| Year |
Citation |
Score |
| 2012 |
Mobarok MH, McDonald R, Ferguson MJ, Cowie M. Mixed bis(μ-silylene) and (μ-silylene)/(μ-germylene) complexes involving the Rh/Ir metal combination: nature of the Si···Si interactions in the bis(μ-silylene) species. Inorganic Chemistry. 51: 9249-58. PMID 22897501 DOI: 10.1021/Ic300720Y |
0.794 |
|
| 2012 |
Mobarok MH, McDonald R, Ferguson MJ, Cowie M. Germyl- and germylene-bridged complexes of Rh/Ir and subsequent chemistry of a bridging germylene group. Inorganic Chemistry. 51: 4020-34. PMID 22439660 DOI: 10.1021/Ic2021269 |
0.844 |
|
| 2012 |
Slaney ME, Anderson DJ, Ristic-Petrovic D, McDonald R, Cowie M. Facile carbon-fluorine bond activation and subsequent functionalisation of 1,1-difluoroethylene and tetrafluoroethylene promoted by adjacent metal centres. Chemistry (Weinheim An Der Bergstrasse, Germany). 18: 4723-37. PMID 22378610 DOI: 10.1002/Chem.201101835 |
0.856 |
|
| 2012 |
Zamora MT, Ferguson MJ, McDonald R, Cowie M. Unsymmetrical dicarbenes based on N-heterocyclic/mesoionic carbene frameworks: A stepwise metalation strategy for the generation of a dicarbene-bridged mixed-metal Pd/Rh complex Organometallics. 31: 5463-5477. DOI: 10.1021/Om3004543 |
0.781 |
|
| 2012 |
Zamora MT, Ferguson MJ, Cowie M. Di-mesoionic carbene-bridged complexes of Rh 2, Ir 2, and RhIr: A stepwise metalation strategy for the synthesis of di-MIC-bridged mixed-metal systems Organometallics. 31: 5384-5395. DOI: 10.1021/Om300423Z |
0.821 |
|
| 2012 |
MacDougall TJ, Ferguson MJ, McDonald R, Cowie M. Diverse coordination modes and transformations of allenes at adjacent iridium/osmium centers Organometallics. 31: 4516-4528. DOI: 10.1021/Om300316H |
0.837 |
|
| 2012 |
Mobarok MH, Ferguson MJ, Cowie M. Multiple Si-H bond activations in a bis(diethylphosphino)methane-bridged complex of rhodium and iridium: Synthesis of an unusual bis(silyl)/μ-silylene complex Organometallics. 31: 4722-4728. DOI: 10.1021/Om300283K |
0.849 |
|
| 2012 |
Slaney ME, Anderson DJ, Ferguson MJ, McDonald R, Cowie M. Bis(diethylphosphino)methane as a bridging ligand in complexes of Ir 2, Rh 2, and IrRh: Geminal C-H activation of α-olefins Organometallics. 31: 2286-2301. DOI: 10.1021/Om201214Z |
0.844 |
|
| 2012 |
MacDougall TJ, Samant RG, Trepanier SJ, Ferguson MJ, McDonald R, Cowie M. Geminal carbon-hydrogen bond activation in cumulenes promoted by adjacent iridium/ruthenium centers Organometallics. 31: 1857-1869. DOI: 10.1021/Om201201H |
0.843 |
|
| 2012 |
Slaney ME, Ferguson MJ, McDonald R, Cowie M. Tandem C-F and C-H bond activation in fluoroolefins promoted by a bis(diethylphosphino)methane-bridged diiridium complex: Role of water in the activation processes Organometallics. 31: 1384-1396. DOI: 10.1021/Om2011968 |
0.841 |
|
| 2011 |
Hounjet LJ, McDonald R, Ferguson MJ, Cowie M. Comparison of structure and reactivity of phosphine-amido and hemilabile phosphine-amine chelates of rhodium. Inorganic Chemistry. 50: 5361-78. PMID 21591636 DOI: 10.1021/Ic101883U |
0.773 |
|
| 2011 |
Wells KD, McDonald R, Ferguson MJ, Cowie M. Unusual ligand transformations initiated by dppm deprotonation in methylene-bridged Rh/Os complexes. Inorganic Chemistry. 50: 3523-38. PMID 21395301 DOI: 10.1021/Ic102470J |
0.59 |
|
| 2011 |
MacDougall TJ, Trepanier SJ, Dutton JL, Ferguson MJ, McDonald R, Cowie M. Facile carbon-carbon bond formation and multiple carbon-hydrogen bond activations promoted by methylene-bridged iridium/ruthenium complexes Organometallics. 30: 5882-5893. DOI: 10.1021/Om200732P |
0.843 |
|
| 2011 |
Hounjet LJ, Ferguson MJ, Cowie M. Phosphine - Amido complexes of ruthenium and mechanistic implications for ketone transfer hydrogenation catalysis Organometallics. 30: 4108-4114. DOI: 10.1021/Om2004173 |
0.797 |
|
| 2011 |
Wells KD, McDonald R, Ferguson MJ, Cowie M. Influences of N-heterocyclic carbene and PMe3 ligands on the tautomerism between methylene/hydride and bridging methyl complexes of Rh/Os and unusual examples of ligand deprotonation by the NHC group Organometallics. 30: 2654-2669. DOI: 10.1021/Om1010066 |
0.582 |
|
| 2011 |
Wells KD, Ferguson MJ, McDonald R, Cowie M. Ethylene substitution in a bis-ethylene complex of Rh/Os and unusual brønsted-lowry basicity of an N-heterocyclic carbene Organometallics. 30: 815-825. DOI: 10.1021/Om101000Y |
0.595 |
|
| 2011 |
MacDougall TJ, Llamazares A, Kuhnert O, Ferguson MJ, McDonald R, Cowie M. Alkyne/methylene coupling at adjacent iridium/osmium centers: Facile carbon-carbon and carbon-oxygen bond formation Organometallics. 30: 952-964. DOI: 10.1021/Om1009999 |
0.847 |
|
| 2010 |
Mobarok MH, Oke O, Ferguson MJ, McDonald R, Cowie M. Multiple silicon-hydrogen bond activations at adjacent rhodium and iridium centers. Inorganic Chemistry. 49: 11556-72. PMID 21077657 DOI: 10.1021/Ic1017196 |
0.842 |
|
| 2010 |
Slaney ME, Anderson DJ, Ferguson MJ, McDonald R, Cowie M. The bridged binding mode as a new, versatile template for the selective activation of carbon-fluorine bonds in fluoroolefins: activation of trifluoroethylene. Journal of the American Chemical Society. 132: 16544-58. PMID 21028880 DOI: 10.1021/Ja106723U |
0.854 |
|
| 2010 |
Hounjet LJ, Bierenstiel M, Ferguson MJ, McDonald R, Cowie M. Coordinatively diverse ortho-phosphinoaniline complexes of ruthenium and isolation of a putative intermediate in ketone transfer hydrogenation catalysis. Inorganic Chemistry. 49: 4288-300. PMID 20364836 DOI: 10.1021/Ic100165T |
0.778 |
|
| 2009 |
Zamora MT, Ferguson MJ, McDonald R, Cowie M. Carbene-anchored/pendent-imidazolium species as precursors to di-N-heterocyclic carbene-bridged mixed-metal complexes. Dalton Transactions (Cambridge, England : 2003). 7269-87. PMID 20449172 DOI: 10.1039/B906884H |
0.83 |
|
| 2009 |
Hounjet LJ, Bierenstiel M, Ferguson MJ, McDonald R, Cowie M. Mono- and binuclear complexes of rhodium involving a new series of hemilabile o-phosphinoaniline ligands. Dalton Transactions (Cambridge, England : 2003). 4213-26. PMID 19452072 DOI: 10.1039/B822170G |
0.807 |
|
| 2009 |
Samant RG, Trepanier SJ, Wigginton JR, Xu L, Bierenstiel M, McDonald R, Ferguson MJ, Cowie M. Unsymmetrically Bridged Methyl Groups as Intermediates in the Transformation of Bridging Methylene to Bridging Acetyl Groups: Ligand Migrations and Migratory Insertions in Mixed Iridium/Ruthenium Complexes Organometallics. 28: 3407-3420. DOI: 10.1021/Om900127U |
0.847 |
|
| 2008 |
Wells KD, Ferguson MJ, McDonald R, Cowie M. A-frame complexes of dirhodium bridged by dicarbene and diphosphine ligands Organometallics. 27: 691-703. DOI: 10.1021/Om7007937 |
0.562 |
|
| 2008 |
Samant RG, Graham TW, Rowsell BD, McDonald R, Cowie M. Coordination and activation of diazoalkanes in the presence of Rh/Ru and Rh/Os metal combinations Organometallics. 27: 3070-3081. DOI: 10.1021/Om700756Q |
0.855 |
|
| 2007 |
Anderson DJ, McDonald R, Cowie M. Carbon-fluorine bond activation in fluoroolefins: clear documentation of cooperative C-F bond activation by adjacent metal centers. Angewandte Chemie (International Ed. in English). 46: 3741-4. PMID 17410625 DOI: 10.1002/Anie.200603972 |
0.352 |
|
| 2007 |
Dennett JN, Bierenstiel M, Ferguson MJ, McDonald R, Cowie M. Various coordination modes of the bis(di(o-N,N-dimethylanilinyl)phosphino)methane ligand in mononuclear and binuclear complexes of group 8 and group 9 metals. Inorganic Chemistry. 45: 3705-17. PMID 16634605 DOI: 10.1021/Ic051639C |
0.469 |
|
| 2005 |
Cowie M. 2003 Alcan Award Lecture - Roles of the adjacent metals in the coupling of methylene groups promoted by heterobinuclear complexes of group 8 and 9 metals Canadian Journal of Chemistry. 83: 1043-1055. DOI: 10.1139/V05-122 |
0.542 |
|
| 2005 |
Wigginton JR, Chokshi A, Graham TW, Mcdonald R, Ferguson MJ, Cowie M. Alkyne/Methylene Coupling Reactions at Adjacent Rh/Os Centers: Stepwise Transformations from C1- through C4-Bridged Species Organometallics. 24: 6398-6410. DOI: 10.1021/Om058041X |
0.557 |
|
| 2005 |
Wigginton JR, Trepanier SJ, McDonald R, Ferguson MJ, Cowie M. Bridging methylene and methyl complexes of rhodium/ osmium: Influence of the ancillary ligands on the methyl binding mode Organometallics. 24: 6194-6211. DOI: 10.1021/Om0580405 |
0.828 |
|
| 2005 |
Hilts RW, Oke O, Ferguson MJ, Mcdonald R, Cowie M. Dialkyl and Trialkyl Heterobinuclear Complexes of Rhodium and Iridium: Models for Adjacent-Metal Involvement in Bimetallic Catalysts Organometallics. 24: 4393-4405. DOI: 10.1021/Om058013E |
0.591 |
|
| 2005 |
Ristic-Petrovic D, Anderson DJ, Torkelson JR, Ferguson MJ, Mcdonald R, Cowie M. Binuclear activation of cumulenes : Roles of the adjacent metals and the cumulene binding mode in the activation process Organometallics. 24: 3711-3724. DOI: 10.1021/Om0580102 |
0.597 |
|
| 2004 |
Trepanier SJ, Dennett JN, Sterenberg BT, McDonald R, Cowie M. Selective coupling of methylene groups at a Rh/Os core, yielding C2, C3, or C4 fragments: roles of the adjacent metals in carbon-carbon bond formation. Journal of the American Chemical Society. 126: 8046-58. PMID 15212555 DOI: 10.1021/Ja040054Z |
0.842 |
|
| 2004 |
Chokshi A, Rowsell BD, Trepanier SJ, Ferguson aMJ, Cowie M. Carbon−Carbon Bond Formation by Cumulene Insertion into “Rh(μ-CH2)M” Moieties (M = Ru, Os): Roles of the Cumulenes and the Metals in Product Formation Organometallics. 23: 4759-4770. DOI: 10.1021/Om040074+ |
0.835 |
|
| 2004 |
Rowsell BD, McDonald R, Cowie M. Bridging methylene to bridging acyl conversion in heterobinuclear Rh/Ru complexes: Models for adjacent-metal involvement in bimetallic catalysts Organometallics. 23: 3873-3883. DOI: 10.1021/Om040051V |
0.862 |
|
| 2003 |
Ristic-Petrovic D, Anderson DJ, Torkelson JR, Mcdonald R, Cowie M. Olefin Binding in a Binuclear Iridium Complex as a Function of Fluorine Substitution: Ethylene to Tetrafluoroethylene Organometallics. 22: 4647-4657. DOI: 10.1021/Om030328B |
0.56 |
|
| 2003 |
Trepanier SJ, McDonald R, Cowie M. Methylene-to-acetyl conversion in heterobinuclear Rh/Os complexes: Models for oxygenate formation by bimetallic Fischer-Tropsch catalysts Organometallics. 22: 2638-2651. DOI: 10.1021/Om030282M |
0.834 |
|
| 2003 |
Rowsell BD, McDonald R, Ferguson MJ, Cowie M. Carbon-carbon bond formation promoted by adjacent metal centers: Regioselective alkyne insertions into a "Rh(μ-CH2)Ru" moiety yielding C3- And C5-bridged fragments Organometallics. 22: 2944-2955. DOI: 10.1021/Om030165R |
0.851 |
|
| 2002 |
Ristic-Petrovic D, Wang M, Mcdonald R, Cowie M. Binuclear Fluorovinyl Complexes of Iridium: Transformation of an Iridium-Bound Trifluorovinyl Group into a trans-[Ir−C(F)C(F)CH3] Moiety Organometallics. 21: 5172-5181. DOI: 10.1021/Om020295K |
0.604 |
|
| 2002 |
Rowsell BD, Trepanier SJ, Lam R, McDonald R, Cowie M. Methylene-bridged complexes of rhodium/ruthenium as models for bimetallic fischer-tropsch catalysts: Comparisons with the Rh/Os and Ir/Ru analogues Organometallics. 21: 3228-3237. DOI: 10.1021/Om020118J |
0.834 |
|
| 2001 |
Dell'Anna MM, Trepanier SJ, McDonald R, Cowie M. Methylene-bridged heterobinuclear complexes of iridium and ruthenium: Models for bimetallic Fischer-Tropsch catalysts Organometallics. 20: 88-99. DOI: 10.1021/Om000639B |
0.853 |
|
| 2000 |
Torkelson JR, Oke O, Muritu J, McDonald aR, Cowie M. Reactions of the Binuclear Complexes [MIr(CO)3(Ph2PCH2PPh2)2] (M = Rh, Ir) with Alkyl Halides: Dramatic Reactivity Differences as a Function of Metal Combination and Alkyl Halide Organometallics. 19: 854-864. DOI: 10.1021/Om990845N |
0.563 |
|
| 2000 |
Ristic-Petrovic D, Torkelson JR, Hilts RW, McDonald aR, Cowie M. Double Activation of the Geminal Carbon−Hydrogen Bonds in 1,3-Butadiene by a Diiridium Complex Organometallics. 19: 4432-4434. DOI: 10.1021/Om0006054 |
0.574 |
|
| 2000 |
George DSA, Hilts RW, McDonald R, Cowie M. Sulfur–carbon bond formation and bond cleavage in alkynyl-bridged heterobinuclear complexes of rhodium and iridium Inorganica Chimica Acta. 300: 353-368. DOI: 10.1016/S0020-1693(99)00605-2 |
0.495 |
|
| 1999 |
George DSA, Hilts RW, McDonald R, Cowie M. An unusual example of allyl-to-alkynyl migration in a phenylacetylide-bridged heterobinuclear complex of rhodium and iridium Organometallics. 18: 5330-5343. DOI: 10.1021/Om9906565 |
0.483 |
|
| 1999 |
Torkelson JR, McDonald R, Cowie M. C−H Bond Activation and C−C Bond Formation in the Reactions of the Methyl Complex [Ir2(CH3)(CO)2(Ph2PCH2PPh2)2][CF3SO3] with Alkynes Organometallics. 18: 4134-4146. DOI: 10.1021/Om990291O |
0.845 |
|
| 1999 |
Graham TW, Llamazares A, McDonald R, Cowie M. Tetranuclear, Early−Late Heterobimetallic Complexes Bridged by the Bifunctional Phosphinoalkylcyclopentadienyl Ligands [Ph2P(CH2)nC5H4]- (n = 1, 2) Organometallics. 18: 3502-3510. DOI: 10.1021/Om990280V |
0.538 |
|
| 1999 |
Graham TW, Llamazares A, McDonald R, Cowie M. ((Diaryl- and Dialkylphosphino)alkyl)cyclopentadienyl Ligands and Their Use in the Preparation of Heterobinuclear Ti/Mo and Zr/Mo Complexes Organometallics. 18: 3490-3501. DOI: 10.1021/Om990279W |
0.56 |
|
| 1999 |
Graham TW, Gastel FV, McDonald aR, Cowie M. Mixed-Metal Hydrocarbyl Complexes Involving the Rh/Mo and Rh/W Metal Combinations Organometallics. 18: 2177-2188. DOI: 10.1021/Om990074N |
0.481 |
|
| 1999 |
Oke O, McDonald R, Cowie M. Heterobinuclear Methyl Complexes Of Rhodium/Iridium : Reactivity With Nucleophiles And Subsequent Ligand Rearrangements Organometallics. 18: 1629-1640. DOI: 10.1021/Om980947Y |
0.431 |
|
| 1999 |
Trepanier SJ, Sterenberg BT, McDonald R, Cowie M. Selective coupling of methylene units in a Rh/Os complex to give either C3 or C4 fragments [9] Journal of the American Chemical Society. 121: 2613-2614. DOI: 10.1021/Ja983626M |
0.771 |
|
| 1999 |
Torkelson JR, Antwi-Nsiah FH, McDonald R, Cowie M, Pruis JG, Jalkanen KJ, DeKock RL. Metal−Metal Cooperativity Effects in Promoting C−H Bond Cleavage of a Methyl Group by an Adjacent Metal Center Journal of the American Chemical Society. 121: 3666-3683. DOI: 10.1021/Ja983525O |
0.566 |
|
| 1998 |
George DSA, McDonald R, Cowie M. Reactivity of the Heterobinuclear Phenylacetylide-Bridged A-Frame [RhIr(CO)2(μ-CCPh)(Ph2PCH2PPh2)2][O3SCF3] with Small Molecules Organometallics. 17: 2553-2566. DOI: 10.1021/Om970946Q |
0.494 |
|
| 1998 |
Torkelson JR, McDonald R, Cowie M. Binuclear Complexes as Models for Adjacent-Metal Involvement in C−H Bond-Cleavage and C−C Bond-Formation Steps Relevant to Fischer−Tropsch Chemistry Journal of the American Chemical Society. 120: 4047-4048. DOI: 10.1021/Ja973927G |
0.394 |
|
| 1997 |
Sterenberg BT, McDonald R, Cowie M. Heterobinuclear Vinyl, Allyl, and Related Complexes of Rhodium/Osmium from Terminal Alkynes and Allenes, Vinyl to Carbene Transformations, and the Structures of [RhOs(C(CH3)CH2)(CO)3(Ph2PCH2PPh2)2] and [RhOs(C(CH3)C(CH3)2)(CH3)(CO)3(Ph2PCH2PPh2)2][CF3SO3] Organometallics. 16: 2297-2312. DOI: 10.1021/Om9609067 |
0.535 |
|
| 1997 |
Antwi-Nsiah FH, Torkelson JR, Cowie M. Alkyne or alkene binding versus hydrogenation in reactions with [Ir2H(CO)2 (μ-H) 2(Ph2PCH2PPh2)2] [BF4]. Structure of [Ir2(C2H4) (CO) 2(μ-H) (Ph2PCH2PPh2)2] [BF4] Inorganica Chimica Acta. 259: 213-226. DOI: 10.1016/S0020-1693(97)05464-9 |
0.825 |
|
| 1996 |
George DSA, McDonald R, Cowie M. Parallel vs. perpendicular alkyne coordination in binuclear complexes. The first examples of reactivity differences in isomers differing in their alkyne coordination modes Canadian Journal of Chemistry. 74: 2289-2303. DOI: 10.1139/V96-257 |
0.425 |
|
| 1996 |
Antwi-Nsiah FH, Oke O, Cowie M. Heterobinuclear alkyl complexes of rhodium and iridium. Migratory insertion or Ir-to-Rh migration of a methyl group in reactions with small molecules Organometallics. 15: 1042-1054. DOI: 10.1021/Om9505874 |
0.589 |
|
| 1996 |
Antwi-Nsiah FH, Oke O, Cowie M. Diverse Reactivity of Alkynes with the Binuclear Methyl and Incipient Methyl Complexes [RhIr(CH3)(CO)3(Ph2PCH2PPh2)2][CF3SO3] and [Ir2H(CO)3(μ-CH2)(Ph2PCH2PPh2)2][CF3SO3] Organometallics. 15: 506-520. DOI: 10.1021/Om9505118 |
0.587 |
|
| 1996 |
Antwi-Nsiah FH, Oke O, Cowie M. Diverse reactivity of alkynes with the binuclear methyl and incipient methyl complexes [RhIr(CH3)(CO)3(Ph2PCH2PPh 2)2][CF3SO3] and [Ir2H(CO)3(μ-CH2)(Ph2PCH 2PPh2)2][CF3SO3] Organometallics. 15: 506-520. |
0.565 |
|
| 1995 |
Wang L, Cowie M. Alkyne transformations at RhMn centres. Facile conversion between parallel and perpendicular alkyne binding modes and conversions to vinyl groups Canadian Journal of Chemistry. 73: 1057-1071. DOI: 10.1139/V95-131 |
0.589 |
|
| 1995 |
Wang LS, Cowie M. Cationic vinylidene-bridged complexes and their reactions with alkynes to yield either alkyne- and vinylidene-bridged or bis(vinylidene) products. Facile interconversion between terminal and bridging vinylidene bonding modes Organometallics. 14: 3040-3057. DOI: 10.1021/Om00006A054 |
0.554 |
|
| 1995 |
Wang L, Cowie M. Bridging Vinylidene Complexes Of Rhmn And Evidence For Migratory Insertions To Give Terminal Vinyl Groups Organometallics. 14: 2374-2386. DOI: 10.1021/Om00005A039 |
0.393 |
|
| 1995 |
Sterenberg BT, Hilts RW, Moro G, McDonald R, Cowie M. Heterobinuclear Hydrido, Alkyl, and Related Complexes of Rh/Os. Site-Specific Reductive Elimination of Methane from a Rh/Os Core and the Structures of [RhOs(CH2CN)(CO)3(dppm)2] and [RhOs(CH3)(CO)3(dppm)2] Journal of the American Chemical Society. 117: 245-258. DOI: 10.1021/Ja00106A028 |
0.501 |
|
| 1994 |
Seyferth D, Ruschke DP, Davis WM, Cowie M, Hunter AD. Reactions Of Triethylammonium Salts Of The (Mu -Co)(Mu -Rs)Fe2(Co)6- Anions With Alkynylmercury Compounds. Unexpected Products Via Hydrogen Migration Processes Organometallics. 13: 3834-3848. DOI: 10.1021/Om00022A019 |
0.559 |
|
| 1994 |
Wang LS, McDonald R, Cowie M. S-H Bond activation in H2S and thiols by [RhMn(CO)4(Ph2PCH2PPh2) 2]. Compounds containing terminal or bridging sulfhydryl and thiolato groups Inorganic Chemistry. 33: 3735-3744. DOI: 10.1021/Ic00095A017 |
0.535 |
|
| 1993 |
Xiao J, Cowie M. "A-frame" vs. "open-book" geometries in binuclear complexes bridged by diphosphines and mercaptothiazolinate ligands. Unusual examples involving a bridging bis(diphenylphosphino)ethane group Canadian Journal of Chemistry. 71: 726-737. DOI: 10.1139/V93-096 |
0.468 |
|
| 1993 |
Xiao J, Cowie M. Alkyne-to-vinylidene tautomerism mediated by two adjacent metal centers. Structures of iridium complexes [Ir2I2(CO)2(.mu.-CCHR)(Ph2PCH2PPh2)2] (R = H, Ph) Organometallics. 12: 463-472. DOI: 10.1021/Om00026A033 |
0.416 |
|
| 1993 |
Xiao J, Santarsiero BD, Vaartstra BA, Cowie M. Structure and reactivity studies of the unusual peroxo-bridged iridium complex, [Ir2I2(CO)2(.mu.-O2)(Ph2PCH2PPh2)2]: the first compound having a peroxide moiety bridging a metal-metal bond Journal of the American Chemical Society. 115: 3212-3220. DOI: 10.1021/Ja00061A020 |
0.484 |
|
| 1993 |
McDonald R, Cowie M. Sulfur-hydrogen and selenium-hydrogen bond activation by both metal centers in [MM[prime](CO)[sub 3](Ph[sub 2]PCH[sub 2]PPh[sub 2])[sub 2]] (M, M[prime] = Rh, Ir) Inorganic Chemistry. 32: 1671-1680. DOI: 10.1021/Ic00061A024 |
0.331 |
|
| 1993 |
McDonald R, Cowie M. Sulfur-hydrogen and selenium-hydrogen bond activation by both metal centers in [MM′(CO)3(Ph2PCH2PPh2) 2] (M, M′ = Rh, Ir) Inorganic Chemistry. 32: 1671-1680. |
0.439 |
|
| 1993 |
Xiao J, Cowie M. Alkyne-to-vinylidene tautomerism mediated by two adjacent metal centers. Structures of [Ir2I2(CO)2(μ-CC(H)R)(Ph2PCH 2PPh2)2] (R = H, Ph) Organometallics. 12: 463-472. |
0.432 |
|
| 1992 |
Seyferth D, Anderson LL, Davis WB, Cowie M. Reactions of thioallenes with triiron dodecacarbonyl: A route to thioallyl-bridged diiron hexacarbonyl complexes Organometallics. 11: 3736-3744. DOI: 10.1021/Om00059A042 |
0.425 |
|
| 1992 |
Seyferth D, Anderson LL, Villafane F, Cowie M, Hilts RW. Reactions of 2-furyl, 2-thienyl, and N-methyl-2-pyrrolyl mercurials with [Et3NH][(.mu.-CO)(.mu.-RS)Fe2(CO)6] complexes. Synthesis of Fe2(CO)6 complexes with bridging .eta.1:.eta.2-furyl and thienyl ligands Organometallics. 11: 3262-3271. DOI: 10.1021/Om00046A024 |
0.393 |
|
| 1992 |
Antwi-Nsiah F, Cowie M. Binuclear alkyl complexes: Unusual ethylene adducts and facile C-H activation of a methyl group by an adjacent metal Organometallics. 11: 3157-3160. DOI: 10.1021/Om00046A001 |
0.558 |
|
| 1992 |
Jenkins JA, Cowie M. Novel binuclear bis(dimethylphosphino)methane-bridged complexes of rhodium containing two and three alkyne molecules Organometallics. 11: 2774-2782. DOI: 10.1021/Om00044A015 |
0.476 |
|
| 1992 |
Jenkins JA, Cowie M. Unusual low-valent dirhodium complexes bridged by bis(dimethylphosphino)methane ligands Organometallics. 11: 2767-2774. DOI: 10.1021/Om00044A014 |
0.576 |
|
| 1991 |
Seyferth D, Archer CM, Ruschke DP, Cowie M, Hilts RW. Reactions of triethylammonium salts of the [(.mu.-CO)(.mu.-RS)Fe2(CO)6]- anion with alkyl-, aryl-, and vinylmercuric halides. Formal C-alkylation of the bridging CO ligand Organometallics. 10: 3363-3380. DOI: 10.1021/Om00055A062 |
0.414 |
|
| 1991 |
Vaartstra BA, Xiao J, Jenkins JA, Verhagen R, Cowie M. Binding of .pi.-acid ligands in diiridium and rhodium-iridium iodo complexes, including rare examples of ethylene coordination in a "a-frame" compounds. Structure of [Ir2I2(CO)(.mu.-CO)(Ph2PCH2PPh2)2].cntdot.CH2Cl2 Organometallics. 10: 2708-2717. DOI: 10.1021/Om00054A037 |
0.394 |
|
| 1991 |
Antonelli DM, Cowie M. Unusual, coordinatively unsaturated rhodium/rhenium and iridium/rhenium, alkyl, acyl, and hydrido complexes. Structure of [RhRe(CH3)(CO)4(Ph2PCH2PPh2)2][CF3SO3].cntdot.3CH2Cl2 Organometallics. 10: 2550-2559. DOI: 10.1021/Om00054A011 |
0.739 |
|
| 1991 |
Antonelli DM, Cowie M. Unusual mixed-metal carbonate-bridged complexes via oxidation of a carbonyl ligand in [RhM(CO)4(Ph2PCH2PPh2)2] (M = Mn, Re) and [IrRe(CO)5(Ph2PCH2PPh2)2] Organometallics. 10: 2173-2177. DOI: 10.1021/Om00053A020 |
0.666 |
|
| 1991 |
Hilts RW, Franchuk RA, Cowie M. Diphosphine-bridged, heterobimetallic complexes containing iridium and osmium. Reversible ortho metalation of a bridging bis(diphenylphosphino)methane group at the Iridium Center promoted by the Adjacent Osmium Center Organometallics. 10: 1297-1304. DOI: 10.1021/Om00051A018 |
0.574 |
|
| 1991 |
Hilts RW, Franchuk RA, Cowie M. Low-valent, heterobinuclear complexes of rhodium and osmium. Influence of the coordinatively unsaturated rhodium center on the reactivity Organometallics. 10: 304-316. DOI: 10.1021/Om00047A065 |
0.547 |
|
| 1991 |
Antonelli DM, Cowie M. Unusual, coordinatively unsaturated rhodium/rhenium and iridium/rhenium alkyl, acyl, and hydrido complexes. Structure of [RhRe(CH3)(CO)4(Ph2PCH2PPh 2)2][CF3SO3]·3CH 2Cl2 Organometallics. 10: 2550-2559. |
0.752 |
|
| 1990 |
McDonald R, Cowie M. Binuclear oxidative additions of silanes to [Ir2(CO)3(Ph2PCH2PPh 2)2] to yield silylene-bridged dihydride complexes Organometallics. 9: 2468-2478. DOI: 10.1021/Om00159A014 |
0.528 |
|
| 1990 |
Antonelli DM, Cowie M. A convenient general route to a series of diphosphine-bridged heterobinuclear complexes that contain rhodium and structures of the mixed-valent complexes [RhM(CO)4(Ph2PCH2PPh2)2] (M = Mn, Re) Organometallics. 9: 1818-1826. DOI: 10.1021/Om00156A022 |
0.665 |
|
| 1990 |
Vaartstra BA, Cowie M. Models for multicenter catalysts. 4. Reactions of binuclear hydrides with alkynes and the structure of [Ir2(H)2Cl(CH3O2CC = C(H)CO2CH3)2(CO)2(Ph2PCH2PPh2)2]-[BF4].cntdot.3THF, a model hydrogenation intermediate containing mutually adjacent alkenyl and hydrido ligands Organometallics. 9: 1594-1602. DOI: 10.1021/Om00119A035 |
0.47 |
|
| 1990 |
Vaartstra BA, Xiao J, Cowie M. First example of a peroxo-bridged complex having an accompanying metal-metal bond Journal of the American Chemical Society. 112: 9425-9426. DOI: 10.1021/Ja00181A073 |
0.359 |
|
| 1990 |
Antonelli DM, Cowie M. Oxidative-addition reactions involving the mixed-valence complex bis[bis(diphenylphosphino)methane]tetracarbonylrheniumrhodium. Influence of the coordinatively unsaturated Rh(+I) center on the saturated Re(-I) center Inorganic Chemistry. 29: 4039-4045. DOI: 10.1021/Ic00345A026 |
0.691 |
|
| 1990 |
Hilts RW, Cowie M. Dithiophosphinate-bridged ruthenium(I) and ruthenium(II) complexes. The structure of [(Ru2(CO)4(.mu.-S2PMe2)2(PPh3)2].cntdot.1/2CH2Cl2 Inorganic Chemistry. 29: 3349-3354. DOI: 10.1021/Ic00343A019 |
0.472 |
|
| 1990 |
Antonelli DM, Cowie M. Ascertaining the roles of each metal in the activation of S-H bonds in hydrogen sulfide and thiols by the heterobinuclear complex tetracarbonylbis(bis(diphenylphosphino)methane)rheniumrhodium Inorganic Chemistry. 29: 3339-3345. DOI: 10.1021/Ic00343A017 |
0.687 |
|
| 1990 |
Hilts RW, Sherlock SJ, Cowie M, Singleton E, Steyn MMdV. Polymeric ruthenium(I) and binuclear ruthenium(I) and osmium(I) carboxylate-bridged complexes containing diphoshine, diarsine, arsinophosphine, diphosphine chalcogenide, and dithioether ligands: the structure of [Ru2(CO)4(.mu.-O2CMe)2(MeSCH2SMe)]2.cntdot.THF Inorganic Chemistry. 29: 3161-3167. DOI: 10.1021/Ic00342A022 |
0.465 |
|
| 1990 |
McDonald R, Cowie M. Diphosphine-bridged heterobimetallic hydride and carbonyl complexes of rhodium and iridium. Structure of [RhIr(CO)3(Ph2PCH2PPh2)2], a complex containing an Ir(-I) .fwdarw. Rh(I) dative bond Inorganic Chemistry. 29: 1564-1571. DOI: 10.1021/Ic00333A024 |
0.534 |
|
| 1990 |
Antonelli DM, Cowie M. Ascertaining the roles of each metal in the activation of S-H bonds in hydrogen sulfide and thiols by the heterobinuclear complex [RhRe(CO)4(Ph2PCH2PPh2)2] Inorganic Chemistry. 29: 3339-3345. |
0.686 |
|
| 1990 |
Antonelli DM, Cowie M. Oxidative-addition reactions involving the mixed-valence complex [RhRe(CO)4(Ph2PCH2PPh2) 2]. Influence of the coordinatively unsaturated Rh(+I) center on the saturated Re(-I) center Inorganic Chemistry. 29: 4039-4045. |
0.697 |
|
| 1990 |
McDonald R, Cowie M. Diphosphine-bridged heterobimetallic hydride and carbonyl complexes of rhodium and iridium. Structure of [RhIr(CO)3(Ph2PCH2PPh2) 2], a complex containing an Ir(-I)→Rh(I) dative bond Inorganic Chemistry. 29: 1564-1571. |
0.447 |
|
| 1990 |
Vaartstra BA, Cowie M. Models for multicenter catalysts. 4. Reactions of binuclear hydrides with alkynes and the structure of [Ir2(H)2Cl(CH3O2CC=C(H)CO 2CH3)2(CO)2(Ph2PCH 2PPh2)2]-[BF4]·3THF, a model hydrogenation intermediate containing .. Organometallics. 9: 1594-1602. |
0.518 |
|
| 1990 |
Hilts RW, Cowie M. Dithiophosphinate-bridged ruthenium(I) and ruthenium(II) complexes. Structure of [Ru2(CO)4(μ-S2PMe2) 2(PPh3)2]·1/2CH2Cl 2 Inorganic Chemistry. 29: 3349-3354. |
0.438 |
|
| 1989 |
Vaartstra BA, Cowie M. Binuclear diiridium and mixed-metal rhodium-iridium complexes containing terminal .eta.2-alkynes: the structure of [Ir2(CO)(.eta.2-F3CC CF3)(.mu.-S)(.mu.-CO)(Ph2PCH2PPh2)2].cntdot.CH2Cl2 Organometallics. 8: 2388-2394. DOI: 10.1021/Om00112A020 |
0.424 |
|
| 1989 |
Seyferth D, Ruschke DP, Davis WM, Cowie M, Hunter AD. The unexpected formation of a diiron hexacarbonyl complex containing a .mu.2-bridging carbyne ligand: structure and reactivity Organometallics. 8: 836-839. DOI: 10.1021/Om00105A042 |
0.632 |
|
| 1989 |
Cowie M, DeKock RL, Wagenmaker TR, Seyferth D, Henderson RS, Gallagher MK. Chemistry of (μ-dithio)bis(tricarbonyliron), an inorganic mimic of organic disulfides. 3. Reaction with low-valent metal compounds and some interesting isolobal analogies involving the products Organometallics. 8: 119-132. DOI: 10.1021/Om00103A015 |
0.379 |
|
| 1989 |
Vaartstra BA, Cowie M. Models for multicenter catalysts. 3. Facile hydride rearrangements in A-frame and related complexes and the structure of [RhIr(H)2(CO)2(.mu.-Cl)(DPM)2][BF4].cntdot.CH2Cl2, the product of hydrogen addition at one metal center in the A-frame pocket Inorganic Chemistry. 28: 3138-3147. DOI: 10.1021/Ic00315A014 |
0.428 |
|
| 1989 |
Sherlock SJ, Cowie M, Singleton E, Margot MM. The synthesis of some binuclear ruthenium(I) complexes bridged by anionic groups. X-ray structures of pyrazolate- and oxypyridinate-bridged complexes Journal of Organometallic Chemistry. 361: 353-367. DOI: 10.1016/0022-328X(89)87007-X |
0.48 |
|
| 1989 |
Vaartstra BA, Cowie M. Models for multicenter catalysts. 3. Facile hydride rearrangements in A-frame and related complexes and the structure of [RhIr(H)2(CO)2(μ-Cl)(DPM)2][BF 4]·CH2Cl2, the product of H2 addition at one metal center in the A-frame pocket Inorganic Chemistry. 28: 3138-3147. |
0.473 |
|
| 1988 |
Seyferth D, Hoke JB, Rheingold AL, Cowie M, Hunter AD. Novel organotransition-metal cluster complexes via reactions of dinuclear metal carbonyls with (.mu.-.sigma.,.pi.-alkynyl)(.mu.-alkanethiolato)bis(tricarbonyliron) complexes Organometallics. 7: 2163-2172. DOI: 10.1021/Om00100A013 |
0.633 |
|
| 1988 |
Jenkins JA, Ennett JP, Cowie M. Binuclear bis(dimethylphosphino)methane complexes of rhodium and some comparisons with the bis(diphenylphosphino)methane analogues of rhodium and iridium Organometallics. 7: 1845-1853. DOI: 10.1021/Om00098A023 |
0.491 |
|
| 1988 |
Sherlock SJ, Cowie M, Singleton E, Steyn MMdV. A convenient route to an uncommon class of polymeric and binuclear ruthenium(I) complexes containing diphosphine and dithioether ligands Organometallics. 7: 1663-1666. DOI: 10.1021/Om00097A037 |
0.455 |
|
| 1988 |
Sielisch T, Cowie M. Binuclear complexes of rhodium and iridium bridged by some new bifunctional anionic ligands Organometallics. 7: 707-714. DOI: 10.1021/Om00093A022 |
0.429 |
|
| 1988 |
Vaartstra BA, O'Brien KN, Eisenberg R, Cowie M. Oxidative addition of hydrogen molecule to the A-frame complex bis[bis(diphenylphosphino)methane]dicarbonyl-.mu.-sulfidoiridium: a reinvestigation Inorganic Chemistry. 27: 3668-3672. DOI: 10.1021/Ic00293A048 |
0.402 |
|
| 1988 |
Seyferth D, Hoke JB, Cowie M, Hunter AD. Synthesis of (μ3η2-vinylidene)(μ-CO)nonacarbonyltriiron complexes Journal of Organometallic Chemistry. 346: 91-104. DOI: 10.1016/0022-328X(88)87008-6 |
0.625 |
|
| 1988 |
McKeer IR, Sherlock SJ, Cowie M. Binuclear methylene- and alkyne-bridged complexes of rhodium not containing accompanying metalmetal bonds Journal of Organometallic Chemistry. 352: 205-222. DOI: 10.1016/0022-328X(88)83036-5 |
0.598 |
|
| 1988 |
Cowie M, Sielisch T. Binuclear rhodium(I) compounds bridged by the bifunctional 2-mercaptothiazolinate anion Journal of Organometallic Chemistry. 348: 241-254. DOI: 10.1016/0022-328X(88)80400-5 |
0.406 |
|
| 1987 |
Seyferth D, Womack GB, Gallagher MK, Cowie M, Hames BW, Fackler JP, Mazany AM. Novel anionic rearrangements in hexacarbonyldiiron complexes of chelating organosulfur ligands Organometallics. 6: 283-294. DOI: 10.1021/Om00145A009 |
0.556 |
|
| 1987 |
McDonald R, Sutherland BR, Cowie M. Diphosphine-bridged binuclear polyhydride complexes of iridium and the structure of bis[bis(diphenylphosphino)methane]dicarbonylhydridodi-.mu.-hydridodiiridium(1+) chloride hemi(methylene chloride) Inorganic Chemistry. 26: 3333-3339. DOI: 10.1021/Ic00267A024 |
0.464 |
|
| 1987 |
Cowie M, Dickson RS. The structure of [(PPh3)PdFe(SC5H4)2]· 0.5C6H5CH3: an unusual heterobinuclear complex containing a weak Fe → Pd dative bond Journal of Organometallic Chemistry. 326: 269-280. DOI: 10.1016/0022-328X(87)80162-6 |
0.436 |
|
| 1987 |
McDonald R, Sutherland BR, Cowie M. Diphosphine-bridged binuclear polyhydride complexes of iridium and the structure of [Ir2(H)(CO)2(μ-H)2(Ph2PCH 2PPh2)2][Cl]·1.2CH2Cl 2 Inorganic Chemistry. 26: 3333-3339. |
0.451 |
|
| 1986 |
Sutherland BR, Cowie M. The structure of [Ir2(CO)2(μ-H)(μ-CO)(Ph2PCH2PPh2)2][BF4] and comparisons with its rhodium analogue and other related doubly bridged A-frames Canadian Journal of Chemistry. 64: 464-469. DOI: 10.1139/V86-072 |
0.503 |
|
| 1986 |
Seyferth D, Womack GB, Henderson RS, Cowie M, Hames BW. Michael-type addition reactions of bis(μ-mercapto)bis(tricarbonyliron): Proximity-induced formation of bidentate organosulfur ligands Organometallics. 5: 1568-1575. DOI: 10.1021/Om00139A010 |
0.484 |
|
| 1986 |
Cowie M, McKeer IR, Loeb SJ, Gauthier MD. Diazoalkane activation by iridium phosphine compounds. 2. Unusual products resulting from nitrogen loss from the dibenzoyldiazomethane ligand: structures of cyclic-[IrCl[HC(COPh)2](PC6H4Ph2)(PPh3)].1/2PhMe and cyclic-[IrCl[(C6H4)COCCPhOPPh2](PPh3)2].PhMe Organometallics. 5: 860-868. DOI: 10.1021/Om00136A005 |
0.418 |
|
| 1986 |
Cowie M, Loeb SJ, McKeer IR. Diazoalkane activation by iridium phosphine compounds. 1. Complexes containing the intact dibenzoyldiazomethane ligand and interconversion between the η1-N-bound and a chelated N,O-bound form of the ligand accompanied by hydride migration Organometallics. 5: 854-860. DOI: 10.1021/Om00136A004 |
0.472 |
|
| 1986 |
Seyferth D, Gallagher MK, Cowie M. The bridging sulfide anion reactivity of Roussin's red salt Organometallics. 5: 539-548. DOI: 10.1021/Om00134A024 |
0.343 |
|
| 1986 |
Cowie M, Vasapollo G, Sutherland BR, Ennett JP. Transformation of a terminal to a bridging carbonyl ligand accompanied by iridium-iridium bond cleavage: an example of transmission of electronic effects from one metal center to another Inorganic Chemistry. 25: 2648-2653. DOI: 10.1021/Ic00235A032 |
0.374 |
|
| 1986 |
Cowie M, Vasapollo G, Sutherland BR, Ennett JP. Transformation of a Terminal to a Bridging Carbonyl Ligand Accompanied by Ir‐Ir Bond Cleavage: An Example of Transmission of Electronic Effects from One Metal Center to Another. Cheminform. 17. DOI: 10.1002/Chin.198648297 |
0.367 |
|
| 1986 |
Cowie M, McKeer IR, Loeb SJ, Gauthier MD. Diazoalkane activation by iridium phosphine compounds. 2. Unusual products resulting from N2 loss from the dibenzoyldiazomethane ligand: Structures of [IrCl(HC(C(O)Ph)2)(PC6H4Ph 2)(PPh3)]·1/2C6H5CH 3 and [IrCl((C6H .. Organometallics. 5: 860-868. |
0.401 |
|
| 1985 |
Sutherland BR, Cowie M. Binuclear diphosphine-bridged iridium complexes as models for the catalytic hydrogenation of alkynes in the presence of two metal centers. The structure of [Ir2Cl2(CH3O2CC:CHCO2CH3)2(CO)2(DPM)2], a product of alkyne insertions into two iridium-hydrogen bonds Organometallics. 4: 1801-1810. DOI: 10.1021/Om00129A021 |
0.396 |
|
| 1985 |
Sutherland BR, Cowie M. Hydroxy- and hydrido-bridged binuclear complexes of iridium: Synthesis, characterization, and attempts to model binuclear water-gas shift catalysts. Structure of [Ir2(CO)2(μ-OH·Cl)(Ph2PCH 2PPh2)2] Organometallics. 4: 1637-1648. DOI: 10.1021/Om00128A027 |
0.551 |
|
| 1985 |
Cowie M, Loeb SJ. Structure of [Rh2(CO)2(.mu.-C2CMe3)(Ph2PCH2PPh2)2]ClO4].cntdot.O.866CH2Cl2: an "A-frame" compound containing a .sigma.,.pi.-acetylido group Organometallics. 4: 852-857. DOI: 10.1021/Om00124A009 |
0.396 |
|
| 1985 |
Cowie M, Loeb SJ. Structure of [Rh2(CO)2(μ-C2-t-Bu)(Ph2PCH 2PPh2)2][ClO4]·0.866CH 2Cl2: An "A-frame" compound containing a σ,π-acetylido group Organometallics. 4: 852-857. |
0.409 |
|
| 1985 |
Sutherland BR, Cowie M. Binuclear diphosphine-bridged iridium complexes as models for the catalytic hydrogenation of alkynes in the presence of two metal centers. The structure of [Ir2Cl2(CH3O2CC=CHCO 2CH3)2(CO)2(DPM)2], a product of alkyne insertions into two Ir-H bonds Organometallics. 4: 1801-1810. |
0.486 |
|
| 1984 |
Seyferth D, Womack GB, Cowie M, Hames BW. Reactions of dithio esters and O-alkyl thio esters with diiron nonacarbonyl. Unexpectedly different products formed from RC(S)OR′ and HC(S)OR′ Organometallics. 3: 1891-1897. DOI: 10.1021/Om00090A017 |
0.343 |
|
| 1984 |
Cowie M, Dickson RS, Hames BW. Probing metal-metal bond reactivity in a series of acetylene-bridged binuclear complexes and the structure of a methyl isocyanide adduct, [Rh2Cl(CNMe)2(μ-CF3C2CF 3)(Ph2PCH2PPh2)2][BF 4] Organometallics. 3: 1879-1890. DOI: 10.1021/Om00090A016 |
0.55 |
|
| 1984 |
Sutherland BR, Cowie M. Neutral and cationic alkyne-bridged complexes of iridium and the structure of [Ir2Cl2(CO)2(.mu.-CH3O2CC2CO2CH3)(Ph2PCH2PPh2)2].2CH2Cl2 Organometallics. 3: 1869-1878. DOI: 10.1021/Om00090A015 |
0.426 |
|
| 1984 |
Gibson JAE, Cowie M. Isothiocyanate activation by two metal centers: examples of bridging isothiocyanate coordination, subsequent condensation and rearrangement reactions, and isocyanide formation. Structure of [Rh2Cl2(CO)(.mu.-SCNC(S)N(Ph)C(O)OEt)(Ph2PCH2PPh2)2].cntdot.1/2PhMe Organometallics. 3: 984-996. DOI: 10.1021/Om00085A005 |
0.453 |
|
| 1984 |
Gibson JAE, Cowie M. Oxidative addition of dimethylthiocarbamoyl chloride to [Rh2Cl2(.mu.-CO)(Ph2PCH2PPh2)2], the facile interconversion between chelating .eta.2 and bridging coordination modes of the SCNMe2 group, and the structure of [Rh2Cl2(CO)(SCNMe2)(Ph2PCH2PPh2)2][BF4].1.833CH2Cl2 Organometallics. 3: 722-731. DOI: 10.1021/Om00083A013 |
0.345 |
|
| 1984 |
Sutherland BR, Cowie M. Preparation and characterization of some binuclear DPM-bridged complexes of iridium and the structure of one product, [Ir2Cl2(CO)2(.mu.-CO)(Ph2PCH2PPh2)2].3C4H8O Inorganic Chemistry. 23: 2324-2331. DOI: 10.1021/Ic00183A023 |
0.502 |
|
| 1984 |
Sutherland BR, Cowie M. Rhodium-rhodium bond protonation in [Rh2Cl2(.mu.-CO)(Ph2PCH2PPh2)2] and the structure of an unusual oxidative-addition product, [Rh2Cl3(.mu.-H)(.mu.-CO)(Ph2PCH2PPh2)2].cntdot.H2O Inorganic Chemistry. 15: 1290-1297. DOI: 10.1021/Ic00177A023 |
0.389 |
|
| 1984 |
Sutherland BR, Cowie M. Rh-Rh bond protonation in [Rh2Cl2(μ-CO)(Ph2PCH2PPh 2)2] and the structure of an unusual oxidative-addition product, [Rh2Cl3(μ-H)(μ-CO)(Ph2PCH 2PPh2)2]·H2O Inorganic Chemistry. 23: 1290-1297. |
0.467 |
|
| 1984 |
Gibson JAE, Cowie M. Oxidative addition of dimethylthiocarbamoyl chloride to [Rh2Cl2(μ-CO)(Ph2PCH2PPh 2)2], the facile interconversion between chelating η2 and bridging coordination modes of the SCNMe2 group, and the structure of [Rh2Cl2(CO)(SCNMe2)(Ph .. Organometallics. 3: 722-731. |
0.417 |
|
| 1984 |
Sutherland BR, Cowie M. Neutral and cationic alkyne-bridged complexes of iridium and the structure of [Ir2Cl2(CO)2(μ-CH3O 2CC2CO2CH3)(Ph2PCH 2PPh2)2]·2CH2Cl2 Organometallics. 3: 1869-1878. |
0.41 |
|
| 1984 |
Gibson JAE, Cowie M. Isothiocyanate activation by two metal centers: Examples of bridging isothiocyanate coordination, subsequent condensation and rearrangement reactions, and isocyanide formation. Structure of [Rh2Cl2(CO)(μ-SCNC(S)N(Ph)C(O)OEt)-(Ph 2PCH2PPh2)2]·1/ 2C6H5CH3 Organometallics. 3: 984-996. |
0.361 |
|
| 1984 |
Sutherland BR, Cowie M. Preparation and characterization of some binuclear DPM-bridged complexes of indium and the structure of one product, [Ir2Cl2(CO)2(μ-CO)(Ph2PCH 2PPh2)2]·3C4H8O Inorganic Chemistry. 23: 2324-2331. |
0.493 |
|
| 1983 |
Seyferth D, Womack GB, Cowie M, Hames BW. Unexpected rearrangement of the deprotonation product of a thioformic acid ester-hexacarbonyldiiron complex: formation of an exocluster sulfonium function Organometallics. 2: 1696-1698. DOI: 10.1021/Om50005A042 |
0.317 |
|
| 1983 |
Cowie M, Gauthier MD, Loeb SJ, McKeer IR. Unexpected ortho-metalated products resulting from dibenzoyldiazomethane activation in the presence of iridium phosphine complexes Organometallics. 2: 1057-1059. DOI: 10.1021/Om50002A026 |
0.387 |
|
| 1983 |
Seyferth D, Hames BW, Rucker TG, Cowie M, Dickson RS. A novel palladium complex with iron-palladium dative bonding derived from 1,2,3-trithia[3]ferrocenophane, (Ph3P)PdFe(SC5H4)2.cntdot.0.5C6H5CH3 Organometallics. 2: 472-474. DOI: 10.1021/Om00075A027 |
0.377 |
|
| 1982 |
Cowie M, Southern TG. Acetylene activation in binuclear rhodium complexes and the structure of [Rh2Cl2(.mu.-CO)(.mu.-CH3O2CC2CO2CH3)(Ph2PCH2PPh2)2]: a complex containing a bridging acetylene and a ketonic carbonyl ligand Inorganic Chemistry. 13: 246-253. DOI: 10.1021/Ic00131A046 |
0.458 |
|
| 1982 |
McKeer IR, Cowie M. A novel binuclear rhodium complex containing bridging methylene and acetylene ligands not accompanied by a metal-metal bond Inorganica Chimica Acta. 65. DOI: 10.1016/S0020-1693(00)93511-4 |
0.413 |
|
| 1982 |
Cowie M, Southern TG. Acetylene activation in binuclear rhodium complexes and the structure of [Rh2Cl2(μ-CO)(μ-CH3O2CC 2CO2CH3)(Ph2PCH2PPh 2)2]: A complex containing a bridging acetylene and a ketonic carbonyl ligand Inorganic Chemistry. 21: 246-253. |
0.429 |
|
| 1981 |
Cowie M, Gauthier MD. The structure of benzoylphenyldiazomethane Canadian Journal of Chemistry. 59: 1463-1469. DOI: 10.1139/V81-214 |
0.338 |
|
| 1981 |
Cowie M, Dickson RS. Structure of [Rh2Cl2(μ-CF3C2CF 3)(Ph2PCH2PPh2)2]: A binuclear complex containing an acetylene molecule bound as a cis-dimetalated olefin and accompanied by a rhodium-rhodium bond Inorganic Chemistry. 20: 2682-2688. DOI: 10.1021/Ic50222A058 |
0.455 |
|
| 1981 |
Cowie M, Dwight SK. Structure of trans-[RhCl(CO)(Ph2AsCH2AsPh2)]2.CH2Cl2: a complex showing a significant rhodium-rhodium shortening relative to that of the unsolvated analog Inorganic Chemistry. 20: 1534-1538. DOI: 10.1021/Ic50219A040 |
0.414 |
|
| 1981 |
Cowie M, Dwight SK. The activation of carbon disulfide by binuclear rhodium complexes and the structure of [Rh2Cl2(CO)(C2S4)(Ph2PCH2PPh2)2] Journal of Organometallic Chemistry. 214: 233-252. DOI: 10.1016/S0022-328X(00)86633-4 |
0.481 |
|
| 1981 |
Cowie M, Dwight SK. Structure Of Trans-(Rhcl(Co)(Ph2Asch2Asph2))2.Ch2Cl2: A Complex Showing A Significant Rhodium-Rhodium Shortening Relative To That Of The Unsolvated Analog Cheminform. 12. DOI: 10.1002/Chin.198132062 |
0.414 |
|
| 1981 |
Cowie M, Dwight SK. Structure of trans-[RhCl(CO) (Ph2AsCH2AsPh2)]2·CH 2Cl2: A complex showing a significant Rh-Rh shortening relative to that of the unsolvated analogue Inorganic Chemistry. 20: 1534-1538. |
0.359 |
|
| 1980 |
Cowie M, Gauthier MD. Structure of [(.eta.5-C5H5)2W(H2NNC6H5)][BF4]: a complex containing the unusual side-on-bonded phenylhydrazido(1-) ligand Inorganic Chemistry. 12: 3142-3148. DOI: 10.1021/Ic50212A064 |
0.56 |
|
| 1980 |
Cowie M, Dwight SK. Structure of [Rh2Br2(μ-CO)((C6H5) 2PCH2P(C6H5)2) 2]: A binuclear rhodium carbonyl complex having an unusually low carbonyl stretching frequency Inorganic Chemistry. 19: 2508-2513. DOI: 10.1021/Ic50211A005 |
0.536 |
|
| 1980 |
Cowie M, Dwight SK. Unusual structural and chemical trends within a series of binuclear rhodium carbonyl halide complexes and the structure of one member of this series, trans-[Rh2Cl2(CO)2((C6H 5)2PCH2P(C6H5) 2)2] Inorganic Chemistry. 19: 2500-2507. DOI: 10.1021/Ic50211A004 |
0.514 |
|
| 1980 |
Cowie M, Dwight KS. Binuclear rhodium complexes: their chemistry with sulfur dioxide and the structure of [Rh2Cl2(.mu.-SO2)((C6H5)2PCH2P(C6H5)2)2] Inorganic Chemistry. 19: 209-216. DOI: 10.1021/Ic50203A042 |
0.301 |
|
| 1980 |
Cowie M, Southern TG. Novel binuclear rhodium complexes containing ketonic carbonyl and acetylene ligands Journal of Organometallic Chemistry. 193. DOI: 10.1016/S0022-328X(00)85628-4 |
0.549 |
|
| 1980 |
Cowie M, Dwight SK. The coordination and activation of carbon disulfide in binuclear rhodium complexes Journal of Organometallic Chemistry. 198. DOI: 10.1016/S0022-328X(00)84676-8 |
0.413 |
|
| 1980 |
Cowie M, Dwight SK. Structure of [Rh2(CO)2(.mu.-Cl)((C6H5)2PCH2P(C6H5)2)2][BF4]. A binuclear "A-frame" complex showing the open "active" site Cheminform. 11. DOI: 10.1002/Chin.198002075 |
0.511 |
|
| 1980 |
Cowie M, Gauthier MD. Structure of [(η5-C5H5)2W(H 2NNC6H5)][BF4]: A complex containing the unusual side-on-bonded phenylhydrazido(1-) ligand Inorganic Chemistry. 19: 3142-3148. |
0.387 |
|
| 1980 |
Cowie M, Dwight SK. Binuclear rhodium complexes: Their chemistry with sulfur dioxide and the structure of [Rh2Cl2(μ-SO2)((C6H 5)2PCH2P(C6H5) 2)2] Inorganic Chemistry. 19: 209-216. |
0.43 |
|
| 1979 |
Carroll JA, Sutton D, Cowie M, Gauthier MD. 'Side-on' co-ordination of a phenylhydrazido ligand: Synthesis and X-ray structure determination of [(η5-C5H5) 2W(H2NNPh)] [BF4] Journal of the Chemical Society, Chemical Communications. 1058-1059. DOI: 10.1039/C39790001058 |
0.523 |
|
| 1979 |
Cowie M, Gleizes A, Grynkewich G, Kalina D, McClure M, Scaringe R, Teitelbaum R, Ruby S, Ibers J, Kannewurf C, Marks T. Additions and Corrections - Rational Synthesis of Unidimensional Mixed Valence Solids. Structural, Spectral, and Electrical Studies of Charge Distribution and Transport in Partially Oxidized Nickel and Palladium Bisdephenylglyoximates Journal of the American Chemical Society. 101: 7438-7438. DOI: 10.1021/Ja00518A608 |
0.375 |
|
| 1979 |
Cowie M, Gleizes A, Grynkewich GW, Kalina DW, McClure MS, Scaringe RP, Teitelbaum RC, Ruby SL, Ibers JA. Rational synthesis of unidimensional mixed valence solids. Structural, spectral, and electrical studies of charge distribution and transport in partially oxidized nickel and palladium bisdiphenylglyoximates Journal of the American Chemical Society. 101: 2921-2936. DOI: 10.1021/Ja00505A021 |
0.398 |
|
| 1979 |
Cowie M, Mague J, Sanger A. Additions and Corrections - Novel Binuclear Cationic Complexes of Rhodium(I) and Iridium(I) Journal of the American Chemical Society. 101: 1908-1908. DOI: 10.1021/Ja00501A602 |
0.419 |
|
| 1979 |
Cowie M, Dwight SK. Structure of [Rh2(CO)2(.mu.-Cl)((C6H5)2PCH2P(C6H5)2)2][BF4]. A binuclear "A-frame" complex showing the open "active" site Inorganic Chemistry. 18: 2700-2706. DOI: 10.1021/Ic50200A013 |
0.511 |
|
| 1979 |
Cowie M, Dwight SK. Structure of [RhCl(H)((C6H5)2PCH2P(C 6H5)2)2][B(C6H 5)4]: A rhodium(III) hydrido complex containing chelating bis(diphenylphosphino)methane ligands Inorganic Chemistry. 18: 1209-1214. DOI: 10.1021/Ic50195A006 |
0.554 |
|
| 1979 |
Cowie M. Structure of [Rh2(CO)2(.mu.-CO)(.mu.-Cl)((C6H5)2PCH2P(C6H5)2)2][B(C6H5)4]: an "A-frame" complex having a carbonyl ligand coordinated in the proposed active site Inorganic Chemistry. 18: 286-292. DOI: 10.1021/Ic50192A016 |
0.526 |
|
| 1979 |
Cowie M. Structure of [Rh2(CO)2(.mu.-CO)(.mu.-Cl)((C6H5)2PCH2P(C6H5)2)2][B(C6H5)4]: an "A-frame" complex having a carbonyl ligand coordinated in the proposed active site Cheminform. 10. DOI: 10.1002/Chin.197918084 |
0.526 |
|
| 1979 |
Cowie M, Dwight SK, Sanger AR. Novel Complexes Of Rhodium(I) Containing Bridging Sulfur Dioxide Ligands Cheminform. 10. DOI: 10.1002/Chin.197906286 |
0.45 |
|
| 1979 |
Cowie M. Structure of [Rh2(CO)2(μ-CO)(μ-Cl)((C6H 5)2PCH2P(C6H5) 2)2][B(C6H5)4]: An "A-frame" complex having a carbonyl ligand coordinated in the proposed active site Inorganic Chemistry. 18: 286-292. |
0.441 |
|
| 1979 |
Cowie M, Dwight SK. Structure of [Rh2(CO)2(μ-Cl)((C6H5) 2PCH2P(C6H5)2) 2][BF4]. A binuclear "A-frame" complex showing the open "active" site Inorganic Chemistry. 18: 2700-2706. |
0.422 |
|
| 1978 |
Cowie M, Mague JT, Sanger AR. Novel binuclear cationic complexes of rhodium(I) and iridium(I) Journal of the American Chemical Society. 100: 3628-3629. DOI: 10.1021/Ja00479A071 |
0.422 |
|
| 1978 |
Cowie M, Dwight SK, Sanger AR. Nova Complexes or Rhodium(I) Containing Bridging SO2 Ligands Inorganica Chimica Acta. 31. DOI: 10.1016/S0020-1693(00)94940-5 |
0.445 |
|
| 1978 |
Cowie M, Mague JT, Sanger AR. Novel binuclear cationic complexes of rhodium(I) and iridium(I) [22] Journal of the American Chemical Society. 100: 3628-3629. |
0.308 |
|
| 1977 |
Cowie M, Bennett MJ. Bonding of hydrido ligands in transition metal-silyl complexes: Terminal or bridging? 2. Structure of bis(μ-diethylsilicon)-(tricarbonyldihydridorhenium)(tetracarbonylrhenium)(Re- Re), Re2(CO)7H2(Si(C2H5) 2)2 Inorganic Chemistry. 16: 2325-2329. DOI: 10.1021/Ic50175A035 |
0.644 |
|
| 1977 |
Cowie M, Bennett MJ. Bonding of hydrido ligands in transition metal-silyl complexes: Terminal or bridging? 1. Structure of bis(μ-diethylsilicon)-bis(tricarbonyldihydridorhenium)(Re-Re), Re2(CO)6H4(Si(C2H5) 2)2 Inorganic Chemistry. 16: 2321-2325. DOI: 10.1021/Ic50175A034 |
0.588 |
|
| 1976 |
Cowie M, Haymore BL, Ibers JA. Aryldiazo complexes. Synthesis and structure of a five-coordinate complex possessing a "half doubly bent" aryldiazo ligand and an intermediate coordination geometry, chloro(phenyldiazo)tris(methyldiphenylphosphine)iridium hexafluorophosphate Journal of the American Chemical Society. 98: 7608-7617. DOI: 10.1021/Ja00440A026 |
0.73 |
|
| 1976 |
Cowie M, Bennett MJ. Trigonal-prismatic vs. octahedral coordination in a series of tris(benzene-1,2-dithiolato) complexes. 3. Crystal and molecular structure of bis(tetramethylammonium) tris(benzene-1,2-dithiolato)zirconate(IV), [(CH3)4N]2[Zr(S2C6H 4)3] Inorganic Chemistry. 15: 1595-1603. DOI: 10.1021/Ic50161A025 |
0.585 |
|
| 1976 |
Cowie M, Bennett MJ. Trigonal-prismatic vs. octahedral coordination in a series of tris(benzene-1,2-dithiolato) complexes. 2. Crystal and molecular structure of tetraphenylarsonium tris(benzene-1,2-dithiolato)niobate(V), [(C6H5)4As][Nb(S2C6H 4)3] Inorganic Chemistry. 15: 1589-1595. DOI: 10.1021/Ic50161A024 |
0.616 |
|
| 1976 |
Cowie M, Bennett MJ. Trigonal-prismatic vs. octahedral coordination in a series of tris(benzene-1,2-dithiolato) complexes. 1. Crystal and molecular structure of tris(benzene-1,2-dithiolato)molybdenum(VI), Mo(S2C6H4)3 Inorganic Chemistry. 15: 1584-1589. DOI: 10.1021/Ic50161A023 |
0.564 |
|
| 1976 |
Komiya S, Ito T, Cowie M, Yamamoto A, Ibers JA. Carbon-hydrogen bond activation by transition metal complexes. Oxidative addition of alkyl methacrylate to ruthenium. The structure of hydrido(2-n-butoxycarbonylpropenyl-C1,O)tris(triphenylphosphine)ruthenium(II) Journal of the American Chemical Society. 98: 3874-3884. DOI: 10.1002/Chin.197638330 |
0.527 |
|
| 1976 |
Cowie M, Ibers JA. A tridentate ligand formed by the condensation of two benzoyl isothiocyanate molecules in the presence of RhCl(P(C6H5)3)3. Structure of RhCl((C6H5)CONCS)2(P(C6H 5)3)2·(C2H5) 2O Inorganic Chemistry. 15: 552-557. |
0.45 |
|
| 1976 |
Cowie M, Haymore BL, Ibers JA. Aryldiazo complexes. Synthesis and structure of a five-coordinate complex possessing a "half doubly bent" aryldiazo ligand and an intermediate coordination geometry, [IrCl(N2C6H5)(P(CH3)(C 6H5)2)3][PF6] Journal of the American Chemical Society. 98: 7608-7617. |
0.745 |
|
| 1975 |
Cowie M, Haymore BL, Ibers JA. Aryldiazo complexes. Structure of a hydridoaryldiazo complex of osmium, OsH(CO)(N2C6H5)(P(C6H5)3)2.CH2Cl2 Inorganic Chemistry. 14: 2617-2623. DOI: 10.1002/Chin.197602322 |
0.76 |
|
| 1975 |
Cowie M, Ibers JA, Ishii Y, Itoh K, Matsuda I, Ueda F. A Novel Tridentate Ligand Formed By The Condensation Of Two Benzoyl Isothiocyanate Molecules In The Presence Of Rhcl(Pph3)3 Cheminform. 6. DOI: 10.1002/Chin.197542427 |
0.505 |
|
| 1975 |
Cowie M, Haymore BL, Ibers JA. Aryldiazo complexes. Structure of a hydrido-aryldiazo complex of osmium, OsH(CO)(N2C6H5)(P(C6H 5)3)2·CH2Cl2 Inorganic Chemistry. 14: 2617-2623. |
0.704 |
|
| 1973 |
Bennett MJ, Cowie M, Martin JL, Takats J. Trigonal prismatic and antiprismatic coordination in an isoelectronic series of tris(benzenedithiolato) complexes [3] Journal of the American Chemical Society. 95: 7504-7505. |
0.317 |
|
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