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David M. Lemal - Publications

Affiliations: 
1958-1965 University of Wisconsin, Madison, Madison, WI 
 1965- Chemistry Dartmouth College, Hanover, NH, United States 
Area:
Organofluorine chemistry; unusual organic species, stable and short-lived
Website:
http://dartmouth.edu/faculty-directory/david-lemal
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61 high-probability publications. We are testing a new system for linking publications to authors. You can help! If you notice any inaccuracies, please sign in and mark papers as correct or incorrect matches. If you identify any major omissions or other inaccuracies in the publication list, please let us know.

Year Citation  Score
2019 Hughes RP, Lemal DM. Competing (4+2) and (2+2) cycloaddition reactions of tetrafluorothiophene-S,S-dioxide with phenylacetylene: A computational study Journal of Fluorine Chemistry. 221: 42-47. DOI: 10.1016/J.Jfluchem.2019.03.006  0.329
2018 Junk CP, He Y, Zhang Y, Smith JR, Dixon DA, Vasiliu M, Lemal DM. Chemistry of the Highly Strained Alkene Perfluorobicyclo[2.2.0]hex-1(4)-ene European Journal of Organic Chemistry. 2018: 3167-3179. DOI: 10.1002/Ejoc.201800058  0.721
2017 Lemal DM. Pathways for Concerted [2 + 2] Cycloaddition to Cumulenes. The Journal of Organic Chemistry. 82: 13012-13019. PMID 29190091 DOI: 10.1021/Acs.Joc.7B01911  0.323
2016 Lemal DM. Cycloaddition Chemistry of Tetrafluorothiophene S,S-Dioxide. The Journal of Organic Chemistry. PMID 27246658 DOI: 10.1021/Acs.Joc.6B00848  0.327
2015 Junk CP, He Y, Zhang Y, Smith JR, Gleiter R, Kass SR, Jasinski JP, Lemal DM. Synthesis and properties of the strained alkene perfluorobicyclo[2.2.0]hex-1(4)-ene. The Journal of Organic Chemistry. 80: 1523-32. PMID 25574561 DOI: 10.1021/Jo502456H  0.751
2013 Lemal DM, Akashi M, Lou Y, Kumar V. Tetrafluorothiophene S,S-dioxide: a perfluorinated building block. The Journal of Organic Chemistry. 78: 12330-7. PMID 24313897 DOI: 10.1021/Jo402373X  0.455
2010 Lemal DM. Chemistry of hexafluorobicyclo[1.1.0]butane: a computational study. The Journal of Organic Chemistry. 75: 6411-5. PMID 20825173 DOI: 10.1021/Jo100842A  0.338
2009 Lemal DM, Sang D, Ramanathan S. o-Fluoranil: stereochemistry and mechanism of its Diels-Alder reactions. The Journal of Organic Chemistry. 74: 7804-11. PMID 19761264 DOI: 10.1021/Jo9015562  0.336
2009 Lemal DM. The effect of fluorine substitution on ring inversion in bicyclo[1.1.0]butanes. The Journal of Organic Chemistry. 74: 2413-6. PMID 19226158 DOI: 10.1021/Jo802693V  0.354
2008 Lemal DM, Ramanathan S, Shellito J. o-Fluoranil chemistry: Diels-Alder versus hetero-Diels-Alder cycloaddition. The Journal of Organic Chemistry. 73: 3392-6. PMID 18355036 DOI: 10.1021/Jo7026678  0.359
2007 Eger EI, Lemal D, Laster MJ, Liao M, Jankowska K, Raghavanpillai A, Popov AV, Gan Y, Lou Y. Anesthetic properties of some fluorinated oxolanes and oxetanes. Anesthesia and Analgesia. 104: 1090-7, tables of co. PMID 17456657 DOI: 10.1213/01.Ane.0000260299.36174.A8  0.378
2007 Ramanathan S, Lemal DM. Synthesis, mechanism of formation, and dynamics of a highly fluorinated methylenecyclobutene. The Journal of Organic Chemistry. 72: 1570-4. PMID 17288480 DOI: 10.1021/Jo061946F  0.343
2007 Ramanathan S, Lemal DM. Conformational and configurational dynamics of a highly fluorinated hydrazone. The Journal of Organic Chemistry. 72: 1566-9. PMID 17288479 DOI: 10.1021/Jo061945N  0.311
2007 Lemal DM, Chen X. Fluorinated Cyclobutanes and Their Derivatives Cheminform. 38. DOI: 10.1002/9780470682531.Pat0335  0.38
2006 Wei Y, Liu Y, Wong T, Lemal DM. Extremely facile ring inversion and rearrangement in fluorobicyclo[2.1.0]pentanes Journal of Fluorine Chemistry. 127: 688-703. DOI: 10.1016/J.Jfluchem.2005.12.029  0.744
2004 Chen X, Lemal DM. Synthesis, basicity, and dynamics of a perfluorocyclohexenyl anion. The Journal of Organic Chemistry. 69: 8205-8. PMID 15549788 DOI: 10.1021/Jo040246C  0.337
2004 Wei Y, Lemal DM. Novel concerted fragmentation upon alcoholysis of a urazole. Organic Letters. 6: 3837-9. PMID 15469362 DOI: 10.1021/Ol040051R  0.528
2003 He Y, Junk CP, Lemal DM. Diels-Alder reactions of perfluorobicyclo[2.2.0]hex-1(4)-ene with aromatics. Organic Letters. 5: 2135-6. PMID 12790547 DOI: 10.1021/Ol0300524  0.752
2003 Lou Y, He Y, Kendall JT, Lemal DM. New syntheses and chemistry of hexafluorotropone. The Journal of Organic Chemistry. 68: 3891-5. PMID 12737568 DOI: 10.1021/Jo020723W  0.582
2003 He Y, Junk CP, Cawley JJ, Lemal DM. A remarkable [2.2.2]propellane. Journal of the American Chemical Society. 125: 5590-1. PMID 12733871 DOI: 10.1021/Ja030077Y  0.76
2003 Richardson AD, Hedberg K, Junk CP, Lemal DM. Electron-diffraction and theoretical investigation of the molecular structure of octafluorobicyclo[2.2.0]hex-1(4)-ene in the gas phase: Another example of a molecule with an unusually long C(sp3)-C(sp3) single bond Journal of Physical Chemistry A. 107: 3064-3068. DOI: 10.1021/Jp022518Q  0.699
2003 He Y, Lemal DM. A photoprecursor for difluorocarbene Journal of Fluorine Chemistry. 119: 75-80. DOI: 10.1016/S0022-1139(02)00274-9  0.492
2002 Lou Y, Chang J, Jorgensen J, Lemal DM. Octachloroazulene. Journal of the American Chemical Society. 124: 15302-7. PMID 12487605 DOI: 10.1021/ja012051h  0.485
2002 Lombardi PJ, Gan Y, Lemal DM. Synthesis and chemistry of highly fluorinated oxepane-2,7-diols Collection of Czechoslovak Chemical Communications. 67: 1486-1492. DOI: 10.1135/Cccc20021486  0.741
2001 Lemal DM. Hexafluorobenzene photochemistry: wellspring of fluorocarbon structures. Accounts of Chemical Research. 34: 662-71. PMID 11513574 DOI: 10.1021/Ar960057J  0.356
2000 Liu Y, Lemal DM. Concerning the 'Wanzlick equilibrium' Tetrahedron Letters. 41: 599-602. DOI: 10.1016/S0040-4039(99)02161-9  0.699
1999 Liu Y, Lindner PE, Lemal DM. Thermodynamics of a diaminocarbene-tetraaminoethylene equilibrium [1] Journal of the American Chemical Society. 121: 10626-10627. DOI: 10.1021/Ja9922678  0.685
1999 Smith JR, Lemal DM. Highly fluorinated sulfonium enolates Journal of Fluorine Chemistry. 97: 145-148. DOI: 10.1016/S0022-1139(99)00041-X  0.312
1999 Takenaka NE, Hamlin R, Spector T, Junk CP, Lemal DM. 1,8H-perfluorocyclooctatetraene and its congeners. Dynamic equilibrium among four valence isomers Israel Journal of Chemistry. 39: 141-146. DOI: 10.1002/Ijch.199900017  0.735
1997 Lindner PE, Lemal DM. Energetics of fluoroalkene double bond isomerizations Journal of the American Chemical Society. 119: 3267-3273. DOI: 10.1021/Ja963789F  0.329
1997 Lindner PE, Lemal DM. Perfluorinated cyclic and acyclic keto-enol systems: A remarkable contrast Journal of the American Chemical Society. 119: 3259-3266. DOI: 10.1021/Ja963788N  0.362
1997 Kendall JT, Lemal DM. A mild and selective dehydrohalogenating agent Journal of Fluorine Chemistry. 83: 171-174. DOI: 10.1016/S0022-1139(97)00014-6  0.312
1996 Lindner PE, Lemal DM. Highly fluorinated cyclopentanones and their enols Journal of Organic Chemistry. 61: 5109-5115. DOI: 10.1021/Jo9602940  0.346
1996 Lindner PE, Correa RA, Gino J, Lemal DM. Novel keto-enol systems: Cyclobutane derivatives Journal of the American Chemical Society. 118: 2556-2563. DOI: 10.1021/Ja952998H  0.357
1996 Lindner PE, Lemal DM. Energetics of hydrate and hemiketal formation for highly fluorinated ketones Tetrahedron Letters. 37: 9165-9168. DOI: 10.1016/S0040-4039(96)02149-1  0.315
1994 Goldman GD, Roberts BE, Cohen TD, Lemal DM. 1,2- And 1,8-dichloroperfluorocyclooctatetraene: Stable bond-shift isomers Journal of Organic Chemistry. 59: 7421-7425. DOI: 10.1021/Jo00103A039  0.301
1994 Jing N, Lemal DM. The perfluoro-1,3,5-hexatrienes Journal of Organic Chemistry. 59: 1844-1848. DOI: 10.1021/Jo00086A040  0.354
1993 Correa RA, Jing N, Lemal DM. Interrelationships among C6F10 valence isomers Journal of Organic Chemistry. 58: 6406-6409. DOI: 10.1021/Jo00075A040  0.343
1991 Lemal DM, Klopotek DL, Wilterdink JL, Saunders WD. Carbonyl chemistry of tetrafluorocyclopentadienone Journal of Organic Chemistry. 56: 157-160. DOI: 10.1021/Jo00001A032  0.331
1991 Arnold-Stanton R, Lemal DM. Tandem nucleophilic additions of aryloxides Journal of Organic Chemistry. 56: 151-157. DOI: 10.1021/Jo00001A031  0.325
1991 Arnold-Stanton R, Lemal DM. Fluorinated bifunctional derivatives of bisphenol A Journal of Organic Chemistry. 56: 146-151. DOI: 10.1021/Jo00001A030  0.348
1990 Moklesur Rahman M, Secor BA, Morgan KM, Shafer PR, Lemal DM. Valence isomerization equilibria of highly fluorinated cycloocta-1,3,5-trienes Journal of the American Chemical Society. 112: 5986-5990. DOI: 10.1021/Ja00172A011  0.351
1990 Roberts BE, Goldman GD, Lemal DM. State-dependent photochemistry of highly fluorinated bicyclo[4.2.0]octa-2,4-dienes Journal of Fluorine Chemistry. 48: 353-360. DOI: 10.1016/S0022-1139(00)80220-1  0.379
1989 Dailey WP, Ralli P, Wasserman D, Lemal DM. 1,2-Cycloadditions to cis-5,6-dichlorohexafluorocyclohexa-1,3-diene Journal of Organic Chemistry. 54: 5516-5522. DOI: 10.1021/Jo00284A024  0.576
1989 Dailey WP, Correa RA, Harrison E, Lemal DM. 5,6-Dichlorohexafluorocyclohexa-1,3-dienes: Hexafluorobenzene synthons Journal of Organic Chemistry. 54: 5511-5516. DOI: 10.1021/Jo00284A023  0.551
1989 Soelch RR, McNierney E, Tannenbaum GA, Lemal DM. Synthesis and chemistry of highly fluorinated bicyclo[2.2.0]hexenones Journal of Organic Chemistry. 54: 5502-5511. DOI: 10.1021/Jo00284A022  0.346
1988 Rahman MM, Lemal DM, Dailey WP. Negative hyperconjugation. The rotation-inversion barrier in .alpha.-fluoramines Journal of the American Chemical Society. 110: 1964-1966. DOI: 10.1021/Ja00214A051  0.533
1988 Lemal DM, Goldman GD. Synthesis of azulene, a blue hydrocarbon Journal of Chemical Education. 65: 923-925. DOI: 10.1021/Ed065P923  0.312
1988 Rahman MM, Lemal DM, Dailey WP. Negative hyperconjugation. The rotation-inversion barrier in α-fluoramines Journal of the American Chemical Society. 110: 1964-1966.  0.498
1984 Dailey WP, Lemal DM. Perfluorotropilidene valence isomers and the perfluorotropylium ion Journal of the American Chemical Society. 106: 1169-1170. DOI: 10.1002/Chin.198421125  0.547
1982 Fox MA, Lemal DM, Johnson DW, Hohman JR. Photolysis of some chlorinated pyridazines Journal of Organic Chemistry. 47: 398-404. DOI: 10.1021/Jo00342A003  0.454
1980 Barefoot AC, Saunders WD, Buzby JM, Grayston MW, Lemal DM. Configurations and chemistry of the perfluorotricyclo[4.2.0.02,5]octa-3,7-dienes Journal of Organic Chemistry. 45: 4292-4295. DOI: 10.1021/Jo01310A008  0.324
1973 Brogli F, Eberbach W, Haselbach E, Heilbronner E, Hornung V, Lemal DM. Die Photoelektronen-Spektren des Tricyclo[4.2.1.02,5]nonadiens und seines 3,4-Diaza-Analogons. Ein Beitrag zur Kenntnis der Wechselwirkung zwischen den einsamen Elektronenpaaren dercis-konfigurierten Azogruppe Helvetica Chimica Acta. 56: 1933-1944. DOI: 10.1002/Hlca.19730560613  0.358
1972 Lemal DM, Dunlap LH. Kinetics and thermodynamics of (CCF3)6 valence isomer interconversions Journal of the American Chemical Society. 94: 6562-6564. DOI: 10.1021/Ja00773A061  0.324
1969 Lemal DM, Staros JV, Austel V. Valence isomers of (CCF3)6 [hexakis(trifluoromethyl)benzene] Journal of the American Chemical Society. 91: 3373-3374. DOI: 10.1021/Ja01040A047  0.679
1969 Lemal DM, Staros JV, Austel V. Valence isomers of (CCF3)6 [2] Journal of the American Chemical Society. 91: 3373-3374.  0.626
1966 Lemal DM, McGregor SD. Dienes from 3-Pyrrolines. A Stereospecific Deamination Journal of the American Chemical Society. 88: 1335-1336. DOI: 10.1021/Ja00958A056  0.363
1964 Lemal DM, Fry AJ. Photolysis of nortricyclanone tosylhydrazone sodium salt Journal of Organic Chemistry. 29: 1673-1676. DOI: 10.1021/Jo01030A003  0.51
1964 Lemal DM, Menger F, Coats E. The diazene-hydrazone rearrangement Journal of the American Chemical Society. 86: 2395-2401. DOI: 10.1021/Ja01066A021  0.494
1962 Lemal DM, Pacht PD, Woodward RB. The synthesis of L-()-mycarose and L-()-cladinose Tetrahedron. 18: 1275-1293. DOI: 10.1016/0040-4020(62)80009-X  0.453
1961 Lemal DM, Fry AJ. The preparation of silver fluoroborate: a warning Tetrahedron Letters. 2: 775-776.  0.455
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