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Andrew S. Borovik - Publications

Affiliations: 
1993-1996 Kansas State University, Manhattan, KS, United States 
 1996-2006 University of Kansas, Lawrence, KS, United States 
 2006- Chemistry University of California, Irvine, Irvine, CA 
Area:
develop synthetic systems containing structural motifs and functional properties found in the active sites of metalloproteins
Website:
http://www.faculty.uci.edu/profile.cfm?faculty_id=5349
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122 high-probability publications. We are testing a new system for linking publications to authors. You can help! If you notice any inaccuracies, please sign in and mark papers as correct or incorrect matches. If you identify any major omissions or other inaccuracies in the publication list, please let us know.

Year Citation  Score
2023 Sun C, Jaimes JL, Follmer AH, Ziller JW, Borovik AS. Selective C-H Bond Cleavage with a High-Spin Fe-Oxido Complex. Molecules (Basel, Switzerland). 28. PMID 37375309 DOI: 10.3390/molecules28124755  0.406
2020 Oswald VF, Lee JL, Biswas S, Weitz AC, Mittra K, Fan R, Li J, Zhao J, Hu MY, Alp EE, Bominaar EL, Guo Y, Green MT, Hendrich MP, Borovik AS. Effects of Non-covalent Interactions on High-spin Fe(IV)-oxido Complexes. Journal of the American Chemical Society. PMID 32489096 DOI: 10.1021/Jacs.0C03085  0.835
2020 Miller KR, Paretsky JD, Follmer AH, Heinisch T, Mittra K, Gul S, Kim IS, Fuller FD, Batyuk A, Sutherlin KD, Brewster AS, Bhowmick A, Sauter NK, Kern J, Yano J, ... ... Borovik AS, et al. Artificial Iron Proteins: Modeling the Active Sites in Non-Heme Dioxygenases. Inorganic Chemistry. PMID 32309932 DOI: 10.1021/Acs.Inorgchem.9B03791  0.807
2019 Brazzolotto D, Bogart JA, Ross DL, Ziller JW, Borovik AS. Stabilizing a Ni-aqua complex via intramolecular hydrogen bonds: synthesis, structure, and redox properties. Inorganica Chimica Acta. 495. PMID 31607758 DOI: 10.1016/J.Ica.2019.118960  0.445
2019 Barman SK, Jones JR, Sun C, Hill EA, Ziller JW, Borovik AS. Regulating the Basicity of Metal-Oxido Complexes with a Single Hydrogen Bond and Its Effect on C-H Bond Cleavage. Journal of the American Chemical Society. PMID 31274298 DOI: 10.1021/Jacs.9B03688  0.822
2019 Biswas S, Lau N, Borovik AS, Hendrich MP, Bominaar EL. Analysis of the Puzzling Exchange-Coupling Constants in a Series of Heterobimetallic Complexes. Inorganic Chemistry. PMID 31241914 DOI: 10.1021/Acs.Inorgchem.9B00757  0.799
2019 Gupta R, Borovik AS. Preface to the special issue in honor of Professor Rabindranath Mukherjee on the occasion of his 65th birthday Inorganica Chimica Acta. 486: 506-507. DOI: 10.1016/J.Ica.2018.11.005  0.395
2018 Weitz A, Hill EA, Oswald VF, Bominaar EL, Borovik AS, Hendrich MP, Guo Y. Probing hydrogen bonding interactions to iron-oxido/hydroxido units via 57Fe nuclear resonance vibrational spectroscopy. Angewandte Chemie (International Ed. in English). PMID 30353620 DOI: 10.1002/Anie.201810227  0.82
2018 Oswald VF, Weitz AC, Biswas S, Ziller JW, Hendrich MP, Borovik AS. Manganese-Hydroxido Complexes Supported by a Urea/Phosphinic Amide Tripodal Ligand. Inorganic Chemistry. PMID 30299920 DOI: 10.1021/Acs.Inorgchem.8B01886  0.84
2018 Lau N, Sano Y, Ziller JW, Borovik AS. Modular bimetallic complexes with a sulfonamido-based ligand. Dalton Transactions (Cambridge, England : 2003). PMID 30118133 DOI: 10.1039/C8Dt02455C  0.803
2018 Mann SI, Heinisch T, Ward TR, Borovik AS. Coordination chemistry within a protein host: regulation of the secondary coordination sphere. Chemical Communications (Cambridge, England). PMID 29645031 DOI: 10.1039/C8Cc01931B  0.81
2018 Olshansky L, Huerta-Lavorie R, Nguyen AI, Vallapurackal J, Furst A, Tilley TD, Borovik AS. Artificial Metalloproteins Containing Co4O4 Cubane Active Sites. Journal of the American Chemical Society. PMID 29401385 DOI: 10.1021/Jacs.7B13052  0.786
2018 Weitz AC, Hill EA, Oswald VF, Bominaar EL, Borovik AS, Hendrich MP, Guo Y. Back Cover: Probing Hydrogen Bonding Interactions to Iron‐Oxido/Hydroxido Units by 57 Fe Nuclear Resonance Vibrational Spectroscopy (Angew. Chem. Int. Ed. 49/2018) Angewandte Chemie International Edition. 57: 16234-16234. DOI: 10.1002/Anie.201812786  0.791
2018 Weitz AC, Hill EA, Oswald VF, Bominaar EL, Borovik AS, Hendrich MP, Guo Y. Rücktitelbild: Probing Hydrogen Bonding Interactions to Iron‐Oxido/Hydroxido Units by 57 Fe Nuclear Resonance Vibrational Spectroscopy (Angew. Chem. 49/2018) Angewandte Chemie. 130: 16470-16470. DOI: 10.1002/Ange.201812786  0.791
2017 Lau N, Sano Y, Ziller JW, Borovik AS. Terminal Ni(II)-OH/-OH2 complexes in trigonal bipyramidal geometries derived from H2O. Polyhedron. 125: 179-185. PMID 29170577 DOI: 10.1016/J.Poly.2016.11.015  0.843
2017 Mann SI, Heinisch T, Ward TR, Borovik AS. Peroxide Activation Regulated by Hydrogen Bonds within Artificial Cu Proteins. Journal of the American Chemical Society. PMID 29117678 DOI: 10.1021/Jacs.7B10452  0.802
2017 Sano Y, Lau N, Weitz AC, Ziller JW, Hendrich MP, Borovik AS. Models for Unsymmetrical Active Sites in Metalloproteins: Structural, Redox, and Magnetic Properties of Bimetallic Complexes with M(II)-(μ-OH)-Fe(III) Cores. Inorganic Chemistry. PMID 29112385 DOI: 10.1021/Acs.Inorgchem.7B02230  0.829
2017 Kubin M, Kern J, Gul S, Kroll T, Chatterjee R, Löchel H, Fuller FD, Sierra RG, Quevedo W, Weniger C, Rehanek J, Firsov A, Laksmono H, Weninger C, Alonso-Mori R, ... ... Borovik AS, et al. Soft x-ray absorption spectroscopy of metalloproteins and high-valent metal-complexes at room temperature using free-electron lasers. Structural Dynamics (Melville, N.Y.). 4: 054307. PMID 28944255 DOI: 10.1063/1.4986627  0.745
2017 Jones JR, Ziller JW, Borovik AS. Modulating the Primary and Secondary Coordination Spheres within a Series of Co(II)-OH Complexes. Inorganic Chemistry. PMID 28094522 DOI: 10.1021/Acs.Inorgchem.6B01956  0.76
2016 Kroll T, Kern J, Kubin M, Ratner D, Gul S, Fuller FD, Löchel H, Krzywinski J, Lutman A, Ding Y, Dakovski GL, Moeller S, Turner JJ, Alonso-Mori R, Nordlund DL, ... ... Borovik A, et al. X-ray absorption spectroscopy using a self-seeded soft X-ray free-electron laser. Optics Express. 24: 22469-22480. PMID 27828320 DOI: 10.1364/Oe.24.022469  0.714
2016 Mann SI, Heinisch T, Weitz AC, Hendrich MP, Ward TR, Borovik AS. Modular Artificial Cupredoxins. Journal of the American Chemical Society. PMID 27385206 DOI: 10.1021/Jacs.6B05428  0.767
2015 Cook SA, Borovik AS. Molecular designs for controlling the local environments around metal ions. Accounts of Chemical Research. 48: 2407-14. PMID 26181849 DOI: 10.1021/Acs.Accounts.5B00212  0.734
2015 Cook SA, Hill EA, Borovik AS. Lessons from Nature: A Bio-Inspired Approach to Molecular Design. Biochemistry. PMID 26079379 DOI: 10.1021/Acs.Biochem.5B00249  0.774
2015 Gupta R, Taguchi T, Lassalle-Kaiser B, Bominaar EL, Yano J, Hendrich MP, Borovik AS. High-spin Mn-oxo complexes and their relevance to the oxygen-evolving complex within photosystem II. Proceedings of the National Academy of Sciences of the United States of America. 112: 5319-24. PMID 25852147 DOI: 10.1073/Pnas.1422800112  0.492
2015 Lau N, Ziller JW, Borovik AS. Sulfonamido tripods: tuning redox potentials via ligand modifications. Polyhedron. 85: 777-782. PMID 25419035 DOI: 10.1016/J.Poly.2014.09.014  0.839
2015 Cook SA, Borovik AS. Molecular Designs for Controlling the Local Environments around Metal Ions Accounts of Chemical Research. 48: 2407-2414. DOI: 10.1021/acs.accounts.5b00212  0.517
2015 Cook SA, Lacy DC, Borovik AS. Terminal Metal-Oxo Species with Unusual Spin States Spin States in Biochemistry and Inorganic Chemistry: Influence On Structure and Reactivity. 203-227. DOI: 10.1002/9781118898277.ch10  0.724
2014 Taguchi T, Stone KL, Gupta R, Kaiser-Lassalle B, Yano J, Hendrich MP, Borovik AS. Preparation and Properties of an Mn(IV-)Hydroxide Complex: Proton and Electron Transfer at a Mononuclear Manganese Site and its Relationship to the Oxygen Evolving Complex within Photosystem II. Chemical Science (Royal Society of Chemistry : 2010). 5: 3064-3071. PMID 25580212 DOI: 10.1039/C4Sc00453A  0.54
2014 Cook SA, Ziller JW, Borovik AS. Iron(II) complexes supported by sulfonamido tripodal ligands: endogenous versus exogenous substrate oxidation. Inorganic Chemistry. 53: 11029-35. PMID 25264932 DOI: 10.1021/Ic501531G  0.712
2014 Sickerman NS, Peterson SM, Ziller JW, Borovik AS. Synthesis, structure and reactivity of Fe(II/III)-NH3 complexes bearing a tripodal sulfonamido ligand. Chemical Communications (Cambridge, England). 50: 2515-7. PMID 24457593 DOI: 10.1039/C3Cc48804G  0.832
2013 Sickerman NS, Henry RM, Ziller JW, Borovik AS. Preparation and Structural Properties of In(III)-H Complexes. Polyhedron. 58: 65-70. PMID 25309019 DOI: 10.1016/J.Poly.2012.07.098  0.826
2013 Lacy DC, Mukherjee J, Lucas RL, Day VW, Borovik AS. Metal complexes with varying intramolecular hydrogen bonding networks. Polyhedron. 52: 261-267. PMID 24904193 DOI: 10.1016/J.Poly.2012.09.034  0.795
2013 Gupta R, Taguchi T, Borovik AS, Hendrich MP. Characterization of monomeric Mn(II/III/IV)-hydroxo complexes from X- and Q-band dual mode electron paramagnetic resonance (EPR) spectroscopy. Inorganic Chemistry. 52: 12568-75. PMID 24156406 DOI: 10.1021/Ic401681R  0.392
2013 Usharani D, Lacy DC, Borovik AS, Shaik S. Dichotomous hydrogen atom transfer vs proton-coupled electron transfer during activation of X-H bonds (X = C, N, O) by nonheme iron-oxo complexes of variable basicity. Journal of the American Chemical Society. 135: 17090-104. PMID 24124906 DOI: 10.1021/Ja408073M  0.731
2013 Park YJ, Cook SA, Sickerman NS, Sano Y, Ziller JW, Borovik AS. Heterobimetallic Complexes with M(III)-(μ-OH)-M(II) Cores (M(III) = Fe, Mn, Ga; M(II) = Ca, Sr, and Ba): Structural, Kinetic, and Redox Properties. Chemical Science (Royal Society of Chemistry : 2010). 4: 717-726. PMID 24058726 DOI: 10.1039/C2Sc21400H  0.824
2013 Sano Y, Weitz AC, Ziller JW, Hendrich MP, Borovik AS. Unsymmetrical bimetallic complexes with M(II)-(μ-OH)-M(III) cores (M(II)M(III) = Fe(II)Fe(III), Mn(II)Fe(III), Mn(II)Mn(III)): structural, magnetic, and redox properties. Inorganic Chemistry. 52: 10229-31. PMID 23992041 DOI: 10.1021/Ic401561K  0.351
2013 Cook SA, Borovik AS. Inorganic chemistry: Deconstructing water oxidation. Nature Chemistry. 5: 259-60. PMID 23511412 DOI: 10.1038/Nchem.1606  0.6
2012 Lacy DC, Park YJ, Ziller JW, Yano J, Borovik AS. Assembly and properties of heterobimetallic Co(II/III)/Ca(II) complexes with aquo and hydroxo ligands. Journal of the American Chemical Society. 134: 17526-35. PMID 22998407 DOI: 10.1021/Ja304525N  0.714
2012 Gupta R, Lacy DC, Bominaar EL, Borovik AS, Hendrich MP. Electron paramagnetic resonance and Mössbauer spectroscopy and density functional theory analysis of a high-spin Fe(IV)-oxo complex. Journal of the American Chemical Society. 134: 9775-84. PMID 22574962 DOI: 10.1021/Ja303224P  0.752
2012 Sickerman NS, Park YJ, Ng GK, Bates JE, Hilkert M, Ziller JW, Furche F, Borovik AS. Synthesis, structure, and physical properties for a series of trigonal bipyramidal M(II)-Cl complexes with intramolecular hydrogen bonds. Dalton Transactions (Cambridge, England : 2003). 41: 4358-64. PMID 22334366 DOI: 10.1039/C2Dt12244H  0.841
2012 Ng GK, Ziller JW, Borovik AS. Preparation and structures of dinuclear complexes containing M(II)-OH centers. Chemical Communications (Cambridge, England). 48: 2546-8. PMID 22288074 DOI: 10.1039/C2Cc16277F  0.367
2012 Taguchi T, Gupta R, Lassalle-Kaiser B, Boyce DW, Yachandra VK, Tolman WB, Yano J, Hendrich MP, Borovik AS. Preparation and properties of a monomeric high-spin Mn(V)-oxo complex. Journal of the American Chemical Society. 134: 1996-9. PMID 22233169 DOI: 10.1021/Ja210957U  0.393
2011 Ng GK, Ziller JW, Borovik AS. Structural diversity in metal complexes with a dinucleating ligand containing carboxyamidopyridyl groups. Inorganic Chemistry. 50: 7922-4. PMID 21793511 DOI: 10.1021/Ic200881T  0.526
2011 Park YJ, Ziller JW, Borovik AS. The effects of redox-inactive metal ions on the activation of dioxygen: isolation and characterization of a heterobimetallic complex containing a Mn(III)-(μ-OH)-Ca(II) core. Journal of the American Chemical Society. 133: 9258-61. PMID 21595481 DOI: 10.1021/Ja203458D  0.349
2011 Shook RL, Peterson SM, Greaves J, Moore C, Rheingold AL, Borovik AS. Catalytic reduction of dioxygen to water with a monomeric manganese complex at room temperature. Journal of the American Chemical Society. 133: 5810-7. PMID 21425844 DOI: 10.1021/Ja106564A  0.837
2011 Borovik AS. Role of metal-oxo complexes in the cleavage of C-H bonds. Chemical Society Reviews. 40: 1870-4. PMID 21365079 DOI: 10.1039/C0Cs00165A  0.421
2011 Peterson SM, Shook RL, Borovik AS. Catalytic reduction of dioxygen to water using monomeric cobalt and manganese complexes Acs National Meeting Book of Abstracts.  0.797
2010 Powell-Jia DA, Pham MT, Ziller JW, Borovik AS. Nickel(II) complexes stabilized by bis[N-(6-pivalamido-2-pyridylmethyl)]benzylamine: Synthesis and characterization of complexes stabilized by a hydrogen bonding network. Inorganica Chimica Acta. 363: 2728-2733. PMID 22745511 DOI: 10.1016/J.Ica.2010.05.006  0.834
2010 Lacy DC, Gupta R, Stone KL, Greaves J, Ziller JW, Hendrich MP, Borovik AS. Formation, structure, and EPR detection of a high spin Fe(IV)-oxo species derived from either an Fe(III)-oxo or Fe(III)-OH complex. Journal of the American Chemical Society. 132: 12188-90. PMID 20704272 DOI: 10.1021/Ja1047818  0.756
2010 Park YJ, Sickerman NS, Ziller JW, Borovik AS. Utilizing tautomerization of 2-amino-oxazoline in hydrogen bonding tripodal ligands. Chemical Communications (Cambridge, England). 46: 2584-6. PMID 20449315 DOI: 10.1039/C000160K  0.801
2010 Shook RL, Borovik AS. Role of the secondary coordination sphere in metal-mediated dioxygen activation. Inorganic Chemistry. 49: 3646-60. PMID 20380466 DOI: 10.1021/Ic901550K  0.794
2009 Powell-Jia D, Ziller JW, Dipasquale AG, Rheingold AL, Borovik AS. A structure and reactivity analysis of monomeric Ni(II)-hydroxo complexes prepared from water. Dalton Transactions (Cambridge, England : 2003). 2986-92. PMID 19352526 DOI: 10.1039/B820209E  0.812
2009 Stone KL, Borovik AS. Lessons from nature: unraveling biological CH bond activation. Current Opinion in Chemical Biology. 13: 114-8. PMID 19297238 DOI: 10.1016/J.Cbpa.2009.02.008  0.336
2009 Parsell TH, Yang MY, Borovik AS. C-H bond cleavage with reductants: re-investigating the reactivity of monomeric Mn(III/IV)-oxo complexes and the role of oxo ligand basicity. Journal of the American Chemical Society. 131: 2762-3. PMID 19196005 DOI: 10.1021/Ja8100825  0.847
2009 Nguyen JG, Johnson CA, Sharma S, Subramaniam B, Borovik AS. Green methods for processing and utilizing metal complexes Acs Symposium Series. 1006: 274-289. DOI: 10.1021/bk-2009-1006.ch015  0.602
2009 Johnson C, Ottiger S, Pini R, Gorman EM, Nguyen JG, Munson EJ, Mazzotti M, Borovik AS, Subramaniam B. Near-Stoichiometric O 2 binding on metal centers in Co(salen) nanoparticles Aiche Journal. 55: 1040-1045. DOI: 10.1002/Aic.11740  0.635
2008 Shook RL, Borovik AS. The effects of hydrogen bonds on metal-mediated O2 activation and related processes. Chemical Communications (Cambridge, England). 6095-107. PMID 19082087 DOI: 10.1039/B810957E  0.801
2008 Shook RL, Gunderson WA, Greaves J, Ziller JW, Hendrich MP, Borovik AS. A monomeric Mn(III)-peroxo complex derived directly from dioxygen. Journal of the American Chemical Society. 130: 8888-9. PMID 18570414 DOI: 10.1021/Ja802775E  0.809
2008 Mukherjee J, Lucas RL, Zart MK, Powell DR, Day VW, Borovik AS. Synthesis, structure, and physical properties for a series of monomeric iron(III) hydroxo complexes with varying hydrogen-bond networks. Inorganic Chemistry. 47: 5780-6. PMID 18498155 DOI: 10.1021/Ic800048E  0.544
2008 Johnson C, Long B, Nguyen JG, Day VW, Borovik AS, Subramaniam B, Guzman J. Correlation between active center structure and enhanced dioxygen binding in Co(salen) nanoparticles: Characterization by in situ infrared, Raman, and X-ray absorption spectroscopies Journal of Physical Chemistry C. 112: 12272-12281. DOI: 10.1021/Jp803985B  0.628
2008 Nguyen JG, Johnson CA, Subramaniam B, Borovik AS. Nitric oxide disproportionation at mild temperatures by a nanoparticulate cobalt(II) complex Chemistry of Materials. 20: 5939-5941. DOI: 10.1021/Cm801406Y  0.599
2007 Zart MK, Powell D, Borovik AS. Synthesis and Structures of Dimeric Iron(III)-Oxo and -Imido Complexes Containing Intramolecular Hydrogen Bonds. Inorganica Chimica Acta. 360: 2397-2402. PMID 19946568 DOI: 10.1016/J.Ica.2006.12.020  0.552
2007 Zinn PJ, Sorrell TN, Powell DR, Day VW, Borovik AS. Acetonitrile hydration and ethyl acetate hydrolysis by pyrazolate-bridged cobalt(II) dimers containing hydrogen-bond donors. Inorganic Chemistry. 46: 10120-32. PMID 17973474 DOI: 10.1021/Ic700685G  0.719
2006 Lucas RL, Zart MK, Mukherjee J, Murkerjee J, Sorrell TN, Powell DR, Borovik AS. A modular approach toward regulating the secondary coordination sphere of metal ions: differential dioxygen activation assisted by intramolecular hydrogen bonds. Journal of the American Chemical Society. 128: 15476-89. PMID 17132015 DOI: 10.1021/Ja063935+  0.744
2006 Lieberman RL, Kondapalli KC, Shrestha DB, Hakemian AS, Smith SM, Telser J, Kuzelka J, Gupta R, Borovik AS, Lippard SJ, Hoffman BM, Rosenzweig AC, Stemmler TL. Characterization of the particulate methane monooxygenase metal centers in multiple redox states by X-ray absorption spectroscopy. Inorganic Chemistry. 45: 8372-81. PMID 16999437 DOI: 10.1021/Ic060739V  0.551
2006 Dey A, Hocking RK, Larsen P, Borovik AS, Hodgson KO, Hedman B, Solomon EI. X-ray absorption spectroscopy and density functional theory studies of [(H3buea)FeIII-X]n- (X = S2-, O2-, OH-): comparison of bonding and hydrogen bonding in oxo and sulfido complexes. Journal of the American Chemical Society. 128: 9825-33. PMID 16866539 DOI: 10.1021/Ja061618X  0.628
2006 Parsell TH, Behan RK, Green MT, Hendrich MP, Borovik AS. Preparation and properties of a monomeric Mn(IV)-oxo complex. Journal of the American Chemical Society. 128: 8728-9. PMID 16819856 DOI: 10.1021/Ja062332V  0.817
2006 Zinn PJ, Powell DR, Day VW, Hendrich MP, Sorrell TN, Borovik AS. Pyrazolate-bridging dinucleating ligands containing hydrogen-bond donors: synthesis and structure of their cobalt analogues. Inorganic Chemistry. 45: 3484-6. PMID 16634575 DOI: 10.1021/Ic060009N  0.715
2006 Sharma S, Kerler B, Subramaniam B, Borovik AS. Immobilized metal complexes in porous hosts: Catalytic oxidation of substituted phenols in CO2 media Green Chemistry. 8: 972-977. DOI: 10.1039/B602965E  0.326
2006 Mitchell-Koch JT, Padden KM, Borovik AS. Modification of immobilized metal complexes toward the design and synthesis of functional materials for nitric oxide delivery Journal of Polymer Science, Part a: Polymer Chemistry. 44: 2282-2292. DOI: 10.1002/Pola.21314  0.436
2005 Welbes LL, Borovik AS. Confinement of metal complexes within porous hosts: development of functional materials for gas binding and catalysis. Accounts of Chemical Research. 38: 765-74. PMID 16231872 DOI: 10.1021/Ar0402513  0.347
2005 Lucas RL, Powell DR, Borovik AS. Preparation of iron amido complexes via putative Fe(IV) imido intermediates. Journal of the American Chemical Society. 127: 11596-7. PMID 16104724 DOI: 10.1021/Ja052952G  0.538
2005 Johnson CA, Sharma S, Subramaniam B, Borovik AS. Nanoparticulate metal complexes prepared with compressed carbon dioxide: correlation of particle morphology with precursor structure. Journal of the American Chemical Society. 127: 9698-9. PMID 15998069 DOI: 10.1021/Ja052040E  0.357
2005 Borovik AS. Bioinspired hydrogen bond motifs in ligand design: the role of noncovalent interactions in metal ion mediated activation of dioxygen. Accounts of Chemical Research. 38: 54-61. PMID 15654737 DOI: 10.1021/Ar030160Q  0.535
2004 Welbes LL, Scarrow RC, Borovik AS. Development of porous materials for heterogeneous catalysis: kinetic resolution of epoxides. Chemical Communications (Cambridge, England). 2544-5. PMID 15543271 DOI: 10.1039/B408553A  0.665
2004 Larsen PL, Gupta R, Powell DR, Borovik AS. Chalcogens as terminal ligands to iron: synthesis and structure of complexes with Fe(III)-S and Fe(III)-Se motifs. Journal of the American Chemical Society. 126: 6522-3. PMID 15161258 DOI: 10.1021/Ja049118W  0.663
2004 MacBeth CE, Gupta R, Mitchell-Koch KR, Young VG, Lushington GH, Thompson WH, Hendrich MP, Borovik AS. Utilization of hydrogen bonds to stabilize M-O(H) units: synthesis and properties of monomeric iron and manganese complexes with terminal oxo and hydroxo ligands. Journal of the American Chemical Society. 126: 2556-67. PMID 14982465 DOI: 10.1021/Ja0305151  0.819
2004 Seitz M, Kaiser A, Powell DR, Borovik AS, Reiser O. Predetermined helical chirality in octahedral complexes with a novel pentadentate C2-symmetrical chiral bis(oxazoline) ligand Advanced Synthesis and Catalysis. 346: 737-741. DOI: 10.1002/Adsc.200404020  0.417
2003 Larsen PL, Parolin TJ, Powell DR, Hendrich MP, Borovik AS. Hydrogen bonds around M(mu-O)2M rhombs: stabilizing a {CoIII(mu-O)2CoIII} complex at room temperature. Angewandte Chemie (International Ed. in English). 42: 85-9. PMID 19757598 DOI: 10.1002/Anie.200390060  0.372
2003 Gupta R, Borovik AS. Monomeric MnIII/II and FeIII/II complexes with terminal hydroxo and oxo ligands: probing reactivity via O-H bond dissociation energies. Journal of the American Chemical Society. 125: 13234-42. PMID 14570499 DOI: 10.1021/Ja030149L  0.619
2003 Zart MK, Sorrell TN, Powell D, Borovik AS. Development of bio-inspired chelates with hydrogen bond donors: Synthesis and structure of monomeric metal acetate complexes with intramolecular hydrogen bonds Dalton Transactions. 1986-1992. DOI: 10.1039/B210794P  0.729
2003 Borovik AS, Gupta R, Zart MK, Larsen PL. Metal ion mediated activation of dioxygen: Formation of non-heme complexes with terminal oxo and hydroxo ligands Journal of Inorganic Biochemistry. 96: 75. DOI: 10.1016/S0162-0134(03)80530-5  0.574
2002 Gupta R, Zhang ZH, Powell D, Hendrich MP, Borovik AS. Synthesis and characterization of completely delocalized mixed-valent dicopper complexes. Inorganic Chemistry. 41: 5100-6. PMID 12354043 DOI: 10.1021/Ic0202918  0.523
2002 Gupta R, MacBeth CE, Young VG, Borovik AS. Isolation of monomeric Mn(III/II)-H and Mn(III)-complexes from water: evaluation of O-H bond dissociation energies. Journal of the American Chemical Society. 124: 1136-7. PMID 11841259 DOI: 10.1021/Ja016741X  0.803
2002 Shirin Z, Thompson J, Liable-Sands L, Yap GPA, Rheingold AL, Borovik AS. C2-Symmetric ligands containing hydrogen bond donors: Synthesis and properties of Cu(II) complexes of 2,6-bis[N,N′-(2-carboxamidophenyl)carbamoyl]pyridine Journal of the Chemical Society, Dalton Transactions. 1714-1720. DOI: 10.1039/B107166C  0.496
2002 MacBeth CE, Larsen PL, Sorrell TN, Powell D, Borovik AS. A bidentate ligand with appended hydrogen bond donors: Synthesis and structure of four-coordinate metal complexes with bis[(tert-butyl)aminocarbonyl]-1,2-diaminoethane Inorganica Chimica Acta. 341: 77-84. DOI: 10.1016/S0020-1693(02)01181-7  0.839
2001 MacBeth CE, Hammes BS, Young VG, Borovik AS. Hydrogen-Bonding Cavities about Metal Ions:  Synthesis, Structure, and Physical Properties for a Series of Monomeric M-OH Complexes Derived from Water. Inorganic Chemistry. 40: 4733-4741. PMID 28960977 DOI: 10.1021/Ic010250W  0.804
2001 MacBeth CE, Hammes BS, Young VG, Borovik AS. Hydrogen-bonding cavities about metal ions: synthesis, structure, and physical properties for a series of monomeric M-OH complexes derived from water. Inorganic Chemistry. 40: 4733-41. PMID 11511223 DOI: 10.1021/ic010250w  0.794
2001 Padden KM, Krebs JF, MacBeth CE, Scarrow RC, Borovik AS. Immobilized metal complexes in porous organic hosts: development of a material for the selective and reversible binding of nitric oxide. Journal of the American Chemical Society. 123: 1072-9. PMID 11456660 DOI: 10.1021/Ja003282B  0.804
2001 Padden KM, Krebs JF, Trafford KT, Yap GPA, Rheingold AH, Borovik AS, Scarrow RC. Probing the structure of immobilized metal sites in porous organic hosts by x-ray absorption spectroscopy Chemistry of Materials. 13: 4305-4313. DOI: 10.1021/Cm010502R  0.709
2000 Borovik AS, Bott SG, Barron AR. Hydrogen/Deuterium Exchange Catalyzed by an Unusually Stable Mercury-Toluene Complex This work and the Texas Center for Crystallography at Rice University are supported by the Robert A. Welch Foundation (USA). Angewandte Chemie (International Ed. in English). 39: 4117-4118. PMID 11093225 DOI: 10.1002/1521-3773(20001117)39:22<4117::Aid-Anie4117>3.0.Co;2-D  0.311
2000 MacBeth CE, Golombek AP, Young VG, Yang C, Kuczera K, Hendrich MP, Borovik AS. O2 activation by nonheme iron complexes: A monomeric Fe(III)-Oxo complex derived from O2. Science (New York, N.Y.). 289: 938-41. PMID 10937994 DOI: 10.1126/Science.289.5481.938  0.777
2000 Shirin Z, Hammes BS, Young VG, Borovik AS. Hydrogen bonding in metal oxo complexes: Synthesis and structure of a monomeric manganese(III) - Oxo complex and its hydroxo analogue [18] Journal of the American Chemical Society. 122: 1836-1837. DOI: 10.1021/Ja993818X  0.512
2000 Sharma AC, Borovik AS. Design, synthesis, and characterization of templated metal sites in porous organic hosts: Application to reversible dioxygen binding Journal of the American Chemical Society. 122: 8946-8955. DOI: 10.1021/Ja0014739  0.364
1999 Hammes BS, Young VG, Borovik AS. Hydrogen-Bonding Cavities about Metal Ions: A Redox Pair of Coordinatively Unsaturated Paramagnetic Co-OH Complexes. Angewandte Chemie (International Ed. in English). 38: 666-669. PMID 29711545 DOI: 10.1002/(Sici)1521-3773(19990301)38:5<666::Aid-Anie666>3.0.Co;2-X  0.49
1999 Yu Q, Baroni TE, Liable-Sands L, Yap GPA, Rheingold AL, Borovik AS. Hydrogen bonded antiparallel β-strand motifs promoted by 2,6-bis(carbamoylpeptide)pyridine Chemical Communications. 1467-1468. DOI: 10.1039/A900541B  0.337
1999 Ray M, Golombek AP, Hendrich MP, Yap GPA, Liable-Sands LM, Rheingold AL, Borovik AS. Structure and Magnetic Properties of Trigonal Bipyramidal Iron Nitrosyl Complexes Inorganic Chemistry. 38: 3110-3115. DOI: 10.1021/Ic990070A  0.742
1999 Hammes BS, Young VG, Borovik AS. Hydrogen-bonding cavities about metal ions: A redox pair of coordinatively unsaturated paramagnetic Co - OH complexes Angewandte Chemie - International Edition. 38: 666-669.  0.349
1998 Borovik AS, Krebs JF. Dioxygen binding to immobilized CoII complexes in porous organic hosts: evidence for site isolation Chemical Communications. 553-554. DOI: 10.1039/A707909E  0.334
1998 Kawamoto T, Hammes BS, Ostrander R, Rheingold AL, Borovik AS. Syntheses and Structures of Nickel(II) and Copper(II) Complexes of 2,6-Bis[(2-acetylphenyl)carbamoyl]pyridine: Effects of Molecular Structure on Crystal Lattice Architecture Inorganic Chemistry. 37: 3424-3427. DOI: 10.1021/Ic9713184  0.484
1998 Ray M, Hammes BS, Yap GPA, Rheingold AL, Borovik AS. Structure and Physical Properties of Trigonal Monopyramidal Iron(II), Cobalt(II), Nickel(II), and Zinc(II) Complexes Inorganic Chemistry. 37: 1527-1532. DOI: 10.1021/Ic970831E  0.725
1998 Yu Q, Baroni TE, Liable-Sands L, Rheingold AL, Borovik A. Synthesis and structure of chiral 2,6-bis[(2-carbamoylphenyl)carbamoyl]pyridine ligands Tetrahedron Letters. 39: 6831-6834. DOI: 10.1016/S0040-4039(98)01486-5  0.449
1998 Hammes BS, Ramos-Maldonado D, Yap GP, Rheingold AL, Young VG, Borovik A. The use of C3-symmetric tripodal ligands in crystal engineering Coordination Chemistry Reviews. 174: 241-253. DOI: 10.1016/S0010-8545(98)00051-4  0.35
1997 Hammes BS, Ramos-Maldonado D, Yap GP, Liable-Sands L, Rheingold AL, Young VG, Borovik AS. C(3)-Symmetric Chiral Amidate Complexes: Effects of Ligand Binding on Cavity Structure. Inorganic Chemistry. 36: 3210-3211. PMID 11669981 DOI: 10.1021/Ic970124L  0.466
1997 Shirin Z, Young VG, Borovik AS. Synthesis and structure of a MnIII(OH) complex generated from dioxygen Chemical Communications. 1967-1968. DOI: 10.1039/A703395H  0.482
1996 Ray M, Golombek AP, Hendrich MP, Young VG, Borovik AS. Synthesis and structure of a trigonal monopyramidal Fe(II) complex and its paramagnetic carbon monoxide derivative Journal of the American Chemical Society. 118: 6084-6085. DOI: 10.1021/Ja960036K  0.715
1995 Ray M, Yap GPA, Rheingold AL, Borovik AS. Synthesis and characterization of a trigonal monopyramidal nickel(II) complex Journal of the Chemical Society, Chemical Communications. 1777-1778. DOI: 10.1039/C39950001777  0.745
1995 Krebs JF, Borovik AS. Metallo-network polymers: Reversible CO binding to an immobilized copper(I) complex Journal of the American Chemical Society. 117: 10593-10594. DOI: 10.1021/Ja00147A030  0.317
1995 Borovik AS, Du Bois J, Raymond KN. Metal oxo cation receptors: Multimode coordination to the dioxoosmium(VI) cation Angewandte Chemie (International Edition in English). 34: 1359-1362. DOI: 10.1002/Anie.199513591  0.43
1990 Borovik AS, Hendrich MP, Holman TR, Münck E, Papaefthymiou V, Que L. Models for diferrous forms of iron-oxo proteins. Structure and properties of [Fe2BPMP(O2CR)2]BPh4 complexes Journal of the American Chemical Society. 112: 6031-6038. DOI: 10.1021/Ja00172A019  0.673
1990 Borovik AS, Hendrich MP, Holman TR, Munck E, Papaefthymiou V, Que L. Models for diferrous forms of iron-oxo proteins. Structure and properties of [Fe2BPMP(O2CR)2]BPh4 complexes Journal of the American Chemical Society. 112: 6031-6038. DOI: 10.1021/ja00172a019  0.534
1989 Borovik AS, Papaefthymiou V, Taylor LF, Anderson OP, Que L. Models for iron-oxo proteins. Structures and properties of FeIIFeIII, ZnIIFeIII, and FeIIGaIII complexes with (.mu.-phenoxo)bis(.mu.-carboxylato)dimetal cores Journal of the American Chemical Society. 111: 6183-6195. DOI: 10.1021/Ja00198A032  0.374
1988 Borovik AS, Que L. Models for the iron(II)iron(III) and iron(II)iron(II) forms of iron-oxo proteins Journal of the American Chemical Society. 110: 2345-2347. DOI: 10.1021/Ja00215A079  0.321
1988 Borovik AS, Que L, Papaefthymiou V, Münck E, Taylor LF, Anderson OP. Heterobimetallic complexes with (μ-phenoxo)bis(μ-carboxylato) cores Journal of the American Chemical Society. 110: 1986-1988. DOI: 10.1021/Ja00214A065  0.627
1987 Borovik AS, Murch BP, Que L, Papaefthymiou V, Münck E. Models for iron-oxo proteins: A mixed-valence iron(II)-iron(III) complex Journal of the American Chemical Society. 109: 7190-7191. DOI: 10.1021/Ja00257A048  0.57
1987 Sorrell TN, Borovik AS. Synthesis, structure, and spectroscopic properties of an unusual copper(I) dimer having imidazole ligands. A model for the carbonyl derivative of hemocyanin and implications for the structure of deoxyhemocyanin Journal of the American Chemical Society. 109: 4255-4260. DOI: 10.1021/Ja00248A020  0.654
1987 Sorrell TN, Borovik AS. Absorption, emission, and photophysical properties of copper(I) pyrazole complexes and their carbonyl adducts Inorganic Chemistry. 26: 1957-1964. DOI: 10.1021/Ic00259A029  0.645
1986 Sorrell TN, Borovik AS. Luminescence behavior of copper(I)-imidazole complexes. A spectroscopic model for the carbonyl derivative of hemocyanin. Journal of the American Chemical Society. 108: 2479-81. PMID 22175622 DOI: 10.1002/Chin.198634046  0.65
1986 Sorrell TN, Borovik AS, Caswell DS, Grygon C, Spiro TG. Ultraviolet absorption and resonance Raman spectra of copper(I) complexes Journal of the American Chemical Society. 108: 5636-5637. DOI: 10.1021/Ja00278A051  0.627
1986 Sorrell TN, Borovik AS, Shen CC. Synthesis of new tripod ligands providing a phenolate donor. Structure of a stable monomeric copper(I) phenolate complex [1] Inorganic Chemistry. 25: 589-590. DOI: 10.1021/Ic00225A001  0.685
1986 Sorrell TN, Borovik AS, Caswell DS, Grygon C, Spiro TG. Ultraviolet absorption and resonance raman spectra of copper(I) complexes Journal of the American Chemical Society. 108: 5636-5637.  0.591
1984 Sorrell TN, Borovik AS. Synthesis of a phenoxy-bridged copper(I) dimer and its reaction with dioxygen: Implications for the reversible binding of O2 by hemocyanin Journal of the Chemical Society, Chemical Communications. 1489-1490. DOI: 10.1039/C39840001489  0.654
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