda = N,N,N′,N′- tetramethylethylenediamine): A VII-VIII mixed valence complex Journal of the Chemical Society, Chemical Communications. 951-953. DOI: 10.1039/C39900000951  0.398
1990 Wielstra Y, Gambarotta S, Spek AL, Smeets WJJ. Binuclear zirconium(III) and zirconium(IV) complexes: mild oxidation of low-valent zirconium as a synthetic pathway to a class of tri- and tetravalent zirconium fulvalene complexes. Molecular structures of [.eta.5:.eta.5-C10H8][CpZrSPh]2, [.eta.5:.eta.5-C10H8][CpZr(CH3)2]2, and [.eta.5:.eta.5-C10H8][CpZr]2[.mu.-S]2 Organometallics. 9: 2142-2148. DOI: 10.1021/Om00157A027  0.446
1990 Wielstra Y, Meetsma A, Gambarotta S, Khan S. Cyclopentadiene functionalization versus fulvalene formation in the oxidation of [(.eta.1:.eta.5-C5H4)ZrCp(PMe3)]2: preparation and crystal structures of [(.eta.1:.eta.5-C5H4)ZrCp]2[.mu.-NSiMe3] and [(.eta.1:.eta.5-C5H4)][.mu.-NSiMe3][CpZrSPh][Cp(C5H4SPh)Zr] Organometallics. 9: 876-879. DOI: 10.1021/Om00117A060  0.409
1990 Wielstra Y, Gambarotta S, Spek AL. Monocyclopentadienyl zirconium and hafnium alkyls: synthesis, hydrogen-transfer reactions and catalytic features in the reactivity with .alpha.-olefins. The x-ray structure of CpZr(.eta.4-butadiene)(DMPE)Cl [DMPE = 1,2-bis(dimethylphosphino)ethane] Organometallics. 9: 572-577. DOI: 10.1021/Om00117A007  0.347
1990 Edema JJH, Gambarotta S, Meetsma A, Van Bolhuis F, Spek AL, Smeets WJJ. The unpredictable structural features of chromium(II) pyrrolyls: synthesis and x-ray structures of monomeric square-planar (.eta.1-2,5-Me2C4H2N)2Cr(py)2, square-pyramidal (.eta.1-C4H4N)2Cr(py)3, dimeric [(7-azaindolyl)2Cr(DMF)]2, and polymeric [(.eta.1-2,5-Me2C4N2)4CrNa2(THF)2(Et2O)]n. An aborted Cr-Cr quadruple bond formation? Inorganic Chemistry. 29: 2147-2153. DOI: 10.1021/Ic00336A022  0.346
1990 Edema JJH, Stauthamer W, Van Bolhuis F, Gambarotta S, Smeets WJJ, Spek AL. Novel vanadium(II) amine complexes: a facile entry in the chemistry of divalent vanadium. Synthesis and characterization of mononuclear L4VCl2 [L = amine, pyridine]: x-ray structures of trans-(TMEDA)2VCl2 [TMEDA = N,N,N',N'-tetramethylethylenediamine] and trans-Mz2V(py)2 [Mz = o-C6H4CH2N(CH3)2, py = pyridine] Inorganic Chemistry. 29: 1302-1306. DOI: 10.1021/Ic00332A003  0.418
1990 J.H. Edema J, Gambarotta S, van Bolhuis F, J.J. Smeets W, Spek AL, Chiang MY. Monomeric arylchromium(II) complexes: the crystal structures of [cis-Mes2Cr(THF)2](THF), [cis-Mes2Cr(bipy)](THF), [Mes4CrLi2(THF)2](THF) and Ph4CrLi2(THF)4 (Mes = 2,4,6-mesityl; bipy = 2,2′-bipyridine) Journal of Organometallic Chemistry. 389: 47-59. DOI: 10.1016/0022-328X(90)85392-C  0.344
1990 Wielstra Y, Gambarotta S, Spek AL, Smeets WJJ. Binuclear zirconium(III) and zirconium(IV) complexes: Mild oxidation of low-valent zirconium as a synthetic pathway to a class of tri- and tetravalent zirconium fulvalene complexes. Molecular structures of [η5:η5-C10H8][CpZrSPh] 2, [η5:η5-C10H8][CpZr(CH .. Organometallics. 9: 2142-2148.  0.308
1990 Edema JJH, Stauthamer W, Van Bolhuis F, Gambarotta S, Smeets WJJ, Spek AL. Novel vanadium(II) amine complexes: A facile entry in the chemistry of divalent vanadium. Synthesis and characterization of mononuclear L4VCl2 [L = amine, pyridine]: X-ray structures of trans-(TMEDA)2VCl2 [TMEDA = N,N,N′,N′,-tetramethylethylenediamine] and trans-Mz2V(py)2 [Mz .. Inorganic Chemistry. 29: 1302-1306.  0.348
1989 Wielstra Y, Gambarotta S, Meetsma A, Spek AL. The controversy over the thermal stability of bis(cyclopentadienyl)zirconium(III) halides. Synthesis of Cp'2ZrX (Cp' = Cp, C5H4Me; X = Cl, Br, I) via photolysis of Cp'2Zr(CH2CHMe2)X. The x-ray structures of [(C5H4Me)2Zr(.mu.-I)]2 and [.eta.5:.eta.5-C10H8] [CpZr(.mu.-I)]2 Organometallics. 8: 2948-2952. DOI: 10.1021/Om00114A032  0.316
1989 Wielstra Y, Gambarotta S, Meetsma A, De Boer JL, Chiang MY. Carbon-carbon bond formation versus hydrogen transfer in the reaction of alkynes with mono(cyclopentadienyl)zirconium(II) complexes: regioselective dimerization, cocyclotrimerization, and catalytic cyclotrimerization. The preparation and x-ray structures of Cp(dmpe)XZr[(R)C:C(R')C(R):C(R')] [R = CH3; R' = H, CH3; X = Cl, CH3; dmpe = 1,2-bis(dimethylphosphino)ethane] and of CpZr(dmpe)Cl[C.tplbond.C(t-Bu)][CH:CH(t-Bu)] Organometallics. 8: 2696-2702. DOI: 10.1021/Om00113A028  0.403
1989 Meyer EM, Gambarotta S, Floriani C, Chiesi-Villa A, Guastini C. Polynuclear aryl derivatives of Group 11 metals. Synthesis, solid state-solution structural relationship, and reactivity with phosphines Organometallics. 8: 1067-1079. DOI: 10.1021/Om00106A031  0.461
1989 Wielstra Y, Meetsma A, Gambarotta S. Synthesis Of New Monomeric Zirconium And Hafnium Hydride Butadiene Complexes - The X-Ray Structure Of (Eta-5-Cyclopentadienyl) (Eta-4-Butadiene)-[1,2-Bis(Dimethylphosphino)Ethane]Hydridozirconium Organometallics. 8: 258-259. DOI: 10.1021/Om00103A038  0.332
1989 Wielstra Y, Gambarotta S, Meetsma A, Deboer J. Preparation And X-Ray Structure Of [Cp2Zr(Mu-I)]2 - A Thermally Unstable Zirconium(Iii) Complex Organometallics. 8: 250-251. DOI: 10.1021/Om00103A034  0.317
1989 Edema JJH, Meetsma A, Gambarotta S. Divalent Vanadium And Dinitrogen Fixation - The Preparation And X-Ray Structure Of (Mu-N2)([(O-Me2Nch2)C6H4]2V(Py))2(Thf)2 Journal of the American Chemical Society. 111: 6878-6880. DOI: 10.1021/Ja00199A079  0.35
1989 Edema JJH, Gambarotta S, Van Bolhuis F, Spek AL. Chromium(II) alkoxides: Synthesis and crystal structure of the monomeric [(RO)4Cr][Na(TMEDA)]2 (R = 2,6-dimethylphenyl) and dimeric [(RO)8Cr2][NaL]4 (R = phenyl; L = THF, pyridine) without a Cr-Cr bond. An insight into the question of Cr-Cr quadruple bond formation Journal of the American Chemical Society. 111: 2142-2147. DOI: 10.1021/Ja00188A030  0.414
1989 Edema JJH, Gambarotta S, Van Der Sluis P, Smeets WJJ, Spek AL. Preparation and X-ray structure of (tetramethyldibenzotetraaza[14]annulene) chromium dimer, [(tmtaa)Cr]2. A multiply bonded complex of dichromium(II) without bridging ligands Inorganic Chemistry. 28: 3782-3784. DOI: 10.1021/Ic00319A005  0.404
1989 Edema JJH, Gambarotta S, Van Bolhuis F, Smeets WJJ, Spek AL. New classes of monomeric and dimeric square-planar chromium(II) aryloxides: Syntheses and structures Inorganic Chemistry. 28: 1407-1410. DOI: 10.1021/Ic00306A038  0.329
1989 Edema JJH, Gambarotta S, Spek AL. Synthesis and X-ray structure of the first dinuclear homoleptic chromium(II) amide, {[(i-Pr)2N]Cr[μ-(i-Pr)2N]}2 Inorganic Chemistry. 28: 811-812. DOI: 10.1021/Ic00304A001  0.359
1989 Wielstra Y, Gambarotta S, Meetsma A, De Boer JL. Preparation and X-ray structure of [Cp2Zr(μ-I)]2. A thermally unstable zirconium(III) complex Organometallics. 8: 250-251.  0.303
1988 Wielstra Y, Gambarotta S, Roedelof JB, Chiang MY. Mono(cyclopentadienyl)zirconium(II) and -hafnium(II) chemistry: synthesis and reactivity of CpM(CO)2(dmpe)Cl [M = Zr, Hf; Cp = cyclopentadienyl; dmpe = 1,2-bis(dimethylphosphino)ethane] via mild-condition carbonylation reaction of CpM(dmpe)2Cl. The crystal structure of CpZr(CO)2(dmpe)Cl Organometallics. 7: 2177-2182. DOI: 10.1021/Om00100A015  0.38
1988 Wielstra Y, Gambarotta S, Chiang MY. [1,2-Bis(Dimethylphosphino)Ethane](Cyclo-Pentadienyl)Methylzirconium(Ii) [Cpzrme(Dmpe)2] - A Catalyst Precursor For The Selective Dimerization Of Ethylene To 1-Butene Organometallics. 7: 1866-1867. DOI: 10.1021/Om00098A027  0.339
1988 Gambarotta S, Chiesi-Villa A, Guastini C. Synthesis, reactivity, and crystal structure of CpV(CO)3tht (tht = tetrahydrothiophene). A mild-condition synthetic pathway to substitution derivatives of CpV(CO)4 and preparation and X-ray characterization of cis-CpV(CO)2bpy (bpy = 2,2′-bipyridine) Inorganic Chemistry. 27: 99-102. DOI: 10.1021/Ic00274A021  0.374
1988 Wielstra Y, Gambarotta S, Roedelof JB, Chiang MY. Mono(cyclopentadienyl)zirconium(II) and -hafnium(II) chemistry: Synthesis and reactivity of CpM(CO)2(dmpe)Cl [M = Zr, Hf; Cp = cyclopentadienyl; dmpe = 1,2-bis(dimethylphosphino)ethane] via mild-condition carbonylation reaction of CpM(dmpe)2Cl. The crystal structure of CpZr(CO)2(dmpe)Cl Organometallics. 7: 2177-2182.  0.31
1987 Floriani C, Gambarotta S, Chiesi-Villa A, Guastini C. Reaction of elemental sulphur with bis(pentamethylcyclopentadienyl)vanadium derivatives: disulphido and µ-sulphido complexes. Crystal structures of [V(η-C5Me5)2(S2)] and [V2(η-C5Me5)2Cl2(µ-S)2] Journal of the Chemical Society-Dalton Transactions. 2099-2103. DOI: 10.1039/Dt9870002099  0.532
1987 Gambarotta S, Bracci M, Floriani C, Chiesi-Villa A, Guastini C. Tetranuclear amido complexes of copper(I): a synthetic and structural study Journal of the Chemical Society-Dalton Transactions. 1883-1888. DOI: 10.1039/Dt9870001883  0.364
1987 Gambarotta S, Stella S, Floriani C, Chiesi-Villa A, Guastini C. Co-oligomerization of diphenylketene and ethylene promoted by (η5-cyclopentadienyl)bis(ethylene)cobalt(I): synthesis and X-ray structure of a heterocycle containing cobalt(III) Journal of the Chemical Society-Dalton Transactions. 1789-1792. DOI: 10.1039/Dt9870001789  0.585
1987 Gambarotta S, Chiang MY. Synthesis of a diamagnetic fulvalene zirconium(III) derivative. The crystal structure of (.eta.5:.eta.5-C10H8)[(.eta.5-C5H5)Zr(.mu.-Cl)]2 Organometallics. 6: 897-899. DOI: 10.1021/Om00147A040  0.345
1987 FLORIANI C, GAMBAROTTA S, CHIESI-VILLA A, GUASTINI C. ChemInform Abstract: Reaction of Elemental Sulfur with Bis(pentamethylcyclopentadienyl)vanadium Derivatives: Disulfido and μ-Sulfido Complexes. Crystal Structures of (V(η-C5Me5)2(S2)) and (V2(η-C5Me5)2Cl2(μ-S)2). Cheminform. 18. DOI: 10.1002/chin.198752275  0.48
1987 GAMBAROTTA S, BRACCI M, FLORIANI C, CHIESI-VILLA A, GUASTINI C. ChemInform Abstract: Tetranuclear Amido Complexes of Copper(I): A Synthetic and Structural Study. Cheminform. 18. DOI: 10.1002/chin.198748295  0.427
1987 GAMBAROTTA S, STELLA S, FLORIANI C, CHIESI-VILLA A, GUASTINI C. ChemInform Abstract: Cooligomerization of Diphenylketene and Ethylene Promoted by (η5-Cyclopentadienyl)bis(ethylene)cobalt(I): Synthesis and X-Ray Structure of a Heterocycle Containing Cobalt(III). Cheminform. 18. DOI: 10.1002/chin.198744290  0.43
1986 Gambarotta S, Floriani C, Chiesi-Villa A, Guastini C. Metal-formaldehyde chemistry: metal-promoted elementary transformations of formaldehyde Organometallics. 5: 2425-2433. DOI: 10.1021/Om00143A005  0.448
1986 Gambarotta S, Mazzanti M, Floriani C, Chiesi-Villa A, Guastini C. Vanadium(III)-Schiff base complexes: a synthetic and structural study Inorganic Chemistry. 25: 2308-2314. DOI: 10.1021/Ic00234A006  0.647
1986 MAZZANTI M, GAMBAROTTA S, FLORIANI C, CHIESI-VILLA A, GUASTINI C. ChemInform Abstract: Schiff Base Complexes: A Synthetic and Structural Study. Chemischer Informationsdienst. 17. DOI: 10.1002/Chin.198647296  0.643
1986 Ciurli S, Gambarotta S, Floriani C, Chiesi-Villa A, Guastini C. Reduced Cobalt-meso-Tetraphenylporphyrin Complexes: Synthesis and Structure of[Na(thf)3]2[Co(TPP)] Angewandte Chemie International Edition in English. 25: 553-554. DOI: 10.1002/Chin.198641296  0.659
1986 CIURLI S, GAMBAROTTA S, FLORIANI C, CHIESI-VILLA A, GUASTINI C. ChemInform Abstract: Reduced Cobalt-meso-tetraphenylporphyrin Complexes: Synthesis and Structure of [Na(THF)3]2[Co(′TPP)]. Chemischer Informationsdienst. 17. DOI: 10.1002/chin.198641296  0.629
1986 GAMBAROTTA S, STELLA S, FLORIANI C, CHIESI-VILLA A, GUASTINI C. ChemInform Abstract: Synthesis and Structure of the Co3Ti2Complex [{μ-[(C5H5)2TiOC]}2{(C5H5)3Co3}]; CO Reduction by Two Different Metal Centres. Chemischer Informationsdienst. 17. DOI: 10.1002/Chin.198627270  0.508
1986 GAMBAROTTA S, STROLOGO S, FLORIANI C, CHIESI-VILLA A, GUASTINI C. ChemInform Abstract: Stepwise Reduction of Carbon Dioxide to Formaldehyde and Methanol: Reactions of CO2and CO2-like Molecules with Hydridochlorobis(cyclopentadienyl)zirconium(IV). Chemischer Informationsdienst. 17. DOI: 10.1002/Chin.198607272  0.468
1986 Gambarotta S, Stella S, Floriani C, Chiesi-Villa A, Guastini C. Synthesis and Structure of the Co3Ti2 Complex [{?3-[(C5H5)2TiOC]}2{(C5H5)3Co3}]: CO Reduction by Two Different Metal Centers Angewandte Chemie International Edition in English. 25: 254-255. DOI: 10.1002/anie.198602541  0.464
1986 Ciurli S, Gambarotta S, Floriani C, Chiesi-Villa A, Guastini C. Reduzierte Cobalt-meso-tetraphenylporphyrin-Komplexe: Synthese und Struktur von [Na(thf)3]2[Co(TPP)] Angewandte Chemie. 98: 553-555. DOI: 10.1002/Ange.19860980612  0.561
1986 Gambarotta S, Stella S, Floriani C, Chiesi-Villa A, Guastini C. Synthese und Struktur des Co3Ti2-Komplexes [{μ3-[(C5H5)2TiOC]}2{(C5H5)3Co3}]; CO-Reduktion unter Nutzung zweier verschiedener Metallzentren Angewandte Chemie. 98: 283-284. DOI: 10.1002/ange.19860980329  0.411
1985 Gambarotta S, Mazzanti M, Floriani C, Chiesi-Villa A, Guastini C. Organometallic derivatives of N,N′-ethylene bis(acetylacetoneiminato)vanadium(III) containing a vanadium–carbon σ-bond Journal of the Chemical Society, Chemical Communications. 829-830. DOI: 10.1039/C39850000829  0.669
1985 Gambarotta S, Strologo S, Floriani C, Chiesi-Villa A, Guastini C. Stepwise reduction of carbon dioxide to formaldehyde and methanol: reactions of carbon dioxide and carbon dioxide like molecules with hydridochlorobis(cyclopentadienyl)zirconium(IV) Journal of the American Chemical Society. 107: 6278-6282. DOI: 10.1021/Ja00308A019  0.48
1985 Gambarotta S, Strologo S, Floriani C, Chiesi-Villa A, Guastini C. Insertion of carbon dioxide-like molecules into zirconium-carbon bonds: reactivity of dialkylbis(cyclopentadienyl)zirconium(IV) with diphenylketene, aryl isocyanates, and p-tolylcarbodiimide Inorganic Chemistry. 24: 654-660. DOI: 10.1021/Ic00199A005  0.452
1985 Gambarotta S, Floriani C, Chiesi-Villa A, Guastini C. Rearrangement of ethylene to hydrido and ethylidyne ligands and formaldehyde decarbonylation in the synthesis of [(η5-C5H5)4Co4] derivatives. Crystal structure of [(η5-C5H5)4Co4(μ3-CO)2] Journal of Organometallic Chemistry. 296: c6-c10. DOI: 10.1016/0022-328X(85)80359-4  0.465
1985 Gambarotta S, Floriani C, Chiesi-Villa A, Guastini C. Carbon dioxide and formaldehyde coordination on molybdenocene to metal and hydrogen bonds of the C1 molecule in the solid state Journal of the American Chemical Society. 107: 2985-2986. DOI: 10.1002/Chin.198542295  0.492
1985 GAMBAROTTA S, FLORIANI C, CHIESI-VILLA A, GUASTINI C. ChemInform Abstract: CARBON DIOXIDE AND FORMALDEHYDE COORDINATION ON MOLYBDENOCENE TO METAL AND HYDROGEN BONDS OF THE C1 MOLECULE IN THE SOLID STATE Chemischer Informationsdienst. 16. DOI: 10.1002/chin.198542295  0.424
1985 GAMBAROTTA S, STROLOGO S, FLORIANI C, CHIESI-VILLA A, GUASTINI C. ChemInform Abstract: INSERTION OF CARBON DIOXIDE-LIKE MOLECULES INTO ZIRCONIUM-CARBON BONDS: REACTIVITY OF DIALKYLBIS(CYCLOPENTADIENYL)ZIRCONIUM(IV) WITH DIPHENYLKETENE, ARYL ISOCYANATES, AND P-TOLYLCARBODIIMIDE Chemischer Informationsdienst. 16. DOI: 10.1002/chin.198530318  0.381
1985 GAMBAROTTA S, FIALLO ML, FLORIANI C, CHIESI-VILLA A, GUASTINI C. ChemInform Abstract: REACTIVITY OF DECAMETHYLVANADOCENE WITH PHENYL ISOTHIOCYANATE AND CARBONYL SULFIDE: REACTIONS RELATED TO THE DESULFURIZATION OF THE THIOCARBONYL GROUP Chemischer Informationsdienst. 16. DOI: 10.1002/chin.198507282  0.401
1984 Gambarotta S, Corazza F, Floriani C, Zehnder M. A tetranuclear iron(II)–sodium complex formed from the complexation of sodium ethoxide by N,N′-ethylenebis(3-hydroxy-1-methylbut-2-enylideneaminato)iron(II) Journal of the Chemical Society, Chemical Communications. 1305-1307. DOI: 10.1039/C39840001305  0.512
1984 Gambarotta S, Mazzanti M, Floriani C, Zehnder M. A tetranuclear polyfunctional sodium-vanadium(III) complex containing a vanadium(III)-vanadium(III) double bond Journal of the Chemical Society, Chemical Communications. 1116-1118. DOI: 10.1039/C39840001116  0.687
1984 Gambarotta S, Floriani C, Chiesi-Villa A, Guastini C. A tri-σ-aryl vanadium(III) derivative: structural determination of trimesitylvanadium(III)–tetrahydrofuran Journal of the Chemical Society, Chemical Communications. 886-887. DOI: 10.1039/C39840000886  0.532
1984 Gambarotta S, Strologo S, Floriani C, Chiesi-Villa A, Guastini C. Synthesis and structure of a mononuclear copper(I) complex containing the copper(I) .sigma.-phenyl functionality Organometallics. 3: 1444-1445. DOI: 10.1021/Om00087A025  0.381
1984 Gambarotta S, Floriani C, Chiesi-Villa A, Guastini C. Decamethylvanadocene chemistry: synthesis, structure, and reactions of vanadium(II) and vanadium(III) derivatives with carbon monoxide and isocyanides Inorganic Chemistry. 23: 1739-1747. DOI: 10.1021/Ic00180A020  0.514
1984 Gambarotta S, Fiallo ML, Floriani C, Chiesi-Villa A, Guastini C. Reactivity of decamethylvanadocene with phenyl isothiocyanate and carbonyl sulfide: reactions related to the desulfurization of the thiocarbonyl group Inorganic Chemistry. 23: 3532-3537. DOI: 10.1002/Chin.198507282  0.471
1984 GAMBAROTTA S, FLORIANI C, CHIESI-VILLA A, GUASTINI C. ChemInform Abstract: DECAMETHYLVANADOCENE CHEMISTRY: SYNTHESIS, STRUCTURE, AND REACTIONS OF VANADIUM(II) AND VANADIUM(III) DERIVATIVES WITH CARBON MONOXIDE AND ISOCYANIDES Chemischer Informationsdienst. 15. DOI: 10.1002/chin.198438264  0.435
1984 GAMBAROTTA S, URSO F, FLORIANI C, CHIESI-VILLA A, GUASTINI C. ChemInform Abstract: CARBON-CARBON BOND FORMING AND BREAKING BY A METAL-ASSISTED REDOX PROCESS IN A NICKEL(II)-SCHIFF BASE COMPLEX Chemischer Informationsdienst. 15. DOI: 10.1002/chin.198413285  0.449
1984 GAMBAROTTA S, FLORIANI C, CHIESI-VILLA A, GUASTINI C. ChemInform Abstract: CYCLOPENTADIENYLDICHLOROTITANIUM(III): A FREE-RADICAL-LIKE REAGENT FOR REDUCING AZO (N:N) MULTIPLE BONDS IN AZO AND DIAZO COMPOUNDS Chemischer Informationsdienst. 15. DOI: 10.1002/chin.198412271  0.457
1983 Gambarotta S, Floriani C, Chiesi-Villa A, Guastini C. A homoleptic arylgold(I) complex: synthesis and structure of pentanuclear mesitylgold(I) Journal of the Chemical Society, Chemical Communications. 1304-1306. DOI: 10.1039/C39830001304  0.55
1983 Gambarotta S, Floriani C, Chiesi-Villa A, Guastini C. Ring contraction in an arylcopper(I) compound promoted by a sulphur donor ligand : penta[mesitylcopper(I)] forms a tetra[mesitylcopper(I)] compound Journal of the Chemical Society, Chemical Communications. 1156-1158. DOI: 10.1039/C39830001156  0.519
1983 Gambarotta S, Floriani C, Chiesi-Villa A, Guastini C. A homoleptic arylmanganese(II) complex : synthesis and structure of a thermally stable trinuclear mesitylmanganese(II) complex Journal of the Chemical Society, Chemical Communications. 1128-1129. DOI: 10.1039/C39830001128  0.559
1983 Gambarotta S, Floriani C, Chiesi-Villa A, Guastini C. A thermally stable and soluble arylsilver(I) compound: synthesis and structure of mesitylsilver(I) Journal of the Chemical Society, Chemical Communications. 1087-1089. DOI: 10.1039/C39830001087  0.444
1983 Gambarotta S, Floriani C, Chiesi-Villa A, Guastini C. Decamethylvanadocene forming a disulphur complex from elemental sulphur and desulphurization reactions Journal of the Chemical Society, Chemical Communications. 184-186. DOI: 10.1039/C39830000184  0.591
1983 Gambarotta S, Floriani C, Chiesi-Villa A, Guastini C. Genesis, bonding mode and reaction with carbon monoxide of an oxymethylene unit bridging two metal atoms Journal of the American Chemical Society. 105: 1690-1691. DOI: 10.1021/Ja00344A066  0.535
1983 Gambarotta S, Floriani C, Chiesi-Villa A, Guastini C. Hydrazonato ligands from the insertion of diazoalkanes into zirconium-carbon and zirconium-hydrogen bonds Inorganic Chemistry. 22: 2029-2034. DOI: 10.1021/Ic00156A019  0.493
1983 Gambarotta S, Urso F, Floriani C, Chiesi-Villa A, Guastini C. Carbon-carbon bond forming and breaking by a metal-assisted redox process in a nickel(II)-Schiff base complex Inorganic Chemistry. 22: 3966-3972. DOI: 10.1002/Chin.198413285  0.514
1983 Gambarotta S, Floriani C, Chiesi-Villa A, Guastini C. Cyclopentadienyldichlorotitanium(III): a free-radical-like reagent for reducing azo (N:N) multiple bonds in azo and diazo compounds Journal of the American Chemical Society. 105: 7295-7301. DOI: 10.1002/Chin.198412271  0.521
1983 GAMBAROTTA S, FLORIANI C, CHIESI-VILLA A, GUASTINI C. ChemInform Abstract: GENESIS, BONDING MODE AND REACTION WITH CARBON MONOXIDE OF AN OXYMETHYLENE UNIT BRIDGING TWO METAL ATOMS Chemischer Informationsdienst. 14. DOI: 10.1002/chin.198339284  0.427
1982 Gambarotta S, Floriani C, Chiesi-Villa A, Guastini C. Nitrogen–nitrogen multiple bond cleavage and reduction in diphenyldiazomethane and azobenzene by a titanium (III) complex Journal of the Chemical Society, Chemical Communications. 1015-1017. DOI: 10.1039/C39820001015  0.624
1982 Gambarotta S, Arena F, Floriani C, Gaetani-Manfredotti A. Activation of CO2-like molecules by a multifunctional complex: possible pathways leading to C–C bond formation involving functional groups simulating CO2 Journal of the Chemical Society, Chemical Communications. 835-837. DOI: 10.1039/C39820000835  0.562
1982 Gambarotta S, Floriani C, Chiesi-Villa A, Guastini C. Carbon–carbon bond formation and cleavage resulting from a long-range metal-promoted redox process in the reactions of nickel(II) complexes of N,N′-o-phenylenebis(salicylideneamine) Journal of the Chemical Society, Chemical Communications. 756-758. DOI: 10.1039/C39820000756  0.562
1982 Gambarotta S, Fiallo ML, Floriani C, Chiesi-Villa A, Guastini C. Alkali metal cations controlling the reactivity of cobalt(II) Schiff base complexes: synthesis of a µ-persulphido-ligand from S8 reacting with a cobalt(II) oxygen carrier compound Journal of the Chemical Society, Chemical Communications. 503-505. DOI: 10.1039/C39820000503  0.579
1982 Gambarotta S, Basso-Bert M, Floriani C, Guastini C. Nitrogen–carbon and nitrogen–hydrogen bond formation by insertion of a diazoalkane into metal–carbon and metal–hydrogen bonds Journal of the Chemical Society, Chemical Communications. 374-375. DOI: 10.1039/C39820000374  0.556
1982 Gambarotta S, Arena F, Floriani C, Zanazzi PF. Carbon dioxide fixation: bifunctional complexes containing acidic and basic sites working as reversible carriers Journal of the American Chemical Society. 104: 5082-5092. DOI: 10.1021/Ja00383A015  0.529
1982 Gambarotta S, Floriani C, Chiesi-Villa A, Guastini C. Metal-formaldehyde chemistry: coordination, disproportionation and Lewis acid-promoted transformation to oxymethylene derivatives Journal of the American Chemical Society. 104: 2019-2020. DOI: 10.1021/Ja00371A038  0.469
1982 Gambarotta S, Floriani C, Chiesi-Villa A, Guastini C. Titanium-promoted synthesis of a carbohydrazido ligand from carbon monoxide and diphenyldiazomethane: diazoalkane coordination and activation by dicyclopentadienyltitanium(II) and -vanadium(II) complexes Journal of the American Chemical Society. 104: 1918-1924. DOI: 10.1021/Ja00371A021  0.53
1982 GAMBAROTTA S, ARENA F, FLORIANI C, ZANAZZI PF. ChemInform Abstract: CARBON DIOXIDE FIXATION: BIFUNCTIONAL COMPLEXES CONTAINING ACIDIC AND BASIC SITES WORKING AS REVERSIBLE CARRIERS Chemischer Informationsdienst. 13. DOI: 10.1002/chin.198251331  0.388
1982 GAMBAROTTA S, FLORIANI C, CHIESI-VILLA A, GUASTINI C. ChemInform Abstract: TITANIUM-PROMOTED SYNTHESIS OF A CARBOHYDRAZIDO LIGAND FROM CARBON MONOXIDE AND DIPHENYLDIAZOMETHANE: DIAZOALKANE COORDINATION AND ACTIVATION BY DICYCLOPENTADIENYLTITANIUM(II) AND -VANADIUM(II) COMPLEXES Chemischer Informationsdienst. 13. DOI: 10.1002/chin.198230255  0.467
1981 Gambarotta S, Alper H. Phase transfer catalyzed hydroxyacylation of allenes The Journal of Organic Chemistry. 46: 2142-2144. DOI: 10.1021/Jo00323A033  0.391
1981 Gambarotta S, Pasquali M, Floriani C, Chiesi-Villa A, Guastini C. Activation of carbon dioxide-like molecules: .eta.1-O and .eta.2-C,O carbonylic functional groups metal anchored to the bis(cyclopentadienyl)vanadium unit Inorganic Chemistry. 20: 1173-1178. DOI: 10.1021/Ic50218A043  0.476
1981 Pasquali M, Gambarotta S, Floriani C, Chiesi-Villa A, Guastini C. Activation of carbon dioxide-like molecules: synthetic and structural studies on a .eta.2-carbon, nitrogen metal-bonded carbodiimide and its conversion into a .eta.2-carbon, nitrogen metal-bonded amidinyl ligand Inorganic Chemistry. 20: 165-171. DOI: 10.1021/Ic50215A034  0.494
1981 GAMBAROTTA S, PASQUALI M, FLORIANI C, CHIESI-VILLA A, GUASTINI C. ChemInform Abstract: ACTIVATION OF CARBON DIOXIDE-LIKE MOLECULES: η1-O AND η2-C,O CARBONYLIC FUNCTIONAL GROUPS METAL ANCHORED TO THE BIS(CYCLOPENTADIENYL)VANADIUM UNIT Chemischer Informationsdienst. 12. DOI: 10.1002/chin.198128300  0.42
1981 PASQUALI M, GAMBAROTTA S, FLORIANI C, CHIESI-VILLA A, GUASTINI C. ChemInform Abstract: ACTIVATION OF CARBON DIOXIDE-LIKE MOLECULES: SYNTHETIC AND STRUCTURAL STUDIES ON A η2-CARBON, NITROGEN METAL-BONDED CARBODIIMIDE AND ITS CONVERSION INTO A η2-CARBON, NITROGEN METAL-BONDED AMIDINYL LIGAND Chemischer Informationsdienst. 12. DOI: 10.1002/Chin.198117084  0.504
1980 Alper H, Hachem K, Gambarotta S. The mild rhodium(I), and phase transfer catalyzed, dehydrogenation of benzylic alcohols Canadian Journal of Chemistry. 58: 1599-1601. DOI: 10.1139/V80-253  0.514
1980 Gambarotta S, Alper H. The carbonylation of phase-transfer agents Journal of Organometallic Chemistry. 194: C19-C21. DOI: 10.1016/S0022-328X(00)90350-4  0.337
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