Rajendra Rathore - Publications

Affiliations: 
Chemistry Marquette University, Milwaukee, WI, United States 
Area:
Physical Chemistry, Organic Chemistry, Materials Science Engineering
Website:
http://www.marquette.edu/chem/Rathore.shtml

154 high-probability publications. We are testing a new system for linking publications to authors. You can help! If you notice any inaccuracies, please sign in and mark papers as correct or incorrect matches. If you identify any major omissions or other inaccuracies in the publication list, please let us know.

Year Citation  Score
2023 Rathore R, Abdelwahed SH. Design and Synthesis of Cofacially-Arrayed Polyfluorene Wires for Electron and Energy Transfer Studies. Molecules (Basel, Switzerland). 28. PMID 37175127 DOI: 10.3390/molecules28093717  0.75
2022 Rathore R, Lindeman SV, Abdelwahed SH. Design, Synthesis, Electronic Properties, and X-ray Structural Characterization of Various Modified Electron-Rich Calixarene Derivatives and Their Conversion to Stable Cation Radical Salts. Molecules (Basel, Switzerland). 27. PMID 36144725 DOI: 10.3390/molecules27185994  0.782
2021 Hossain MM, Thakur K, Talipov MR, Lindeman SV, Mirzaei S, Rathore R. Regioselectivity in the Scholl Reaction: Mono and Double [7]Helicenes. Organic Letters. PMID 34126005 DOI: 10.1021/acs.orglett.1c01706  0.544
2020 Thakur K, Wang D, Mirzaei S, Rathore R. Electron transfer induced self-assembly of a molecular tweezer platform. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 32608146 DOI: 10.1002/Chem.202001919  0.651
2019 Mirzaei S, Wang D, Lindeman SV, Timerghazin QK, Rathore R. Redox-Induced Molecular Actuators: The Case of Oxy-Alternate Bridged Cyclotetraveratrylene. Organic Letters. PMID 31553195 DOI: 10.1021/Acs.Orglett.9B02971  0.389
2019 Wang D, Mirzaei S, Lindeman SV, Rathore R. Accessing highly electron-rich calix[n]arene (n = 4 and 8) derivatives from acid-catalyzed condensation of 1,3,5-tripropoxybenzene Tetrahedron Letters. 60: 151215. DOI: 10.1016/J.Tetlet.2019.151215  0.415
2019 Rathore R, Wadumethrige SH. Highly robust cation radical salts: Aromatic oxidants from cycloannulated aromatic donors Journal of Photochemistry and Photobiology a: Chemistry. 382: 111882. DOI: 10.1016/J.Jphotochem.2019.111882  0.826
2019 Rathore R, Wadumethrige SH. Non- planar dodecaalkoxy-hexa-peri-hexabenzocoronene with six reversible oxidation States Journal of Photochemistry and Photobiology a: Chemistry. 382: 111881. DOI: 10.1016/J.Jphotochem.2019.111881  0.789
2019 Abzhanova A, Ivanova LV, Wang D, Navale TS, Abdelwahed SH, Ivanov MV, Lindeman S, Rathore R, Reid SA. Charge-transfer or excimeric state? Exploring the nature of the excited state in cofacially arrayed polyfluorene derivatives Journal of Photochemistry and Photobiology a: Chemistry. 374: 125-130. DOI: 10.1016/J.Jphotochem.2019.01.030  0.801
2019 Vyas VS, Lindeman SV, Rathore R. Photophysical properties of 1,3,6,8-tetraarylpyrenes and their cation radicals Journal of Photochemistry and Photobiology a: Chemistry. 375: 209-218. DOI: 10.1016/J.Jphotochem.2019.01.014  0.789
2018 Wang D, Zhang D, Lindeman SV, Rathore R. Calix[4]arene-Based Bis(Nitric Oxide) Complexes: Synthesis, Physical Properties, and Structural Characterization. Chemistry, An Asian Journal. PMID 30549456 DOI: 10.1002/Asia.201801683  0.38
2018 Kokkin D, Ivanov M, Loman J, Cai JZ, Uhler B, Reilly N, Rathore R, Reid SA. - stacking vs. C-H/ interaction: Excimer formation and charge resonance stabilization in van der Waals clusters of 9,9'-dimethylfluorene. The Journal of Chemical Physics. 149: 134314. PMID 30292228 DOI: 10.1063/1.5044648  0.373
2018 Ivanov MV, Wang D, Zhang D, Rathore R, Reid SA. Vertical vs. adiabatic ionization energies in solution and gas-phase: probing ionization-induced reorganization in conformationally-mobile bichromophoric actuators using photoelectron spectroscopy, electrochemistry and theory. Physical Chemistry Chemical Physics : Pccp. PMID 30283939 DOI: 10.1039/C8Cp02936A  0.319
2018 Wang D, Ivanova LV, Ivanov M, Mirzaei S, Timerghazin Q, Reid S, Rathore R. An electron-rich calix[4]arene-based receptor with unprecedented binding affinity for nitric oxide. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 30238528 DOI: 10.1002/Chem.201804245  0.428
2018 Wang D, Ivanov MV, Mirzaei S, Lindeman SV, Rathore R. An electron-transfer induced conformational transformation: from non-cofacial "sofa" to cofacial "boat" in cyclotetraveratrylene (CTTV) and formation of charge transfer complexes. Organic & Biomolecular Chemistry. PMID 30047977 DOI: 10.1039/C8Ob01118D  0.425
2018 Thakur K, Wang D, Lindeman SV, Rathore R. A synthesis of doubly-annulated m-terphenyl based molecular tweezers and their charge-transfer complexes with DDQ as a guest. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 30033629 DOI: 10.1002/Chem.201803137  0.615
2018 Wang D, Talipov MR, Ivanov MV, Mirzaei S, Lindeman SV, Cai S, Rathore R, Reid SA. Molecular Actuators in Action: Electron Transfer-Induced Conformation Transformation in Cofacially Arrayed Polyfluorenes. The Journal of Physical Chemistry Letters. PMID 29985630 DOI: 10.1021/Acs.Jpclett.8B01918  0.421
2018 Ivanov MV, Reid SA, Rathore R. Game of Frontier Orbitals: A View on the Rational Design of Novel Charge-Transfer Materials. The Journal of Physical Chemistry Letters. PMID 29952570 DOI: 10.1021/Acs.Jpclett.8B01093  0.375
2018 Ivanova LV, Navale TS, Wang D, Lindeman S, Ivanov MV, Rathore R. Towards the rational design of novel charge-transfer materials: biaryls with a dihedral angle-independent hole delocalization mechanism. Chemical Communications (Cambridge, England). PMID 29770400 DOI: 10.1039/C8Cc02595A  0.782
2018 Wang D, Ivanov M, Kokkin D, Loman J, Cai JZ, Rathore R, Reid S. Role of Torsional Dynamics on Hole and Exciton Stabilization in pi-Stacked Assemblies: Design of Novel Rigid Torsionomers of a Cofacial Bifluorene. Angewandte Chemie (International Ed. in English). PMID 29733488 DOI: 10.1002/Anie.201804337  0.379
2018 Ivanov MV, Wang D, Rathore R. From Static to Dynamic: Electron Density of HOMO at Biaryl Linkage Controls the Mechanism of Hole Delocalization. Journal of the American Chemical Society. 140: 4765-4769. PMID 29595254 DOI: 10.1021/Jacs.8B00466  0.377
2018 Ivanov M, Wang D, Navale T, Lindeman S, Rathore R. From Intramolecular (Circular) in an Isolated Molecule to Intermolecular Hole Delocalization in a Two-Dimensional Solid-State Assembly: The Case of Pillarene. Angewandte Chemie (International Ed. in English). PMID 29327390 DOI: 10.1002/Anie.201712159  0.786
2018 Ivanov MV, Shukla R, Lindeman SV, Wang D, Rathore R. Pyrene-Like HOMO Governs Polaron Delocalization in Model Graphitic Strips: A Combined Experimental and Computational Analysis Journal of Physical Chemistry C. 122: 24527-24534. DOI: 10.1021/Acs.Jpcc.8B06068  0.443
2018 Hossain MM, Ivanov MV, Wang D, Reid SA, Rathore R. Spreading Electron Density Thin: Increasing the Chromophore Size in Polyaromatic Wires Decreases Interchromophoric Electronic Coupling Journal of Physical Chemistry C. 122: 17668-17675. DOI: 10.1021/Acs.Jpcc.8B05299  0.404
2018 Ivanova LV, Wang D, Lindeman SV, Ivanov MV, Rathore R. Probing Charge Delocalization in Solid State Polychromophoric Cation Radicals Using X-ray Crystallography and DFT Calculations Journal of Physical Chemistry C. 122: 9339-9345. DOI: 10.1021/Acs.Jpcc.8B02184  0.441
2018 Ivanov MV, Talipov MR, Navale TS, Rathore R. Ask Not How Many, But Where They Are: Substituents Control Energetic Ordering of Frontier Orbitals/Electronic Structures in Isomeric Methoxy-Substituted Dibenzochrysenes The Journal of Physical Chemistry C. 122: 2539-2545. DOI: 10.1021/Acs.Jpcc.7B11232  0.793
2017 Navale TS, Ivanov MV, Hossain MM, Rathore R. FHBC, a Hexa-peri-hexabenzocoronene-Fluorene Hybrid: A Platform for Highly Soluble, Easily Functionalizable HBCs with an Expanded Graphitic Core. Angewandte Chemie (International Ed. in English). PMID 29194947 DOI: 10.1002/Anie.201711739  0.755
2017 Ivanov MV, Reilly N, Uhler B, Kokkin D, Rathore R, Reid SA. Cofacially Arrayed Polyfluorenes: Spontaneous Formation of π-Stacked Assemblies in the Gas Phase. The Journal of Physical Chemistry Letters. 5272-5276. PMID 29020769 DOI: 10.1021/Acs.Jpclett.7B02627  0.365
2017 Ivanov MV, Wang D, Wadumethridge SH, Rathore R. When Substituents Don't Matter: Frontier Orbitals Explain Unusually High and Invariant Oxidation Potential in Alkoxy-, Alkyl- and H-substituted Iptycenes. The Journal of Physical Chemistry Letters. PMID 28825830 DOI: 10.1021/Acs.Jpclett.7B01971  0.387
2017 Bongard RD, Lepley M, Thakur K, Talipov MR, Nayak J, Lipinski RAJ, Bohl C, Sweeney N, Ramchandran R, Rathore R, Sem DS. Serendipitous discovery of light-induced (In Situ) formation of an Azo-bridged dimeric sulfonated naphthol as a potent PTP1B inhibitor. Bmc Biochemistry. 18: 10. PMID 28569147 DOI: 10.1186/S12858-017-0083-3  0.504
2017 Ivanov M, Wadumethrige S, Wang D, Rathore R. Unraveling the Coulombic forces in electronically decoupled bichromophoric systems during two successive electron transfers. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 28513900 DOI: 10.1002/Chem.201702211  0.805
2017 Ivanov MV, Chebny VJ, Talipov MR, Rathore R. Poly-p-hydroquinone ethers: Isoenergetic Molecular Wires with Length-Invariant Oxidation Potentials and Cation Radical Excitation Energies. Journal of the American Chemical Society. PMID 28282988 DOI: 10.1021/Jacs.7B01226  0.812
2017 Ivanov MV, Thakur K, Bhatnagar A, Rathore R. Isolation of a chiral anthracene cation radical: X-ray crystallography and computational interrogation of its racemization. Chemical Communications (Cambridge, England). PMID 28203653 DOI: 10.1039/C6Cc10307C  0.649
2017 Ivanov MV, Wadumethrige SH, Wang D, Rathore R. Through-Space or Through-Bond? The Important Role of Cofaciality in Orbital Reordering and Its Implications for Hole (De)stabilization in Polychromophoric Assemblies The Journal of Physical Chemistry C. 121: 15639-15643. DOI: 10.1021/Acs.Jpcc.7B05804  0.809
2017 Uhler B, Ivanov MV, Kokkin D, Reilly N, Rathore R, Reid SA. Effect of Facial Encumbrance on Excimer Formation and Charge Resonance Stabilization in Model Bichromophoric Assemblies Journal of Physical Chemistry C. 121: 15580-15588. DOI: 10.1021/Acs.Jpcc.7B04255  0.381
2017 Ivanov MV, Thakur K, Boddeda A, Wang D, Rathore R. Nodal Arrangement of HOMO Controls the Turning On/Off the Electronic Coupling in Isomeric Polypyrene Wires The Journal of Physical Chemistry C. 121: 9202-9208. DOI: 10.1021/Acs.Jpcc.7B02264  0.656
2017 Ivanov MV, Talipov MR, Boddeda A, Abdelwahed SH, Rathore R. Hückel Theory + Reorganization Energy = Marcus–Hush Theory: Breakdown of the 1/n Trend in π-Conjugated Poly-p-phenylene Cation Radicals Is Explained The Journal of Physical Chemistry C. 121: 1552-1561. DOI: 10.1021/Acs.Jpcc.6B12111  0.733
2016 Wang D, Talipov MR, Ivanov MV, Rathore R. Energy Gap between the Poly-p-phenylene Bridge and Donor Groups Controls the Hole Delocalization in Donor-Bridge-Donor Wires. Journal of the American Chemical Society. 138: 16337-16344. PMID 27998092 DOI: 10.1021/Jacs.6B09209  0.398
2016 Talipov MR, Navale TS, Hossain MM, Shukla R, Ivanov MV, Rathore R. Dihedral Angle-Controlled Crossover from Static Hole Delocalization to Dynamic Hopping in Biaryl Cation Radicals. Angewandte Chemie (International Ed. in English). PMID 27897375 DOI: 10.1002/Anie.201609695  0.785
2016 Reilly N, Ivanov MV, Uhler B, Talipov MR, Rathore R, Reid SA. First Experimental Evidence for the Diverse Requirements of Excimer vs. Hole Stabilization in π-Stacked Assemblies. The Journal of Physical Chemistry Letters. PMID 27447947 DOI: 10.1021/Acs.Jpclett.6B01201  0.364
2016 Talipov MR, Ivanov MV, Reid SA, Rathore R. Two's Company, Three's a Crowd: Exciton Localization in Cofacially-Arrayed Polyfluorenes. The Journal of Physical Chemistry Letters. PMID 27409718 DOI: 10.1021/Acs.Jpclett.6B01268  0.337
2016 Talipov MR, Hossain MM, Boddeda A, Thakur K, Rathore R. A search for blues brothers: X-ray crystallographic/spectroscopic characterization of the tetraarylbenzidine cation radical as a product of aging of solid magic blue. Organic & Biomolecular Chemistry. 14: 2961-8. PMID 26878458 DOI: 10.1039/C6Ob00140H  0.679
2016 Talipov MR, Abdelwahed SH, Thakur K, Reid SA, Rathore R. From Wires to Cables: Attempted Synthesis of 1,3,5-Trifluorenylcyclohexane as a Platform for Molecular Cables. The Journal of Organic Chemistry. PMID 26783949 DOI: 10.1021/Acs.Joc.5B02792  0.788
2016 Navale TS, Talipov MR, Shukla R, Rathore R. Interplay between Entropy and Enthalpy in (Intramolecular) Cyclophane-Like Folding versus (Intermolecular) Dimerization of Diarylalkane Cation Radicals Journal of Physical Chemistry C. 120: 19558-19565. DOI: 10.1021/Acs.Jpcc.6B07006  0.79
2016 Talipov MR, Ivanov MV, Rathore R. Inclusion of Asymptotic Dependence of Reorganization Energy in the Modified Marcus-Based Multistate Model Accurately Predicts Hole Distribution in Poly-p-phenylene Wires Journal of Physical Chemistry C. 120: 6402-6408. DOI: 10.1021/Acs.Jpcc.6B00514  0.32
2016 Khan FA, Wang D, Pemberton B, Talipov MR, Rathore R. Toroidal delocalization of a single electron through circularly-arrayed benzophenone chromophores in hexakis(4-benzoylphenyl)benzene Journal of Photochemistry and Photobiology a: Chemistry. DOI: 10.1016/J.Jphotochem.2016.05.002  0.466
2016 Talipov MR, Boddeda A, Hossain MM, Rathore R. Quantitative generation of cation radicals and dications using aromatic oxidants: Effect of added electrolyte on the redox potentials of aromatic electron donors Journal of Physical Organic Chemistry. 29: 227-233. DOI: 10.1002/Poc.3523  0.447
2015 Talipov MR, Jasti R, Rathore R. A Circle Has No End: Role of Cyclic Topology and Accompanying Structural Reorganization on the Hole Distribution in Cyclic and Linear Poly-p-phenylene Molecular Wires. Journal of the American Chemical Society. PMID 26545043 DOI: 10.1021/Jacs.5B09596  0.412
2015 Talipov MR, Navale TS, Rathore R. The HOMO Nodal Arrangement in Polychromophoric Molecules and Assemblies Controls the Interchromophoric Electronic Coupling. Angewandte Chemie (International Ed. in English). 54: 14468-72. PMID 26425818 DOI: 10.1002/Anie.201506402  0.785
2015 Talipov MR, Boddeda A, Lindeman SV, Rathore R. Does Koopmans' Paradigm for 1-Electron Oxidation Always Hold? Breakdown of IP/Eox Relationship for p-Hydroquinone Ethers and the Role of Methoxy Group Rotation. The Journal of Physical Chemistry Letters. 3373-3378. PMID 26267839 DOI: 10.1021/Acs.Jpclett.5B01532  0.452
2014 Talipov MR, Boddeda A, Timerghazin QK, Rathore R. Key Role of End-Capping Groups in Optoelectronic Properties of Poly-p-phenylene Cation Radicals. The Journal of Physical Chemistry. C, Nanomaterials and Interfaces. 118: 21400-21408. PMID 25264475 DOI: 10.1021/Jp5082752  0.434
2014 Talipov MR, Hewage JS, Lindeman SV, Gardinier JR, Rathore R. Comment on "synthesis, characterization, and structures of persistent aniline radical cation": it is a protonated aniline and not an aniline radical cation. Angewandte Chemie (International Ed. in English). 53: 938-42. PMID 24446126 DOI: 10.1002/Anie.201305293  0.386
2014 Lindeman S, Talipov M, Wadumethrige S, Dolomanov O, Rathore R. Electronic interactions in 1D-π-assemblies from TLS analysis of thermal motion Acta Crystallographica Section a Foundations and Advances. 70: C659-C659. DOI: 10.1107/S2053273314093401  0.812
2014 Aryanpour K, Roberts A, Sandhu A, Rathore R, Shukla A, Mazumdar S. Subgap two-photon states in polycyclic aromatic hydrocarbons: Evidence for strong electron correlations Journal of Physical Chemistry C. 118: 3331-3339. DOI: 10.1021/Jp410793R  0.361
2013 Talipov MR, Timerghazin QK, Rathore R. Controlling the structure of reactive intermediates via incipient covalent bonding with the counterions: Coexistence of two distinct forms of the C 6F6 cation radical in a single crystal Journal of Physical Chemistry C. 117: 23568-23574. DOI: 10.1021/Jp408912G  0.401
2012 Qi H, Chang J, Abdelwahed SH, Thakur K, Rathore R, Bard AJ. Electrochemistry and electrogenerated chemiluminescence of π-stacked poly(fluorenemethylene) oligomers. Multiple, interacting electron transfers. Journal of the American Chemical Society. 134: 16265-74. PMID 22946643 DOI: 10.1021/Ja3057997  0.793
2012 Navale TS, Thakur K, Vyas VS, Wadumethrige SH, Shukla R, Lindeman SV, Rathore R. Charge delocalization in self-assembled mixed-valence aromatic cation radicals. Langmuir : the Acs Journal of Surfaces and Colloids. 28: 71-83. PMID 21882882 DOI: 10.1021/La202611W  0.805
2012 Lindeman S, Wadumethrige S, Rathore R, Dolomanov O. Thermal motion in the crystals of octamethylanthracene and its ion-radical salts Acta Crystallographica Section a Foundations of Crystallography. 68: s247-s247. DOI: 10.1107/S0108767312095207  0.766
2012 Navale TS, Rathore R. A practical synthesis of 1,4,5,8-tetramethoxyanthracene from inexpensive and readily available 1,8-dihydroxyanthraquinone Synthesis. 44: 805-809. DOI: 10.1055/S-0031-1289695  0.747
2011 Navale TS, Thakur K, Rathore R. Sequential oxidative transformation of tetraarylethylenes to 9,10-diarylphenanthrenes and dibenzo[g,p]chrysenes using DDQ as an oxidant. Organic Letters. 13: 1634-7. PMID 21361296 DOI: 10.1021/Ol200069C  0.785
2011 Lindeman S, Vyas V, Rathore R. Incommensurate electronic motifs in tetramethylpyrene polyiodide crystals Acta Crystallographica Section a Foundations of Crystallography. 67: C755-C755. DOI: 10.1107/S0108767311080949  0.734
2011 Wang X, Rathore R, Songtipya P, Jimenez-Gasco MDM, Manias E, Wilkie CA. EVA-layered double hydroxide (nano)composites: Mechanism of fire retardancy Polymer Degradation and Stability. 96: 301-313. DOI: 10.1016/J.Polymdegradstab.2010.03.014  0.323
2010 He J, Crase JL, Wadumethrige SH, Thakur K, Dai L, Zou S, Rathore R, Hartley CS. ortho-Phenylenes: unusual conjugated oligomers with a surprisingly long effective conjugation length. Journal of the American Chemical Society. 132: 13848-57. PMID 20831203 DOI: 10.1021/Ja106050S  0.788
2010 Zhai L, Shukla R, Wadumethrige SH, Rathore R. Probing the arenium-ion (protontransfer) versus the cation-radical (electron transfer) mechanism of Scholl reaction using DDQ as oxidant. The Journal of Organic Chemistry. 75: 4748-60. PMID 20575516 DOI: 10.1021/Jo100611K  0.801
2010 Vura-Weis J, Abdelwahed SH, Shukla R, Rathore R, Ratner MA, Wasielewski MR. Crossover from single-step tunneling to multistep hopping for molecular triplet energy transfer. Science (New York, N.Y.). 328: 1547-50. PMID 20558715 DOI: 10.1126/Science.1189354  0.753
2010 Shukla R, Thakur K, Chebny VJ, Reid SA, Rathore R. Direct observation of electron-transfer-induced conformational transformation (molecular actuation) in a bichromophoric electron donor. The Journal of Physical Chemistry. B. 114: 14592-5. PMID 20491456 DOI: 10.1021/Jp102357W  0.805
2010 Kríz J, Toman P, Makrlík E, Budka J, Shukla R, Rathore R. Cooperative interaction of hydronium ion with an ethereally fenced hexaarylbenzene-based receptor: an NMR and theoretical study. The Journal of Physical Chemistry. A. 114: 5327-34. PMID 20364854 DOI: 10.1021/Jp101080H  0.333
2010 Vyas VS, Rathore R. Preparation of a tetraphenylethylene-based emitter: synthesis, structure and optoelectronic properties of tetrakis(pentaphenylphenyl)ethylene. Chemical Communications (Cambridge, England). 46: 1065-7. PMID 20126714 DOI: 10.1039/B923915D  0.733
2010 Lindeman SV, Thakur K, Rathore R. Novel 2D assembly of triptycene cation radicalsversustraditional 1D motifs Acta Crystallographica Section a Foundations of Crystallography. 66: s247-s247. DOI: 10.1107/S0108767310094389  0.529
2010 Toman P, Makrlík E, Vaňura P, Kašička V, Rathore R. Theoretical study on the complexation of the sodium cation with a hexaarylbenzene-based receptor Monatshefte Fur Chemie. 141: 1309-1311. DOI: 10.1007/S00706-010-0400-7  0.303
2009 Modjewski M, Lindeman SV, Rathore R. A versatile preparation of Geländer-type p-terphenyls from a readily available diacetylenic precursor. Organic Letters. 11: 4656-9. PMID 19769387 DOI: 10.1021/Ol901938F  0.365
2009 Shukla R, Lindeman SV, Rathore R. Terphenyl crowns: a new family of receptors containing ethereal canopies that direct potassium cation onto benzenoid platforms for cation-pi interactions. Chemical Communications (Cambridge, England). 5600-2. PMID 19753370 DOI: 10.1039/B912796H  0.357
2009 Zhai L, Shukla R, Rathore R. Oxidative C-C bond formation (Scholl reaction) with DDQ as an efficient and easily recyclable oxidant. Organic Letters. 11: 3474-7. PMID 19594139 DOI: 10.1021/Ol901331P  0.36
2009 Chebny VJ, Navale TS, Shukla R, Lindeman SV, Rathore R. X-ray structural characterization of charge delocalization onto the three equivalent benzenoid rings in hexamethoxytriptycene cation radical. Organic Letters. 11: 2253-6. PMID 19473043 DOI: 10.1021/Ol900558S  0.809
2009 Navale TS, Zhai L, Lindeman SV, Rathore R. Octamethoxydibenzochrysene: isolation and X-ray crystallographic characterization of a twisted polyaromatic cation radical. Chemical Communications (Cambridge, England). 2857-9. PMID 19436889 DOI: 10.1039/B903133B  0.775
2009 Chebny VJ, Shukla R, Lindeman SV, Rathore R. Molecular actuator: redox-controlled clam-like motion in a bichromophoric electron donor. Organic Letters. 11: 1939-42. PMID 19331350 DOI: 10.1021/Ol900371M  0.818
2009 Debroy P, Lindeman SV, Rathore R. A versatile synthesis of electroactive stilbenoprismands for effective binding of metal cations. The Journal of Organic Chemistry. 74: 2080-7. PMID 19191713 DOI: 10.1021/Jo802579F  0.467
2009 Banerjee M, Shukla R, Rathore R. Synthesis, optical, and electronic properties of soluble poly-p-phenylene oligomers as models for molecular wires. Journal of the American Chemical Society. 131: 1780-6. PMID 19146375 DOI: 10.1021/Ja805102D  0.419
2009 Chebny VJ, Navale TS, Shukla R, Lindeman SV, Rathore R. Benzenoid Rings in Triptycene are Communicated Synfacts. 2009: 1101-1101. DOI: 10.1055/S-0029-1217931  0.725
2009 Rathore R, Wadumethrige S. Synthesis of Alkoxy-Substituted Hexa-peri-hexabenzocoronene Synfacts. 2009: 0275-0275. DOI: 10.1055/S-0028-1087764  0.775
2009 Modjewski MJ, Shukla R, Lindeman SV, Rathore R. Isolation and X-ray structural characterization of a dicationic homotrimer of 2,3,6,7-tetramethoxy-9,10-dimethylanthracene cation radical Tetrahedron Letters. 50: 6687-6690. DOI: 10.1016/J.Tetlet.2009.09.081  0.413
2009 Vyas VS, Banerjee M, Rathore R. Synthesis and electronic properties of nanometer-size symmetrical tetrakis(poly-p-phenylene)ethylenes Tetrahedron Letters. 50: 6159-6162. DOI: 10.1016/J.Tetlet.2009.08.077  0.736
2008 Wadumethrige SH, Rathore R. A facile synthesis of elusive alkoxy-substituted hexa-peri-hexabenzocoronene. Organic Letters. 10: 5139-42. PMID 18959424 DOI: 10.1021/Ol8020429  0.812
2008 Jia J, Sarker M, Steinmetz MG, Shukla R, Rathore R. Photochemical elimination of leaving groups from zwitterionic intermediates generated via electrocyclic ring closure of alpha,beta-unsaturated anilides. The Journal of Organic Chemistry. 73: 8867-79. PMID 18939880 DOI: 10.1021/Jo8017445  0.307
2008 Shukla R, Wadumethrige SH, Lindeman SV, Rathore R. Synthesis, electronic properties, and X-ray structural characterization of tetrarylbenzo[1,2-b:4,5-b']difuran cation radicals. Organic Letters. 10: 3587-90. PMID 18616340 DOI: 10.1021/Ol801356E  0.811
2008 Banerjee M, Vyas VS, Lindeman SV, Rathore R. Isolation and X-ray structural characterization of tetraisopropylpyrene cation radical. Chemical Communications (Cambridge, England). 1889-91. PMID 18401508 DOI: 10.1039/B800168E  0.751
2008 Emond SJ, Debroy P, Rathore R. Duplexiphane: a polyaromatic receptor containing two adjoined Delta-shaped cavities for an efficient hopping of a single silver cation. Organic Letters. 10: 389-92. PMID 18163637 DOI: 10.1021/Ol7026762  0.358
2008 Shukla R, Rathore R. Octahydro[1,4:5,8]dimethanoanthraquinone as a cheap and readily available electron-transfer oxidant for biaryl synthesis from organocuprates Synthesis. 3769-3774. DOI: 10.1055/S-0028-1083232  0.407
2008 Chebny VJ, Gwengo C, Gardinier JR, Rathore R. Synthesis and electronic properties of iso-alkyl substituted hexa-peri-hexabenzocoronenes (HBC's) from a versatile new HBC synthon, hexakis(4-acetylphenyl)benzene Tetrahedron Letters. 49: 4869-4872. DOI: 10.1016/J.Tetlet.2008.06.005  0.804
2007 Banerjee M, Emond SJ, Lindeman SV, Rathore R. Practical synthesis of unsymmetrical tetraarylethylenes and their application for the preparation of [triphenylethylene-spacer-triphenylethylene] triads. The Journal of Organic Chemistry. 72: 8054-61. PMID 17880244 DOI: 10.1021/Jo701474Y  0.39
2007 Debroy P, Lindeman SV, Rathore R. Hexabenzo[4.4.4]propellane: a helical molecular platform for the construction of electroactive materials. Organic Letters. 9: 4091-4. PMID 17867690 DOI: 10.1021/Ol7015466  0.406
2007 Fukui M, Mori T, Inoue Y, Rathore R. A new class of chiroptical molecular switches based on the redox-induced conformational changes. Organic Letters. 9: 3977-80. PMID 17760453 DOI: 10.1021/Ol701639U  0.325
2007 Chebny VJ, Rathore R. Convergent synthesis of alternating fluorene-p-xylene oligomers and delineation of the (silver) cation-induced folding. Journal of the American Chemical Society. 129: 8458-65. PMID 17571884 DOI: 10.1021/Ja0687522  0.785
2007 Banerjee M, Lindeman SV, Rathore R. Structural characterization of quaterphenyl cation radical: X-ray crystallographic evidence of quinoidal charge delocalization in poly-p-phenylene cation radicals. Journal of the American Chemical Society. 129: 8070-1. PMID 17559215 DOI: 10.1021/Ja0720356  0.451
2007 Chebny VJ, Banerjee M, Rathore R. Preparation of a polymer-supported fluorene-based receptor for quantitative and efficient binding of silver cations. Chemistry (Weinheim An Der Bergstrasse, Germany). 13: 6508-13. PMID 17508374 DOI: 10.1002/Chem.200601776  0.767
2007 Shukla R, Lindeman SV, Rathore R. Electron transfer prompted ejection of a tightly bound K(+) from the ethereal cavity of a hexaarylbenzene-based receptor. Organic Letters. 9: 1291-4. PMID 17326648 DOI: 10.1021/Ol070122X  0.403
2007 Nelsen SF, Weaver MN, Yamazaki D, Komatsu K, Rathore R, Bally T. Calculations of the optical spectra of hydrocarbon radical cations based on Koopmans' theorem. The Journal of Physical Chemistry. A. 111: 1667-76. PMID 17288409 DOI: 10.1021/Jp066384I  0.383
2007 Debroy P, Shukla R, Lindeman SV, Rathore R. Preparation of chiral cholestanofluorene and its electron-rich derivatives for isolation of a stable cation-radical salt. The Journal of Organic Chemistry. 72: 1765-9. PMID 17263580 DOI: 10.1021/Jo062300Q  0.368
2006 Szigeti Z, Malon A, Vigassy T, Csokai V, Grün A, Wygladacz K, Ye N, Xu C, Chebny VJ, Bitter I, Rathore R, Bakker E, Pretsch E. Novel potentiometric and optical silver ion-selective sensors with subnanomolar detection limits. Analytica Chimica Acta. 572: 1-10. PMID 17723454 DOI: 10.1016/J.Aca.2006.05.009  0.754
2006 Chebny VJ, Shukla R, Rathore R. Toroidal hopping of a single hole through the circularly-arrayed naphthyl groups in hexanaphthylbenzene cation radical. The Journal of Physical Chemistry. A. 110: 13003-6. PMID 17134159 DOI: 10.1021/Jp063654O  0.81
2006 Chebny VJ, Dhar D, Lindeman SV, Rathore R. Simultaneous ejection of six electrons at a constant potential by hexakis(4-ferrocenylphenyl)benzene. Organic Letters. 8: 5041-4. PMID 17048838 DOI: 10.1021/Ol061904D  0.805
2006 Stevenson CD, Kiesewetter MK, Reiter RC, Chebny VJ, Rathore R. Selective intercalation of Cs+ in the "V"-shaped cavity of a bichromophoric anion radical: Cs+ assisted pi-s-pi-delocalization of an electron. The Journal of Physical Chemistry. A. 110: 9602-6. PMID 16884193 DOI: 10.1021/Jp0624653  0.808
2006 Shukla R, Brody DM, Lindeman SV, Rathore R. A practical synthesis of bridged diarylacetylenes. The Journal of Organic Chemistry. 71: 6124-9. PMID 16872195 DOI: 10.1021/Jo060817W  0.424
2006 Shukla R, Lindeman SV, Rathore R. A polyaromatic receptor with an ethereal fence that directs K+ for effective cation-pi interaction. Journal of the American Chemical Society. 128: 5328-9. PMID 16620089 DOI: 10.1021/Ja060502Y  0.322
2006 Rathore R, Abdelwahed SH, Kiesewetter MK, Reiter RC, Stevenson CD. Intramolecular electron transfer in cofacially pi-stacked fluorenes: evidence of tunneling. The Journal of Physical Chemistry. B. 110: 1536-40. PMID 16471711 DOI: 10.1021/Jp052737M  0.755
2005 Rathore R, Chebny VJ, Abdelwahed SH. A versatile and conformationally adaptable fluorene-based receptor for efficient binding of silver cation. Journal of the American Chemical Society. 127: 8012-3. PMID 15926815 DOI: 10.1021/Ja051935O  0.787
2005 Stevenson CD, Kiesewetter MK, Reiter RC, Abdelwahed SH, Rathore R. Intramolecular C-H/C-D exchange in cofacially stacked polyfluorenes via electron-induced bond activation. Journal of the American Chemical Society. 127: 5282-3. PMID 15826141 DOI: 10.1021/Ja0432261  0.767
2005 Rathore R, Chebny VJ, Kopatz EJ, Guzei IA. Redox-induced transformation from an extended to a pi-stacked conformer in acyclic bis(catecholacetal)s of acetylacetone. Angewandte Chemie (International Ed. in English). 44: 2771-4. PMID 15798981 DOI: 10.1002/Anie.200463103  0.758
2005 Rathore R, Burns CL, Denmark SE, Fujimori S. Preparation of hexakis(4-Bromophenyl)benzene (HBB) [1,1':2',1''-Terphenyl, 4,4''-dibromo-3',4',5',6'-tetrakis(4-Bromophenyl)-] Organic Syntheses. 82: 30-33. DOI: 10.15227/Orgsyn.082.0030  0.314
2005 Rathore R, Burns CL, Deselnicu MI, Denmark SE, Bui T. Preparation of 1,4: 5,8-dimethano-1,2,3,4,5,6,7,8-octahydro-9,10-dimethoxyanthracenium hexachloroantimonate (4+•SbCl6 -): A highly robust radical-cation salt: [1,4:5,8-dimethanoanthracene, 1,2,3,4,5,6,7,8-octahydro-9,10-dimethoxy-, radical ion(1+), hexachloroantimonate(1-)] Organic Syntheses. 82: 1-9. DOI: 10.15227/Orgsyn.082.0001  0.353
2005 Rathore R, Burns CL. Preparation of hexakis(4-bromophenyl)benzene (HBB) Organic Syntheses. 82: 30-33. DOI: 10.1002/0471264229.Os082.05  0.342
2004 Rathore R, Abdelwahed SH, Guzei IA. Synthesis of a calix[4]arene derivative for isolation of a stable cation radical salt for use as a colorimetric sensor of nitric oxide. Journal of the American Chemical Society. 126: 13582-3. PMID 15493892 DOI: 10.1021/Ja0454900  0.763
2004 Rathore R, Burns CL, Abdelwahed SA. Hopping of a single hole in hexakis[4-(1,1,2-triphenyl-ethenyl)phenyl]benzene cation radical through the hexaphenylbenzene propeller. Organic Letters. 6: 1689-92. PMID 15151390 DOI: 10.1021/Ol036037G  0.465
2004 Rathore R, Burns CL, Guzei IA. Synthesis and isolation of polytrityl cations by utilizing hexaphenylbenzene and tetraphenylmethane scaffolds. The Journal of Organic Chemistry. 69: 1524-30. PMID 14987006 DOI: 10.1021/Jo035598I  0.391
2004 Rathore R, Abdelwahed SH. Soluble cycloannulated tetroxa[8]circulane derivatives: Synthesis, optical and electrochemical properties, and generation of their robust cation-radical salts Tetrahedron Letters. 45: 5267-5270. DOI: 10.1016/J.Tetlet.2004.05.019  0.764
2003 Rathore R, Abdelwahed SH, Guzei IA. Synthesis, structure, and evaluation of the effect of multiple stacking on the electron-donor properties of pi-stacked polyfluorenes. Journal of the American Chemical Society. 125: 8712-3. PMID 12862451 DOI: 10.1021/Ja035518S  0.769
2003 Rathore R, Burns CL. A practical one-pot synthesis of soluble hexa-peri-hexabenzocoronene and isolation of its cation-radical salt. The Journal of Organic Chemistry. 68: 4071-4. PMID 12737593 DOI: 10.1021/Jo034271E  0.387
2003 Rosokha SV, Lindeman SV, Rathore R, Kochi JK. Molecular recognition of NO/NO+ via multicenter (charge-transfer) binding to bridged diarene donors. Effect of structure on the optical transitions and complexation thermodynamics. The Journal of Organic Chemistry. 68: 3947-57. PMID 12737577 DOI: 10.1021/Jo030015Q  0.445
2002 Rathore R, Lindeman SV, Zhu CJ, Mori T, Schleyer PV, Kochi JK. Steric hindrance as a mechanistic probe for olefin reactivity: variability of the hydrogenic canopy over the isomeric adamantylideneadamantane/sesquihomoadamantene pair (a combined experimental and theoretical study). The Journal of Organic Chemistry. 67: 5106-16. PMID 12126394 DOI: 10.1021/Jo0200724  0.378
2001 Rathore R, Burns CL, Deselnicu MI. Multiple-electron transfer in a single step. Design and synthesis of highly charged cation-radical salts Organic Letters. 3: 2887-2890. PMID 11529782 DOI: 10.1021/Ol0163474  0.506
2001 Sun D, Lindeman SV, Rathore R, Kochi JK. Intramolecular (electron) delocalization between aromatic donors and their tethered cation-radicals. Application of electrochemical and structural probes Journal of the Chemical Society, Perkin Transactions 2. 1585-1594. DOI: 10.1039/B103139M  0.411
2000 Lindeman SV, Rathore R, Kochi JK. Silver(I) complexation of (poly)aromatic ligands. Structural criteria for depth penetration into cis-stilbenoid cavities. Inorganic Chemistry. 39: 5707-16. PMID 11151371 DOI: 10.1021/Ic000770B  0.317
2000 Kochi JK, Rathore R, Zhu And C, Lindeman SV. Structural Characterization of Novel Olefinic Cation Radicals: X-ray Crystallographic Evidence of sigma-pi Hyperconjugation We thank the National Science Foundation and the Robert A. Welch Foundation for financial support. Angewandte Chemie (International Ed. in English). 39: 3671-3674. PMID 11091435 DOI: 10.1002/1521-3773(20001016)39:20<3671::Aid-Anie3671>3.0.Co;2-D  0.354
2000 Kochi JK, Rathore R, Magueres PL. Stable dimeric aromatic cation-radicals. Structural and spectral characterization of through-space charge delocalization The Journal of Organic Chemistry. 65: 6826-36. PMID 11030998 DOI: 10.1021/Jo000570H  0.431
2000 Rathore R, Zhu C, Lindeman SV, Kochi JK. Spontaneous oxidation of organic donors to their cation radicals using Brønsted acids. Identification of the elusive oxidant Journal of the Chemical Society. Perkin Transactions 2. 1837-1840. DOI: 10.1039/B003860L  0.352
2000 King JF, Rathore R, Guo Z, Li M, Payne NC. Experimental evidence for negative hyperconjugation as a component of the polar effect: Variation of the ease of α-sulfonyl carbanion formation with the orientation of a β-alkoxy substituent Journal of the American Chemical Society. 122: 10308-10324. DOI: 10.1021/Ja001320L  0.563
2000 Rathore R, Kochi JK. Donor/acceptor organizations and the electron-transfer paradigm for organic reactivity Advances in Physical Organic Chemistry. 35: 193-318. DOI: 10.1016/S0065-3160(00)35014-6  0.422
1999 Rathore R, Kochi JK. Vicinal-diaryl interactions in stilbenoid hydrocarbons as observed in the through-space charge delocalization of their cation radicals Canadian Journal of Chemistry. 77: 913-921. DOI: 10.1139/V99-081  0.404
1999 Hoffman RV, Rathore R, Hecht J, Kochi JK. Isolation and X-ray structure of chloroarenium cations as Wheland intermediates in electrophilic aromatic chlorination Chemtracts. 12: 817-821. DOI: 10.1021/Ja983314J  0.372
1998 Rathore R, Kumar AS, Lindeman SV, Kochi JK. Preparation and Structures of Crystalline Aromatic Cation-Radical Salts. Triethyloxonium Hexachloroantimonate as a Novel (One-Electron) Oxidant. The Journal of Organic Chemistry. 63: 5847-5856. PMID 11672186 DOI: 10.1021/Jo980407A  0.428
1998 Rathore R, Kochi JK. Acid catalysis vs. electron-transfer catalysis via organic cations or cation-radicals as the reactive intermediate. Are these distinctive mechanisms? Acta Chemica Scandinavica. 52: 114-130. DOI: 10.3891/Acta.Chem.Scand.52-0114  0.415
1998 Mori T, Rathore R. X-Ray structure of bridged 2,2′-bi(adamant-2-ylidene) chloronium cation and comparison of its reactivity with a singly-bonded chloroarenium cation Chemical Communications. 927-928. DOI: 10.1039/A709063C  0.393
1998 Rathore R, Lindeman SV, Kumar AS, Kochi JK. Disproportionation and structural changes of tetraarylethylene donors upon successive oxidation to cation radicals and to dications Journal of the American Chemical Society. 120: 6931-6939. DOI: 10.1021/Ja981095W  0.413
1998 Rathore R. Novel synthesis and structures of tris-annelated benzene donors for the electron-density elucidation of the classical Mills-Nixon effect Journal of the American Chemical Society. 120: 6012-6018. DOI: 10.1021/Ja980805V  0.444
1997 Rathore R, Lindeman SV, Kochi JK. Charge-transfer probes for molecular recognition via steric hindrance in donor-acceptor pairs Journal of the American Chemical Society. 119: 9393-9404. DOI: 10.1021/Ja9720319  0.37
1997 Rathore R, Hubig SM, Kochi JK. Direct observation and structural characterization of the encounter complex in bimolecular electron transfers with photoactivated acceptors Journal of the American Chemical Society. 119: 11468-11480. DOI: 10.1021/Ja971188Y  0.399
1996 Rathore R, Kochi JK. alpha-Nitration of Ketones via Enol Silyl Ethers. Radical Cations as Reactive Intermediates in Thermal and Photochemical Processes. The Journal of Organic Chemistry. 61: 627-639. PMID 11666984 DOI: 10.1021/Jo9515687  0.424
1996 Rathore R, Weigand U, Kochi JK. Efficient hydrogenation of sterically hindered olefins with borane-methyl sulfide complex Journal of Organic Chemistry. 61: 5246-5256. DOI: 10.1021/Jo960357E  0.445
1995 Rathore R, Kochi JK. Radical-cation catalysis in the synthesis of diphenylmethanes via the dealkylative coupling of benzylic ethers The Journal of Organic Chemistry. 60: 7479-7490. DOI: 10.1021/Jo00128A020  0.385
1995 Rathore R, Kochi JK. Isolation of novel radical cations from hydroquinone ethers. Conformational transition of the methoxy group upon electron transfer Journal of Organic Chemistry. 60: 4399-4411. DOI: 10.1021/Jo00119A017  0.425
1994 Rathore R, Bosch E, Kochi JK. Oxidative dealkylation of hydroquinone ethers with nitrogen dioxide in the convenient preparation of quinones Journal of the Chemical Society, Perkin Transactions 2. 1157-1166. DOI: 10.1039/P29940001157  0.397
1994 Rathore R, Kim JS, Kochi JK. Catalytic autoxidation of benzoquinone dioximes with nitrogen oxides: Steric effects on the preparation of monomeric dinitrosobenzenes Journal of the Chemical Society, Perkin Transactions 1. 2675-2684. DOI: 10.1039/P19940002675  0.373
1994 Bosch E, Rathore R, Kochi JK. Novel catalysis of hydroquinone autoxidation with nitrogen oxides Journal of Organic Chemistry. 59: 2529-2536. DOI: 10.1021/Jo00088A039  0.379
1994 Rathore R, Loyd SH, Kochi JK. Isolation, structure, and reactivity of a novel chloro-arenium cation for electrophilic (transfer) chlorinations Journal of the American Chemical Society. 116: 8414-8415. DOI: 10.1021/Ja00097A078  0.354
1994 Rathore R, Kochi JK. Quantitative assessment of electron-donor properties of enol silyl ethers: Charge-transfer complex formation, photoelectron spectra and transient electrochemical oxidation Tetrahedron Letters. 35: 8577-8580. DOI: 10.1016/S0040-4039(00)78440-1  0.441
1994 Rathore R, Bosch E, Kochi JK. Selective nitration versus oxidative dealkylation of hydroquinone ethers with nitrogen dioxide Tetrahedron. 50: 6727-6758. DOI: 10.1016/S0040-4020(01)81329-6  0.395
1992 King JF, Rathore R, Lam JYL, Guo ZR, Klassen DF. PH optimization of nucleophilic reactions in water Journal of the American Chemical Society. 114: 3028-3033. DOI: 10.1021/Ja00034A040  0.536
1990 King JF, Rathore R. Geometry dependence of the effect of a β-substituent on the rate of h-d exchange: Evidence for a stereoelectronic component of the polar effect Journal of the American Chemical Society. 112: 2001-2002. DOI: 10.1021/Ja00161A057  0.529
1989 King JF, Rathore R. An easy preparation of simple sultines and hydroxyalkanesulfinate salts Tetrahedron Letters. 30: 2763-2766. DOI: 10.1016/S0040-4039(00)99119-6  0.552
1987 King JF, Webster MR, Chiba N, Allen JK, Parker KJM, Rathore R, Skonieczny S. ω-Hydroxy-1-alkanesulfonyl chlorides Phosphorus Sulfur and Silicon and the Related Elements. 31: 161-175. DOI: 10.1080/03086648708079353  0.574
1987 King JF, Rathore R. Hydroxyalkanesulfonyl Chlorides From Chlorination Of Hydroxyalkanesulfinate Salts In A Nonpolar Medium: 3-Hydroxy-1-Propanesulfonyl And 4-Hydroxy-1-Butanesulfonyl Chlorides Phosphorus Sulfur and Silicon and the Related Elements. 33: 165-171. DOI: 10.1080/03086648708074297  0.551
1986 Rathore R, Saxena N, Chandrasekaran S. A convenient method of benzylic oxidation with pyridinium chlorochromate Synthetic Communications. 16: 1493-1498. DOI: 10.1080/00397918608056400  0.303
1986 Rathore R, Vankar PS, Chandrasekaran S. Substituent directed oxidative cyclization with cetyltrimethylammonium permanganate: A general approach to the synthesis of γ- and δ-lactones Tetrahedron Letters. 27: 4079-4082. DOI: 10.1016/S0040-4039(00)84916-3  0.312
1985 Narasimhan V, Rathore R, Chandrasekaran S. Highly selective oxidative cleavage of aryl substituted olefins with pyridinium chlorochromate Synthetic Communications. 15: 769-774. DOI: 10.1080/00397918508063871  0.329
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