Andrew S. Weller - Publications

Affiliations: 
2020- Chemistry University of York (UK) 

197 high-probability publications. We are testing a new system for linking publications to authors. You can help! If you notice any inaccuracies, please sign in and mark papers as correct or incorrect matches. If you identify any major omissions or other inaccuracies in the publication list, please let us know.

Year Citation  Score
2023 Townrow OPE, Weller AS, Goicoechea JM. Controlled cluster expansion at a Zintl cluster surface. Angewandte Chemie (International Ed. in English). e202316120. PMID 38010628 DOI: 10.1002/anie.202316120  0.508
2023 Gyton MR, Royle CG, Beaumont SK, Duckett SB, Weller AS. Mechanistic Insights into Molecular Crystalline Organometallic Heterogeneous Catalysis through Parahydrogen-Based Nuclear Magnetic Resonance Studies. Journal of the American Chemical Society. 145: 2619-2629. PMID 36688560 DOI: 10.1021/jacs.2c12642  0.374
2022 Royle CG, Sotorrios L, Gyton MR, Brodie CN, Burnage AL, Furfari SK, Marini A, Warren MR, Macgregor SA, Weller AS. Single-Crystal to Single-Crystal Addition of H to [Ir(Pr-PONOP)(propene)][BAr ] and Comparison Between Solid-State and Solution Reactivity. Organometallics. 41: 3270-3280. PMID 36466791 DOI: 10.1021/acs.organomet.2c00274  0.827
2022 Brodie CN, Sotorrios L, Boyd TM, Macgregor SA, Weller AS. Dehydropolymerization of HB·NMeH Mediated by Cationic Iridium(III) Precatalysts Bearing κ- Pr-PN P Pincer Ligands ( = H, Me): An Unexpected Inner-Sphere Mechanism. Acs Catalysis. 12: 13050-13064. PMID 36313521 DOI: 10.1021/acscatal.2c03778  0.424
2022 Townrow OPE, Duckett SB, Weller AS, Goicoechea JM. Zintl cluster supported low coordinate Rh(i) centers for catalytic H/D exchange between H and D. Chemical Science. 13: 7626-7633. PMID 35872810 DOI: 10.1039/d2sc02552c  0.643
2022 Doyle LR, Galpin MR, Furfari SK, Tegner BE, Martínez-Martínez AJ, Whitwood AC, Hicks SA, Lloyd-Jones GC, Macgregor SA, Weller AS. Inverse Isotope Effects in Single-Crystal to Single-Crystal Reactivity and the Isolation of a Rhodium Cyclooctane σ-Alkane Complex. Organometallics. 41: 284-292. PMID 35273423 DOI: 10.1021/acs.organomet.1c00639  0.82
2021 Perutz RN, Sabo-Etienne S, Weller AS. Metathesis by partner interchange in σ-bond ligands: expanding applications of the σ-CAM mechanism. Angewandte Chemie (International Ed. in English). PMID 34694734 DOI: 10.1002/anie.202111462  0.303
2021 Race JJ, Burnage AL, Boyd TM, Heyam A, Martínez-Martínez AJ, Macgregor SA, Weller AS. -aryl substituted DPEphos ligands: rhodium complexes featuring C-H anagostic interactions and B-H agostic bonds. Chemical Science. 12: 8832-8843. PMID 34257884 DOI: 10.1039/d1sc01430g  0.43
2021 Townrow OPE, Weller AS, Goicoechea JM. Cluster expansion and vertex substitution pathways in nickel germanide Zintl clusters. Chemical Communications (Cambridge, England). PMID 34180473 DOI: 10.1039/d1cc02912f  0.528
2021 Bukvic AJ, Burnage AL, Tizzard GJ, Martínez-Martínez AJ, McKay AI, Rees NH, Tegner BE, Krämer T, Fish H, Warren MR, Coles SJ, Macgregor SA, Weller AS. A Series of Crystallographically Characterized Linear and Branched σ-Alkane Complexes of Rhodium: From Propane to 3-Methylpentane. Journal of the American Chemical Society. PMID 33769815 DOI: 10.1021/jacs.1c00738  0.377
2021 Johnson A, Royle CG, Brodie CN, Martínez-Martínez AJ, Duckett SB, Weller AS. η-Alkene Complexes of [Rh(PONOP-Pr)(L)] Cations (L = COD, NBD, Ethene). Intramolecular Alkene-Assisted Hydrogenation and Dihydrogen Complex [Rh(PONOP-Pr)(η-H)]. Inorganic Chemistry. PMID 33570930 DOI: 10.1021/acs.inorgchem.0c03687  0.431
2020 Furfari S, Tegner B, Burnage A, Doyle L, Bukvic A, Macgregor S, Weller AS. Selectivity of Rh···H-C Binding in a σ-Alkane Complex Controlled by the Secondary Microenvironment in the Solid-State. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 33112000 DOI: 10.1002/chem.202004585  0.827
2020 Townrow OPE, Chung C, Macgregor SA, Weller AS, Goicoechea JM. A Neutral Heteroatomic Zintl Cluster for the Catalytic Hydrogenation of Cyclic Alkenes. Journal of the American Chemical Society. PMID 33052653 DOI: 10.1021/jacs.0c09742  0.548
2020 Martínez-Martínez AJ, Royle CG, Furfari SK, Suriye K, Weller AS. Solid-State Molecular Organometallic Catalysis in Gas/Solid Flow (Flow-SMOM) as Demonstrated by Efficient Room Temperature and Pressure 1-Butene Isomerization. Acs Catalysis. 10: 1984-1992. PMID 32296595 DOI: 10.1021/Acscatal.9B03727  0.82
2020 Azpeitia S, Martínez-Martínez AJ, Garralda MA, Weller AS, Huertos MA. Si-C(sp) bond activation through oxidative addition at a Rh(i) centre. Dalton Transactions (Cambridge, England : 2003). PMID 32250374 DOI: 10.1039/D0Dt00725K  0.343
2020 Bukvic AJ, Crivoi DG, Garwood HG, McKay AI, Chen TTD, Martínez-Martínez AJ, Weller AS. Tolerant to air σ-alkane complexes by surface modification of single crystalline solid-state molecular organometallics using vapour-phase cationic polymerisation: SMOM@polymer. Chemical Communications (Cambridge, England). PMID 32191244 DOI: 10.1039/D0Cc01140A  0.321
2020 Boyd TM, Tegner B, Tizzard G, Martinez-Martinez A, Neale S, Hayward M, Coles S, Macgregor S, Weller AS. A Structurally Characterized Cobalt(I) σ-Alkane Complex. Angewandte Chemie (International Ed. in English). PMID 31943626 DOI: 10.1002/Anie.201914940  0.48
2020 Ryan DE, Andrea K, Race J, Boyd TM, Lloyd-Jones GC, Weller AS. Amine–Borane Dehydropolymerization Using Rh-BasedPrecatalysts: Resting State, Chain Control, and Efficient PolymerSynthesis Acs Catalysis. 10: 7443-7448. DOI: 10.1021/Acscatal.0C02211  0.407
2020 Boyd TM, Tegner BE, Tizzard GJ, Martínez‐Martínez AJ, Neale SE, Hayward MA, Coles SJ, Macgregor SA, Weller AS. Back Cover: A Structurally Characterized Cobalt(I) σ‐Alkane Complex (Angew. Chem. Int. Ed. 15/2020) Angewandte Chemie International Edition. 59: 6290-6290. DOI: 10.1002/Anie.202002162  0.36
2020 Boyd TM, Tegner BE, Tizzard GJ, Martínez‐Martínez AJ, Neale SE, Hayward MA, Coles SJ, Macgregor SA, Weller AS. Rücktitelbild: A Structurally Characterized Cobalt(I) σ‐Alkane Complex (Angew. Chem. 15/2020) Angewandte Chemie. 132: 6349-6349. DOI: 10.1002/Ange.202002162  0.365
2019 Boyd TM, Andrea KA, Baston K, Johnson A, Ryan DE, Weller AS. A simple cobalt-based catalyst system for the controlled dehydropolymerisation of HB·NMeH on the gram-scale. Chemical Communications (Cambridge, England). PMID 31829388 DOI: 10.1039/C9Cc08864D  0.316
2019 McKay A, Barwick-Silk J, Savage M, Willis M, Weller AS. Synthesis of highly fluorinated arene complexes of [Rh(chelating phosphine)]+ cations, and their use in synthesis and catalysis. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 31749160 DOI: 10.1002/Chem.201904668  0.49
2019 Martinez-Martinez A, Rees NH, Weller AS. Reversible Encapsulation of Xenon and CH2Cl2 in a Solid-State Molecular OrganoMetallic Framework (Guest@SMOM). Angewandte Chemie (International Ed. in English). PMID 31539184 DOI: 10.1002/Anie.201910539  0.386
2019 Spearing-Ewyn EAK, Beattie NA, Colebatch AL, Martinez-Martinez AJ, Docker A, Boyd TM, Baillie G, Reed R, Macgregor SA, Weller AS. The role of neutral Rh(PONOP)H, free NMeH, boronium and ammonium salts in the dehydrocoupling of dimethylamine-borane using the cationic pincer [Rh(PONOP)(η-H)] catalyst. Dalton Transactions (Cambridge, England : 2003). PMID 31538996 DOI: 10.1039/C9Dt03358K  0.814
2019 McKay AI, Bukvic AJ, Tegner BE, Burnage AL, Martinez-Martinez AJ, Rees NH, Macgregor SA, Weller AS. Room Temperature Acceptorless Alkane Dehydrogenation from Molecular σ-Alkane Complexes. Journal of the American Chemical Society. PMID 31246012 DOI: 10.1021/Jacs.9B05577  0.523
2019 Johnson A, Martínez-Martínez AJ, Macgregor SA, Weller AS. A d Ag(i) amine-borane σ-complex and comparison with a d Rh(i) analogue: structures on the η to η:η continuum. Dalton Transactions (Cambridge, England : 2003). PMID 31012457 DOI: 10.1039/C9Dt00971J  0.376
2019 Adams GM, Ryan DE, Beattie NA, McKay AI, Lloyd-Jones GC, Weller AS. Dehydropolymerization of HB·NMeH Using a [Rh(DPEphos)] Catalyst: The Promoting Effect of NMeH. Acs Catalysis. 9: 3657-3666. PMID 30984472 DOI: 10.1021/Acscatal.9B00081  0.444
2019 Martínez-Martínez AJ, Weller AS. Solvent-free anhydrous Li, Na and K salts of [B(3,5-(CF)CH)], [BAr]. Improved synthesis and solid-state structures. Dalton Transactions (Cambridge, England : 2003). PMID 30762068 DOI: 10.1039/C9Dt00235A  0.333
2019 Dietz M, Johnson A, Martínez-Martínez A, Weller AS. The [Rh(Xantphos)]+ catalyzed hydroboration of diphenylacetylene using trimethylamine-borane Inorganica Chimica Acta. 491: 9-13. DOI: 10.1016/J.Ica.2019.03.032  0.434
2018 Martínez-Martínez AJ, Tegner BE, McKay AI, Bukvic AJ, Rees NH, Tizzard GJ, Coles SJ, Warren MR, Macgregor SA, Weller AS. Modulation of σ-Alkane Interactions in [Rh(L)(alkane)] Solid-State Molecular Organometallic (SMOM) Systems by Variation of the Chelating Phosphine and Alkane: Access to η,η-σ-Alkane Rh(I), η-σ-Alkane Rh(III) Complexes, and Alkane Encapsulation. Journal of the American Chemical Society. PMID 30351014 DOI: 10.1021/Jacs.8B09364  0.414
2018 Colebatch AL, Weller AS. Amine-borane Dehydropolymerization: Challenges and Opportunities. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 30338876 DOI: 10.1002/Chem.201804592  0.748
2018 Barwick-Silk J, Hardy S, Willis MC, Weller AS. Rh(DPEPhos)-Catalyzed Alkyne Hydroacylation using β-Carbonyl Substituted Aldehydes. Mechanistic Insight Leads to Low Catalyst Loadings that Enables Selective Catalysis on Gram-Scale. Journal of the American Chemical Society. PMID 29763563 DOI: 10.1021/Jacs.8B04086  0.395
2018 Manners I, Turner J, Chilton N, Kumar A, Whittell G, Colebatch A, Sparkes H, Weller A. Iron Precatalysts with Bulky Tri(t-butyl)cyclopentadienyl Ligands for the Dehydrocoupling of Dimethylamine-Borane. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 29573487 DOI: 10.1002/Chem.201705316  0.793
2018 Colebatch AL, Hawkey Gilder BW, Whitell GR, Oldroyd NL, Manners I, Weller AS. A General, Rhodium-Catalyzed, Synthesis of Deuterated Boranes and N-Methyl Polyaminoboranes. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 29504649 DOI: 10.1002/Chem.201800737  0.775
2018 Rosseinsky MJ, Grigoropoulos A, McKay AI, Katsoulidis AP, Davies RP, Haynes A, Brammer L, Xiao J, Weller AS. Encapsulation of Crabtree's catalyst in sulfonated MIL-101(Cr): enhancement of stability and selectivity between competing reaction pathways by the MOF chemical microenvironment. Angewandte Chemie (International Ed. in English). PMID 29377466 DOI: 10.1002/Anie.201710091  0.349
2018 McKay AI, Martínez-Martínez AJ, Griffiths HJ, Rees NH, Waters JB, Weller AS, Krämer T, Macgregor SA. Controlling Structure and Reactivity in Cationic Solid-State Molecular Organometallic Systems Using Anion Templating Organometallics. 37: 3524-3532. DOI: 10.1021/Acs.Organomet.8B00215  0.456
2018 Adams GM, Weller AS. POP-type ligands: Variable coordination and hemilabile behaviour Coordination Chemistry Reviews. 355: 150-172. DOI: 10.1016/J.Ccr.2017.08.004  0.362
2017 Adams GM, Colebatch AL, Skornia JT, McKay AI, Johnson HC, Lloyd-Jones GC, Macgregor SA, Beattie NA, Weller AS. The Dehydropolymerization of H3B•NMeH2 to form Polyaminoboranes using [Rh(Xantphos-alkyl)] Catalysts. Journal of the American Chemical Society. PMID 29286647 DOI: 10.1021/Jacs.7B11975  0.776
2017 Chadwick FM, McKay AI, Martinez-Martinez AJ, Rees NH, Krämer T, Macgregor SA, Weller AS. Solid-state molecular organometallic chemistry. Single-crystal to single-crystal reactivity and catalysis with light hydrocarbon substrates. Chemical Science. 8: 6014-6029. PMID 28989631 DOI: 10.1039/C7Sc01491K  0.787
2017 Coxon TJ, Fernández M, Barwick-Silk J, McKay AI, Britton LE, Weller AS, Willis MC. Exploiting Carbonyl Groups to Control Intermolecular Rhodium-Catalyzed Alkene and Alkyne Hydroacylation. Journal of the American Chemical Society. PMID 28715214 DOI: 10.1021/Jacs.7B05713  0.357
2017 Wang X, Hooper TN, Kumar A, Priest IK, Sheng Y, Samuels TOM, Wang S, Robertson AW, Pacios M, Bhaskaran H, Weller AS, Warner JH. Oligomeric aminoborane precursors for the chemical vapour deposition growth of few-layer hexagonal boron nitride Crystengcomm. 19: 285-294. DOI: 10.1039/C6Ce02006B  0.313
2017 Colebatch AL, McKay AI, Beattie NA, Macgregor SA, Weller AS. Fluoroarene Complexes with Small Bite Angle Bisphosphines: Routes to Amine-Borane and Aminoborylene Complexes European Journal of Inorganic Chemistry. 2017: 4533-4540. DOI: 10.1002/Ejic.201700600  0.397
2016 Hooper TN, Weller AS, Beattie NA, Macgregor SA. Dehydrocoupling of phosphine-boranes using the [RhCp*Me(PMe)(CHCl)][BAr] precatalyst: stoichiometric and catalytic studies. Chemical Science. 7: 2414-2426. PMID 29997783 DOI: 10.1039/C5Sc04150C  0.437
2016 Grigoropoulos A, Whitehead GFS, Perret N, Katsoulidis AP, Chadwick FM, Davies RP, Haynes A, Brammer L, Weller AS, Xiao J, Rosseinsky MJ. Encapsulation of an organometallic cationic catalyst by direct exchange into an anionic MOF. Chemical Science. 7: 2037-2050. PMID 29899929 DOI: 10.1039/C5Sc03494A  0.764
2016 Chadwick FM, Kraemer T, Gutmann T, Rees NH, Thompson AL, Edwards AJ, Buntkowsky G, Macgregor SA, Weller AS. Selective C-H Activation at a Molecular Rhodium Sigma-Alkane Complex by Solid/Gas Single-Crystal to Single-Crystal H/D Exchange. Journal of the American Chemical Society. PMID 27631345 DOI: 10.1021/Jacs.6B07968  0.808
2016 Kumar A, Beattie NA, Pike SD, Macgregor SA, Weller AS. The Simplest Amino-borane H2 B=NH2 Trapped on a Rhodium Dimer: Pre-Catalysts for Amine-Borane Dehydropolymerization. Angewandte Chemie (International Ed. in English). PMID 27100775 DOI: 10.1002/Anie.201600898  0.801
2016 Drover MW, Bowes EG, Schafer LL, Love JA, Weller AS. Phosphoramidate-Supported Cp*Ir(III) Aminoborane H2B=NR2 Complexes: Synthesis, Structure, and Solution Dynamics. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 26946099 DOI: 10.1002/Chem.201600951  0.81
2016 Kumar A, Priest IK, Hooper TN, Weller AS. Variable coordination modes and catalytic dehydrogenation of B-phenyl amine-boranes. Dalton Transactions (Cambridge, England : 2003). PMID 26936754 DOI: 10.1039/C6Dt00197A  0.568
2016 Chadwick FM, Rees NH, Weller AS, Krämer T, Iannuzzi M, Macgregor SA. A Rhodium-Pentane Sigma-Alkane Complex: Characterization in the Solid State by Experimental and Computational Techniques. Angewandte Chemie (International Ed. in English). PMID 26880330 DOI: 10.1002/Anie.201511269  0.79
2016 Grigoropoulos A, Whitehead GFS, Perret N, Katsoulidis AP, Chadwick FM, Davies RP, Haynes A, Brammer L, Weller AS, Xiao J, Rosseinsky MJ. Encapsulation of an organometallic cationic catalyst by direct exchange into an anionic MOF Chemical Science. 7: 2037-2050. DOI: 10.1039/c5sc03494a  0.737
2016 Theron R, Wu Y, Yunker LPE, Hesketh AV, Pernik I, Weller AS, McIndoe JS. Simultaneous Orthogonal Methods for the Real-Time Analysis of Catalytic Reactions Acs Catalysis. 6: 6911-6917. DOI: 10.1021/Acscatal.6B01489  0.35
2016 McKay AI, Krämer T, Rees NH, Thompson AL, Christensen KE, Macgregor SA, Weller AS. Formation of a σ-alkane Complex and a Molecular Rearrangement in the Solid-State: [Rh(Cyp2PCH2CH2PCyp2)(η2:η2-C7H12)][BArF4] Organometallics. 36: 22-25. DOI: 10.1021/Acs.Organomet.6B00645  0.452
2016 Weller AS, Chadwick FM, McKay AI. Chapter Five - Transition Metal Alkane-Sigma Complexes: Synthesis, Characterization, and Reactivity Advances in Organometallic Chemistry. 66: 223-276. DOI: 10.1016/Bs.Adomc.2016.09.001  0.411
2015 Kumar A, Ishibashi JS, Hooper TN, Mikulas TC, Dixon DA, Liu SY, Weller AS. The Synthesis, Characterization and Dehydrogenation of Sigma-Complexes of BN-Cyclohexanes. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 26602704 DOI: 10.1002/Chem.201502986  0.586
2015 Johnson HC, Weller AS. PC-Activated Bimetallic Rhodium Xantphos Complexes: Formation and Catalytic Dehydrocoupling of Amine-Boranes. Angewandte Chemie (International Ed. in English). 54: 10173-7. PMID 26140498 DOI: 10.1002/Anie.201504073  0.478
2015 Prades A, Fernández M, Pike SD, Willis MC, Weller AS. Well-Defined and Robust Rhodium Catalysts for the Hydroacylation of Terminal and Internal Alkenes. Angewandte Chemie (International Ed. in English). PMID 26069052 DOI: 10.1002/Anie.201503208  0.783
2015 Adams GM, Chadwick FM, Pike SD, Weller AS. A CH2Cl2 complex of a [Rh(pincer)](+) cation. Dalton Transactions (Cambridge, England : 2003). 44: 6340-2. PMID 25763935 DOI: 10.1039/C5Dt00481K  0.815
2015 Pike SD, Weller AS. Organometallic synthesis, reactivity and catalysis in the solid state using well-defined single-site species. Philosophical Transactions. Series a, Mathematical, Physical, and Engineering Sciences. 373. PMID 25666064 DOI: 10.1098/Rsta.2014.0187  0.758
2015 Pike SD, Chadwick FM, Rees NH, Scott MP, Weller AS, Krämer T, Macgregor SA. Solid-state synthesis and characterization of σ-alkane complexes, [Rh(L2)(η(2),η(2)-C7H12)][BAr(F)4] (L2 = bidentate chelating phosphine). Journal of the American Chemical Society. 137: 820-33. PMID 25506741 DOI: 10.1021/Ja510437P  0.822
2015 Pike SD, Krämer T, Rees NH, Macgregor SA, Weller AS. Stoichiometric and catalytic solid-gas reactivity of rhodium bis-phosphine complexes Organometallics. 34: 1487-1497. DOI: 10.1021/Om5013133  0.485
2015 Ren P, Pike SD, Pernik I, Weller AS, Willis MC. Rh-POP pincer Xantphos complexes for C-S and C-H activation. Implications for carbothiolation catalysis Organometallics. 34: 711-723. DOI: 10.1021/Om500984Y  0.432
2015 Drover MW, Johnson HC, Schafer LL, Love JA, Weller AS. Reactivity of an Unsaturated Iridium(III) Phosphoramidate Complex, [Cp∗Ir{κ2- N,O }][BArF4] Organometallics. 34: 3849-3856. DOI: 10.1021/Acs.Organomet.5B00397  0.797
2015 Luo J, Theron R, Sewell LJ, Hooper TN, Weller AS, Oliver AG, McIndoe JS. Rhodium-Catalyzed Selective Partial Hydrogenation of Alkynes Organometallics. 34: 3021-3028. DOI: 10.1021/Acs.Organomet.5B00322  0.403
2015 Ren P, Pike SD, Pernik I, Weller AS, Willis MC. Correction to Rh–POP Pincer Xantphos Complexes for C–S and C–H Activation. Implications for Carbothiolation Catalysis Organometallics. 34: 1137-1137. DOI: 10.1021/Acs.Organomet.5B00152  0.356
2015 Chadwick FM, Olliff N, Weller AS. A convenient route to a norbornadiene adduct of iridium with chelating phosphines, [Ir(R2PCH2CH2PR2)(NBD)][BAr4F] and a comparison of reactivity with H2 in solution and the solid-state Journal of Organometallic Chemistry. DOI: 10.1016/J.Jorganchem.2015.12.001  0.787
2015 Pike SD, Pernik I, Theron R, Mcindoe JS, Weller AS. Relative binding affinities of fluorobenzene ligands in cationic rhodium bisphosphine η6-fluorobenzene complexes probed using collision-induced dissociation Journal of Organometallic Chemistry. 784: 75-83. DOI: 10.1016/J.Jorganchem.2014.08.012  0.354
2015 Weller A. Organometallics and Catalysis. An Introduction. By Manfred Bochmann. Angewandte Chemie International Edition. 54: 7747-7747. DOI: 10.1002/Anie.201504479  0.328
2014 Johnson HC, Leitao EM, Whittell GR, Manners I, Lloyd-Jones GC, Weller AS. Mechanistic studies of the dehydrocoupling and dehydropolymerization of amine-boranes using a [Rh(Xantphos)]⁺ catalyst. Journal of the American Chemical Society. 136: 9078-93. PMID 24844130 DOI: 10.1021/Ja503335G  0.374
2014 Hooper TN, Huertos MA, Jurca T, Pike SD, Weller AS, Manners I. Effect of the phosphine steric and electronic profile on the Rh-promoted dehydrocoupling of phosphine-boranes. Inorganic Chemistry. 53: 3716-29. PMID 24617924 DOI: 10.1021/Ic500032F  0.786
2014 Algarra AG, Sewell LJ, Johnson HC, Macgregor SA, Weller AS. A combined experimental and computational study of fluxional processes in sigma amine-borane complexes of rhodium and iridium. Dalton Transactions (Cambridge, England : 2003). 43: 11118-28. PMID 24296549 DOI: 10.1039/C3Dt52771A  0.44
2014 Etienne M, Weller AS. Intramolecular C-C agostic complexes: C-C sigma interactions by another name. Chemical Society Reviews. 43: 242-59. PMID 24019058 DOI: 10.1039/C3Cs60295H  0.355
2014 Kumar A, Johnson HC, Hooper TN, Weller AS, Algarra AG, Macgregor SA. Multiple metal-bound oligomers from Ir-catalysed dehydropolymerisation of H3B·NH3 as probed by experiment and computation Chemical Science. 5: 2546-2553. DOI: 10.1039/C4Sc00735B  0.407
2014 Johnson HC, Torry-Harris R, Ortega L, Theron R, McIndoe JS, Weller AS. Exploring the mechanism of the hydroboration of alkenes by amine-boranes catalysed by [Rh(xantphos)]+ Catalysis Science and Technology. 4: 3486-3494. DOI: 10.1039/C4Cy00597J  0.346
2013 Pike SD, Weller AS. C-Cl activation of the weakly coordinating anion [B(3,5-Cl2C6H3)4]- at a Rh(I) centre in solution and the solid-state. Dalton Transactions (Cambridge, England : 2003). 42: 12832-5. PMID 23884210 DOI: 10.1039/C3Dt51617B  0.78
2013 Johnson HC, McMullin CL, Pike SD, Macgregor SA, Weller AS. Dehydrogenative boron homocoupling of an amine-borane. Angewandte Chemie (International Ed. in English). 52: 9776-80. PMID 23873710 DOI: 10.1002/Anie.201304382  0.743
2013 Shuttleworth TA, Huertos MA, Pernik I, Young RD, Weller AS. Bis(phosphine)boronium salts. Synthesis, structures and coordination chemistry. Dalton Transactions (Cambridge, England : 2003). 42: 12917-25. PMID 23715206 DOI: 10.1039/C3Dt50817J  0.756
2013 Sewell LJ, Huertos MA, Dickinson ME, Weller AS, Lloyd-Jones GC. Dehydrocoupling of dimethylamine borane catalyzed by Rh(PCy3)2H2Cl. Inorganic Chemistry. 52: 4509-16. PMID 23544802 DOI: 10.1021/Ic302804D  0.514
2013 Hooper JF, Young RD, Weller AS, Willis MC. Traceless chelation-controlled rhodium-catalyzed intermolecular alkene and alkyne hydroacylation. Chemistry (Weinheim An Der Bergstrasse, Germany). 19: 3125-30. PMID 23325542 DOI: 10.1002/Chem.201204056  0.698
2013 Huertos MA, Weller AS. Revealing the P-B coupling event in the rhodium catalysed dehydrocoupling of phosphine-boranes H3B·PR2H (R = tBu, Ph) Chemical Science. 4: 1881-1888. DOI: 10.1039/C3Sc50122A  0.344
2013 Hooper JF, Young RD, Pernik I, Weller AS, Willis MC. Carbon-carbon bond construction using boronic acids and aryl methyl sulfides: Orthogonal reactivity in Suzuki-type couplings Chemical Science. 4: 1568-1572. DOI: 10.1039/C3Sc00052D  0.713
2013 Chaplin AB, Weller AS. The influence of phosphine cone angle on the synthesis and structures of [Rh(PR3)(Binor-S)]+ complexes that show C-C sigma interactions Journal of Organometallic Chemistry. 730: 90-94. DOI: 10.1016/J.Jorganchem.2012.09.013  0.445
2013 Hooper JF, Young RD, Pernik I, Weller AS, Willis MC. ChemInform Abstract: Carbon-Carbon Bond Construction Using Boronic Acids and Aryl Methyl Sulfides: Orthogonal Reactivity in Suzuki-Type Couplings. Cheminform. 44: no-no. DOI: 10.1002/CHIN.201334062  0.636
2012 Pike SD, Thompson AL, Algarra AG, Apperley DC, Macgregor SA, Weller AS. Synthesis and characterization of a rhodium(I) σ-alkane complex in the solid state. Science (New York, N.Y.). 337: 1648-51. PMID 22923436 DOI: 10.1126/Science.1225028  0.796
2012 Huertos MA, Weller AS. Intermediates in the Rh-catalysed dehydrocoupling of phosphine-borane. Chemical Communications (Cambridge, England). 48: 7185-7. PMID 22662328 DOI: 10.1039/C2Cc32696E  0.398
2012 Chaplin AB, Hooper JF, Weller AS, Willis MC. Intermolecular hydroacylation: high activity rhodium catalysts containing small-bite-angle diphosphine ligands. Journal of the American Chemical Society. 134: 4885-97. PMID 22324763 DOI: 10.1021/Ja211649A  0.75
2012 Hooper JF, Chaplin AB, González-Rodríguez C, Thompson AL, Weller AS, Willis MC. Aryl methyl sulfides as substrates for rhodium-catalyzed alkyne carbothiolation: arene functionalization with activating group recycling. Journal of the American Chemical Society. 134: 2906-9. PMID 22296656 DOI: 10.1021/Ja2108992  0.651
2012 Sewell LJ, Lloyd-Jones GC, Weller AS. Development of a generic mechanism for the dehydrocoupling of amine-boranes: a stoichiometric, catalytic, and kinetic study of H3B·NMe2H using the [Rh(PCy3)2]+ fragment. Journal of the American Chemical Society. 134: 3598-610. PMID 22263695 DOI: 10.1021/Ja2112965  0.429
2012 Pawley RJ, Huertos MA, Lloyd-Jones GC, Weller AS, Willis MC. Intermolecular alkyne hydroacylation. mechanistic insight from the isolation of the vinyl intermediate that precedes reductive elimination Organometallics. 31: 5650-5659. DOI: 10.1021/Om300647N  0.335
2012 Dallanegra R, Chaplin AB, Weller AS. Rhodium cyclopentyl phosphine complexes of wide-bite-angle ligands DPEphos and xantphos Organometallics. 31: 2720-2728. DOI: 10.1021/Om201034M  0.45
2012 Johnson HC, Robertson APM, Chaplin AB, Sewell LJ, Thompson AL, Haddow MF, Manners I, Weller AS. Correction to Catching the First Oligomerization Event in the Catalytic Formation of Polyaminoboranes: H3B·NMeHBH2·NMeH2 Bound to Iridium Journal of the American Chemical Society. 134: 3932-3932. DOI: 10.1021/Ja211731P  0.321
2012 Pernik I, Hooper JF, Chaplin AB, Weller AS, Willis MC. Exploring small bite-angle ligands for the rhodium-catalyzed intermolecular hydroacylation of βs-substituted aldehydes with 1-octene and 1-octyne Acs Catalysis. 2: 2779-2786. DOI: 10.1021/Cs300541M  0.415
2012 Johnson HC, Weller AS. A tert-butyl-substituted amino-borane bound to an iridium fragment: A latent source of free H2BNtBuH Journal of Organometallic Chemistry. 721: 17-22. DOI: 10.1016/J.Jorganchem.2012.07.018  0.423
2011 Chaplin AB, Weller AS. A rhodium(III) complex of the linear diborazine H3B·NMe2BH2·NMe2H: an intermediate in the dehydrocoupling of H3B·NMe2H. Acta Crystallographica. Section C, Crystal Structure Communications. 67: m355-8. PMID 22051952 DOI: 10.1107/S0108270111043447  0.741
2011 Sparkes HA, Krämer T, Brayshaw SK, Green JC, Weller AS, Howard JA. Experimental charge density study into C-C σ-interactions in a Binor-S rhodium complex. Dalton Transactions (Cambridge, England : 2003). 40: 10708-18. PMID 21912799 DOI: 10.1039/C1Dt10303B  0.333
2011 Weller A. Ligand design: the two faces of carboranes. Nature Chemistry. 3: 577-8. PMID 21778973 DOI: 10.1038/Nchem.1102  0.323
2011 Chaplin AB, Green JC, Weller AS. C-C activation in the solid state in an organometallic σ-complex. Journal of the American Chemical Society. 133: 13162-8. PMID 21736363 DOI: 10.1021/Ja2047599  0.706
2011 Sewell LJ, Chaplin AB, Weller AS. Hydroboration of an alkene by amine-boranes catalysed by a [Rh(PR3)2]+ fragment. Mechanistic insight and tandem hydroboration/dehydrogenation. Dalton Transactions (Cambridge, England : 2003). 40: 7499-501. PMID 21713289 DOI: 10.1039/C1Dt10819K  0.707
2011 Johnson HC, Robertson AP, Chaplin AB, Sewell LJ, Thompson AL, Haddow MF, Manners I, Weller AS. Catching the first oligomerization event in the catalytic formation of polyaminoboranes: H3B·NMeHBH2·NMeH2 bound to iridium. Journal of the American Chemical Society. 133: 11076-9. PMID 21699193 DOI: 10.1021/Ja2040738  0.716
2011 Dallanegra R, Pilgrim BS, Chaplin AB, Donohoe TJ, Weller AS. Dehydrogenation of cyclic thioethers bound to a [Rh(diphosphine)]+ fragment. Dalton Transactions (Cambridge, England : 2003). 40: 6626-8. PMID 21611674 DOI: 10.1039/C1Dt10503E  0.698
2011 González-Rodríguez C, Pawley RJ, Chaplin AB, Thompson AL, Weller AS, Willis MC. Rhodium-catalyzed branched-selective alkyne hydroacylation: a ligand-controlled regioselectivity switch. Angewandte Chemie (International Ed. in English). 50: 5134-8. PMID 21506226 DOI: 10.1002/Anie.201100956  0.673
2011 Stevens CJ, Dallanegra R, Chaplin AB, Weller AS, Macgregor SA, Ward B, McKay D, Alcaraz G, Sabo-Etienne S. [Ir(PCy3)2(H)2(H2B-NMe2)]+ as a latent source of aminoborane: probing the role of metal in the dehydrocoupling of H3B⋅NMe2H and retrodimerisation of [H2BNMe2]2. Chemistry (Weinheim An Der Bergstrasse, Germany). 17: 3011-20. PMID 21322070 DOI: 10.1002/Chem.201002517  0.734
2011 Dallanegra R, Robertson AP, Chaplin AB, Manners I, Weller AS. Tuning the [L2Rh···H3B·NR3]+ interaction using phosphine bite angle. Demonstration by the catalytic formation of polyaminoboranes. Chemical Communications (Cambridge, England). 47: 3763-5. PMID 21293798 DOI: 10.1039/C0Cc05460G  0.707
2011 Chaplin AB, Weller AS. [Rh{NC5H3-2,6-(CH2PtBu2)2}(PCy3)][BArF4]: A Latent Low-Coordinate Rhodium(I) PNP Pincer Compound Organometallics. 30: 4466-4469. DOI: 10.1021/Om2004964  0.444
2011 Pontiggia AJ, Chaplin AB, Weller AS. Cationic iridium complexes of the Xantphos ligand. Flexible coordination modes and the isolation of the hydride insertion product with an alkene Journal of Organometallic Chemistry. 696: 2870-2876. DOI: 10.1016/J.Jorganchem.2011.01.036  0.51
2011 Pike SD, Pawley RJ, Chaplin AB, Thompson AL, Hooper JA, Willis MC, Weller AS. Exploring (Ph2PCH2CH2)2E ligand space (E = O, S, PPh) in RhI alkene complexes as potential hydroacylation catalysts European Journal of Inorganic Chemistry. 5558-5565. DOI: 10.1002/Ejic.201100958  0.379
2011 Woolf A, Alibadi MAM, Chaplin AB, McGrady JE, Weller AS. {Rh(PiBu3)2}+ fragments ligated to arenes: From benzene to polyaromatic hydrocarbons, part II - Computational analysis of pathways for haptotropic migration European Journal of Inorganic Chemistry. 1626-1634. DOI: 10.1002/Ejic.201001264  0.367
2011 Woolf A, Chaplin AB, McGrady JE, Alibadi MAM, Rees N, Draper S, Murphy F, Weller AS. {Rh(PiBu3)2}+ fragments ligated to arenes: From benzene to polyaromatic hydrocarbons, part I - An experimental approach European Journal of Inorganic Chemistry. 1614-1625. DOI: 10.1002/Ejic.201001263  0.373
2010 Sparkes HA, Chaplin AB, Weller AS, Howard JA. Bond catastrophes in rhodium complexes: experimental charge-density studies of [Rh(C7H8)(P(t)Bu3)Cl] and [Rh(C7H8)(PCy3)Cl]. Acta Crystallographica. Section B, Structural Science. 66: 503-14. PMID 20841918 DOI: 10.1107/S0108768110031496  0.699
2010 Sewell LJ, Chaplin AB, Abdalla JA, Weller AS. Reversible C-H activation of a P(t)Bu(i)Bu2 ligand to reveal a masked 12 electron [Rh(PR3)2]+ cation. Dalton Transactions (Cambridge, England : 2003). 39: 7437-9. PMID 20623070 DOI: 10.1039/C0Dt00449A  0.717
2010 Townsend NS, Chaplin AB, Abu Naser M, Thompson AL, Rees NH, Macgregor SA, Weller AS. Reactivity of the latent 12-electron fragment [Rh(PiBu3)2]+ with aryl bromides: aryl-Br and phosphine ligand C-H activation. Chemistry (Weinheim An Der Bergstrasse, Germany). 16: 8376-89. PMID 20572181 DOI: 10.1002/Chem.201000554  0.758
2010 Hiney RM, Chaplin AB, Harmer J, Green JC, Weller AS. Using EPR to follow reversible dihydrogen addition to paramagnetic clusters of high hydride count: [Rh(6)(PCy(3))(6)H(12)](+) and [Rh(6)(PCy(3))(6)H(14)](+). Dalton Transactions (Cambridge, England : 2003). 39: 1726-33. PMID 20449414 DOI: 10.1039/B919209C  0.716
2010 Dallanegra R, Chaplin AB, Tsim J, Weller AS. Amino-borane oligomers bound to a Rh(I) metal fragment. Chemical Communications (Cambridge, England). 46: 3092-4. PMID 20424747 DOI: 10.1039/C003055D  0.716
2010 Chaplin AB, Weller AS. Amine- and dimeric amino-borane complexes of the {Rh(P(i)Pr3)2}+ fragment and their relevance to the transition-metal-mediated dehydrocoupling of amine-boranes. Inorganic Chemistry. 49: 1111-21. PMID 20052982 DOI: 10.1021/Ic9020542  0.768
2010 Chaplin AB, Weller AS. B-H activation at a rhodium(I) center: isolation of a bimetallic complex relevant to the transition-metal-catalyzed dehydrocoupling of amine-boranes. Angewandte Chemie (International Ed. in English). 49: 581-4. PMID 19937888 DOI: 10.1002/Anie.200905185  0.697
2010 Pawley RJ, Moxham GL, Dallanegra R, Chaplin AB, Brayshaw SK, Weller AS, Willis MC. Controlling Selectivity in Intermolecular Alkene or Aldehyde Hydroacylation Reactions Catalyzed by {Rh(L2)}+Fragments Organometallics. 29: 1717-1728. DOI: 10.1021/Om9011104  0.521
2010 Alcaraz G, Chaplin AB, Stevens CJ, Clot E, Vendier L, Weller AS, Sabo-Etienne S. Ruthenium, rhodium, and iridium bis(σ-B-H) diisopropylaminoborane complexes Organometallics. 29: 5591-5595. DOI: 10.1021/Om1004995  0.476
2010 Chaplin AB, Tonner R, Weller AS. Isolation of a Low-Coordinate Rhodium Phosphine Complex Formed by C−C Bond Activation of Biphenylene Organometallics. 29: 2710-2714. DOI: 10.1021/Om100149W  0.442
2010 Chaplin AB, Weller AS. C−C Bond Activation of a Cyclopropyl Phosphine: Isolation and Reactivity of a Tetrameric Rhodacyclobutane Organometallics. 29: 2332-2342. DOI: 10.1021/Om100105P  0.436
2010 Moret S, Dallanegra R, Chaplin AB, Douglas TM, Hiney RM, Weller AS. Alkyl dehydrogenation in iridium tri-cyclopentyl phosphines Inorganica Chimica Acta. 363: 574-580. DOI: 10.1016/J.Ica.2009.03.004  0.496
2010 Chaplin AB, Weller AS. [B(3,5-C6H3Cl2)4]-as a Useful Anion for Organometallic Chemistry European Journal of Inorganic Chemistry. 2010: 5124-5128. DOI: 10.1002/Ejic.201000686  0.417
2009 Douglas TM, Chaplin AB, Weller AS, Yang X, Hall MB. Monomeric and oligomeric amine-borane sigma-complexes of rhodium. intermediates in the catalytic dehydrogenation of amine-boranes. Journal of the American Chemical Society. 131: 15440-56. PMID 19785431 DOI: 10.1021/Ja906070R  0.742
2009 Dallanegra R, Chaplin AB, Weller AS. Bis(sigma-amine-borane) complexes: an unusual binding mode at a transition-metal center. Angewandte Chemie (International Ed. in English). 48: 6875-8. PMID 19688804 DOI: 10.1002/Anie.200903121  0.693
2009 Chaplin AB, Poblador-Bahamonde AI, Sparkes HA, Howard JA, Macgregor SA, Weller AS. Alkyl dehydrogenation in a Rh(I) complex via an isolated agostic intermediate. Chemical Communications (Cambridge, England). 244-6. PMID 19099083 DOI: 10.1039/B816739G  0.681
2009 Hiney RM, Marken F, Raithby PR, Weller AS. Aqueous-organic biphasic redox-chemistry of high-hydride content rhodium clusters: Towards immobilisation of redox-switchable H2 binding materials on a surface Journal of Organometallic Chemistry. 694: 2808-2813. DOI: 10.1016/J.Jorganchem.2009.02.003  0.371
2009 Chaplin A, Weller A. Cover Picture: BH Activation at a Rhodium(I) Center: Isolation of a Bimetallic Complex Relevant to the Transition-Metal-Catalyzed Dehydrocoupling of Amine-Boranes (Angew. Chem. Int. Ed. 3/2010) Angewandte Chemie International Edition. 49: 463-463. DOI: 10.1002/Anie.200906381  0.37
2008 Douglas TM, Chaplin AB, Weller AS. Amine-borane sigma-complexes of rhodium. relevance to the catalytic dehydrogenation of amine-boranes. Journal of the American Chemical Society. 130: 14432-3. PMID 18844358 DOI: 10.1021/Ja806582N  0.71
2008 Sparkes HA, Brayshaw SK, Weller AS, Howard JA. [Rh(C7H8)(PPh3)Cl]: an experimental charge-density study. Acta Crystallographica. Section B, Structural Science. 64: 550-7. PMID 18799842 DOI: 10.1107/S0108768108026384  0.435
2008 Moxham GL, Randell-Sly H, Brayshaw SK, Weller AS, Willis MC. Intermolecular alkene and alkyne hydroacylation with beta-S-substituted aldehydes: mechanistic insight into the role of a hemilabile P-O-P ligand. Chemistry (Weinheim An Der Bergstrasse, Germany). 14: 8383-97. PMID 18666296 DOI: 10.1002/Chem.200800738  0.545
2008 Douglas TM, Brayshaw SK, Raithby PR, Weller AS. Reversible addition of water to the high-hydride-content cluster [Rh6(PiPr3)6H12][BArF4]2. Synthesis and Structure of [Rh6PiPr3)6H11(OH)][BArF4]2. Inorganic Chemistry. 47: 778-80. PMID 18181618 DOI: 10.1021/Ic702195B  0.405
2008 Douglas TM, Brayshaw SK, Dallanegra R, Kociok-Köhn G, Macgregor SA, Moxham GL, Weller AS, Wondimagegn T, Vadivelu HP. Intramolecular alkyl phosphine dehydrogenation in cationic rhodium complexes of tris(cyclopentylphosphine) Chemistry - a European Journal. 14: 1004-1022. PMID 17992682 DOI: 10.1002/Chem.200700954  0.494
2008 Douglas TM, Weller AS. Acceptorless, intramolecular, alkyl dehydrogenation in the solid-state in a rhodium phosphine complex; reversible uptake of three equivalents of H 2 per molecule New Journal of Chemistry. 32: 966-969. DOI: 10.1039/B718615K  0.509
2008 Douglas TM, Chaplin AB, Weller AS. Dihydrogen loss from a 14-electron rhodium(III) bis-phosphine dihydride to give a rhodium(I) complex that undergoes oxidative addition with aryl chlorides Organometallics. 27: 2918-2921. DOI: 10.1021/Om800373D  0.457
2007 Molinos E, Brayshaw SK, Kociok-Köhn G, Weller AS. Cationic rhodium mono-phosphine fragments partnered with carborane monoanions [closo-CB11H6X6]- (X = H, Br). Synthesis, structures and reactivity with alkenes. Dalton Transactions (Cambridge, England : 2003). 4829-44. PMID 17955135 DOI: 10.1039/B711468K  0.483
2007 Brayshaw SK, Green JC, Edge R, McInnes EJ, Raithby PR, Warren JE, Weller AS. [Rh(7)(PiPr(3))(6)H(18)][BAr(F) (4)](2): a molecular Rh(111) surface decorated with 18 hydrogen atoms. Angewandte Chemie (International Ed. in English). 46: 7844-8. PMID 17823903 DOI: 10.1002/Anie.200703069  0.396
2007 Brayshaw SK, Green JC, Hazari N, Weller AS. A DFT based investigation into the electronic structure and properties of hydride rich rhodium clusters. Dalton Transactions (Cambridge, England : 2003). 1781-92. PMID 17471373 DOI: 10.1039/B701683B  0.407
2007 Moxham GL, Brayshaw SK, Weller AS. [Ir(PPh3)2(H)2(ClCH2CH2Cl)][BArF4]: a well characterised transition metal dichloroethane complex. Dalton Transactions (Cambridge, England : 2003). 1759-61. PMID 17471370 DOI: 10.1039/B702399E  0.503
2007 Brayshaw SK, Sceats EL, Green JC, Weller AS. C-C sigma complexes of rhodium. Proceedings of the National Academy of Sciences of the United States of America. 104: 6921-6. PMID 17435164 DOI: 10.1073/Pnas.0609824104  0.409
2007 Brayshaw SK, Harrison A, McIndoe JS, Marken F, Raithby PR, Warren JE, Weller AS. Sequential reduction of high hydride count octahedral rhodium clusters [Rh6(PR3)6H12][BArF4]2: redox-switchable hydrogen storage. Journal of the American Chemical Society. 129: 1793-804. PMID 17284009 DOI: 10.1021/Ja066940M  0.448
2007 Brayshaw SK, Molinos E, Weller AS. catena-Poly[[(tetrafluoroborato-κF)silver(I)]-μ-triphenylphosphine-κ2P:C3] Acta Crystallographica Section E Structure Reports Online. 63: m302-m303. DOI: 10.1107/S1600536806054511  0.305
2007 Molinos E, Brayshaw SK, Kociok-Köhn G, Weller AS. Sequential Dehydrogenative Borylation/Hydrogenation Route to Polyethyl-Substituted, Weakly Coordinating Carborane Anions Organometallics. 26: 2370-2382. DOI: 10.1021/Om070043P  0.507
2007 Douglas TM, Molinos E, Brayshaw SK, Weller AS. Rhodium phosphine olefin complexes of the weakly coordinating anions [BAr4F]- and [1-closo-CB11H 6Br6]-. Kinetic versus thermodynamic factors in anion coordination and complex reactivity Organometallics. 26: 463-465. DOI: 10.1021/Om060975D  0.485
2007 Weller AS, McIndoe JS. Reversible Binding of Dihydrogen in Multimetallic Complexes European Journal of Inorganic Chemistry. 2007: 4411-4423. DOI: 10.1002/Ejic.200700661  0.379
2006 Moxham GL, Douglas TM, Brayshaw SK, Kociok-Köhn G, Lowe JP, Weller AS. The role of halogenated carborane monoanions in olefin hydrogenation catalysed by cationic iridium phosphine complexes. Dalton Transactions (Cambridge, England : 2003). 5492-505. PMID 17117219 DOI: 10.1039/B612049K  0.521
2006 Moxham GL, Randell-Sly HE, Brayshaw SK, Woodward RL, Weller AS, Willis MC. A second-generation catalyst for intermolecular hydroacylation of alkenes and alkynes using beta-S-substituted aldehydes: the role of a hemilabile P-O-P ligand. Angewandte Chemie (International Ed. in English). 45: 7618-22. PMID 17044106 DOI: 10.1002/Anie.200603133  0.333
2006 Douglas TM, Le Nôtre J, Brayshaw SK, Frost CG, Weller AS. Phosphine-olefin ligands: a facile dehydrogenative route to catalytically active rhodium complexes. Chemical Communications (Cambridge, England). 3408-10. PMID 16896477 DOI: 10.1039/B608129K  0.428
2006 Brayshaw SK, Ingleson MJ, Green JC, McIndoe JS, Raithby PR, Kociok-Köhn G, Weller AS. High hydride count rhodium octahedra, [Rh6(PR3)6H12][BArF4]2: synthesis, structures, and reversible hydrogen uptake under mild conditions. Journal of the American Chemical Society. 128: 6247-63. PMID 16669695 DOI: 10.1021/Ja0604663  0.668
2006 Brayshaw SK, Green JC, Kociok-Köhn G, Sceats EL, Weller AS. A rhodium complex with one Rh...C-C and one Rh...H-C agostic bond. Angewandte Chemie (International Ed. in English). 45: 452-6. PMID 16323235 DOI: 10.1002/Anie.200503036  0.388
2006 Molinos E, Player TPH, Kociok-Köhn G, Ruggerio GD, Weller AS. [1-Me-1-closo-SnB11H11]− as a potential weakly coordinating anion: Synthesis of Rh(PPh3)2(1-Me-closo-SnB11H11) and comparisons with Rh(PR3)2 (1-H-closo-CB11 H11) Heteroatom Chemistry. 17: 174-180. DOI: 10.1002/Hc.20218  0.47
2006 Merle N, Frost CG, Kociok-Köhn G, Willis MC, Weller AS. Chelating Phosphane–Boranes as Hemilabile Ligands – Synthesis of[Mn(CO)3(η2-H3B·dppm)][BArF4] and [Mn(CO)4(η1-H3B·dppm)][BArF4] European Journal of Inorganic Chemistry. 2006: 4068-4073. DOI: 10.1002/Ejic.200600526  0.416
2005 Brayshaw SK, Ingleson MJ, Green JC, Raithby PR, Kociok-Köhn G, McIndoe JS, Weller AS. Holding onto lots of hydrogen: a 12-hydride rhodium cluster that reversibly adds two molecules of H2. Angewandte Chemie (International Ed. in English). 44: 6875-8. PMID 16206315 DOI: 10.1002/Anie.200502221  0.621
2005 Molinos E, Kociok-Köhn G, Weller AS. Polyethyl substituted weakly coordinating carborane anions: a sequential dehydrogenative borylation-hydrogenation route. Chemical Communications (Cambridge, England). 3609-11. PMID 16010340 DOI: 10.1039/B504630K  0.359
2005 Ingleson MJ, Brayshaw SK, Mahon MF, Ruggiero GD, Weller AS. Dihydrogen complexes of rhodium: [RhH2(H2)x (PR3)2]+ (R = Cy, iPr; x = 1, 2). Inorganic Chemistry. 44: 3162-71. PMID 15847423 DOI: 10.1021/Ic0482739  0.719
2005 Merle N, Frost CG, Kociok-Köhn G, Willis MC, Weller AS. Ruthenium (II) complexes of the chelating phosphine borane H2ClB·dppm Journal of Organometallic Chemistry. 690: 2829-2834. DOI: 10.1016/J.Jorganchem.2005.01.048  0.439
2005 Ingleson MJ, Kociok-Köhn G, Weller AS. B–C activation in highly alkylated carborane monoanions partnered with cationic transition metal fragments: observations and comments Inorganica Chimica Acta. 358: 1571-1580. DOI: 10.1016/J.Ica.2004.09.048  0.657
2004 Merle N, Koicok-Köhn G, Mahon MF, Frost CG, Ruggerio GD, Weller AS, Willis MC. Transition metal complexes of the chelating phosphine borane ligand Ph2PCH2Ph2P.BH3. Dalton Transactions (Cambridge, England : 2003). 3883-92. PMID 15540133 DOI: 10.1039/B413650K  0.472
2004 Ingleson MJ, Mahon MF, Weller AS. [PtMe(iPr3P)2]+: a Pt(II) complex with an agostic interaction that undergoes C-H activation. Chemical Communications (Cambridge, England). 2398-9. PMID 15514784 DOI: 10.1039/B410846A  0.673
2004 Cotgreave JH, Colclough D, Kociok-Köhn G, Ruggiero G, Frost CG, Weller AS. Well-defined indium(III)N-heterocyclic carbene complexes with triflate ligands: structural models for the In(OTf)3 catalyst. Dalton Transactions (Cambridge, England : 2003). 1519-20. PMID 15252598 DOI: 10.1039/B404179H  0.451
2004 Ingleson MJ, Mahon MF, Raithby PR, Weller AS. [(iPr3P)6Rh6H12]2+: a high-hydride content octahedron that bridges the gap between late and early transition metal clusters. Journal of the American Chemical Society. 126: 4784-5. PMID 15080675 DOI: 10.1021/Ja049402N  0.698
2004 Clarke AJ, Ingleson MJ, Kociok-Köhn G, Mahon MF, Patmore NJ, Rourke JP, Ruggiero GD, Weller AS. Silver-phosphine complexes of the highly methylated carborane monoanion [closo-1-H-CB11Me11]-. Journal of the American Chemical Society. 126: 1503-17. PMID 14759209 DOI: 10.1021/Ja038173M  0.692
2004 Rifat A, Kociok-Köhn G, Steed JW, Weller AS. Cationic iridium phosphines partnered with [closo-CB11H6Br6]-: (see abstract) Organometallics. 23: 428-432. DOI: 10.1021/Om034177O  0.5
2003 Ingleson MJ, Clarke A, Mahon MF, Rourke JP, Weller AS. [Cp2ZrMe(12-mu-Me-1-closo-CB11HMe10)]: a transition metal complex of a highly-methylated carborane anion. Chemical Communications (Cambridge, England). 1930-1. PMID 12932038 DOI: 10.1039/B304568D  0.635
2003 Patmore NJ, Ingleson MJ, Mahon MF, Weller AS. Investigation of the synthesis of {Mo(η5-C5H5)(CO)3}+ fragments partnered with the monoanionic carboranes [closo-CB11H11Br]−, [closo-CB11H6Br6]− and [closo-HCB11Me11]− by silver salt metathesis and hydride abstraction Dalton Transactions. 2894-2904. DOI: 10.1039/B303537A  0.693
2003 Lassahn P, Lozan V, Wu B, Weller AS, Janiak C. Dihalogeno(diphosphane)metal(II) complexes (metal = Co, Ni, Pd) as pre-catalysts for the vinyl/addition polymerization of norbornene – elucidation of the activation process with B(C6F5)3/AlEt3 or Ag[closo-1-CB11H12] and evidence for the in situ formation of “naked” Pd2+ as a highly active species Dalton Transactions. 4437-4450. DOI: 10.1039/B302937A  0.42
2003 Rifat A, Laing V, Kociok-Köhn G, Mahon M, Ruggiero G, Weller A. exo-closo-Rhodacarboranes: synthesis and characterisation of [{exo-(R3P)2Rh}(closo-CB11H12)] [R3P=P(OMe)3, PCy3, 1/2dppe] Journal of Organometallic Chemistry. 680: 127-135. DOI: 10.1016/S0022-328X(03)00230-4  0.465
2003 Rifat A, Mahon MF, Weller AS. Dehydrogenation of cyclohexenes to cyclohexadienes by [(PPh3)2Rh]+. The isolation of an intermediate in the dehydrogenation of cyclohexane to benzene: crystal structure of [(η4-C6H8)Rh(PPh3)2][closo-CB11H6Br6] Journal of Organometallic Chemistry. 667: 1-4. DOI: 10.1016/S0022-328X(02)01923-X  0.438
2003 Patmore NJ, Mahon MF, Weller AS. Bi- and tri-metallic {Cp*RhCl} fragments partnered with carborane monoanions [CB11H6Y6]? (Y = H, Br): control of nuclearity by choice of anion Applied Organometallic Chemistry. 17: 388-392. DOI: 10.1002/Aoc.440  0.496
2002 Ingleson MJ, Mahon MF, Patmore NJ, Ruggiero GD, Weller AS. [(PPh(3))Ag(HCB(11)Me(11))]: a complex with intermolecular Ag.H3C interactions. Angewandte Chemie (International Ed. in English). 41: 3694-7; 3522. PMID 12370934 DOI: 10.1002/1521-3773(20021004)41:19<3694::Aid-Anie3694>3.0.Co;2-B  0.624
2002 Fox MA, Mahon MF, Patmore NJ, Weller AS. Solution and solid-state structure of the anion [Ag(2)[closo-CB(11)H(12)](4)](2-). Inorganic Chemistry. 41: 4567-73. PMID 12184776 DOI: 10.1021/Ic025730H  0.4
2002 Patmore NJ, Hague C, Cotgreave JH, Mahon MF, Frost CG, Weller AS. Silver phosphanes partnered with carborane monoanions: synthesis, structures and use as highly active Lewis acid catalysts in a hetero-Diels-Alder reaction. Chemistry (Weinheim An Der Bergstrasse, Germany). 8: 2088-98. PMID 11981894 DOI: 10.1002/1521-3765(20020503)8:9<2088::Aid-Chem2088>3.0.Co;2-L  0.494
2002 Rifat A, Patmore NJ, Mahon MF, Weller AS. Rhodium phosphines partnered with the carborane monoanions [CB11H6Y6]- (Y = H, Br). Synthesis and evaluation as alkene hydrogenation catalysts Organometallics. 21: 2856-2865. DOI: 10.1021/Om020077R  0.409
2001 Hague C, Patmore NJ, Frost CG, Mahon MF, Weller AS. [(PPh3)Ag(CB11H6Y6)] (Y = H, Br): Highly active, selective and recyclable Lewis acids for a hetero-Diels-Alder reaction Chemical Communications. 2286-2287. DOI: 10.1039/B106719B  0.381
2001 Ingleson M, Patmore NJ, Ruggiero GD, Frost CG, Mahon MF, Willis MC, Weller AS. Chelating monoborane phosphines: Rational and high-yield synthesis of [(COD)Rh{(η2-BH3)Ph2PCH2PPh 2}][PF6] (COD = 1,5-cyclooctadiene) Organometallics. 20: 4434-4436. DOI: 10.1021/Om0103759  0.71
2001 Moreau C, Hague C, Weller AS, Frost CG. Rhodium-catalysed aryl transfer to aldehydes: Counterion effects with nitrogen containing ligands Tetrahedron Letters. 42: 6957-6960. DOI: 10.1016/S0040-4039(01)01421-6  0.391
2000 Patmore NJ, Steed JW, Weller AS. Transition metal complexes of the weakly coordinating carborane anion [CB11H12]−: the first isolation and structural characterisation of an intermediate in a silver salt metathesis reaction Chemical Communications. 1055-1056. DOI: 10.1039/B002585M  0.38
2000 Weller AS, Mahon MF, Steed JW. Rhodium cyclooctadiene complexes of the weakly co-ordinating carborane anion [closo-CB11H12]−. Isolation and crystal structures of [(COD)Rh(η2-CB11H12)] and [(COD)Rh(THF)2][CB11H12] Journal of Organometallic Chemistry. 614: 113-119. DOI: 10.1016/S0022-328X(00)00608-2  0.524
1999 Weller AS, Andrews CD, Burrows AD, Green M, Lynam JM, Mahon MF, Jones C. Facile, metal promoted, oxidation of η4-1,3-diphosphacyclobutadiene by water or methanol: synthesis of [MoCl(CO)(η4-1,3-P2C2But2)(η5-L)] (L = C5H5, C5Me5) and [MoCl(CO){η3,λ3,λ5-PC2But2PH(OR)}(η5-L)] (L= C5H5,R = H, Me) Chemical Communications. 2147-2148. DOI: 10.1039/A905240B  0.389
1999 Weller AS, Shang M, Fehlner TP. New Structural Motifs in Metallaborane Chemistry. Synthesis, Characterization, and Solid-State Structures of (Cp*W)3(μ-H)B8H8, (Cp*W)2B7H9, and (Cp*Re)2B7H7 (Cp* = η-C5Me5) Organometallics. 18: 853-863. DOI: 10.1021/Om980814C  0.609
1999 Weller AS, Fehlner TP. Molecular orbital analysis of the trend in 11B NMR chemical shifts for (Cp*M)2B5H9 (M = Cr, Mo, W; Cp* = η5-C5Me5) Organometallics. 18: 447-450. DOI: 10.1021/Om980808G  0.529
1999 Weller AS, Shang M, Fehlner TP. Synthesis of mono- and ditungstaboranes from reaction of Cp*WCl4 and [Cp*WCl2]2 with BH3·thf or LiBH4 (Cp*=η5-C5Me5). Control of reaction pathway by choice of monoboron reagent and oxidation state of metal center Organometallics. 18: 53-64. DOI: 10.1021/Om980743H  0.575
1999 Weller AS, Aldridge S, Fehlner TP. Early versus late transition metals. Electronic structure of nido-2-CpMLnB4H8, CpMLn=CpTaCl2, CpWH3 and CpCo Inorganica Chimica Acta. 289: 85-94. DOI: 10.1016/S0020-1693(99)00061-4  0.589
1998 Johansen K, Rosair GM, Weller AS, Welch AJ. 3-(η3-Allyl)-3,3-dicarbonyl-4-(dimethyl sulfido)-3,1,2-molybdadicarba-closo-dodecaborane(12) Acta Crystallographica Section C Crystal Structure Communications. 54: 214-217. DOI: 10.1107/S0108270197011372  0.632
1998 Weller AS, Shang M, Fehlner TP. Synthesis and characterization of the nine-atom, rhena- And tungsta-boranes (Cp*Re)2B7H7 and (Cp*W)2B7H9, Cp*=η 5-C5Me5. Molecular mimics of hypoelectronic main-group clusters in Zintl phases Chemical Communications. 1787-1788. DOI: 10.1039/A805356A  0.54
1998 Rosair GM, Welch AJ, Weller AS. Sterically Encumbered, Charge-Compensated Metallacarboranes.†Synthesis and Structures of Ruthenium Pentamethylcyclopentadienyl Derivatives Organometallics. 17: 3227-3235. DOI: 10.1021/Om980353V  0.356
1998 Weller AS, Shang M, Fehlner TP. Synthesis and structure of the metallaborane Cp*3(μ-H)W3B8H8 from the thermolysis of Cp*H3WB4H8 (Cp* = η5-C5Me5). A close-packed 11- atom boron-rich cluster [20] Journal of the American Chemical Society. 120: 8283-8284. DOI: 10.1021/Ja981101O  0.573
1998 Teixidor F, Viñas C, Flores MA, Rosair GM, Welch AJ, Weller AS. Metalation of a Bis(thiophenyl)carborane Giving Both Exo and Endo Products. Synthesis and Structural Characterization of RuCl{7,8-(SPh)2-7,8-nido-C2B9H10}(p-cymene) and 1,2-(SPh)2-3-(p-cymene)-3,1,2-RuC2B9H9† Inorganic Chemistry. 37: 5394-5395. DOI: 10.1021/Ic980370C  0.321
1998 Boyd AS, Rosair GM, Tiarks FB, Weller AS, Zahn SK, Welch AJ. Charge-compensated carbarhodaboranes. Synthesis and molecular structures of 3-L-3,3- (I) 24-SMe2-3,1,2-closo-RhC2B9H10, L = CO or PPh3 Polyhedron. 17: 2627-2632. DOI: 10.1016/S0277-5387(98)00011-4  0.608
1998 Beckering CL, Rosair GM, Weller AS. Ferrocenyl substituted carboranes: synthesis and characterisation Journal of Organometallic Chemistry. 556: 55-66. DOI: 10.1016/S0022-328X(97)00676-1  0.411
1998 Adams KJ, McGrath TD, Rosair GM, Weller AS, Welch AJ. Rhodathiaboranes with `anomalous' electron counts: synthesis, structure and reactivity Journal of Organometallic Chemistry. 550: 315-329. DOI: 10.1016/S0022-328X(97)00546-9  0.465
1997 Welch AJ, Weller AS. Synthesis and reactivity of 7,9-diphenyl-nido-carbaundecaboranes: rearrangement processes in carbaplatinaboranes revisited Journal of the Chemical Society-Dalton Transactions. 1205-1212. DOI: 10.1039/A607523A  0.38
1997 Jeffery JC, Weller AS. Synthesis, characterisation and reactivity of group six alkylidynes bearing the tridentate phosphine PPh(C2H4PPh2)2-‘triphos’. Crystal structure of mer-[W(NCMe)(≡CC6H4Me-4)PPh(C2H4PPh2)2(CO)][BF4] Journal of Organometallic Chemistry. 548: 195-203. DOI: 10.1016/S0022-328X(97)00412-9  0.645
1997 Rosair GM, Welch AJ, Weller AS, Zahn SK. Sterically Encumbered Charge-Compensated Carbaboranes: Synthesis And Reactivity Molecular Structures Of 7-Ph-11-Sme2-7,8-Nido-C2B9H10 And 1-Ph-3,3-(Co )2-7-Sme2-3,1,2-Closo-Rhc2B9H8 Journal of Organometallic Chemistry. 536: 299-308. DOI: 10.1016/S0022-328X(96)06740-X  0.587
1997 Adams KJ, McGrath TD, Thomas RL, Weller AS, Welch AJ. Reversible on/off switching of interactions in rhodathiaboranes with “anomalous” electron counts. Synthesis and molecular structure of [(Ph3P2N][1-dppe-1,2-closo-RhSB9H9] Journal of Organometallic Chemistry. 527: 283-285. DOI: 10.1016/S0022-328X(96)06419-4  0.419
1997 Dunn S, Rosair GM, Thomas RL, Weller AS, Welch AJ. Isolierung einer nicht-ikosaedrischen Zwischenstufe der Isomerisierung eines ikosaedrischen Metallacarborans Angewandte Chemie. 109: 617-619. DOI: 10.1002/Ange.19971090609  0.508
1996 Rosair GM, Welch AJ, Weller AS. 8-[1,2-Bis(diphenylphosphino)ethane]-9,10-μ-hydrido-8-rhoda-7-thia-nido-undecaborane(10)–Dichloromethane (2/1) Acta Crystallographica Section C Crystal Structure Communications. 52: 3020-3024. DOI: 10.1107/S0108270196010748  0.462
1996 Rosair GM, Welch AJ, Weller AS. 9-Dicyclohexylphenylphosphino-arachno-6-thiadecaborane(11) Acta Crystallographica Section C Crystal Structure Communications. 52: 2851-2853. DOI: 10.1107/S0108270196008244  0.328
1996 Grädler U, Weller AS, Welch AJ, Reed D. Synthesis, characterisation and molecular structures of the closo and pseudocloso heptamethylindenyl carbarhodaboranes 1-Ph-3-(η-C9Me7)-3,1,2-closo-RhC2B9H10and 1,2-Ph2-3-(η-C9Me7)-3,1,2-pseudocloso-RhC2B9H9. Experimental assignment of the11B NMR spectrum of a pseudocloso carbametallaborane Journal of the Chemical Society-Dalton Transactions. 335-342. DOI: 10.1039/Dt9960000335  0.612
1996 Welch AJ, Weller AS. Mixed Sandwich Carborane/Thiamacrocycle Compounds. Synthesis and Characterization of 1-Ph-3,3,3-[9]aneS3-κ3-S,S‘,S‘‘-3,1,2-closo-RuC2B9H10and 1,2-Ph2-3,3,3-[9]aneS3-κ3-S,S‘,S‘‘-3,1,2-pseudocloso-RuC2B9H9†,‡ Inorganic Chemistry. 35: 4548-4554. DOI: 10.1021/Ic9601899  0.559
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