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Douglas Stephan, Ph.D. - Publications

Affiliations: 
Chemistry University of Toronto, Toronto, ON, Canada 
Website:
http://www.chem.utoronto.ca/ppl/faculty_profile.php?id=168
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283 high-probability publications. We are testing a new system for linking publications to authors. You can help! If you notice any inaccuracies, please sign in and mark papers as correct or incorrect matches. If you identify any major omissions or other inaccuracies in the publication list, please let us know.

Year Citation  Score
2024 Thomson J, Michailovich S, Miao L, Farrell JM, Murray JA, Lough A, Stephan DW. Triple -substitution reactions of B(CF) and [(CF)PF] with P(SiMe). Dalton Transactions (Cambridge, England : 2003). PMID 38465721 DOI: 10.1039/d4dt00251b  0.67
2023 Ju S, Zhang C, Tang B, Liu LL, Stephan DW, Wu Y. The Lewis superacidic aluminium cation: [(NHC)Al(CF)]. Chemical Communications (Cambridge, England). PMID 38111304 DOI: 10.1039/d3cc05440c  0.631
2023 Yeganeh-Salman A, Yeung J, Miao L, Stephan DW. Coordination chemistry and FLP reactivity of 1,1- and 1,2-bis-boranes. Dalton Transactions (Cambridge, England : 2003). PMID 38108120 DOI: 10.1039/d3dt03660j  0.364
2023 Bedi V, Mandal D, Hussain Z, Chen SM, Wu Y, Qu ZW, Grimme S, Stephan DW. The impact of Lewis acid variation on reactions with di--butyl diazo diesters. Dalton Transactions (Cambridge, England : 2003). PMID 38093643 DOI: 10.1039/d3dt03506a  0.304
2023 Luo YA, Zhao Z, Chen T, Li Y, Zhao Y, Stephan DW, Wu Y. Stannyl phosphaketene as a synthon for phosphorus analogues of β-lactams. Chemical Communications (Cambridge, England). PMID 37608644 DOI: 10.1039/d3cc03117a  0.468
2023 Hussain Z, Luo YA, Wu Y, Qu ZW, Grimme S, Stephan DW. Reactivity of frustrated Lewis pairs with BOC protected diazocarboxylates: FLP capture of diazene. Chemical Communications (Cambridge, England). PMID 37093155 DOI: 10.1039/d3cc01571h  0.308
2023 Kim H, Stephan DW. Reactive FLP-alkyne addition products: a route to anionic and zwitterionic phosphines. Dalton Transactions (Cambridge, England : 2003). PMID 37017137 DOI: 10.1039/d3dt00607g  0.37
2023 Chen T, Mei Y, Liu LL, Zhao Y, Wu Y, Stephan DW. Alkoxyphosphorane /Borane Cooperative alkylations: A Frustrated Lewis Pair Version of the Mitsunobu Reaction. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 36715454 DOI: 10.1002/chem.202300264  0.686
2022 Tan J, Hu C, Yang X, Ju S, Cao LL, Wu Y, Liu LL, Stephan DW. Structure and reactivity studies of the aluminum analogue of Piers' borane [HAl(CF)]. Chemical Communications (Cambridge, England). PMID 36484802 DOI: 10.1039/d2cc06075b  0.595
2022 Zhao Z, Tan J, Chen T, Hussain Z, Li Y, Wu Y, Stephan DW. Ambiphilic Behavior of Ge(II)-Pseudohalides in Inter- and Intramolecular Frustrated Lewis Pair Alkyne Addition Reactions. Inorganic Chemistry. PMID 36346947 DOI: 10.1021/acs.inorgchem.2c03171  0.356
2022 Wu Y, Zhao Z, Chen T, Tan J, Qu ZW, Grimme S, Zhao Y, Stephan DW. The Varied Frustrated Lewis Pair Reactivity of the Germylene Phosphaketene (CH{(CMe)(2,6- Pr C H N)} )GePCO. Chemistry (Weinheim An Der Bergstrasse, Germany). e202200666. PMID 35262970 DOI: 10.1002/chem.202200666  0.499
2022 Wang T, Xu M, Jupp AR, Chen SM, Qu ZW, Grimme S, Stephan DW. Frustrated Lewis pair catalyzed hydrodehalogenation of benzyl-halides. Chemical Communications (Cambridge, England). PMID 34981087 DOI: 10.1039/d1cc05943b  0.331
2021 Wang T, Xu M, Jupp A, Qu ZW, Grimme S, Stephan DW. Steric Influence on Reactions of Benzyl Potassium Species with CO. Chemistry, An Asian Journal. PMID 34592053 DOI: 10.1002/asia.202101127  0.314
2021 Stephan DW, Burton KI, Elser I, Waked AE, Wagener T, Andrews RJ, Glorius F. Bipyridinium and Phenanthrolinium Dications for Metal-Free Hydrodefluorination: Distinctive Carbon-Based Reactivity. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 34107119 DOI: 10.1002/chem.202101534  0.316
2021 Yang X, Wei R, Shi Y, Liu LL, Wu Y, Zhao Y, Stephan DW. Oxyphosphoranes as precursors to bridging phosphate-catecholate ligands. Chemical Communications (Cambridge, England). PMID 33439178 DOI: 10.1039/d0cc07736d  0.654
2020 Bamford KL, Stephan DW. Insertion reactions of the C-B-N-substituted borinium cation [MesBNPr]. Dalton Transactions (Cambridge, England : 2003). PMID 33231245 DOI: 10.1039/d0dt03665j  0.33
2020 Zhu D, Qu ZW, Zhou J, Stephan DW. The Reactivity of Isomeric Nitrenium Lewis Acids with Phosphines, Carbenes and Phosphide. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 33137240 DOI: 10.1002/chem.202004798  0.627
2020 Zhou J, Kim H, Liu LL, Cao LL, Stephan DW. An arene-stabilized η-pentamethylcyclopentadienyl antimony dication acts as a source of Sb or Sb cations. Chemical Communications (Cambridge, England). PMID 32985631 DOI: 10.1039/D0Cc02710C  0.746
2020 Guddorf BJ, Hepp A, Daniliuc C, Stephan DW, Lips F. An intermolecular FLP System derived from an NHC-coordinated trisilacyclopropylidene. Dalton Transactions (Cambridge, England : 2003). 49: 13386-13392. PMID 32955533 DOI: 10.1039/D0Dt02797A  0.3
2020 Murphy MC, Trofimova A, LaFortune JHW, Vogels CM, Geier SJ, Binder JF, Macdonald CLB, Stephan DW, Westcott SA. The phosphinoboration of acyl chlorides. Dalton Transactions (Cambridge, England : 2003). PMID 32167110 DOI: 10.1039/D0Dt00579G  0.331
2020 Lam J, Cao LL, Farrell JM, Stephan DW. Reactions of carbene-stabilized borenium cations. Dalton Transactions (Cambridge, England : 2003). PMID 31965118 DOI: 10.1039/C9Dt04731J  0.665
2020 Guo J, Cheong O, Bamford KL, Zhou J, Stephan DW. Frustrated Lewis pair-catalyzed double hydroarylation of alkynes with N-substituted pyrroles. Chemical Communications (Cambridge, England). PMID 31950939 DOI: 10.1039/C9Cc08654D  0.617
2020 Briceno-Strocchia AI, Johnstone TC, Stephan DW. Using frustrated Lewis pairs to explore C-F bond activation. Dalton Transactions (Cambridge, England : 2003). PMID 31912805 DOI: 10.1039/C9Dt04588K  0.339
2019 Zhu D, Qu ZW, Stephan DW. Addition reactions and diazomethane capture by the intramolecular P-O-B FLP: tBuPOBcat. Dalton Transactions (Cambridge, England : 2003). PMID 31859700 DOI: 10.1039/C9Dt04560K  0.301
2019 Stephan DW, Zhou J, Liu LL, Cao LL. Base-Stabilized [PO]+/[PO2]+ Cations. Angewandte Chemie (International Ed. in English). PMID 31609496 DOI: 10.1002/Anie.201912009  0.729
2019 Cao L, Zhou J, Qu ZW, Stephan DW. Single Electron Transfer to Diazomethane-Borane Adducts Prompts C-H Bond Activations. Angewandte Chemie (International Ed. in English). PMID 31589360 DOI: 10.1002/Anie.201912338  0.648
2019 Liu LL, Zhou J, Cao LL, Stephan DW. Phosphaaluminirenes: Synthons for Main Group Heterocycles. Journal of the American Chemical Society. PMID 31557435 DOI: 10.1021/Jacs.9B09330  0.737
2019 Liu LL, Zhou J, Kim Y, Cao LL, Stephan DW. Oligomerization of phosphaalkynes mediated by bulky N-heterocyclic carbenes: avenues to novel phosphorus frameworks. Dalton Transactions (Cambridge, England : 2003). PMID 31453597 DOI: 10.1039/C9Dt03185E  0.749
2019 Waked AE, Chitnis SS, Stephan DW. P(v) dications: carbon-based Lewis acid initiators for hydrodefluorination. Chemical Communications (Cambridge, England). PMID 31290494 DOI: 10.1039/C9Cc04010B  0.68
2019 Liu LL, Zhou J, Cao LL, Kim Y, Stephan DW. Reversible Intramolecular Cycloaddition of Phosphaalkene to an Arene Ring. Journal of the American Chemical Society. PMID 31055918 DOI: 10.1021/Jacs.9B03721  0.736
2019 Andrews RJ, Chitnis SS, Stephan DW. Carbonyl and olefin hydrosilylation mediated by an air-stable phosphorus(iii) dication under mild conditions. Chemical Communications (Cambridge, England). PMID 31020971 DOI: 10.1039/C9Cc02460C  0.691
2019 Kim Y, Liu L, Stephan DW. N-Heterocyclic Carbene Derived 3-Azabutadiene as a π-Base in Classic and Frustrated Lewis Pair Chemistry. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 30968983 DOI: 10.1002/Chem.201901609  0.641
2019 Bamford KL, Qu ZW, Stephan DW. Activation of H and EtSiH by the Borinium Cation [MesB]: Avenues to Cations [MesB(μ-H)(μ-Mes)BMes] and [HB(μ-H)(μ-Mes)B(μ-Mes)(μ-H)BH]. Journal of the American Chemical Society. 141: 6180-6184. PMID 30943365 DOI: 10.1021/Jacs.9B02510  0.31
2019 Xu M, Jupp A, Ong M, Burton K, Chitnis S, Stephan DW. Synthesis of Urea Derivatives from CO2 and Silylamines. Angewandte Chemie (International Ed. in English). PMID 30821888 DOI: 10.1002/Anie.201900058  0.7
2019 Zhou J, Liu L, Cao L, Stephan DW. The Arene-Stabilized η5-Pentamethylcyclopentadienyl Arsenic Dication [(η5-Cp*)As(toluene)]2. Angewandte Chemie (International Ed. in English). PMID 30802353 DOI: 10.1002/Anie.201902039  0.765
2019 Liu LL, Stephan DW. Radicals derived from Lewis acid/base pairs. Chemical Society Reviews. PMID 30724924 DOI: 10.1039/C8Cs00940F  0.563
2019 Zhu D, LaFortune JHW, Melen RL, Stephan DW. Electrophilic boron carboxylate and phosphinate complexes. Dalton Transactions (Cambridge, England : 2003). PMID 30656327 DOI: 10.1039/C8Dt04818E  0.627
2019 Süsse L, LaFortune JHW, Stephan DW, Oestreich M. Axially Chiral, Electrophilic Fluorophosphonium Cations: Synthesis, Lewis Acidity, and Reactivity in the Hydrosilylation of Ketones Organometallics. 38: 712-721. DOI: 10.1021/Acs.Organomet.8B00912  0.489
2019 Zhou J, Liu LL, Cao LL, Stephan DW. The Arene‐Stabilized η 5 ‐Pentamethylcyclopentadienyl Arsenic Dication [(η 5 ‐Cp*)As(toluene)] 2+ Angewandte Chemie. 131: 5461-5466. DOI: 10.1002/Ange.201902039  0.718
2018 Lam J, Sampaolesi S, LaFortune JHW, Coe JW, Stephan DW. Design considerations for chiral frustrated Lewis pairs: B/N FLPs derived from 3,5-bicyclic aryl piperidines. Dalton Transactions (Cambridge, England : 2003). 48: 133-141. PMID 30484790 DOI: 10.1039/C8Dt04070B  0.327
2018 Liu L, Cao L, Zhou J, Stephan DW. Facile Cleavage of the P=P Double Bond in Vinyl-Substituted Diphosphenes. Angewandte Chemie (International Ed. in English). PMID 30444313 DOI: 10.1002/Anie.201812592  0.732
2018 Bamford K, Chitnis S, Qu ZW, Stephan DW. Interactions of C-F bonds with hydridoboranes: Reduction, Borylation and Friedel-Crafts Alkylation. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 30222215 DOI: 10.1002/Chem.201804705  0.678
2018 Schneider C, LaFortune JHW, Melen RL, Stephan DW. Lewis and Brønsted basicity of phosphine-diazomethane derivatives. Dalton Transactions (Cambridge, England : 2003). PMID 30151513 DOI: 10.1039/C8Dt02420K  0.62
2018 LaFortune JHW, Szkop KM, Farinha FE, Johnstone TC, Postle S, Stephan DW. Probing steric influences on electrophilic phosphonium cations: a comparison of [(3,5-(CF)CH)PF] and [(CF)PF]. Dalton Transactions (Cambridge, England : 2003). PMID 30063062 DOI: 10.1039/C8Dt02594K  0.323
2018 Liu LL, Zhou J, Andrews R, Stephan DW. A Room-Temperature-Stable Phosphanorcaradiene. Journal of the American Chemical Society. PMID 29860832 DOI: 10.1021/Jacs.8B04930  0.738
2018 Liu LL, Cao LL, Zhu D, Zhou J, Stephan DW. Homolytic cleavage of peroxide bonds via a single electron transfer of a frustrated Lewis pair. Chemical Communications (Cambridge, England). PMID 29781011 DOI: 10.1039/C8Cc03522A  0.746
2018 Zhou J, Liu L, Cao L, Stephan DW. Reductive Coupling and Loss of N2 from Magnesium Diazomethane Derivatives. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 29719075 DOI: 10.1002/Chem.201802138  0.716
2018 Eaton SS, Ngendahimana T, Eaton GR, Jupp AR, Stephan DW. Electron paramagnetic resonance of aB-containing heterocyclic radical. Journal of Magnetic Resonance (San Diego, Calif. : 1997). 290: 76-84. PMID 29579535 DOI: 10.1016/J.Jmr.2018.03.007  0.389
2018 Chitnis S, Krischer F, Stephan DW. Catalytic hydrodefluorination of C-F bonds by an air-stable P(III) Lewis acid. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 29575313 DOI: 10.1002/Chem.201801305  0.726
2018 Zhou J, Liu LL, Cao LL, Stephan DW. An umpolung of Lewis acidity/basicity at nitrogen by deprotonation of a cyclic (amino)(aryl)nitrenium cation. Chemical Communications (Cambridge, England). PMID 29527605 DOI: 10.1039/C8Cc01331D  0.717
2018 Cao L, Bamford K, Liu L, Stephan DW. Zinc-Containing Radical Anions via Single Electron Transfer to Donor-Acceptor Adducts. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 29411915 DOI: 10.1002/Chem.201800607  0.574
2018 Zhou J, Liu L, Cao L, Stephan DW. Nitrogen-Based Lewis Acids: Synthesis and Reactivity of A Cyclic (Alkyl)(Amino)Nitrenium Cation. Angewandte Chemie (International Ed. in English). PMID 29397010 DOI: 10.1002/Anie.201713118  0.726
2018 Chitnis SS, LaFortune JHW, Cummings H, Liu LL, Andrews R, Stephan DW. Phosphorus Coordination Chemistry in Catalysis: Air Stable P(III)-Dications as Lewis Acid Catalysts for the Allylation of C–F Bonds Organometallics. 37: 4540-4544. DOI: 10.1021/Acs.Organomet.8B00686  0.774
2018 Vogler M, Süsse L, LaFortune JHW, Stephan DW, Oestreich M. Electrophilic Phosphonium Cations as Lewis Acid Catalysts in Diels–Alder Reactions and Nazarov Cyclizations Organometallics. 37: 3303-3313. DOI: 10.1021/acs.organomet.8b00496  0.441
2018 Zhou J, Liu LL, Cao LL, Stephan DW. A Phosphorus Lewis Super Acid: η5-Pentamethylcyclopentadienyl Phosphorus Dication Chem. 4: 2699-2708. DOI: 10.1016/J.Chempr.2018.08.038  0.752
2018 Zhou J, Liu LL, Cao LL, Stephan DW. Cover Feature: Reductive Coupling and Loss of N2 from Magnesium Diazomethane Derivatives (Chem. Eur. J. 34/2018) Chemistry - a European Journal. 24: 8455-8455. DOI: 10.1002/Chem.201802732  0.685
2018 Zhou J, Liu LL, Cao LL, Stephan DW. Frontispiece: Nitrogen-Based Lewis Acids: Synthesis and Reactivity of a Cyclic (Alkyl)(Amino)Nitrenium Cation Angewandte Chemie International Edition. 57. DOI: 10.1002/Anie.201881361  0.712
2017 Liu LL, Zhou J, Cao LL, Andrews R, Falconer R, Russell CA, Stephan DW. A Transient Vinylphosphinidene via a Phosphirene-Phosphinidene Rearrangement. Journal of the American Chemical Society. PMID 29272583 DOI: 10.1021/Jacs.7B11791  0.752
2017 Liu LL, Stephan DW. An imine-gallium Lewis pair stabilized oxophosphinidene via an unexpected phosphirene rearrangement. Chemical Communications (Cambridge, England). PMID 29271427 DOI: 10.1039/C7Cc09090K  0.586
2017 Tsao FA, Stephan DW. Synthesis and reactions of 4H-1,4-telluraborine. Chemical Communications (Cambridge, England). PMID 29230466 DOI: 10.1039/C7Cc08765A  0.311
2017 LaFortune JHW, Bayne JM, Johnstone TC, Fan L, Stephan DW. Catalytic double hydroarylation of alkynes to 9,9-disubstituted 9,10-dihydroacridine derivatives by an electrophilic phenoxyphosphonium dication. Chemical Communications (Cambridge, England). PMID 29139487 DOI: 10.1039/C7Cc08037A  0.304
2017 Barrado AG, Bayne JM, Johnstone TC, Lehmann CW, Stephan DW, Alcarazo M. Dicationic phosphonium salts: Lewis acid initiators for the Mukaiyama-aldol reaction. Dalton Transactions (Cambridge, England : 2003). PMID 29134217 DOI: 10.1039/C7Dt03197A  0.314
2017 Tang C, Liang Q, Jupp A, Johnstone T, Neu R, Song D, Grimme S, Stephan DW. 1,1-Hydroboration and Borane Adduct of Diphenyldiazomethane: A Prelude to FLP-N2 Chemistry? Angewandte Chemie (International Ed. in English). PMID 29108092 DOI: 10.1002/Anie.201710337  0.806
2017 Mehta M, Johnstone TC, Lam J, Bagh B, Hermannsdorfer A, Driess M, Stephan DW. Synthesis and oxidation of phosphine cations. Dalton Transactions (Cambridge, England : 2003). PMID 28981130 DOI: 10.1039/C7Dt03175K  0.747
2017 Liu LL, Cao LL, Shao Y, Stephan DW. Single Electron Delivery to Lewis Pairs: An Avenue to Anions by Small Molecule Activation. Journal of the American Chemical Society. PMID 28654746 DOI: 10.1021/Jacs.7B05120  0.582
2017 Mallov I, Johnstone TC, Burns DC, Stephan DW. A model for C-F activation by electrophilic phosphonium cations. Chemical Communications (Cambridge, England). PMID 28632273 DOI: 10.1039/C7Cc04057A  0.307
2017 Zhou J, Cao LL, Liu LL, Stephan DW. FLP reactivity of [Ph3C](+) and (o-tolyl)3P and the capture of a Staudinger reaction intermediate. Dalton Transactions (Cambridge, England : 2003). PMID 28548663 DOI: 10.1039/C7Dt01726J  0.733
2017 Tsao FA, Stephan DW. Facile access to unsymmetrically substituted tellurium-boron based heterocycles. Chemical Communications (Cambridge, England). PMID 28548160 DOI: 10.1039/C7Cc03648E  0.31
2017 Bamford KL, Longobardi LE, Liu L, Grimme S, Stephan DW. FLP reduction and hydroboration of phenanthrene o-iminoquinones and α-diimines. Dalton Transactions (Cambridge, England : 2003). PMID 28382362 DOI: 10.1039/C7Dt01024A  0.307
2017 Szkop KM, Stephan DW. Metal-free pincer ligand chemistry polycationic phosphonium Lewis acids. Dalton Transactions (Cambridge, England : 2003). PMID 28265626 DOI: 10.1039/C7Dt00441A  0.36
2017 Liu LL, Zhu D, Cao LL, Stephan DW. N-Heterocyclic carbene stabilized parent sulfenyl, selenenyl, and tellurenyl cations (XH(+), X = S, Se, Te). Dalton Transactions (Cambridge, England : 2003). PMID 28145552 DOI: 10.1039/C7Dt00186J  0.549
2017 Liu L(, Cao LL, Shao Y, Ménard G, Stephan DW. A Radical Mechanism for Frustrated Lewis Pair Reactivity Chem. 3: 259-267. DOI: 10.1016/J.Chempr.2017.05.022  0.742
2017 Caputo CB, Stephan DW. Non-conventional Lewis acids and bases in frustrated Lewis pair chemistry Structure and Bonding. 171. DOI: 10.1007/430_2015_177  0.619
2016 Eaton SS, Huber K, Elajaili H, McPeak J, Eaton GR, Longobardi LE, Stephan DW. Electron spin relaxation of a boron-containing heterocyclic radical. Journal of Magnetic Resonance (San Diego, Calif. : 1997). 276: 7-13. PMID 28081476 DOI: 10.1016/J.Jmr.2016.12.013  0.416
2016 Longobardi LE, Zatsepin P, Korol R, Liu L, Grimme S, Stephan DW. Reactions of Boron-Derived Radicals with Nucleophiles. Journal of the American Chemical Society. PMID 28026172 DOI: 10.1021/Jacs.6B11190  0.316
2016 LaFortune JH, Johnstone TC, Pérez M, Winkelhaus D, Podgorny V, Stephan DW. Electrophilic phenoxy-substituted phosphonium cations. Dalton Transactions (Cambridge, England : 2003). PMID 27785488 DOI: 10.1039/C6Dt03544B  0.316
2016 Lam J, Günther BA, Farrell JM, Eisenberger P, Bestvater BP, Newman PD, Melen RL, Crudden CM, Stephan DW. Chiral carbene-borane adducts: precursors for borenium catalysts for asymmetric FLP hydrogenations. Dalton Transactions (Cambridge, England : 2003). PMID 27383522 DOI: 10.1039/C6Dt02202B  0.752
2016 Postle S, Podgorny V, Stephan DW. Electrophilic phosphonium cations (EPCs) with perchlorinated-aryl substituents: towards air-stable phosphorus-based Lewis acid catalysts. Dalton Transactions (Cambridge, England : 2003). PMID 27140402 DOI: 10.1039/C6Dt01339B  0.309
2016 Pranckevicius C, Liu L, Bertrand G, Stephan DW. Synthesis of a Carbodicyclopropenylidene: A Carbodicarbene based Solely on Carbon. Angewandte Chemie (International Ed. in English). PMID 27028936 DOI: 10.1002/Anie.201600765  0.637
2016 Cao LL, Daley E, Johnstone TC, Stephan DW. Cationic aluminum hydride complexes: reactions of carbene-alane adducts with trityl-borate. Chemical Communications (Cambridge, England). PMID 27001908 DOI: 10.1039/C6Cc01585A  0.335
2016 Melen RL, Stephan DW. Main group transformations. Dalton Transactions (Cambridge, England : 2003). PMID 26997409 DOI: 10.1039/C6Dt90027E  0.489
2016 McKinty AM, Stephan DW. Ru alkylidene compounds bearing tridentate, dianionic ligands: Lewis acid activation and olefin metathesis. Dalton Transactions (Cambridge, England : 2003). PMID 26822161 DOI: 10.1039/C5Dt04481B  0.773
2016 Mehta M, Garcia De La Arada I, Perez M, Porwal D, Oestreich M, Stephan DW. Metal-Free Phosphine Oxide Reductions Catalyzed by B(C6F5)3 and Electrophilic Fluorophosphonium Cations Organometallics. 35: 1030-1035. DOI: 10.1021/Acs.Organomet.6B00158  0.46
2015 Farrell JM, Posaratnanathan RT, Stephan DW. A family of N-heterocyclic carbene-stabilized borenium ions for metal-free imine hydrogenation catalysis. Chemical Science. 6: 2010-2015. PMID 29449920 DOI: 10.1039/C4Sc03675A  0.65
2015 Zhu J, Pérez M, Caputo CB, Stephan DW. Use of Trifluoromethyl Groups for Catalytic Benzylation and Alkylation with Subsequent Hydrodefluorination. Angewandte Chemie (International Ed. in English). PMID 26663711 DOI: 10.1002/Anie.201510494  0.678
2015 Hansmann MM, Melen RL, Rudolph M, Rominger F, Wadepohl H, Stephan DW, Hashmi AS. Cyclopropanation / Carboboration Reactions of Enynes with B(C6F5)3. Journal of the American Chemical Society. PMID 26580316 DOI: 10.1021/Jacs.5B09311  0.655
2015 Farrell JM, Stephan DW. Synthesis of a diboryl-N-heterocycle and its conversion to a bidentate cationic Lewis acid. Chemical Communications (Cambridge, England). 51: 14322-5. PMID 26273801 DOI: 10.1039/C5Cc06248A  0.687
2015 Vom Stein T, Peréz M, Dobrovetsky R, Winkelhaus D, Caputo CB, Stephan DW. Electrophilic Fluorophosphonium Cations in Frustrated Lewis Pair Hydrogen Activation and Catalytic Hydrogenation of Olefins. Angewandte Chemie (International Ed. in English). 54: 10178-82. PMID 26178268 DOI: 10.1002/Anie.201504109  0.61
2015 Mahdi T, Stephan DW. Stoichiometric and catalytic inter- and intramolecular hydroamination of terminal alkynes by frustrated Lewis pairs. Chemistry (Weinheim An Der Bergstrasse, Germany). 21: 11134-42. PMID 26110237 DOI: 10.1002/Chem.201501535  0.338
2015 Eller C, Kehr G, Daniliuc CG, Stephan DW, Erker G. Thiophene synthesis via 1,1-carboboration. Chemical Communications (Cambridge, England). 51: 7226-9. PMID 25813555 DOI: 10.1039/C5Cc01806D  0.335
2015 Longobardi LE, Mahdi T, Stephan DW. B(C6F5)3 mediated arene hydrogenation/transannulation of para-methoxyanilines. Dalton Transactions (Cambridge, England : 2003). 44: 7114-7. PMID 25797146 DOI: 10.1039/C5Dt00921A  0.325
2015 Caputo CB, Winkelhaus D, Dobrovetsky R, Hounjet LJ, Stephan DW. Synthesis and Lewis acidity of fluorophosphonium cations. Dalton Transactions (Cambridge, England : 2003). 44: 12256-64. PMID 25785571 DOI: 10.1039/C5Dt00217F  0.669
2015 Pérez M, Qu ZW, Caputo CB, Podgorny V, Hounjet LJ, Hansen A, Dobrovetsky R, Grimme S, Stephan DW. Hydrosilylation of ketones, imines and nitriles catalysed by electrophilic phosphonium cations: functional group selectivity and mechanistic considerations. Chemistry (Weinheim An Der Bergstrasse, Germany). 21: 6491-500. PMID 25758303 DOI: 10.1002/Chem.201406356  0.66
2015 Farrell JM, Stephan DW. Planar N-heterocyclic carbene diarylborenium ions: synthesis by cationic borylation and reactivity with Lewis bases. Angewandte Chemie (International Ed. in English). 54: 5214-7. PMID 25756464 DOI: 10.1002/Anie.201500198  0.668
2015 Melen RL, Stephan DW. Cycloaddition reactions of (C6F5)2BN3 with dialkyl acetylenedicarboxylates. Dalton Transactions (Cambridge, England : 2003). 44: 5045-8. PMID 25687829 DOI: 10.1039/C5Dt00316D  0.615
2015 Dobrovetsky R, Takeuchi K, Stephan DW. Metal-free Lewis acid mediated dehydrocoupling of phosphines and concurrent hydrogenation. Chemical Communications (Cambridge, England). 51: 2396-8. PMID 25564430 DOI: 10.1039/C4Cc09526J  0.348
2015 Dahcheh F, Stephan DW. Bis-mixed-carbene ruthenium-thiolate-alkylidene complexes: synthesis and olefin metathesis activity. Dalton Transactions (Cambridge, England : 2003). 44: 1724-33. PMID 25462569 DOI: 10.1039/C4Dt03137G  0.788
2015 Holthausen MH, Colussi M, Stephan DW. B(C6F5)3-mediated transformations and hydrogenation of carbodiimides. Chemistry (Weinheim An Der Bergstrasse, Germany). 21: 2193-9. PMID 25428578 DOI: 10.1002/Chem.201405014  0.335
2015 Dahcheh F, Stephan DW, Bertrand G. Oxidative addition at a carbene center: synthesis of an iminoboryl-CAAC adduct. Chemistry (Weinheim An Der Bergstrasse, Germany). 21: 199-204. PMID 25414006 DOI: 10.1002/Chem.201405887  0.806
2015 Bagh B, McKinty AM, Lough AJ, Stephan DW. 1,2,3-Triazolylidene ruthenium(II)-cyclometalated complexes and olefin selective hydrogenation catalysis. Dalton Transactions (Cambridge, England : 2003). 44: 2712-23. PMID 25407939 DOI: 10.1039/C4Dt03156C  0.806
2015 Melen RL, Stephan DW. Cycloaddition reactions of (C6F5)2BN3 with dialkyl acetylenedicarboxylates Dalton Transactions. 44: 5045-5048. DOI: 10.1039/c5dt00316d  0.614
2015 Farrell JM, Posaratnanathan RT, Stephan DW. A family of N-heterocyclic carbene-stabilized borenium ions for metal-free imine hydrogenation catalysis Chemical Science. 6: 2010-2015. DOI: 10.1039/c4sc03675a  0.579
2015 Dahcheh F, Stephan DW. Bis-mixed-carbene ruthenium-thiolate-alkylidene complexes: Synthesis and olefin metathesis activity Dalton Transactions. 44: 1724-1733. DOI: 10.1039/c4dt03137g  0.788
2015 Melen RL, Wilkins LC, Kariuki BM, Wadepohl H, Gade LH, Hashmi ASK, Stephan DW, Hansmann MM. Diverging Pathways in the Activation of Allenes with Lewis Acids and Bases: Addition, 1,2-Carboboration, and Cyclization Organometallics. 34: 4127-4137. DOI: 10.1021/Acs.Organomet.5B00546  0.693
2015 Dahcheh F, Stephan DW, Bertrand G. Oxidative addition at a carbene center: Synthesis of an iminoboryl-CAAC adduct Chemistry - a European Journal. 21: 199-204. DOI: 10.1002/chem.201405887  0.769
2015 Farrell JM, Stephan DW. Planar N-heterocyclic carbene diarylborenium ions: Synthesis by cationic borylation and reactivity with Lewis bases Angewandte Chemie - International Edition. 54: 5214-5217. DOI: 10.1002/anie.201500198  0.59
2014 Dahcheh F, Martin D, Stephan DW, Bertrand G. Synthesis and reactivity of a CAAC-aminoborylene adduct: a hetero-allene or an organoboron isoelectronic with singlet carbenes. Angewandte Chemie (International Ed. in English). 53: 13159-63. PMID 25267591 DOI: 10.1002/Anie.201408371  0.789
2014 Longobardi LE, Tang C, Stephan DW. Stoichiometric reductions of alkyl-substituted ketones and aldehydes to borinic esters. Dalton Transactions (Cambridge, England : 2003). 43: 15723-6. PMID 25250629 DOI: 10.1039/C4Dt02648A  0.357
2014 Bagh B, Stephan DW. Half sandwich ruthenium(II) hydrides: hydrogenation of terminal, internal, cyclic and functionalized olefins. Dalton Transactions (Cambridge, England : 2003). 43: 15638-45. PMID 25208607 DOI: 10.1039/C4Dt02407A  0.743
2014 Ekkert O, Caputo CB, Pranckevicius C, Daniliuc CG, Kehr G, Erker G, Stephan DW. Reactivity of an intramolecular fluorophosphonium fluoroborate. Chemistry (Weinheim An Der Bergstrasse, Germany). 20: 11287-90. PMID 25065355 DOI: 10.1002/Chem.201403110  0.627
2014 Ekkert O, Caputo CB, Pranckevicius C, Daniliuc CG, Kehr G, Erker G, Stephan DW. Reactivity of an intramolecular fluorophosphonium fluoroborate. Chemistry (Weinheim An Der Bergstrasse, Germany). 20: 11287-90. PMID 25065355 DOI: 10.1002/Chem.201403110  0.627
2014 Pérez M, Caputo CB, Dobrovetsky R, Stephan DW. Metal-free transfer hydrogenation of olefins via dehydrocoupling catalysis. Proceedings of the National Academy of Sciences of the United States of America. 111: 10917-21. PMID 25002489 DOI: 10.1073/Pnas.1407484111  0.665
2014 Bagh B, McKinty AM, Lough AJ, Stephan DW. 1,2,3-Triazolylidene ruthenium(II)(η⁶-arene) complexes: synthesis, metallation and reactivity. Dalton Transactions (Cambridge, England : 2003). 43: 12842-50. PMID 24931360 DOI: 10.1039/C4Dt01174K  0.808
2014 Jochmann P, Stephan DW. Zincocene and dizincocene N-heterocyclic carbene complexes and catalytic hydrogenation of imines and ketones. Chemistry (Weinheim An Der Bergstrasse, Germany). 20: 8370-8. PMID 24861200 DOI: 10.1002/Chem.201402875  0.308
2014 Hansmann MM, Melen RL, Rominger F, Hashmi AS, Stephan DW. B(C₆F₅)₃ promoted cyclisation of internal propargyl esters: structural characterisation of 1,3-dioxolium compounds. Chemical Communications (Cambridge, England). 50: 7243-5. PMID 24817134 DOI: 10.1039/C4Cc01370K  0.603
2014 Hansmann MM, Melen RL, Rominger F, Hashmi AS, Stephan DW. B(C₆F₅)₃ promoted cyclisation of internal propargyl esters: structural characterisation of 1,3-dioxolium compounds. Chemical Communications (Cambridge, England). 50: 7243-5. PMID 24817134 DOI: 10.1039/C4Cc01370K  0.603
2014 Pranckevicius C, Stephan DW. Ruthenium complexes of an abnormally bound, anionic N-heterocyclic carbene. Chemistry (Weinheim An Der Bergstrasse, Germany). 20: 6597-602. PMID 24782270 DOI: 10.1002/Chem.201402080  0.321
2014 Winkelhaus D, Stephan DW. Boron perturbed click reactions prompt aromatic C-H activations. Angewandte Chemie (International Ed. in English). 53: 5414-7. PMID 24729472 DOI: 10.1002/Anie.201402567  0.32
2014 Boone MP, Stephan DW. Ru-η(6) -arene cations [{(Ph2 PC6 H4 )2 B(η(6) -Ph)}RuX](+) (X=Cl, H) as Lewis acids. Chemistry (Weinheim An Der Bergstrasse, Germany). 20: 3333-41. PMID 24616079 DOI: 10.1002/Chem.201304289  0.81
2014 Voicu D, Abolhasani M, Choueiri R, Lestari G, Seiler C, Menard G, Greener J, Guenther A, Stephan DW, Kumacheva E. Microfluidic studies of CO2 sequestration by frustrated Lewis pairs. Journal of the American Chemical Society. 136: 3875-80. PMID 24555752 DOI: 10.1021/Ja411601A  0.608
2014 Voicu D, Abolhasani M, Choueiri R, Lestari G, Seiler C, Menard G, Greener J, Guenther A, Stephan DW, Kumacheva E. Microfluidic studies of CO2 sequestration by frustrated Lewis pairs. Journal of the American Chemical Society. 136: 3875-80. PMID 24555752 DOI: 10.1021/Ja411601A  0.608
2014 Dahcheh F, Stephan DW. Reactions of ruthenium hydrides with ethyl-vinyl sulfide. Dalton Transactions (Cambridge, England : 2003). 43: 3501-7. PMID 24441082 DOI: 10.1039/C3Dt53326C  0.802
2014 McKinty AM, Stephan DW. A facile route to Ru-alkylidenes. Dalton Transactions (Cambridge, England : 2003). 43: 2710-2. PMID 24385088 DOI: 10.1039/C3Dt53525H  0.796
2014 Hansmann MM, Melen RL, Rominger F, Hashmi AS, Stephan DW. Activation of alkynes with B(C₆F₅)₃--boron allylation reagents derived from propargyl esters. Journal of the American Chemical Society. 136: 777-82. PMID 24354408 DOI: 10.1021/Ja4110842  0.659
2014 Hatnean JA, Thomson JW, Chase PA, Stephan DW. Imine hydrogenation by alkylaluminum catalysts. Chemical Communications (Cambridge, England). 50: 301-3. PMID 24247254 DOI: 10.1039/C3Cc47889K  0.601
2014 Bagh B, Stephan DW. Half sandwich ruthenium(ii) hydrides: Hydrogenation of terminal, internal, cyclic and functionalized olefins Dalton Transactions. 43: 15638-15645. DOI: 10.1039/c4dt02407a  0.696
2014 Bagh B, McKinty AM, Lough AJ, Stephan DW. 1,2,3-Triazolylidene ruthenium(ii)(η6-arene) complexes: Synthesis, metallation and reactivity Dalton Transactions. 43: 12842-12850. DOI: 10.1039/c4dt01174k  0.781
2014 McKinty AM, Stephan DW. A facile route to Ru-alkylidenes Dalton Transactions. 43: 2710-2712. DOI: 10.1039/c3dt53525h  0.777
2014 Dahcheh F, Stephan DW. Reactions of ruthenium hydrides with ethyl-vinyl sulfide Dalton Transactions. 43: 3501-3507. DOI: 10.1039/c3dt53326c  0.768
2014 Hatnean JA, Thomson JW, Chase PA, Stephan DW. Imine hydrogenation by alkylaluminum catalysts Chemical Communications. 50: 301-303. DOI: 10.1039/c3cc47889k  0.586
2014 Hansmann MM, Rominger F, Boone MP, Stephan DW, Hashmi ASK. Reactivity of organogold compounds with B(C6F5)3: Gold-boron transmetalation via σ-B/π-Au species Organometallics. 33: 4461-4470. DOI: 10.1021/Om5006885  0.803
2014 Sgro MJ, Dahcheh F, Stephan DW. Synthesis and reactivity of ruthenium hydride complexes containing a tripodal aminophosphine ligand Organometallics. 33: 578-586. DOI: 10.1021/Om4011388  0.766
2014 Boone MP, Stephan DW. Ancillary metal centers in frustrated lewis pair chemistry: Ruthenium acetylide as a lewis base in the activation of CO2, aldehyde, and alkyne Organometallics. 33: 387-393. DOI: 10.1021/Om401118N  0.811
2014 Hansmann MM, Melen RL, Rominger F, Hashmi ASK, Stephan DW. ChemInform Abstract: Activation of Alkynes with B(C6F5)3- Boron Allylation Reagents Derived from Propargyl Esters. Cheminform. 45: no-no. DOI: 10.1002/chin.201430181  0.623
2014 Boone MP, Stephan DW. Cover Picture: Ru-η6-Arene Cations [{(Ph2PC6H4)2B(η6-Ph)}RuX]+(X=Cl, H) as Lewis Acids (Chem. Eur. J. 12/2014) Chemistry - a European Journal. 20: 3237-3237. DOI: 10.1002/Chem.201490046  0.798
2014 Boone MP, Stephan DW. Ru-η6-arene cations [{(Ph2PC6H 4)2B(η6-Ph)}RuX]+ (X=Cl, H) as Lewis acids Chemistry - a European Journal. 20: 3333-3341. DOI: 10.1002/chem.201304289  0.798
2014 Dahcheh F, Martin D, Stephan DW, Bertrand G. Synthesis and reactivity of a CAAC-aminoborylene adduct: A hetero-allene or an organoboron isoelectronic with singlet carbenes Angewandte Chemie - International Edition. 53: 13159-13163. DOI: 10.1002/anie.201408371  0.783
2013 Pérez M, Hounjet LJ, Caputo CB, Dobrovetsky R, Stephan DW. Olefin isomerization and hydrosilylation catalysis by Lewis acidic organofluorophosphonium salts. Journal of the American Chemical Society. 135: 18308-10. PMID 24256456 DOI: 10.1021/Ja410379X  0.68
2013 Pérez M, Hounjet LJ, Caputo CB, Dobrovetsky R, Stephan DW. Olefin isomerization and hydrosilylation catalysis by Lewis acidic organofluorophosphonium salts. Journal of the American Chemical Society. 135: 18308-10. PMID 24256456 DOI: 10.1021/Ja410379X  0.68
2013 Mahdi T, Stephan DW. Frustrated Lewis pair catalyzed hydroamination of terminal alkynes. Angewandte Chemie (International Ed. in English). 52: 12418-21. PMID 24115279 DOI: 10.1002/Anie.201307254  0.325
2013 Caputo CB, Hounjet LJ, Dobrovetsky R, Stephan DW. Lewis acidity of organofluorophosphonium salts: hydrodefluorination by a saturated acceptor. Science (New York, N.Y.). 341: 1374-7. PMID 24052304 DOI: 10.1126/Science.1241764  0.643
2013 Melen RL, Hansmann MM, Lough AJ, Hashmi AS, Stephan DW. Cyclisation versus 1,1-Carboboration: Reactions of B(C6F5)3 with Propargyl Amides. Chemistry (Weinheim An Der Bergstrasse, Germany). 19: 11928-38. PMID 23922200 DOI: 10.1002/Chem.201301899  0.653
2013 Ménard G, Tran L, Stephan DW. Activation of H2 using P/Al based frustrated Lewis pairs and reactions with olefins. Dalton Transactions (Cambridge, England : 2003). 42: 13685-91. PMID 23903205 DOI: 10.1039/C3Dt51739J  0.663
2013 Hounjet LJ, Bannwarth C, Garon CN, Caputo CB, Grimme S, Stephan DW. Combinations of ethers and B(C6F5)3 function as hydrogenation catalysts. Angewandte Chemie (International Ed. in English). 52: 7492-5. PMID 23775686 DOI: 10.1002/Anie.201303166  0.646
2013 Boone MP, Stephan DW. A Ru-η6-arene complex as a C-based Lewis acid in the activation of hydrogen and hydrogenation catalysis. Journal of the American Chemical Society. 135: 8508-11. PMID 23718884 DOI: 10.1021/Ja403912N  0.826
2013 Melen RL, Lough AJ, Stephan DW. Boron azides in Staudinger oxidations and cycloadditions. Dalton Transactions (Cambridge, England : 2003). 42: 8674-83. PMID 23652382 DOI: 10.1039/C3Dt50791B  0.652
2013 Ménard G, Hatnean JA, Cowley HJ, Lough AJ, Rawson JM, Stephan DW. C-H bond activation by radical ion pairs derived from R3P/Al(C6F5)3 frustrated Lewis pairs and N2O. Journal of the American Chemical Society. 135: 6446-9. PMID 23594345 DOI: 10.1021/Ja402964H  0.644
2013 Melen RL, Stephan DW. Cycloaddition reactions between dicyclohexylboron azide and alkynes. Dalton Transactions (Cambridge, England : 2003). 42: 4795-8. PMID 23436044 DOI: 10.1039/C3Dt00068K  0.6
2013 Ménard G, Stephan DW. CO2 reduction via aluminum complexes of ammonia boranes. Dalton Transactions (Cambridge, England : 2003). 42: 5447-53. PMID 23423186 DOI: 10.1039/C3Dt00098B  0.647
2013 Hounjet LJ, Caputo CB, Stephan DW. The Lewis acidity of fluorophosphonium salts: access to mixed valent phosphorus(III)/(V) species. Dalton Transactions (Cambridge, England : 2003). 42: 2629-35. PMID 23232443 DOI: 10.1039/C2Dt32711B  0.614
2013 Caputo CB, Zhu K, Vukotic VN, Loeb SJ, Stephan DW. Heterolytic activation of H2 using a mechanically interlocked molecule as a frustrated lewis base. Angewandte Chemie (International Ed. in English). 52: 960-3. PMID 23184655 DOI: 10.1002/Anie.201207783  0.574
2013 Neu RC, Jiang C, Stephan DW. Bulky derivatives of boranes, boronic acids and boronate esters via reaction with diazomethanes. Dalton Transactions (Cambridge, England : 2003). 42: 726-36. PMID 23060040 DOI: 10.1039/C2Dt31868G  0.799
2013 Thomson JW, Hatnean JA, Hastie JJ, Pasternak A, Stephan DW, Chase PA. Improving the industrial feasibility of metal-free hydrogenation catalysts using chemical scavengers Organic Process Research and Development. 17: 1287-1292. DOI: 10.1021/Op4000847  0.602
2013 McKinty AM, Lund C, Stephan DW. A tridentate-dithiolate ruthenium alkylidene complex: An olefin metathesis catalyst activated by BCl3 Organometallics. 32: 4730-4732. DOI: 10.1021/Om400794U  0.793
2013 Dahcheh F, Stephan DW. A new route to ruthenium thiolate alkylidene complexes Organometallics. 32: 5253-5255. DOI: 10.1021/Om400740P  0.791
2013 Ménard G, Gilbert TM, Hatnean JA, Kraft A, Krossing I, Stephan DW. Stoichiometric reduction of CO2 to CO by phosphine/AlX 3-based frustrated Lewis pairs Organometallics. 32: 4416-4422. DOI: 10.1021/Om400619Y  0.647
2013 Ménard G, Tran L, McCahill JSJ, Lough AJ, Stephan DW. Contrasting the reactivity of ethylene and propylene with P/Al and P/B frustrated Lewis pairs Organometallics. 32: 6759-6763. DOI: 10.1021/Om400222W  0.641
2013 Wang T, Pranckevicius C, Lund CL, Sgro MJ, Stephan DW. Ruthenium carbene-diether ligand complexes: Catalysts for hydrogenation of Olefins Organometallics. 32: 2168-2177. DOI: 10.1021/Om400044W  0.367
2012 Zhao X, Liang L, Stephan DW. Facile synthesis of electrophilic vinyl boranes: reactions of alkynyl-borates and diazonium salts. Chemical Communications (Cambridge, England). 48: 10189-91. PMID 22968259 DOI: 10.1039/C2Cc35553A  0.596
2012 Farrell JM, Hatnean JA, Stephan DW. Activation of hydrogen and hydrogenation catalysis by a borenium cation. Journal of the American Chemical Society. 134: 15728-31. PMID 22931196 DOI: 10.1021/Ja307995F  0.647
2012 Ménard G, Stephan DW. H2 activation and hydride transfer to olefins by Al(C6F5)3-based frustrated Lewis pairs. Angewandte Chemie (International Ed. in English). 51: 8272-5. PMID 22778027 DOI: 10.1002/Anie.201203362  0.609
2012 Hounjet LJ, Caputo CB, Stephan DW. Phosphorus as a Lewis acid: CO2 sequestration with amidophosphoranes. Angewandte Chemie (International Ed. in English). 51: 4714-7. PMID 22473879 DOI: 10.1002/Anie.201201422  0.568
2012 Granville SL, Welch GC, Stephan DW. Ni, Pd, Pt, and Ru complexes of phosphine-borate ligands. Inorganic Chemistry. 51: 4711-21. PMID 22458594 DOI: 10.1021/Ic2026895  0.572
2012 Ménard G, Stephan DW. C-H activation of isobutylene using frustrated Lewis Pairs: aluminum and boron σ-allyl complexes. Angewandte Chemie (International Ed. in English). 51: 4409-12. PMID 22447372 DOI: 10.1002/Anie.201200328  0.637
2012 Neu RC, Ménard G, Stephan DW. Exchange chemistry of tBu3P(CO2)B(C6F5)2Cl. Dalton Transactions (Cambridge, England : 2003). 41: 9016-8. PMID 22367061 DOI: 10.1039/C2Dt30206C  0.811
2012 Caputo CB, Geier SJ, Winkelhaus D, Mitzel NW, Vukotic VN, Loeb SJ, Stephan DW. Reactions of substituted pyridines with electrophilic boranes. Dalton Transactions (Cambridge, England : 2003). 41: 2131-9. PMID 22186932 DOI: 10.1039/C1Dt11820J  0.646
2012 Caputo CB, Geier SJ, Ouyang EY, Kreitner C, Stephan DW. Chloro- and phenoxy-phosphines in frustrated Lewis pair additions to alkynes. Dalton Transactions (Cambridge, England : 2003). 41: 237-42. PMID 21904729 DOI: 10.1039/C1Dt11196E  0.648
2012 Zhao X, Stephan DW. Frustrated Lewis pair olefin addition reactions: P-, N-, C- and H-based nucleophilic additions to an olefin-tethered borane Chemical Science. 3: 2123-2132. DOI: 10.1039/C2Sc20262J  0.649
2012 Caputo CB, Geier SJ, Winkelhaus D, Mitzel NW, Vukotic VN, Loeb SJ, Stephan DW. Reactions of substituted pyridines with electrophilic boranes Dalton Transactions. 41: 2131-2139. DOI: 10.1039/c1dt11820j  0.633
2012 Reddy JS, Xu BH, Mahdi T, Fröhlich R, Kehr G, Stephan DW, Erker G. Alkenylborane-derived frustrated Lewis pairs: Metal-free catalytic hydrogenation reactions of electron-deficient alkenes Organometallics. 31: 5638-5649. DOI: 10.1021/Om3006068  0.336
2012 Dahcheh F, Stephan DW. Ruthenium and rhodium complexes of thioether-alkynylborates Organometallics. 31: 3222-3227. DOI: 10.1021/Om300075R  0.795
2012 Voss T, Mahdi T, Otten E, Fröhlich R, Kehr G, Stephan DW, Erker G. Frustrated Lewis pair behavior of intermolecular amine/B(C 6F 5) 3 pairs Organometallics. 31: 2367-2378. DOI: 10.1021/Om300017U  0.345
2012 Neu RC, Stephan DW. Insertion reactions of diazomethanes and electrophilic boranes Organometallics. 31: 46-49. DOI: 10.1021/Om2011613  0.804
2012 Caputo CB, Stephan DW. Activation of alkyl C-F Bonds by B(C 6F 5) 3: Stoichiometric and catalytic transformations Organometallics. 31: 27-30. DOI: 10.1021/Om200885C  0.662
2012 Caputo CB, Zhu K, Vukotic VN, Loeb SJ, Stephan DW. Cover Picture: Heterolytic Activation of H2Using a Mechanically Interlocked Molecule as a Frustrated Lewis Base (Angew. Chem. Int. Ed. 3/2013) Angewandte Chemie International Edition. 52: 773-773. DOI: 10.1002/Anie.201209490  0.55
2012 Caputo CB, Zhu K, Vukotic VN, Loeb SJ, Stephan DW. Titelbild: Heterolytic Activation of H2Using a Mechanically Interlocked Molecule as a Frustrated Lewis Base (Angew. Chem. 3/2013) Angewandte Chemie. 125: 803-803. DOI: 10.1002/Ange.201209490  0.551
2011 Peuser I, Neu RC, Zhao X, Ulrich M, Schirmer B, Tannert JA, Kehr G, Fröhlich R, Grimme S, Erker G, Stephan DW. CO2 and formate complexes of phosphine/borane frustrated Lewis pairs. Chemistry (Weinheim An Der Bergstrasse, Germany). 17: 9640-50. PMID 21961180 DOI: 10.1002/Chem.201100286  0.81
2011 Zhao X, Stephan DW. Olefin-borane "van der Waals complexes": intermediates in frustrated Lewis pair addition reactions. Journal of the American Chemical Society. 133: 12448-50. PMID 21770390 DOI: 10.1021/Ja205598K  0.62
2011 Ménard G, Stephan DW. Stoichiometric reduction of CO2 to CO by aluminum-based frustrated Lewis pairs. Angewandte Chemie (International Ed. in English). 50: 8396-9. PMID 21761539 DOI: 10.1002/Anie.201103600  0.569
2011 Kreitner C, Geier SJ, Stanlake LJ, Caputo CB, Stephan DW. Ring openings of lactone and ring contractions of lactide by frustrated Lewis pairs. Dalton Transactions (Cambridge, England : 2003). 40: 6771-7. PMID 21614351 DOI: 10.1039/C1Dt10449G  0.669
2011 Stanlake LJ, Stephan DW. Reactions of Zn bis-ferrocenyl-β-diketiminates with [Ph3C][B(C6F5)4]. Dalton Transactions (Cambridge, England : 2003). 40: 5836-40. PMID 21547312 DOI: 10.1039/C1Dt10452G  0.346
2011 Zhao X, Lough AJ, Stephan DW. Synthesis and reactivity of alkynyl-linked phosphonium borates. Chemistry (Weinheim An Der Bergstrasse, Germany). 17: 6731-43. PMID 21544880 DOI: 10.1002/Chem.201100203  0.616
2011 Stephan DW, Greenberg S, Graham TW, Chase P, Hastie JJ, Geier SJ, Farrell JM, Brown CC, Heiden ZM, Welch GC, Ullrich M. Metal-free catalytic hydrogenation of polar substrates by frustrated Lewis pairs. Inorganic Chemistry. 50: 12338-48. PMID 21534552 DOI: 10.1021/Ic200663V  0.773
2011 Heiden ZM, Stephan DW. Metal-free diastereoselective catalytic hydrogenations of imines using B(C6F5)3. Chemical Communications (Cambridge, England). 47: 5729-31. PMID 21503337 DOI: 10.1039/C1Cc10438A  0.32
2011 Cariou R, Graham TW, Dahcheh F, Stephan DW. Oxidative addition of aryl halides: routes to mono- and dimetallic nickel amino-bis-phosphinimine complexes. Dalton Transactions (Cambridge, England : 2003). 40: 5419-22. PMID 21491049 DOI: 10.1039/C1Dt10341E  0.792
2011 Cariou R, Dahcheh F, Graham TW, Stephan DW. Mononuclear and dinuclear palladium and nickel complexes of phosphinimine-based tridentate ligands. Dalton Transactions (Cambridge, England : 2003). 40: 4918-25. PMID 21431159 DOI: 10.1039/C1Dt10131E  0.783
2011 Heiden ZM, Schedler M, Stephan DW. Synthesis and reactivity of o-benzylphosphino- and o-α-methylbenzyl(N,N-dimethyl)amine-boranes. Inorganic Chemistry. 50: 1470-9. PMID 21268612 DOI: 10.1021/Ic102044Z  0.334
2011 Zhao X, Stephan DW. Bis-boranes in the frustrated Lewis pair activation of carbon dioxide. Chemical Communications (Cambridge, England). 47: 1833-5. PMID 21206951 DOI: 10.1039/C0Cc04791K  0.593
2011 Geier SJ, Gilbert TM, Stephan DW. Synthesis and reactivity of the phosphinoboranes R2PB(C6F5)2. Inorganic Chemistry. 50: 336-44. PMID 21126055 DOI: 10.1021/Ic102003X  0.336
2011 Neu RC, Otten E, Lough A, Stephan DW. The synthesis and exchange chemistry of frustrated Lewis pair-nitrous oxide complexes Chemical Science. 2: 170-176. DOI: 10.1039/C0Sc00398K  0.823
2011 Boone MP, Stephan DW. Reactions of Ru-alkynyl complexes with electrophilic boranes Organometallics. 30: 5537-5542. DOI: 10.1021/Om200815S  0.822
2011 Farrell JM, Heiden ZM, Stephan DW. Metal-free transfer hydrogenation catalysis by B(C6F 5)3 Organometallics. 30: 4497-4500. DOI: 10.1021/Om2005832  0.649
2011 Zhao X, Stephan DW. Correction to Olefin–Borane “van der Waals Complexes”: Intermediates in Frustrated Lewis Pair Addition Reactions Journal of the American Chemical Society. 134: 744-744. DOI: 10.1021/Ja210776R  0.576
2010 Multani K, Stanlake LJ, Stephan DW. Ti and Zr complexes of ferrocenyl amidinates. Dalton Transactions (Cambridge, England : 2003). 39: 8957-66. PMID 20714635 DOI: 10.1039/C0Dt00530D  0.31
2010 Zhao X, Gilbert TM, Stephan DW. C-C coupling by thermolysis of alkynyl phosphonium borates. Chemistry (Weinheim An Der Bergstrasse, Germany). 16: 10304-8. PMID 20665589 DOI: 10.1002/Chem.201001575  0.536
2010 Geier SJ, Chase PA, Stephan DW. Metal-free reductions of N-heterocycles via Lewis acid catalyzed hydrogenation. Chemical Communications (Cambridge, England). 46: 4884-6. PMID 20548991 DOI: 10.1039/C0Cc00719F  0.676
2010 Neu RC, Ouyang EY, Geier SJ, Zhao X, Ramos A, Stephan DW. Probing substituent effects on the activation of H(2) by phosphorus and boron frustrated Lewis pairs. Dalton Transactions (Cambridge, England : 2003). 39: 4285-94. PMID 20422086 DOI: 10.1039/C001133A  0.809
2010 Sgro MJ, Stephan DW. Synthesis and exchange reactions of Ni-dimine-COD, acetylene and olefin complexes. Dalton Transactions (Cambridge, England : 2003). 39: 5786-94. PMID 20372736 DOI: 10.1039/C001312A  0.3
2010 Webb JD, Laberge VS, Geier SJ, Stephan DW, Crudden CM. Borohydrides from organic hydrides: reactions of Hantzsch's esters with B(C(6)F(5))(3). Chemistry (Weinheim An Der Bergstrasse, Germany). 16: 4895-902. PMID 20309967 DOI: 10.1002/Chem.200903005  0.352
2010 Zhao X, Otten E, Song D, Stephan DW. Ni-->B interactions in nickel phosphino-alkynyl-borane complexes. Chemistry (Weinheim An Der Bergstrasse, Germany). 16: 2040-4. PMID 20091720 DOI: 10.1002/Chem.200902888  0.593
2010 Ménard G, Stephan DW. Room temperature reduction of CO2 to methanol by Al-based frustrated Lewis pairs and ammonia borane. Journal of the American Chemical Society. 132: 1796-7. PMID 20088527 DOI: 10.1021/Ja9104792  0.638
2010 Stephan DW, Erker G. Frustrated Lewis pairs: metal-free hydrogen activation and more. Angewandte Chemie (International Ed. in English). 49: 46-76. PMID 20025001 DOI: 10.1002/Anie.200903708  0.319
2010 Geier SJ, Stephan DW. Lewis acid mediated P-P bond hydrogenation and hydrosilylation Chemical Communications. 46: 1026-1028. DOI: 10.1039/B925126J  0.326
2010 Dureen MA, Brown CC, Stephan DW. Deprotonation and addition reactions of frustrated Lewis pairs with alkynes Organometallics. 29: 6594-6607. DOI: 10.1021/Om1009044  0.342
2010 Dureen MA, Brown CC, Stephan DW. Addition of enamines or pyrroles and B(C6F5) 3 "frustrated Lewis Pairs" to alkynes Organometallics. 29: 6422-6432. DOI: 10.1021/Om1008346  0.349
2010 Boone MP, Brown CC, Ancelet TA, Stephan DW. Interconversion of ruthenium-O(CH2CH2PCy 2)2 alkylidene and alkylidyne hydride complexes Organometallics. 29: 4369-4374. DOI: 10.1021/Om100707A  0.787
2010 Zhao X, Otten E, Song D, Stephan DW. Ni→ B interactions in nickel phosphino-alkynyl-borane complexes Chemistry - a European Journal. 16: 2040-2044. DOI: 10.1002/chem.200902888  0.557
2009 Chase PA, Gille AL, Gilbert TM, Stephan DW. Frustrated Lewis pairs derived from N-heterocyclic carbenes and Lewis acids. Dalton Transactions (Cambridge, England : 2003). 7179-88. PMID 20449161 DOI: 10.1039/B908737K  0.689
2009 Neu RC, Otten E, Stephan DW. Bridging binding modes of phosphine-stabilized nitrous oxide to Zn(C6F5)2. Angewandte Chemie (International Ed. in English). 48: 9709-12. PMID 19921733 DOI: 10.1002/anie.200905650  0.76
2009 McCahill JS, Welch GC, Stephan DW. Sterically hindered phosphine and phosphonium-based activators and additives for olefin polymerization. Dalton Transactions (Cambridge, England : 2003). 8555-61. PMID 19809731 DOI: 10.1039/B911489K  0.569
2009 Dureen MA, Welch GC, Gilbert TM, Stephan DW. Heterolytic cleavage of disulfides by frustrated Lewis pairs. Inorganic Chemistry. 48: 9910-7. PMID 19757814 DOI: 10.1021/Ic901590S  0.579
2009 Otten E, Neu RC, Stephan DW. Complexation of nitrous oxide by frustrated Lewis pairs. Journal of the American Chemical Society. 131: 9918-9. PMID 19569691 DOI: 10.1021/Ja904377V  0.781
2009 Yadav K, McCahill JS, Bai G, Stephan DW. Phosphinimide complexes with pendant hemilabile donors: synthesis, structure and ethylene polymerization activity. Dalton Transactions (Cambridge, England : 2003). 1636-43. PMID 19421609 DOI: 10.1039/B817959J  0.311
2009 Welch GC, Prieto R, Dureen MA, Lough AJ, Labeodan OA, Höltrichter-Rössmann T, Stephan DW. Reactions of phosphines with electron deficient boranes. Dalton Transactions (Cambridge, England : 2003). 1559-70. PMID 19421599 DOI: 10.1039/B814486A  0.595
2009 Geier SJ, Stephan DW. Lutidine/B(C6F5)3: at the boundary of classical and frustrated Lewis pair reactivity. Journal of the American Chemical Society. 131: 3476-7. PMID 19243095 DOI: 10.1021/ja900572x  0.325
2009 Ramos A, Lough AJ, Stephan DW. Activation of H2 by frustrated Lewis pairs derived from mono- and bis-phosphinoferrocenes and B(C6F5)3. Chemical Communications (Cambridge, England). 1118-20. PMID 19225655 DOI: 10.1039/b819525k  0.321
2009 Alhomaidan O, Welch GC, Bai G, Stephan DW. Hafnium–phosphinimide complexes Canadian Journal of Chemistry. 87: 1163-1172. DOI: 10.1139/V09-082  0.525
2009 Ramos A, Lough AJ, Stephan DW. Activation of H2 by frustrated Lewis pairs derived from mono- and bis-phosphinoferrocenes and B(C6F5)3 Chemical Communications. 1118-1120. DOI: 10.1039/B819525K  0.326
2009 Otten E, Neu RC, Stephan DW. Complexation of nitrous oxide by frustrated lewis pairs Journal of the American Chemical Society. 131: 9918-9919. DOI: 10.1021/ja904377v  0.765
2009 Neu RC, Otten E, Stephan DW. Bridging binding modes of phosphine-stabilized nitrous oxide to Zn(C 6F5)2 Angewandte Chemie - International Edition. 48: 9709-9712. DOI: 10.1002/Ange.200905650  0.793
2008 Chase PA, Stephan DW. Hydrogen and amine activation by a frustrated Lewis pair of a bulky N-heterocyclic carbene and B(C6F5)3. Angewandte Chemie (International Ed. in English). 47: 7433-7. PMID 18655208 DOI: 10.1002/Anie.200802596  0.657
2008 Chase PA, Jurca T, Stephan DW. Lewis acid-catalyzed hydrogenation: B(C6F5)3-mediated reduction of imines and nitriles with H2. Chemical Communications (Cambridge, England). 1701-3. PMID 18368170 DOI: 10.1039/B718598G  0.678
2008 Welch GC, Holtrichter-Roessmann T, Stephan DW. Thermal rearrangement of phosphine-B(C6F5)3 adducts. Inorganic Chemistry. 47: 1904-6. PMID 18284195 DOI: 10.1021/Ic702485R  0.563
2008 Holschumacher D, Bannenberg T, Hrib C, Jones P, Tamm M, Chase P, Stephan D. Titelbild: Heterolytic Dihydrogen Activation by a Frustrated Carbene-Borane Lewis Pair / Hydrogen and Amine Activation by a Frustrated Lewis Pair of a Bulky N-Heterocyclic Carbene and B(C6F5)3(Angew. Chem. 39/2008) Angewandte Chemie. 120: 7479-7479. DOI: 10.1002/Ange.200890244  0.655
2007 Chase PA, Welch GC, Jurca T, Stephan DW. Metal-free catalytic hydrogenation. Angewandte Chemie (International Ed. in English). 46: 8050-3. PMID 17696181 DOI: 10.1002/Anie.200702908  0.759
2007 Welch GC, Cabrera L, Chase PA, Hollink E, Masuda JD, Wei P, Stephan DW. Tuning Lewis acidity using the reactivity of "frustrated Lewis pairs": facile formation of phosphine-boranes and cationic phosphonium-boranes. Dalton Transactions (Cambridge, England : 2003). 3407-14. PMID 17664977 DOI: 10.1039/B704417H  0.783
2007 McCahill JS, Welch GC, Stephan DW. Reactivity of "frustrated Lewis pairs": three-component reactions of phosphines, a borane, and olefins. Angewandte Chemie (International Ed. in English). 46: 4968-71. PMID 17526043 DOI: 10.1002/Anie.200701215  0.539
2007 Welch GC, Stephan DW. Facile heterolytic cleavage of dihydrogen by phosphines and boranes. Journal of the American Chemical Society. 129: 1880-1. PMID 17260994 DOI: 10.1021/Ja067961J  0.538
2007 Cornelissen C, Chan G, Masuda JD, Stephan DW. Aluminum pentafluorophenyl–amide complexes Canadian Journal of Chemistry. 85: 135-140. DOI: 10.1139/V07-003  0.525
2007 Alhomaidan O, Hollink E, Stephan DW. Main Group Heterocycles from Lithiated Phosphinimines Organometallics. 26: 3041-3048. DOI: 10.1021/Om070154O  0.309
2007 Chase P, Welch G, Jurca T, Stephan D. Cover Picture: Metal-Free Catalytic Hydrogenation (Angew. Chem. Int. Ed. 42/2007) Angewandte Chemie International Edition. 46: 7903-7903. DOI: 10.1002/Anie.200790210  0.693
2007 Bai G, Stephan DW. Formation of C-C and C-N bonds in NiII ketimide complexes via transient NiIII aryl imides Angewandte Chemie - International Edition. 46: 1856-1859. DOI: 10.1002/Anie.200604547  0.304
2007 Chase P, Welch G, Jurca T, Stephan D. Titelbild: Metal-Free Catalytic Hydrogenation (Angew. Chem. 42/2007) Angewandte Chemie. 119: 8049-8049. DOI: 10.1002/Ange.200790210  0.694
2006 Welch GC, San Juan RR, Masuda JD, Stephan DW. Reversible, metal-free hydrogen activation. Science (New York, N.Y.). 314: 1124-6. PMID 17110572 DOI: 10.1126/Science.1134230  0.723
2006 Masuda JD, Hoskin AJ, Graham TW, Beddie C, Fermin MC, Etkin N, Stephan DW. Catalytic P--H activation by Ti and Zr catalysts. Chemistry (Weinheim An Der Bergstrasse, Germany). 12: 8696-707. PMID 16952126 DOI: 10.1002/Chem.200600429  0.564
2006 Masuda JD, Stephan DW. Neutral and cationic aluminium complexes of a sterically demanding N-imidoylamidine ligand. Dalton Transactions (Cambridge, England : 2003). 2089-97. PMID 16625253 DOI: 10.1039/B513531A  0.601
2006 Welch GC, Masuda JD, Stephan DW. Phosphonium-borate zwitterions, anionic phosphines, and dianionic phosphonium-dialkoxides via tetrahydrofuran ring-opening reactions. Inorganic Chemistry. 45: 478-80. PMID 16411674 DOI: 10.1021/Ic051713R  0.693
2006 Beddie C, Wei P, Stephan DW. Titanium pyridyl-phosphinimide complexes — Synthesis, structure, and ethylene polymerization catalysis Canadian Journal of Chemistry. 84: 755-761. DOI: 10.1139/V06-071  0.319
2006 Bai G, Wei P, Das A, Stephan DW. Mono- and Bimetallic (NacNac)Ni Cyclopentadienyl Complexes† Organometallics. 25: 5870-5878. DOI: 10.1021/Om060757K  0.304
2006 Cabrera L, Welch GC, Masuda JD, Wei P, Stephan DW. Pyridine and phosphine reactions with [CPh3][B(C6F5)4] Inorganica Chimica Acta. 359: 3066-3071. DOI: 10.1016/J.Ica.2006.02.006  0.712
2005 Masuda JD, Stephan DW. Transition metal complexes of a sterically demanding diimine ligand Canadian Journal of Chemistry. 83: 477-484. DOI: 10.1139/V05-057  0.569
2005 Masuda JD, Stephan DW. Synthesis and structure of a (NacNac)rhodium terminal dinitrogen complex Canadian Journal of Chemistry. 83: 324-327. DOI: 10.1139/V05-012  0.581
2004 Graham TW, Kickham J, Courtenay S, Wei P, Stephan DW. Reduction of Titanium(IV)-Phosphinimide Complexes:  Routes to Ti(III) Dimers, Ti(IV)-Metallacycles, and Ti(II) Species Organometallics. 23: 3309-3318. DOI: 10.1021/Om049826Q  0.304
2004 Masuda JD, Walsh DM, Wei P, Stephan DW. Neutral and Cationic Group 13 Alkyl and Hydride Complexes of a Phosphinimine−Amide Ligand Organometallics. 23: 1819-1824. DOI: 10.1021/Om0306776  0.555
2004 Hollink E, Wei P, Stephan DW. The Effects of Activators on Zirconium Phosphinimide Ethylene Polymerization Catalysts Organometallics. 23: 1562-1569. DOI: 10.1021/Om030631C  0.368
2004 Chan KTK, Spencer LP, Masuda JD, McCahill JSJ, Wei P, Stephan DW. Anionic Phosphinimine-Chelate Complexes of Rhodium and Iridium:  Steric and Electronic Influences on Oxidative Addition of CH2Cl2 Organometallics. 23: 381-390. DOI: 10.1021/Om030539G  0.564
2003 Wei P, Stephan DW. Cationic and neutral phosphido-bridged pentamethylcyclopentadienyl-chromium dimers Organometallics. 22: 1712-1717. DOI: 10.1021/Om0209881  0.329
2002 Courtenay S, Smith S, Hollink E, Blaschke U, Kehr G, Fröhlich R, Erker G, Stephan DW. Synthesis of a Dinuclear μ-(η2-Thioaldehyde)zirconocene Cation Complex Zeitschrift FüR Naturforschung B. 57: 1184-1188. DOI: 10.1515/Znb-2002-1017  0.35
2001 Kickham JE, Guérin F, Stewart JC, Urbanska E, Stephan DW. Multiple C−H Bond Activation:  Reactions of Titanium−Phosphinimide Complexes with Trimethylaluminum Organometallics. 20: 1175-1182. DOI: 10.1021/Om001047W  0.341
2001 Courtenay S, Stephan DW. Synthesis and Reactivity of Neutral, Zwitterionic and Cationic Pentamethylcyclopentadienyl−Tantalum−Phosphinimide Complexes Organometallics. 20: 1442-1450. DOI: 10.1021/Om0009785  0.334
2000 Carraz C, Stephan DW. Titanium Complexes of Sterically Demanding Cage-Phosphinimide Ligands Organometallics. 19: 3791-3796. DOI: 10.1021/Om0003178  0.32
1998 Firth AV, Witt E, Stephan DW. Thermal Reactions of Titanium Thiolates:  Terminal Titanium Sulfides in CS Bond Cleavage Reactions Organometallics. 17: 3716-3722. DOI: 10.1021/Om9804428  0.312
1996 Breen TL, Stephan DW. Synthesis and Reactivity of Phosphametallacycles:  Sterically Induced Epimerizations and Retrocycloadditions Organometallics. 15: 5729-5737. DOI: 10.1021/Om9607053  0.312
1996 Huang Y, Etkin N, Heyn RR, Nadasdi TT, Stephan DW. Synthesis and Structural and Reactivity Studies of Thiatitanacyclopropane Complexes [Cp†Ti(SCHCH2CH2S)]2(Cp†= Cp, MeCp) Organometallics. 15: 2320-2330. DOI: 10.1021/Om960108G  0.316
1994 Ho J, Breen TL, Ozarowski A, Stephan DW. Early Metal Mediated P-P Bond Formation in Cp2M((PR)2) and Cp2M((PR)3) Complexes Inorganic Chemistry. 33: 865-870. DOI: 10.1021/Ic00083A007  0.312
1993 Hou Z, Breen TL, Stephan DW. Formation and reactivity of the early metal phosphides and phosphinidenes Cp*2Zr:PR, Cp*2Zr(PR)2, and Cp*2Zr(PR)3 Organometallics. 12: 3158-3167. DOI: 10.1021/Om00032A044  0.544
1993 Ho J, Hou Z, Drake RJ, Stephan DW. Phosphorus-hydrogen and cyclopentadienyl carbon-hydrogen activation en route to homo- and heterobinuclear zirconocene phosphide and phosphinidene complexes Organometallics. 12: 3145-3157. DOI: 10.1021/Om00032A043  0.541
1992 Dick DG, Hou Z, Stephan DW. Monophosphido-bridged early/late heterobimetallics: synthesis, structure, and electrochemistry of titanium-metal complexes Cp2Ti(.mu.-PEt2)(.mu.-.eta.1:.eta.2-OC)M(CO)Cp (M = Mo, W) Organometallics. 11: 2378-2382. DOI: 10.1021/Om00043A018  0.523
1992 Hou Z, Stephan DW. Generation and reactivity of the first mononuclear early metal phosphinidene complex, Cp*2Zr:P(C6H2Me3-2,4,6) Journal of the American Chemical Society. 114: 10088-10089. DOI: 10.1021/Ja00051A067  0.55
1991 Toth RT, Stephan DW. Towards supported catalyst models: the synthesis, characterization, redox chemistry, and structures of the complexes Ti(OAr′)4 (Ar′ = C6H4(2-t-Bu), C6H(2,3,5,6-Me)4) Canadian Journal of Chemistry. 69: 172-178. DOI: 10.1139/V91-027  0.325
1990 Baidya N, Mascharak PK, Stephan DW, Campagna CF. Mononuclear nickel(II) thiolates of square-planar geometry: syntheses, spectral and redox properties of [Ni(SCH2CH2S)2]2- and [Ni(SCH(CH3)CH(CH3)S)2]2- and the structure of (Ph4P)2[Ni(SCH2CH2S)2]·4H2O Inorganica Chimica Acta. 177: 233-238. DOI: 10.1016/S0020-1693(00)85981-2  0.506
1989 Brown SJ, Hudson SE, Stephan DW, Mascharak PK. Syntheses, structures, and spectral properties of a synthetic analog of copper(II)-bleomycin and an intermediate in the process of its formation Inorganic Chemistry. 28: 468-477. DOI: 10.1021/ic00302a018  0.409
1989 BROWN SJ, HUDSON SE, STEPHAN DW, MASCHARAK PK. ChemInform Abstract: Syntheses, Structures, and Spectral Properties of a Synthetic Analogue of Copper(II)-Bleomycin and an Intermediate in the Process of Its Formation. Cheminform. 20. DOI: 10.1002/chin.198921271  0.416
1988 Brown SJ, Stephan DW, Mascharak PK. Characterization of a crystalline synthetic analog of copper(II)-bleomycin Journal of the American Chemical Society. 110: 1996-1997. DOI: 10.1021/Ja00214A071  0.395
1988 Brown SJ, Tao X, Wark TA, Stephan DW, Mascharak PK. Synthetic analog approach to metallobleomycins. 4. New halobridged dimeric and polymeric (infinite zigzag chain) complexes of copper(II) with peptide ligands related to bleomycins Inorganic Chemistry. 27: 1581-1587. DOI: 10.1021/Ic00282A014  0.465
1988 Rosenfield SG, Berends HP, Gelmini L, Stephan DW, Mascharak PK. New octahedral thiolato complexes of divalent nickel: syntheses, structures, and properties of (Et4N)[Ni(SC5H4N)3] and (Ph4P)[Ni(SC4H3N2)3].CH3CN [Erratum to document cited in CA107(12):108108H] Inorganic Chemistry. 27: 1512-1512. DOI: 10.1021/Ic00281A041  0.443
1988 BROWN SJ, TAO X, WARK TA, STEPHAN DW, MASCHARAK PK. ChemInform Abstract: Synthetic Analogue Approach to Metallobleomycins. Part 4. New Halo-Bridged Dimeric and Polymeric (Infinite Zigzag Chain) Complexes of Copper(II) with Peptide Ligands Related to Bleomycins. Cheminform. 19. DOI: 10.1002/chin.198834272  0.439
1988 BROWN SJ, MASCHARAK PK, STEPHAN DW. ChemInform Abstract: Characterization of a Crystalline Synthetic Analogue of Copper(II)-Bleomycin. Cheminform. 19. DOI: 10.1002/chin.198828215  0.406
1988 ROSENFIELD SG, WONG MLY, STEPHAN DW, MASCHARAK PK. ChemInform Abstract: Synthesis, Structure, and Properties of Tetraphenylphosphonium Tetrakis(2-mercaptopropionato)trinickelate(II), (Ph4P)2(Ni3(SCH(CH3)COO)4): A Linear Trimeric Thiolato Complex of Nickel. Cheminform. 19. DOI: 10.1002/chin.198812286  0.474
1987 Boeré RT, Esser DE, Willis CJ, Stephan DW, Obal TW. Complexes of hybrid ligands. The synthesis of a thioanisole-substituted fluoro-alcohol and its complexes with Pd2+ and Pt2+; the structure of a palladium(II) complex containing alkoxide, phosphine, thioether, and chloride donors Canadian Journal of Chemistry. 65: 798-803. DOI: 10.1139/V87-135  0.584
1987 Rosenfield SG, Wong MLY, Stephan DW, Mascharak PK. Synthesis, structure and properties of tetraphenylphosphonium tetrakis(2-mercaptopropionato)trinickelate(II) (PH4P)2[Ni3(SCH(CH3)COO)4]: a linear trimeric thiolato complex of nickel Inorganic Chemistry. 26: 4119-4122. DOI: 10.1021/Ic00271A030  0.469
1987 Rosenfield SG, Berends HP, Gelmini L, Stephan DW, Mascharak PK. New octahedral thiolato complexes of divalent nickel: syntheses, structures, and properties of (Et4N)[Ni(SC5H4N)3] and (Ph4P)[Ni(SC4H3N2)3].CH3CN Inorganic Chemistry. 26: 2792-2797. DOI: 10.1021/Ic00264A015  0.476
1987 Tao X, Stephan DW, Mascharak PK. Synthetic analog approach to metallobleomycins. 2. Synthesis, structure, and properties of the low-spin iron(III) complex of N-(2-(4-imidazolyl)ethyl)pyridine-2-carboxamide Inorganic Chemistry. 26: 754-759. DOI: 10.1021/Ic00252A022  0.455
1987 ROSENFIELD SG, BERENDS HP, GELMINI L, STEPHAN DW, MASCHARAK PK. ChemInform Abstract: New Octahedral Thiolato Complexes of Divalent Nickel: Synthesis, Structures, and Properties of (Et4N)(Ni(SC5H4N)3) and (Ph4P)(Ni(SC4H3N2)3)·CH3CN. Cheminform. 18. DOI: 10.1002/chin.198750297  0.447
1987 TAO X, STEPHAN DW, MASCHARAK PK. ChemInform Abstract: Synthetic Analogue Approach to Metallobleomycins. Part 2. Synthesis, Structure, and Properties of the Low-Spin Iron(III) Complex of N-(2-(4-Imidazolyl)ethyl)pyridine-2-carboxamide. Cheminform. 18. DOI: 10.1002/chin.198730248  0.434
1987 BROWN SJ, TAO X, STEPHAN DW, MASCHARAK PK. ChemInform Abstract: Synthetic Analogue Approach to Metallobleomycins. Part 1. Syntheses, Structures, and Properties of the Copper Complexes of Two Peptides Related to Bleomycins. Cheminform. 18. DOI: 10.1002/chin.198703294  0.417
1986 Brown SJ, Tao X, Stephan DW, Mascharak PK. Synthetic analog approach to metallobleomycins. 1. Syntheses, structures and properties of the copper complexes of two peptides related to bleomycins Inorganic Chemistry. 25: 3377-3384. DOI: 10.1021/Ic00239A013  0.488
1985 Boere RT, Brown WM, Stephan DW, Willis CJ. Coordination modes of polydentate ligands. 3. Five-coordinate complexes of cobalt(2+), copper(2+), and nickel(2+) containing a tridentate thioether-alkoxy ligand Inorganic Chemistry. 24: 593-597. DOI: 10.1021/Ic00198A032  0.591
1983 Stephan DW, Papaefthymiou GC, Frankel RB, Holm RH. Analogs of the [4Fe-4S]+ sites of reduced ferredoxins: structural and spectroscopic properties of [(C2H5)4N]3[Fe4S4(S-p-C6H4Br)4] in crystalline and solution phases Inorganic Chemistry. 22: 1550-1557. DOI: 10.1021/Ic00152A026  0.362
1983 HAGEN KS, STEPHAN DW, HOLM RH. ChemInform Abstract: METAL ION EXCHANGE REACTIONS IN CAGE MOLECULES: THE SYSTEMS (M4-NM′N(SC6H5)10)2- (M, M′ = FE(II), CO(II), ZN(II), CD(II)) WITH ADAMANTANE-LIKE STEREOCHEMISTRY AND THE STRUCTURE OF (FE4(SC6H5)10)2- Chemischer Informationsdienst. 14. DOI: 10.1002/chin.198304317  0.338
1982 Hagen KS, Stephan DW, Holm RH. Metal ion exchange reactions in cage molecules: the systems [M4-nM'n(SC6H5)10]2- (M, M' = Fe(II), Co(II), Zn(II), Cd(II)) with adamantane-like stereochemistry and the structure of [Fe4(SC6H5)10]2- Inorganic Chemistry. 21: 3928-3936. DOI: 10.1021/Ic00141A015  0.336
1981 Payne NC, Stephan DW. Studies in enantiomeric discrimination. I. Chiral phosphine complexes of platinum Journal of Organometallic Chemistry. 221: 223-230. DOI: 10.1016/S0022-328X(00)89057-9  0.605
1981 Payne NC, Stephan DW. Preparation and 31P NMR studies of platinum complexes of some chiral, bidentate phosphines Journal of Organometallic Chemistry. 221: 203-221. DOI: 10.1016/S0022-328X(00)89056-7  0.593
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