Xiaochen Cai, Ph.D. - Publications

Affiliations: 
Chemistry University of Miami, Coral Gables, FL 
Area:
Organometallic Chemistry

12 high-probability publications. We are testing a new system for linking publications to authors. You can help! If you notice any inaccuracies, please sign in and mark papers as correct or incorrect matches. If you identify any major omissions or other inaccuracies in the publication list, please let us know.

Year Citation  Score
2018 Koppaka A, Cai X, Majumdar S, Etezadi S, Serafim LF, Temprado M, Captain B, Hoff CD. Reactions of Sn(Si( Bu)2Me)3 with HM(CO)3C5R5 (M = Cr or Mo, R = H or CH3) and Hg. Ionic, covalent, and μ-CO bonding patterns between transition metals and tin Inorganica Chimica Acta. 469: 550-560. DOI: 10.1016/J.Ica.2017.09.052  0.586
2017 Palluccio TD, Cai X, Majumdar S, Serafim LF, Tomson NC, Wieghardt K, Cazin CSJ, Nolan SP, Rybak-Akimova EV, Fernández-González MA, Temprado M, Captain B, Hoff CD. Ligand-directed Reactivity in Dioxygen and Water Binding to cis-[Pd(NHC)2(η2-O2)]. Journal of the American Chemical Society. PMID 29172489 DOI: 10.1021/Jacs.7B09905  0.686
2017 Cai X, Majumdar S, Serafim LF, Temprado M, Nolan SP, Cazin CS, Captain B, Hoff CD. N-heterocyclic carbene complexes of palladium in oxygen atom transfer reactions involving the making and breaking of N-O bonds Inorganica Chimica Acta. 468: 285-293. DOI: 10.1016/J.Ica.2017.05.069  0.714
2016 Cai X, Majumdar S, Fortman GC, Koppaka A, Serafim L, Captain B, Temprado M, Hoff CD. Thermodynamic, Kinetic, Structural, and Computational Studies of the Ph3Sn-H, Ph3Sn-SnPh3, and Ph3Sn-Cr(CO)3C5Me5 Bond Dissociation Enthalpies. Inorganic Chemistry. PMID 27704803 DOI: 10.1021/Acs.Inorgchem.6B01978  0.716
2014 Majumdar S, Stauber JM, Palluccio TD, Cai X, Velian A, Rybak-Akimova EV, Temprado M, Captain B, Cummins CC, Hoff CD. Role of axial base coordination in isonitrile binding and chalcogen atom transfer to vanadium(III) complexes. Inorganic Chemistry. 53: 11185-96. PMID 25280113 DOI: 10.1021/Ic5017005  0.662
2013 Palluccio TD, Rybak-Akimova EV, Majumdar S, Cai X, Chui M, Temprado M, Silvia JS, Cozzolino AF, Tofan D, Velian A, Cummins CC, Captain B, Hoff CD. Thermodynamic and kinetic study of cleavage of the N-O bond of N-oxides by a vanadium(III) complex: enhanced oxygen atom transfer reaction rates for adducts of nitrous oxide and mesityl nitrile oxide. Journal of the American Chemical Society. 135: 11357-72. PMID 23805977 DOI: 10.1021/Ja405395Z  0.661
2013 Karikachery AR, Lee HB, Masjedi M, Ross A, Moody MA, Cai X, Chui M, Hoff CD, Sharp PR. High quantum yield molecular bromine photoelimination from mononuclear platinum(IV) complexes. Inorganic Chemistry. 52: 4113-9. PMID 23484618 DOI: 10.1021/Ic4004998  0.57
2013 Temprado M, Majumdar S, Cai X, Captain B, Hoff CD. Synthesis, structure, and thermochemistry of adduct formation between N-heterocyclic carbenes and isocyanates or mesitylnitrile oxide Structural Chemistry. 24: 2059-2068. DOI: 10.1007/S11224-013-0305-2  0.604
2012 Cozzolino AF, Tofan D, Cummins CC, Temprado M, Palluccio TD, Rybak-Akimova EV, Majumdar S, Cai X, Captain B, Hoff CD. Two-step binding of O2 to a vanadium(III) trisanilide complex to form a non-vanadyl vanadium(V) peroxo complex. Journal of the American Chemical Society. 134: 18249-52. PMID 23082724 DOI: 10.1021/Ja309621H  0.656
2011 Cai X, Majumdar S, Fortman GC, Frutos LM, Temprado M, Clough CR, Cummins CC, Germain ME, Palluccio T, Rybak-Akimova EV, Captain B, Hoff CD. Thermodynamic, kinetic, and mechanistic study of oxygen atom transfer from mesityl nitrile oxide to phosphines and to a terminal metal phosphido complex. Inorganic Chemistry. 50: 9620-30. PMID 21875050 DOI: 10.1021/Ic2013599  0.73
2011 Cai X, Majumdar S, Fortman GC, Cazin CS, Slawin AM, Lhermitte C, Prabhakar R, Germain ME, Palluccio T, Nolan SP, Rybak-Akimova EV, Temprado M, Captain B, Hoff CD. Oxygen binding to [Pd(L)(L')] (L= NHC, L' = NHC or PR3, NHC = N-heterocyclic carbene). synthesis and structure of a paramagnetic trans-[Pd(NHC)2(η(1)-O2)2] complex. Journal of the American Chemical Society. 133: 1290-3. PMID 21204538 DOI: 10.1021/Ja1103348  0.721
2009 Achord P, Fujita E, Muckerman JT, Scott B, Fortman GC, Temprado M, Cai X, Captain B, Isrow D, Weir JJ, McDonough JE, Hoff CD. Experimental and computational studies of binding of dinitrogen, nitriles, azides, diazoalkanes, pyridine, and pyrazines to M(PR(3))(2)(CO)(3) (M = Mo, W; R = Me, (i)Pr). Inorganic Chemistry. 48: 7891-904. PMID 19621935 DOI: 10.1021/Ic900764E  0.697
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