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André M. Beauchemin, Ph.D. - Publications

Affiliations: 
Chemistry and Centre for Catalysis Research and Innovation University of Ottawa, Ottawa, ON, Canada 
Area:
Organic Cheistry
Website:
http://mysite.science.uottawa.ca/abeauche/BEAUCHEMIN_E.htm
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63 high-probability publications. We are testing a new system for linking publications to authors. You can help! If you notice any inaccuracies, please sign in and mark papers as correct or incorrect matches. If you identify any major omissions or other inaccuracies in the publication list, please let us know.

Year Citation  Score
2023 Allen MA, Volosheniuk M, Nicol EA, Schwan AL, Beauchemin AM. Cope-Type Hydroamination of Vinylboronates. Organic Letters. 25: 3045-3048. PMID 37097727 DOI: 10.1021/acs.orglett.3c00857  0.385
2023 Vuillermet F, Dahab MA, Abdelhamid D, Polat DE, Gill MA, Beauchemin AM. Synthesis of 1,2,4-Triazinones Exploiting the Reactivity of Diazadiene and -Isocyanate Intermediates. The Journal of Organic Chemistry. 88: 2095-2102. PMID 36749643 DOI: 10.1021/acs.joc.2c02494  0.433
2022 Xiao YQ, Li MM, Zhou ZX, Li YJ, Cao MY, Liu XP, Lu HH, Li R, Lu LQ, Beauchemin AM, Xiao WJ. Taming Chiral Quaternary Stereocenters via Remote H-Bonding Stereoinduction in Palladium-Catalyzed (3+2) Cycloadditions. Angewandte Chemie (International Ed. in English). PMID 36377924 DOI: 10.1002/anie.202212444  0.346
2022 Allen MA, Ivanovich RA, Polat DE, Beauchemin AM. Correction to "Synthesis of -Oxyureas by Substitution and Cope-Type Hydroamination Reactions Using -Isocyanate Precursors". Organic Letters. 24: 6884. PMID 36103293 DOI: 10.1021/acs.orglett.2c02632  0.443
2020 Derasp JS, Barbera EA, Séguin NR, Brzezinski DD, Beauchemin AM. Synthesis of Hydroxamic Acid Derivatives Using Blocked (Masked) -Isocyanate Precursors. Organic Letters. PMID 32880464 DOI: 10.1021/acs.orglett.0c02782  0.317
2019 Ivanovich RA, Quartus JAM, Das Neves N, Loiseau F, Raymond M, Beauchemin AM. Aminimide Synthesis Using Concerted Amination Reactions of Alkenes: Scope and Mechanistic Information. The Journal of Organic Chemistry. PMID 31290665 DOI: 10.1021/acs.joc.9b01259  0.372
2019 Polat DE, Brzezinski DD, Beauchemin AM. Formation of Complex Hydrazine Derivatives via Aza-Lossen Rearrangement. Organic Letters. PMID 31184909 DOI: 10.1021/acs.orglett.9b01742  0.39
2019 Derasp JS, Beauchemin AM. Rhodium-Catalyzed Synthesis of Amides from Functionalized Blocked Isocyanates Acs Catalysis. 9: 8104-8109. DOI: 10.1021/ACSCATAL.9B02641  0.42
2017 Wang Q, An J, Alper H, Xiao WJ, Beauchemin AM. Catalytic substitution/cyclization sequences of O-substituted Isocyanates: synthesis of 1-alkoxybenzimidazolones and 1-alkoxy-3,4-dihydroquinazolin-2(1H)-ones. Chemical Communications (Cambridge, England). PMID 29165447 DOI: 10.1039/C7Cc07926E  0.315
2017 Li BJ, Ei-Nachef C, Beauchemin AM. Organocatalysis using aldehydes: the development and improvement of catalytic hydroaminations, hydrations and hydrolyses. Chemical Communications (Cambridge, England). PMID 29131221 DOI: 10.1039/c7cc07352f  0.356
2017 Elkaeed EB, An J, Beauchemin AM. Synthesis of Indazolones via Friedel-Crafts Cyclization of Blocked (Masked) N-Isocyanates. The Journal of Organic Chemistry. PMID 28829915 DOI: 10.1021/acs.joc.7b01607  0.34
2016 Vincent-Rocan JF, Ivanovich RA, Clavette C, Leckett K, Bejjani J, Beauchemin AM. Cascade reactions of nitrogen-substituted isocyanates: a new tool in heterocyclic chemistry. Chemical Science. 7: 315-328. PMID 29861985 DOI: 10.1039/C5Sc03197D  0.442
2016 Bongers A, Ranasinghe I, Lemire P, Perozzo A, Vincent-Rocan JF, Beauchemin AM. Synthesis of Cyclic Azomethine Imines by Cycloaddition Reactions of N-Isocyanates and N-Isothiocyanates. Organic Letters. PMID 27458786 DOI: 10.1021/Acs.Orglett.6B01788  0.488
2016 An J, Alper H, Beauchemin AM. Copper-Catalyzed Cascade Substitution/Cyclization of N-Isocyanates: A Synthesis of 1-Aminobenzimidazolones. Organic Letters. PMID 27341005 DOI: 10.1021/Acs.Orglett.6B01686  0.47
2016 Ivanovich RA, Clavette C, Vincent-Rocan JF, Roveda JG, Gorelsky SI, Beauchemin AM. Intramolecular Alkene Aminocarbonylation Using Concerted Cycloadditions of Amino-Isocyanates. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 27112602 DOI: 10.1002/Chem.201600574  0.442
2016 Derasp JS, Vincent-Rocan JF, Beauchemin AM. Divergent Reactivity of N-Isocyanates with Primary and Secondary Amines: Access to Pyridazinones and Triazinones. Organic Letters. PMID 26852776 DOI: 10.1021/Acs.Orglett.5B03590  0.439
2016 Beauchemin A, Dahab M, Derasp J. Thieme Chemistry Journals Awardees – Where Are They Now? A Cascade Synthesis of 1,2,4-Triazin-3(2H)-ones Using Nitrogen-Substituted Isocyanates Synlett. 28: 456-460. DOI: 10.1055/s-0036-1588099  0.308
2015 Bongers A, Moon PJ, Beauchemin AM. Kinetic Resolution of Azomethine Imines by Brønsted Acid Catalyzed Enantioselective Reduction. Angewandte Chemie (International Ed. in English). PMID 26554537 DOI: 10.1002/Anie.201507548  0.404
2015 Hesp CR, MacDonald MJ, Zahedi MM, Bilodeau DA, Zhao SB, Pesant M, Beauchemin AM. Formaldehyde as Tethering Organocatalyst: Highly Diastereoselective Hydroaminations of Allylic Amines. Organic Letters. PMID 26417922 DOI: 10.1021/Acs.Orglett.5B02675  0.462
2015 Vincent-Rocan JF, Derasp JS, Beauchemin AM. Diversity-oriented heterocyclic synthesis using divergent reactivity of N-substituted iso(thio)cyanates. Chemical Communications (Cambridge, England). 51: 16405-8. PMID 26412362 DOI: 10.1039/C5Cc07212C  0.447
2015 Ivanovich RA, Vincent-Rocan JF, Elkaeed EB, Beauchemin AM. One-Pot Synthesis of Aza-Diketopiperazines Enabled by Controlled Reactivity of N-Isocyanate Precursors. Organic Letters. 17: 4898-901. PMID 26394075 DOI: 10.1021/Acs.Orglett.5B02464  0.445
2015 Lavergne K, Bongers A, Betit L, Beauchemin AM. Modular Synthesis of Pyrazolones Using an Alkene Aminocarbonylation Reaction. Organic Letters. PMID 26126788 DOI: 10.1021/Acs.Orglett.5B01719  0.496
2015 Vincent-Rocan JF, Clavette C, Leckett K, Beauchemin AM. A cascade synthesis of aminohydantoins using in situ-generated N-substituted isocyanates. Chemistry (Weinheim An Der Bergstrasse, Germany). 21: 3886-90. PMID 25631378 DOI: 10.1002/Chem.201405648  0.521
2015 Vincent-Rocan JF, Ivanovich RA, Clavette C, Leckett K, Bejjani J, Beauchemin AM. Cascade reactions of nitrogen-substituted isocyanates: A new tool in heterocyclic chemistry Chemical Science. 7: 315-328. DOI: 10.1039/c5sc03197d  0.329
2014 Hu XQ, Chen JR, Wei Q, Liu FL, Deng QH, Beauchemin AM, Xiao WJ. Photocatalytic generation of N-centered hydrazonyl radicals: a strategy for hydroamination of β,γ-unsaturated hydrazones. Angewandte Chemie (International Ed. in English). 53: 12163-7. PMID 25513705 DOI: 10.1002/Anie.201406491  0.329
2014 Hsieh SY, Wanner B, Wheeler P, Beauchemin AM, Rovis T, Bode JW. Stereoelectronic basis for the kinetic resolution of N-heterocycles with chiral acylating reagents. Chemistry (Weinheim An Der Bergstrasse, Germany). 20: 7228-31. PMID 24839065 DOI: 10.1002/Chem.201402818  0.521
2013 Dion I, Vincent-Rocan JF, Zhang L, Cebrowski PH, Lebrun ME, Pfeiffer JY, Bédard AC, Beauchemin AM. Studies on difficult intramolecular hydroaminations in the context of four syntheses of alkaloid natural products. The Journal of Organic Chemistry. 78: 12735-49. PMID 24274926 DOI: 10.1021/Jo4023149  0.456
2013 Clavette C, Vincent Rocan JF, Beauchemin AM. Diversity-oriented synthesis of hydrazine-derived compounds from amino isocyanates generated in situ. Angewandte Chemie (International Ed. in English). 52: 12705-8. PMID 24123509 DOI: 10.1002/Anie.201306379  0.4
2013 Beauchemin AM. Recent developments in Cope-type hydroamination reactions of hydroxylamine and hydrazine derivatives. Organic & Biomolecular Chemistry. 11: 7039-50. PMID 24056974 DOI: 10.1039/C3Ob41172A  0.491
2013 Beauchemin AM. Site-selective reactions: Exploiting intramolecularity. Nature Chemistry. 5: 731-2. PMID 23965669 DOI: 10.1038/Nchem.1737  0.382
2013 Garland K, Gan W, Depatie-Sicard C, Beauchemin AM. A practical approach to semicarbazone and hydrazone derivatives via imino-isocyanates. Organic Letters. 15: 4074-7. PMID 23902571 DOI: 10.1021/Ol4016089  0.406
2013 Hunt AD, Dion I, Das Neves N, Taing S, Beauchemin AM. Synthesis of azomethine imines using an intramolecular alkyne hydrohydrazination approach. The Journal of Organic Chemistry. 78: 8847-52. PMID 23895439 DOI: 10.1021/Jo4011409  0.482
2013 Chigrinova M, McKay CS, Beaulieu LP, Udachin KA, Beauchemin AM, Pezacki JP. Rearrangements and addition reactions of biarylazacyclooctynones and the implications to copper-free click chemistry. Organic & Biomolecular Chemistry. 11: 3436-41. PMID 23629512 DOI: 10.1039/C3Ob40683K  0.302
2013 Gan W, Moon PJ, Clavette C, Das Neves N, Markiewicz T, Toderian AB, Beauchemin AM. Synthesis and reactivity of unsymmetrical azomethine imines formed using alkene aminocarbonylation. Organic Letters. 15: 1890-3. PMID 23565796 DOI: 10.1021/Ol400542B  0.456
2013 MacDonald MJ, Hesp CR, Schipper DJ, Pesant M, Beauchemin AM. Highly enantioselective intermolecular hydroamination of allylic amines with chiral aldehydes as tethering catalysts. Chemistry (Weinheim An Der Bergstrasse, Germany). 19: 2597-601. PMID 23307591 DOI: 10.1002/Chem.201203462  0.601
2012 Zhao SB, Bilodeau E, Lemieux V, Beauchemin AM. Hydrogen bonding directed intermolecular Cope-type hydroamination of alkenes. Organic Letters. 14: 5082-5. PMID 23005340 DOI: 10.1021/Ol3023177  0.382
2012 Guimond N, MacDonald MJ, Lemieux V, Beauchemin AM. Catalysis through temporary intramolecularity: mechanistic investigations on aldehyde-catalyzed Cope-type hydroamination lead to the discovery of a more efficient tethering catalyst. Journal of the American Chemical Society. 134: 16571-7. PMID 22971001 DOI: 10.1021/Ja303320X  0.463
2012 Clavette C, Gan W, Bongers A, Markiewicz T, Toderian AB, Gorelsky SI, Beauchemin AM. A tunable route for the synthesis of azomethine imines and β-aminocarbonyl compounds from alkenes. Journal of the American Chemical Society. 134: 16111-4. PMID 22966807 DOI: 10.1021/Ja305491T  0.443
2011 MacDonald MJ, Schipper DJ, Ng PJ, Moran J, Beauchemin AM. A catalytic tethering strategy: simple aldehydes catalyze intermolecular alkene hydroaminations. Journal of the American Chemical Society. 133: 20100-3. PMID 22098595 DOI: 10.1021/Ja208867G  0.736
2011 Loiseau F, Clavette C, Raymond M, Roveda JG, Burrell A, Beauchemin AM. Improved Cope-type hydroamination reactivity of hydrazine derivatives. Chemical Communications (Cambridge, England). 47: 562-4. PMID 20927442 DOI: 10.1039/C0Cc02403A  0.4
2009 Pfeiffer JY, Beauchemin AM. Simple reaction conditions for the formation of ketonitrones from ketones and hydroxylamines. The Journal of Organic Chemistry. 74: 8381-3. PMID 19791735 DOI: 10.1021/Jo901653D  0.39
2009 Rizk T, Bilodeau EJ, Beauchemin AM. Synthesis of pyridines and pyrazines using an intramolecular hydroamination-based reaction sequence. Angewandte Chemie (International Ed. in English). 48: 8325-7. PMID 19784988 DOI: 10.1002/Anie.200903922  0.489
2009 Roveda JG, Clavette C, Hunt AD, Gorelsky SI, Whipp CJ, Beauchemin AM. Hydrazides as tunable reagents for alkene hydroamination and aminocarbonylation. Journal of the American Chemical Society. 131: 8740-1. PMID 19505097 DOI: 10.1021/Ja902558J  0.345
2009 Moran J, Pfeiffer JY, Gorelsky SI, Beauchemin AM. Ketonitrones via Cope-type hydroamination of allenes. Organic Letters. 11: 1895-8. PMID 19331345 DOI: 10.1021/Ol900292R  0.631
2009 Bourgeois J, Dion I, Cebrowski PH, Loiseau F, Bédard AC, Beauchemin AM. The tandem Cope-type hydroamination/[2,3]-rearrangement sequence: a strategy to favor the formation of intermolecular hydroamination products and enable difficult cyclizations. Journal of the American Chemical Society. 131: 874-5. PMID 19119816 DOI: 10.1021/Ja8077895  0.433
2009 Lebrun ME, Pfeiffer JY, Beauchemin AM. Synthesis of 2-epi-pumiliotoxin C via a challenging intramolecular hydroamination key step Synlett. 1087-1090. DOI: 10.1055/S-0028-1088146  0.456
2008 Moran J, Gorelsky SI, Dimitrijevic E, Lebrun ME, Bédard AC, Séguin C, Beauchemin AM. Intermolecular cope-type hydroamination of alkenes and alkynes using hydroxylamines. Journal of the American Chemical Society. 130: 17893-906. PMID 19053470 DOI: 10.1021/Ja806300R  0.63
2008 Evans DA, Kvaernø L, Dunn TB, Beauchemin A, Raymer B, Mulder JA, Olhava EJ, Juhl M, Kagechika K, Favor DA. Total synthesis of (+)-azaspiracid-1. An exhibition of the intricacies of complex molecule synthesis. Journal of the American Chemical Society. 130: 16295-309. PMID 19006391 DOI: 10.1021/Ja804659N  0.704
2008 Beauchemin AM, Moran J, Lebrun ME, Séguin C, Dimitrijevic E, Zhang L, Gorelsky SI. Intermolecular cope-type hydroamination of alkenes and alkynes. Angewandte Chemie (International Ed. in English). 47: 1410-3. PMID 18203221 DOI: 10.1002/Anie.200703495  0.548
2008 Cebrowski PH, Roveda JG, Moran J, Gorelsky SI, Beauchemin AM. Intermolecular Cope-type hydroamination of alkynes using hydrazines. Chemical Communications (Cambridge, England). 492-3. PMID 18188478 DOI: 10.1039/B715022A  0.52
2008 Moran J, Cebrowski PH, Beauchemin AM. Intermolecular hydroaminations via strained (E)-cycloalkenes. The Journal of Organic Chemistry. 73: 1004-7. PMID 18161984 DOI: 10.1021/Jo701985W  0.631
2007 Moran J, Dornan P, Beauchemin AM. Strain-release electrophilic activation via E-cycloalkenones. Organic Letters. 9: 3893-6. PMID 17784766 DOI: 10.1021/Ol701496B  0.57
2007 Evans DA, Dunn TB, Kvaernø L, Beauchemin A, Raymer B, Olhava EJ, Mulder JA, Juhl M, Kagechika K, Favor DA. Total synthesis of (+)-azaspiracid-1. Part II: synthesis of the EFGHI sulfone and completion of the synthesis. Angewandte Chemie (International Ed. in English). 46: 4698-703. PMID 17546578 DOI: 10.1002/Anie.200701520  0.689
2007 Evans DA, Kvaernø L, Mulder JA, Raymer B, Dunn TB, Beauchemin A, Olhava EJ, Juhl M, Kagechika K. Total synthesis of (+)-azaspiracid-1. Part I: Synthesis of the fully elaborated ABCD aldehyde. Angewandte Chemie (International Ed. in English). 46: 4693-7. PMID 17546577 DOI: 10.1002/Anie.200701515  0.731
2006 Moran J, Suen T, Beauchemin AM. Photoinduced 1,4-additions of indoles to enones. The Journal of Organic Chemistry. 71: 676-9. PMID 16408979 DOI: 10.1021/Jo0521044  0.618
2004 Charette AB, Beauchemin A. Simmons‐Smith Cyclopropanation Reaction Organic Reactions. 1-415. DOI: 10.1002/0471264180.Or058.01  0.728
2002 Charette A, Beauchemin A, Francoeur S, Bélanger-Gariépy F, Enright GD. Photoinduced alkyl group exchange of ethylzinc alkoxides: X-ray crystal structure of an iodomethylzinc methoxide. Chemical Communications (Cambridge, England). 466-7. PMID 12120544 DOI: 10.1039/B110736D  0.636
2001 Charette AB, Beauchemin A, Francoeur S. Acyloxymethylzinc reagents: preparation, reactivity, and solid-state structure of this novel class of cyclopropanating reagents. Journal of the American Chemical Society. 123: 8139-40. PMID 11506580 DOI: 10.1021/Ja0109287  0.628
2001 Charette AB, Beauchemin A. Reinvestigation of the chemoselective cyclopropanation of allylic alcohols, allylic ethers and alkenes: A comparison between various reagents and protocols Journal of Organometallic Chemistry. 617: 702-708. DOI: 10.1016/S0022-328X(00)00725-7  0.682
2000 Charette AB, Marcoux JF, Molinaro C, Beauchemin A, Brochu C, Isabel E. Preparation, solid-state structure, and synthetic applications of isolable and storable haloalkylzinc reagents [1] Journal of the American Chemical Society. 122: 4508-4509. DOI: 10.1021/Ja994371V  0.71
1999 Charette AB, Beauchemin A, Marcoux JF. Preparation and reactivity of some functionalized halomethylzinc carbenoids Tetrahedron Letters. 40: 33-36. DOI: 10.1016/S0040-4039(98)80012-9  0.656
1998 Charette AB, Beauchemin A, Marcoux JF. Photoinduced synthesis of diorganozinc and organozinc iodide reagents [2] Journal of the American Chemical Society. 120: 5114-5115. DOI: 10.1021/Ja980318F  0.739
1998 Beauchemin A, Gareau Y. Studies of triphenylsilanethiol addition to alkynes: Preparation of vinyl sulfides Phosphorus, Sulfur and Silicon and Related Elements. 139: 187-192.  0.349
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