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Jillian L. Dempsey - Publications

Affiliations: 
Chemistry University of North Carolina, Chapel Hill, Chapel Hill, NC 
Area:
Inorganic Spectroscopy and Solar Energy Conversion
Website:
http://www.chem.unc.edu/people/faculty/dempsey/index.html
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58 high-probability publications. We are testing a new system for linking publications to authors. You can help! If you notice any inaccuracies, please sign in and mark papers as correct or incorrect matches. If you identify any major omissions or other inaccuracies in the publication list, please let us know.

Year Citation  Score
2021 Kurtz DA, Dhar D, Elgrishi N, Kandemir B, McWilliams SF, Howland WC, Chen CH, Dempsey JL. Redox-Induced Structural Reorganization Dictates Kinetics of Cobalt(III) Hydride Formation via Proton-Coupled Electron Transfer. Journal of the American Chemical Society. PMID 33621088 DOI: 10.1021/jacs.0c11992  0.723
2020 Lee KJ, Gruninger CT, Lodaya KM, Qadeer S, Griffith BE, Dempsey JL. Analysis of multi-electron, multi-step homogeneous catalysis by rotating disc electrode voltammetry: theory, application, and obstacles. The Analyst. PMID 31984999 DOI: 10.1039/C9An02192B  0.342
2020 Lee KJ, Lodaya KM, Gruninger CT, Rountree ES, Dempsey JL. Redox mediators accelerate electrochemically-driven solubility cycling of molecular transition metal complexes Chemical Science. DOI: 10.1039/D0Sc02592E  0.377
2020 Barrett SM, Stratakes BM, Chambers MB, Kurtz DA, Pitman CL, Dempsey JL, Miller AJM. Mechanistic basis for tuning iridium hydride photochemistry from H2 evolution to hydride transfer hydrodechlorination Chemical Science. 11: 6442-6449. DOI: 10.1039/D0Sc00422G  0.403
2020 Huang T, Rodriguez TM, Gruninger CT, Kurtz DA, Jordan AM, Chen C, Dempsey JL. Electrosynthetic Route to Cyclopentadienyl Rhenium Hydride Complexes Enabled by Electrochemical Investigations of their Redox-Induced Formation Organometallics. 39: 1730-1743. DOI: 10.1021/Acs.Organomet.0C00049  0.333
2019 Kurtz DA, Dempsey JL. Proton-Coupled Electron Transfer Kinetics for the Photoinduced Generation of a Cobalt(III)-Hydride Complex. Inorganic Chemistry. PMID 31755267 DOI: 10.1021/Acs.Inorgchem.9B02445  0.441
2019 Wang D, Niu F, Mortelliti MJ, Sheridan MV, Sherman BD, Zhu Y, McBride JR, Dempsey JL, Shen S, Dares CJ, Li F, Meyer TJ. A stable dye-sensitized photoelectrosynthesis cell mediated by a NiO overlayer for water oxidation. Proceedings of the National Academy of Sciences of the United States of America. PMID 31488721 DOI: 10.1073/Pnas.1821687116  0.317
2019 Dempsey JL, Lancaster KM. Celebrating the Year of the Periodic Table: Emerging Investigators in Inorganic Chemistry. Inorganic Chemistry. 58: 10433-10435. PMID 31422668 DOI: 10.1021/Acs.Inorgchem.9B02174  0.541
2019 Lennox JC, Danilov EO, Dempsey JL. Delayed photoacidity produced through the triplet-triplet annihilation of a neutral pyranine derivative. Physical Chemistry Chemical Physics : Pccp. PMID 31309943 DOI: 10.1039/C9Cp02929J  0.703
2019 Lee KJ, McCarthy BD, Dempsey JL. On decomposition, degradation, and voltammetric deviation: the electrochemist's field guide to identifying precatalyst transformation. Chemical Society Reviews. PMID 31089606 DOI: 10.1039/C8Cs00851E  0.308
2019 Rountree ES, McCarthy BD, Dempsey JL. Decoding Proton-Coupled Electron Transfer with Potential-p K Diagrams: Applications to Catalysis. Inorganic Chemistry. PMID 31033279 DOI: 10.1021/Acs.Inorgchem.8B03368  0.388
2019 Hartley CL, Dempsey JL. Electron-Promoted X-Type Ligand Displacement at CdSe Quantum Dot Surfaces. Nano Letters. PMID 30640472 DOI: 10.1021/Acs.Nanolett.8B04544  0.301
2018 Huang T, Rountree ES, Traywick AP, Bayoumi M, Dempsey JL. Switching between Stepwise and Concerted Proton-Coupled Electron Transfer Pathways in Tungsten Hydride Activation. Journal of the American Chemical Society. PMID 30362720 DOI: 10.1021/Jacs.8B07102  0.411
2018 Kessler ML, Starr HE, Knauf RR, Rountree KJ, Dempsey JL. Exchange equilibria of carboxylate-terminated ligands at PbS nanocrystal surfaces. Physical Chemistry Chemical Physics : Pccp. PMID 30191247 DOI: 10.1039/C8Cp04275F  0.326
2018 Kurtz DA, Brereton KR, Ruoff KP, Tang HM, Felton GAN, Miller AJM, Dempsey JL. Bathochromic Shifts in Rhenium Carbonyl Dyes Induced through Destabilization of Occupied Orbitals. Inorganic Chemistry. PMID 29648794 DOI: 10.1021/Acs.Inorgchem.8B00360  0.333
2018 Han Y, Dillon RJ, Flynn CJ, Rountree ES, Alibabaei L, Cahoon JF, Papanikolas JM, Dempsey JL. Interfacial electron transfer yields in dye-sensitized NiO photocathodes correlated to excited-state dipole orientation of ruthenium chromophores Canadian Journal of Chemistry. 96: 865-874. DOI: 10.1139/Cjc-2017-0359  0.346
2018 Lee KJ, Dempsey JL. PCET2018 Highlights: Proton-Coupled Electron Transfers for Energy Conversion Strategies Acs Energy Letters. 3: 2477-2479. DOI: 10.1021/Acsenergylett.8B01598  0.348
2017 Lennox JC, Dempsey JL. Influence of Proton Acceptors on the Proton-Coupled Electron Transfer Reaction Kinetics of a Ruthenium-Tyrosine Complex. The Journal of Physical Chemistry. B. PMID 29130684 DOI: 10.1021/Acs.Jpcb.7B06443  0.743
2017 Dempsey JL, Hartings MR. Hop to It. Biochemistry. PMID 29028319 DOI: 10.1021/Acs.Biochem.7B00950  0.645
2017 Lee KJ, McCarthy BD, Rountree ES, Dempsey JL. Identification of an Electrode-Adsorbed Intermediate in the Catalytic Hydrogen Evolution Mechanism of a Cobalt Dithiolene Complex. Inorganic Chemistry. PMID 28165236 DOI: 10.1021/Acs.Inorgchem.6B02586  0.335
2017 McCarthy BD, Dempsey JL. Decoding Proton-Coupled Electron Transfer with Potential-pKa Diagrams. Inorganic Chemistry. PMID 28075117 DOI: 10.1021/Acs.Inorgchem.6B02325  0.376
2017 Lee KJ, Elgrishi N, Kandemir B, Dempsey JL. Electrochemical and spectroscopic methods for evaluating molecular electrocatalysts Nature Reviews Chemistry. 1. DOI: 10.1038/s41570-017-0039  0.705
2017 Lennox JC, Kurtz DA, Huang T, Dempsey JL. Excited-State Proton-Coupled Electron Transfer: Different Avenues for Promoting Proton/Electron Movement with Solar Photons Acs Energy Letters. 2: 1246-1256. DOI: 10.1021/Acsenergylett.7B00063  0.377
2017 Elgrishi N, Rountree KJ, McCarthy BD, Rountree ES, Eisenhart TT, Dempsey JL. A Practical Beginner’s Guide to Cyclic Voltammetry Journal of Chemical Education. 95: 197-206. DOI: 10.1021/Acs.Jchemed.7B00361  0.671
2016 Elgrishi N, Kurtz DA, Dempsey JL. Reaction Parameters Influencing Cobalt Hydride Formation Kinetics: Implications for Benchmarking H2-Evolution Catalysts. Journal of the American Chemical Society. PMID 27997157 DOI: 10.1021/Jacs.6B10148  0.717
2016 Eisenhart TT, Howland WC, Dempsey JL. Proton-Coupled Electron Transfer Reactions with Photometric Bases Reveal Free Energy Relationships for Proton Transfer. The Journal of Physical Chemistry. B. PMID 27500804 DOI: 10.1021/Acs.Jpcb.6B04011  0.731
2016 Rountree ES, Dempsey JL. Reactivity of Proton Sources with a Nickel Hydride Complex in Acetonitrile: Implications for the Study of Fuel-Forming Catalysts. Inorganic Chemistry. PMID 27140318 DOI: 10.1021/Acs.Inorgchem.6B00885  0.374
2016 Martin DJ, McCarthy BD, Rountree ES, Dempsey JL. Qualitative extension of the EC' Zone Diagram to a molecular catalyst for a multi-electron, multi-substrate electrochemical reaction. Dalton Transactions (Cambridge, England : 2003). PMID 26998812 DOI: 10.1039/C6Dt00302H  0.339
2016 Dempsey JL. Ligand steals spotlight from metal to orchestrate hydrogen production. Proceedings of the National Academy of Sciences of the United States of America. PMID 26747604 DOI: 10.1073/Pnas.1522759113  0.333
2016 Rountree ES, Martin DJ, McCarthy BD, Dempsey JL. Correction to “Linear Free Energy Relationships in the Hydrogen Evolution Reaction: Kinetic Analysis of a Cobaloxime Catalyst” Acs Catalysis. 6: 5684-5684. DOI: 10.1021/Acscatal.6B02013  0.311
2016 Elgrishi N, McCarthy BD, Rountree ES, Dempsey JL. Reaction Pathways of Hydrogen-Evolving Electrocatalysts: Electrochemical and Spectroscopic Studies of Proton-Coupled Electron Transfer Processes Acs Catalysis. 6: 3644-3659. DOI: 10.1021/Acscatal.6B00778  0.741
2016 Rountree ES, Martin DJ, McCarthy BD, Dempsey JL. Linear Free Energy Relationships in the Hydrogen Evolution Reaction: Kinetic Analysis of a Cobaloxime Catalyst Acs Catalysis. 6: 3326-3335. DOI: 10.1021/Acscatal.6B00667  0.382
2016 Knauf RR, Lennox JC, Dempsey JL. Quantifying Ligand Exchange Reactions at CdSe Nanocrystal Surfaces Chemistry of Materials. 28: 4762-4770. DOI: 10.1021/Acs.Chemmater.6B01827  0.324
2015 McCarthy BD, Donley CL, Dempsey JL. Electrode initiated proton-coupled electron transfer to promote degradation of a nickel(ii) coordination complex. Chemical Science. 6: 2827-2834. PMID 29403633 DOI: 10.1039/C5Sc00476D  0.372
2015 Rountree ES, Dempsey JL. Potential-Dependent Electrocatalytic Pathways: Controlling Reactivity with pKa for Mechanistic Investigation of a Nickel-Based Hydrogen Evolution Catalyst. Journal of the American Chemical Society. 137: 13371-80. PMID 26451852 DOI: 10.1021/Jacs.5B08297  0.365
2015 Martin DJ, McCarthy BD, Donley CL, Dempsey JL. Electrochemical hydrogenation of a homogeneous nickel complex to form a surface adsorbed hydrogen-evolving species. Chemical Communications (Cambridge, England). 51: 5290-3. PMID 25470993 DOI: 10.1039/C4Cc08662G  0.328
2014 Dempsey JL. Proton-coupled electron transfer: metal hydrides find the sweet spot. Nature Chemistry. 7: 101-2. PMID 25615662 DOI: 10.1038/Nchem.2162  0.351
2014 Rountree ES, McCarthy BD, Eisenhart TT, Dempsey JL. Evaluation of homogeneous electrocatalysts by cyclic voltammetry. Inorganic Chemistry. 53: 9983-10002. PMID 25247280 DOI: 10.1021/Ic500658X  0.345
2014 Bhattacharjee A, Chavarot-Kerlidou M, Dempsey JL, Gray HB, Fujita E, Muckerman JT, Fontecave M, Artero V, Arantes GM, Field MJ. Theoretical modeling of low-energy electronic absorption bands in reduced cobaloximes. Chemphyschem : a European Journal of Chemical Physics and Physical Chemistry. 15: 2951-8. PMID 25113847 DOI: 10.1002/Cphc.201402398  0.562
2014 Eisenhart TT, Dempsey JL. Photo-induced proton-coupled electron transfer reactions of acridine orange: comprehensive spectral and kinetics analysis. Journal of the American Chemical Society. 136: 12221-4. PMID 25046022 DOI: 10.1021/Ja505755K  0.387
2014 McKone JR, Ardo S, Blakemore JD, Bracher PJ, Dempsey JL, Darnton TV, Hansen MC, Harman WH, Rose MJ, Walter MG, Dasgupta S, Winkler JR, Gray HB. The Solar Army: A Case Study in Outreach Based on Solar Photoelectrochemistry Reviews in Advanced Sciences and Engineering. 3: 288-303. DOI: 10.1166/rase.2014.1076  0.641
2014 Bradshaw LR, May JW, Dempsey JL, Li X, Gamelin DR. Ferromagnetic excited-state Mn 2 + dimers in Zn 1 - X Mn x Se quantum dots observed by time-resolved magnetophotoluminescence Physical Review B - Condensed Matter and Materials Physics. 89. DOI: 10.1103/Physrevb.89.115312  0.482
2014 Nayak A, Knauf RR, Hanson K, Alibabaei L, Concepcion JJ, Ashford DL, Dempsey JL, Meyer TJ. Synthesis and photophysical characterization of porphyrin and porphyrin-Ru(ii) polypyridyl chromophore-catalyst assemblies on mesoporous metal oxides Chemical Science. 5: 3115-3119. DOI: 10.1039/C4Sc00875H  0.34
2013 White MA, Dempsey JL, Carroll GM, Gallagher JD, Gamelin DR. Photoconductive ZnO films with embedded quantum dot or ruthenium dye sensitizers Apl Materials. 1. DOI: 10.1063/1.4820428  0.716
2013 Knauf RR, Brennaman MK, Alibabaei L, Norris MR, Dempsey JL. Revealing the relationship between semiconductor electronic structure and electron transfer dynamics at metal oxide-chromophore interfaces Journal of Physical Chemistry C. 117: 25259-25268. DOI: 10.1021/Jp407587R  0.334
2013 Dempsey JL, Winkler JR, Gray HB. Solar Fuels: Approaches to Catalytic Hydrogen Evolution Comprehensive Inorganic Chemistry Ii (Second Edition): From Elements to Applications. 8: 553-565. DOI: 10.1016/B978-0-08-097774-4.00806-8  0.529
2012 Valdez CN, Dempsey JL, Brunschwig BS, Winkler JR, Gray HB. Catalytic hydrogen evolution from a covalently linked dicobaloxime. Proceedings of the National Academy of Sciences of the United States of America. 109: 15589-93. PMID 22786932 DOI: 10.1073/Pnas.1118329109  0.606
2011 Dempsey JL, Winkler JR, Gray HB. Redox reactivity of photogenerated osmium(II) complexes. Dalton Transactions (Cambridge, England : 2003). 40: 10633-6. PMID 21892445 DOI: 10.1039/C1Dt11138H  0.577
2010 Dempsey JL, Winkler JR, Gray HB. Proton-coupled electron flow in protein redox machines. Chemical Reviews. 110: 7024-39. PMID 21082865 DOI: 10.1021/Cr100182B  0.595
2010 Dempsey JL, Winkler JR, Gray HB. Mechanism of H(2) evolution from a photogenerated hydridocobaloxime. Journal of the American Chemical Society. 132: 16774-6. PMID 21067158 DOI: 10.1021/Ja109351H  0.593
2010 Dempsey JL, Winkler JR, Gray HB. Kinetics of electron transfer reactions of H2-evolving cobalt diglyoxime catalysts. Journal of the American Chemical Society. 132: 1060-5. PMID 20043639 DOI: 10.1021/Ja9080259  0.588
2010 Dempsey JL, Brunschwig BS, Winkler JR, Gray HB. ChemInform Abstract: Hydrogen Evolution Catalyzed by Cobaloximes Cheminform. 41: no-no. DOI: 10.1002/chin.201021228  0.516
2009 Dempsey JL, Brunschwig BS, Winkler JR, Gray HB. Hydrogen evolution catalyzed by cobaloximes. Accounts of Chemical Research. 42: 1995-2004. PMID 19928840 DOI: 10.1021/Ar900253E  0.619
2009 Dempsey JL, Valdez CN, Winkler JR, Gray HB. Probing mechanisms of cobalt-catalyzed dihydrogen production in homogeneous solutions Acs National Meeting Book of Abstracts.  0.491
2007 Esswein AJ, Dempsey JL, Nocera DG. A RhII-AuII bimetallic core with a direct metal-metal bond. Inorganic Chemistry. 46: 2362-4. PMID 17326627 DOI: 10.1021/Ic062203F  0.561
2007 Dempsey JL, Winkler JR, Gray HB. Solar photochemistry Acs National Meeting Book of Abstracts.  0.438
2005 Dempsey JL, Esswein AJ, Manke DR, Rosenthal J, Soper JD, Nocera DG. Molecular chemistry of consequence to renewable energy. Inorganic Chemistry. 44: 6879-92. PMID 16180843 DOI: 10.1021/Ic0509276  0.606
2005 Rosenthal J, Bachman J, Dempsey JL, Esswein AJ, Gray TG, Hodgkiss JM, Manke DR, Luckett TD, Pistorio BJ, Veige AS, Nocera DG. Oxygen and hydrogen photocatalysis by two-electron mixed-valence coordination compounds Coordination Chemistry Reviews. 249: 1316-1326. DOI: 10.1016/J.Ccr.2005.03.034  0.588
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