Robert A. McClelland - Publications

Affiliations: 
University of Toronto, Toronto, ON, Canada 

138 high-probability publications. We are testing a new system for linking publications to authors. You can help! If you notice any inaccuracies, please sign in and mark papers as correct or incorrect matches. If you identify any major omissions or other inaccuracies in the publication list, please let us know.

Year Citation  Score
2010 Tee OS, Trani M, McClelland RA, Seaman E. Tetrahedral Intermediates in the Hydrolytic Ring-Opening of Pyrimidinium and Quinazolinium Cations Bulletin Des SociéTéS Chimiques Belges. 91: 393-393. DOI: 10.1002/Bscb.19820910552  0.615
2010 McClelland RA, Santry LJ. Rate and Equilibrium Constants for the Formation and Decomposition of Tetrahedral Intermediates Bulletin Des SociéTéS Chimiques Belges. 91: 392-392. DOI: 10.1002/Bscb.19820910551  0.311
2006 McClelland RA, Postigo A. Solvent effects on the reactivity of fluorenyl nitrenium ion with DNA-like probes. Biophysical Chemistry. 119: 213-8. PMID 16242233 DOI: 10.1016/J.Bpc.2005.09.014  0.388
2002 McClelland RA, Sanchez C, Sauer E, Vukovic S. Reaction of the tamoxifen cation and the bis-(4-methoxyphenyl)methyl cation in aqueous solutions containing 2'-deoxyguanosine Canadian Journal of Chemistry. 80: 269-280. DOI: 10.1139/V02-011  0.428
2002 Ruane PH, Ahmed AR, McClelland RA. N-Arylbenzonitrilium ions. Photochemical generation and effect of substituents in the phenyl rings on lifetimes in water and reactivity with azide ion Journal of the Chemical Society-Perkin Transactions 1. 312-317. DOI: 10.1039/B107028M  0.415
2002 McClelland RA, Leung M. Mechanism of hydrolysis of aryl vinyl selenides. Selenium-stabilized carbonium ions Cheminform. 11. DOI: 10.1002/Chin.198025268  0.368
2001 McClelland RA, Licence VE. The 2-carbazolylnitrenium ion and its conjugate acid and base forms Arkivoc. 2001. DOI: 10.3998/Ark.5550190.0002.C08  0.385
2001 Cheng B, McClelland RA. Reaction of arylnitrenium ions with guanine derivatives: N1-methylguanosine and N2,N2-dimethylguanosine Canadian Journal of Chemistry. 79: 1881-1886. DOI: 10.1139/V01-179  0.386
2001 Ruane PH, McClelland RA. Kinetic stabilizing effect of the 4-N-methylacetamido substituent on the phenylnitrenium ion Canadian Journal of Chemistry. 79: 1875-1880. DOI: 10.1139/V01-178  0.407
2000 Sanchez C, McClelland RA. The tamoxifen cation reacts to give indene products Canadian Journal of Chemistry. 78: 1186-1193. DOI: 10.1139/V00-122  0.354
1999 Cozens FL, Kanagasabapathy VM, McClelland RA, Steenken S. Lifetimes and UV-visible absorption spectra of benzyl, phenethyl, and cumyl carbocations and corresponding vinyl cations. A laser flash photolysis study Canadian Journal of Chemistry. 77: 2069-2082. DOI: 10.1139/V99-210  0.372
1999 Engell KM, McClelland RA, Sørensen PE. The decomposition of methyl hemiacetals of benzaldehyde in aqueous solution: a study of the effect of aromatic substitution Canadian Journal of Chemistry. 77: 978-989. DOI: 10.1139/V99-102  0.383
1999 Bose R, Ahmad AR, Dicks AP, Novak M, Kayser KJ, McClelland RA. Spectroscopic characterization by laser flash photolysis of electrophilic intermediates derived from 4-aminostilbenes. Stilbene “nitrenium” ions and quinone methide imines† Journal of the Chemical Society-Perkin Transactions 1. 1591-1600. DOI: 10.1039/A904230J  0.411
1999 Ramlall P, Li Y, McClelland RA. Irradiation of 5-azido-8-methoxypsoralen† in water–acetonitrile gives nitrenium ion and triplet nitrene transients, but only nitrenium ion products Journal of the Chemical Society-Perkin Transactions 1. 1601-1608. DOI: 10.1039/A902317H  0.418
1999 Dicks AP, Ahmad AR, D’Sa R, McClelland RA. Tautomers and conjugate base of the nitrenium ion derived from N-acetylbenzidine Journal of the Chemical Society-Perkin Transactions 1. 1-4. DOI: 10.1039/A808322C  0.392
1999 Ramlall P, McClelland RA. Photochemical Generation And Lifetimes In Water Of P-Aryloxy- And P-Alkoxyphenylnitrenium Ions Journal of the Chemical Society-Perkin Transactions 1. 225-232. DOI: 10.1039/A807567K  0.399
1999 Ruane PH, McClelland RA, Hegarty AF, Steenken S. Photochemical generation of the N-isopropylbenzonitrilium ion and unusually slow trapping by azide ion Journal of the Chemical Society-Perkin Transactions 1. 43-48. DOI: 10.1039/A807346E  0.388
1999 McClelland RA, Ahmad A, Dicks aAP, Licence VE. Spectroscopic Characterization of the Initial C8 Intermediate in the Reaction of the 2-Fluorenylnitrenium Ion with 2‘-Deoxyguanosine Journal of the American Chemical Society. 121: 3303-3310. DOI: 10.1021/Ja9836702  0.433
1999 and TAG, McClelland RA. Photochemistry of 2-Azido-1-methylimidazole in Aqueous Solutions. Observation of the 1-Methyl-2-imidazolylnitrenium Ion Journal of the American Chemical Society. 121: 1459-1465. DOI: 10.1021/Ja9827090  0.444
1998 McClelland RA, Licence VE, Richard JP, Williams KB, Lin S. Remarkable kinetic stability of α-thiocarbamoyl substituted 4-methoxybenzylcations Canadian Journal of Chemistry. 76: 1910-1915. DOI: 10.1139/V98-225  0.363
1998 McClelland RA, Gadosy TA, Ren D. 1997 Alfred Bader Award Lecture Reactivities of arylnitrenium ions with guanine derivatives and other nucleophiles Canadian Journal of Chemistry. 76: 1327-1337. DOI: 10.1139/V98-187  0.394
1998 Ren D, McClelland RA. Carbocation-like reactivity patterns in X'-substituted-4-biphenylylnitrenium ions Canadian Journal of Chemistry. 76: 78-84. DOI: 10.1139/V97-204  0.338
1998 Sanchez C, Shibutani S, Dasaradhi L, Bolton JL, Fan PW, McClelland RA. Lifetime and reactivity of an ultimate tamoxifen carcinogen: The tamoxifen carbocation [1] Journal of the American Chemical Society. 120: 13513-13514. DOI: 10.1021/Ja982701Q  0.672
1998 Faria JL, McClelland RA, Steenken S. Photohomolysis and Photoionization of Substituted Tetraphenylethanes and C–C Fragmentation of 1,1,2,2‐Tetra(p‐R‐phenyl)ethane Radical Cations (R=H, CH3, OCH3, Cl) Chemistry: a European Journal. 4: 1275-1280. DOI: 10.1002/(Sici)1521-3765(19980710)4:7<1275::Aid-Chem1275>3.0.Co;2-X  0.322
1997 McClelland RA, Ren D, Ghobrial D, Gadosy TA. Reactions and lifetime of the 6,6-dimethyl-3-phenylbenzenium ion inaqueous solution. Comparison with the 6-imino-3-phenylbenzenium ion(biphenyl-4-ylnitrenium ion) Journal of the Chemical Society-Perkin Transactions 1. 451-456. DOI: 10.1039/A606786G  0.419
1996 Macknight E, McClelland RA. A photochemical retro-Friedel–Crafts alkylation. Rapid rearrangement of cyclohexadienyl cations Canadian Journal of Chemistry. 74: 2518-2527. DOI: 10.1139/V96-282  0.342
1996 Fishbein JC, McClelland RA. Halide ion trapping of nitrenium ions formed in the Bamberger rearrangement of N-arylhydroxylamines. Lifetime of the parent phenylnitrenium ion in water Canadian Journal of Chemistry. 74: 1321-1328. DOI: 10.1139/V96-147  0.405
1996 McClelland RA, Cozens FL, Li J, Steenken S. Flash photolysis study of a Friedel–Crafts alkylation. Reaction of the photogenerated 9-fluorenyl cation with aromatic compounds Journal of the Chemical Society-Perkin Transactions 1. 1531-1543. DOI: 10.1039/P29960001531  0.377
1996 Sukhai P, McClelland RA. Direct observation of 4-alkoxyphenylnitrenium ions upon irradiation of 4-alkoxyphenyl azides in aqueous solution Journal of the Chemical Society-Perkin Transactions 1. 1529-1530. DOI: 10.1039/P29960001529  0.384
1996 McClelland RA, Kahley MJ, Davidse aPA, Hadzialic G. Acid−Base Properties of Arylnitrenium Ions Journal of the American Chemical Society. 118: 4794-4803. DOI: 10.1021/Ja954248D  0.444
1996 McClelland RA. Flash photolysis generation and reactivities of carbenium ions and nitrenium ions Tetrahedron. 52: 6823-6858. DOI: 10.1016/0040-4020(96)00020-8  0.35
1996 McClelland RA, Kahley MJ, Davidse PA. Reactivity of the 4‐biphenylyl and 2‐fluorenylnitrenium ions with heterocyclic and carbon nucleophiles Journal of Physical Organic Chemistry. 9: 355-360. DOI: 10.1002/(Sici)1099-1395(199606)9:6<355::Aid-Poc792>3.0.Co;2-Q  0.332
1995 Fishbein JC, McClelland RA. Nature of nitrenium:carboxylate ion pair intermediates in the hydrolysis of O-aroyl-N-acetyl-N-(2,6-dimethylphenyl)hydroxylamines Journal of the Chemical Society-Perkin Transactions 1. 663-671. DOI: 10.1039/P29950000663  0.419
1995 Fishbein JC, McClelland RA. Cyclohexadienes from the rearrangement of O-aroyl-N-acetyl-N-(2,6-dimethylphenyl)hydroxylamines. Reaction in aqueous solution to meta- and para-substituted 2,6-dimethylacetanilides Journal of the Chemical Society-Perkin Transactions 1. 653-662. DOI: 10.1039/P29950000653  0.414
1995 McClelland RA, Davidse PA, Hadzialic G. Electron-Deficient Strong Bases. Generation Of The 4-Biphenylyl- And 2-Fluorenylnitrenium Ions By Nitrene Protonation In Water Journal of the American Chemical Society. 117: 4173-4174. DOI: 10.1021/Ja00119A035  0.323
1994 McClelland RA, Sukhai P, Engell KM, Sorensen PE. Hydration equilibria of 9-acridinecarboxaldehyde Canadian Journal of Chemistry. 72: 2333-2338. DOI: 10.1139/V94-297  0.409
1994 McClelland RA, Engell KM, Larsen TS, Sørensen PE. Hemiacetals of acetophenone. Aromatic substituent effects in the H+- and general-base-catalysed decomposition in aqueous solution Journal of the Chemical Society-Perkin Transactions 1. 2199-2206. DOI: 10.1039/P29940002199  0.385
1994 Lew CSQ, McClelland RA, Johnston LJ, Schepp NP. Photochemical generation of the 9-(trimethylsilylmethyl)fluoren-9-yl cation. Flash photolysis observation of a β-silyl-substituted carbenium ion Journal of the Chemical Society-Perkin Transactions 1. 395-397. DOI: 10.1039/P29940000395  0.363
1994 Davidse PA, Kahley MJ, Mcclelland RA, Novak M. Flash Photolysis Observation and Lifetimes of 2-Fluorenyl- and 4-Biphenylylacetylnitrenium Ions in Aqueous Solution Journal of the American Chemical Society. 116: 4513-4514. DOI: 10.1021/Ja00089A065  0.364
1993 Farah SF, McClelland RA. Preparation and reactions of bromo-2-nitro- and bromo-2-aminoimidazoles Canadian Journal of Chemistry. 71: 427-432. DOI: 10.1139/V93-063  0.324
1993 McClelland RA, Watada B, Lew CSQ. Reversibility of the ring-opening step in the acid hydrolysis of cyclic acetophenone acetals Journal of the Chemical Society-Perkin Transactions 1. 1723-1727. DOI: 10.1039/P29930001723  0.373
1993 McClelland RA, Cozens FL, Steenken S, Amyes TL, Richard JP. Direct observation of β-fluoro-substituted 4-methoxyphenethyl cations by laser flash photolysis Journal of the Chemical Society-Perkin Transactions 1. 1717-1722. DOI: 10.1039/P29930001717  0.362
1993 Lew CSQ, McClelland RA. Photochemical protodesilylation of 2-R3Si-1,3-dimethoxybenzenes. Direct observation of .beta.-silyl-substituted cyclohexadienyl cations Journal of the American Chemical Society. 115: 11516-11520. DOI: 10.1021/Ja00077A058  0.326
1993 Cozens FL, McClelland RA, Steenken S. Observation of cationic intermediates in the photolysis of 1-phenylcyclohexene Journal of the American Chemical Society. 115: 5050-5055. DOI: 10.1021/Ja00065A014  0.335
1992 Bérubé LR, Farah S, McClelland RA, Rauth AM. Depletion of intracellular glutathione by 1-methyl-2-nitrosoimidazole. International Journal of Radiation Oncology, Biology, Physics. 22: 817-20. PMID 1544856 DOI: 10.1016/0360-3016(92)90531-L  0.309
1992 Cozens FL, Mathivanan N, McClelland RA, Steenken S. Reactivities of 9-arylfluoren-9-yl and 1-(4-dimethylaminophenyl)ethyl cations in water and trifluoroethanol studied by laser flash photolysis Journal of the Chemical Society-Perkin Transactions 1. 2083-2090. DOI: 10.1039/P29920002083  0.382
1992 Kazanis S, McClelland RA. Electrophilic intermediate in the reaction of glutathione and nitroso arenes Journal of the American Chemical Society. 114: 3052-3059. DOI: 10.1021/Ja00034A043  0.335
1992 Cozens F, McClelland RA, Steenken S. Flash photolysis observation and lifetimes of the cation intermediates in the intramolecular photoprotonation of tryptamine, tryptophan and their N-methyl derivatives Tetrahedron Letters. 33: 173-176. DOI: 10.1016/0040-4039(92)88042-4  0.313
1991 McClelland RA, Kanagasabapathy VM, Mathivanan N. Kinetics of breakdown of aryl hemiacetals of α-bromoacetophenone. Effect of phenol leaving groups on the lifetimes of tetrahedral intermediates Canadian Journal of Chemistry. 69: 2084-2093. DOI: 10.1139/V91-301  0.33
1991 McGall GH, McClelland RA. Hydrolysis of a monocyclic oxyphosphorane containing a five-membered ring Canadian Journal of Chemistry. 69: 2075-2083. DOI: 10.1139/V91-300  0.452
1991 McGall GH, McClelland RA. Kinetics and mechanism of the hydrolysis of a (5,6)-spirophosphorane. Thermodynamics of the hydrolysis of cyclic five-membered and six-membered phosphonium ions Canadian Journal of Chemistry. 69: 2064-2074. DOI: 10.1139/V91-299  0.42
1991 McClelland RA, Kanagasabapathy VM, Banait NS, Steenken S. Reactivities of triarylmethyl and diarylmethyl cations with azide ion investigated by laser flash photolysis. Diffusion-controlled reactions Journal of the American Chemical Society. 113: 1009-1014. DOI: 10.1021/Ja00003A040  0.361
1991 McClelland RA, Chan C, Cozens F, Modro A, Steenken S. Laser Flash Photolysis Generation, Spectra, and Lifetimes of Phenylcarbenium Ions in Trifluoroethanol and Hexafluoroisopropyl Alcohol. On the UV Spectrum of the Benzyl Cation Angewandte Chemie International Edition in English. 30: 1337-1339. DOI: 10.1002/Anie.199113371  0.307
1990 McClelland RA, Kanagasabapathy VM, Steenken S. Flash photolysis production of the tetrahedral intermediate of the methanolysis of methyl benzoate. Direct measurement of the rate of breakdown of the conjugate base form Canadian Journal of Chemistry. 68: 375-382. DOI: 10.1139/V90-057  0.35
1990 Mathivanan N, McClelland RA, Steenken S. A kinetic method for the measurement of the pKR value of the triphenylmethyl cation in the aqueous standard state Journal of the American Chemical Society. 112: 8454-8457. DOI: 10.1021/Ja00179A033  0.304
1989 Panicucci R, McClelland RA. 4,5-Dihydro-4,5-dihydroxyimidazoles as products of the reduction of 2-nitroimidazoles. HPLC assay and demonstration of equilibrium transfer of glyoxal to guanine Canadian Journal of Chemistry. 67: 2128-2135. DOI: 10.1139/V89-331  0.341
1989 Farah SF, McClelland RA, Peterson MR, Csizmadia IG. Molecular structure and relative proton and electron affinities of isomeric nitroimidazoles Canadian Journal of Chemistry. 67: 1666-1671. DOI: 10.1139/V89-255  0.322
1989 Bolton JL, McClelland RA. Azide ion trapping and lifetime in aqueous solution of a primary carbenium ion stabilized by a 2-imidazoyl ring Canadian Journal of Chemistry. 67: 1139-1143. DOI: 10.1139/V89-171  0.595
1989 Bolton JL, McClelland RA. Kinetics and mechanism of the decomposition in aqueous solutions of 2-(hydroxyamino)imidazoles Journal of the American Chemical Society. 111: 8172-8181. DOI: 10.1021/Ja00203A018  0.635
1989 McClelland RA, Kanagasabapathy VM, Banait NS, Steenken S. Flash-photolysis generation and reactivities of triarylmethyl and diarylmethyl cations in aqueous solutions Journal of the American Chemical Society. 111: 3966-3972. DOI: 10.1021/Ja00193A031  0.307
1989 McClelland RA, Banait N, Steenken S. Electrophilic reactions of xanthylium carbocations produced by flash photolysis of 9-xanthenols Journal of the American Chemical Society. 111: 2929-2935. DOI: 10.1021/Ja00190A030  0.316
1988 Noss MB, Panicucci R, McClelland RA, Rauth AM. Preparation, toxicity and mutagenicity of 1-methyl-2-nitrosoimidazole. A toxic 2-nitroimidazole reduction product. Biochemical Pharmacology. 37: 2585-93. PMID 3214494 DOI: 10.1016/0006-2952(88)90250-X  0.301
1988 Bolton JL, Peterson MR, McClelland RA. Experimental and theoretical investigation of C-nitroso rotation in 2-nitrosoimidazoles Canadian Journal of Chemistry. 66: 3044-3049. DOI: 10.1139/V88-471  0.518
1988 McClelland RA, Steenken S. Radiation chemical production, lifetimes, and structure-activity relations for .alpha.-dialkoxyalkyl carbocations in aqueous solutions: Importance of solvation for cation reactivity Journal of the American Chemical Society. 110: 5860-5866. DOI: 10.1021/Ja00225A042  0.31
1988 Santry LJ, Azer S, McClelland RA. Alkyl group effects on the rate constants and equilibrium constants for formation of cyclic tetrahedral intermediates Journal of the American Chemical Society. 110: 2909-2914. DOI: 10.1021/Ja00217A036  0.326
1988 Bolton JL, McClelland RA. Theoretical studies of imidazole nitrenium and carbenium ions Journal of Molecular Structure: Theochem. 165: 379-389. DOI: 10.1016/0166-1280(88)87034-9  0.589
1987 McClelland RA, Seaman NE. Kinetic and equilibrium study of the ring opening of 2-aryl-1-methyl-1-pyrrolinium ions in aqueous solution Canadian Journal of Chemistry. 65: 1689-1694. DOI: 10.1139/V87-283  0.411
1987 McClelland RA, Steenken S. Pronounced solvent effect on the absorption spectra of the photochemically produced 2,4-dinitrobenzyl carbanion Canadian Journal of Chemistry. 65: 353-356. DOI: 10.1139/V87-060  0.325
1987 Fishbein JC, McClelland RA. Azide ion trapping of the intermediate in the Bamberger rearrangement. Lifetime of a free nitrenium ion in aqueous solution Journal of the American Chemical Society. 109: 2824-2825. DOI: 10.1021/Ja00243A045  0.379
1986 Panicucci R, McClelland RA, Rauth AM. Stable reduction product of misonidazole. International Journal of Radiation Oncology, Biology, Physics. 12: 1227-30. PMID 3744942 DOI: 10.1016/0360-3016(86)90264-6  0.389
1986 McClelland RA, Sørensen PE. Kinetics of the equilibration of 3-hydroxyphthalide and o-formylbenzoic acid. Hemiacetal breakdown with a carboxylic acid leaving group Canadian Journal of Chemistry. 64: 1196-1200. DOI: 10.1139/V86-198  0.362
1986 Lennox RB, McClelland RA. Electrophilic bromination of micelle-associated alkenes as a probe of micelle structure Journal of the American Chemical Society. 108: 3771-3781. DOI: 10.1021/Ja00273A035  0.533
1986 Mcclelland RA, Devine DB, Soerensen PE. Hemiacetal Formation with a Phenol Nucleophile: Simple Proton Transfers as Rate- Limiting Steps. Cheminform. 17. DOI: 10.1002/Chin.198601066  0.319
1985 McClelland RA, Moreau C. Reversible ring opening in the hydrolysis of spiro ortho esters Canadian Journal of Chemistry. 63: 2673-2678. DOI: 10.1139/V85-444  0.326
1985 McClelland RA, Seaman NE, Duff JM, Branston RE. Kinetics and equilibrium in the ammonolysis of substituted phthalimides Canadian Journal of Chemistry. 63: 121-128. DOI: 10.1139/V85-020  0.405
1985 McGall GH, McClelland RA. Reversible ring-opening in the hydrolysis of spirophosphoranes Journal of the Chemical Society, Chemical Communications. 560-561. DOI: 10.1039/C39850000560  0.408
1985 Devine DB, McClelland RA. Hydration of the flavylium ion. 3. The effect of 3-alkyl substitution Journal of Organic Chemistry. 50: 5656-5660. DOI: 10.1021/Jo00350A046  0.362
1985 McClelland RA, Devine DB, Soerensen PE. Hemiacetal formation with a phenol nucleophile: simple proton transfers as rate-limiting steps Journal of the American Chemical Society. 107: 5459-5463. DOI: 10.1021/Ja00305A022  0.338
1985 McGall GH, McClelland RA. Oxyphosphorane hydrolysis. Reversible ring opening of spirophosphoranes containing six-atom rings Journal of the American Chemical Society. 107: 5198-5203. DOI: 10.1021/Ja00304A028  0.329
1985 McClelland RA, Panicucci R, Rauth AM. Electrophilic intermediate in the reactions of a 2-(hydroxyamino)imidazole. A model for biological effects of reduced nitroimidazoles Journal of the American Chemical Society. 107: 1762-1763. DOI: 10.1021/Ja00292A053  0.307
1985 Mcclelland RA, Mcgall GH, Patel G. Kinetics And Mechanism Of The Hydrolysis Of Acyclic Oxyphosphonium Salts Cheminform. 16. DOI: 10.1002/Chin.198551240  0.308
1984 McClelland RA, Fuller JR, Seaman NE, Rauth AM, Battistella R. 2-Hydroxylaminoimidazoles--unstable intermediates in the reduction of 2-nitroimidazoles. Biochemical Pharmacology. 33: 303-9. PMID 6704152 DOI: 10.1016/0006-2952(84)90489-1  0.319
1984 McClelland RA, Seaman NE. A change in rate-determining step in the hydrolysis of cyclic ketals Canadian Journal of Chemistry. 62: 1608-1612. DOI: 10.1139/V84-276  0.342
1984 McClelland RA, Lam PWK. Hydrolysis of trioxaadamantane ortho esters. II. Kinetic analysis and the nature of the rate-determining step Canadian Journal of Chemistry. 62: 1074-1080. DOI: 10.1139/V84-177  0.372
1984 McClelland RA, Lam PWK. Hydrolysis of trioxaadamantane ortho esters. I. Dialkoxycarbocation – ortho ester equilibrium and acidity function Canadian Journal of Chemistry. 62: 1068-1073. DOI: 10.1139/V84-176  0.406
1984 Edward JT, Wong SC, McClelland RA. Rate of lactamization of benzylstrychnine in acid solution Canadian Journal of Chemistry. 62: 144-146. DOI: 10.1139/V84-030  0.348
1984 McClelland RA, Seaman NE, Cramm D. Observation of a stable hemiortho ester anion. Acidity constant for a tetrahedral intermediate Journal of the American Chemical Society. 106: 4511-4515. DOI: 10.1021/Ja00328A034  0.317
1984 Mcclelland RA, Seaman NE, Cramm D. Observation Of A Stable Hemiortho Ester Anion. Acidity Constant For A Tetrahedral Intermediate Cheminform. 15. DOI: 10.1002/Chin.198446100  0.389
1984 McClelland RA, Santry LJ. Reactivity of tetrahedral intermediates Cheminform. 15. DOI: 10.1002/Chin.198412352  0.32
1983 Santry LJ, McClelland RA. Kinetics of breakdown of the tetrahedral intermediate of an O,S-acyl transfer reaction Journal of the American Chemical Society. 105: 3167-3172. DOI: 10.1021/Ja00348A034  0.3
1983 McClelland RA, Santry LJ. Reactivity of tetrahedral intermediates Accounts of Chemical Research. 16: 394-399. DOI: 10.1021/Ar00095A001  0.32
1983 Santry LJ, McClelland RA. Orientation effects on the rate and equilibrium constants for formation and decomposition of tetrahedral intermediates Cheminform. 14. DOI: 10.1002/Chin.198352114  0.301
1983 Tee OS, Trani M, Mcclelland RA, Seaman NE. Observation Of A Tetrahedral Intermediate And Its Anion In A Hydrolysis Reaction. Ring Opening Of A Quinazolinium Ion Cheminform. 14. DOI: 10.1002/Chin.198311063  0.671
1982 McClelland RA, McGall GH. Hydration of the flavylium ion. 2. The 4'-hydroxyflavylium ion Journal of Organic Chemistry. 14: 3730-3736. DOI: 10.1021/Jo00140A027  0.338
1982 Tee OS, Trani M, McClelland RA, Seaman NE. Observation of a tetrahedral intermediate and its anion in a hydrolysis reaction. Ring opening of a quinazolinium ion Journal of the American Chemical Society. 104: 7219-7224. DOI: 10.1021/Ja00389A053  0.671
1982 McClelland RA, Somani R. Kinetic analysis of the ring opening of an N-alkyloxazolidine. Hydrolysis of 2-(4-methylphenyl)-2,3-dimethyl-1,3-oxazolidine Cheminform. 13. DOI: 10.1002/Chin.198215125  0.305
1982 Mcclelland RA, Patel G, Cirinna C. Hydrolysis Of Spirobicyclic Oxyphosphoranes. Associative And Dissociative Reactions Cheminform. 13. DOI: 10.1002/Chin.198205090  0.307
1981 McClelland RA, Alibhai M. The tetrahedral intermediate of a lactonization reaction Canadian Journal of Chemistry. 59: 1169-1176. DOI: 10.1139/V81-171  0.438
1981 McClelland RA, Somani R. Kinetic analysis of the ring opening of an N-alkyloxazolidine. Hydrolysis of 2-(4-methylphenyl)-2,3-dimethyl-1,3-oxazolidine Journal of Organic Chemistry. 46: 4345-4350. DOI: 10.1021/Jo00335A004  0.305
1981 McClelland RA, Patel G, Lam PWK. Synthesis of aryl ortho esters from benzanilide acetals Journal of Organic Chemistry. 12: 1011-1012. DOI: 10.1021/Jo00318A032  0.302
1981 McClelland RA, Gedge S, Bohonek J. Nature of the slow step in the hydrolysis of cyclic and bicyclic ortho esters containing 1,3-dioxane rings Journal of Organic Chemistry. 46: 886-891. DOI: 10.1021/Jo00318A013  0.333
1981 McClelland RA, Patel G. Rate and equilibrium constants for the formation and decomposition of the tetrahedral intermediate of the methanolysis of methyl benzoates Journal of the American Chemical Society. 103: 6912-6915. DOI: 10.1021/Ja00413A025  0.322
1981 McClelland RA, Patel G. Kinetics and mechanism of the hydrolysis of anilide acetals Journal of the American Chemical Society. 103: 6908-6911. DOI: 10.1021/Ja00413A024  0.307
1981 McClelland RA, Patel G, Cirinna C. Hydrolysis of spirobicyclic oxyphosphoranes. Associative and dissociative reactions Journal of the American Chemical Society. 103: 6432-6436. DOI: 10.1021/Ja00411A029  0.307
1981 McClelland RA, Gedge S, Bohonek J. Nature of the slow step in the hydrolysis of cyclic and bicyclic ortho esters containing 1,3-dioxane rings Cheminform. 12. DOI: 10.1002/Chin.198128116  0.333
1980 McClelland RA, Potter JP. The partitioning of tetrahedral intermediates of the hydrolysis of benzimidatonium ions in acid solutions Canadian Journal of Chemistry. 58: 2318-2325. DOI: 10.1139/V80-374  0.426
1980 McClelland RA. Oxygen exchange in methanol in acid solutions. Transition state activity coefficients Canadian Journal of Chemistry. 58: 393-398. DOI: 10.1139/V80-063  0.343
1980 McClelland RA, Leung M. Mechanism of hydrolysis of aryl vinyl selenides. Selenium-stabilized carbonium ions Journal of Organic Chemistry. 45: 187-189. DOI: 10.1021/Jo01289A046  0.368
1980 McClelland RA, Gedge S. Hydration of the flavylium ion Journal of the American Chemical Society. 102: 5838-5848. DOI: 10.1021/Ja00538A024  0.34
1979 McClelland RA, Reynolds WF. Hydrogen exchange and isomerization in ortho substituted benzamides. On the question of free rotation in an N-protonated amide Canadian Journal of Chemistry. 57: 2896-2901. DOI: 10.1139/V79-473  0.351
1979 McClelland RA, Ahmad M, Bohonek J, Gedge S. Carbonyl oxygen exchange of glycol monoesters. Rate and equilibrium constants for the formation of a tetrahedral intermediate Canadian Journal of Chemistry. 57: 1531-1540. DOI: 10.1139/V79-250  0.448
1979 McClelland RA, Ahmad M. Amide acetal hydrolysis. 2-Aryl-2-(N,N-dimethylamino)-1,3-dioxolanes. Rapid and reversible ring opening in neutral and basic solutions. Rate-determining decomposition of hydrogen ortho esters in acidic solutions Journal of Organic Chemistry. 44: 1855-1860. DOI: 10.1021/Jo01325A024  0.356
1979 Csizmadia VM, Koshy KM, Lau KCM, McClelland RA, Nowlan VJ, Tidwell TT. Acid-catalyzed hydrolysis of N-vinylacetamides (enamides). Substituent effects of the acetamido and amino groups and linear free energy correlations of cyclohexene reactivities Journal of the American Chemical Society. 101: 974-979. DOI: 10.1021/Ja00498A029  0.311
1979 McClelland RA, Ahmad M, Mandrapilias G. The reversibility of the ring-opening step in the hydrolysis of tropone ethylene ketal and tropone trimethylene ketal Journal of the American Chemical Society. 101: 970-974. DOI: 10.1021/Ja00498A028  0.311
1979 McClelland RA, Ahmad M. Amide acetal hydrolysis. 2-Aryl-2-(N,N-dimethylamino)-1,3-dioxolanes. Rapid and reversible ring opening in neutral and basic solutions. Rate-determining decomposition of hydrogen ortho esters in acidic solutions Cheminform. 10. DOI: 10.1002/Chin.197938163  0.356
1979 Csizmadia VM, Koshy KM, Lau KCM, McClelland RA, Nowlan VJ, Tidwell TT. Acid-catalyzed hydrolysis of N-vinylacetamides (enamides). Substituent effects of the acetamido and amino groups and linear free energy correlations of cyclohexene reactivities Cheminform. 10. DOI: 10.1002/Chin.197921111  0.311
1979 McClelland RA, Ahmad M, Mandrapilias G. The reversibility of the ring-opening step in the hydrolysis of tropone ethylene ketal and tropone trimethylene ketal Cheminform. 10. DOI: 10.1002/Chin.197921110  0.311
1979 Mcclelland RA, Ahmad M. The Reactivity Of Oxocarbonium Ions. 1. Detection As Transient Intermediates In The Hydrolysis Of Ketals And Ortho Esters Cheminform. 10. DOI: 10.1002/Chin.197905106  0.388
1978 McClelland RA, Ahmad M. The reactivity of oxocarbonium ions. 2. Hydrolysis in sulfuric acid solutions and estimates of reactivity in water Journal of the American Chemical Society. 100: 7031-7036. DOI: 10.1021/Ja00490A042  0.375
1978 McClelland RA, Ahmad M. The reactivity of oxocarbonium ions. 1. Detection as transient intermediates in the hydrolysis of ketals and ortho esters Journal of the American Chemical Society. 100: 7027-7031. DOI: 10.1021/Ja00490A041  0.388
1977 McClelland RA. Vinyl sulfide hydrolysis Canadian Journal of Chemistry. 55: 548-551. DOI: 10.1139/V77-076  0.42
1977 McClelland RA, Ahmad M. Dialkoxycarbonium ions as ambident electrophiles in their hydrolysis in aqueous sulfuric acid solutions Journal of the American Chemical Society. 99: 5356-5360. DOI: 10.1021/Ja00458A021  0.401
1977 McClelland RA, Ahmad M. Dialkoxycarbonium ions as ambident electrophiles in their hydrolysis in aqueous sulfuric acid solutions Cheminform. 8. DOI: 10.1002/Chin.197745149  0.401
1976 McClelland RA, Reynolds WF. A 13C nuclear magnetic resonance study of aliphatic ketone protonation in sulfuric acid solutions Canadian Journal of Chemistry. 54: 718-725. DOI: 10.1139/V76-104  0.344
1975 McClelland RA. Mechanisms of Thioacylal Hydrolysis in Sulfuric Acid Solutions Canadian Journal of Chemistry. 53: 2763-2771. DOI: 10.1139/V75-392  0.384
1975 Mcclelland RA. Benzamide oxygen exchange concurrent with acid hydrolysis Journal of the American Chemical Society. 97: 5281-5282. DOI: 10.1021/Ja00851A045  0.319
1975 McClelland RA, Modro TA, Goldman MF, Yates K. Transition state activity coefficients in the acid-catalyzed hydrolysis of esters Canadian Journal of Chemistry. 55: 3050-3057. DOI: 10.1021/Ja00851A033  0.556
1975 Mcclelland RA. AAl2 Hydrolysis of 2,6-dimethylbenzimidate esters in sulfuric acid solutions Journal of the American Chemical Society. 97: 3177-3181. DOI: 10.1021/Ja00844A042  0.331
1975 Mcclelland RA. Mechanisms Of Acylal And Thioacylal Hydrolysis In Sulfuric Acid Solutions Cheminform. 6. DOI: 10.1002/Chin.197551112  0.332
1975 Mcclelland RA, Modro TA, Goldman MF, Yates K. Transition State Activity Coefficients In The Acid-Catalyzed Hydrolysis Of Esters Cheminform. 6. DOI: 10.1002/Chin.197546183  0.504
1974 Yates K, McClelland RA. Thermodynamics of Transfer of Organic Molecules from Water to Acid Solutions. The Effects of Nitro Substitution Canadian Journal of Chemistry. 52: 1098-1107. DOI: 10.1139/V74-174  0.538
1974 McClelland RA. Alkyl carbon-oxygen bond cleavage in the hydrolysis of imidate esters to amides in acid solution Journal of the American Chemical Society. 96: 3690-3691. DOI: 10.1021/Ja00818A074  0.322
1973 Yates K, McClelland RA. Hydronium ion activity in strongly acidic media. Remarkable agreement between independent estimates Journal of the American Chemical Society. 95: 3055-3057. DOI: 10.1021/Ja00790A076  0.535
1973 Yates K, Wai H, Welch G, McClelland RA. Medium dependence of acidity functions and activity coefficients in perchloric acid Journal of the American Chemical Society. 95: 418-426. DOI: 10.1021/Ja00783A018  0.497
1973 Yates K, Wai H, Welch G, Mcclelland RA. Medium-Abhaengigkeit Von Aciditaetsfunktionen Und Aktivitaetskoeffizienten In Perchlorsaeure Cheminform. 4. DOI: 10.1002/Chin.197329118  0.439
1973 Yates K, Mcclelland RA. Hydroniumionenaktivitaet In Stark Sauren Medien, Bemerkenswerte Uebereinstimmung Zwischen Unabhaengigen Bestimmungen Cheminform. 4. DOI: 10.1002/Chin.197327025  0.453
1969 Hopkinson AC, McClelland RA, Yates K, Csizmadia IG. An attempted application of the extended hückel molecular orbital approach to reactions involving charged species Theoretical Chemistry Accounts. 13: 65-78. DOI: 10.1007/Bf00527320  0.52
1967 Yates K, McClelland RA. Mechanisms of ester hydrolysis in aqueous sulfuric acids Journal of the American Chemical Society. 89: 2686-2692. DOI: 10.1021/Ja00987A033  0.537
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