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Kyle Matthew Lancaster, Ph.D. - Publications

Affiliations: 
2012- Department of Chemistry and Chemical Biology Cornell University, Ithaca, NY, United States 
Area:
Bioinorganic chemistry, Inorganic spectroscopy
Website:
http://lancaster.chem.cornell.edu
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100 high-probability publications. We are testing a new system for linking publications to authors. You can help! If you notice any inaccuracies, please sign in and mark papers as correct or incorrect matches. If you identify any major omissions or other inaccuracies in the publication list, please let us know.

Year Citation  Score
2024 Knoell T, Polanco J, MacMillan SN, Bertke JA, Foroutan-Nejad C, Lancaster KM, 'Gus' Bakhoda A. Alkaline earth metal-assisted dinitrogen activation at nickel. Dalton Transactions (Cambridge, England : 2003). 53: 4689-4697. PMID 38362644 DOI: 10.1039/d3dt03984f  0.624
2023 Senthil S, Kwon S, Kong RY, MacMillan SN, Zatsepin P, Gau MR, Carroll PJ, Baik MH, Lancaster KM, Mindiola DJ. Tellurolate: an effective Te-atom transfer reagent to prepare the triad of group 5 metal bis(tellurides). Chemical Science. 14: 12277-12282. PMID 37969607 DOI: 10.1039/d3sc03470d  0.771
2023 Kong RY, Parry JB, Anello GR, Ong ME, Lancaster KM. Accelerating σ-Bond Metathesis at Sn(II) Centers. Journal of the American Chemical Society. 145: 24136-24144. PMID 37870565 DOI: 10.1021/jacs.3c07997  0.645
2023 Bollmeyer MM, Majer SH, Coleman RE, Lancaster KM. Outer coordination sphere influences on cofactor maturation and substrate oxidation by cytochrome P460. Chemical Science. 14: 8295-8304. PMID 37564409 DOI: 10.1039/d3sc02288a  0.767
2023 DiMucci IM, Titus CJ, Nordlund D, Bour JR, Chong E, Grigas DP, Hu CH, Kosobokov MD, Martin CD, Mirica LM, Nebra N, Vicic DA, Yorks LL, Yruegas S, MacMillan SN, ... ... Lancaster KM, et al. Scrutinizing formally Ni centers through the lenses of core spectroscopy, molecular orbital theory, and valence bond theory. Chemical Science. 14: 6915-6929. PMID 37389249 DOI: 10.1039/d3sc02001k  0.669
2023 Bollmeyer MM, Coleman RE, Majer SH, Ferrao SD, Lancaster KM. Cytochrome P460 Cofactor Maturation Proceeds via Peroxide-Dependent Post-translational Modification. Journal of the American Chemical Society. 145: 14404-14416. PMID 37338957 DOI: 10.1021/jacs.3c03608  0.76
2023 Azbell TJ, Pitt TA, Bollmeyer MM, Cong C, Lancaster KM, Milner P. Ionothermal Synthesis of Metal-Organic Frameworks Using Low-Melting Metal Salt Precursors. Angewandte Chemie (International Ed. in English). e202218252. PMID 36811601 DOI: 10.1002/anie.202218252  0.758
2022 Dey A, Albert T, Kong RY, MacMillan SN, Moënne-Loccoz P, Lancaster KM, Goldberg DP. Direct Reduction of NO to NO by a Mononuclear Nonheme Thiolate Ligated Iron(II) Complex via Formation of a Metastable {FeNO} Complex. Inorganic Chemistry. 61: 14909-14917. PMID 36107151 DOI: 10.1021/acs.inorgchem.2c02383  0.765
2022 Kayser AK, Wolczanski PT, Cundari TR, Bollmeyer MM, Lancaster KM, MacMillan SN. TEMPO coordination and reactivity in group 6; pseudo-pentagonal planar (η-TEMPO)CrX (X = Cl, TEMPO). Chemical Communications (Cambridge, England). PMID 35975596 DOI: 10.1039/d2cc03838b  0.775
2022 Roy MD, Trenerry MJ, Thakuri B, MacMillan SN, Liptak MD, Lancaster KM, Berry JF. Electronic Structure of Ru Complexes with Electron-Rich Anilinopyridinate Ligands. Inorganic Chemistry. PMID 35175754 DOI: 10.1021/acs.inorgchem.1c03346  0.658
2022 Skubi KL, Hooper RX, Mercado BQ, Bollmeyer MM, MacMillan SN, Lancaster KM, Holland PL. Iron Complexes of a Proton-Responsive SCS Pincer Ligand with a Sensitive Electronic Structure. Inorganic Chemistry. PMID 34986307 DOI: 10.1021/acs.inorgchem.1c03499  0.805
2021 Nava M, Zhang S, Pastore KS, Feng X, Lancaster KM, Nocera DG, Cummins CC. Lithium superoxide encapsulated in a benzoquinone anion matrix. Proceedings of the National Academy of Sciences of the United States of America. 118. PMID 34903644 DOI: 10.1073/pnas.2019392118  0.436
2021 Pokhriyal D, Heins SP, Sifri RJ, Gentekos DT, Coleman RE, Wolczanski PT, Cundari TR, Fors BP, Lancaster KM, MacMillan SN. Reversible C-C Bond Formation, Halide Abstraction, and Electromers in Complexes of Iron Containing Redox-Noninnocent Pyridine-imine Ligands. Inorganic Chemistry. 60: 18662-18673. PMID 34889590 DOI: 10.1021/acs.inorgchem.1c01815  0.655
2021 Dey A, Gordon JB, Albert T, Sabuncu S, Siegler MA, MacMillan SN, Lancaster KM, Moënne-Loccoz P, Goldberg DP. A Nonheme Mononuclear {FeNO} Complex that Produces N O in the Absence of an Exogenous Reductant. Angewandte Chemie (International Ed. in English). PMID 34415659 DOI: 10.1002/anie.202109062  0.641
2021 Liu J, Bollmeyer MM, Kim Y, Xiao D, MacMillan SN, Chen Q, Leng X, Kim SH, Zhao L, Lancaster KM, Deng L. An Isolable Mononuclear Palladium(I) Amido Complex. Journal of the American Chemical Society. PMID 34232039 DOI: 10.1021/jacs.1c04965  0.764
2021 Liu J, Bollmeyer MM, Kim Y, Xiao D, MacMillan SN, Chen Q, Leng X, Kim SH, Zhao L, Lancaster KM, Deng L. An Isolable Mononuclear Palladium(I) Amido Complex. Journal of the American Chemical Society. PMID 34232039 DOI: 10.1021/jacs.1c04965  0.764
2021 Zhang Y, Su D, Dzikovski B, Majer SH, Coleman R, Chandrasekaran S, Fenwick MK, Crane BR, Lancaster KM, Freed JH, Lin H. Dph3 Enables Aerobic Diphthamide Biosynthesis by Donating One Iron Atom to Transform a [3Fe-4S] to a [4Fe-4S] Cluster in Dph1-Dph2. Journal of the American Chemical Society. PMID 34154323 DOI: 10.1021/jacs.1c03956  0.777
2020 Rathnayaka SC, Islam SM, DiMucci IM, MacMillan SN, Lancaster KM, Mankad NP. Probing the electronic and mechanistic roles of the μ-sulfur atom in a synthetic Cu model system. Chemical Science. 11: 3441-3447. PMID 34745516 DOI: 10.1039/c9sc06251c  0.629
2020 Nagelski AL, Fataftah MS, Bollmeyer MM, McWilliams SF, MacMillan SN, Mercado BQ, Lancaster KM, Holland PL. The influences of carbon donor ligands on biomimetic multi-iron complexes for N reduction. Chemical Science. 11: 12710-12720. PMID 34094466 DOI: 10.1039/d0sc03447a  0.798
2020 Reinholdt A, Pividori D, Laughlin AL, DiMucci IM, MacMillan SN, Jafari MG, Gau MR, Carroll PJ, Krzystek J, Ozarowski A, Telser J, Lancaster KM, Meyer K, Mindiola DJ. A Mononuclear and High-Spin Tetrahedral Ti Complex. Inorganic Chemistry. PMID 33258366 DOI: 10.1021/acs.inorgchem.0c02586  0.78
2020 DiMucci IM, MacMillan SN, Walroth RC, Lancaster KM. Scrutinizing "Ligand Bands" via Polarized Single-Crystal X-ray Absorption Spectra of Copper(I) and Copper(II) Bis-2,2'-bipyridine Species. Inorganic Chemistry. 59: 13416-13426. PMID 32871080 DOI: 10.1021/Acs.Inorgchem.0C01800  0.641
2020 Shreiber ST, DiMucci IM, Khrizanforov MN, Titus CJ, Nordlund D, Dudkina Y, Cramer RE, Budnikova Y, Lancaster KM, Vicic DA. [(MeCN)Ni(CF)] and [Ni(CF)]: Foundations toward the Development of Trifluoromethylations at Unsupported Nickel. Inorganic Chemistry. PMID 32573210 DOI: 10.1021/Acs.Inorgchem.0C01020  0.375
2020 Wu T, MacMillan SN, Rajabimoghadam K, Siegler MA, Lancaster KM, Garcia-Bosch I. Structure, spectroscopy and reactivity of a mononuclear copper hydroxide complex in three molecular oxidation states. Journal of the American Chemical Society. PMID 32531159 DOI: 10.1021/Jacs.0C03867  0.706
2020 Coleman RE, Vilbert AC, Lancaster KM. The Heme-Lys Cross-Link in Cytochrome P460 Promotes Catalysis by Enforcing Secondary Coordination Sphere Architecture. Biochemistry. PMID 32525655 DOI: 10.1021/Acs.Biochem.0C00261  0.343
2020 Goodwin CAP, Réant BLL, Vettese GF, Kragskow JGC, Giansiracusa MJ, DiMucci IM, Lancaster KM, Mills DP, Sproules S. Heteroleptic Samarium(III) Chalcogenide Complexes: Opportunities for Giant Exchange Coupling in Bridging σ- and π-Radical Lanthanide Dichalcogenides. Inorganic Chemistry. PMID 32421315 DOI: 10.1021/Acs.Inorgchem.0C00470  0.451
2020 Ferousi C, Majer SH, DiMucci IM, Lancaster KM. Biological and Bioinspired Inorganic N-N Bond-Forming Reactions. Chemical Reviews. PMID 32108471 DOI: 10.1021/Acs.Chemrev.9B00629  0.781
2020 Carsch KM, Lukens JT, DiMucci IM, Iovan DA, Zheng SL, Lancaster KM, Betley TA. Electronic Structures and Reactivity Profiles of Aryl Nitrenoid-Bridged Dicopper Complexes. Journal of the American Chemical Society. PMID 31917556 DOI: 10.1021/Jacs.9B09616  0.425
2020 Nagelski AL, Fataftah MS, Bollmeyer MM, McWilliams SF, MacMillan SN, Mercado BQ, Lancaster KM, Holland PL. The influences of carbon donor ligands on biomimetic multi-iron complexes for N2 reduction Chemical Science. DOI: 10.1039/D0Sc03447A  0.434
2020 Rathnayaka SC, Islam SM, DiMucci IM, MacMillan SN, Lancaster KM, Mankad NP. Probing the electronic and mechanistic roles of the μ4-sulfur atom in a synthetic CuZ model system Chemical Science. 11: 3441-3447. DOI: 10.1039/C9Sc06251C  0.31
2020 Dong Y, Lukens JT, Clarke RM, Zheng S, Lancaster KM, Betley TA. Synthesis, characterization and C–H amination reactivity of nickel iminyl complexes Chemical Science. 11: 1260-1268. DOI: 10.1039/C9Sc04879K  0.36
2020 He X, Looker BG, Dinh KT, Stubbs AW, Chen T, Meyer RJ, Serna P, Román-Leshkov Y, Lancaster KM, Dincă M. Cerium(IV) Enhances the Catalytic Oxidation Activity of Single-Site Cu Active Sites in MOFs Acs Catalysis. 10: 7820-7825. DOI: 10.1021/Acscatal.0C02493  0.317
2019 Dong Y, Lukens JT, Clarke RM, Zheng SL, Lancaster KM, Betley TA. Synthesis, characterization and C-H amination reactivity of nickel iminyl complexes. Chemical Science. 11: 1260-1268. PMID 34123250 DOI: 10.1039/c9sc04879k  0.332
2019 MacLeod KC, DiMucci IM, Zovinka EP, McWilliams SF, Mercado BQ, Lancaster KM, Holland PL. Masked Radicals: Iron Complexes of Trityl, Benzophenone, and Phenylacetylene. Organometallics. 38: 4224-4232. PMID 34103782 DOI: 10.1021/acs.organomet.9b00534  0.307
2019 DiMucci IM, Lukens JT, Chatterjee S, Carsch KM, Titus CJ, Lee SJ, Nordlund D, Betley TA, MacMillan SN, Lancaster KM. The Myth of d Copper(III). Journal of the American Chemical Society. PMID 31710466 DOI: 10.1021/Jacs.9B09016  0.692
2019 Gordon JB, Vilbert AC, DiMucci IM, MacMillan SN, Lancaster KM, Moënne-Loccoz P, Goldberg DP. Activation of Dioxygen by a Mononuclear Nonheme Iron Complex: Sequential Peroxo, Oxo, and Hydroxo Intermediates. Journal of the American Chemical Society. PMID 31647656 DOI: 10.1021/Jacs.9B05274  0.667
2019 Carsch KM, DiMucci IM, Iovan DA, Li A, Zheng SL, Titus CJ, Lee SJ, Irwin KD, Nordlund D, Lancaster KM, Betley TA. Synthesis of a copper-supported triplet nitrene complex pertinent to copper-catalyzed amination. Science (New York, N.Y.). 365: 1138-1143. PMID 31515388 DOI: 10.1126/Science.Aax4423  0.391
2019 Dunn PL, Chatterjee S, MacMillan SN, Pearce AJ, Lancaster KM, Tonks IA. The 4-Electron Cleavage of a N═N Double Bond by a Trimetallic TiNi Complex. Inorganic Chemistry. PMID 31436979 DOI: 10.1021/Acs.Inorgchem.9B01805  0.718
2019 Dempsey JL, Lancaster KM. Celebrating the Year of the Periodic Table: Emerging Investigators in Inorganic Chemistry. Inorganic Chemistry. 58: 10433-10435. PMID 31422668 DOI: 10.1021/Acs.Inorgchem.9B02174  0.531
2019 Muok AR, Deng Y, Gumerov VM, Chong JE, DeRosa JR, Kurniyati K, Coleman RE, Lancaster KM, Li C, Zhulin IB, Crane BR. A di-iron protein recruited as an Fe[II] and oxygen sensor for bacterial chemotaxis functions by stabilizing an iron-peroxy species. Proceedings of the National Academy of Sciences of the United States of America. PMID 31270241 DOI: 10.1073/Pnas.1904234116  0.341
2019 Lukens JT, DiMucci IM, Kurogi T, Mindiola DJ, Lancaster KM. Scrutinizing metal-ligand covalency and redox non-innocence nitrogen K-edge X-ray absorption spectroscopy. Chemical Science. 10: 5044-5055. PMID 31183055 DOI: 10.1039/C8Sc03350A  0.418
2019 Smith MA, Majer SH, Vilbert AC, Lancaster KM. Controlling a burn: outer-sphere gating of hydroxylamine oxidation by a distal base in cytochrome P460. Chemical Science. 10: 3756-3764. PMID 31015919 DOI: 10.1039/C9Sc00195F  0.794
2019 Confer AM, Vilbert AC, Dey A, Lancaster KM, Goldberg DP. A Mononuclear, Nonheme Fe-Piloty's Acid (PhSONHOH) Adduct: An Intermediate in the Production of {FeNO} Complexes from Piloty's Acid. Journal of the American Chemical Society. PMID 30994347 DOI: 10.1021/Jacs.9B01700  0.416
2019 Moore JT, Chatterjee S, Tarrago M, Clouston LJ, Sproules S, Bill E, Bernales V, Gagliardi L, Ye S, Lancaster KM, Lu CC. Enhanced Fe-Centered Redox Flexibility in Fe-Ti Heterobimetallic Complexes. Inorganic Chemistry. PMID 30957996 DOI: 10.1021/Acs.Inorgchem.9B00442  0.576
2019 Reinholdt A, Majer SH, Gelardi RM, MacMillan SN, Hill AF, Wendt OF, Lancaster KM, Bendix J. An Approach to Carbide-Centered Cluster Complexes. Inorganic Chemistry. PMID 30916952 DOI: 10.1021/Acs.Inorgchem.8B03222  0.793
2019 Gordon JB, Vilbert AC, Siegler MA, Lancaster KM, Moënne-Loccoz P, Goldberg DP. A Nonheme Thiolate-Ligated Cobalt Superoxo Complex: Synthesis and Spectroscopic Characterization, Computational Studies, and Hydrogen Atom Abstraction Reactivity. Journal of the American Chemical Society. PMID 30776222 DOI: 10.1021/Jacs.8B13134  0.396
2019 Roy L, Al-Afyouni MH, DeRosha DE, Mondal B, DiMucci IM, Lancaster KM, Shearer J, Bill E, Brennessel WW, Neese F, Ye S, Holland PL. Reduction of CO by a masked two-coordinate cobalt(i) complex and characterization of a proposed oxodicobalt(ii) intermediate. Chemical Science. 10: 918-929. PMID 30774886 DOI: 10.1039/C8Sc02599A  0.379
2019 MacLeod KC, DiMucci IM, Zovinka EP, McWilliams SF, Mercado BQ, Lancaster KM, Holland PL. Masked Radicals: Iron Complexes of Trityl, Benzophenone, and Phenylacetylene Organometallics. 38: 4224-4232. DOI: 10.1021/Acs.Organomet.9B00534  0.422
2019 Hulley EB, Heins SP, Wolczanski PT, Lancaster KM, Lobkovsky EB. Azaallyl-derived ring formation via redox coupling in first row transition metals Polyhedron. 158: 225-233. DOI: 10.1016/J.Poly.2018.10.070  0.314
2018 Leguto AJ, Smith MA, Morgada MN, Zitare UA, Murgida DH, Lancaster KM, Vila AJ. Dramatic electronic perturbations of Cu centers via subtle geometric changes. Journal of the American Chemical Society. PMID 30582893 DOI: 10.1021/Jacs.8B12335  0.322
2018 Siu JC, Sauer GS, Saha A, Macey RL, Fu N, Chauvire T, Lancaster KM, Lin S. Electrochemical Azidooxygenation of Alkenes Mediated by a TEMPO-N3 Charge-Transfer Complex. Journal of the American Chemical Society. PMID 30160949 DOI: 10.1021/Jacs.8B06744  0.363
2018 Cook BJ, Di Francesco GN, Ferreira RB, Lukens JT, Silberstein KE, Keegan BC, Catalano VJ, Lancaster KM, Shearer J, Murray LJ. Chalcogen Impact on Covalency within Molecular [Cu(μ-E)] Clusters (E = O, S, Se): A Synthetic, Spectroscopic, and Computational Study. Inorganic Chemistry. PMID 30160943 DOI: 10.1021/Acs.Inorgchem.8B01000  0.354
2018 Goldberg DP, Dey A, Confer AM, Vilbert AC, Moënne-Loccoz P, Lancaster KM. A Nonheme Sulfur-ligated {FeNO}6 Complex and Comparison with Redox-Interconvertible {FeNO}7 and {FeNO}8 Analogs. Angewandte Chemie (International Ed. in English). PMID 30125450 DOI: 10.1002/Anie.201806146  0.453
2018 Chen JG, Crooks RM, Seefeldt LC, Bren KL, Bullock RM, Darensbourg MY, Holland PL, Hoffman B, Janik MJ, Jones AK, Kanatzidis MG, King P, Lancaster KM, Lymar SV, Pfromm P, et al. Beyond fossil fuel-driven nitrogen transformations. Science (New York, N.Y.). 360. PMID 29798857 DOI: 10.1126/Science.Aar6611  0.58
2018 Goodwin CAP, Réant BLL, Kragskow JGC, DiMucci IM, Lancaster KM, Mills DP, Sproules S. Heteroleptic samarium(iii) halide complexes probed by fluorescence-detected L-edge X-ray absorption spectroscopy. Dalton Transactions (Cambridge, England : 2003). PMID 29790545 DOI: 10.1039/C8Dt01452C  0.432
2018 Lancaster KM. Sizing up a supercharged ferryl. Proceedings of the National Academy of Sciences of the United States of America. PMID 29666275 DOI: 10.1073/Pnas.1804490115  0.403
2018 Broere D, Mercado B, Lukens J, Vilbert A, Banerjee G, Lant H, Lee SH, Bill E, Lancaster K, Sproules S, Holland P. Reversible Ligand-Centered Reduction in Low- Coordinate Iron Formazanate Complexes. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 29663542 DOI: 10.1002/Chem.201801298  0.427
2018 Broere DLJ, Mercado BQ, Bill E, Lancaster KM, Sproules S, Holland PL. Alkali Cation Effects on Redox-Active Formazanate Ligands in Iron Chemistry. Inorganic Chemistry. PMID 29629752 DOI: 10.1021/Acs.Inorgchem.8B00226  0.438
2018 Vilbert AC, Caranto JD, Lancaster KM. Influences of the heme-lysine crosslink in cytochrome P460 over redox catalysis and nitric oxide sensitivity. Chemical Science. 9: 368-379. PMID 29629106 DOI: 10.1039/C7Sc03450D  0.757
2018 Dong M, Kathiresan V, Fenwick MK, Torelli AT, Zhang Y, Caranto JD, Dzikovski B, Sharma A, Lancaster KM, Freed JH, Ealick SE, Hoffman BM, Lin H. Organometallic and radical intermediates reveal mechanism of diphthamide biosynthesis. Science (New York, N.Y.). 359: 1247-1250. PMID 29590073 DOI: 10.1126/Science.Aao6595  0.735
2018 Lancaster KM, Caranto JD, Majer SH, Smith MA. Alternative Bioenergy: Updates to and Challenges in Nitrification Metalloenzymology Joule. 2: 421-441. DOI: 10.1016/J.Joule.2018.01.018  0.768
2017 Smith MA, Lancaster KM. The Eponymous Cofactors in Cytochrome P460s from Ammonia-Oxidizing Bacteria Are Iron Porphyrinoids Whose Macrocycles Are Dibasic. Biochemistry. PMID 29211462 DOI: 10.1021/Acs.Biochem.7B00921  0.34
2017 Agnew DW, DiMucci IM, Arroyave A, Gembicky M, Moore CE, MacMillan SN, Rheingold AL, Lancaster KM, Figueroa JS. Crystalline Coordination Networks of Zero-Valent Metal Centers: Formation of a 3-Dimensional Ni(0) Framework with m-Terphenyl Diisocyanides. Journal of the American Chemical Society. PMID 29131949 DOI: 10.1021/Jacs.7B09569  0.64
2017 Wilding MJT, Iovan DA, Wrobel AT, Lukens JT, MacMillan SN, Lancaster KM, Betley TA. Direct comparison of C-H bond amination efficacy through manipulation of nitrogen-valence centered redox: imido versus iminyl. Journal of the American Chemical Society. PMID 28937756 DOI: 10.1021/Jacs.7B08714  0.708
2017 Walroth RC, Miles KC, Lukens JT, MacMillan SN, Stahl SS, Lancaster KM. Electronic Structural Analysis of Copper(II)-TEMPO/ABNO Complexes Provides Evidence for Copper(I)-Oxoammonium Character. Journal of the American Chemical Society. PMID 28921958 DOI: 10.1021/Jacs.7B07186  0.657
2017 Obanda A, Martinez K, Schmehl RH, Mague JT, Rubtsov IV, MacMillan SN, Lancaster KM, Sproules S, Donahue JP. Expanding the Scope of Ligand Substitution from [M(S2C2Ph2] (M = Ni(2+), Pd(2+), Pt(2+)) To Afford New Heteroleptic Dithiolene Complexes. Inorganic Chemistry. PMID 28820242 DOI: 10.1021/Acs.Inorgchem.7B00971  0.652
2017 Caranto JD, Lancaster KM. Nitric oxide is an obligate bacterial nitrification intermediate produced by hydroxylamine oxidoreductase. Proceedings of the National Academy of Sciences of the United States of America. PMID 28716929 DOI: 10.1073/Pnas.1704504114  0.742
2017 MacMillan SN, Lancaster KM. X-ray Spectroscopic Interrogation of Transition-Metal-Mediated Homogeneous Catalysis: Primer and Case Studies Acs Catalysis. 7: 1776-1791. DOI: 10.1021/Acscatal.6B02875  0.343
2016 Caranto JD, Vilbert AC, Lancaster KM. Nitrosomonas europaea cytochrome P460 is a direct link between nitrification and nitrous oxide emission. Proceedings of the National Academy of Sciences of the United States of America. PMID 27856762 DOI: 10.1073/Pnas.1611051113  0.759
2016 Walroth RC, Lukens JT, MacMillan SN, Finkelstein KD, Lancaster KM. Spectroscopic Evidence for a 3d(10) Ground State Electronic Configuration and Ligand Field Inversion in [Cu(CF3)4](1.) Journal of the American Chemical Society. PMID 26844693 DOI: 10.1021/Jacs.5B10819  0.661
2016 Varela-Álvarez A, Yang T, Jennings H, Kornecki KP, MacMillan SN, Lancaster KM, Mack JB, Du Bois J, Berry JF, Musaev DG. Rh2(II,III) Catalysts with Chelating Carboxylate and Carboxamidate Supports: Electronic Structure and Nitrene Transfer Reactivity. Journal of the American Chemical Society. PMID 26820386 DOI: 10.1021/Jacs.5B12790  0.646
2016 Corcos AR, Villanueva O, Walroth RC, Sharma SK, Bacsa J, Lancaster KM, MacBeth CE, Berry JF. Oxygen Activation by Co(II) and a Redox Non-Innocent Ligand: Spectroscopic Characterization of a Radical-Co(II)-Superoxide Complex with Divergent Catalytic Reactivity. Journal of the American Chemical Society. PMID 26799113 DOI: 10.1021/Jacs.5B12643  0.372
2015 Walroth RC, Uebler JW, Lancaster KM. Probing Cu(I) in homogeneous catalysis using high-energy-resolution fluorescence-detected X-ray absorption spectroscopy. Chemical Communications (Cambridge, England). 51: 9864-7. PMID 25994112 DOI: 10.1039/C5Cc01827G  0.352
2015 Yao SA, Martin-Diaconescu V, Infante I, Lancaster KM, Götz AW, DeBeer S, Berry JF. Electronic Structure of Ni₂E₂ Complexes (E = S, Se, Te) and a Global Analysis of M₂E₂ Compounds: A Case for Quantized E₂(n-) Oxidation Levels with n = 2, 3, or 4. Journal of the American Chemical Society. 137: 4993-5011. PMID 25797853 DOI: 10.1021/Ja511607J  0.765
2015 Morsing TJ, MacMillan SN, Uebler JW, Brock-Nannestad T, Bendix J, Lancaster KM. Stabilizing coordinated radicals via metal-ligand covalency: a structural, spectroscopic, and theoretical investigation of group 9 tris(dithiolene) complexes. Inorganic Chemistry. 54: 3660-9. PMID 25756298 DOI: 10.1021/Acs.Inorgchem.5B00289  0.763
2015 MacMillan SN, Walroth RC, Perry DM, Morsing TJ, Lancaster KM. Ligand-sensitive but not ligand-diagnostic: evaluating Cr valence-to-core X-ray emission spectroscopy as a probe of inner-sphere coordination. Inorganic Chemistry. 54: 205-14. PMID 25496512 DOI: 10.1021/Ic502152R  0.656
2015 Zeng T, Lancaster KM, Ananth N, Hoffmann R. Anomalous orbital admixture in ammine complexes Journal of Organometallic Chemistry. DOI: 10.1016/J.Jorganchem.2015.05.032  0.379
2014 Neu HM, Quesne MG, Yang T, Prokop-Prigge KA, Lancaster KM, Donohoe J, DeBeer S, de Visser SP, Goldberg DP. Dramatic influence of an anionic donor on the oxygen-atom transfer reactivity of a Mn(V) -oxo complex. Chemistry (Weinheim An Der Bergstrasse, Germany). 20: 14584-8. PMID 25256417 DOI: 10.1002/Chem.201404349  0.618
2014 Pollock CJ, Lancaster KM, Finkelstein KD, DeBeer S. Study of iron dimers reveals angular dependence of valence-to-core X-ray emission spectra. Inorganic Chemistry. 53: 10378-85. PMID 25211540 DOI: 10.1021/Ic501462Y  0.769
2014 Jayarathne U, Chandrasekaran P, Greene AF, Mague JT, DeBeer S, Lancaster KM, Sproules S, Donahue JP. X-ray absorption spectroscopy systematics at the tungsten L-edge. Inorganic Chemistry. 53: 8230-41. PMID 25068843 DOI: 10.1021/Ic500256A  0.622
2014 Pollock CJ, Tan LL, Zhang W, Lancaster KM, Lee SC, DeBeer S. Light-atom influences on the electronic structures of iron-sulfur clusters. Inorganic Chemistry. 53: 2591-7. PMID 24552488 DOI: 10.1021/Ic402944R  0.766
2013 Kornecki KP, Briones JF, Boyarskikh V, Fullilove F, Autschbach J, Schrote KE, Lancaster KM, Davies HM, Berry JF. Direct spectroscopic characterization of a transitory dirhodium donor-acceptor carbene complex. Science (New York, N.Y.). 342: 351-4. PMID 24030489 DOI: 10.1126/Science.1243200  0.391
2013 Yan Y, Keating C, Chandrasekaran P, Jayarathne U, Mague JT, DeBeer S, Lancaster KM, Sproules S, Rubtsov IV, Donahue JP. Ancillary ligand effects upon dithiolene redox noninnocence in tungsten bis(dithiolene) complexes. Inorganic Chemistry. 52: 6743-51. PMID 23675834 DOI: 10.1021/Ic4009174  0.579
2013 Lancaster KM, Hu Y, Bergmann U, Ribbe MW, DeBeer S. X-ray spectroscopic observation of an interstitial carbide in NifEN-bound FeMoco precursor. Journal of the American Chemical Society. 135: 610-2. PMID 23276198 DOI: 10.1021/Ja309254G  0.596
2013 Williams VA, Hulley EB, Wolczanski PT, Lancaster KM, Lobkovsky EB. Exploring the limits of redox non-innocence: Pseudo square planar [{κ4-Me2C(CH2NCHpy)2}Ni] n (n = 2+, 1+, 0, -1, -2) favor Ni(ii) Chemical Science. 4: 3636-3648. DOI: 10.1039/C3Sc50743B  0.324
2012 Palmer JH, Lancaster KM. Molecular redox: revisiting the electronic structures of the group 9 metallocorroles. Inorganic Chemistry. 51: 12473-82. PMID 23116160 DOI: 10.1021/Ic3018826  0.555
2012 Kropp H, King AE, Khusniyarov MM, Heinemann FW, Lancaster KM, DeBeer S, Bill E, Meyer K. Manganese nitride complexes in oxidation states III, IV, and V: synthesis and electronic structure. Journal of the American Chemical Society. 134: 15538-44. PMID 22920682 DOI: 10.1021/Ja306647C  0.627
2012 Yao SA, Lancaster KM, Götz AW, DeBeer S, Berry JF. X-ray absorption spectroscopic, crystallographic, theoretical (DFT) and chemical evidence for a chalcogen-chalcogen two-center/three-electron half bond in an unprecedented "subselenide" Se2(3-) ligand. Chemistry (Weinheim An Der Bergstrasse, Germany). 18: 9179-83. PMID 22730046 DOI: 10.1002/Chem.201201291  0.605
2012 Warren JJ, Lancaster KM, Richards JH, Gray HB. Inner- and outer-sphere metal coordination in blue copper proteins. Journal of Inorganic Biochemistry. 115: 119-26. PMID 22658756 DOI: 10.1016/J.Jinorgbio.2012.05.002  0.644
2012 Lancaster KM, Zaballa ME, Sproules S, Sundararajan M, DeBeer S, Richards JH, Vila AJ, Neese F, Gray HB. Outer-sphere contributions to the electronic structure of type zero copper proteins. Journal of the American Chemical Society. 134: 8241-53. PMID 22563915 DOI: 10.1021/Ja302190R  0.629
2012 Potapov A, Lancaster KM, Richards JH, Gray HB, Goldfarb D. Spin delocalization over type zero copper. Inorganic Chemistry. 51: 4066-75. PMID 22432748 DOI: 10.1021/Ic202336M  0.45
2012 Scarborough CC, Lancaster KM, DeBeer S, Weyhermüller T, Sproules S, Wieghardt K. Experimental fingerprints for redox-active terpyridine in [Cr(tpy)2](PF6)n (n = 3-0), and the remarkable electronic structure of [Cr(tpy)2]1-. Inorganic Chemistry. 51: 3718-32. PMID 22424275 DOI: 10.1021/Ic2027219  0.629
2011 Lancaster KM, Roemelt M, Ettenhuber P, Hu Y, Ribbe MW, Neese F, Bergmann U, DeBeer S. X-ray emission spectroscopy evidences a central carbon in the nitrogenase iron-molybdenum cofactor. Science (New York, N.Y.). 334: 974-7. PMID 22096198 DOI: 10.1126/Science.1206445  0.599
2011 Lancaster KM, Finkelstein KD, DeBeer S. Kβ X-ray emission spectroscopy offers unique chemical bonding insights: revisiting the electronic structure of ferrocene. Inorganic Chemistry. 50: 6767-74. PMID 21692497 DOI: 10.1021/Ic200822B  0.615
2011 Lancaster KM, Farver O, Wherland S, Crane EJ, Richards JH, Pecht I, Gray HB. Electron transfer reactivity of type zero Pseudomonas aeruginosa azurin. Journal of the American Chemical Society. 133: 4865-73. PMID 21405124 DOI: 10.1021/Ja1093919  0.44
2011 El Nahhas A, Consani C, Blanco-Rodríguez AM, Lancaster KM, Braem O, Cannizzo A, Towrie M, Clark IP, Zális S, Chergui M, Vlcek A. Ultrafast excited-state dynamics of rhenium(I) photosensitizers [Re(Cl)(CO)3(N,N)] and [Re(imidazole)(CO)3(N,N)]+: diimine effects. Inorganic Chemistry. 50: 2932-43. PMID 21388162 DOI: 10.1021/Ic102324P  0.337
2010 Lancaster KM, Sproules S, Palmer JH, Richards JH, Gray HB. Outer-sphere effects on reduction potentials of copper sites in proteins: the curious case of high potential type 2 C112D/M121E Pseudomonas aeruginosa azurin. Journal of the American Chemical Society. 132: 14590-5. PMID 20879734 DOI: 10.1021/Ja105731X  0.611
2010 Lancaster KM, Gerken JB, Durrell AC, Palmer JH, Gray HB. Electronic structures, photophysical properties, and electrochemistry of ruthenium(II)(bpy)2 pyridylimidazole complexes Coordination Chemistry Reviews. 254: 1803-1811. DOI: 10.1016/J.Ccr.2010.04.005  0.632
2009 Lancaster KM, DeBeer George S, Yokoyama K, Richards JH, Gray HB. Type-zero copper proteins. Nature Chemistry. 1: 711-5. PMID 20305734 DOI: 10.1038/Nchem.412  0.471
2009 Palmer JH, Mahammed A, Lancaster KM, Gross Z, Gray HB. Structures and reactivity patterns of group 9 metallocorroles. Inorganic Chemistry. 48: 9308-15. PMID 19736908 DOI: 10.1021/Ic901164R  0.608
2009 Lancaster KM, Yokoyama K, Richards JH, Winkler JR, Gray HB. High-potential C112D/M121X (X = M, E, H, L) Pseudomonas aeruginosa azurins. Inorganic Chemistry. 48: 1278-80. PMID 19113863 DOI: 10.1021/Ic802322E  0.574
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