Marc Robert - Publications

Affiliations: 
Paris Diderot University 

129 high-probability publications. We are testing a new system for linking publications to authors. You can help! If you notice any inaccuracies, please sign in and mark papers as correct or incorrect matches. If you identify any major omissions or other inaccuracies in the publication list, please let us know.

Year Citation  Score
2023 Bharti J, Chen L, Guo Z, Cheng L, Wellauer J, Wenger OS, von Wolff N, Lau KC, Lau TC, Chen G, Robert M. Correction to "Visible-Light-Driven CO Reduction with Homobimetallic Complexes. Cooperativity between Metals and Activation of Different Pathways". Journal of the American Chemical Society. PMID 38153202 DOI: 10.1021/jacs.3c14220  0.718
2023 Bharti J, Chen L, Guo Z, Cheng L, Wellauer J, Wenger OS, von Wolff N, Lau KC, Lau TC, Chen G, Robert M. Visible-Light-Driven CO Reduction with Homobimetallic Complexes. Cooperativity between Metals and Activation of Different Pathways. Journal of the American Chemical Society. PMID 37947126 DOI: 10.1021/jacs.3c07799  0.753
2022 Tocqueville D, Crisanti F, Guerrero J, Nubret E, Robert M, Milstein D, von Wolff N. Electrification of a Milstein-type catalyst for alcohol reformation. Chemical Science. 13: 13220-13224. PMID 36425491 DOI: 10.1039/d2sc04533h  0.777
2022 Boutin E, Salamé A, Merakeb L, Chatterjee T, Robert M. On the Existence and Role of Formaldehyde During Aqueous Electrochemical Reduction of Carbon Monoxide to Methanol by Cobalt Phthalocyanine. Chemistry (Weinheim An Der Bergstrasse, Germany). e202200697. PMID 35267221 DOI: 10.1002/chem.202200697  0.591
2021 von Wolff N, Robert M. Taming Electron Transfers: From Breaking Bonds to Creating Molecules. Chemical Record (New York, N.Y.). PMID 34235842 DOI: 10.1002/tcr.202100151  0.783
2020 Chen L, Chen G, Leung CF, Cometto C, Robert M, Lau TC. Molecular quaterpyridine-based metal complexes for small molecule activation: water splitting and CO reduction. Chemical Society Reviews. PMID 32954394 DOI: 10.1039/D0Cs00927J  0.345
2020 Kostopoulos N, Achaibou C, Noël JM, Kanoufi F, Robert M, Fave C, Anxolabéhère-Mallart E. Electrocatalytic O Activation by Fe Tetrakis(pentafluorophenyl)porphyrin in Acidic Organic Media. Evidence of High-Valent Fe Oxo Species. Inorganic Chemistry. 59: 11577-11583. PMID 32799464 DOI: 10.1021/Acs.Inorgchem.0C01379  0.345
2020 Boutin E, Merakeb L, Ma B, Boudy B, Wang M, Bonin J, Anxolabéhère-Mallart E, Robert M. Molecular catalysis of CO reduction: recent advances and perspectives in electrochemical and light-driven processes with selected Fe, Ni and Co aza macrocyclic and polypyridine complexes. Chemical Society Reviews. PMID 32697210 DOI: 10.1039/D0Cs00218F  0.432
2020 Pati PB, Wang R, Boutin E, Diring S, Jobic S, Barreau N, Odobel F, Robert M. Photocathode functionalized with a molecular cobalt catalyst for selective carbon dioxide reduction in water. Nature Communications. 11: 3499. PMID 32661340 DOI: 10.1038/S41467-020-17125-4  0.355
2020 Bonetto R, Altieri R, Tagliapietra M, Barbon A, Bonchio M, Robert M, Sartorel A. Electrochemical conversion of CO2 to CO by a competent Fe(I) intermediate bearing a Schiff base ligand. Chemsuschem. PMID 32657523 DOI: 10.1002/Cssc.202001143  0.399
2020 Kwok CL, Cheng SC, Ho PY, Yiu SM, Man WL, Au VK, Tsang PK, Leung CF, Ko CC, Robert M. Precious-metal free photocatalytic production of an NADH analogue using cobalt diimine-dioxime catalysts under both aqueous and organic conditions. Chemical Communications (Cambridge, England). PMID 32497158 DOI: 10.1039/D0Cc02604B  0.343
2020 Qin Y, Chen L, Chen G, Guo Z, Wang L, Fan H, Robert M, Lau TC. A highly active and robust iron quinquepyridine complex for photocatalytic CO reduction in aqueous acetonitrile solution. Chemical Communications (Cambridge, England). PMID 32373815 DOI: 10.1039/D0Cc01930E  0.344
2020 Ishida H, Machan C, Robert M, Iwasawa N. Editorial: Molecular Catalysts for CO Fixation/Reduction. Frontiers in Chemistry. 8: 59. PMID 32158743 DOI: 10.3389/Fchem.2020.00059  0.311
2020 Ma B, Chen G, Fave C, Chen L, Kuriki R, Maeda K, Ishitani O, Lau TC, Bonin J, Robert M. Efficient Visible-Light Driven CO2 Reduction by a Cobalt Molecular Catalyst Covalently Linked to Mesoporous Carbon Nitride. Journal of the American Chemical Society. PMID 32148034 DOI: 10.1021/Jacs.9B13930  0.371
2020 Chatterjee T, Boutin E, Robert M. Manifesto for the routine use of NMR for the liquid product analysis of aqueous CO reduction: from comprehensive chemical shift data to formaldehyde quantification in water. Dalton Transactions (Cambridge, England : 2003). PMID 32129388 DOI: 10.1039/C9Dt04749B  0.582
2020 Torbensen K, Han C, Boudy B, von Wolff N, Bertail C, Braun W, Robert M. Iron Porphyrin Does Fast and Selective Electrocatalytic Conversion of CO2 to CO in a Flow Cell. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 31943389 DOI: 10.1002/Chem.202000160  0.743
2020 Zheng B, Ma L, Li B, Chen D, Li X, He J, Xie J, Robert M, Lau T. pH universal Ru@N-doped carbon catalyst for efficient and fast hydrogen evolution Catalysis Science & Technology. 10: 4405-4411. DOI: 10.1039/C9Cy02552A  0.393
2020 Torbensen K, Joulié D, Ren S, Wang M, Salvatore D, Berlinguette CP, Robert M. Molecular Catalysts Boost the Rate of Electrolytic CO2 Reduction Acs Energy Letters. 5: 1512-1518. DOI: 10.1021/Acsenergylett.0C00536  0.34
2020 Torbensen K, Boudy B, Joulié D, Wolff Nv, Robert M. Emergence of CO2 electrolyzers including supported molecular catalysts Current Opinion in Electrochemistry. 24: 49-55. DOI: 10.1016/J.Coelec.2020.07.001  0.383
2019 Boutin E, Wang M, Lin JC, Mesnage M, Mendoza D, Lassalle-Kaiser B, Hahn C, Jaramillo T, Robert M. Aqueous Electrochemical Reduction of Carbon Dioxide and Carbon Monoxide into Methanol with Cobalt Phthalocyanine. Angewandte Chemie (International Ed. in English). PMID 31496012 DOI: 10.1002/Anie.201909257  0.382
2019 Cometto C, Chen L, Mendoza D, Lassalle-Kaiser B, Lau TC, Robert M. An iron quaterpyridine complex as a precursor for the electrocatalytic reduction of CO2 into methane. Chemsuschem. PMID 31432616 DOI: 10.1002/Cssc.201902040  0.32
2019 Wang M, Torbensen K, Salvatore D, Ren S, Joulié D, Dumoulin F, Mendoza D, Lassalle-Kaiser B, Işci U, Berlinguette CP, Robert M. CO electrochemical catalytic reduction with a highly active cobalt phthalocyanine. Nature Communications. 10: 3602. PMID 31399585 DOI: 10.1038/S41467-019-11542-W  0.367
2019 Ren S, Joulié D, Salvatore D, Torbensen K, Wang M, Robert M, Berlinguette CP. Molecular electrocatalysts can mediate fast, selective CO reduction in a flow cell. Science (New York, N.Y.). 365: 367-369. PMID 31346062 DOI: 10.1126/Science.Aax4608  0.345
2019 Anxolabéhère-Mallart E, Bonin J, Fave C, Robert M. Small-molecule activation with iron porphyrins using electrons, photons and protons: some recent advances and future strategies. Dalton Transactions (Cambridge, England : 2003). PMID 30848271 DOI: 10.1039/C9Dt00136K  0.436
2019 Chen L, Qin Y, Chen G, Li M, Cai L, Qiu Y, Fan H, Robert M, Lau TC. A molecular noble metal-free system for efficient visible light-driven reduction of CO to CO. Dalton Transactions (Cambridge, England : 2003). PMID 30778461 DOI: 10.1039/C9Dt00425D  0.389
2019 Rotundo L, Garino C, Priola E, Sassone D, Rao H, Ma B, Robert M, Fiedler J, Gobetto R, Nervi C. Electrochemical and Photochemical Reduction of CO2 Catalyzed by Re(I) Complexes Carrying Local Proton Sources Organometallics. 38: 1351-1360. DOI: 10.1021/Acs.Organomet.8B00588  0.386
2019 Cometto C, Chen L, Anxolabéhère-Mallart E, Fave C, Lau T, Robert M. Molecular Electrochemical Catalysis of the CO2-to-CO Conversion with a Co Complex: A Cyclic Voltammetry Mechanistic Investigation Organometallics. 38: 1280-1285. DOI: 10.1021/Acs.Organomet.8B00555  0.409
2018 Rao H, Lim CH, Bonin J, Miyake GM, Robert M. Visible-Light-Driven Conversion of CO2 to CH4 with an Organic Sensitizer and an Iron Porphyrin Catalyst. Journal of the American Chemical Society. PMID 30525556 DOI: 10.1021/Jacs.8B09740  0.369
2018 Cometto C, Kuriki R, Chen L, Maeda K, Lau TC, Ishitani O, Robert M. A Carbon Nitride/Fe Quaterpyridine Catalytic System for Photostimulated CO-to-CO Conversion with Visible Light. Journal of the American Chemical Society. PMID 29888920 DOI: 10.1021/Jacs.8B04007  0.348
2018 Robert M, Lau TC, Wang M, Chen L. Hybrid Co Quaterpyridine Complex /Carbon Nanotube Catalytic Material for CO2 Reduction in Water. Angewandte Chemie (International Ed. in English). PMID 29693759 DOI: 10.1002/Anie.201802792  0.368
2018 Cometto C, Chen L, Lo P, Guo Z, Lau K, Anxolabéhère-Mallart E, Fave C, Lau T, Robert M. Highly Selective Molecular Catalysts for the CO2-to-CO Electrochemical Conversion at Very Low Overpotential. Contrasting Fe vs Co Quaterpyridine Complexes upon Mechanistic Studies Acs Catalysis. 8: 3411-3417. DOI: 10.1021/Acscatal.7B04412  0.421
2018 Rao H, Bonin J, Robert M. Toward Visible-Light Photochemical CO2-to-CH4 Conversion in Aqueous Solutions Using Sensitized Molecular Catalysis Journal of Physical Chemistry C. 122: 13834-13839. DOI: 10.1021/Acs.Jpcc.8B00950  0.4
2017 Soria-Castro SM, Andrada DM, Caminos DA, Argúello JE, Robert M, Peñeñory AB. Mechanistic Insight into the Cu-Catalyzed C-S Cross-Coupling of Thioacetate with Aryl Halides. A Joint Experimental-Computational Study. The Journal of Organic Chemistry. PMID 28960986 DOI: 10.1021/Acs.Joc.7B01991  0.442
2017 Robert M, Rao H, Bonin J. Visible-light Homogeneous Photocatalytic Conversion of CO2 to CO in Aqueous Solutions with an Fe Catalyst. Chemsuschem. PMID 28862388 DOI: 10.1002/Cssc.201701467  0.405
2017 Robert M, Guo Z, Yu F, Yang Y, Leung CF, Ng SM, Ko CC, Cometto C, Lau TC. Photocatalytic CO2-to-CO Conversion by a Copper(II) Quaterpyridine Complex. Chemsuschem. PMID 28840967 DOI: 10.1002/Cssc.201701354  0.362
2017 Rao H, Schmidt LC, Bonin J, Robert M. Visible-light-driven methane formation from CO2 with a molecular iron catalyst. Nature. PMID 28723895 DOI: 10.1038/Nature23016  0.391
2017 Rao H, Bonin J, Robert M. Non-sensitized selective photochemical reduction of CO2 to CO under visible light with an iron molecular catalyst. Chemical Communications (Cambridge, England). PMID 28217798 DOI: 10.1039/C6Cc09967J  0.355
2017 Nervi C, Franco F, Cometto C, Nencini L, Barolo C, Sordello F, Minero C, Fiedler J, Robert M, Gobetto R. Local Proton Source in the Electrocatalytic CO2 Reduction by Mn(bpy-R)(CO)3Br Complexes. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 28106930 DOI: 10.1002/Chem.201605546  0.388
2017 Lassalle-Kaiser B, Zitolo A, Fonda E, Robert M, Anxolabéhère-Mallart E. In Situ Observation of the Formation and Structure of Hydrogen Evolving Amorphous Cobalt Electrocatalysts. Acs Energy Letters. 2: 2545-2551. DOI: 10.1021/Acsenergylett.7B00789  0.325
2017 Costentin C, Robert M, Savéant J. Molecular catalysis of electrochemical reactions Current Opinion in Electrochemistry. 2: 26-31. DOI: 10.1016/J.Coelec.2017.02.006  0.476
2017 Bonin J, Maurin A, Robert M. Molecular catalysis of the electrochemical and photochemical reduction of CO2 with Fe and Co metal based complexes. Recent advances Coordination Chemistry Reviews. 334: 184-198. DOI: 10.1016/J.Ccr.2016.09.005  0.395
2016 Azcarate I, Costentin C, Robert M, Savéant JM. Through-Space Charge Interaction Substituent Effects in Molecular Catalysis Leading to the Design of the Most Efficient Catalyst of CO2-to-CO Electrochemical Conversion. Journal of the American Chemical Society. PMID 27976580 DOI: 10.1021/Jacs.6B07014  0.482
2016 Maurin A, Robert M. Catalytic CO2-to-CO conversion in water by covalently functionalized carbon nanotubes with a molecular iron catalyst. Chemical Communications (Cambridge, England). 52: 12084-12087. PMID 27709201 DOI: 10.1039/C6Cc05430G  0.336
2016 Maurin A, Ng CO, Chen L, Lau TC, Robert M, Ko CC. Photochemical and electrochemical catalytic reduction of CO2 with NHC-containing dicarbonyl rhenium(i) bipyridine complexes. Dalton Transactions (Cambridge, England : 2003). PMID 27293154 DOI: 10.1039/C6Dt01686C  0.372
2016 Tatin A, Comminges C, Kokoh B, Costentin C, Robert M, Savéant JM. Efficient electrolyzer for CO2 splitting in neutral water using earth-abundant materials. Proceedings of the National Academy of Sciences of the United States of America. 113: 5526-9. PMID 27140621 DOI: 10.1073/Pnas.1604628113  0.482
2016 Sartorel A, Prevedello A, Bazzan I, Dalle Carbonare N, Giuliani A, Bhardwaj S, Africh C, Cepek C, Argazzi R, Bonchio M, Caramori S, Robert M. Heterogeneous and homogeneous routes in water oxidation catalysis starting from Cu(II) complexes with tetraaza macrocyclic ligands. Chemistry, An Asian Journal. PMID 26888601 DOI: 10.1002/Asia.201501446  0.335
2016 Maurin A, Robert M. Noncovalent Immobilization of a Molecular Iron-Based Electrocatalyst on Carbon Electrodes for Selective, Efficient CO2-to-CO Conversion in Water. Journal of the American Chemical Society. 138: 2492-5. PMID 26886174 DOI: 10.1021/Jacs.5B12652  0.392
2016 Azcarate I, Costentin C, Robert M, Savéant J. Dissection of Electronic Substituent Effects in Multielectron–Multistep Molecular Catalysis. Electrochemical CO2-to-CO Conversion Catalyzed by Iron Porphyrins Journal of Physical Chemistry C. 120: 28951-28960. DOI: 10.1021/Acs.Jpcc.6B09947  0.574
2015 Costentin C, Robert M, Savéant JM. Current Issues in Molecular Catalysis Illustrated by Iron Porphyrins as Catalysts of the CO2-to-CO Electrochemical Conversion. Accounts of Chemical Research. 48: 2996-3006. PMID 26559053 DOI: 10.1021/Acs.Accounts.5B00262  0.539
2015 Chen L, Guo Z, Wei XG, Gallenkamp C, Bonin J, Anxolabéhère-Mallart E, Lau KC, Lau TC, Robert M. Molecular Catalysis of the Electrochemical and Photochemical Reduction of CO2 with Earth-Abundant Metal Complexes. Selective Production of CO vs HCOOH by Switching of the Metal Center. Journal of the American Chemical Society. 137: 10918-21. PMID 26267016 DOI: 10.1021/Jacs.5B06535  0.305
2015 Costentin C, Robert M, Savéant JM, Tatin A. Efficient and selective molecular catalyst for the CO2-to-CO electrochemical conversion in water. Proceedings of the National Academy of Sciences of the United States of America. 112: 6882-6. PMID 26038542 DOI: 10.1073/Pnas.1507063112  0.496
2015 Oksdath-Mansilla G, Hajj V, Andrada DM, Argüello JE, Bonin J, Robert M, Peñéñory AB. Photoremoval of protecting groups: mechanistic aspects of 1,3-dithiane conversion to a carbonyl group. The Journal of Organic Chemistry. 80: 2733-9. PMID 25686007 DOI: 10.1021/Jo502953T  0.453
2015 Bouchet LM, Peñeñory AB, Robert M, Argüello JE. Breaking bonds with electrons: stepwise and concerted reductive cleavage of C–S, C–Se and Se–CN bonds in phenacylthiocyanates and phenacylselenocyanates Rsc Advances. 5: 11753-11760. DOI: 10.1039/C4Ra16154H  0.41
2014 Costentin C, Passard G, Robert M, Savéant JM. Ultraefficient homogeneous catalyst for the CO2-to-CO electrochemical conversion. Proceedings of the National Academy of Sciences of the United States of America. 111: 14990-4. PMID 25288744 DOI: 10.1073/Pnas.1416697111  0.456
2014 Costentin C, Passard G, Robert M, Savéant JM. Pendant acid-base groups in molecular catalysts: H-bond promoters or proton relays? Mechanisms of the conversion of CO2 to CO by electrogenerated iron(0)porphyrins bearing prepositioned phenol functionalities. Journal of the American Chemical Society. 136: 11821-9. PMID 25078392 DOI: 10.1021/Ja506193V  0.599
2014 Costentin C, Robert M, Savéant JM, Tard C. Breaking bonds with electrons and protons. Models and examples. Accounts of Chemical Research. 47: 271-80. PMID 24016042 DOI: 10.1021/Ar4001444  0.637
2014 Anxolabéhère-Mallart E, Costentin C, Fournier M, Robert M. Cobalt-bisglyoximato diphenyl complex as a precatalyst for electrocatalytic H2 evolution Journal of Physical Chemistry C. 118: 13377-13381. DOI: 10.1021/Jp500813R  0.341
2014 Bonin J, Costentin C, Robert M, Routier M, Savéant J. Correction to “Proton-Coupled Electron Transfers: pH-Dependent Driving Forces? Fundamentals and Artifacts” Journal of the American Chemical Society. 136: 8484-8484. DOI: 10.1021/Ja412398G  0.532
2014 Bonin J, Chaussemier M, Robert M, Routier M. Homogeneous photocatalytic reduction of CO2 to CO using iron(0) porphyrin catalysts: Mechanism and intrinsic limitations Chemcatchem. 6: 3200-3207. DOI: 10.1002/Cctc.201402515  0.388
2013 Telitel S, Vallet AL, Schweizer S, Delpech B, Blanchard N, Morlet-Savary F, Graff B, Curran DP, Robert M, Lacôte E, Lalevée J. Formation of N-heterocyclic carbene-boryl radicals through electrochemical and photochemical cleavage of the B-S bond in N-heterocyclic carbene-boryl sulfides. Journal of the American Chemical Society. 135: 16938-47. PMID 24111491 DOI: 10.1021/Ja4066267  0.332
2013 Bonin J, Costentin C, Robert M, Routier M, Savéant JM. Proton-coupled electron transfers: PH-dependent driving forces? Fundamentals and artifacts Journal of the American Chemical Society. 135: 14359-14366. PMID 23972082 DOI: 10.1021/Ja406712C  0.61
2013 Costentin C, Drouet S, Passard G, Robert M, Savéant JM. Proton-coupled electron transfer cleavage of heavy-atom bonds in electrocatalytic processes. Cleavage of a C-O bond in the catalyzed electrochemical reduction of CO2. Journal of the American Chemical Society. 135: 9023-31. PMID 23692448 DOI: 10.1021/Ja4030148  0.635
2013 Costentin C, Robert M, Savéant JM. Catalysis of the electrochemical reduction of carbon dioxide. Chemical Society Reviews. 42: 2423-36. PMID 23232552 DOI: 10.1039/C2Cs35360A  0.465
2013 Costentin C, Passard G, Robert M, Savéant J. Concertedness in proton-coupled electron transfer cleavages of carbon–metal bonds illustrated by the reduction of an alkyl cobalt porphyrin Chemical Science. 4: 819-823. DOI: 10.1039/C2Sc21788K  0.625
2013 Ghachtouli SE, Fournier M, Cherdo S, Guillot R, Charlot M, Anxolabéhère-Mallart E, Robert M, Aukauloo A. Monometallic cobalt-trisglyoximato complexes as precatalysts for catalytic H2 evolution in water Journal of Physical Chemistry C. 117: 17073-17077. DOI: 10.1021/Jp405134A  0.36
2013 Bonin J, Costentin C, Robert M, Savéant J, Tard C. Correction to Hydrogen-Bond Relays in Concerted Proton–Electron Transfers Accounts of Chemical Research. 46: 1910-1910. DOI: 10.1021/Ar400175E  0.512
2012 Costentin C, Drouet S, Robert M, Savéant JM. A local proton source enhances CO2 electroreduction to CO by a molecular Fe catalyst. Science (New York, N.Y.). 338: 90-4. PMID 23042890 DOI: 10.1126/science.1224581  0.491
2012 Costentin C, Drouet S, Robert M, Savéant JM. Turnover numbers, turnover frequencies, and overpotential in molecular catalysis of electrochemical reactions. Cyclic voltammetry and preparative-scale electrolysis. Journal of the American Chemical Society. 134: 11235-42. PMID 22670885 DOI: 10.1021/Ja303560C  0.472
2012 Anxolabéhère-Mallart E, Costentin C, Fournier M, Nowak S, Robert M, Savéant JM. Boron-capped tris(glyoximato) cobalt clathrochelate as a precursor for the electrodeposition of nanoparticles catalyzing H2 evolution in water. Journal of the American Chemical Society. 134: 6104-7. PMID 22458714 DOI: 10.1021/ja301134e  0.452
2012 Balasubramanian R, Blondin G, Canales JC, Costentin C, Latour JM, Robert M, Savéant JM. Proton-coupled intervalence charge transfer: concerted processes. Journal of the American Chemical Society. 134: 1906-9. PMID 22260712 DOI: 10.1021/Ja2075482  0.568
2012 Costentin C, Louault C, Robert M, Rogé V, Savéant JM. Reorganization energy and pre-exponential factor from temperature-dependent experiments in electron transfer reactions. A typical example: the reduction of tert-nitrobutane. Physical Chemistry Chemical Physics : Pccp. 14: 1581-4. PMID 22173685 DOI: 10.1039/C2Cp23050J  0.579
2012 Bonin J, Costentin C, Robert M, Savéant JM, Tard C. Hydrogen-bond relays in concerted proton-electron transfers. Accounts of Chemical Research. 45: 372-81. PMID 22029773 DOI: 10.1021/Ar200132F  0.626
2012 Robert M. Proton-coupled electron transfer Energy & Environmental Science. 5: 7695. DOI: 10.1039/C2EE90013K  0.304
2011 Costentin C, Hajj V, Louault C, Robert M, Savéant JM. Concerted proton-electron transfers. Consistency between electrochemical kinetics and their homogeneous counterparts. Journal of the American Chemical Society. 133: 19160-7. PMID 22067039 DOI: 10.1021/Ja206561N  0.63
2011 Bonin J, Robert M. Photoinduced proton-coupled electron transfers in biorelevant phenolic systems Photochemistry and Photobiology. 87: 1190-1203. PMID 21895665 DOI: 10.1111/J.1751-1097.2011.00996.X  0.486
2011 Costentin C, Hajj V, Robert M, Savéant JM, Tard C. Concerted heavy-atom bond cleavage and proton and electron transfers illustrated by proton-assisted reductive cleavage of an O-O bond. Proceedings of the National Academy of Sciences of the United States of America. 108: 8559-64. PMID 21551101 DOI: 10.1073/Pnas.1104952108  0.596
2011 Bonin J, Costentin C, Robert M, Savéant JM. Pyridine as proton acceptor in the concerted proton electron transfer oxidation of phenol Organic and Biomolecular Chemistry. 9: 4064-4069. PMID 21499600 DOI: 10.1039/C1Ob05090G  0.605
2011 Bonin J, Costentin C, Louault C, Robert M, Savéant JM. Water (in Water) as an intrinsically efficient proton acceptor in concerted proton electron transfers Journal of the American Chemical Society. 133: 6668-6674. PMID 21476550 DOI: 10.1021/Ja110935C  0.601
2011 Anxolabéhère-Mallart E, Costentin C, Policar C, Robert M, Savéant JM, Teillout AL. Proton-coupled electron transfers in biomimetic water bound metal complexes. The electrochemical approach. Faraday Discussions. 148: 83-95; discussion 97. PMID 21322479 DOI: 10.1039/C004276E  0.586
2011 Costentin C, Robert M, Savéant JM, Tard C. H-bond relays in proton-coupled electron transfers. Oxidation of a phenol concerted with proton transport to a distal base through an OH relay. Physical Chemistry Chemical Physics : Pccp. 13: 5353-8. PMID 21225050 DOI: 10.1039/C0Cp02275F  0.57
2010 Costentin C, Robert M, Savéant JM. Update 1 of: Electrochemical approach to the mechanistic study of proton-coupled electron transfer. Chemical Reviews. 110: PR1-40. PMID 21192326 DOI: 10.1021/Cr100038Y  0.572
2010 Costentin C, Robert M, Savéant JM. Reorganization energies and pre-exponential factors in the one-electron electrochemical and homogeneous oxidation of phenols coupled with an intramolecular amine-driven proton transfer. Physical Chemistry Chemical Physics : Pccp. 12: 13061-9. PMID 20689874 DOI: 10.1039/C0Cp00017E  0.604
2010 Costentin C, Robert M, Savéant JM. Concerted proton-electron transfers in the oxidation of phenols. Physical Chemistry Chemical Physics : Pccp. 12: 11179-90. PMID 20625575 DOI: 10.1039/C0Cp00063A  0.62
2010 Costentin C, Hajj V, Robert M, Savéant JM, Tard C. Effect of base pairing on the electrochemical oxidation of guanine. Journal of the American Chemical Society. 132: 10142-7. PMID 20597511 DOI: 10.1021/Ja103421F  0.575
2010 Costentin C, Robert M, Savéant JM, Tard C. Inserting a hydrogen-bond relay between proton exchanging sites in proton-coupled electron transfers. Angewandte Chemie (International Ed. in English). 49: 3803-6. PMID 20408150 DOI: 10.1002/Anie.200907192  0.567
2010 Costentin C, Robert M, Savéant JM. Concerted proton-electron transfers: electrochemical and related approaches. Accounts of Chemical Research. 43: 1019-29. PMID 20232879 DOI: 10.1021/Ar9002812  0.608
2010 Bonin J, Costentin C, Louault C, Robert M, Routier M, Savéant JM. Intrinsic reactivity and driving force dependence in concerted proton-electron transfers to water illustrated by phenol oxidation Proceedings of the National Academy of Sciences of the United States of America. 107: 3367-3372. PMID 20139306 DOI: 10.1073/Pnas.0914693107  0.614
2010 ANDRIEUX CP, DIFFERDING E, ROBERT M, SAVEANT J. ChemInform Abstract: Controlling Factors of Stepwise Versus Concerted Reductive Cleavages. Illustrative Examples in the Electrochemical Reductive Breaking of Nitrogen-Halogen Bonds in Aromatic N-Halosultams. Cheminform. 24: no-no. DOI: 10.1002/CHIN.199347049  0.445
2010 Monot J, Solovyev A, Bonin-Dubarle H, Derat É, Curran DP, Robert M, Fensterbank L, Malacria M, Lacôte E. Inside Cover: Generation and Reactions of an Unsubstituted N-Heterocyclic Carbene Boryl Anion (Angew. Chem. Int. Ed. 48/2010) Angewandte Chemie International Edition. 49: 9014-9014. DOI: 10.1002/Anie.201005438  0.329
2010 Monot J, Solovyev A, Bonin-Dubarle H, Derat É, Curran DP, Robert M, Fensterbank L, Malacria M, Lacôte E. Innentitelbild: Generation and Reactions of an Unsubstituted N-Heterocyclic Carbene Boryl Anion (Angew. Chem. 48/2010) Angewandte Chemie. 122: 9198-9198. DOI: 10.1002/Ange.201005438  0.329
2009 Bonin J, Costentin C, Mahet M, Mulon JB, Robert M. Photoinduced reductive cleavage of some chlorobenzylic compounds. New insights from comparison with electrochemically induced reactions Physical Chemistry Chemical Physics. 11: 10275-10280. PMID 19890509 DOI: 10.1039/B911932A  0.398
2009 Costentin C, Louault C, Robert M, Savéant JM. The electrochemical approach to concerted proton--electron transfers in the oxidation of phenols in water. Proceedings of the National Academy of Sciences of the United States of America. 106: 18143-8. PMID 19822746 DOI: 10.1073/Pnas.0910065106  0.577
2009 Costentin C, Robert M, Savéant JM, Teillout AL. Concerted proton-coupled electron transfers in aquo/hydroxo/oxo metal complexes: electrochemistry of [OsII(bpy)2py(OH2)]2+ in water. Proceedings of the National Academy of Sciences of the United States of America. 106: 11829-36. PMID 19584254 DOI: 10.1073/Pnas.0905020106  0.582
2009 Costentin C, Donati L, Robert M. Passage from stepwise to concerted dissociative electron transfer through modulation of electronic states coupling. Chemistry (Weinheim An Der Bergstrasse, Germany). 15: 785-92. PMID 19040226 DOI: 10.1002/Chem.200801240  0.476
2009 Costentin C, Robert M, Savéant JM, Teillout AL. Concerted and stepwise proton-coupled electron transfers in aquo/hydroxo complex couples in water: oxidative electrochemistry of [Os(II)(bpy)(2)(py)(OH(2))](2+). Chemphyschem : a European Journal of Chemical Physics and Physical Chemistry. 10: 191-8. PMID 18816536 DOI: 10.1002/Cphc.200800361  0.611
2008 Costentin C, Louault C, Robert M, Savéant JM. Evidence for concerted proton-electron transfer in the electrochemical oxidation of phenols with water as proton acceptor. Tri-tert-butylphenol. Journal of the American Chemical Society. 130: 15817-9. PMID 18975863 DOI: 10.1021/Ja8064914  0.613
2007 Costentin C, Robert M, Savéant JM. Adiabatic and non-adiabatic concerted proton-electron transfers. Temperature effects in the oxidation of intramolecularly hydrogen-bonded phenols. Journal of the American Chemical Society. 129: 9953-63. PMID 17637055 DOI: 10.1021/Ja071150D  0.62
2007 Costentin C, Robert M, Savéant JM. Concerted proton-electron transfer reactions in water. are the driving force and rate constant depending on pH when water acts as proton donor or acceptor? Journal of the American Chemical Society. 129: 5870-9. PMID 17428051 DOI: 10.1021/Ja067950Q  0.567
2007 Costentin C, Robert M, Saveant J. Acceleration of the Homogeneous and Electrochemical Reductions of Dioxygen in Aprotic Media by Ammonium Ions. Is the Driving Force a Function of NH4+ Concentration? What Is the Mechanism of the Reaction? Journal of Physical Chemistry C. 111: 12877-12880. DOI: 10.1021/Jp0750654  0.615
2006 Boussicault F, Robert M. Electrochemical approach to the repair of oxetanes mimicking DNA (6-4) photoproducts. The Journal of Physical Chemistry. B. 110: 21987-93. PMID 17064168 DOI: 10.1021/Jp062425Z  0.384
2006 Costentin C, Robert M, Savéant JM. Carboxylates as proton-accepting groups in concerted proton-electron transfers. Electrochemistry of the 2,5-dicarboxylate 1,4-hydrobenzoquinone/2,5-dicarboxy 1,4-benzoquinone couple. Journal of the American Chemical Society. 128: 8726-7. PMID 16819855 DOI: 10.1021/Ja0621750  0.611
2006 Costentin C, Robert M, Savéant JM. Electrochemical and homogeneous proton-coupled electron transfers: concerted pathways in the one-electron oxidation of a phenol coupled with an intramolecular amine-driven proton transfer. Journal of the American Chemical Society. 128: 4552-3. PMID 16594674 DOI: 10.1021/Ja060527X  0.631
2006 Costentin C, Robert M, Savéant J. Electrochemical concerted proton and electron transfers. Potential-dependent rate constant, reorganization factors, proton tunneling and isotope effects Journal of Electroanalytical Chemistry. 588: 197-206. DOI: 10.1016/J.Jelechem.2005.12.027  0.571
2006 Costentin C, Robert M, Savéant J. Electron transfer and bond breaking: Recent advances Chemical Physics. 324: 40-56. DOI: 10.1016/J.Chemphys.2005.09.029  0.551
2006 Costentin C, Robert M, Saveant J. Electron Transfer and Bond Breaking — Recent Advances Cheminform. 37. DOI: 10.1002/CHIN.200637258  0.504
2005 Costentin C, Louault C, Robert M, Teillout AL. Sticky dissociative electron transfer to polychloroacetamides. In-cage ion-dipole interaction control through the dipole moment and intramolecular hydrogen bond. The Journal of Physical Chemistry. A. 109: 2984-90. PMID 16833619 DOI: 10.1021/Jp0442549  0.454
2005 Diekert G, Gugova D, Limoges B, Robert M, Savéant JM. Electroenzymatic reactions. Investigation of a reductive dehalogenase by means of electrogenerated redox cosubstrates. Journal of the American Chemical Society. 127: 13583-8. PMID 16190723 DOI: 10.1021/Ja053403D  0.545
2005 Costentin C, Evans DH, Robert M, Savéant JM, Singh PS. Electrochemical approach to concerted proton and electron transfers. Reduction of the water-superoxide ion complex. Journal of the American Chemical Society. 127: 12490-1. PMID 16144387 DOI: 10.1021/Ja053911N  0.568
2005 Costentin C, Robert M, Savéant JM. Does catalysis of reductive dechlorination of tetra- and trichloroethylenes by vitamin B12 and corrinoid-based dehalogenases follow an electron transfer mechanism? Journal of the American Chemical Society. 127: 12154-5. PMID 16131156 DOI: 10.1021/Ja0520464  0.598
2004 Costentin C, Robert M, Savéant JM. Stepwise and concerted electron-transfer/bond breaking reactions. solvent control of the existence of unstable pi ion radicals and of the activation barriers of their heterolytic cleavage. Journal of the American Chemical Society. 126: 16834-40. PMID 15612722 DOI: 10.1021/Ja045294T  0.568
2004 Costentin C, Robert M, Savéant JM. Fragmentation of aryl halide pi anion radicals. Bending of the cleaving bond and activation vs driving force relationships. Journal of the American Chemical Society. 126: 16051-7. PMID 15584739 DOI: 10.1021/Ja045989U  0.577
2004 Boussicault F, Krüger O, Robert M, Wille U. Dissociative electron transfer to and from pyrimidine cyclobutane dimers: an electrochemical study. Organic and Biomolecular Chemistry. 2: 2742-2750. PMID 15455145 DOI: 10.1039/B406923D  0.422
2003 Costentin C, Robert M, Savéant JM. Successive removal of chloride ions from organic polychloride pollutants. Mechanisms of reductive electrochemical elimination in aliphatic gem-polychlorides, alpha,beta-polychloroalkenes, and alpha,beta-polychloroalkanes in mildly protic medium. Journal of the American Chemical Society. 125: 10729-39. PMID 12940759 DOI: 10.1021/Ja036141T  0.59
2003 Costentin C, Robert M, Savéant JM. Activation barriers in the homolytic cleavage of radicals and ion radicals. Journal of the American Chemical Society. 125: 105-12. PMID 12515511 DOI: 10.1021/Ja027287F  0.508
2002 Cardinale A, Isse AA, Gennaro A, Robert M, Savéant JM. Dissociative electron transfer to haloacetonitriles. An example of the dependency of in-cage ion-radical interactions upon the leaving group. Journal of the American Chemical Society. 124: 13533-9. PMID 12418908 DOI: 10.1021/Ja0275212  0.49
2001 Pause L, Robert M, Savéant JM. Stabilities of ion/radical adducts in the liquid phase as derived from the dependence of electrochemical cleavage reactivities upon solvent. Journal of the American Chemical Society. 123: 11908-16. PMID 11724597 DOI: 10.1021/Ja0117985  0.468
2001 Pause L, Robert M, Savéant JM. Stepwise and concerted pathways in photoinduced and thermal electron-transfer/bond-breaking reactions. experimental illustration of similarities and contrasts. Journal of the American Chemical Society. 123: 4886-95. PMID 11457315 DOI: 10.1021/Ja004234U  0.57
2001 Pause L, Robert M, Heinicke J, Kühl O. Radical anions of carbenes and carbene homologues. DFT study and preliminary experimental results Journal of the Chemical Society-Perkin Transactions 1. 1383-1388. DOI: 10.1039/B101228M  0.37
2000 Pause L, Robert M, Savéant JM. Quantum yields lower than unity in photo- induced dissociative electron transfers: the reductive cleavage of carbon tetrachloride. Chemphyschem : a European Journal of Chemical Physics and Physical Chemistry. 1: 199-205. PMID 23696321 DOI: 10.1002/1439-7641(20001215)1:4<199::Aid-Cphc199>3.0.Co;2-W  0.567
2000 Costentin C, Robert M, Savéant J. Stepwise and Concerted Pathways in Thermal and Photoinduced Electron-Transfer/Bond-Breaking Reactions Journal of Physical Chemistry A. 104: 7492-7501. DOI: 10.1021/Jp994426F  0.558
1999 Adcock W, Blokhin AV, Elsey GM, Head NH, Krstic AR, Levin MD, Michl J, Munton J, Pinkhassik E, Robert M, Savéant JM, Shtarev A, Stibor I. Manifestations of Bridgehead-Bridgehead Interactions in the Bicyclo[1.1.1]pentane Ring System. The Journal of Organic Chemistry. 64: 2618-2625. PMID 11674328 DOI: 10.1021/Jo982124O  0.48
1999 Pause L, Robert M, Savéant J. Can Single-Electron Transfer Break an Aromatic Carbon−Heteroatom Bond in One Step? A Novel Example of Transition between Stepwise and Concerted Mechanisms in the Reduction of Aromatic Iodides Journal of the American Chemical Society. 121: 7158-7159. DOI: 10.1021/Ja991365Q  0.615
1998 Robert M, Likhotvorik I, Platz MS, Abbot SC, Kirchhoff MM, Johnson R. Laser flash photolysis study of alkylhalocarbenes generated from non-nitrogenous precursors Journal of Physical Chemistry A. 102: 1507-1513. DOI: 10.1021/Jp972464Y  0.49
1998 Robert M, Snoonian JR, Platz MS, Wu G, Hong H, Thamattoor DM, Jones M. A laser flash photolysis study of dibromocarbene and bromochlorocarbene Journal of Physical Chemistry A. 102: 587-592. DOI: 10.1021/Jp9723980  0.505
1997 Chen T, Platz MS, Robert M, Savéant JM, Marcinek A, Rogowski J, Gebicki J, Zhu Z, Bally T. Electron transfer chemistry of psoralen and coumarin derivatives by means of radiolytic and electrochemical experiments Journal of Physical Chemistry A. 101: 2124-2130. DOI: 10.1021/Jp963097D  0.678
1996 Robert M, Toscano JP, Platz MS, Abbot SC, Kirchhoff MM, Johnson RP. Laser flash photolysis study of chlorocarbene Journal of Physical Chemistry. 100: 18426-18430. DOI: 10.1021/Jp962333H  0.653
1995 Andrieux CP, Robert M, Saveant J. Role of Environmental Factors in the Dynamics of Intramolecular Dissociative Electron Transfer. Effect of Solvation and Ion-Pairing on Cleavage Rates of Anion Radicals Journal of the American Chemical Society. 117: 9340-9346. DOI: 10.1021/Ja00141A028  0.538
1994 Andrieux CP, Robert M, Saeva FD, Saveant J-. Passage from Concerted to Stepwise Dissociative Electron Transfer as a Function of the Molecular Structure and of the Energy of the Incoming Electron. Electrochemical Reduction of Aryldialkyl Sulfonium Cations Journal of the American Chemical Society. 116: 7864-7871. DOI: 10.1021/Ja00096A049  0.573
1993 Andrieux CP, Differding E, Robert M, Saveant JM. Controlling factors of stepwise versus concerted reductive cleavages. Illustrative examples in the electrochemical reductive breaking of nitrogen-halogen bonds in aromatic N-halosultams Journal of the American Chemical Society. 115: 6592-6599. DOI: 10.1021/JA00068A016  0.444
Show low-probability matches.