☰

Mark R. Biscoe, Ph.D. - Publications

Affiliations: 
2009- Chemistry City College of New York, New York, NY, United States 
Area:
Organic, organometallics
Website:
http://www.sci.ccny.cuny.edu/~mbiscoe/index.html
Tree Info Similar researchers PubMed Report error

31 high-probability publications. We are testing a new system for linking publications to authors. You can help! If you notice any inaccuracies, please sign in and mark papers as correct or incorrect matches. If you identify any major omissions or other inaccuracies in the publication list, please let us know.

Year Citation  Score
2023 Binayeva M, Ma X, Ghaemimohammadi P, Biscoe MR. A general approach to stereospecific Pd-catalyzed cross-coupling reactions of benzylic stereocenters. Chemical Science. 14: 14124-14130. PMID 38098708 DOI: 10.1039/d3sc04519f  0.585
2022 Zhao H, Jose AT, Asany A, Khan SM, Biscoe MR. Pd-Catalyzed Arylation of Secondary α-Alkoxytricyclohexylstannanes. Organic Letters. PMID 36399722 DOI: 10.1021/acs.orglett.2c03729  0.739
2021 Murray B, Zhao S, Aramini JM, Wang H, Biscoe MR. The Stereochemical Course of Pd-Catalyzed Suzuki Reactions Using Primary Alkyltrifluoroborate Nucleophiles. Acs Catalysis. 11: 2504-2510. PMID 34667656 DOI: 10.1021/acscatal.0c04325  0.486
2021 Murray B, Zhao S, Aramini JM, Wang H, Biscoe MR. The Stereochemical Course of Pd-Catalyzed Suzuki Reactions Using Primary Alkyltrifluoroborate Nucleophiles Acs Catalysis. 11: 2504-2510. DOI: 10.1021/ACSCATAL.0C04325  0.498
2020 Ma X, Murray B, Biscoe MR. Stereoselectivity in Pd-catalysed cross-coupling reactions of enantioenriched nucleophiles. Nature Reviews. Chemistry. 4: 584-599. PMID 33869786 DOI: 10.1038/s41570-020-00222-9  0.521
2020 Ma X, Zhao H, Binayeva M, Ralph G, Diane M, Zhao S, Wang CY, Biscoe MR. A General Approach to Stereospecific Cross-Coupling Reactions of Nitrogen-Containing Stereocenters. Chem. 6: 781-791. PMID 32440572 DOI: 10.1016/J.Chempr.2020.02.002  0.593
2019 Ralph G, Biscoe MR. Preparation of Enantioenriched Alkylcarbastannatranes via Nucleophilic Inversion of Alkyl Mesylates for Use in Stereospecific Cross-Coupling Reactions. Organometallics. 38: 3912-3915. PMID 33824546 DOI: 10.1021/Acs.Organomet.9B00467  0.515
2018 Zhao S, Gensch T, Murray B, Niemeyer ZL, Sigman MS, Biscoe MR. Enantiodivergent Pd-catalyzed C-C bond formation enabled through ligand parameterization. Science (New York, N.Y.). PMID 30237245 DOI: 10.1126/Science.Aat2299  0.617
2017 Ma X, Diane M, Ralph G, Chen C, Biscoe MR. Stereospecific Electrophilic Fluorination of Alkylcarbastannatrane Reagents. Angewandte Chemie (International Ed. in English). PMID 28833888 DOI: 10.1002/Anie.201704672  0.466
2016 Wang CY, Ralph G, Derosa J, Biscoe MR. Stereospecific Palladium-Catalyzed Acylation of Enantioenriched Alkylcarbastannatranes: A General Alternative to Asymmetric Enolate Reactions. Angewandte Chemie (International Ed. in English). PMID 27981696 DOI: 10.1002/Anie.201609930  0.726
2015 Wang CY, Derosaa J, Biscoe MR. Configurationally Stable, Enantioenriched Organometallic Nucleophiles in Stereospecific Pd-Catalyzed Cross-Coupling Reactions: An Alternative Approach to Asymmetric Synthesis. Chemical Science (Royal Society of Chemistry : 2010). 6: 5105-5113. PMID 26388985 DOI: 10.1039/C5Sc01710F  0.604
2015 Wang CY, Derosa J, Biscoe MR. Configurationally stable, enantioenriched organometallic nucleophiles in stereospecific Pd-catalyzed cross-coupling reactions: an alternative approach to asymmetric synthesis Chemical Science. 6: 5105-5113. DOI: 10.1039/c5sc01710f  0.728
2014 Li L, Zhao S, Joshi-Pangu A, Diane M, Biscoe MR. Stereospecific pd-catalyzed cross-coupling reactions of secondary alkylboron nucleophiles and aryl chlorides. Journal of the American Chemical Society. 136: 14027-30. PMID 25226092 DOI: 10.1021/Ja508815W  0.605
2013 Li L, Wang CY, Huang R, Biscoe MR. Stereoretentive Pd-catalysed Stille cross-coupling reactions of secondary alkyl azastannatranes and aryl halides. Nature Chemistry. 5: 607-12. PMID 23787752 DOI: 10.1038/Nchem.1652  0.602
2012 Joshi-Pangu A, Biscoe MR. The Use of Tertiary Alkylmagnesium Nucleophiles in Ni-Catalyzed Cross-Coupling Reactions. Synlett : Accounts and Rapid Communications in Synthetic Organic Chemistry. 23: 1103-1107. PMID 23641126 DOI: 10.1055/S-0031-1290765  0.552
2012 Joshi-Pangu A, Ma X, Diane M, Iqbal S, Kribs RJ, Huang R, Wang CY, Biscoe MR. Palladium-catalyzed borylation of primary alkyl bromides. The Journal of Organic Chemistry. 77: 6629-33. PMID 22774861 DOI: 10.1021/Jo301156E  0.601
2011 Joshi-Pangu A, Wang CY, Biscoe MR. Nickel-catalyzed Kumada cross-coupling reactions of tertiary alkylmagnesium halides and aryl bromides/triflates. Journal of the American Chemical Society. 133: 8478-81. PMID 21553878 DOI: 10.1021/Ja202769T  0.542
2011 Joshi-Pangu A, Ganesh M, Biscoe MR. Nickel-catalyzed Negishi cross-coupling reactions of secondary alkylzinc halides and aryl iodides. Organic Letters. 13: 1218-21. PMID 21309529 DOI: 10.1021/Ol200098D  0.582
2011 Joshi-Pangu A, Ganesh M, Biscoe MR. Ni-Catalyzed Negishi Cross-Coupling of Secondary AlkylzincHalides Synfacts. 2011: 662-662. DOI: 10.1055/S-0030-1259901  0.385
2009 Lee BK, Biscoe MR, Buchwald SL. Simple, Efficient Protocols for the Pd-Catalyzed Cross-Coupling Reaction of Aryl Chlorides and Dimethylamine. Tetrahedron Letters. 50: 3672-3674. PMID 21818164 DOI: 10.1016/J.Tetlet.2009.03.137  0.678
2009 Biscoe MR, Buchwald SL. Selective monoarylation of acetate esters and aryl methyl ketones using aryl chlorides. Organic Letters. 11: 1773-5. PMID 19296693 DOI: 10.1021/Ol900295U  0.606
2008 Fors BP, Watson DA, Biscoe MR, Buchwald SL. A highly active catalyst for Pd-catalyzed amination reactions: cross-coupling reactions using aryl mesylates and the highly selective monoarylation of primary amines using aryl chlorides. Journal of the American Chemical Society. 130: 13552-4. PMID 18798626 DOI: 10.1021/Ja8055358  0.776
2008 Biscoe MR, Fors BP, Buchwald SL. A new class of easily activated palladium precatalysts for facile C-N cross-coupling reactions and the low temperature oxidative addition of aryl chlorides. Journal of the American Chemical Society. 130: 6686-7. PMID 18447360 DOI: 10.1021/Ja801137K  0.753
2007 Ikawa T, Barder TE, Biscoe MR, Buchwald SL. Pd-catalyzed amidation of aryl chlorides using monodentate biaryl phosphine ligands: a kinetic, computational, and synthetic investigation. Journal of the American Chemical Society. 129: 13001-7. PMID 17918833 DOI: 10.1021/Ja0717414  0.768
2007 Biscoe MR, Barder TE, Buchwald SL. Electronic effects on the selectivity of pd-catalyzed C-N bond-forming reactions using biarylphosphine ligands: the competitive roles of amine binding and acidity. Angewandte Chemie (International Ed. in English). 46: 7232-5. PMID 17680583 DOI: 10.1002/Anie.200702122  0.749
2007 Barder TE, Biscoe MR, Buchwald SL. Structural insights into active catalyst structures and oxidative addition to (biaryl)phosphine - palladium complexes via density functional theory and experimental studies Organometallics. 26: 2183-2192. DOI: 10.1021/Om0701017  0.731
2006 Uyeda C, Biscoe M, LePlae P, Breslow R. Hydrophobically directed selective reduction of ketones using amine boranes Tetrahedron Letters. 47: 127-130. DOI: 10.1016/J.Tetlet.2005.10.117  0.606
2005 Biscoe MR, Breslow R. Oxaziridinium salts as hydrophobic epoxidation reagents: remarkable hydrophobically-directed selectivity in olefin epoxidation. Journal of the American Chemical Society. 127: 10812-3. PMID 16076170 DOI: 10.1021/Ja053660I  0.543
2004 Biscoe MR, Uyeda C, Breslow R. Requirements for selective hydrophobic acceleration in the reduction of ketones. Organic Letters. 6: 4331-4. PMID 15524476 DOI: 10.1021/Ol0481481  0.521
2003 Biscoe MR, Breslow R. Hydrophobically directed selective reduction of ketones. Journal of the American Chemical Society. 125: 12718-9. PMID 14558814 DOI: 10.1021/Ja0379924  0.592
2001 Biscoe MR, Fry AJ. Dual reaction pathways in the magnesium-mediated synthesis of aziridines from benzal halides and imines Tetrahedron Letters. 42: 2759-2762. DOI: 10.1016/S0040-4039(01)00271-4  0.628
Show low-probability matches.