John R. Shapley - Publications

Affiliations: 
1972- Chemistry University of Illinois, Urbana-Champaign, Urbana-Champaign, IL 
Area:
inorganic and organometallic chemistry
Website:
http://www.chemistry.illinois.edu/faculty/John_Shapley.html

199 high-probability publications. We are testing a new system for linking publications to authors. You can help! If you notice any inaccuracies, please sign in and mark papers as correct or incorrect matches. If you identify any major omissions or other inaccuracies in the publication list, please let us know.

Year Citation  Score
2016 Liu J, Wu D, Su X, Han M, Kimura SY, Gray DL, Shapley JR, Abu-Omar MM, Werth CJ, Strathmann TJ. Configuration Control in the Synthesis of Homo- and Heteroleptic Bis(oxazolinylphenolato/thiazolinylphenolato) Chelate Ligand Complexes of Oxorhenium(V): Isomer Effect on Ancillary Ligand Exchange Dynamics and Implications for Perchlorate Reduction Catalysis. Inorganic Chemistry. PMID 26894635 DOI: 10.1021/Acs.Inorgchem.5B02940  0.343
2015 Liu J, Choe JK, Wang Y, Shapley JR, Werth CJ, Strathmann TJ. Bioinspired complex-nanoparticle hybrid catalyst system for aqueous perchlorate reduction: Rhenium speciation and its influence on catalyst activity Acs Catalysis. 5: 511-522. DOI: 10.1021/Cs501286W  0.396
2013 Malosh TJ, Shapley JR, Lawson RJ, Hay DNT, Rohrabaugh TN. Diene-iridium-tin complexes. Comparison of conjugated versus non-conjugated dienes and trimethyltin versus trichlorotin as ligands. Ring opening metathesis polymerization of norbornene by Ir(1,5-cycloocta-diene)2SnCl 3 Journal of Organometallic Chemistry. 745: 98-105. DOI: 10.1016/J.Jorganchem.2013.07.015  0.789
2013 Zhang R, Shuai D, Guy KA, Shapley JR, Strathmann TJ, Werth CJ. Elucidation of Nitrate Reduction Mechanisms on a Pd-In Bimetallic Catalyst using Isotope Labeled Nitrogen Species Chemcatchem. 5: 313-321. DOI: 10.1002/Cctc.201200457  0.776
2012 Chaplin BP, Reinhard M, Schneider WF, Schüth C, Shapley JR, Strathmann TJ, Werth CJ. Critical review of Pd-based catalytic treatment of priority contaminants in water. Environmental Science & Technology. 46: 3655-70. PMID 22369144 DOI: 10.1021/Es204087Q  0.661
2012 Shuai D, Choe JK, Shapley JR, Werth CJ. Enhanced activity and selectivity of carbon nanofiber supported Pd catalysts for nitrite reduction. Environmental Science & Technology. 46: 2847-55. PMID 22295991 DOI: 10.1021/Es203200D  0.338
2012 Chaplin BP, Reinhard M, Schneider WF, Schüth C, Shapley JR, Strathmann TJ, Werth CJ. Response to comment on "critical review of Pd-based catalytic treatment of priority contaminants in water" Environmental Science and Technology. 46: 11469-11470. DOI: 10.1021/Es303162R  0.644
2012 McCalman DC, Kelley KH, Werth CJ, Shapley JR, Schneider WF. Aqueous N 2O reduction with H 2 over Pd-based catalyst: Mechanistic insights from experiment and simulation Topics in Catalysis. 55: 300-312. DOI: 10.1007/S11244-012-9795-1  0.352
2011 Zhang Y, Hurley KD, Shapley JR. Heterogeneous catalytic reduction of perchlorate in water with Re-Pd/C catalysts derived from an oxorhenium(V) molecular precursor. Inorganic Chemistry. 50: 1534-43. PMID 21226477 DOI: 10.1021/Ic102158A  0.754
2010 Choe JK, Shapley JR, Strathmann TJ, Werth CJ. Influence of rhenium speciation on the stability and activity of Re/Pd bimetal catalysts used for perchlorate reduction. Environmental Science & Technology. 44: 4716-21. PMID 20481620 DOI: 10.1021/Es100227Z  0.347
2010 Shuai D, Chaplin BP, Shapley JR, Menendez NP, McCalman DC, Schneider WF, Werth CJ. Enhancement of oxyanion and diatrizoate reduction kinetics using selected azo dyes on Pd-based catalysts. Environmental Science & Technology. 44: 1773-9. PMID 20143806 DOI: 10.1021/Es9029842  0.663
2010 Malosh TJ, Shapley JR. Fluorous triosmium clusters. Preparation, properties, and reactivity of Os and Os. Crystal structure of Os. Ring opening metathesis polymerization of norbornene by Journal of Organometallic Chemistry. 695: 1776-1786. DOI: 10.1016/J.Jorganchem.2010.03.026  0.792
2009 Hurley KD, Zhang Y, Shapley JR. Ligand-enhanced reduction of perchlorate in water with heterogeneous Re-Pd/C catalysts. Journal of the American Chemical Society. 131: 14172-3. PMID 19772317 DOI: 10.1021/Ja905446T  0.764
2009 Guy KA, Shapley JR. H-D exchange between N-heterocyclic compounds and D 2O with a Pd/PVP colloid catalyst Organometallics. 28: 4020-4027. DOI: 10.1021/Om9001796  0.776
2009 Guy KA, Xu H, Yang JC, Werth CJ, Shapley JR. Catalytic nitrate and nitrite reduction with Pd-Cu/PVP colloids in water: Composition, structure, and reactivity correlations Journal of Physical Chemistry C. 113: 8177-8185. DOI: 10.1021/Jp810049Y  0.779
2009 Malosh TJ, Wilson SR, Shapley JR. Binuclear ruthenium complexes of fluorous phosphine ligands: Synthesis, properties, and biphasic catalytic activity. Crystal structure of [Ru(μ-O2CMe)(CO)2P(CH2CH2(CF2)5CF3)3]2 Journal of Organometallic Chemistry. 694: 3331-3337. DOI: 10.1016/J.Jorganchem.2009.06.014  0.798
2009 Malosh TJ, Wilson SR, Shapley JR. Comparative properties of fluorous phosphine ligand complexes: W(CO)5LF. Crystal structure of W(CO)5P(C6H4-4-CH2CH 2(CF2)7CF3)3 Inorganica Chimica Acta. 362: 2849-2855. DOI: 10.1016/J.Ica.2009.01.011  0.796
2009 Chaplin BP, Shapley JR, Werth CJ. The selectivity and sustainability of a Pd-In/γ-Al2O 3 catalyst in a packed-bed reactor: The effect of solution composition Catalysis Letters. 130: 56-62. DOI: 10.1007/S10562-009-9883-4  0.677
2009 Chaplin BP, Shapley JR, Werth CJ. Oxidative regeneration of sulfide-fouled catalysts for water treatment Catalysis Letters. 132: 174-181. DOI: 10.1007/S10562-009-0083-Z  0.675
2008 Frierdich AJ, Shapley JR, Strathmann TJ. Rapid reduction of N-nitrosamine disinfection byproducts in water with hydrogen and porous nickel catalysts. Environmental Science & Technology. 42: 262-9. PMID 18350906 DOI: 10.1021/Es0712928  0.363
2008 Knitt LE, Shapley JR, Strathmann TJ. Rapid metal-catalyzed hydrodehalogenation of Iodinated x-ray contrast media. Environmental Science & Technology. 42: 577-83. PMID 18284165 DOI: 10.1021/Es071837Y  0.357
2008 Liu Z, Guy KA, Shapley JR, Werth CJ, Wang Q, Frenkel AI, Yang JC. Microstructural characterization of colloid-derived bimetallic Pd-Cu nanocatalysts supported on γ-Al2O3 for nitrate reduction Microscopy and Microanalysis. 14: 186-187. DOI: 10.1017/S1431927608087138  0.782
2008 Chaplin BP, Shapley JR, Werth CJ. Effect of solution conditions on the product distribution of catalytic nitrate reduction using Pd-In catalysts in a continuous-flow packed-bed reactor Acs National Meeting Book of Abstracts 0.633
2007 Chaplin BP, Shapley JR, Werth CJ. Regeneration of sulfur-fouled bimetallic Pd-based catalysts. Environmental Science & Technology. 41: 5491-7. PMID 17822122 DOI: 10.1021/Es0704333  0.677
2007 Hurley KD, Shapley JR. Efficient heterogeneous catalytic reduction of perchlorate in water. Environmental Science & Technology. 41: 2044-9. PMID 17410803 DOI: 10.1021/Es0624218  0.737
2006 Davie MG, Reinhard M, Shapley JR. Metal-catalyzed reduction of N-nitrosodimethylamine with hydrogen in water. Environmental Science & Technology. 40: 7329-35. PMID 17180985 DOI: 10.1021/Es061097D  0.328
2006 Chaplin BP, Roundy E, Guy KA, Shapley JR, Werth CJ. Effects of natural water ions and humic acid on catalytic nitrate reduction kinetics using an alumina supported Pd-Cu catalyst. Environmental Science & Technology. 40: 3075-81. PMID 16719114 DOI: 10.1021/Es0525298  0.776
2006 Yang JC, Xu F, Xu H, Menard L, Guy K, Wang LL, Shapley J, Frenkel A, Johnson D, Nuzzo R. Structural characterization of supported metal nanoparticles Microscopy and Microanalysis. 12: 782-783. DOI: 10.1017/S1431927606061496  0.773
2005 Xu H, Twesten R, Guy K, Shapley J, Werth C, Frenkel A, Johnson D, Yang J. Structural changes of bimetallic Pdx/Cu(1-x) nanocatalysts developed for nitrate reduction of drinking water Materials Research Society Symposium Proceedings. 876: 52-57. DOI: 10.1557/Proc-876-R4.8  0.785
2003 Cree ME, Shapley JR. Preparation and properties of triosmium propyl and propylidene complexes Inorganica Chimica Acta. 345: 345-352. DOI: 10.1016/S0020-1693(02)01355-5  0.412
2002 Comstock MC, Shapley JR. Formation of Cs-Ir3(CO)3(η5-C9H 7)3. Interconversion of Cs and C3v isomers Organometallics. 21: 5983-5986. DOI: 10.1021/Om020863W  0.372
2002 Khayatpoor R, Shapley JR. Dinuclear tungsten, molybdenum, and ruthenium complexes derived from 1,2-bis(3-indenyl)ethane Organometallics. 21: 4794-4798. DOI: 10.1021/Om0206711  0.773
2002 Babcock AJ, Li J, Lee K, Shapley JR. Electrochemistry of carbidopentaruthenium C60 complexes and related clusters Organometallics. 21: 3940-3946. DOI: 10.1021/Om020553D  0.574
2001 Wright CA, Shapley JR. Carbidoheptarhenate cluster complexes of cadmium and zinc units: the structure of [PPh(4)](2)[Re(7)C(CO)(21)(mu3-ZnCl)]. Inorganic Chemistry. 40: 6338-40. PMID 11703142 DOI: 10.1021/Ic0106064  0.578
2001 Wright CA, Brand U, Shapley JR. Synthesis and characterization of the dimercury(I)-linked compound [PPn]4[(Re7C(CO)21Hg)2]. Oxidative cleavage of the mercury-mercury bond leading to carbidoheptarhenate complexes of mercury(II), including [PPN][Re7C(CO)21Hg(S=C(NME2)2)]. Inorganic Chemistry. 40: 4896-901. PMID 11531437 DOI: 10.1021/Ic0011213  0.601
2000 Brand U, Shapley JR. Carbidohexarhenate cluster cores bicapped by mercury with acetate or thiolate ligands. Inorganic Chemistry. 39: 32-6. PMID 11229028 DOI: 10.1021/Ic990722V  0.373
2000 Park JT, Shapley JR, Lee K, Song H. Hydrocarbyl Ligand Transformation on the Tungsten-Triosmium Cluster Framework Journal of Cluster Science. 11: 343-358. DOI: 10.1023/A:1009097706507  0.537
2000 Khayatpoor R, Shapley JR. Mono- and bimetalated rhenium and manganese carbonyl derivatives of 1,2-bis(indenyl)ethane Organometallics. 19: 2382-2388. DOI: 10.1021/Om990896K  0.789
2000 Hamilton DH, Shapley JR. Synthesis and Characterization of (μ-H)2Os3(CO)9(PPh3)(μ-CH 2) and Related Compounds. Phosphine Ligand Effects on the Methylene/Methyl Tautomerization Organometallics. 19: 761-769. DOI: 10.1021/Om9904293  0.448
2000 Hsu HF, Shapley JR. Triruthenium cluster complexes of C60 and C70: Carbonyl site exchange probed via triphenylphosphine ligand derivatives Journal of Organometallic Chemistry. 599: 97-105. DOI: 10.1016/S0022-328X(00)00016-4  0.588
1999 Khayatpoor R, Shapley JR. Formation of (η5-C9H7)2Re2(CO)4(μ-CO) and Its Rearrangement to (η5-C9H7)Re(CO)2(μ-η2,η5-C9H7)Re(CO)3 Organometallics. 18: 1353-1356. DOI: 10.1021/Om9808514  0.78
1998 Brand U, Shapley JR. Carbidoheptarhenate Cluster Complexes of Mercury with Hydrosulfide or Functionalized Thiolate Ligands. Inorganic Chemistry. 37: 5697-5699. PMID 11670724 DOI: 10.1021/Ic980591I  0.317
1998 Somerville DM, Shapley JR. Zeolite-NaY-supported Ir/Sn catalysts derived from single- and dual-source organometallic precursors. Preparation and characterization of highly selective dehydrogenation catalysts Catalysis Letters. 52: 123-129. DOI: 10.1023/A:1019056411553  0.346
1998 Lee K, Shapley JR. Substitution site specificity on the Ru10C2 cluster framework. Multiple convergent pathways to the mixed hydrocarbon ligand derivative Ru10C2(CO)21(NBD)(C2R2) Organometallics. 17: 4368-4373. DOI: 10.1021/Om980565S  0.519
1998 Lee K, Shapley JR. Substitution of [Ru10C2(CO)24]2-with Allene. Reversible Formation of [Ru10C2(CO)22(μ-η2:η2-C3H4)]2-and [Ru10C2(CO)20(μ-η2:η2-C3H4)2]2- Organometallics. 17: 4030-4036. DOI: 10.1021/Om980486G  0.464
1998 Hamilton DH, Shapley JR. Phosphine ligand effects on the formation, equilibration, and reactivity of the isomeric vinyl complexes (μ-H)Os3(CO)9(PR3)(μ-η 2-CH=CH2) Organometallics. 17: 3087-3090. DOI: 10.1021/Om980015U  0.398
1998 Lee K, Wilson SR, Shapley JR. Reversible transformation between methylene and methylidyne-hydride moieties on the Ru10C2 framework Organometallics. 17: 4113-4116. DOI: 10.1021/Om971120R  0.606
1998 Lee K, Shapley JR. Face-coordinated C60 complexes with carbido pentaruthenium cluster cores including a bimetallic platinum-pentaruthenium complex Organometallics. 17: 3020-3026. DOI: 10.1021/Om971091K  0.588
1998 Hsu HF, Du Y, Albrecht-Schmitt TE, Wilson SR, Shapley JR. Structural comparison of M(CO)3(dppe)(η2-C60) (M = Mo, W), Mo(CO)3(dppe)(η2-C70), and W(CO)3(dppe)(η2-trans-C2H 2(CO2Me)2) Organometallics. 17: 1756-1761. DOI: 10.1021/Om971013X  0.672
1998 Nashner MS, Frenkel AI, Somerville D, Hills CW, Shapley JR, Nuzzo RG. Core shell inversion during nucleation and growth of bimetallic Pt/Ru nanoparticles Journal of the American Chemical Society. 120: 8093-8101. DOI: 10.1021/Ja980638Z  0.302
1998 Linqing M, Brand U, Shapley JR. Synthesis of a Heptanuclear Rhenium - Iridium Carbido Carbonyl Cluster and of (Triphenylphosphine)gold(I) Derivatives Inorganic Chemistry. 37: 3060-3065. DOI: 10.1021/Ic9706109  0.362
1998 Latten JL, Hsu G, Henly TJ, Wilson SR, Shapley JR. Hydride and Gold(triphenylphosphine) Derivatives of Hexarhenium Carbido Octadecacarbonyl Inorganic Chemistry. 37: 2520-2524. DOI: 10.1021/Ic9705756  0.387
1998 Serp P, Kalck P, Feurer R, Morancho R, Lee KY, Shapley JR. Tri(μ-carbonyl)nonacarbonyltetrarhodium, Rh4(μ-CO) 3(CO)9 Inorganic Syntheses. 32: 284-287. DOI: 10.1002/9780470132630.Ch45  0.392
1998 Adams RD, Barnard TS, Cortopassi JE, Wu W, Li Z, Shapley JR, Lee K. Platinum-ruthenium carbonyl cluster complexes Inorganic Syntheses. 32: 280-284. DOI: 10.1002/9780470132630.Ch44  0.309
1998 Cifuentes MP, Humphrey MG, Shapley JR, Lee K. High nuclearity hydridodecaruthenium clusters Inorganic Syntheses. 32: 287-293.  0.419
1998 Lee K, Shapley JR. Substitution of [Ru10C2(CO)24]2- with allene. Reversible formation of [Ru10C2(CO)22(μ-η2:η 2-C3H4)]2- and [Ru10C2(CO)20(μ-η2 Organometallics. 17: 4030-4036.  0.302
1997 Comstock MC, Prussak-Wieckowska T, Wilson SR, Shapley JR. Synthesis and Properties of IrRe(2)(&mgr;-H)(2)(CO)(9)(eta(5)-C(9)H(7)). Inorganic Chemistry. 36: 4397-4404. PMID 11670098 DOI: 10.1021/Ic960990I  0.35
1997 Brand U, Coffer JL, Henly TJ, Wilson SR, Shapley JR. Carbidoheptarhenate Complexes of Mercury Hydroxide and Arenethiolate. Crystal Structures of [NEt(3)Bz](2)[Re(7)C(CO)(21)HgOH] and [PPh(4)](2)[Re(7)C(CO)(21)HgSC(6)H(4)Br]. Inorganic Chemistry. 36: 3386-3389. PMID 11670008 DOI: 10.1021/Ic970068O  0.355
1997 Hsu HF, Wilson SR, Shapley JR. Triruthenium cluster complexes of C70. Synthesis and structural characterization of {Ru3(CO)9}x(μ3-η 2,η2,η2-C70) (x = 1, 2) Chemical Communications. 1125-1126. DOI: 10.1039/A701753G  0.598
1997 Somerville D, Nashner M, Nuzzo R, Shapley J. Catalysis Letters. 46: 17-25. DOI: 10.1023/A:1019045929957  0.31
1997 Comstock MC, Shapley JR. Synthesis and reactivity of Ir(CO)(η2-C2R2)(η5-C 9H7) (R = Ph, Tol). Alkyne coupling and arene C-H bond activation forming a substituted butadiene ligand Organometallics. 16: 4816-4823. DOI: 10.1021/Om970579I  0.381
1997 Hsu HF, Wilson SR, Shapley JR. Reversible phenyl coordination of a cluster-bound triphenylphosphine ligand: Ru6C(CO)13{PPh2(μ-η6-C 6H6)} Organometallics. 16: 4937-4939. DOI: 10.1021/Om9705261  0.619
1997 Benson JW, Ishida T, Lee K, Wilson SR, Shapley JR. Oxidative substitution of [Ru10C2(CO)24]2- with disubstituted alkynes: Facile formation and reduction of Ru10C2(CO)23(C2RR′) Organometallics. 16: 4929-4932. DOI: 10.1021/Om9703752  0.508
1997 Lee K, Hsu HF, Shapley JR. Coordination of C60 to penta- and hexaruthenium cluster frames Organometallics. 16: 3876-3877. DOI: 10.1021/Om970265V  0.578
1997 Comstock MC, Prussak-Wieckowska T, Wilson SR, Shapley JR. Complexes of Ir3(CO)3(η5-C9H 7)3 with metal fragment electrophiles Organometallics. 16: 4033-4040. DOI: 10.1021/Om960460U  0.463
1997 Nashner MS, Frenkel AI, Adler DL, Shapley JR, Nuzzo RG. Structural characterization of carbon-supported platinum-ruthenium nanoparticles from the molecular cluster precursor PtRu5C(CO)16 Journal of the American Chemical Society. 119: 7760-7771. DOI: 10.1021/Ja971039F  0.315
1997 Brand U, Shapley JR. A Carbidoheptarhenate Complex of Thallium(I) Inorganic Chemistry. 36: 253-255. DOI: 10.1021/Ic9609867  0.323
1996 Bauer JA, Chung JH, Boyd EP, Liu J, Strickland DS, Kneuper HJ, Shapley JR, Shore SG. Reduction of the Unique Carbonyl in (&mgr;-H)(2)Os(3)(CO)(9)(&mgr;(3)-CCO) by BH(3).THF. Molecular Structure of (&mgr;-H)(3)Os(3)(CO)(9)(&mgr;(3)-CCH(3)). Inorganic Chemistry. 35: 1405-1407. PMID 11666344 DOI: 10.1021/Ic951118X  0.372
1996 Hsu G, Wilson SR, Shapley JR. Synthesis, Characterization, and Comparative Properties of [PPN](2)[Re(6)C(CO)(18)Mo(CO)(4)] and [PPN](2)[Re(6)C(CO)(18)Ru(CO)(3)]. Inorganic Chemistry. 35: 923-928. PMID 11666266 DOI: 10.1021/Ic950887D  0.334
1996 Koike M, Hamilton DH, Wilson SR, Shapley JR. Reaction of (μ-H)2Os3(CO)9(PPh3) with acetylene and ethylene. Structures, dynamics, and interconversion of two isomers of the vinyl complex (μ-H)Os3(CO)9(PPh3)(μ-CH=CH2) Organometallics. 15: 4930-4938. DOI: 10.1021/Om9607006  0.424
1996 Hsu HF, Shapley JR. Ru3(CO)9(μ3-η2,η2,η2-C60): A cluster face-capping, arene-like complex of C60 Journal of the American Chemical Society. 118: 9192-9193. DOI: 10.1021/Ja962077M  0.547
1995 Ralph SF, Simerly SW, Shapley JR. Carbonyl ligand substitution at rhodium in the heterometallic cluster [PPN]2[Re7C(CO)21Rh(CO)2]. A reactivity comparison with mononuclear (n5-C5H5Rh(CO)2 and related compounds Inorganica Chimica Acta. 240: 615-621. DOI: 10.1016/0020-1693(95)04590-2  0.357
1995 Comstock MC, Shapley JR. Hydrocarbyl ligand derivatives of group 6-group 9 heterometallic clusters Coordination Chemistry Reviews. 143: 501-533. DOI: 10.1016/0010-8545(95)01140-K  0.306
1994 Hsu G, Wilson SR, Shapley JR. Methylene Complexes of Higher Nuclearity Clusters: [PPN][Re7C(CO)21(.mu.-CH2)] and [PPN]2[Re6C(CO)18(.mu.-CH2)] Organometallics. 13: 4159-4161. DOI: 10.1021/Om00023A013  0.405
1994 Comstock MC, Wilson SR, Shapley JR. Synthesis, Characterization, and Structure of (.eta.5-C9H7)3Ir3(.mu.-CO)3. Comparative Spectroscopic Properties of (.eta.5-C9H7)3Ir3 - xRhx(.mu.-CO)3 (x = 0-3) Organometallics. 13: 3805-3809. DOI: 10.1021/Om00022A015  0.415
1994 Koike M, VanderVelde DG, Shapley JR. Solution Structure and Dynamics of (.mu.-H)Os3(CO)10(.mu.-CH3). New 1H and 13C NMR Studies Organometallics. 13: 1404-1410. DOI: 10.1021/Om00016A048  0.373
1994 Szajek LP, Shapley JR. Stereodynamics and Reactivity of the Indenyliridium(I) Complex (.eta.5-C9H7)Ir(.eta.2-C8H14)(CO). Comparison with the Cyclopentadienyl Analog (.eta.5-C5H5)Ir(.eta.2-C8H14)(CO) Organometallics. 13: 1395-1403. DOI: 10.1021/Om00016A047  0.389
1994 Park JT, Chi Y, Shapley JR, Churchill MR, Ziller JW. Characterization of the oxo-alkylidyne complex CpWOs3(CO) 10(μ-O)(μ3-CCH2Tol) resulting from acyl ligand C-O bond scission. Interconversion of alkylidyne, alkylidene, vinylidene, and alkyne ligand moieties in a single heterometallic cluster system Organometallics. 13: 813-821. DOI: 10.1021/Om00015A015  0.535
1994 Szajek LP, Shapley JR. Observation of intermediates in the protonation of (.eta.5-C9H7)Ir(.eta.4-C8H12) with trifluoroacetic acid. [Erratum to document cited in CA119(19):203599a] Organometallics. 13: 744-744. DOI: 10.1021/Om00014A056  0.356
1994 Koike M, Shapley JR. The reaction of (μ-H)2Os3(CO)9(PPh3) with ethylene affords the ethylidene complex (μ-H)2Os3(CO)9(PPh3)(μ-CHCH3) Journal of Organometallic Chemistry. 470: 199-205. DOI: 10.1016/0022-328X(94)80168-1  0.343
1994 Comstock MC, Wilson SR, Shapley JR. Synthesis, characterization, and structure of (η5-C9H7)3Ir 3(μ-CO)3. Comparative spectroscopic properties of (η5-C9H7)3Ir 3-xRhx(μ-CO)3 (x = 0-3) Organometallics. 13: 3805-3809.  0.313
1994 Szajek LP, Shapley JR. Stereodynamics and reactivity of the indenyliridium(I) complex (η5-C9H7)Ir(η2-C 8H14)(CO). Comparison with the cyclopentadienyl analog (η5-C5H5)Ir(η2-C 8H14)(CO) Organometallics. 13: 1395-1403.  0.313
1993 Szajek LP, Shapley JR. Observation of intermediates in the protonation of (.eta.5-C9H7)Ir(.eta.4-C8H12) with trifluoroacetic acid Organometallics. 12: 3772-3775. DOI: 10.1021/Om00033A058  0.381
1993 Zhang S, Brown TL, Du Y, Shapley JR. Metalation of fullerene (C60) with pentacarbonylrhenium radicals. Reversible formation of C60{Re(CO)5}2 Journal of the American Chemical Society. 115: 6705-6709. DOI: 10.1021/Ja00068A030  0.302
1993 Linqing M, Shapley JR. Selective substitution and oxidative addition reactions at the iridium vertex in [Re7C(CO)21Ir(C8H14)(CO)]2- and related clusters Inorganica Chimica Acta. 212: 303-310. DOI: 10.1016/S0020-1693(00)92337-5  0.397
1993 Ma L, Williams GK, Shapley JR. Organometallic chemistry of hexanuclear carbonyl clusters Coordination Chemistry Reviews. 128: 261-284. DOI: 10.1016/0010-8545(93)80034-3  0.337
1993 Szajek LP, Shapley JR. Observation of intermediates in the protonation of (η5-C9H7)Ir(η4-C 8H12) with CF3CO2H Organometallics. 12: 3772-3775.  0.305
1992 Koefod RS, Xu C, Lu W, Shapley JR, Hill MG, Mann KR. An electrochemical and spectroelectrochemical study of an iridium-buckminsterfullerene complex. Evidence for C60-localized reductions Journal of Physical Chemistry. 96: 2928-2930. DOI: 10.1021/J100186A029  0.328
1992 Zhu Y, Koefod RS, Devadoss C, Shapley JR, Schuster GB. Effect of transition metal coordination on the photophysical properties of fullerene, C60. Triplet formation and lifetime in (.eta.5-C9H7)Ir(CO)(.eta.2-C60) Inorganic Chemistry. 31: 3505-3506. DOI: 10.1021/Ic00043A005  0.378
1992 Frauenhoff GR, Liu JC, Wilson SR, Shapley JR. Triosmium carbonyl cluster complexes of bridging phosphonate, arsonate, and phosphinate ligands Journal of Organometallic Chemistry. 437: 347-361. DOI: 10.1016/0022-328X(92)85079-C  0.421
1991 Szajek LP, Shapley JR. Unexpected synthesis of CpIr(.eta.4-C5H6) and a proton and carbon-13 NMR comparison with its cobalt and rhodium congeners Organometallics. 10: 2512-2515. DOI: 10.1021/Om00053A066  0.378
1991 Ma L, Szajek LP, Shapley JR. Site-selective oxidative-addition reactions in a heterometallic octanuclear carbido cluster compound. A reactivity parallel with mononuclear indenyliridium complexes Organometallics. 10: 1662-1664. DOI: 10.1021/Om00052A009  0.353
1991 Szajek LP, Lawson RJ, Shapley JR. The "indenyl effect" on ethylene rotation in iridium(I) complexes Organometallics. 10: 357-361. DOI: 10.1021/Om00047A074  0.342
1991 Frauenhoff GR, Wilson SR, Shapley JR. Isolation, characterization, and substitution reactions of the osmium trinuclear triflate complex H2Os3(CO)9(O3SCF3)2. X-ray crystal structure of the mixed oxyligand cluster (.mu.-H)2Os3(CO)9(.mu.,.eta.2-O2CCH3)(.eta.1-O3SCF3) Inorganic Chemistry. 30: 78-85. DOI: 10.1021/Ic00001A015  0.405
1991 Strickland DA, Shapley JR. Ester and amide functionalized alkylidyne triosmium clusters. rearrangement of acyl-coordinated alkylidene complexe Journal of Organometallic Chemistry. 401: 187-197. DOI: 10.1016/0022-328X(91)86207-7  0.354
1991 Szajek LP, Shapley JR. Unexpected synthesis of CpIr(η4-C5H6) and a 1H and 13C NMR comparison with its cobalt and rhodium congeners Organometallics. 10: 2512-2515.  0.308
1990 Akita M, Shapley JR. Selective synthesis of functionalized alkylidynetriosmium compounds via silicon and tin reagents Organometallics. 9: 2209-2211. DOI: 10.1021/Om00158A016  0.556
1990 Ma L, Shapley JR, Wilson SR. Synthesis and characterization of heptarhenium carbido clusters with (.eta.2-olefin)iridium capping moieties Inorganic Chemistry. 29: 5133-5136. DOI: 10.1021/Ic00350A024  0.302
1990 Frauenhoff GR, Shapley JR. Attack at coordinated carbon monoxide in a set of dihydrido triosmium carbonyl clusters Journal of Organometallic Chemistry. 397: 359-370. DOI: 10.1016/0022-328X(90)85335-V  0.348
1989 Henly TJ, Shapley JR. Synthesis, characterization, and some ligand-redistribution reactions of the mercuric complexes [Re7C(CO)21HgY]2- Organometallics. 8: 2729-2733. DOI: 10.1021/Om00113A033  0.38
1989 Shapley JR, Whittlesey BR, Wilson SR. Preparation and crystal structure of [(1,5-C8H12)Rh( μ-η2-ReO4)]η Polyhedron. 8: 375-377. DOI: 10.1016/S0277-5387(00)80430-1  0.427
1989 Yeh WY, Wilson SR, Shapley JR. Synthesis, characterization and crystal structure of Os3(CO)8(η1-C(OMe)Ph)(μ3-CPh)(μ3-COMe), a cluster with a carbene and two carbyne ligands Journal of Organometallic Chemistry. 371: 257-265. DOI: 10.1016/0022-328X(89)88031-3  0.415
1989 Chi Y, Shapley JR, Churchill MR, Fettinger JC. Competitive addition and substitution reactions in the interaction of CpWOs3(CO)9(μ-O)(μ3-CCH2Tol) with phosphorus donors. The crystal structure of CpWOs3(CO)8(PPh2Me)(μ-O)(μ3-CCH2Tol) Journal of Organometallic Chemistry. 372: 273-285. DOI: 10.1016/0022-328X(89)87101-3  0.343
1989 Schacht HT, Powell AK, Vahrenkamp H, Koike M, Kneuper HJ, Shapley JR. Synthesis, characterization, and X-ray crystal structure of (μ-H)2Os3(CO)9(μ3-Te) Journal of Organometallic Chemistry. 368: 269-275. DOI: 10.1016/0022-328X(89)85404-X  0.345
1988 Park JT, Shapley JR, Bueno C, Ziller JW, Churchill MR. Structural studies on polynuclear osmium carbonyl hydrides. Part 35. Coordination and scission of alkynes on a tungsten-triosmium framework. Crystal structures of (.eta.5-C5H5)WOs3(CO)10[.mu.3-.eta.2-C2(C6H4CH3)2]H and (.eta.5-C5H5)WOs3(CO)10[.mu.3-.eta.2-C2(CO2C2H5)2]H - species with an alkyne ligand bound to Os3 and WOs2 faces of tetrahedral WOs3 clusters Organometallics. 7: 2307-2316. DOI: 10.1021/Om00101A010  0.445
1988 Henly TJ, Shapley JR, Rheingold AL, Geib SJ. Systematic synthesis of mixed-metal clusters via capping reactions. Characterization of a set of octanuclear carbido clusters involving rhenium and various platinum metals Organometallics. 7: 441-448. DOI: 10.1021/Om00092A031  0.339
1988 Hayward CMT, Folkers JP, Shapley JR. Electrophilic substitution of carbidoheneicosacarbonylheptarhenate (3-). Synthesis and characterization of bis[bis(diphenylphosphine)nitrogen] carbidoeicosacarbonylnitrosylheptarhenate(2-). Inorganic Chemistry. 27: 3685-3687. DOI: 10.1021/Ic00293A055  0.302
1988 Henly TJ, Wilson SR, Shapley JR. Synthesis and crystal structure of [Et4N]2[Re7C(CO)21Pd(C 9H9)] (C9H9 = η3-1-Phenylallyl). An example of a non-"slipped" palladium(II) capping moiety Inorganic Chemistry. 27: 2551-2553. DOI: 10.1021/Ic00287A037  0.427
1988 Kneuper HJ, Strickland DS, Shapley JR. Synthesis and characterization of nonacarbonyl(.mu.3-fluoromethylidyne)trihydridotriosmium. Carbon-13 NMR comparison of triosmium- and tricobalt-substituted methylidyne complexes Inorganic Chemistry. 27: 1110-1111. DOI: 10.1021/Ic00279A037  0.317
1988 Yeh WY, Kneuper HJ, Shapley JR. Interconversion of benzylidyne and methylbenzyne triosmium complexes Polyhedron. 7: 961-965. DOI: 10.1016/S0277-5387(00)86316-0  0.354
1988 Churchill MR, Ziller JW, Shapley JR, Yeh WY. Reaction of (μ-H)Os3(CO)10(μ3-CPh) with diphenylacetylene. Alkylidynealkyne coupling and the crystal structure of Os3(CO)8(μ,η2-CPhCHPh)(μ,η3-C3Ph3) Journal of Organometallic Chemistry. 353: 103-117. DOI: 10.1016/0022-328X(88)80304-8  0.37
1988 HENLY TJ, WILSON SR, SHAPLEY JR. ChemInform Abstract: Synthesis and Crystal Structure of (Et4N)2(Re7C(CO)21Pd(C9H9)) (C9H9 = η3-1-Phenylallyl). An Example of a Non-“Slipped” Palladium(II) Capping Moiety. Cheminform. 19. DOI: 10.1002/chin.198846284  0.313
1988 Park JT, Shapley JR, Bueno C, Ziller JW, Churchill MR. Coordination and scission of alkynes on a tungsten-triosmium framework. Crystal structures of (η5-C5H5)WOs3(CO) 10[μ3η2-C2(C 6H4CH3)2]H and (η5-C5H5)WOs3(CO) .. Organometallics. 7: 2307-2316.  0.31
1987 Henly TJ, Wilson SR, Shapley JR. Intermediates in the direct synthesis of rhenium carbide clusters from rhenium carbonyl. Crystal structure of [Et4N]2[HRe5(μ5-C)(CO) 16] Organometallics. 6: 2618-2620. DOI: 10.1021/Om00155A034  0.342
1987 Kneuper HJ, Shapley JR. Rapid, reversible proton exchange between ring and metal sites in the aryne complexes H2Os3(CO)9(.mu.3,.eta.2-C6H4) and related derivatives Organometallics. 6: 2455-2456. DOI: 10.1021/Om00154A033  0.376
1987 Chi Y, Shapley JR, Ziller JW, Churchill MR. Synthesis, crystal structure, and stereoisomerism of the alkylidene complex (.eta.5-C5H5)WOs3(CO)9(.mu.-O)(.mu.-Cl)(.mu.-CHCH2C6H4Me-4) and related complexes Organometallics. 6: 301-307. DOI: 10.1021/Om00145A011  0.571
1987 Yeh WY, Shapley JR, Ziller JW, Churchill MR. Phenylation reactions with triosmium carbyne and carbene cluster complexes. The crystal structure of Os3(CO)8[.mu.3,.eta.5-C(OMe)C(1,2-C6H4CPh)], a cluster complex containing an osmacyclopentadiene system linked to a Fischer-type carbene ligand Organometallics. 6: 1-7. DOI: 10.1021/Om00144A001  0.371
1987 VanderVelde DG, Holmgren JS, Shapley JR. Proton site exchange in (.mu.-H)3M3(CO)9(.mu.3-CH) (M = Ru, Os) Inorganic Chemistry. 26: 3077-3078. DOI: 10.1021/Ic00265A033  0.366
1987 CHI Y, SHAPLEY JR, CHURCHILL MR, LI Y. ChemInform Abstract: Structural Studies on Polynuclear Osmium Carbonyl Hydrides. Part 33. Formation of Tungsten-Triosmium Clusters. Crystal Structure and Reactivity of (η5-C5H5)WOs3(CO)12(μ3-CC6H4CH3)(μ-H)2. Cheminform. 18. DOI: 10.1002/chin.198711280  0.316
1987 Chi Y, Shapley JR, Ziller JW, Churchill MR. Synthesis, crystal structure, and stereoisomerism of the alkylidene complex (η5-C5H5)WOs3(CO) 9(μ-O)(μ-Cl)(μ-CHCH2Tol) and related complexes Organometallics. 6: 301-307.  0.304
1986 Holmgren JS, Shapley JR, Wilson SR, Pennington WT. Methylene-carbonyl coupling: formation of bridging .eta.3-ketene and .eta.4-oxaallyl complexes. Journal of the American Chemical Society. 108: 508-10. PMID 22175472 DOI: 10.1021/Ja00263A027  0.389
1986 Keiter RL, Strickland DS, Wilson SR, Shapley JR. Cluster complexes of tridentate sulfate and (hydrogen) phosphate. The crystal structure of H2Os3(CO)9(μ3-O3SO) Journal of the American Chemical Society. 108: 3846-3847. DOI: 10.1021/Ja00273A059  0.336
1986 Cree-Uchiyama M, Shapley JR, St. George GM. HOs3(CO)10(C2H5): an alkyl complex with observable .alpha.,.beta. and reductive elimination processes Journal of the American Chemical Society. 108: 1316-1317. DOI: 10.1021/Ja00266A043  0.326
1986 Chi Y, Shapley JR, Churchill MR, Li YJ. Formation of tungsten-triosmium clusters. Crystal structure and reactivity of (η5-C5H5)WOs3(CO) 12(μ3-CC6H4CH 3)(μ-H)2 Inorganic Chemistry. 25: 4165-4170. DOI: 10.1021/Ic00243A022  0.42
1986 Henly TJ, Shapley JR, Rheingold AL. Crystal structure of [Ph4As]2[Re7C(CO)21Au(PPh3)]. Comparison of H+ and Au(PPh3)+ coordination to [Re7C(CO)21]3- Journal of Organometallic Chemistry. 310: 55-65. DOI: 10.1016/S0022-328X(00)99660-8  0.383
1986 Yeh WY, Shapley JR. Alkylidyne-alkylidyne and alkylidyne-carbonyl coupling on the triosmium framework Journal of Organometallic Chemistry. 315: C29-C31. DOI: 10.1016/0022-328X(86)80426-0  0.379
1986 Churchill MR, Li YJ, Shapley JR, Foose DS, Uchiyama WS. Iridium-carbonyl clusters. VI. Mixed-metal clusters via metal-hydride coupling. Synthesis of CpMM′3(CO)11 (M = Mo, W; M′ = Co, Ir) and the crystal structure of CpMoIr3(CO)11 Journal of Organometallic Chemistry. 312: 121-131. DOI: 10.1016/0022-328X(86)80285-6  0.387
1986 KEITER RL, STRICKLAND DS, WILSON SR, SHAPLEY JR. ChemInform Abstract: Cluster Complexes of Tridentate Sulfate and (Hydrogen) Phosphate. Chemischer Informationsdienst. 17. DOI: 10.1002/Chin.198642284  0.302
1986 Cree-Uchiyama M, Shapley JR, St. George GM. HOs3(CO)10(C2H5): An alkyl complex with observable α, β, and reductive elimination processes Journal of the American Chemical Society. 108: 1316-1317. DOI: 10.1002/Chin.198629278  0.339
1986 Holmgren JS, Shapley JR, Wilson SR, Pennington WT. Methylene-carbonyl coupling: Formation of bridging η3-ketene and η4-oxaallyl complexes Journal of the American Chemical Society. 108: 508-510. DOI: 10.1002/Chin.198623296  0.345
1985 Chi Y, Shapley JR. Reversible alkyne ligand scission: formation and reactivity of Cp2W2Os(CO)5(.mu.-CTol)(.mu.3-CTol) Organometallics. 4: 1900-1901. DOI: 10.1021/Om00129A040  0.526
1985 Shapley JR, Yeh WY, Churchill MR, Li YJ. Synthesis and crystal structure of (.mu.-H)Os3(CO)9(.eta.1-C(OMe)2)(.mu.3-CPh), a mixed carbene carbyne cluster complex Organometallics. 4: 1898-1900. DOI: 10.1021/Om00129A039  0.377
1985 Holmgren JS, Shapley JR. Synthesis, characterization, and fluxionality of Ru3(CO)10(.mu.-CO)(.mu.-CH2) Organometallics. 4: 793-794. DOI: 10.1021/Om00123A030  0.431
1985 Churchill MR, Biondi LV, Shapley JR, McAteer CH. Synthesis and X-ray structure of (η5-C5H5)2W2Ir2(CO)7(CHCO2Et)2, a tetrahedral heterometal cluster with two different environments for ethylcarboxylatocarbene ligands Journal of Organometallic Chemistry. 280: c63-c66. DOI: 10.1016/0022-328X(85)88123-7  0.371
1985 Holmgren JS, Shapley JR, Belmonte PA. Observation and interpretation of HH coupling in 1H187Os satellite NMR spectra Journal of Organometallic Chemistry. 284: C5-C8. DOI: 10.1016/0022-328X(85)80020-6  0.301
1985 PARK JT, SHAPLEY JR, CHURCHILL MR, BUENO C. ChemInform Abstract: STRUCTURAL STUDIES ON POLYNUCLEAR OSMIUM CARBONYL HYDRIDES. 29. DEGENERATE FRAMEWORK REARRANGEMENT IN A CAPPED-SQUARE-PYRAMIDAL METAL-CARBON CLUSTER AND ITS CONVERSION TO A CAPPED-TRIGONAL-BIPYRAMIDAL CLUSTER. CRYSTAL STRUCTURES OF (η Chemischer Informationsdienst. 16. DOI: 10.1002/Chin.198520263  0.33
1985 Holmgren JS, Shapley JR. Synthesis, characterization, and fluxionality of Ru3(CO)10(μ-CO)(μ-CH2) Organometallics. 4: 793-794.  0.306
1984 Shapley JR, McAteer CH, Churchill MR, Biondi LV. Coordination and scission of alkynes on a ditungsten-diiridium framework. The crystal structure of (.eta.5-C5H5)2W2Ir2(CO)6(.mu.3-CPh)(.mu.3-.eta.3-C3Ph3) Organometallics. 3: 1595-1596. DOI: 10.1021/Om00088A027  0.348
1984 Holmgren JS, Shapley JR. Synthesis, characterization, and reactivity of HRu3(CO)10(CH) and H2Ru3(CO)9(CCO) Organometallics. 3: 1322-1323. DOI: 10.1021/Om00086A038  0.4
1984 Clauss AD, Shapley JR, Wilker CN, Hoffmann R. Alkyne Scission on a Trimetallic Framework: Experimental Evidence and Theoretical Analysis Organometallics. 3: 619-623. DOI: 10.1021/Om00082A020  0.305
1984 Shapley JR, Park JT, Churchill MR, Ziller JW, Beanan LR. Thermal carbon-oxygen bond scission in a .mu.3-.eta.2-coordinated acyl. Structural characterization of a doubly bridging four-electron oxo ligand Journal of the American Chemical Society. 106: 1144-1145. DOI: 10.1021/Ja00316A069  0.378
1984 Park JT, Shapley JR, Churchill MR, Bueno C. Structural studies on polynuclear osmium carbonyl hydrides. 29. Degenerate framework rearrangement in a capped-square-pyramidal metal-carbon cluster and its conversion to a capped-trigonal-bipyramidal cluster. Crystal structures of (.eta.5-C5H5)WOs3(CO)10(.mu.3-CC6H4CH3)2H and (.eta.5-C5H5)WOs3(CO)9(.mu.3-CC6H4CH3)2H Inorganic Chemistry. 23: 4476-4486. DOI: 10.1021/Ic00194A016  0.398
1984 Churchill MR, Bueno C, Park JT, Shapley JR. Structural studies on polynuclear osmium carbonyl hydrides. 28. Synthesis and structure of (.eta.5-C5H5)WOs3(CO)8(.mu.-O)(.mu.3-.eta.2-C2H2)(.mu.-H), a tetrahedral tungsten-triosmium cluster complex with a unique unsymmetrical (W, Os) edge-bridging oxo ligand Inorganic Chemistry. 23: 1017-1021. DOI: 10.1021/Ic00176A006  0.423
1984 Samkoff DE, Shapley JR, Churchill MR, Wasserman HJ. Structural studies on polynuclear osmium carbonyl hydrides. 25. Synthesis, characterization, and reversible photochemical/thermal interconversion of .eta.1- and .eta.2-bridged (aryldiazo)triosmium clusters. Crystal structure of (.mu.-H)Os3(CO)10(.mu.-.eta.2-N:NPh) Inorganic Chemistry. 23: 397-402. DOI: 10.1021/Ic00172A004  0.368
1984 CHURCHILL MR, BUENO C, PARK JT, SHAPLEY JR. ChemInform Abstract: STRUCTURAL STUDIES ON POLYNUCLEAR OSMIUM CARBONYL HYDRIDES. 28. SYNTHESIS AND D STRUCTURE OF (η5-C5H5)WOS3(CO)8(μ-O)(μ3-η2-C2H2)(μ-H), A TETRAHEDRAL TUNGSTEN-TRIOSMIUM CLUSTER COMPLEX WITH A UNIQUE UNSYMMETRICAL (W, OS) EDGE-BRIDGING Chemischer Informationsdienst. 15. DOI: 10.1002/Chin.198429297  0.447
1984 SAMKOFF DE, SHAPLEY JR, CHURCHILL MR, WASSERMAN HJ. ChemInform Abstract: STRUCTURAL STUDIES ON POLYNUCLEAR OSMIUM CARBONYL HYDRIDES. 25. SYNTHESIS, CHARACTERIZATION, AND REVERSIBLE PHOTOCHEMICAL/THERMAL INTERCONVERSION OF η1- AND η2-BRIDGED (ARYLDIAZO)TRIOSMIUM CLUSTERS. CRYSTAL STRUCTURE OF (μ-H)OS3(CO)10 Chemischer Informationsdienst. 15. DOI: 10.1002/Chin.198421308  0.383
1984 Shapley JR, Park JT, Churchill MR, Ziller JW, Beanan LR. THERMAL CARBON-OXYGEN BOND SCISSION IN A μ3-η2-COORDINATED ACYL. STRUCTURAL CHARACTERIZATION OF A DOUBLY BRIDGING FOUR-ELECTRON OXO LIGAND Cheminform. 15. DOI: 10.1002/Chin.198421306  0.319
1984 Shapley JR, McAteer CH, Churchill MR, Biondi LV. Coordination and scission of alkynes on a ditungsten-dilridium framework. The crystal structure of (η5-C5H5)2W2Ir 2(CO)6(μ3-CPh)(μ3-η 3-C3Ph) Organometallics. 3: 1595-1596.  0.306
1984 Churchill MR, Bueno C, Park JT, Shapley JR. Synthesis and structure of (η5-C5H5)WOs3(CO) 8(μ-O)(μ3-η2-C2H 2)(μ-H), a tetrahedral tungsten-triosmium cluster complex with a unique unsymmetrical (W, Os) edge-bridging oxo ligand Inorganic Chemistry. 23: 1017-1021.  0.344
1983 Shapley JR, Strickland DS, St. George GM, Churchill MR, Bueno C. Coupling of methylidyne and carbonyl ligands on the triosmium cluster framework. Crystal structure of (.mu.-H)2Os3(CO)9(.mu.3-.eta.1-CCO) Organometallics. 2: 185-187. DOI: 10.1021/Om00073A044  0.354
1983 Park JT, Shapley JR, Churchill MR, Bueno C. Coordination and scission of alkynes on a tungsten-triosmium framework Journal of the American Chemical Society. 105: 6182-6184. DOI: 10.1021/Ja00357A053  0.308
1983 Park JT, Shapley JR, Churchill MR, Bueno C. Reaction of (.mu.-H)2Os3(CO)10 with (.eta.5-C5H5)(CO)2W.tplbond.CC6H4CH3. Crystal structure of (.eta.5-C5H5)WOs3(CO)11[C(O)CH2C6H4CH3]..apprx.0.5CCl4, a complex with a triply bridging (.mu.3,.eta.2) acyl ligand on the surface of a triangulated rhomboidal metal cluster Inorganic Chemistry. 22: 1579-1584. DOI: 10.1021/Ic00153A003  0.454
1983 PARK JT, SHAPLEY JR, CHURCHILL MR, BUENO C. ChemInform Abstract: REACTION OF (μ-H)2OS3(CO)10 WITH (η5-C5H5)(CO)2WCC6H4CH3. CRYSTAL STRUCTURE OF (η5-C5H5)WOS3(CO)11(C(O)CH2C6H4CH3).≅0.5CCL4, A COMPLEX WITH A TRIPLY BRIDGING (μ3,η2) ACYL LIGAND ON THE SURFACE OF A TRIANGULATED RHOMBOIDAL METAL CLUST Chemischer Informationsdienst. 14. DOI: 10.1002/Chin.198335338  0.454
1983 Shapley JR, Cree-Uchiyama ME, St. George GM, Churchill MR, Bueno C. Synthesis and reactivity of a "semi" triply bridging methylidyne complex. Crystal structure of HOs3(CO)10(CH) Journal of the American Chemical Society. 105: 140-142. DOI: 10.1002/Chin.198316296  0.41
1983 Park JT, Shapley JR, Churchill MR, Bueno C. Reaction of (μ-H)2Os3(CO)10 with (η5-C5H5)(CO)2W≡CC 6H4CH3. Crystal structure of (η5-C5H5)WOs3(CO) 11[C(O)CH2C6H4CH 3]·∼0.5CCl .. Inorganic Chemistry. 22: 1579-1584.  0.308
1982 Sievert AC, Strickland DS, Shapley JR, Steinmetz GR, Geoffroy GL. Conversion of a bridging methylene ligand to a ketenylidene moiety. Synthesis and reactivity of carbomethoxymethylidynenonacarbonyldihydrotriosmium Organometallics. 1: 214-215. DOI: 10.1021/Om00061A036  0.338
1982 Hayward CMT, Shapley JR, Churchill MR, Bueno C, Rheingold AL. Synthesis, characterization, and crystal structure of the [Ru10C2(CO)24] dianion. An edge-fused bioctahedral dicarbide cluster Journal of the American Chemical Society. 104: 7347-7349. DOI: 10.1021/Ja00389A090  0.301
1982 Shapley JR, St. George GM, Churchill MR, Hollander FJ. Structural studies on polynuclear osmium carbonyl hydrides. 23. Vibrational study and crystal structure of (.mu.-hydrido)(.mu.-formato)decacarbonyltriosmium (.mu.-H)(.mu.-O2CH)Os3(CO)10 Inorganic Chemistry. 21: 3295-3303. DOI: 10.1021/Ic00139A010  0.309
1982 Shapley JR, Adair PC, Lawson RJ, Pierpont CG. Thermal elimination of dihydrogen from (.eta.5-C5H5)Ir(CO)H2. Formation, structure, and reactivity of Cs-(.eta.5-C5H5)3Ir3(CO)3 Inorganic Chemistry. 21: 1701-1702. DOI: 10.1021/Ic00134A096  0.399
1982 Shapley JR, Samkoff DE, Bueno C, Churchill MR. Reaction of Os3(CO)10(NCCH3)2 with imidazole and related aromatic heterocycles. The crystal and molecular structure of (.mu.-H)Os3(CO)10(.mu.-3,4-.eta.2-N2C3H3) Inorganic Chemistry. 21: 634-639. DOI: 10.1021/Ic00132A034  0.315
1982 Dimas PA, Shapley JR. Reaction of the unsaturated complex [(η5-C5Me5)2Rh2(μ-NO)(μ-CO)] BF4 with diazo compounds Journal of Organometallic Chemistry. 228: C12-C14. DOI: 10.1016/S0022-328X(00)86780-7  0.4
1982 SHAPLEY JR, HARDWICK SJ, FOOSE DS, STUCKY GD, CHURCHILL MR, BUENO C, HUTCHINSON JP. ChemInform Abstract: BIMETALLIC CATALYSTS FROM PSEUDOTETRAHEDRAL IRIDIUM-TUNGSTEN CLUSTERS. SYNTHESIS AND CRYSTAL STRUCTURES OF (η5-C5H5)WIR3(CO)11 AND (η5-C5H5)2W2IR2(CO)10 Chemischer Informationsdienst. 13. DOI: 10.1002/Chin.198211325  0.447
1982 SHAPLEY JR, PARK JT, CHURCHILL MR, BUENO C, WASSERMAN HJ. ChemInform Abstract: REMARKABLY FACILE OSMIUM-OSMIUM BOND CLEAVAGE IN THE REACTION OF H2OS3(CO)10 WITH A TUNGSTEN CARBYNE. CRYSTAL STRUCTURES OF CPWOS3(CO)11(C(O)CH2C6H4ME) AND CP2W2OS(CO)7(C2(C6H4ME)2) Chemischer Informationsdienst. 13. DOI: 10.1002/Chin.198211323  0.305
1982 Shapley JR, Sievert AC, Churchill MR, Wasserman HJ. Coordination and coupling of alkylidene groups on a triosmium cluster framework. Crystal structure of Os3(CO)10(.mu.-CO)(.mu.-CHSiMe3) Cheminform. 13. DOI: 10.1002/Chin.198208335  0.305
1981 Shapley JR, Park JT, Churchill MR, Bueno C, Wasserman HJ. Remarkably facile Os-Os bond cleavage in the reaction of H2Os3(CO)10 with a tungsten carbyne. Crystal structures of CpWOs3(CO)11[C(O)CH2C6H 4Me] and Cp2W2Os(CO)7[C2(C6H 4Me)2] Journal of the American Chemical Society. 103: 7385-7387. DOI: 10.1021/Ja00414A081  0.376
1981 Shapley JR, Hardwick SJ, Foose DS, Stucky GD, Churchill MR, Bueno C, Hutchinson JP. Bimetallic catalysts from pseudotetrahedral iridium-tungsten clusters. Synthesis and crystal structures of (.eta.5-C5H5)WIr3(CO)11 and (.eta.5-C5H5)2W2Ir2(CO)10 Journal of the American Chemical Society. 103: 7383-7385. DOI: 10.1021/Ja00414A080  0.437
1981 Shapley JR, Sievert AC, Churchill MR, Wasserman HJ. Coordination and coupling of alkylidene groups on a triosmium cluster framework. Crystal structure of Os3(CO)10(.mu.-CO)(.mu.-CHSiMe3) Journal of the American Chemical Society. 103: 6975-6977. DOI: 10.1021/Ja00413A041  0.305
1981 Churchill MR, Hollander FJ, Lashewycz RA, Pearson GA, Shapley JR. Mixed-metal clusters by metal hydride coupling. Crystal structures of (.mu.-H)Os3Re(CO)15(NCCH3) and (.mu.-H)5Os3Re(CO)12. Direct conversion of a metalloligated cluster to a closed polyhedron Journal of the American Chemical Society. 103: 2430-2431. DOI: 10.1021/Ja00399A059  0.322
1981 Dimas PA, Lawson RJ, Shapley JR. Synthesis and characterization of bis(cyclopentadienyl)dinitrosyldirhodium and tris(cyclopentadienyl)dinitrosyltrirhodium Inorganic Chemistry. 20: 281-283. DOI: 10.1021/Ic50215A058  0.311
1981 Churchill MR, Hollander FJ, Lashewycz RA, Pearson GA, Shapley JR. Mixed-metal clusters by metal hydride coupling. Crystal structures of (μ-H)Os3Re(CO)15(NCCH3) and (μ-H)5Os3Re(CO)12. Direct conversion of a metalloligated cluster to a closed polyhedron Journal of the American Chemical Society. 103: 2430-2431. DOI: 10.1002/Chin.198131077  0.332
1981 DIMAS PA, DUESLER EN, LAWSON RJ, SHAPLEY JR. ChemInform Abstract: CATIONIC ALKYLIDYNE TRIRHODIUM CLUSTER COMPLEXES. CRYSTAL STRUCTURE ((η5-C5H5)3RH3(μ-CO)2(μ3-CH))PF6(TRIS(η5-CYCLOPENTADIENYL)-BIS(.M# U.2-CARBONYL)-μ3-METHYLIDYNE-TRIRHODIUM) HEXAFLUOROPHOSPHATE Chemischer Informationsdienst. 12. DOI: 10.1002/Chin.198112088  0.452
1981 Shapley JR, Hardwick SJ, Foose DS, Stucky GD, Churchill MR, Bueno C, Hutchinson JP. Bimetallic catalysts from pseudotetrahedral iridium-tungsten clusters. Syntheses and crystal structures of (η5-C5H5)WIr3(CO)11 and (η5-CsH5)2W2Ir 2(CO)10 Journal of the American Chemical Society. 103: 7383-7385.  0.337
1980 Dimas PA, Duesler EN, Lawson RJ, Shapley JR. Cationic alkylidyne trirhodium cluster complexes. Crystal structure [(.eta.5-C5H5)3Rh3(.mu.-CO)2(.mu.3-CH)]PF6[tris(.eta.5-cyclopentadienyl)-bis(.mu.2-carbonyl)-.mu.3-methylidyne-trirhodium] hexafluorophosphate Journal of the American Chemical Society. 102: 7787-7789. DOI: 10.1021/Ja00546A030  0.429
1980 Churchill MR, Lashewycz RA, Shapley JR, Richter SI. Synthesis, crystal structure, and dynamic behavior of tetra-.mu.-hydrido-.mu.-[1,2-bis(diphenylphosphino)ethane]-decacarbonyltetraruthenium, an isomer of (.mu.-H)4Ru4(CO)10(diphos) with a bridging diphos ligand Inorganic Chemistry. 19: 1277-1285. DOI: 10.1021/Ic50207A034  0.361
1980 Churchill MR, Hollander FJ, Shapley JR, Keister JB. Structural studies on polynuclear osmium carbonyl hydrides. 15. Preparation and x-ray crystal structure of (.mu.-H) Os3(CO)10(.mu.-NHSO2C6H4Me), a complex with an Os(.mu.-H)(.mu.-N)Os bridge Inorganic Chemistry. 19: 1272-1277. DOI: 10.1021/Ic50207A033  0.348
1980 Clauss AD, Dimas PA, Shapley JR. Reaction of the unsaturated complex [(μ5-C5Me5)Rh(μ-CO)]2 with diazo compounds Journal of Organometallic Chemistry. 201: C31-C34. DOI: 10.1016/S0022-328X(00)87942-5  0.378
1980 Churchill MR, Lashewycz RA, Shapley JR, Richter SI. Synthesis, crystal structure, and dynamic behavior of tetra-.mu.-hydrido-.mu.-[1,2-bis(diphenylphosphino)ethane]-decacarbonyltetraruthenium, an isomer of (.mu.-H)4Ru4(CO)10(diphos) with a bridging diphos ligand Cheminform. 11. DOI: 10.1002/Chin.198032072  0.361
1980 Dimas PA, Duesler EN, Lawson RJ, Shapley JR. Cationic alkylidyne-trirhodium cluster complexes. Crystal structure of [(η5-C5H5)3Rh 3(μ-CO)2(μ3-CH)]PF6 [9] Journal of the American Chemical Society. 102: 7787-7789.  0.32
1979 Shapley JR, Stuntz GF, Churchill MR, Hutchinson JP. X-Ray crystal structure and dynamic behaviour of [Ir4(CO) 11(CNBut)] Journal of the Chemical Society, Chemical Communications. 219-220. DOI: 10.1039/C39790000219  0.337
1978 Churchill MR, Hollander FJ, Shapley JR, Foose DS. New mixed-metal clusters via metal hydride coupling. Synthesis and crystal structures of [(µ2-H)Os3W(CO)12(η5-C5H5)] and [(µ2-H)3Os3W(CO)11(η5-C5H5)] Journal of the Chemical Society, Chemical Communications. 534-535. DOI: 10.1039/C39780000534  0.456
1978 Pierpont CG, Stuntz GF, Shapley JR. Preparation and crystal structure of Ir7(CO)12(C8H12)(C8H 11)(C8H10), a heptanuclear iridium cluster showing three stages of cyclooctadiene coordination and dehydrogenation [1] Journal of the American Chemical Society. 100: 616-618. DOI: 10.1021/Ja00470A041  0.412
1978 Stuntz GF, Shapley JR, Pierpont CG. Preparation and characterization of organoiridium cluster compounds from the reaction of dodecacarbonyltetrairidium with 1,5-cyclooctadiene. Crystal structure of Ir4(CO)5(C8H12)2(C 8H10) Inorganic Chemistry. 17: 2596-2603. DOI: 10.1021/Ic50187A047  0.437
1978 Lawson RJ, Shapley JR. Carbonyl ligand mobility in the Cs isomer of tris(.eta.5-cyclopentadienyl)tricarbonyltrirhodium Inorganic Chemistry. 17: 772-774. DOI: 10.1021/Ic50181A064  0.317
1978 Shapley JR, Tachikawa M, Churchill MR, Lashewycz RA. Triosmium-induced dehydrogenation of triethylamine. The crystal structure of HOs3 (CO)10 (-CHCH+NEt2) Journal of Organometallic Chemistry. 162: C39-C42. DOI: 10.1016/S0022-328X(00)81410-2  0.328
1977 Churchill MR, Lashewycz RA, Tachikawa M, Shapley JR. Synthesis and crystal structure of [(µ2-H)Os3(CO)8{C(O–)C(CHMe–)CHCHCEt}]: a cluster compound containing a µ3-trisubstituted-η5-cyclopentadienyl system Journal of the Chemical Society, Chemical Communications. 699-700. DOI: 10.1039/C39770000699  0.393
1977 Calvert RB, Shapley JR. Activation of hydrocarbons by unsaturated metal cluster complexes. 6. Synthesis and characterization of methyldecacarbonylhydridotriosmium, methylenedecacarbonyldihydridotriosmium, and methylidynenonacarbonyltrihydridotriosmium. Interconversion of cluster-bound methyl and methylene ligands Journal of the American Chemical Society. 99: 5225-5226. DOI: 10.1021/Ja00457A077  0.33
1977 Tachikawa M, Shapley JR. Two lightly stabilized decacarbonyltriosmium complexes Journal of Organometallic Chemistry. 124: C19-C22. DOI: 10.1016/S0022-328X(00)90975-6  0.326
1977 Tachikawa M, Richter S, Shapley J. Observation of in-plane carbonyl scrambling in a derivative of dodecacarbonyltriosmium. Journal of Organometallic Chemistry. 128: C9-C14. DOI: 10.1016/S0022-328X(00)90136-0  0.321
1976 Lawson RJ, Shapley JR. Intracluster ligand mobility. 3. Tri-.mu.2-carbonyl-tris(.eta.5-cyclopentadienyl)-triangulo-trirhodium. A new, improved preparation and some observations on its dynamic properties Journal of the American Chemical Society. 98: 7433-7435. DOI: 10.1021/Ja00439A060  0.308
1976 Tachikawa M, Shapley JR, Haltiwanger RC, Pierpont CG. Activation of hydrocarbons by unsaturated metal cluster complexes. 4. Decacarbonyltriosmium complexes of some conjugated dienes. The crystal structures of Os3(CO)10(s-cis-C4H6) and Os3(CO)10(s-trans-C4H6) Journal of the American Chemical Society. 98: 4651-4652. DOI: 10.1021/Ja00431A055  0.414
1976 Stuntz GF, Shapley JR. Direct synthesis of mono- and disubstituted phosphorus ligand derivatives of dodecacarbonyltetrairidium Inorganic Chemistry. 15: 1994-1996. DOI: 10.1021/Ic50162A056  0.309
1976 TACHIKAWA M, SHAPLEY JR, HALTIWANGER RC, PIERPONT CG. ChemInform Abstract: ACTIVATION OF HYDROCARBONS BY UNSATURATED METAL CLUSTER COMPLEXES. 4. DECACARBONYLTRIOSMIUM COMPLEXES OF SOME CONJUGATED DIENES. THE CRYSTAL STRUCTURES OF OS3(CO)10(S-CIS-C4H6) AND OS3(CO)10(S-TRANS-C4H6) Chemischer Informationsdienst. 7: no-no. DOI: 10.1002/chin.197642353  0.302
1975 Keister JB, Shapley JR. Reaction of ethylene with the unsaturated cluster complex H2Os3 (CO)10 Journal of Organometallic Chemistry. 85: C29-C31. DOI: 10.1016/S0022-328X(00)80710-X  0.345
1973 Fraser AR, Bird PH, Bezman SA, Shapley JR, White R, Osborn JA. Metal-catalyzed [2 + 2] cycloaddition reactions. A metallocyclic intermediate [11] Journal of the American Chemical Society. 95: 597-598. DOI: 10.1021/Ja00783A054  0.444
1973 Shapley JR, Osborn JA. Rapid intramolecular rearrangements in pentacoordinate transition metal compounds Accounts of Chemical Research. 6: 305-312. DOI: 10.1021/Ar50069A004  0.505
1973 SHAPLEY JR, OSBORN JA. ChemInform Abstract: RAPID INTRAMOLECULAR REARRANGEMENTS IN PENTACOORDINATE TRANSITION METAL COMPOUNDS Chemischer Informationsdienst. 4: no-no. DOI: 10.1002/chin.197352393  0.451
1971 SHAPLEY JR, OSBORN JA. ChemInform Abstract: SCHNELLE INTRAMOLEKULARE UMLAGERUNGEN IN FUENFFACH-KOORDINIERTEN UEBERGANGSMETALL-VERBINDUNGEN, UMLAGERUNGSMECHANISMUS EINIGER IR(I)-KOMPLEXE MIT FLUKTUIERENDEN BINDUNGEN Chemischer Informationsdienst. Organische Chemie. 2: no-no. DOI: 10.1002/Chin.197105070  0.515
1970 Shapley JR, Osborn JA. Rapid intramolecular rearrangements in pentacoordinate transition metal compounds. On the rearrangement mechanism of some fluxional iridium(I) complexes [9] Journal of the American Chemical Society. 92: 6976-6978. DOI: 10.1021/Ja00726A047  0.53
1969 Shapley JR, Schreck RR, Osborn JA. Preparation and catalytic properties of some cationic iridium(III) and rhodium(III) dihydrido complexes [27] Journal of the American Chemical Society. 91: 2816-2817. DOI: 10.1021/Ja01038A088  0.483
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