Marcello Gennari, Ph.D. - Publications

Affiliations: 
2008- Université Grenoble Alpes, France 

47 high-probability publications. We are testing a new system for linking publications to authors. You can help! If you notice any inaccuracies, please sign in and mark papers as correct or incorrect matches. If you identify any major omissions or other inaccuracies in the publication list, please let us know.

Year Citation  Score
2020 Gennari M, Duboc C. Bio-inspired, Multifunctional Metal-Thiolate Motif: From Electron Transfer to Sulfur Reactivity and Small-Molecule Activation. Accounts of Chemical Research. PMID 33074643 DOI: 10.1021/acs.accounts.0c00555  0.657
2020 Wang L, Gennari M, Cantú Reinhard FG, Padamati SK, Philouze C, Flot D, Demeshko S, Browne WR, Meyer F, de Visser SP, Duboc C. O Activation by Non-Heme Thiolate-Based Dinuclear Fe Complexes. Inorganic Chemistry. PMID 32057236 DOI: 10.1021/Acs.Inorgchem.9B03633  0.609
2019 Wang L, Gennari M, Cantú Reinhard FG, Guti Eacute Rrez J, Morozan A, Philouze C, Demeshko S, Artero V, Meyer F, de Visser SP, Duboc C. A non-heme diiron complex for (electro)catalytic reduction of dioxygen: tuning the selectivity through electron-delivery. Journal of the American Chemical Society. PMID 31026148 DOI: 10.1021/Jacs.9B02011  0.664
2019 Wang L, Gennari M, Barrozo A, Fize J, Philouze C, Demeshko S, Meyer F, Orio M, Artero V, Duboc C. Role of the Metal Ion in Bio-Inspired Hydrogenase Models: Investigation of a Homodinuclear FeFe Complex vs Its Heterodinuclear NiFe Analogue Acs Catalysis. 10: 177-186. DOI: 10.1021/Acscatal.9B03212  0.662
2018 Ahmed MEA, Chattopadhyay SC, Wang L, Brazzolotto D, Pramanik DP, Aldakov DA, Fize JF, Morozan A, Gennari M, Duboc C, Dey A, Artero V. Hydrogen evolution from aqueous solution mediated by a heterogenized [NiFe]-hydrogenase model: low pH enables catalysis through enzyme-relevant mechanism. Angewandte Chemie (International Ed. in English). PMID 30307683 DOI: 10.1002/Anie.201808215  0.626
2018 Wang L, Cantú Reinhard FG, Philouze C, Demeshko S, de Visser SP, Meyer F, Gennari M, Duboc C. Solvent- and halide- induced (inter)conversion between iron(II)-disulfide and iron(III) thiolate complexes. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 29869814 DOI: 10.1002/Chem.201801377  0.672
2018 Wang L, Zlatar M, Vlahovic F, Demeshko S, Philouze C, Molton F, Meyer F, Duboc C, Gruden M, Gennari M. Experimental and Theoretical Identification of the Origin of Magnetic Anisotropy in Intermediate Spin Ground State Iron(III) Complexes. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 29447424 DOI: 10.1002/Chem.201705989  0.629
2018 Brazzolotto D, Wang L, Tang H, Gennari M, Queyriaux N, Philouze C, Demeshko S, Meyer F, Orio M, Artero V, Hall MB, Duboc C. Tuning Reactivity of Bioinspired [NiFe]-Hydrogenase Models by Ligand Design and Modeling the CO Inhibition Process Acs Catalysis. 8: 10658-10667. DOI: 10.1021/Acscatal.8B02830  0.658
2017 Balestri D, Roux Y, Mattarozzi M, Mucchino C, Heux L, Brazzolotto D, Artero V, Duboc C, Pelagatti P, Marchiò L, Gennari M. Heterogenization of a [NiFe] Hydrogenase Mimic through Simple and Efficient Encapsulation into a Mesoporous MOF. Inorganic Chemistry. 56: 14801-14808. PMID 29193978 DOI: 10.1021/Acs.Inorgchem.7B01824  0.63
2017 Roux Y, Duboc C, Gennari M. Molecular catalysts for N2 reduction: state of the art, mechanism and challenges. Chemphyschem : a European Journal of Chemical Physics and Physical Chemistry. PMID 28834039 DOI: 10.1002/Cphc.201700665  0.62
2017 Duboc C, Brazzolotto D, Cantú Reinhard FG, Smith-Jones J, Retegan M, Amidani L, Faponle AS, Ray K, Philouze C, de Visser SP, Gennari M. A high-valent non heme μ-oxo MnIV dimer generated from a thiolate-bound MnII complex and O2. Angewandte Chemie (International Ed. in English). PMID 28544340 DOI: 10.1002/Anie.201703215  0.616
2016 Brazzolotto D, Gennari M, Queyriaux N, Simmons TR, Pécaut J, Demeshko S, Meyer F, Orio M, Artero V, Duboc C. Nickel-centred proton reduction catalysis in a model of [NiFe] hydrogenase. Nature Chemistry. 8: 1054-1060. PMID 27768098 DOI: 10.1038/Nchem.2575  0.639
2016 Hall N, Orio M, Gennari M, Wills C, Molton F, Philouze C, Jameson GB, Halcrow MA, Blackman AG, Duboc C. Multifrequency cw-EPR and DFT Studies of an Apparent Compressed Octahedral Cu(II) Complex. Inorganic Chemistry. PMID 26814577 DOI: 10.1021/Acs.Inorgchem.5B02287  0.621
2016 Brazzolotto D, Gennari M, Yu S, Pécaut J, Rouzières M, Clérac R, Orio M, Duboc C. Cover Picture: An Experimental and Theoretical Investigation on Pentacoordinated Cobalt(III) Complexes with an Intermediate S= 1 Spin State: How Halide Ligands Affect their Magnetic Anisotropy (Chem. Eur. J. 3/2016) Chemistry - a European Journal. 22: 821-821. DOI: 10.1002/Chem.201680301  0.619
2015 Brazzolotto D, Gennari M, Yu S, Pécaut J, Rouzières M, Clérac R, Orio M, Duboc C. An Experimental and Theoretical Investigation on Pentacoordinated Cobalt(III) Complexes with an Intermediate S=1 Spin State: How Halide Ligands Affect their Magnetic Anisotropy. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 26663486 DOI: 10.1002/chem.201504707  0.549
2015 Brazzolotto D, Gennari M, Yu S, Pécaut J, Rouzières M, Clérac R, Orio M, Duboc C. An Experimental and Theoretical Investigation on Pentacoordinated Cobalt(III) Complexes with an Intermediate S=1 Spin State: How Halide Ligands Affect their Magnetic Anisotropy. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 26607991 DOI: 10.1002/Chem.201502997  0.654
2015 Gennari M, Brazzolotto D, Yu S, Pécaut J, Philouze C, Rouzières M, Clérac R, Orio M, Duboc C. Effect of the Metal on Disulfide/Thiolate Interconversion: Manganese versus Cobalt. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 26548460 DOI: 10.1002/Chem.201502996  0.649
2015 Beckwith MA, Ames W, Vila FD, Krewald V, Pantazis DA, Mantel C, Pécaut J, Gennari M, Duboc C, Collomb MN, Yano J, Rehr JJ, Neese F, DeBeer S. How Accurately Can Extended X-ray Absorption Spectra Be Predicted from First Principles? Implications for Modeling the Oxygen-Evolving Complex in Photosystem II. Journal of the American Chemical Society. PMID 26352328 DOI: 10.1021/Jacs.5B00783  0.6
2015 Gerey B, Gennari M, Gouré E, Pécaut J, Blackman A, Pantazis DA, Neese F, Molton F, Fortage J, Duboc C, Collomb MN. Calcium and heterometallic manganese-calcium complexes supported by tripodal pyridine-carboxylate ligands: structural, EPR and theoretical investigations. Dalton Transactions (Cambridge, England : 2003). PMID 26089197 DOI: 10.1039/C5Dt01776A  0.766
2015 Gennari M, Brazzolotto D, Pécaut J, Cherrier MV, Pollock CJ, DeBeer S, Retegan M, Pantazis DA, Neese F, Rouzières M, Clérac R, Duboc C. Dioxygen Activation and Catalytic Reduction to Hydrogen Peroxide by a Thiolate-Bridged Dimanganese(II) Complex with a Pendant Thiol. Journal of the American Chemical Society. PMID 26076066 DOI: 10.1021/Jacs.5B04917  0.683
2015 Martin-Diaconescu V, Gennari M, Gerey B, Tsui E, Kanady J, Tran R, Pécaut J, Maganas D, Krewald V, Gouré E, Duboc C, Yano J, Agapie T, Collomb MN, DeBeer S. Ca K-edge XAS as a probe of calcium centers in complex systems. Inorganic Chemistry. 54: 1283-92. PMID 25492398 DOI: 10.1021/Ic501991E  0.593
2015 Castillo CE, Gennari M, Stoll T, Fortage J, Deronzier A, Collomb MN, Sandroni M, Légalité F, Blart E, Pellegrin Y, Delacote C, Boujtita M, Odobel F, Rannou P, Sadki S. Visible light-driven electron transfer from a dye-sensitized p -type NiO photocathode to a molecular catalyst in solution: Toward NiO-based photoelectrochemical devices for solar hydrogen production Journal of Physical Chemistry C. 119: 5806-5818. DOI: 10.1021/Jp511469F  0.522
2015 Martínez-Periñán E, Gennari M, Revenga-Parra M, Abad JM, Mateo-Martí E, Pariente F, Castillo O, Mas-Ballesté R, Zamora F, Lorenzo E. Highly dense nickel hydroxide nanoparticles catalyst electrodeposited from a novel Ni(II) paddle–wheel complex Journal of Catalysis. 329: 22-31. DOI: 10.1016/J.Jcat.2015.04.010  0.426
2015 Duboc C, Gennari M. Experimental Techniques for Determining Spin States Spin States in Biochemistry and Inorganic Chemistry: Influence On Structure and Reactivity. 60-83. DOI: 10.1002/9781118898277.ch4  0.468
2014 Gennari M, Légalité F, Zhang L, Pellegrin Y, Blart E, Fortage J, Brown AM, Deronzier A, Collomb MN, Boujtita M, Jacquemin D, Hammarström L, Odobel F. Long-Lived Charge Separated State in NiO-Based p-Type Dye-Sensitized Solar Cells with Simple Cyclometalated Iridium Complexes. The Journal of Physical Chemistry Letters. 5: 2254-8. PMID 26279543 DOI: 10.1021/Jz5009714  0.758
2014 Gennari M, Givaja G, Castillo O, Hermosilla L, Gómez-García CJ, Duboc C, Lledós A, Mas-Ballesté R, Zamora F. On the road to MM'X polymers: redox properties of heterometallic Ni···Pt paddlewheel complexes. Inorganic Chemistry. 53: 10553-62. PMID 25238139 DOI: 10.1021/Ic501659X  0.647
2014 Gennari M, Gerey B, Hall N, Pécaut J, Collomb MN, Rouzières M, Clérac R, Orio M, Duboc C. A bio-inspired switch based on cobalt(II) disulfide/cobalt(III) thiolate interconversion. Angewandte Chemie (International Ed. in English). 53: 5318-21. PMID 24719198 DOI: 10.1002/Anie.201402125  0.674
2014 Stoll T, Gennari M, Fortage J, Castillo CE, Rebarz M, Sliwa M, Poizat O, Odobel F, Deronzier A, Collomb MN. An efficient Ru(II) -Rh(III) -Ru(II) polypyridyl photocatalyst for visible-light-driven hydrogen production in aqueous solution. Angewandte Chemie (International Ed. in English). 53: 1654-8. PMID 24382834 DOI: 10.1002/Anie.201308132  0.723
2014 Gennari M, Givaja G, Castillo O, Hermosilla L, Gómez-García CJ, Duboc C, Lledós A, Mas-Ballesté R, Zamora F. On the road to MM′X polymers: Redox properties of heterometallic Ni···Pt paddlewheel complexes Inorganic Chemistry. 53: 10553-10562. DOI: 10.1021/ic501659x  0.521
2013 Stoll T, Gennari M, Serrano I, Fortage J, Chauvin J, Odobel F, Rebarz M, Poizat O, Sliwa M, Deronzier A, Collomb MN. [Rh(III)(dmbpy)2Cl2]+ as a highly efficient catalyst for visible-light-driven hydrogen production in pure water: comparison with other rhodium catalysts. Chemistry (Weinheim An Der Bergstrasse, Germany). 19: 782-92. PMID 23169449 DOI: 10.1002/Chem.201202555  0.721
2013 Amo-Ochoa P, Jiménez-Aparicio R, Perles J, Torres MR, Gennari M, Zamora F. Structural Diversity in Paddlewheel Dirhodium(II) Compounds through Ionic Interactions: Electronic and Redox Properties Crystal Growth & Design. 13: 4977-4985. DOI: 10.1021/Cg4011532  0.442
2012 Gennari M, Gerey B, Hall N, Pécaut J, Vezin H, Collomb MN, Orio M, Duboc C. Structural, spectroscopic and redox properties of a mononuclear Co(II) thiolate complex--the reactivity toward S-alkylation: an experimental and theoretical study. Dalton Transactions (Cambridge, England : 2003). 41: 12586-94. PMID 22960784 DOI: 10.1039/C2Dt31222K  0.658
2012 Bassanetti I, Mezzadri F, Comotti A, Sozzani P, Gennari M, Calestani G, Marchiò L. Influence of anions in silver supramolecular frameworks: structural characteristics and sorption properties. Journal of the American Chemical Society. 134: 9142-5. PMID 22616571 DOI: 10.1021/Ja303940D  0.351
2012 Gennari M, Pécaut J, Collomb MN, Duboc C. A copper thiolate centre for electron transfer: Mononuclear vs. dinuclear complexes Dalton Transactions. 41: 3130-3133. PMID 22314404 DOI: 10.1039/C2Dt12355J  0.587
2011 Gennari M, Retegan M, DeBeer S, Pécaut J, Neese F, Collomb MN, Duboc C. Experimental and computational investigation of thiolate alkylation in Ni(II) and Zn(II) complexes: role of the metal on the sulfur nucleophilicity. Inorganic Chemistry. 50: 10047-55. PMID 21932763 DOI: 10.1021/Ic200899W  0.672
2011 Gennari M, Pécaut J, DeBeer S, Neese F, Collomb MN, Duboc C. A fully delocalized mixed-valence bis-μ(thiolato) dicopper complex: a structural and functional model of the biological CuA center. Angewandte Chemie (International Ed. in English). 50: 5662-6. PMID 21557415 DOI: 10.1002/Anie.201100605  0.62
2011 Gennari M, Orio M, Pécaut J, Bothe E, Neese F, Collomb MN, Duboc C. Influence of mixed thiolate/thioether versus dithiolate coordination on the accessibility of the uncommon +I and +III oxidation states for the nickel ion: an experimental and computational study. Inorganic Chemistry. 50: 3707-16. PMID 21428312 DOI: 10.1021/Ic200063D  0.674
2010 Bassanetti I, Gennari M, Marchiò L, Terenghi M, Elviri L. Li+, Cu+, and Ag+ oligonuclear structures with the sterically demanding bis(3,5-tertbutylpyrazol-1-yl)dithioacetate heteroscorpionate ligand. Inorganic Chemistry. 49: 7007-7015. PMID 20604575 DOI: 10.1021/Ic100886X  0.373
2010 Gennari M, Orio M, Pécaut J, Neese F, Collomb MN, Duboc C. Reversible apical coordination of imidazole between the Ni(III) and Ni(II) oxidation states of a dithiolate complex: A process related to the Ni superoxide dismutase Inorganic Chemistry. 49: 6399-6401. PMID 20553029 DOI: 10.1021/Ic100945N  0.667
2010 Gennari M, Bassanetti I, Marchiò L. Metal-organic chains constructed from pre-organized N2S2 donor ligands Polyhedron. 29: 361-371. DOI: 10.1016/J.Poly.2009.05.073  0.351
2009 Gennari M, Lanfranchi M, Marchiò L. Novel carbon-centered heteroscorpionate ligands: Cu(I) complexes and luminescence properties Inorganica Chimica Acta. 362: 4430-4438. DOI: 10.1016/J.Ica.2009.05.014  0.384
2008 Gennari M, Tegoni M, Lanfranchi M, Pellinghelli MA, Giannetto M, Marchiò L. CuI complexes with N,N',S,S' scorpionate ligands: evidence for dimer-monomer equilibria. Inorganic Chemistry. 47: 2223-2232. PMID 18269219 DOI: 10.1021/Ic702108X  0.362
2007 Gennari M, Lanfranchi M, Cammi R, Pellinghelli MA, Marchiò L. Mononuclear and polynuclear copper(I) complexes with a new N,N',S-donor ligand and with structural analogies to the copper thionein core. Inorganic Chemistry. 46: 10143-52. PMID 17973478 DOI: 10.1021/Ic701189B  0.326
2007 Gennari M, Tegoni M, Lanfranchi M, Pellinghelli MA, Marchio L. A new chiral N,N',O-donor heteroscorpionate ligand. Structures of Ni2+, Cu2+, Zn2+ complexes and study of solution equilibria by means of 1H NMR/UV-vis titrations and EXSY NMR spectroscopy. Inorganic Chemistry. 46: 3367-3377. PMID 17367129 DOI: 10.1021/Ic062228E  0.402
2006 Gennari M, Lanfranchi M, Marchiò L, Pellinghelli MA, Tegoni M, Cammi R. Cu(I) dinuclear complexes with tripodal ligands vs monodentate donors: triphenylphosphine, thiourea, and pyridine. A 1H NMR titration study. Inorganic Chemistry. 45: 3456-66. PMID 16602807 DOI: 10.1021/Ic052129L  0.414
2005 Cammi R, Gennari M, Giannetto M, Lanfranchi M, Marchio L, Mori G, Paiola C, Pellinghelli MA. Synthesis, structure, and electrochemical properties of copper(I) complexes with S/N homoscorpionate and heteroscorpionate ligands. Inorganic Chemistry. 44: 4333-45. PMID 15934764 DOI: 10.1021/Ic048221J  0.39
2004 Gennari M, Giannetto M, Lanfranchi M, Marchiò L, Pellinghelli MA, Tegoni M. Synthesis, structure and electrochemical properties of a nickel complex with the hydrotris[thioxotriazolyl-3-(2-pyridyl)]borate podand ligand Polyhedron. 23: 1829-1835. DOI: 10.1016/J.Poly.2004.04.009  0.47
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