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T. Brent Gunnoe, Ph.D. - Publications

Affiliations: 
1999-2009 North Carolina State University, Raleigh, NC 
 2009- Chemistry University of Virginia, Charlottesville, VA 
Area:
Synthetic and Mechanistic Organometallic Chemistry
Website:
http://chem.virginia.edu/faculty-research/faculty/t-brent-gunnoe/

152 high-probability publications. We are testing a new system for linking publications to authors. You can help! If you notice any inaccuracies, please sign in and mark papers as correct or incorrect matches. If you identify any major omissions or other inaccuracies in the publication list, please let us know.

Year Citation  Score
2023 Álvarez-Rodríguez L, Ríos P, Laglera-Gándara CJ, Jurado A, Fernández-de-Córdova FJ, Gunnoe TB, Rodriguez A. Cleavage of Carbon Dioxide C=O Bond Promoted by Nickel Boron Cooperativity in a PBP-Ni Complex. Angewandte Chemie (International Ed. in English). e202306315. PMID 37399341 DOI: 10.1002/anie.202306315  0.305
2022 Kong F, Ríos P, Hauck C, Fernández-de-Córdova FJ, Dickie DA, Habgood LG, Rodríguez A, Gunnoe TB. Ethylene Dimerization and Oligomerization Using Bis(phosphino)boryl Supported Ni Complexes. Journal of the American Chemical Society. 145: 179-193. PMID 36542802 DOI: 10.1021/jacs.2c09471  0.315
2021 Zhu W, Gunnoe TB. Advances in Group 10 Transition-Metal-Catalyzed Arene Alkylation and Alkenylation. Journal of the American Chemical Society. 143: 6746-6766. PMID 33908253 DOI: 10.1021/jacs.1c01810  0.346
2020 Jia X, Frye LI, Zhu W, Gu S, Gunnoe TB. Synthesis of Stilbenes by Rhodium-Catalyzed Aerobic Alkenylation of Arenes via C-H Activation. Journal of the American Chemical Society. PMID 32453558 DOI: 10.1021/Jacs.0C03935  0.427
2020 Zhu W, Gunnoe TB. Advances in Rhodium-Catalyzed Oxidative Arene Alkenylation. Accounts of Chemical Research. PMID 32239913 DOI: 10.1021/Acs.Accounts.0C00036  0.485
2020 Gu S, Nielsen RJ, Taylor KH, Fortman GC, Chen J, Dickie DA, Goddard WA, Gunnoe TB. Use of Ligand Steric Properties to Control the Thermodynamics and Kinetics of Oxidative Addition and Reductive Elimination with Pincer-Ligated Rh Complexes Organometallics. 39: 1917-1933. DOI: 10.1021/Acs.Organomet.0C00122  0.403
2019 Zhu W, Luo Z, Chen J, Liu C, Yang L, Dickie DA, Liu N, Zhang S, Davis RJ, Gunnoe TB. Mechanistic Studies of Single-Step Styrene Production Catalyzed by Rh Complexes with Diimine Ligands: An Evaluation of the Role of Ligands and Induction Period Acs Catalysis. 9: 7457-7475. DOI: 10.1021/Acscatal.9B01480  0.492
2019 Brezicki G, Kammert JD, Gunnoe TB, Paolucci C, Davis RJ. Insights into the Speciation of Cu in the Cu-H-Mordenite Catalyst for the Oxidation of Methane to Methanol Acs Catalysis. 9: 5308-5319. DOI: 10.1021/Acscatal.9B00852  0.369
2019 Liebov NS, Zhu W, Chen J, Webster-Gardiner MS, Schinski WL, Gunnoe TB. Rhodium-Catalyzed Alkenylation of Toluene Using 1-Pentene: Regioselectivity To Generate Precursors for Bicyclic Compounds Organometallics. 38: 3860-3870. DOI: 10.1021/Acs.Organomet.9B00535  0.391
2019 Jia X, Foley AM, Liu C, Vaughan BA, McKeown BA, Zhang S, Gunnoe TB. Styrene Production from Benzene and Ethylene Catalyzed by Palladium(II): Enhancement of Selectivity toward Styrene via Temperature-dependent Vinyl Ester Consumption Organometallics. 38: 3532-3541. DOI: 10.1021/Acs.Organomet.9B00349  0.364
2019 Fu R, Nielsen RJ, Liebov NS, Goddard WA, Gunnoe TB, Groves JT. DFT Mechanistic Study of Methane Mono-Esterification by Hypervalent Iodine Alkane Oxidation Process The Journal of Physical Chemistry C. 123: 15674-15684. DOI: 10.1021/Acs.Jpcc.9B04239  0.35
2018 Chen J, Nielsen RJ, Goddard WA, McKeown BA, Dickie DA, Gunnoe TB. Catalytic Synthesis of Superlinear Alkenyl Arenes Using a Rh(I) Catalyst Supported by a "Capping Arene" Ligand: Access to Aerobic Catalysis. Journal of the American Chemical Society. PMID 30495938 DOI: 10.1021/Jacs.8B07728  0.463
2018 Hoffman ZB, Gray TS, Xu Y, Lin Q, Gunnoe TB, Zangari G. High Selectivity Towards Formate Production by Electrochemical Reduction of Carbon Dioxide at Copper-Bismuth Dendrites. Chemsuschem. PMID 30412343 DOI: 10.1002/Cssc.201801708  0.327
2018 Schwartz NA, Boaz NC, Kalman SE, Zhuang T, Goldberg JM, Fu R, Nielsen RJ, Goddard WA, Groves JT, Gunnoe TB. Mechanism of Hydrocarbon Functionalization by an Iodate/Chloride System: The Role of Ester Protection Acs Catalysis. 8: 3138-3149. DOI: 10.1021/Acscatal.7B04397  0.335
2017 Webster-Gardiner MS, Chen J, Vaughan BA, McKeown BA, Schinski W, Gunnoe TB. Catalytic Synthesis of "Super" Linear Alkenyl Arenes Using an Easily Prepared Rh(I) Catalyst. Journal of the American Chemical Society. PMID 28383890 DOI: 10.1021/Jacs.7B01165  0.413
2017 Chen J, Goforth SK, McKeown BA, Gunnoe TB. Brønsted acid-catalysed intramolecular hydroamination of unactivated alkenes: metal triflates as an in situ source of triflic acid. Dalton Transactions (Cambridge, England : 2003). PMID 28194456 DOI: 10.1039/C6Dt04710F  0.802
2017 Vaughan BA, Khani SK, Gary JB, Kammert JD, Webster-Gardiner MS, McKeown BA, Davis RJ, Cundari TR, Gunnoe TB. Mechanistic Studies of Single-Step Styrene Production Using a Rhodium(I) Catalyst. Journal of the American Chemical Society. PMID 28106388 DOI: 10.1021/Jacs.6B10658  0.584
2017 Munz D, Webster-Gardiner M, Fu R, Strassner T, Goddard WA, Gunnoe TB. Correction to Proton or Metal? The H/D Exchange of Arenes in Acidic Solvents Acs Catalysis. 7: 6990-6990. DOI: 10.1021/Acscatal.7B02947  0.686
2017 Joslin EE, McKeown BA, Cundari TR, Gunnoe TB. Studies of the decomposition of the ethylene hydrophenylation catalyst TpRu(CO)(NCMe)Ph Journal of Organometallic Chemistry. 847: 289-293. DOI: 10.1016/J.Jorganchem.2017.03.051  0.59
2017 Jia X, Gary JB, Gu S, Cundari TR, Gunnoe TB. Oxidative Hydrophenylation of Ethylene Using a Cationic Ru(II) Catalyst: Styrene Production with Ethylene as the Oxidant Israel Journal of Chemistry. 57: 1037-1046. DOI: 10.1002/Ijch.201700099  0.604
2016 Munz D, Wang D, Moyer MM, Webster-Gardiner MS, Kunal P, Watts D, Trewyn BG, Vedernikov AN, Gunnoe TB. Aerobic Epoxidation of Olefin by Platinum Catalysts Supported on Mesoporous Silica Nanoparticles Acs Catalysis. 6: 4584-4593. DOI: 10.1021/Acscatal.6B01532  0.602
2016 O’Reilly ME, Johnson SI, Nielsen RJ, Goddard WA, Gunnoe TB. Transition-Metal-Mediated Nucleophilic Aromatic Substitution with Acids Organometallics. 35: 2053-2056. DOI: 10.1021/Acs.Organomet.6B00285  0.38
2016 Taylor KH, Kalman SE, Gunnoe TB, Sabat M. Combined Furan C–H Activation and Furyl Ring-Opening by an Iron(II) Complex Organometallics. 35: 1978-1985. DOI: 10.1021/Acs.Organomet.6B00276  0.326
2016 Webster-Gardiner MS, Piszel PE, Fu R, McKeown BA, Nielsen RJ, Goddard WA, Gunnoe TB. Electrophilic RhI catalysts for arene H/D exchange in acidic media: Evidence for an electrophilic aromatic substitution mechanism Journal of Molecular Catalysis a: Chemical. DOI: 10.1016/J.Molcata.2016.07.045  0.452
2016 McKeown BA, Lee JP, Mei J, Cundari TR, Gunnoe TB. Transition Metal Mediated C-H Activation and Functionalization: The Role of Poly(pyrazolyl)borate and Poly(pyrazolyl)alkane Ligands European Journal of Inorganic Chemistry. 2016: 2296-2311. DOI: 10.1002/Ejic.201501470  0.666
2015 Joglekar M, Nguyen V, Pylypenko S, Ngo C, Li Q, O'Reilly ME, Gray TS, Hubbard WA, Gunnoe TB, Herring AM, Trewyn BG. Organometallic Complexes Anchored to Conductive Carbon for Electrocatalytic Oxidation of Methane at Low Temperature. Journal of the American Chemical Society. PMID 26492385 DOI: 10.1021/Jacs.5B06392  0.738
2015 Vaughan BA, Webster-Gardiner MS, Cundari TR, Gunnoe TB. Organic chemistry. A rhodium catalyst for single-step styrene production from benzene and ethylene. Science (New York, N.Y.). 348: 421-4. PMID 25908817 DOI: 10.1126/Science.Aaa2260  0.564
2015 Kalman SE, Munz D, Fortman GC, Boaz NC, Groves JT, Gunnoe TB. Partial oxidation of light alkanes by periodate and chloride salts. Dalton Transactions (Cambridge, England : 2003). 44: 5294-8. PMID 25708552 DOI: 10.1039/C5Dt00558B  0.539
2015 Fu R, O'Reilly ME, Nielsen RJ, Goddard WA, Gunnoe TB. Rhodium bis(quinolinyl)benzene complexes for methane activation and functionalization. Chemistry (Weinheim An Der Bergstrasse, Germany). 21: 1286-93. PMID 25418788 DOI: 10.1002/Chem.201405460  0.756
2015 Webster-Gardiner MS, Fu R, Fortman GC, Nielsen RJ, Gunnoe TB, Goddard WA. Arene C-H activation using Rh(I) catalysts supported by bidentate nitrogen chelates Catalysis Science and Technology. 5: 96-100. DOI: 10.1039/C4Cy00972J  0.429
2015 Munz D, Webster-Gardiner M, Fu R, Strassner T, Goddard WA, Gunnoe TB. Proton or metal? The H/D exchange of arenes in acidic solvents Acs Catalysis. 5: 769-775. DOI: 10.1021/Cs501620F  0.719
2015 Chirik PJ, Gunnoe TB. A Meeting of Metals - A Joint Virtual Issue between Organometallics and ACS Catalysis on First-Row Transition Metal Complexes Acs Catalysis. 5: 5584-5585. DOI: 10.1021/Acscatal.5B01831  0.321
2015 Brosnahan AM, Talbot A, McKeown BA, Kalman SE, Gunnoe TB, Ess DH, Sabat M. Phosphine and N-heterocyclic carbene ligands on Pt(II) shift selectivity from ethylene hydrophenylation toward benzene vinylation Journal of Organometallic Chemistry. DOI: 10.1016/J.Jorganchem.2015.03.019  0.494
2015 Burgess SA, Bolaño T, Gunnoe TB, Sabat M, Myers WH. Synthesis of RhIII anilido, hydroxide, and methoxide complexes European Journal of Inorganic Chemistry. 2015: 1041-1052. DOI: 10.1002/Ejic.201403147  0.419
2015 Vaughan BA, Webster-Gardiner MS, Cundari TR, Gunnoe TB. ChemInform Abstract: A Rhodium Catalyst for Single-Step Styrene Production from Benzene and Ethylene. Cheminform. 46: no-no. DOI: 10.1002/chin.201539054  0.433
2014 Jeffers LA, Shen H, Bissinger BW, Khalil S, Gunnoe TB, Roe RM. Polymers for the stabilization and delivery of proteins topically and per os to the insect hemocoel through conjugation with aliphatic polyethylene glycol. Pesticide Biochemistry and Physiology. 115: 58-66. PMID 25307467 DOI: 10.1016/J.Pestbp.2014.08.006  0.414
2014 O'Reilly ME, Fu R, Nielsen RJ, Sabat M, Goddard WA, Gunnoe TB. Long-range C-H bond activation by Rh(III)-carboxylates. Journal of the American Chemical Society. 136: 14690-3. PMID 25303016 DOI: 10.1021/Ja508367M  0.764
2014 Konnick MM, Hashiguchi BG, Devarajan D, Boaz NC, Gunnoe TB, Groves JT, Gunsalus N, Ess DH, Periana RA. Selective CH functionalization of methane, ethane, and propane by a perfluoroarene iodine(III) complex. Angewandte Chemie (International Ed. in English). 53: 10490-4. PMID 25131994 DOI: 10.1002/Anie.201406185  0.558
2014 Joslin EE, Quillian B, Gunnoe TB, Cundari TR, Sabat M, Myers WH. C-H activation of pyrazolyl ligands by Ru(II). Inorganic Chemistry. 53: 6270-9. PMID 24866703 DOI: 10.1021/Ic500811N  0.821
2014 Fortman GC, Boaz NC, Munz D, Konnick MM, Periana RA, Groves JT, Gunnoe TB. Selective monooxidation of light alkanes using chloride and iodate. Journal of the American Chemical Society. 136: 8393-401. PMID 24866148 DOI: 10.1021/Ja502657G  0.661
2014 Burgess SA, Devarajan D, Bolaño T, Ess DH, Gunnoe TB, Sabat M, Myers WH. 1,2-Addition of dihydrogen across rhodium(III)-OMe bonds. Inorganic Chemistry. 53: 5328-40. PMID 24806731 DOI: 10.1021/Ic500636M  0.439
2014 O'Reilly ME, Pahls DR, Webb JR, Boaz NC, Majumdar S, Hoff CD, Groves JT, Cundari TR, Gunnoe TB. Reductive functionalization of a rhodium(III)-methyl bond by electronic modification of the supporting ligand. Dalton Transactions (Cambridge, England : 2003). 43: 8273-81. PMID 24715057 DOI: 10.1039/C4Dt00234B  0.839
2014 Prince BM, Gunnoe TB, Cundari TR. Oxy-functionalization of Group 9 and 10 transition metal methyl ligands: use of pyridine-based hemi-labile ligands. Dalton Transactions (Cambridge, England : 2003). 43: 7608-14. PMID 24699887 DOI: 10.1039/C4Dt00371C  0.623
2014 Pardue DB, Mei J, Cundari TR, Gunnoe TB. Density functional theory study of oxygen-atom insertion into metal-methyl bonds of iron(II), ruthenium(II), and osmium(II) complexes: study of metal-mediated C-O bond formation. Inorganic Chemistry. 53: 2968-75. PMID 24571202 DOI: 10.1021/Ic402759W  0.606
2014 Burgess SA, Joslin EE, Gunnoe TB, Cundari TR, Sabat M, Myers WH. Hydrophenylation of ethylene using a cationic Ru(ii) catalyst: Comparison to a neutral Ru(ii) catalyst Chemical Science. 5: 4355-4366. DOI: 10.1039/C4Sc01665C  0.602
2014 Campos J, Goforth SK, Crabtree RH, Gunnoe TB. Metal-free amidation of ether sp3 C-H bonds with sulfonamides using PhI(OAc)2 Rsc Advances. 4: 47951-47957. DOI: 10.1039/C4Ra09665G  0.809
2014 Mei J, Pardue DB, Kalman SE, Gunnoe TB, Cundari TR, Sabat M. Oxygen atom insertion into iron(II) phenyl and methyl bonds: A key step for catalytic hydrocarbon functionalization Organometallics. 33: 5597-5605. DOI: 10.1021/Om500914H  0.541
2014 O'Reilly ME, Pahls DR, Cundari TR, Gunnoe TB. Reductive functionalization of a rhodium(III)-methyl bond in acidic media: Key step in the electrophilic functionalization of methane Organometallics. 33: 6504-6510. DOI: 10.1021/Om5008456  0.789
2014 Kalman SE, Gunnoe TB, Sabat M. Formation of hydroxyindenyl and vinylidene ligands by reaction of internal alkynes with Cp∗Fe(CO)(NCMe)Ph Organometallics. 33: 5457-5463. DOI: 10.1021/Om500748V  0.443
2014 Pahls DR, Groves JT, Gunnoe TB, Cundari TR. Theoretical study of reductive functionalization of methyl ligands of group 9 complexes supported by two bipyridyl ligands: A key step in catalytic hydrocarbon functionalization Organometallics. 33: 1936-1944. DOI: 10.1021/Om4010093  0.632
2014 Fu R, Nielsen RJ, Goddard WA, Fortman GC, Gunnoe TB. DFT virtual screening identifies rhodium-amidinate complexes as potential homogeneous catalysts for methane-to-methanol oxidation Acs Catalysis. 4: 4455-4465. DOI: 10.1021/Cs5005322  0.435
2014 McKeown BA, Prince BM, Ramiro Z, Gunnoe TB, Cundari TR. PtII-catalyzed hydrophenylation of α-olefins: Variation of linear/branched products as a function of ligand donor ability Acs Catalysis. 4: 1607-1615. DOI: 10.1021/Cs400988W  0.62
2014 Webb JR, Burgess SA, Cundari TR, Gunnoe TB. ChemInform Abstract: Activation of Carbon-Hydrogen Bonds and Dihydrogen by 1,2-CH-Addition Across Metal-Heteroatom Bonds Cheminform. 45: no-no. DOI: 10.1002/chin.201407264  0.654
2013 Webb JR, Burgess SA, Cundari TR, Gunnoe TB. Activation of carbon-hydrogen bonds and dihydrogen by 1,2-CH-addition across metal-heteroatom bonds. Dalton Transactions (Cambridge, England : 2003). 42: 16646-65. PMID 24064606 DOI: 10.1039/C3Dt52164H  0.72
2013 Quillian B, Joslin EE, Gunnoe TB, Sabat M, Myers WH. 2,2,2-Tris(pyrazolyl)ethoxide (Ep(OX)) ruthenium(II) complexes, (Ep(OX))RuCl(L)(L'): synthesis, structure, and reactivity. Inorganic Chemistry. 52: 1113-21. PMID 23270304 DOI: 10.1021/Ic3024474  0.772
2013 Mei J, Carsch KM, Freitag CR, Gunnoe TB, Cundari TR. Variable pathways for oxygen atom insertion into metal-carbon bonds: the case of Cp*W(O)2(CH2SiMe3). Journal of the American Chemical Society. 135: 424-35. PMID 23259753 DOI: 10.1021/Ja309755G  0.597
2013 Bolaño T, Gunnoe TB, Sabat M. Direct coupling of nitriles and aniline to form the triazapentadiene species [upper bond 1 start]Rh(III){NH=C(R)N(Ph)C(R=N[upper bond 1 end]H}. Dalton Transactions (Cambridge, England : 2003). 42: 347-50. PMID 23154799 DOI: 10.1039/C2Dt32606J  0.438
2013 McKeown BA, Gonzalez HE, Michaelos T, Gunnoe TB, Cundari TR, Crabtree RH, Sabat M. Control of olefin hydroarylation catalysis via a sterically and electronically flexible platinum(II) catalyst scaffold Organometallics. 32: 3903-3913. DOI: 10.1021/Om400390E  0.59
2013 McKeown BA, Gonzalez HE, Friedfeld MR, Brosnahan AM, Gunnoe TB, Cundari TR, Sabat M. Platinum(II)-catalyzed ethylene hydrophenylation: Switching selectivity between alkyl- and vinylbenzene production Organometallics. 32: 2857-2865. DOI: 10.1021/Om400306W  0.597
2013 Kalman SE, Petit A, Gunnoe TB, Ess DH, Cundari TR, Sabat M. Facile and regioselective C-H bond activation of aromatic substrates by an fe(II) complex involving a spin-forbidden pathway Organometallics. 32: 1797-1806. DOI: 10.1021/Om301219T  0.601
2013 McKeown BA, Gonzalez HE, Gunnoe TB, Cundari TR, Sabat M. PtII-catalyzed ethylene hydrophenylation: Influence of dipyridyl chelate ring size on catalyst activity and longevity Acs Catalysis. 3: 1165-1171. DOI: 10.1021/Cs400231F  0.554
2013 Webb JR, Figg TM, Otten BM, Cundari TR, Gunnoe TB, Sabat M. PtII and RhIII hydrocarbyl complexes bearing coordinated oxygen atom delivery reagents European Journal of Inorganic Chemistry. 4515-4525. DOI: 10.1002/Ejic.201300434  0.744
2012 Pouy MJ, Milczek EM, Figg TM, Otten BM, Prince BM, Gunnoe TB, Cundari TR, Groves JT. Flavin-catalyzed insertion of oxygen into rhenium-methyl bonds. Journal of the American Chemical Society. 134: 12920-3. PMID 22827584 DOI: 10.1021/Ja3054139  0.545
2012 Devarajan D, Gunnoe TB, Ess DH. Theory of late-transition-metal alkyl and heteroatom bonding: analysis of Pt, Ru, Ir, and Rh complexes. Inorganic Chemistry. 51: 6710-8. PMID 22663146 DOI: 10.1021/Ic300350K  0.423
2012 Joslin EE, McMullin CL, Gunnoe TB, Cundari TR, Sabat M, Myers WH. Coordination chemistry of 4-methyl-2,6,7-trioxa-1-phosphabicyclo[2,2,1]heptane: preparation and characterization of Ru(II) complexes. Inorganic Chemistry. 51: 4791-801. PMID 22452567 DOI: 10.1021/Ic300109B  0.596
2012 Cheng MJ, Bischof SM, Nielsen RJ, Goddard WA, Gunnoe TB, Periana RA. The para-substituent effect and pH-dependence of the organometallic Baeyer-Villiger oxidation of rhenium-carbon bonds. Dalton Transactions (Cambridge, England : 2003). 41: 3758-63. PMID 22327118 DOI: 10.1039/C2Dt11984F  0.538
2012 Figg TM, Webb JR, Cundari TR, Gunnoe TB. Carbon-oxygen bond formation via organometallic Baeyer-Villiger transformations: a computational study on the impact of metal identity. Journal of the American Chemical Society. 134: 2332-9. PMID 22188276 DOI: 10.1021/Ja2102778  0.708
2012 Jeffers LA, Shen H, Khalil S, Bissinger BW, Brandt A, Gunnoe TB, Roe RM. Enhanced activity of an insecticidal protein, trypsin modulating oostatic factor (TMOF), through conjugation with aliphatic polyethylene glycol. Pest Management Science. 68: 49-59. PMID 21710555 DOI: 10.1002/Ps.2219  0.43
2012 Joslin EE, McMullin CL, Gunnoe TB, Cundari TR, Sabat M, Myers WH. Catalytic hydroarylation of ethylene using TpRu(L)(NCMe)Ph (L = 2,6,7-trioxa-1-phosphabicyclo[2,2,1]heptane): Comparison to TpRu(L′)(NCMe) Ph systems (L′ = CO, PMe 3, P(pyr) 3, or P(OCH 2) 3CEt) Organometallics. 31: 6851-6860. DOI: 10.1021/Om300676E  0.556
2012 Pouy MJ, Delp SA, Uddin J, Ramdeen VM, Cochrane NA, Fortman GC, Gunnoe TB, Cundari TR, Sabat M, Myers WH. Intramolecular hydroalkoxylation and hydroamination of alkynes catalyzed by Cu(I) complexes supported by N-heterocyclic carbene ligands Acs Catalysis. 2: 2182-2193. DOI: 10.1021/Cs300544W  0.817
2011 McKeown BA, Gonzalez HE, Friedfeld MR, Gunnoe TB, Cundari TR, Sabat M. Mechanistic studies of ethylene hydrophenylation catalyzed by bipyridyl Pt(II) complexes. Journal of the American Chemical Society. 133: 19131-52. PMID 22060179 DOI: 10.1021/Ja206064V  0.628
2011 Webb JR, Munro-Leighton C, Pierpont AW, Gurkin JT, Gunnoe TB, Cundari TR, Sabat M, Petersen JL, Boyle PD. Pt(II) and Pt(IV) amido, aryloxide, and hydrocarbyl complexes: synthesis, characterization, and reaction with dihydrogen and substrates that possess C-H bonds. Inorganic Chemistry. 50: 4195-211. PMID 21443233 DOI: 10.1021/Ic200153N  0.801
2011 Webb JR, Bolaño T, Gunnoe TB. Catalytic oxy-functionalization of methane and other hydrocarbons: fundamental advancements and new strategies. Chemsuschem. 4: 37-49. PMID 21226209 DOI: 10.1002/Cssc.201000319  0.638
2011 Figg TM, Cundari TR, Gunnoe TB. Non-redox oxy-insertion via organometallic Baeyer-Villiger transformations: A computational Hammett study of platinum(II) complexes Organometallics. 30: 3779-3785. DOI: 10.1021/Om200258D  0.584
2011 Bischof SM, Cheng MJ, Nielsen RJ, Gunnoe TB, Goddard WA, Periana RA. Functionalization of rhenium aryl bonds by O-atom transfer Organometallics. 30: 2079-2082. DOI: 10.1021/Om2002365  0.512
2011 Harrison DP, Nichols-Nielander AC, Zottig VE, Strausberg L, Salomon RJ, Trindle CO, Sabat M, Gunnoe TB, Iovan DA, Myers WH, Harman WD. Hyperdistorted tungsten allyl complexes and their stereoselective deprotonation to form dihapto-coordinated dienes Organometallics. 30: 2587-2597. DOI: 10.1021/Om200183M  0.829
2011 Delp SA, Goj LA, Pouy MJ, Munro-Leighton C, Lee JP, Gunnoe TB, Cundari TR, Petersen JL. Well-defined copper(I) amido complex and aryl iodides reacting to form aryl amines Organometallics. 30: 55-57. DOI: 10.1021/Om101084E  0.822
2011 Morello GR, Cundari TR, Gunnoe TB. DFT study of group 8 catalysts for the hydrophenylation of ethylene: Influence of ancillary ligands and metal identity Journal of Organometallic Chemistry. 697: 15-22. DOI: 10.1016/J.Jorganchem.2011.09.019  0.592
2011 Andreatta JR, McKeown BA, Gunnoe TB. Transition metal catalyzed hydroarylation of olefins using unactivated substrates: Recent developments and challenges Journal of Organometallic Chemistry. 696: 305-315. DOI: 10.1016/J.Jorganchem.2010.09.030  0.819
2011 Webb JR, Bolaño T, Gunnoe TB. Cover Picture: Catalytic Oxy-Functionalization of Methane and Other Hydrocarbons: Fundamental Advancements and New Strategies (ChemSusChem 1/2011) Chemsuschem. 4: 1-1. DOI: 10.1002/Cssc.201190000  0.537
2010 Webb JR, Pierpont AW, Munro-Leighton C, Gunnoe TB, Cundari TR, Boyle PD. Net hydrogenation of Pt-NHPh bond is catalyzed by elemental Pt. Journal of the American Chemical Society. 132: 4520-1. PMID 20222680 DOI: 10.1021/Ja9102309  0.801
2010 Ess DH, Gunnoe TB, Cundari TR, Goddard WA, Periana RA. Ligand lone-pair influence on hydrocarbon C-H activation: A computational perspective Organometallics. 29: 6801-6815. DOI: 10.1021/Om100974Q  0.715
2010 Gunnoe TB, McKeown BA, Friedfeld MR, Cundari TR, Sabat M. Study of ethylene hydrophenylation catalyzed by cationic Pt(II) complexes Acs National Meeting Book of Abstracts 0.535
2009 Foley NA, Lee JP, Ke Z, Gunnoe TB, Cundari TR. Ru(II) catalysts supported by hydridotris(pyrazolyl)borate for the hydroarylation of olefins: reaction scope, mechanistic studies, and guides for the development of improved catalysts. Accounts of Chemical Research. 42: 585-97. PMID 19296659 DOI: 10.1021/Ar800183J  0.828
2009 Lee JP, Ke Z, Ramírez MA, Gunnoe TB, Cundari TR, Boyle PD, Petersen JL. Six-, Five-, and Four-Coordinate Ruthenium(II) hydride complexes supported by N-Heterocyclic Carbene Ligands: Synthesis, characterization, fundamental reactivity, and catalytic hydrogenation of olefins, Aldehydes, and ketones Organometallics. 28: 1758-1775. DOI: 10.1021/Om801111C  0.722
2009 Foley NA, Abernethy RJ, Gunnoe TB, Hill AF, Boyle PD, Sabat M. Chlorination of boron on a ruthenium-coordinated hydridotris(pyrazolyl) borate (Tp) ligand: A caveat for the use of TpRu(PPh 3) 2Cl Organometallics. 28: 374-377. DOI: 10.1021/Om8008074  0.833
2009 Delp SA, Munro-Leighton C, Khosla C, Templeton JL, Alsop NM, Gunnoe TB, Cundari TR. Combined experimental and computational study of W(II), Ru(II), Pt(IV) and Cu(I) amine and amido complexes using 15N NMR spectroscopy Journal of Organometallic Chemistry. 694: 1549-1556. DOI: 10.1016/J.Jorganchem.2009.01.006  0.824
2009 McKeown BA, Gunnoe TB. Hydroarylation of unactivated olefins catalyzed by Pt(II) complexes Acs National Meeting Book of Abstracts 0.302
2008 Munro-Leighton C, Feng Y, Zhang J, Alsop NM, Gunnoe TB, Boyle PD, Petersen JL. Preparation and reactivity of a monomeric octahedral platinum(IV) amido complex. Inorganic Chemistry. 47: 6124-6. PMID 18572882 DOI: 10.1021/Ic800843B  0.819
2008 Munro-Leighton C, Delp SA, Alsop NM, Blue ED, Gunnoe TB. Anti-Markovnikov hydroamination and hydrothiolation of electron-deficient vinylarenes catalyzed by well-defined monomeric copper(I) amido and thiolate complexes. Chemical Communications (Cambridge, England). 111-3. PMID 18399417 DOI: 10.1039/B715507G  0.817
2008 Foley NA, Gunnoe TB, Cundari TR, Boyle PD, Petersen JL. Activation of sp3 carbon-hydrogen bonds by a ruthenium(II) complex and subsequent metal-mediated C-C and C-N bond formation. Angewandte Chemie (International Ed. in English). 47: 726-30. PMID 18067113 DOI: 10.1002/Anie.200704614  0.821
2008 McKeown BA, Foley NA, Lee JP, Gunnoe TB. Hydroarylation of unactivated olefins catalyzed by platinum(II) complexes Organometallics. 27: 4031-4033. DOI: 10.1021/Om8006008  0.823
2008 Foley NA, Zhuofeng K, Gunnoe TB, Cundari TR, Petersen JL. Aromatic C-H activation and catalytic hydrophenylation of ethylene by TpRu{P(OCH2)3CEt}(NCMe)Ph Organometallics. 27: 3007-3017. DOI: 10.1021/Om800275B  0.818
2008 Lail M, Pittard KA, Gunnoe TB. Chemistry Surrounding Group 7 Complexes that Possess Poly(pyrazolyl)borate Ligands Advances in Organometallic Chemistry. 56: 95-153. DOI: 10.1016/S0065-3055(07)56002-8  0.812
2008 Sumiyoshi T, Gunnoe TB, Petersen JL, Boyle PD. Ruthenium(II) complexes possessing the η6-p-cymene ligand Inorganica Chimica Acta. 361: 3254-3262. DOI: 10.1016/J.Ica.2007.10.012  0.411
2007 Cundari TR, Grimes TV, Gunnoe TB. Activation of carbon-hydrogen bonds via 1,2-addition across M-X (X = OH or NH(2)) bonds of d(6) transition metals as a potential key step in hydrocarbon functionalization: a computational study. Journal of the American Chemical Society. 129: 13172-82. PMID 17918940 DOI: 10.1021/Ja074125G  0.647
2007 Foley NA, Lail M, Lee JP, Gunnoe TB, Cundari TR, Petersen JL. Comparative reactivity of TpRu(L)(NCMe)Ph (L = CO or PMe3): impact of ancillary ligand l on activation of carbon-hydrogen bonds including catalytic hydroarylation and hydrovinylation/oligomerization of ethylene. Journal of the American Chemical Society. 129: 6765-81. PMID 17488072 DOI: 10.1021/Ja068542P  0.812
2007 Delp SA, Munro-Leighton C, Goj LA, Ramírez MA, Gunnoe TB, Petersen JL, Boyle PD. Addition of S-H bonds across electron-deficient olefins catalyzed by well-defined copper(I) thiolate complexes. Inorganic Chemistry. 46: 2365-7. PMID 17338519 DOI: 10.1021/Ic070268S  0.836
2007 DeYonker NJ, Foley NA, Cundari TR, Gunnoe TB, Petersen JL. Combined experimental and computational studies on the nature of aromatic C-H activation by octahedral ruthenium(II) complexes: Evidence for σ-bond metathesis from hammett studies Organometallics. 26: 6604-6611. DOI: 10.1021/Om7009057  0.831
2007 Foley NA, Lail M, Gunnoe TB, Cundari TR, Boyle PD, Petersen JL. Combined experimental and computational study of TpRu{P(pyr) 3}(NCMe)Me (pyr = N-pyrrolyl): Inter- And intramolecular activation of C-H bonds and the impact of sterics on catalytic hydroarylation of olefins Organometallics. 26: 5507-5516. DOI: 10.1021/Om700666Y  0.811
2007 Munro-Leighton C, Delp SA, Blue ED, Gunnoe TB. Addition of N-H and O-H bonds of amines and alcohols to electron-deficient olefins catalyzed by monomeric copper(I) systems: Reaction scope, mechanistic details, and comparison of catalyst efficiency Organometallics. 26: 1483-1493. DOI: 10.1021/Om061133H  0.83
2007 Lee JP, Jimenez-Halla JOC, Cundari TR, Gunnoe TB. Reactivity of TpRu(L)(NCMe)R (L = CO, PMe3; R = Me, Ph) systems with isonitriles: Experimental and computational studies toward the intra- and intermolecular hydroarylation of isonitriles Journal of Organometallic Chemistry. 692: 2175-2186. DOI: 10.1016/J.Jorganchem.2007.01.037  0.658
2007 Gunnoe TB. Reactivity of ruthenium(II) and copper(I) complexes that possess anionic heteroatomic ligands: Synthetic exploitation of nucleophilicity and basicity of amido, hydroxo, alkoxo, and aryloxo ligands for the activation of substrates that possess polar bonds as well as nonpolar C-H and H-H bonds European Journal of Inorganic Chemistry. 1185-1203. DOI: 10.1002/Ejic.200601072  0.556
2006 Goj LA, Blue ED, Delp SA, Gunnoe TB, Cundari TR, Pierpont AW, Petersen JL, Boyle PD. Chemistry surrounding monomeric copper(I) methyl, phenyl, anilido, ethoxide, and phenoxide complexes supported by N-heterocyclic carbene ligands: reactivity consistent with both early and late transition metal systems. Inorganic Chemistry. 45: 9032-45. PMID 17054364 DOI: 10.1021/Ic0611995  0.807
2006 Feng Y, Lail M, Foley NA, Gunnoe TB, Barakat KA, Cundari TR, Petersen JL. Hydrogen-deuterium exchange between TpRu(PMe3)(L)X (L = PMe3 and X = OH, OPh, Me, Ph, or NHPh; L = NCMe and X = Ph) and deuterated arene solvents: evidence for metal-mediated processes. Journal of the American Chemical Society. 128: 7982-94. PMID 16771513 DOI: 10.1021/Ja0615775  0.807
2006 Goj LA, Lail M, Pittard KA, Riley KC, Gunnoe TB, Petersen JL. Reactions of TpRu(CO)(NCMe)(Ph) with electron-rich olefins: examples of stoichiometric C-S, C-O and C-H bond cleavage. Chemical Communications (Cambridge, England). 982-4. PMID 16491183 DOI: 10.1039/B516407A  0.795
2006 Munro-Leighton C, Blue ED, Gunnoe TB. Anti-markovnikov N-H and O-H additions to electron-deficient olefins catalyzed by well-defined Cu(I) anilido, ethoxide, and phenoxide systems. Journal of the American Chemical Society. 128: 1446-7. PMID 16448104 DOI: 10.1021/Ja057622A  0.824
2006 Feng Y, Gunnoe TB, Grimes TV, Cundari TR. Octahedral [TpRu(PMe 3) 2OR] n+ complexes (Tp = hydridotris(pyrazolyl)borate; R = H or Ph; n = 0 or 1): Reactions at Ru(II) and Ru(III) oxidation states with substrates that possess carbon-hydrogen bonds Organometallics. 25: 5456-5465. DOI: 10.1021/Om0606385  0.85
2006 Goj LA, Blue ED, Delp SA, Gunnoe TB, Cundari TR, Petersen JL. Single-electron oxidation of monomeric copper(I) alkyl complexes: Evidence for reductive elimination through bimolecular formation of alkanes Organometallics. 25: 4097-4104. DOI: 10.1021/Om060409I  0.804
2006 Lee JP, Pittard KA, DeYonker NJ, Cundari TR, Gunnoe TB, Petersen JL. Reactions of a Ru(II) phenyl complex with substrates that possess C-N or C-O multiple bonds: C-C bond formation, N-H bond cleavage, and decarbonylation reactions Organometallics. 25: 1500-1510. DOI: 10.1021/Om050967H  0.815
2006 Blue ED, Gunnoe TB, Petersen JL, Boyle PD. Protonation of N-heterocyclic carbene ligand coordinated to copper(I): Coordination mode of imidazolium cation as a function of counterion as determined by solid-state structures Journal of Organometallic Chemistry. 691: 6000-6005. DOI: 10.1016/J.Jorganchem.2006.09.051  0.8
2005 Goj LA, Blue ED, Munro-Leighton C, Gunnoe TB, Petersen JL. Cleavage of X-H bonds (X = N, o, or C) by copper(I) alkyl complexes to form monomeric two-coordinate copper(I) systems. Inorganic Chemistry. 44: 8647-9. PMID 16296815 DOI: 10.1021/Ic0517624  0.824
2005 Zhang J, Barakat KA, Cundari TR, Gunnoe TB, Boyle PD, Petersen JL, Day CS. Synthesis of the five-coordinate ruthenium(II) complexes [(PCP)Ru(CO)(L)][BAr'4] [PCP = 2,6-(CH2P(t)Bu2)2C6H3, BAr'4 = 3,5-(CF3)2C6H3, L = eta1-ClCH2Cl, eta1-N2, or mu-Cl-Ru(PCP)(CO)]: reactions with phenyldiazomethane and phenylacetylene. Inorganic Chemistry. 44: 8379-90. PMID 16270976 DOI: 10.1021/Ic051074K  0.786
2005 Feng Y, Lail M, Barakat KA, Cundari TR, Gunnoe TB, Petersen JL. Evidence for the net addition of arene C-H bonds across a Ru(II)-hydroxide bond. Journal of the American Chemical Society. 127: 14174-5. PMID 16218598 DOI: 10.1021/Ja054101E  0.824
2005 Zhang J, Gunnoe TB, Petersen JL. Reactions of (PCP)Ru(CO)(NHPh)(PMe3) (PCP = 2,6-(CH2PtBu2)2C6H3) with substrates that possess polar bonds. Inorganic Chemistry. 44: 2895-907. PMID 15819577 DOI: 10.1021/Ic0483592  0.72
2005 Pittard KA, Cundari TR, Gunnoe TB, Day CS, Petersen JL. Ruthenium(II)-mediated carbon-carbon bond formation between acetonitrile and pyrrole: Combined experimental and computational study Organometallics. 24: 5015-5024. DOI: 10.1021/Om0506668  0.818
2005 Lail M, Gunnoe TB, Barakat KA, Cundari TR. Conversions of Ruthenium(III) alkyl complexes to Ruthenium(II) through Ru-C alkyl bond homolysis Organometallics. 24: 1301-1305. DOI: 10.1021/Om049145V  0.825
2004 Conner D, Jayaprakash KN, Cundari TR, Gunnoe TB. Synthesis and reactivity of a coordinatively unsaturated ruthenium(II) parent amido complex: Studies of X-H activation (X = H or C) Organometallics. 23: 2724-2733. DOI: 10.1021/Om049836R  0.699
2004 Zhang J, Gunnoe TB, Boyle PD. Ruthenium(II) anilido complex containing a bisphosphine pincer ligand: Reversible formation of amidinate ligands via intramolecular C-N bond formation Organometallics. 23: 3094-3097. DOI: 10.1021/Om0497543  0.771
2004 Pittard KA, Lee JP, Cundari TR, Gunnoe TB, Petersen JL. Reactions of TpRu(CO)(NCMe)(Me) (Tp = Hydridotris(pyrazolyl)borate) with heteroaromatic substrates: Stoichiometric and catalytic C-H activation Organometallics. 23: 5514-5523. DOI: 10.1021/Om049508R  0.832
2004 Lail M, Bell CM, Conner D, Cundari TR, Gunnoe TB, Petersen JL. Experimental and computational studies of ruthenium(II)-catalyzed addition of arene C-H bonds to olefins Organometallics. 23: 5007-5020. DOI: 10.1021/Om049404G  0.819
2003 Blue ED, Davis A, Conner D, Gunnoe TB, Boyle PD, White PS. Synthesis, solid-state crystal structure, and reactivity of a monomeric copper(I) anilido complex. Journal of the American Chemical Society. 125: 9435-41. PMID 12889974 DOI: 10.1021/Ja0353659  0.825
2003 Conner D, Jayaprakash KN, Wells MB, Manzer S, Gunnoe TB, Boyle PD. Octahedral Ru(II) amido complexes TpRu(L)(L')(NHR) (Tp = hydridotris(pyrazolyl)borate; L = L' = P(OMe)3 or PMe3 or L = CO and L' = PPh3; R = H, Ph, or tBu): synthesis, characterization, and reactions with weakly acidic C-H bonds. Inorganic Chemistry. 42: 4759-72. PMID 12870969 DOI: 10.1021/Ic034410A  0.677
2003 Lail M, Arrowood BN, Gunnoe TB. Addition of arenes to ethylene and propene catalyzed by ruthenium. Journal of the American Chemical Society. 125: 7506-7. PMID 12812477 DOI: 10.1021/Ja035076K  0.786
2003 Meiere SH, Keane JM, Gunnoe TB, Sabat M, Harman WD. Binding and activation of aromatic molecules by a molybdenum pi-base. Journal of the American Chemical Society. 125: 2024-5. PMID 12590511 DOI: 10.1021/Ja021057J  0.823
2003 Zhang J, Gunnoe TB. Reactions of ruthenium benzylidene complexes with cyclic and acyclic imines: Oligomerization of 1-pyrroline and metathesis via tautomerism Organometallics. 22: 2291-2297. DOI: 10.1021/Om0301029  0.744
2003 Bergman RG, Cundari TR, Gillespie AM, Gunnoe TB, Harman WD, Klinckman TR, Temple MD, White DP. Computational study of methane activation by TpRe(CO)2 and CpRe(CO)2 with a stereoelectronic comparison of cyclopentadienyl and scorpionate ligands Organometallics. 22: 2331-2337. DOI: 10.1021/Om021048J  0.656
2003 Arrowood BN, Lail M, Gunnoe TB, Boyle PD. Radical polymerization of styrene and methyl methacrylate with ruthenium(II) complexes Organometallics. 22: 4692-4698. DOI: 10.1021/Om020871C  0.787
2003 Conner D, Jayaprakash KN, Wells MB, Manzer S, Gunnoe TB, Boyle PD. Octahedral Ru(II) amido complexes TpRu(L)(L′)(NHR) (Tp = hydridotris(pyrazolyl)borate; L = L′ = P(OMe)3 or PMe3 or L = CO and L′ = PPh3; R = H, Ph, or tBu): Synthesis, characterization, and reactions with weakly acidic C-H bonds Inorganic Chemistry. 42: 4759-4772.  0.627
2002 Blue ED, Gunnoe TB, Brooks NR. Synthesis, spectroscopy, and solid-state structural characterization of the hexanuclear copper macrocycle [Cu6Cl6(mu-PCHP)6]. Angewandte Chemie (International Ed. in English). 41: 2571-3. PMID 12203537 DOI: 10.1002/1521-3773(20020715)41:14<2571::Aid-Anie2571>3.0.Co;2-1  0.734
2002 Jayaprakash KN, Gillepsie AM, Gunnoe TB, White DP. Synthesis of the RuIV amido complex [TpRu(CO)(PPh3)(NHPh)][OTf]2 (Tp = hydridotris(pyrazolyl)borate; OTf = trifluoromethanesulfonate) and deprotonation to form an octahedral and d4 imido complex: computational study of RuIV-imido bonding. Chemical Communications (Cambridge, England). 372-3. PMID 12120080 DOI: 10.1039/B110999E  0.46
2002 Conner D, Jayaprakash KN, Gunnoe TB, Boyle PD. Influence of filled d pi-manifold and L/L' ligands on the structure, basicity, and bond rotations of the octahedral and d(6) amido complexes TpRu(L)(L')(NHPh) (Tp = hydridotris(pyrazolyl)borate; L = L' = PMe(3) or P(OMe)(3), or L = CO and L' = PPh(3)): solid-state structures of [TpRu(PMe(3))(2)(NH(2)Ph)][OTf], [TpRu[P(OMe)(3)](2)(NH(2)Ph)][OTf], and TpRu[P(OMe)(3)](2)(NHPh). Inorganic Chemistry. 41: 3042-9. PMID 12033916 DOI: 10.1021/Ic020163J  0.662
2002 Valahovic MT, Gunnoe TB, Sabat M, Harman WD. Ligand-modulated stereo- and regioselective tandem addition reactions of rhenium-bound naphthalene. Journal of the American Chemical Society. 124: 3309-15. PMID 11916415 DOI: 10.1021/Ja012066F  0.832
2002 Conner D, Jayaprakash KN, Gunnoe TB, Boyle PD. Ruthenium(II) anilido complexes TpRuL2(NHPh): Oxidative 4,4′-aryl coupling reactions (Tp = hydridotris(pyrazolylborate); L = PMe3, P(OMe)3, or CO) Organometallics. 21: 5265-5271. DOI: 10.1021/Om0206406  0.706
2001 Jayaprakash KN, Gunnoe TB, Boyle PD. Preparation of the octahedral d(6) amido complex TpRu(CO)(PPh(3))(NHPh) (Tp = Hydridotris(pyrazolyl)borate): solid-state structural characterization and reactivity. Inorganic Chemistry. 40: 6481-6. PMID 11720504 DOI: 10.1021/Ic010785P  0.397
2001 Brooks BC, Meiere SH, Friedman LA, Carrig EH, Gunnoe TB, Harman WD. Interfacial and intrafacial linkage isomerizations of rhenium complexes with aromatic molecules. Journal of the American Chemical Society. 123: 3541-50. PMID 11472125 DOI: 10.1021/Ja003195J  0.8
2001 Jayaprakash KN, Conner D, Gunnoe TB. Synthesis and reactivity of the octahedral d6 parent amido complexes TpRu(L)(L′)(NH2) (Tp = hydridotris(pyrazolyl)borate; L = L′ = PMe3, P(OMe)3; L = CO, L′ = PPh3) and [TpRu(PPh3)(NH2)2][Li] Organometallics. 20: 5254-5256. DOI: 10.1021/Om010739X  0.623
2001 Meiere SH, Brooks BC, Gunnoe TB, Carrig EH, Sabat M, Harman WD. Dihapto coordination of aromatic molecules by the asymmetric π-bases {TpRe(CO)(L)} (Tp = hydridotris(pyrazolyl)borate; L = tBuNC, PMe3, pyridine, 1-methylimidazole, or NH3) Organometallics. 20: 3661-3671. DOI: 10.1021/Om010227I  0.813
2001 Meiere SH, Brooks BC, Gunnoe TB, Sabat M, Harman WD. A promising new dearomatization agent: Crystal structure, synthesis, and exchange reactions of the versatile complex TpRe(CO)(1-methylimidazole)(η2-benzene) (Tp = hydridotris(pyrazolyl)borate) Organometallics. 20: 1038-1040. DOI: 10.1021/Om000900O  0.829
2000 Gunnoe TB, Meiere SH, Sabat M, Harman WD. [TpRe(bpy)]: a novel pentaaminerhenium system that stabilizes both high and low oxidation states (Tp = hydridotris(pyrazolyl)borate; bpy = 2,2'-bipyridyl). Inorganic Chemistry. 39: 6127-30. PMID 11151513 DOI: 10.1021/Ic000707M  0.806
2000 Gunnoe TB, Sabat M, Harman WD. Stereoselective Dihapto-Binding of Prochiral Aromatic Compounds by {TpRe(CO)(PMe3)}: Synthesis, Characterization, Stability, and Enantiofacial Discrimination (Tp = Hydrido(tris)pyrazolylborate) Organometallics. 19: 728-737. DOI: 10.1021/Om9906722  0.539
2000 Tellers DM, Skoog SJ, Bergman RG, Gunnoe TB, Harman WD. Comparison of the Relative Electron-Donating Abilities of Hydridotris(pyrazolyl)borate and Cyclopentadienyl Ligands:  Different Interactions with Different Transition Metals Organometallics. 19: 2428-2432. DOI: 10.1021/Om000043O  0.663
2000 Brooks BC, Gunnoe TB, Harman WD. ChemInform Abstract: Dihapto Binding of Aromatic Molecules by π-Basic Transition Metal Complexes: Development of Alternatives to the {Os(NH3)5}2+ Fragment Cheminform. 31: no-no. DOI: 10.1002/chin.200051230  0.723
1999 Gunnoe TB, Sabat M, Harman WD. Enantiofacial Discrimination in Dihapto-Coordination of Aromatic Molecules by the Chiral π-Base/σ-Lewis Acid {TpRe(CO)(PMe3)} Journal of the American Chemical Society. 121: 6499-6500. DOI: 10.1021/Ja990891E  0.431
1998 Gunnoe TB, Caldarelli JL, White PS, Templeton JL. Spectra, Structure, Ligand Exchange, and Decomposition of a Tungsten(II) Ether Complex. Angewandte Chemie (International Ed. in English). 37: 2093-2096. PMID 29711042 DOI: 10.1002/(Sici)1521-3773(19980817)37:15<2093::Aid-Anie2093>3.0.Co;2-T  0.593
1998 Gunnoe TB, Sabat M, Harman WD. Reactions of TpRe(CO)2(THF) with aromatic molecules (Tp = hydridotris(pyrazolyl)borate) Journal of the American Chemical Society. 120: 8747-8754. DOI: 10.1021/Ja980690V  0.574
1998 Gunnoe TB, Caldarelli JL, White PS, Templeton JL. Spectra, structure, ligand exchange, and decomposition of a tungsten(II) ether complex Angewandte Chemie - International Edition. 37: 2093-2096. DOI: 10.1002/(SICI)1521-3773(19980817)37:15<2093::AID-ANIE2093>3.0.CO;2-T  0.563
1997 Gunnoe TB, Surgan M, White PS, Templeton JL, Casarrubios L. Synthesis and reactivity of tungsten (II) methylene complexes Organometallics. 16: 4865-4874. DOI: 10.1021/Om970470A  0.67
1997 Gunnoe TB, White PS, Templeton JL. Reaction of a tungsten(II) methylene complex with excess base to form a C3H5-bridged dimer Organometallics. 16: 3794-3799. DOI: 10.1021/Om970271R  0.661
1997 Gunnoe TB, White PS, Templeton JL. Synthesis and deprotonation/alkylation reactions of the chiral carbene complex Tp′(CO)(NO)Mo=C(OMe)(Me) Organometallics. 16: 370-377. DOI: 10.1021/Om960593F  0.658
1997 Gunnoe TB, White PS, Templeton JL, Casarrubios L. Electrophilic tungsten(II) methylene carbene complexes: Adduct formation, methylene transfer, and catalysis of aziridine formation from imines and ethyl diazoacetate Journal of the American Chemical Society. 119: 3171-3172. DOI: 10.1021/Ja9640206  0.571
1996 Gunnoe TB, White PS, Templeton JL. Stepwise oxidation of benzylamine coordinated to the [Tp'W(CO)(PhC2Me)]+ moiety Journal of the American Chemical Society. 118: 6916-6923. DOI: 10.1021/Ja953944A  0.652
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