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Robert W. Taft - Publications

Affiliations: 
University of California, Irvine, Irvine, CA 
Area:
physical organic chemistry
Website:
http://texts.cdlib.org/view?docId=hb1p30039g&chunk.id=div00056&brand=calisphere&doc.view=entire_text
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64 high-probability publications. We are testing a new system for linking publications to authors. You can help! If you notice any inaccuracies, please sign in and mark papers as correct or incorrect matches. If you identify any major omissions or other inaccuracies in the publication list, please let us know.

Year Citation  Score
2000 Raczynska ED, Decouzon M, Gal JF, Maria PC, Taft RW, Anvia F. Gas-phase basicity of polyfunctional amidinazines: experimental evidence of preferred site(s) of protonation The Journal of Organic Chemistry. 65: 4635-40. PMID 10959868 DOI: 10.1021/Jo000241P  0.337
2000 Burk P, Koppel IA, Koppel I, Kurg R, Gal JF, Maria PC, Herreros M, Notario R, Abboud JLM, Anvia F, Taft RW. Revised and Expanded Scale of Gas-Phase Lithium Cation Basicities. An Experimental and Theoretical Study Journal of Physical Chemistry A. 104: 2824-2833. DOI: 10.1021/Jp9931399  0.311
1998 Koppel I, Koppel J, Maria PC, Gal JF, Notario R, Vlasov VM, Taft RW. Comparison of Brönsted acidities of neutral NH-acids in gas phase, dimethyl sulfoxide and water International Journal of Mass Spectrometry and Ion Processes. 175: 61-69. DOI: 10.1016/S0168-1176(98)00113-X  0.356
1996 Taft RW, Raczy?ska ED, Maria PC, Leito I, Lewandowski W, Kurg R, Gal JF, Decouzon M, Anvia F. Application of experimental (FT-ICR) and theoretical (AM1) methods to the study of proton-transfer reactions for tautomerizing amidines in the gas phase. Analytical and Bioanalytical Chemistry. 355: 412-4. PMID 15045430 DOI: 10.1007/S0021663550412  0.316
1996 Berthelot M, Laurence C, Lucon M, Rossignol C, Taft RW. Partition coefficients and intramolecular hydrogen bonding. 2. The influence of partition solvents on the intramolecular hydrogen-bond stability of salicyclic acid derivatives Journal of Physical Organic Chemistry. 9: 626-630. DOI: 10.1002/(Sici)1099-1395(199609)9:9<626::Aid-Poc828>3.0.Co;2-M  0.329
1996 Burk P, Koppel IA, Koppel I, Yagupolskii LM, Taft RW. Superacidity of neutral brönsted acids in gas phase Journal of Computational Chemistry. 17: 30-41. DOI: 10.1002/(Sici)1096-987X(19960115)17:1<30::Aid-Jcc3>3.0.Co;2-1  0.323
1994 Koppel IA, Taft RW, Anvia F, Zhu SZ, Hu LQ, Sung KS, DesMarteau DD, Yagupolskii LM, Yagupolskii YL, Ignat'ev NV, Kondratenko NV, Volkonskii AY, Vlasov VM, Notario R, Maria PC. The gas-phase acidities of very strong neutral brønsted acids Journal of the American Chemical Society. 116: 3047-3057. DOI: 10.1021/Ja00086A038  0.302
1993 Abraham MH, Taft RW. Hydrogen bonding. Part 26. The calorimetric acidity scale of Laynez Journal of the Chemical Society, Perkin Transactions 2. 305-306. DOI: 10.1039/P29930000305  0.317
1991 Elguero J, Yranzo GI, Laynez J, Jimënez P, Menéndez M, Catalán J, De Paz JLG, Anvia F, Taft RW. Effect of the replacement of a methyl by a trifluoromethyl group on the acid-base properties of pyrazoles Journal of Organic Chemistry. 56: 3942-3947. DOI: 10.1021/Jo00012A030  0.327
1991 Abboud JLM, Notario R, Bertrán J, Taft RW. Use of Gas-Phase Basicities for the Study of Solution Kinetics: An Unprecedented Extension of Brønsted Correlations Journal of the American Chemical Society. 113: 4738-4740. DOI: 10.1021/Ja00013A004  0.314
1990 Taft RW, Anvia F, Gal JF, Walsh S, Capon M, Holmes MC, Hosn K, Oloumi G, Vasanwala R, Yazdani S. Free energies of cation-molecule complex formation and of cation-solvent transfers (ref. 1) Pure and Applied Chemistry. 62: 17-23. DOI: 10.1351/Pac199062010017  0.342
1990 Taagera M, Taft RW, Hehre WJ. The Effect of Charge Dispersal on Phosphine Basicities and Reactivities Phosphorus Sulfur and Silicon and the Related Elements. 207-210. DOI: 10.1080/10426509008038942  0.318
1989 Fuchs R, Abraham MH, Kamlet MJ, Taft RW. Solute-solvent interactions in chemical and biological systems. IV. Correlations of ?G, ?H andT?S of transfer of aliphatic and aromatic solutes from 2,2,4-trimethylpentane to aqueous solution Journal of Physical Organic Chemistry. 2: 559-564. DOI: 10.1002/Poc.610020708  0.316
1988 Marcus Y, Kamlet MJ, Taft RW. Linear solvation energy relationships. Standard molar Gibbs free energies and enthalpies of transfer of ions from water into nonaqueous solvents Journal of Physical Chemistry. 92: 3613-3622. DOI: 10.1021/J100323A057  0.336
1988 Jinfeng C, Topsom RD, Headley AD, Koppel I, Mishima M, Taft RW, Veji S. Acidities of substituted acetic acids Journal of Molecular Structure: Theochem. 168: 141-146. DOI: 10.1016/0166-1280(88)80349-X  0.31
1987 Abraham MH, Doherty RM, Kamlet MJ, Harris JM, Taft RW. Linear solvation energy relationships. Part 38. An analysis of the use of solvent parameters in the correlation of rate constants, with special reference to the solvolysis of t-butyl chloride Journal of the Chemical Society, Perkin Transactions 2. 1097-1101. DOI: 10.1039/P29870001097  0.312
1987 Abraham MH, Doherty RM, Kamlet MJ, Harris JM, Taft RW. Linear solvation energy relationships. Part 37. An analysis of contributions of dipolarity-polarisability, nucleophilic assistance, electrophilic assistance, and cavity terms to solvent effects on t-butyl halide solvolysis rates Journal of the Chemical Society, Perkin Transactions 2. 913-920. DOI: 10.1039/P29870000913  0.316
1987 Yokoyama T, Taft RW, Kamlet MJ. Resonance and solvent effects on absorption spectra. Part 5. Substituent and solvent effects on infrared spectra of 2- and 4-substituted aniline derivatives Journal of the Chemical Society, Perkin Transactions 2. 875-879. DOI: 10.1039/P29870000875  0.338
1987 Butt G, Topsom RD, Taft RW. Acidities of 3- and 4-substituted pyridinium ions Journal of Molecular Structure: Theochem. 153: 141-146. DOI: 10.1016/0166-1280(87)85011-X  0.316
1986 Begtrup M, Taft RW, Kamlet MJ. Linear solvation energy relationships. 40. A reexamination of carbon-13 NMR shifts and carbon-13-fluorine-19 coupling constants of trifluoroacetic acid complexes with hydrogen bond acceptor bases Journal of Organic Chemistry. 51: 2130-2131. DOI: 10.1021/Jo00361A040  0.308
1986 Taft RW, Anvia F, Taagepera M, Catalán J, Elguero J. Electrostatic proximity effects in the relative basicities and acidities of pyrazole, imidazole, pyridazine, and pyrimidine Journal of the American Chemical Society. 108: 3237-3239. DOI: 10.1021/Ja00272A013  0.324
1986 Taft RW, Gal JF, Geribaldi S, Maria PC. Unique basicity properties of conjugated amino cyclohexenone derivatives. The effects of molecular structure on the disparate basicities toward protonic acids Journal of the American Chemical Society. 108: 861-863. DOI: 10.1021/Ja00265A001  0.301
1986 Marriott S, Topsom RD, Lebrilla CB, Koppel I, Mishima M, Taft RW. Proton affinities of substituted cyanides Journal of Molecular Structure: Theochem. 137: 133-141. DOI: 10.1002/Chin.198631076  0.308
1986 Hehre WJ, Pau CF, Headley AD, Taft RW, Topsom RD. A scale of directional substituent polarizability parameters from ab initio calculations of polarizability potentials Journal of the American Chemical Society. 108: 1711-1712. DOI: 10.1002/Chin.198630067  0.529
1986 Taft RW, Gal J‐, Geribaldi S, Maria P‐. Unique Basicity Properties of Conjugated Amino Cyclohexenone Derivatives. Cheminform. 17. DOI: 10.1002/Chin.198626124  0.319
1985 Kamlet MJ, Gal JF, Maria PC, Taft RW. Linear solvation energy relationships. Part 32. A co-ordinate covalency parameter, Ξ, which, in combination with the hydrogen bond acceptor basicity parameter, β, permits correlation of many properties of neutral oxygen and nitrogen bases (including aqueous pKa) Journal of the Chemical Society, Perkin Transactions 2. 1583-1589. DOI: 10.1039/P29850001583  0.304
1984 Mashima M, McIver RR, Taft RW, Bordwell FG, Olmstead WN. Enhanced substituent solvation assisted resonance effects in dipolar non-hydrogen-bond-donor solvents Journal of the American Chemical Society. 106: 2717-2718. DOI: 10.1021/Ja00321A602  0.312
1982 Abboud JM, Taft RW, Kamlet MJ. Linear Solvation Energy Relationships. 18. Solvent Effects on the Electronic Absorption Spectrum of p-Nitrophenoxide Ion Bulletin of the Chemical Society of Japan. 55: 603-606. DOI: 10.1246/Bcsj.55.603  0.328
1982 Kamlet MJ, Dickinson C, Gramstad T, Taft RW. Linear solvation energy relationships. 16. Dipole/dipole contributions to formation constants of some "hydrogen bonded complexes" Journal of Organic Chemistry. 47: 4971-4975. DOI: 10.1021/Jo00146A028  0.304
1982 Von Nagy-Felsobuki E, Topsom RD, Pollack S, Taft RW. Theoretical studies of the structures of some mono- and di-substituted benzenes Journal of Molecular Structure: Theochem. 88: 255-263. DOI: 10.1002/Chin.198244076  0.569
1981 Kamlet MJ, Dickinson C, Taft RW. Linear solvation energy relationship. Part 11. An analysis of nitrogen-15 solvent shifts in amides Journal of the Chemical Society, Perkin Transactions 2. 353-355. DOI: 10.1039/P29810000353  0.303
1981 Hehre WJ, Taagepera M, Taft RW, Topsom RD. The relationship between substituent-induced energy and charge effects in proton-transfer equilibria Journal of the American Chemical Society. 103: 1344-1349. DOI: 10.1021/Ja00396A007  0.554
1981 Chawla B, Pollack SK, Lebrilla CB, Kamlet MJ, Taft RW. Use of carbon-13 substituent chemical shifts to scale non-hydrogen-bonding dipolar interactions of protonic solvents Journal of the American Chemical Society. 103: 6924-6930. DOI: 10.1002/Chin.198208062  0.592
1981 Taagepera M, Summerhays KD, Hehre WJ, Topsom RD, Pross A, Radom L, Taft RW. Analysis of the acidities of 3- and 4-substituted pyridinium and anilinium ions Journal of Organic Chemistry. 46: 891-903.  0.502
1980 Taagepera M, DeFrees D, Hehre WJ, Taft RW. Theoretical calculations of the aqueous medium effects on the basicities of primary amines [36] Journal of the American Chemical Society. 102: 424-426.  0.498
1979 Taft RW, Kamlet MJ. Linear solvation energy relationships. Part 4. Correlations with and limitations of the α scale of solvent hydrogen bond donor acidities Journal of the Chemical Society, Perkin Transactions 2. 1723-1729. DOI: 10.1039/P29790001723  0.329
1979 Kamlet MJ, Taft RW. Linear solvation energy relationships. Part 3. Some reinterpretations of solvent effects based on correlations with solvent π and α values Journal of the Chemical Society, Perkin Transactions 2. 349-356. DOI: 10.1039/P29790000349  0.35
1979 Kamlet MJ, Jones ME, Taft RW, Abboud JL. Linear solvation energy relationships. Part 2. Correlations of electronic spectral data for aniline indicators with solvent π and β values Journal of the Chemical Society, Perkin Transactions 2. 342-348. DOI: 10.1039/P29790000342  0.328
1979 DeFrees DJ, Taagepera M, Levi BA, Pollack SK, Summerhays KD, Taft RW, Wolfsberg M, Hehre WJ. Role of hyperconjugation in secondary β-deuterium isotope effects Journal of the American Chemical Society. 101: 5532-5536. DOI: 10.1002/Chin.198001064  0.653
1978 Taft RW, Taagepera M, Abbound JLM, Wolf JF, DeFrees DJ, Hehre WJ, Bartmess JE, McIver RT. The separation of polarizability and inductive effects in gas- and solution-phase proton-transfer equilibriums Journal of the American Chemical Society. 100: 7765-7767. DOI: 10.1021/Ja00492A075  0.328
1978 Taft RW, Wolf JF, Beauchamp JL, Scorrano G, Arnett EM. Solvent effects of water and fluorosulfuric acid on proton transfer equilibria and the energies of solvation of gaseous onium ions Journal of the American Chemical Society. 100: 1240-1249. DOI: 10.1021/Ja00472A035  0.337
1978 Taft RW, Taagepera M, Abboud JLM, Wolf JF, DeFrees DJ, Hehre WJ, Bartmess JE, McIver RT. Regarding the separation of polarizability and inductive effects in gas- and solution-phase proton-transfer equilibria [29] Journal of the American Chemical Society. 100: 7765-7767.  0.529
1977 Arnett EM, Chawla B, Bell L, Taagepera M, Hehre WJ, Taft RW. Solvation and hydrogen bonding of pyridinium ions Journal of the American Chemical Society. 99: 5729-5738. DOI: 10.1021/Ja00459A034  0.497
1977 Summerhays KD, Pollack SK, Taft RW, Hehre WJ. Gas-phase basicities of substituted anilines. Inferences about the role of solvent in dictating site of protonation Journal of the American Chemical Society. 99: 4585-4587. DOI: 10.1021/Ja00456A009  0.713
1977 Pollack SK, Devlin JL, Summerhays KD, Taft RW, Hehre WJ. The site of protonation in aniline Journal of the American Chemical Society. 99: 4583-4584. DOI: 10.1021/Ja00456A008  0.683
1977 Pollack SK, Wolf JF, Levi BA, Taft RW, Hehre WJ. Kinetic detection of common intermediates in gas phase ion-molecule reactions Journal of the American Chemical Society. 99: 1350-1353. DOI: 10.1021/Ja00447A010  0.697
1977 Staley RH, Taagepera M, Henderson WG, Koppel I, Beauchamp JL, Taft RW. Effects of alkyl and fluoroalkyl substitution on the heterolytic and homolytic bond dissociation energies of protonated amines Journal of the American Chemical Society. 99: 326-330. DOI: 10.1021/Ja00444A003  0.342
1977 Reynolds WF, Mezey PG, Hehre WJ, Topsom RD, Taft RW. The relationship between substituent effects on energy and on charge from ab initio molecular orbital theory [19] Journal of the American Chemical Society. 99: 5821-5822. DOI: 10.1002/Chin.197747063  0.539
1977 Levi BA, Taft RW, Hehre WJ. Dichlorocarbene Journal of the American Chemical Society. 99: 8454-8455.  0.492
1976 Taagepera M, Hehre WJ, Topsom RD, Taft RW. Calculation of polar substituent parameters by ab initio molecular orbital methods. Proton affinities of substituted primary amines [13] Journal of the American Chemical Society. 98: 7438-7440. DOI: 10.1021/Ja00439A063  0.557
1976 Fredrick Wolf J, Devlin JL, DeFrees DJ, Taft RW, Hehre WJ. Isotope effects on gas phase reaction processes. 2. Equilibrium isotope effects on the proton transfer reactions of methylbenzenes Journal of the American Chemical Society. 98: 5097-5101. DOI: 10.1021/Ja00433A008  0.571
1976 Wolf JF, Devlin JL, Taft RW, Wolfsberg M, Hehre WJ. Isotope effects on gas phase reaction processes. I. The determination of equilibrium isotope effects by ion cyclotron resonance spectroscopy [40] Journal of the American Chemical Society. 98: 287-289. DOI: 10.1021/Ja00417A074  0.57
1976 Abboud JLM, Hehre WJ, Taft RW. Benzyl cation. A long-lived species in the gas phase? [25] Journal of the American Chemical Society. 98: 6072-6073.  0.488
1976 Devlin JL, Wolf JF, Taft RW, Hehre WJ. The proton affinities of toluene [19] Journal of the American Chemical Society. 98: 1990-1992.  0.501
1975 Wolf JF, Harch PG, Taft RW. Concerning negligible aqueous solvent effects on proton transfer equilibrums of aryl carbocations Journal of the American Chemical Society. 97: 2904-2906. DOI: 10.1021/Ja00843A051  0.333
1975 Wolf JF, Harch PG, Taft RW, Hehre WJ. Substituent effects on the stability of carbocations. The anomalous case of phenyl vs. cyclopropyl substitution [3] Journal of the American Chemical Society. 97: 2902-2904.  0.481
1969 Taft RW, Gurka D, Joris L, Schleyer PvR, Rakshys JW. Studies of hydrogen-bonded complex formation with p-fluorophenol. V. Linear free energy relationships with OH reference acids Journal of the American Chemical Society. 91: 4801-4808. DOI: 10.1021/Ja01045A038  0.306
1968 Love P, Cohen RB, Taft RW. Polar substituent effects in gas-phase Lewis acid-base equilibriums. I. Insrinsic basicity of amines Journal of the American Chemical Society. 90: 2455-2462. DOI: 10.1021/Ja01012A001  0.329
1963 Taft RW, Price E, Fox IR, Lewis IC, Andersen KK, Davis GT. Fluorine nuclear magnetic resonance shielding in meta-substituted fluorobenzenes. The effect of solvent on the inductive order Journal of the American Chemical Society. 85: 709-724. DOI: 10.1021/Ja00889A015  0.328
1956 Purlee EL, Taft RW. Distribution Constants for Ethylene and Propylene between the Gas Phase and Aqueous Perchloric Acid1 Journal of the American Chemical Society. 78: 5811-5812. DOI: 10.1021/Ja01603A024  0.303
1953 Levy JB, Taft RW, Hammett LP. The mechanism of the acid-catalyzed hydration of olefins Journal of the American Chemical Society. 75: 1253-1254. DOI: 10.1021/Ja01101A514  0.592
1952 Taft RW, Levy JB, Aaron D, Hammett LP. Rates, equilibrium and temperature coefficients in the reversible hydration of gaseous 1-methylcyclopentene-1 by dilute nitric acid Journal of the American Chemical Society. 74: 4735-4737. DOI: 10.1021/Ja01139A002  0.587
1951 Levy JB, Taft RW, Aaron D, Hammett LP. Rates and temperature coefficients in the hydration of gaseous isobutene by dilute aqueous nitric acid Journal of the American Chemical Society. 73: 3792-3796. DOI: 10.1021/Ja01152A068  0.589
1950 Taft RW, Newman MS, Verhoek FH. The Kinetics of the Base-catalyzed Methanolysis of Ortho, Meta and Para Substituted l-Menthyl Benzoates1,2 Journal of the American Chemical Society. 72: 4511-4519. DOI: 10.1021/Ja01166A048  0.308
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