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Tamio Hayashi - Publications

Affiliations: 
Kyoto University, Kyōto-shi, Kyōto-fu, Japan 
Area:
asymmetric organic reactions catalyzed by transition metal complexes
Website:
http://kuchem.kyoto-u.ac.jp/orgchem/Hayashi_Lab_En/Hayashi_CV.html

500 high-probability publications. We are testing a new system for linking publications to authors. You can help! If you notice any inaccuracies, please sign in and mark papers as correct or incorrect matches. If you identify any major omissions or other inaccuracies in the publication list, please let us know.

Year Citation  Score
2022 Wu ZH, Wang HY, Yang HL, Wei LH, Hayashi T, Duan WL. Secondary Phosphine Sulfide-Enabled Iridium-Catalyzed Asymmetric Allylic Substitution. Angewandte Chemie (International Ed. in English). PMID 36305853 DOI: 10.1002/anie.202213904  0.488
2022 Huang Y, Hayashi T. Chiral Diene Ligands in Asymmetric Catalysis. Chemical Reviews. PMID 35972018 DOI: 10.1021/acs.chemrev.2c00218  0.473
2021 Sun C, Meng H, Chen C, Wei H, Ming J, Hayashi T. Asymmetric Synthesis of Chiral Bicyclo[2.2.1]hepta-2,5-diene Ligands through Rhodium-Catalyzed Asymmetric Arylative Bis-cyclization of a 1,6-Enyne. Organic Letters. PMID 34374556 DOI: 10.1021/acs.orglett.1c02088  0.867
2021 Ng JS, Hayashi T. Asymmetric Synthesis of Fluorinated Allenes by Rhodium-Catalyzed Enantioselective Alkylation/Defluorination of Propargyl Difluorides with Alkylzincs. Angewandte Chemie (International Ed. in English). PMID 34310834 DOI: 10.1002/anie.202109290  0.393
2020 Chen J, Hayashi T. Asymmetric Synthesis of Alkylzincs by Rhodium-Catalyzed Enantioselective Arylative Cyclization of 1,6-Enynes with Arylzincs. Angewandte Chemie (International Ed. in English). PMID 32673429 DOI: 10.1002/Anie.202008770  0.619
2020 Yonesaki R, Kusagawa I, Morimoto H, Hayashi T, Ohshima T. Rhodium(I)/Chiral Diene-Catalyzed Enantioselective Addition of Boronic Acids to N-Unsubstituted Isatin-Derived Ketimines. Chemistry, An Asian Journal. PMID 31903690 DOI: 10.1002/Asia.201901745  0.563
2020 Xing J, Zhu W, Ye B, Lu T, Hayashi T, Dou X. Rhodium-Catalyzed Diverse Arylation of 2,5-Dihydrofuran: Controllable Divergent Synthesis via Four Pathways Acs Catalysis. 10: 2958-2963. DOI: 10.1021/Acscatal.0C00265  0.472
2019 Wang Z, Xue F, Hayashi T. Synthesis of Arylacetaldehydes by Iridium-Catalyzed Arylation of Vinylene Carbonate with Arylboronic Acids. Angewandte Chemie (International Ed. in English). PMID 31192491 DOI: 10.1002/Anie.201906148  0.448
2019 Yin L, Xing J, Wang Y, Shen Y, Lu T, Hayashi T, Dou X. Enantioselective Synthesis of 3,3'-Diaryl-SPINOLS by Rh-Catalyzed Asymmetric Arylation-BF3-Promoted Spirocyclization Reactions. Angewandte Chemie (International Ed. in English). PMID 30600869 DOI: 10.1002/Anie.201812266  0.797
2019 Hayashi T, Yamane M, Ohno A. Stereochemistry in Palladium-Catalyzed Cyclization Forming a Vinyldihydrofuran via a pi-Allylpalladium Intermediate. The Journal of Organic Chemistry. 62: 204-207. PMID 11671384 DOI: 10.1021/Jo9603901  0.516
2018 Ming J, Shi Q, Hayashi T. Addition of arylstannanes to alkynes giving -alkenylarylstannanes catalysed cooperatively by a rhodium complex and zinc chloride. Chemical Science. 9: 7700-7704. PMID 30393531 DOI: 10.1039/C8Sc02459F  0.846
2018 Yao J, Yin L, Shen Y, Lu T, Hayashi T, Dou X. Catalytic Asymmetric Conjugate Arylation of γ,δ-Unsaturated β-Dicarbonyl Compounds. Organic Letters. PMID 30350648 DOI: 10.1021/Acs.Orglett.8B03021  0.742
2018 Ming J, Hayashi T. Rhodium-Catalyzed Arylzincation of Alkynes: Ligand Control of 1,4-Migration Selectivity. Organic Letters. PMID 30232894 DOI: 10.1021/Acs.Orglett.8B02668  0.829
2018 Xue F, Hayashi T. Asymmetric Synthesis of Axially Chiral 2-Aminobiaryls by Rhodium-Catalyzed Benzannulation of 1-Arylalkynes with 2-(Cyanomethyl)phenylboronates. Angewandte Chemie (International Ed. in English). PMID 29944769 DOI: 10.1002/Anie.201806324  0.595
2018 Yin L, Zhang D, Xing J, Wang Y, Wu C, Lu T, Chen Y, Hayashi T, Dou X. Access to Chiral HWE Reagents by Rhodium-Catalyzed Asymmetric Arylation of γ,δ-Unsaturated β-Ketophosphonates. The Journal of Organic Chemistry. PMID 29715022 DOI: 10.1021/Acs.Joc.8B00952  0.775
2018 Zhu Y, Mao Y, Mei H, Pan Y, Han J, Soloshonok VA, Hayashi T. Palladium-Catalyzed Asymmetric Allylic Alkylations of Colby Pro-Enolates with MBH Carbonates: Enantioselective Access to Quaternary C-F Oxindoles. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 29683211 DOI: 10.1002/Chem.201801670  0.429
2017 Wang Z, Hayashi T. Rhodium-Catalyzed Enantioposition Selective Hydroarylation of Divinylphosphine Oxides with Arylboroxines. Angewandte Chemie (International Ed. in English). PMID 29266704 DOI: 10.1002/Anie.201712572  0.342
2017 Lim KM, Hayashi T. Dynamic Kinetic Resolution in Rhodium-Catalyzed Asymmetric Arylation of Phospholene Oxides. Journal of the American Chemical Society. PMID 28587450 DOI: 10.1021/Jacs.7B04570  0.521
2017 Fukazawa T, Ando Y, Ohmori K, Hayashi T, Suzuki K. Enantioselective Access to Bicyclo[3.2.1]octadienone Skeleton: Total Syntheses of (+)-Engelharquinone and Its Epoxide. Organic Letters. PMID 28248526 DOI: 10.1021/Acs.Orglett.7B00464  0.568
2017 Zhou B, Li K, Jiang C, Lu Y, Hayashi T. Modified Amino Acid-Derived Phosphine-Imine Ligands for Palladium-Catalyzed Asymmetric Arylation of Cyclic N -Sulfonyl Imines Advanced Synthesis & Catalysis. 359: 1969-1975. DOI: 10.1002/Adsc.201700003  0.655
2016 Ming J, Hayashi T. Aryloxymethyltrifluoroborates for Rhodium-Catalyzed Asymmetric Conjugate Arylation. o-Methoxyarylation through 1,4-Rhodium Shift. Organic Letters. 18: 6452-6455. PMID 27978666 DOI: 10.1021/Acs.Orglett.6B03347  0.857
2016 Huang Y, Hayashi T. Rhodium-Catalyzed Asymmetric Arylation/Defluorination of 1-(Trifluoromethyl)alkenes Forming Enantioenriched 1,1-Difluoroalkenes. Journal of the American Chemical Society. PMID 27627581 DOI: 10.1021/Jacs.6B07844  0.526
2016 Lu Y, Zhou B, Jiang C, Gandi VR, Hayashi T. Palladium-Catalyzed Asymmetric Arylation for the Preparation of Trifluoromethylated/Perfluoroalkylated 2-Quinazolinone Derivatives with High (>99%) Enantioselectivity. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 27377667 DOI: 10.1002/Chem.201603105  0.719
2016 Dou X, Lu Y, Hayashi T. Base-Free Conditions for Rhodium-Catalyzed Asymmetric Arylation To Produce Stereochemically Labile α-Aryl Ketones. Angewandte Chemie (International Ed. in English). PMID 27100902 DOI: 10.1002/Anie.201601709  0.811
2016 Dou X, Hayashi T. Synthesis of Planar Chiral Shvo Catalysts for Asymmetric Transfer Hydrogenation Advanced Synthesis & Catalysis. 358: 1054-1058. DOI: 10.1002/Adsc.201501162  0.543
2015 Dou X, Huang Y, Hayashi T. Asymmetric Conjugate Alkynylation of Cyclic α,β-Unsaturated Carbonyl Compounds with a Chiral Diene Rhodium Catalyst. Angewandte Chemie (International Ed. in English). PMID 26636764 DOI: 10.1002/Anie.201509778  0.757
2015 Huang Y, Hayashi T. Asymmetric Synthesis of Triarylmethanes by Rhodium-Catalyzed Enantioselective Arylation of Diarylmethylamines with Arylboroxines. Journal of the American Chemical Society. 137: 7556-9. PMID 26035738 DOI: 10.1021/Jacs.5B03277  0.609
2015 Xue F, Zhao J, Hor TS, Hayashi T. Nickel-catalyzed three-component domino reactions of aryl Grignard reagents, alkynes, and aryl halides producing tetrasubstituted alkenes. Journal of the American Chemical Society. 137: 3189-92. PMID 25714497 DOI: 10.1021/Ja513166W  0.536
2015 Lim KM, Hayashi T. Rhodium-catalyzed asymmetric arylation of allyl sulfones under the conditions of isomerization into alkenyl sulfones. Journal of the American Chemical Society. 137: 3201-4. PMID 25706689 DOI: 10.1021/Jacs.5B00216  0.61
2015 He Q, So CM, Bian Z, Hayashi T, Wang J. Rhodium/chiral diene-catalyzed asymmetric 1,4-addition of arylboronic acids to chromones: a highly enantioselective pathway for accessing chiral flavanones. Chemistry, An Asian Journal. 10: 540-3. PMID 25585883 DOI: 10.1002/Asia.201403290  0.579
2015 Su C, Tandiana R, Balapanuru J, Tang W, Pareek K, Nai CT, Hayashi T, Loh KP. Tandem catalysis of amines using porous graphene oxide. Journal of the American Chemical Society. 137: 685-90. PMID 25551171 DOI: 10.1021/Ja512470T  0.388
2015 Xue F, Zhao J, Hor TSA, Hayashi T. Nickel-Catalyzed Three-Component Domino Reactions Synfacts. 11: 535-535. DOI: 10.1055/S-0034-1380635  0.432
2015 Zhou B, Ming So C, Lu Y, Hayashi T. A chiral bicyclo[2.2.2]octa-2,5-diene ligand substituted with the ferrocenyl group and its use for rhodium-catalyzed asymmetric 1,4-addition reactions Organic Chemistry Frontiers. 2: 127-132. DOI: 10.1039/C4Qo00292J  0.629
2015 Huang Y, Hayashi T. Asymmetric Synthesis of Triarylmethanes by Rhodium-Catalyzed Enantioselective Arylation of Diarylmethylamines with Arylboroxines Journal of the American Chemical Society. 137: 7556-7559. DOI: 10.1021/jacs.5b03277  0.505
2015 Sauer DF, Himiyama T, Tachikawa K, Fukumoto K, Onoda A, Mizohata E, Inoue T, Bocola M, Schwaneberg U, Hayashi T, Okuda J. A Highly Active Biohybrid Catalyst for Olefin Metathesis in Water: Impact of a Hydrophobic Cavity in a β-Barrel Protein Acs Catalysis. 5: 7519-7522. DOI: 10.1021/Acscatal.5B01792  0.305
2015 Gandi VR, Lu Y, Hayashi T. A chiral phosphine-olefin ligand derived from l-hydroxyproline and its use in the rhodium-catalyzed asymmetric 1,4-addition Tetrahedron Asymmetry. DOI: 10.1016/J.Tetasy.2015.05.004  0.675
2015 Suzuki R, Yanuma H, Hayashi T, Yamada H, Usuki T. Syntheses of natural and deuterated desmosines via palladium-catalyzed cross-coupling reactions "this paper is dedicated to Professor Koji Nakanishi on the occasion of his 90th birthday." Tetrahedron. 71: 1851-1862. DOI: 10.1016/j.tet.2015.01.064  0.315
2014 Jiang C, Lu Y, Hayashi T. High performance of a palladium phosphinooxazoline catalyst in the asymmetric arylation of cyclic N-sulfonyl ketimines. Angewandte Chemie (International Ed. in English). 53: 9936-9. PMID 25044954 DOI: 10.1002/Anie.201406147  0.689
2014 Huang Y, Li Y, Leung PH, Hayashi T. Asymmetric synthesis of P-stereogenic diarylphosphinites by palladium-catalyzed enantioselective addition of diarylphosphines to benzoquinones. Journal of the American Chemical Society. 136: 4865-8. PMID 24635477 DOI: 10.1021/Ja501007T  0.616
2014 Takeda M, Takatsu K, Shintani R, Hayashi T. Synthesis of quaternary carbon stereocenters by copper-catalyzed asymmetric allylic substitution of allyl phosphates with arylboronates. The Journal of Organic Chemistry. 79: 2354-67. PMID 24601661 DOI: 10.1021/Jo500068P  0.597
2014 Shirakawa E, Tamakuni F, Kusano E, Uchiyama N, Konagaya W, Watabe R, Hayashi T. Single-electron-transfer-induced coupling of arylzinc reagents with aryl and alkenyl halides. Angewandte Chemie (International Ed. in English). 53: 521-5. PMID 24282160 DOI: 10.1002/Anie.201308200  0.477
2014 Shirakawa E, Okura K, Uchiyama N, Murakami T, Hayashi T. Improved Procedure for Single-electron-transfer-induced Grignard Cross-coupling Reaction Chemistry Letters. 43: 922-924. DOI: 10.1246/Cl.140155  0.41
2014 Han JW, Hayashi T. Palladium-catalyzed asymmetric hydrosilylation of styrenes with trichlorosilane Tetrahedron Asymmetry. 25: 479-484. DOI: 10.1016/J.Tetasy.2014.03.002  0.581
2013 Sawano T, Ou K, Nishimura T, Hayashi T. Cobalt-catalyzed asymmetric addition of silylacetylenes to 1,1-disubstituted allenes. The Journal of Organic Chemistry. 78: 8986-93. PMID 23984966 DOI: 10.1021/Jo401604N  0.561
2013 So CM, Kume S, Hayashi T. Rhodium-catalyzed asymmetric hydroarylation of 3-pyrrolines giving 3-arylpyrrolidines: protonation as a key step. Journal of the American Chemical Society. 135: 10990-3. PMID 23865491 DOI: 10.1021/Ja406169S  0.534
2013 Nishimura T, Ebe Y, Fujimoto H, Hayashi T. Asymmetric synthesis of gem-diaryl substituted cyclic sulfamidates and sulfamides by rhodium-catalyzed arylation of cyclic ketimines. Chemical Communications (Cambridge, England). 49: 5504-6. PMID 23661175 DOI: 10.1039/C3Cc42071J  0.628
2013 Takeda M, Shintani R, Hayashi T. Enantioselective synthesis of α-tri- and α-tetrasubstituted allylsilanes by copper-catalyzed asymmetric allylic substitution of allyl phosphates with silylboronates. The Journal of Organic Chemistry. 78: 5007-17. PMID 23647080 DOI: 10.1021/Jo400888B  0.578
2013 Shirakawa E, Watabe R, Murakami T, Hayashi T. Single electron transfer-induced cross-coupling reaction of alkenyl halides with aryl Grignard reagents. Chemical Communications (Cambridge, England). 49: 5219-21. PMID 23628923 DOI: 10.1039/C3Cc41923A  0.403
2013 Nishimura T, Ebe Y, Hayashi T. Iridium-catalyzed [3 + 2] annulation of cyclic N-sulfonyl ketimines with 1,3-dienes via C-H activation. Journal of the American Chemical Society. 135: 2092-5. PMID 23351145 DOI: 10.1021/Ja311968D  0.429
2013 Nishimura T, Noishiki A, Ebe Y, Hayashi T. Hydroxorhodium/chiral diene complexes as effective catalysts for the asymmetric arylation of 3-aryl-3-hydroxyisoindolin-1-ones. Angewandte Chemie (International Ed. in English). 52: 1777-80. PMID 23307761 DOI: 10.1002/Anie.201208593  0.561
2013 Uchiyama N, Shirakawa E, Hayashi T. Single electron transfer-induced Grignard cross-coupling involving ion radicals as exclusive intermediates. Chemical Communications (Cambridge, England). 49: 364-6. PMID 23188064 DOI: 10.1039/C2Cc37643A  0.358
2013 Shirakawa E, Nishikawa R, Uchiyama N, Hata I, Hayashi T. Copper-catalyzed Oxidative C–C, C–O, and C–N Bond Forming Reactions of Arylboronic Acids Chemistry Letters. 42: 269-271. DOI: 10.1246/Cl.2013.269  0.366
2013 Nishimura T, Nagamoto M, Ebe Y, Hayashi T. Enantioselective [3 + 2] annulation via C–H activation between cyclic N-acyl ketimines and 1,3-dienes catalyzed by iridium/chiral diene complexes Chemical Science. 4: 4499. DOI: 10.1039/C3Sc52379A  0.583
2013 Park HS, Han JW, Shintani R, Hayashi T. Asymmetric hydrosilylation of cyclohexa-1,3-diene with trichlorosilane by palladium catalysts coordinated with chiral phosphoramidite ligands Tetrahedron: Asymmetry. 24: 418-420. DOI: 10.1016/j.tetasy.2013.02.002  0.451
2013 Nishimura T, Takiguchi Y, Maeda Y, Hayashi T. ChemInform Abstract: Rhodium-Catalyzed Asymmetric Cycloisomerization of 1,6-Ene-ynamides. Cheminform. 44: no-no. DOI: 10.1002/chin.201338161  0.482
2013 Nishimura T, Takiguchi Y, Maeda Y, Hayashi T. Rhodium-Catalyzed Asymmetric Cycloisomerization of 1,6-Ene-ynamides Advanced Synthesis & Catalysis. 355: 1374-1382. DOI: 10.1002/Adsc.201300148  0.579
2012 Sawano T, Ashouri A, Nishimura T, Hayashi T. Cobalt-catalyzed asymmetric 1,6-addition of (triisopropylsilyl)-acetylene to α,β,γ,δ-unsaturated carbonyl compounds. Journal of the American Chemical Society. 134: 18936-9. PMID 23131028 DOI: 10.1021/Ja309756K  0.461
2012 Shintani R, Maciver EE, Tamakuni F, Hayashi T. Rhodium-catalyzed asymmetric synthesis of silicon-stereogenic dibenzooxasilines via enantioselective transmetalation. Journal of the American Chemical Society. 134: 16955-8. PMID 22998336 DOI: 10.1021/Ja3076555  0.508
2012 Shintani R, Ito T, Nagamoto M, Otomo H, Hayashi T. Palladium-catalyzed asymmetric synthesis of 2-pyrrolidinones with a quaternary carbon stereocenter. Chemical Communications (Cambridge, England). 48: 9936-8. PMID 22935617 DOI: 10.1039/C2Cc35259A  0.616
2012 Imazaki Y, Shirakawa E, Ueno R, Hayashi T. Ruthenium-catalyzed transformation of aryl and alkenyl triflates to halides. Journal of the American Chemical Society. 134: 14760-3. PMID 22916734 DOI: 10.1021/Ja307771D  0.437
2012 Nishimura T, Takiguchi Y, Hayashi T. Effect of chiral diene ligands in rhodium-catalyzed asymmetric addition of arylboronic acids to α,β-unsaturated sulfonyl compounds. Journal of the American Chemical Society. 134: 9086-9. PMID 22616790 DOI: 10.1021/Ja303109Q  0.541
2012 Shintani R, Moriya K, Hayashi T. Palladium-catalyzed desymmetrization of silacyclobutanes with alkynes: enantioselective synthesis of silicon-stereogenic 1-sila-2-cyclohexenes and mechanistic considerations. Organic Letters. 14: 2902-5. PMID 22612531 DOI: 10.1021/Ol301191U  0.53
2012 Sawano T, Ou K, Nishimura T, Hayashi T. Cobalt-catalyzed asymmetric addition of silylacetylenes to oxa- and azabenzonorbornadienes. Chemical Communications (Cambridge, England). 48: 6106-8. PMID 22576160 DOI: 10.1039/C2Cc31880F  0.548
2012 Shintani R, Ito T, Hayashi T. Palladium-catalyzed synthesis of 4-oxaspiro[2.4]heptanes via central attack of oxygen nucleophiles to π-allylpalladium intermediates. Organic Letters. 14: 2410-3. PMID 22530604 DOI: 10.1021/Ol300852V  0.546
2012 Shintani R, Otomo H, Ota K, Hayashi T. Palladium-catalyzed asymmetric synthesis of silicon-stereogenic dibenzosiloles via enantioselective C-H bond functionalization. Journal of the American Chemical Society. 134: 7305-8. PMID 22506681 DOI: 10.1021/Ja302278S  0.466
2012 Nishimura T, Noishiki A, Tsui GC, Hayashi T. Asymmetric synthesis of (triaryl)methylamines by rhodium-catalyzed addition of arylboroxines to cyclic N-sulfonyl ketimines. Journal of the American Chemical Society. 134: 5056-9. PMID 22394013 DOI: 10.1021/Ja300697C  0.786
2012 Gosiewska S, Raskatov JA, Shintani R, Hayashi T, Brown JM. The origins of enantioselectivity in Rh-diene complex catalysed arylation of cyclohex-2-enones. Chemistry (Weinheim An Der Bergstrasse, Germany). 18: 80-4. PMID 22161767 DOI: 10.1002/Chem.201102421  0.523
2012 Nishimura T, Noishiki A, Hayashi T. Electronic tuning of chiral diene ligands in iridium-catalyzed asymmetric 1,6-addition of arylboroxines to δ-aryl-α,β,γ,δ-unsaturated ketones. Chemical Communications (Cambridge, England). 48: 973-5. PMID 22159574 DOI: 10.1039/C2Cc16973H  0.553
2012 Shirakawa E, Ikeda D, Masui S, Yoshida M, Hayashi T. Iron-copper cooperative catalysis in the reactions of alkyl Grignard reagents: exchange reaction with alkenes and carbometalation of alkynes. Journal of the American Chemical Society. 134: 272-9. PMID 22128888 DOI: 10.1021/Ja206745W  0.464
2012 Shirakawa E, Hayashi Y, Itoh K, Watabe R, Uchiyama N, Konagaya W, Masui S, Hayashi T. Cross-coupling of aryl Grignard reagents with aryl iodides and bromides through S(RN)1 pathway. Angewandte Chemie (International Ed. in English). 51: 218-21. PMID 22083948 DOI: 10.1002/Anie.201106086  0.395
2012 Shirakawa E, Hayashi T. Transition-metal-free Coupling Reactions of Aryl Halides Chemistry Letters. 41: 130-134. DOI: 10.1246/Cl.2012.130  0.373
2012 Sasaki K, Nishimura T, Shintani R, Kantchev EAB, Hayashi T. Rhodium/diene-catalyzed tandem 1,4-shift/1,4-addition of (E)-1,2-diphenylethenylboronic acid to enones: density functional theory modeling and asymmetric catalysis Chemical Science. 3: 1278. DOI: 10.1039/C2Sc01093C  0.426
2012 Nishimura T, Ashouri A, Ebe Y, Maeda Y, Hayashi T. Rhodium/chiral diene-catalyzed asymmetric methylation of N-sulfonylarylimines with trimethylboroxine Tetrahedron: Asymmetry. 23: 655-658. DOI: 10.1016/J.Tetasy.2012.04.021  0.573
2012 Sasaki K, Hayashi T. Asymmetric conjugate addition of cis-2-arylethenylboronic acids catalyzed by chiral diene/rhodium complexes: 1,4-rhodium shift from alkenylrhodium to arylrhodium intermediates Tetrahedron: Asymmetry. 23: 373-380. DOI: 10.1016/j.tetasy.2012.03.004  0.398
2012 Narui R, Hayashi S, Otomo H, Shintani R, Hayashi T. (S)-Phenylalanine-derived chiral phosphorus–olefin ligands in rhodium-catalyzed asymmetric 1,4-addition reactions Tetrahedron: Asymmetry. 23: 284-293. DOI: 10.1016/j.tetasy.2012.02.007  0.489
2012 Hayashi T, Kumada M. Asymmetric Coupling Reactions Asymmetric Synthesis. 147-169. DOI: 10.1016/B978-0-08-092493-9.50010-4  0.527
2012 Nishimura T, Ashouri A, Ebe Y, Maeda Y, Hayashi T. ChemInform Abstract: Rhodium/Chiral Diene-Catalyzed Asymmetric Methylation of N-Sulfonylarylimines with Trimethylboroxine. Cheminform. 43: no-no. DOI: 10.1002/chin.201249064  0.369
2012 Imazaki Y, Shirakawa E, Hayashi T. ChemInform Abstract: Ruthenium-Catalyzed Reaction of Alkenyl Triflates with Zinc Thiolates. Cheminform. 43: no-no. DOI: 10.1002/chin.201217042  0.4
2011 Uchiyama N, Shirakawa E, Nishikawa R, Hayashi T. Iron-catalyzed oxidative coupling of arylboronic acids with benzene derivatives through homolytic aromatic substitution. Chemical Communications (Cambridge, England). 47: 11671-3. PMID 21952466 DOI: 10.1039/C1Cc14694G  0.378
2011 Shintani R, Moriya K, Hayashi T. Palladium-catalyzed enantioselective desymmetrization of silacyclobutanes: construction of silacycles possessing a tetraorganosilicon stereocenter. Journal of the American Chemical Society. 133: 16440-3. PMID 21936508 DOI: 10.1021/Ja208621X  0.595
2011 Nishimura T, Kasai A, Nagaosa M, Hayashi T. Rhodium-catalyzed asymmetric addition of arylboroxines to β-alkoxyacrylate esters. Chemical Communications (Cambridge, England). 47: 10488-90. PMID 21850290 DOI: 10.1039/C1Cc14150C  0.461
2011 Nishimura T, Sawano T, Ou K, Hayashi T. Cobalt-catalyzed conjugate addition of silylacetylenes to α,β-unsaturated ketones. Chemical Communications (Cambridge, England). 47: 10142-4. PMID 21833385 DOI: 10.1039/C1Cc14098A  0.435
2011 Shintani R, Takatsu K, Takeda M, Hayashi T. Copper-catalyzed asymmetric allylic substitution of allyl phosphates with aryl- and alkenylboronates. Angewandte Chemie (International Ed. in English). 50: 8656-9. PMID 21793143 DOI: 10.1002/Anie.201103581  0.529
2011 Shirakawa E, Masui S, Narui R, Watabe R, Ikeda D, Hayashi T. Iron-catalyzed aryl- and alkenyllithiation of alkynes and its application to benzosilole synthesis. Chemical Communications (Cambridge, England). 47: 9714-6. PMID 21789294 DOI: 10.1039/C1Cc11989C  0.425
2011 Nishimura T, Maeda Y, Hayashi T. Chiral diene-phosphine tridentate ligands for rhodium-catalyzed asymmetric cycloisomerization of 1,6-enynes. Organic Letters. 13: 3674-7. PMID 21688864 DOI: 10.1021/Ol2013236  0.573
2011 Shintani R, Takeda M, Soh YT, Ito T, Hayashi T. Rhodium-catalyzed asymmetric addition of potassium organotrifluoroborates to N-sulfonyl ketimines. Organic Letters. 13: 2977-9. PMID 21574614 DOI: 10.1021/Ol200958Q  0.483
2011 Takatsu K, Shintani R, Hayashi T. Copper-catalyzed 1,4-addition of organoboronates to alkylidene cyanoacetates: mechanistic insight and application to asymmetric catalysis. Angewandte Chemie (International Ed. in English). 50: 5548-52. PMID 21538738 DOI: 10.1002/Anie.201008196  0.431
2011 Shintani R, Narui R, Tsutsumi Y, Hayashi S, Hayashi T. Design and synthesis of new chiral phosphorus-olefin bidentate ligands and their use in the rhodium-catalyzed asymmetric addition of organoboroxines to N-sulfonyl imines. Chemical Communications (Cambridge, England). 47: 6123-5. PMID 21537505 DOI: 10.1039/C1Cc11823D  0.544
2011 Shintani R, Ikehata K, Hayashi T. Synthesis of nine-membered azlactones by palladium-catalyzed ring-expansion of γ-methylidene-δ-valerolactones with aziridines. The Journal of Organic Chemistry. 76: 4776-80. PMID 21528937 DOI: 10.1021/Jo2006158  0.455
2011 Shirakawa E, Zhang X, Hayashi T. Mizoroki-heck-type reaction mediated by potassium tert-butoxide. Angewandte Chemie (International Ed. in English). 50: 4671-4. PMID 21472936 DOI: 10.1002/Anie.201008220  0.384
2011 Shintani R, Moriya K, Hayashi T. Guiding the nitrogen nucleophile to the middle: palladium-catalyzed decarboxylative cyclopropanation of 2-alkylidenetrimethylene carbonates with isocyanates. Chemical Communications (Cambridge, England). 47: 3057-9. PMID 21301754 DOI: 10.1039/C0Cc05308B  0.462
2011 Morisaki Y, Imoto H, Hirano K, Hayashi T, Chujo Y. Synthesis of enantiomerically pure P-stereogenic diphosphacrowns and their palladium complexes. The Journal of Organic Chemistry. 76: 1795-803. PMID 21291270 DOI: 10.1021/Jo1024442  0.548
2011 Shirakawa E, Uchiyama N, Hayashi T. Iron-catalyzed oxidative coupling of alkylamides with arenes through oxidation of alkylamides followed by Friedel-Crafts alkylation. The Journal of Organic Chemistry. 76: 25-34. PMID 21158393 DOI: 10.1021/Jo102217M  0.431
2011 Shintani R, Hayashi T. Rhodium-catalyzed asymmetric 1,4-addition of sodium tetraarylborates to β,β-disubstituted α,β-unsaturated esters. Organic Letters. 13: 350-2. PMID 21128681 DOI: 10.1021/Ol102674Z  0.397
2011 Hayashi T, Sasaki K. Iron-catalyzed Pinacol Coupling of Aryl Ketones with a Phenyltitanium Reagent: A New Type of Catalytic Reaction Chemistry Letters. 40: 492-494. DOI: 10.1246/Cl.2011.492  0.523
2011 Nishimura T, Noishiki A, Hayashi T. Concise Synthesis of β,β-Diaryl Esters and Ketones from Ethynylcarbonyl Compounds by Rhodium-catalyzed Double Arylation with Arylboroxins Chemistry Letters. 40: 1285-1287. DOI: 10.1246/Cl.2011.1285  0.458
2011 Shirakawa E, Yoneda T, Moriya K, Ota K, Uchiyama N, Nishikawa R, Hayashi T. Iron-catalyzed Oxidative Coupling of Alkylamines with Arenes, Nitroalkanes, and 1,3-Dicarbonyl Compounds Chemistry Letters. 40: 1041-1043. DOI: 10.1246/Cl.2011.1041  0.313
2011 Shintani R, Moriya K, Hayashi T. Palladium-Catalyzed Enantioselective Synthesis of Silacyles Synfacts. 2011: 1284-1284. DOI: 10.1055/S-0031-1289409  0.569
2011 Shintani R, Takatsu K, Takeda M, Hayashi T. Asymmetric Allylic Substitution Synfacts. 2011: 1228-1228. DOI: 10.1055/S-0031-1289198  0.53
2011 Nishimura T, Maeda Y, Hayashi T. Chiral Tridentate Ligand for Rhodium-Catalyzed Cycloisomerization Synfacts. 2011: 978-978. DOI: 10.1055/S-0030-1261009  0.525
2011 Takatsu K, Shintani R, Hayashi T. Copper-Catalyzed 1,4-Addition of Organo-boronates to AlkylideneCyanoacetates Synfacts. 2011: 869-869. DOI: 10.1055/S-0030-1260731  0.381
2011 Ichikawa Y, Nishimura T, Hayashi T. Rhodium/Chiral Diene-Catalyzed Asymmetric Cyclopolymerization of Achiral 1,8-Diynes Organometallics. 30: 2342-2348. DOI: 10.1021/Om200088Q  0.542
2011 Nishimura T, Nagaosa M, Hayashi T. Rhodium-catalyzed oxidative alkynylation of acrylate esters with propargylic alcohols Tetrahedron Letters. 52: 2185-2187. DOI: 10.1016/J.Tetlet.2010.11.120  0.386
2011 Imazaki Y, Shirakawa E, Hayashi T. Ruthenium-catalyzed reaction of alkenyl triflates with zinc thiolates Tetrahedron. 67: 10212-10215. DOI: 10.1016/J.Tet.2011.09.145  0.519
2011 Berthon G, Hayashi T. ChemInform Abstract: Rhodium-and Palladium-Catalyzed Asymmetric Conjugate Additions Cheminform. 42: no-no. DOI: 10.1002/chin.201150251  0.512
2010 Shirakawa E, Itoh K, Higashino T, Hayashi T. tert-Butoxide-mediated arylation of benzene with aryl halides in the presence of a catalytic 1,10-phenanthroline derivative. Journal of the American Chemical Society. 132: 15537-9. PMID 20961045 DOI: 10.1021/Ja1080822  0.507
2010 Sasaki K, Hayashi T. Rhodium-catalyzed asymmetric conjugate addition of arylboroxines to borylalkenes: asymmetric synthesis of β-arylalkylboranes. Angewandte Chemie (International Ed. in English). 49: 8145-7. PMID 20857477 DOI: 10.1002/Anie.201004980  0.484
2010 Shintani R, Takeda M, Tsuji T, Hayashi T. Rhodium-catalyzed asymmetric arylation of N-tosyl ketimines. Journal of the American Chemical Society. 132: 13168-9. PMID 20809623 DOI: 10.1021/Ja106114Q  0.561
2010 Nishimura T, Makino H, Nagaosa M, Hayashi T. Rhodium-catalyzed enantioselective 1,6-addition of arylboronic acids to enynamides: asymmetric synthesis of axially chiral allenylsilanes. Journal of the American Chemical Society. 132: 12865-7. PMID 20806919 DOI: 10.1021/Ja1066509  0.596
2010 Nishimura T, Maeda Y, Hayashi T. Asymmetric cyclopropanation of alkenes with dimethyl diazomalonate catalyzed by chiral diene-rhodium complexes. Angewandte Chemie (International Ed. in English). 49: 7324-7. PMID 20799309 DOI: 10.1002/Anie.201003775  0.582
2010 Shintani R, Takatsu K, Hayashi T. Copper-catalyzed asymmetric addition of arylboronates to isatins: a catalytic cycle involving alkoxocopper intermediates. Chemical Communications (Cambridge, England). 46: 6822-4. PMID 20725672 DOI: 10.1039/C0Cc01635G  0.562
2010 Nishimura T, Sawano T, Tokuji S, Hayashi T. Rhodium-catalyzed asymmetric conjugate alkynylation of nitroalkenes. Chemical Communications (Cambridge, England). 46: 6837-9. PMID 20717608 DOI: 10.1039/C0Cc02181D  0.575
2010 Shintani R, Soh YT, Hayashi T. Rhodium-catalyzed asymmetric arylation of azomethine imines. Organic Letters. 12: 4106-9. PMID 20715836 DOI: 10.1021/Ol101700V  0.575
2010 Nishimura T, Yasuhara Y, Sawano T, Hayashi T. Iridium/chiral diene-catalyzed asymmetric 1,6-addition of arylboroxines to alpha,beta,gamma,delta-unsaturated carbonyl compounds. Journal of the American Chemical Society. 132: 7872-3. PMID 20481533 DOI: 10.1021/Ja1034842  0.491
2010 Shintani R, Tsuji T, Park S, Hayashi T. Mechanistic investigation of the palladium-catalyzed decarboxylative cyclization of gamma-methylidene-delta-valerolactones with isocyanates: kinetic studies and origin of the site selectivity in the nucleophilic attack at a (pi-allyl)palladium. Journal of the American Chemical Society. 132: 7508-13. PMID 20450179 DOI: 10.1021/Ja1023223  0.507
2010 Shintani R, Isobe S, Takeda M, Hayashi T. Rhodium-catalyzed asymmetric synthesis of spirocarbocycles: arylboron reagents as surrogates of 1,2-dimetalloarenes. Angewandte Chemie (International Ed. in English). 49: 3795-8. PMID 20397178 DOI: 10.1002/Anie.201000937  0.554
2010 Shintani R, Takeda M, Nishimura T, Hayashi T. Chiral tetrafluorobenzobarrelenes as effective ligands for rhodium-catalyzed asymmetric 1,4-addition of arylboroxines to beta,beta-disubstituted alpha,beta-unsaturated ketones. Angewandte Chemie (International Ed. in English). 49: 3969-71. PMID 20391549 DOI: 10.1002/Anie.201000467  0.313
2010 Yasuhara Y, Nishimura T, Hayashi T. Rhodium-catalyzed aryl- and alkylation-oligomerization of alkynoates with organoboron reagents giving salicylates. Chemical Communications (Cambridge, England). 46: 2130-2. PMID 20221515 DOI: 10.1039/C000402B  0.557
2010 Shintani R, Tsuji T, Park S, Hayashi T. Palladium-catalyzed intramolecular decarboxylative allylic arylation of alpha-aryl-gamma-methylidene-delta-valerolactones. Chemical Communications (Cambridge, England). 46: 1697-9. PMID 20177620 DOI: 10.1039/B924416F  0.523
2010 Nishimura T, Kawamoto T, Nagaosa M, Kumamoto H, Hayashi T. Chiral tetrafluorobenzobarrelene ligands for the rhodium-catalyzed asymmetric cycloisomerization of oxygen- and nitrogen-bridged 1,6-enynes. Angewandte Chemie (International Ed. in English). 49: 1638-41. PMID 20127779 DOI: 10.1002/Anie.200906792  0.472
2010 Nishimura T, Wang J, Nagaosa M, Okamoto K, Shintani R, Kwong FY, Yu WY, Chan AS, Hayashi T. Rhodium-catalyzed asymmetric addition of arylboronic acids to beta-phthaliminoacrylate esters toward the synthesis of beta-amino acids. Journal of the American Chemical Society. 132: 464-5. PMID 20028118 DOI: 10.1021/Ja909642H  0.356
2010 Nagano T, Jia Z, Li X, Yan M, Lu G, Chan ASC, Hayashi T. Redox Catalysis of Halide Ion for Formal Cross-dehydrogenative Coupling: Bromide Ion-catalyzed Direct Oxidative α-Acetoxylation of Ketones Chemistry Letters. 39: 929-931. DOI: 10.1246/Cl.2010.929  0.39
2010 Nishimura T, Hayashi T, Makino H, Nagaosa M. Rhodium-Catalyzed Asymmetric 1,6-Addition of Enynamides Synfacts. 2010: 1384-1384. DOI: 10.1055/S-0030-1258901  0.604
2010 Shintani R, Hayashi T, Takeda M, Tsuji T. Asymmetric Arylation ofN-Tosyl Ketimines Synfacts. 2010: 1387-1387. DOI: 10.1055/S-0030-1258893  0.581
2010 Nishimura T, Hayashi T, Maeda Y. Asymmetric Cyclopropanation Using Dimethyl Diazomalonate Synfacts. 2010: 1373-1373. DOI: 10.1055/S-0030-1258888  0.549
2010 Shintani R, Hayashi T, Takatsu K. Asymmetric Addition to Isatins Synfacts. 2010: 1258-1258. DOI: 10.1055/S-0030-1258591  0.517
2010 Nishimura T, Hayashi T, Sawano T, Tokuji S. Asymmetric Alkynylation of Nitroalkenes Synfacts. 2010: 1271-1271. DOI: 10.1055/S-0030-1258590  0.53
2010 Nishimura T, Hayashi T, Yasuhara Y, Sawano T. Iridium-Catalyzed Enantioselective 1,6-Addition Synfacts. 2010: 1019-1019. DOI: 10.1055/S-0030-1257993  0.619
2010 Shintani R, Isobe S, Takeda M, Hayashi T. Rhodium-Catalyzed Asymmetric Synthesis of Spirocarbocycles Synfacts. 2010: 785-785. DOI: 10.1055/S-0029-1220075  0.537
2010 Nishimura T, Kawamoto T, Nagaosa M, Kumamoto H, Hayashi T. Rhodium-Catalyzed Asymmetric Cycloisomerization of 1,6-Enynes Synfacts. 2010: 555-555. DOI: 10.1055/S-0029-1219643  0.605
2010 Nishimura T, Sawano T, Hayashi T. Rhodium-Catalyzed Asymmetric Conjugate Alkynylation Synfacts. 2010: 78-78. DOI: 10.1055/S-0029-1218512  0.585
2010 Han JW, Hayashi T. Palladium-catalyzed asymmetric hydrosilylation of 1,3-dienes Tetrahedron: Asymmetry. 21: 2193-2197. DOI: 10.1016/J.Tetasy.2010.07.034  0.558
2010 Guo X, Sawano T, Nishimura T, Hayashi T. Rhodium-catalyzed enantioselective alkynylative cyclization of allenyl aldehydes with terminal alkynes Tetrahedron: Asymmetry. 21: 1730-1736. DOI: 10.1016/J.Tetasy.2010.04.039  0.606
2010 Zhang Z, Lu G, Chen M, Lin N, Li Y, Hayashi T, Chan AS. Organocatalytic asymmetric Mannich-type reaction of N-sulfonylimines with isocyanoacetate leading to optically active 2-imidazoline-4-carboxylates Tetrahedron: Asymmetry. 21: 1715-1721. DOI: 10.1016/J.Tetasy.2010.04.029  0.555
2010 Guo X, Sawano T, Nishimura T, Hayashi T. ChemInform Abstract: Rhodium-Catalyzed Enantioselective Alkynylative Cyclization of Allenyl Aldehydes with Terminal Alkynes. Cheminform. 42: no-no. DOI: 10.1002/chin.201102102  0.501
2010 Shintani R, Tsuji T, Park S, Hayashi T. ChemInform Abstract: Palladium-Catalyzed Intramolecular Decarboxylative Allylic Arylation of α-Aryl-γ-methylidene-δ-valerolactones. Cheminform. 41: no-no. DOI: 10.1002/chin.201028040  0.408
2010 Shintani R, Hayashi T. ChemInform Abstract: Chiral Diene Ligands for Asymmetric Catalysis Cheminform. 41: no-no. DOI: 10.1002/chin.201026238  0.431
2010 Shintani R, Murakami M, Tsuji T, Tanno H, Hayashi T. ChemInform Abstract: Palladium-Catalyzed Decarboxylative [4 + 3] Cyclization of γ-Methylidene-δ-valerolactones with 1,1-Dicyanocyclopropanes Cheminform. 41. DOI: 10.1002/chin.201019055  0.426
2010 Nishimura T, Sawano T, Hayashi T. ChemInform Abstract: Asymmetric Synthesis of β-Alkynyl Aldehydes by Rhodium-Catalyzed Conjugate Alkynylation. Cheminform. 41. DOI: 10.1002/chin.201004049  0.476
2010 Shintani R, Hayshi S, Murakami M, Takeda M, Hayashi T. ChemInform Abstract: Stereoselective Synthesis of Spirooxindoles by Palladium-Catalyzed Decarboxylative Cyclization of γ-Methylidene-δ-valerolactones with Isatins. Cheminform. 41: no-no. DOI: 10.1002/chin.201001109  0.464
2010 Hayashi T, Takahashi M, Takaya Y, Ogasawara M. ChemInform Abstract: Catalytic Cycle of Rhodium-Catalyzed Asymmetric 1,4-Addition of Organoboronic Acids. Arylrhodium, Oxa-π-allylrhodium, and Hydroxorhodium Intermediates. Cheminform. 33: no-no. DOI: 10.1002/chin.200237033  0.409
2010 Senda T, Ogasawara M, Hayashi T. ChemInform Abstract: Rhodium-Catalyzed Asymmetric 1,4-Addition of Organoboron Reagents to 5,6-Dihydro-2(1H)-pyridinones. Asymmetric Synthesis of 4-Aryl-2-piperidinones. Cheminform. 33: no-no. DOI: 10.1002/chin.200209147  0.416
2010 Hayashi T, Senda T, Takaya Y, Ogasawara M. ChemInform Abstract: Rhodium-Catalyzed Asymmetric 1,4-Addition to 1-Alkenylphosphonates. Cheminform. 31: no-no. DOI: 10.1002/chin.200011039  0.491
2010 Takaya Y, Senda T, Kurushima H, Ogasawara M, Hayashi T. ChemInform Abstract: Rhodium-Catalyzed Asymmetric 1,4-Addition of Arylboron Reagents to α,β-Unsaturated Esters. Cheminform. 31: no-no. DOI: 10.1002/chin.200008045  0.33
2010 Takaya Y, Ogasawara M, Hayashi T. ChemInform Abstract: Rhodium-Catalyzed Asymmetric 1,4-Addition of Arylboron Compounds Generated in situ from Aryl Bromides. Cheminform. 30: no-no. DOI: 10.1002/chin.199948034  0.367
2010 Uozumi Y, Kyota H, Kato K, Ogasawara M, Hayashi T. ChemInform Abstract: Design and Preparation of 3,3′-Disubstituted 2,2′-Bis(oxazolyl)-1,1′-binaphthyls (boxax): New Chiral Bis(oxazoline) Ligands for Catalytic Asymmetric Wacker-Type Cyclization. Cheminform. 30: no-no. DOI: 10.1002/chin.199933127  0.538
2010 Hayashi T. ChemInform Abstract: Asymmetric Reactions Catalyzed by Palladium-MOP Complexes Cheminform. 30: no-no. DOI: 10.1002/chin.199913341  0.447
2010 TAKAYA Y, OGASAWARA M, HAYASHI T. ChemInform Abstract: Rhodium-Catalyzed Asymmetric 1,4-Addition of 2-Alkenyl-1,3,2-benzodioxaboroles to α,β-Unsaturated Ketones. Cheminform. 30: no-no. DOI: 10.1002/chin.199906033  0.321
2010 TAKAYA Y, OGASAWARA M, HAYASHI T, SAKAI M, MIYAURA N. ChemInform Abstract: Rhodium-Catalyzed Asymmetric 1,4-Addition of Aryl- and Alkenylboronic Acids to Enones. Cheminform. 29: no-no. DOI: 10.1002/chin.199840067  0.399
2010 UOZUMI Y, DANJO H, HAYASHI T. ChemInform Abstract: New Amphiphilic Palladium-Phosphine Complexes Bound to Solid Supports: Preparation and Use for Catalytic Allylic Substitution in Aqueous Media. Cheminform. 28: no-no. DOI: 10.1002/chin.199734048  0.509
2010 SOLOSHONOK VA, KACHAROV AD, AVILOV DV, HAYASHI T. ChemInform Abstract: Transition Metal Catalyzed Diastereoselective Aldol Reactions of Prochiral Ketones with Methyl Isocyanoacetate. Cheminform. 28: no-no. DOI: 10.1002/chin.199707144  0.314
2010 SOLOSHONOK VA, KACHAROV AD, HAYASHI T. ChemInform Abstract: Gold(I)-Catalyzed Asymmetric Aldol Reactions of Isocyanoacetic Acid Derivatives with Fluoroaryl Aldehydes. Cheminform. 27: no-no. DOI: 10.1002/chin.199615035  0.405
2010 OZAWA F, SUGAWARA M, HAYASHI T. ChemInform Abstract: A New Reactive System for Catalytic Bis-Silylation of Acetylenes and Olefins. Cheminform. 26: no-no. DOI: 10.1002/chin.199503080  0.385
2010 HAYASHI T, IWAMURA H, UOZUMI Y. ChemInform Abstract: Optically Active Allylsilanes. Part 19. Asymmetric Synthesis of Allylsilanes by Palladium-Catalyzed Asymmetric Reduction of Allylic Carbonates with Formic Acid. Cheminform. 25: no-no. DOI: 10.1002/chin.199447040  0.525
2010 SOLOSHONOK VA, HAYASHI T, ISHIKAWA K, NAGASHIMA N. ChemInform Abstract: Highly Diastereoselective Aldol Reaction of Fluoroalkyl Aryl Ketones with Methyl Isocyanoacetate Catalyzed by Silver(I)/Triethylamine. Cheminform. 25: no-no. DOI: 10.1002/chin.199426150  0.421
2010 HAYASHI T. ChemInform Abstract: Asymmetric Allylic Substitution and Grignard Cross-Coupling Cheminform. 25: no-no. DOI: 10.1002/chin.199417301  0.313
2010 UOZUMI Y, HAYASHI T. ChemInform Abstract: The Development and Application of a New Class of Monodentate Optically Active Phosphines (MOP′s). Asymmetric Hydrosilylation of Olefins Catalyzed by Palladium-MOP Complexes Cheminform. 25: no-no. DOI: 10.1002/chin.199413307  0.494
2010 MATSUMOTO Y, OHNO A, HAYASHI T. ChemInform Abstract: Optically Active Allylsilanes. Part 17. Preparation of Silafunctional Allylsilanes by Palladium-Catalyzed Silylation of Allylic Chlorides with 1,1-Dichloro-1-phenyl-2,2,2-trimethyldisilane. Cheminform. 25: no-no. DOI: 10.1002/chin.199405102  0.406
2010 OZAWA F, KUBO A, HAYASHI T. ChemInform Abstract: Catalytic Asymmetric Heck Reaction Cheminform. 24: no-no. DOI: 10.1002/chin.199349306  0.413
2010 MATSUMOTO Y, NAITO M, HAYASHI T. ChemInform Abstract: Palladium(0)-Catalyzed Hydroboration of 1-Buten-3-ynes: Preparation of Allenylboranes. Cheminform. 23: no-no. DOI: 10.1002/chin.199243114  0.471
2010 HAYASHI T, UOZUMI Y, YAMAZAKI A, SAWAMURA M, HAMASHIMA H, ITO Y. ChemInform Abstract: Silver(I)-Catalyzed Asymmetric Aldol Rection of Isocyanoacetate. Cheminform. 23: no-no. DOI: 10.1002/chin.199213208  0.547
2010 HAYASHI T, HENGRASMEE S, MATSUMOTO Y. ChemInform Abstract: Optically Active Allylsilanes. Part 16. Selective Synthesis of Z-1-Ethylidene-2-silylcycloalkanes by Palladium-Catalyzed Hydrosilylation of 1-Vinylcycloalkenes. Cheminform. 22: no-no. DOI: 10.1002/chin.199135192  0.366
2009 Shirakawa E, Imazaki Y, Hayashi T. Ruthenium-catalyzed transformation of alkenyl triflates to alkenyl halides. Chemical Communications (Cambridge, England). 5088-90. PMID 20448955 DOI: 10.1039/B907761H  0.449
2009 Shintani R, Murakami M, Tsuji T, Tanno H, Hayashi T. Palladium-catalyzed decarboxylative [4 + 3] cyclization of gamma-methylidene-delta-valerolactones with 1,1-dicyanocyclopropanes. Organic Letters. 11: 5642-5. PMID 19908855 DOI: 10.1021/Ol902326S  0.518
2009 Nishimura T, Kumamoto H, Nagaosa M, Hayashi T. The concise synthesis of chiral tfb ligands and their application to the rhodium-catalyzed asymmetric arylation of aldehydes. Chemical Communications (Cambridge, England). 5713-5. PMID 19774245 DOI: 10.1039/B911118B  0.587
2009 Nishimura T, Sawano T, Hayashi T. Asymmetric synthesis of beta-alkynyl aldehydes by rhodium-catalyzed conjugate alkynylation. Angewandte Chemie (International Ed. in English). 48: 8057-9. PMID 19768830 DOI: 10.1002/Anie.200904486  0.407
2009 Shintani R, Tsutsumi Y, Nagaosa M, Nishimura T, Hayashi T. Sodium tetraarylborates as effective nucleophiles in rhodium/diene-catalyzed 1,4-addition to beta,beta-disubstituted alpha,beta-unsaturated ketones: catalytic asymmetric construction of quaternary carbon stereocenters. Journal of the American Chemical Society. 131: 13588-9. PMID 19728707 DOI: 10.1021/Ja905432X  0.449
2009 Okamoto K, Hayashi T, Rawal VH. Electronic and steric tuning of chiral diene ligands for rhodium-catalyzed asymmetric arylation of imines. Chemical Communications (Cambridge, England). 4815-7. PMID 19652790 DOI: 10.1039/B904624K  0.577
2009 Shintani R, Hayashi SY, Murakami M, Takeda M, Hayashi T. Stereoselective synthesis of spirooxindoles by palladium-catalyzed decarboxylative cyclization of gamma-methylidene-delta-valerolactones with isatins. Organic Letters. 11: 3754-6. PMID 19637858 DOI: 10.1021/Ol901348F  0.594
2009 Shintani R, Nakatsu H, Takatsu K, Hayashi T. Rhodium-catalyzed asymmetric [5+2] cycloaddition of alkyne-vinylcyclopropanes. Chemistry (Weinheim An Der Bergstrasse, Germany). 15: 8692-4. PMID 19637169 DOI: 10.1002/Chem.200901463  0.609
2009 Nishimura T, Tokuji S, Sawano T, Hayashi T. Rhodium-catalyzed asymmetric conjugate alkynylation of enones with alkynylsilanols. Organic Letters. 11: 3222-5. PMID 19572581 DOI: 10.1021/Ol901119D  0.524
2009 Kawamoto T, Hirabayashi S, Guo XX, Nishimura T, Hayashi T. Rhodium-catalyzed asymmetric hydroalkoxylation and hydrosulfenylation of diphenylphosphinylallenes. Chemical Communications (Cambridge, England). 3528-30. PMID 19521596 DOI: 10.1039/B900976K  0.562
2009 Shirakawa E, Ikeda D, Ozawa T, Watanabe S, Hayashi T. Iron-catalyzed carbolithiation of alkynes having no heteroatoms. Chemical Communications (Cambridge, England). 1885-7. PMID 19319434 DOI: 10.1039/B900345B  0.324
2009 Shintani R, Murakami M, Hayashi T. Stereoselective synthesis of nipecotic acid derivatives via palladium-catalyzed decarboxylative cyclization of gamma-methylidene-delta-valerolactones with imines. Organic Letters. 11: 457-9. PMID 19072063 DOI: 10.1021/Ol802569Q  0.504
2009 Shintani R, Ichikawa Y, Takatsu K, Chen FX, Hayashi T. Tuning the chiral environment of C2-symmetric diene ligands: development of 3,7-disubstituted bicyclo[3.3.1]nona-2,6-dienes. The Journal of Organic Chemistry. 74: 869-73. PMID 19053597 DOI: 10.1021/Jo802437H  0.559
2009 Park S, Shintani R, Hayashi T. Palladium-catalyzed Decarboxylative [4+1] Cyclization of γ-Methylidene-δ-valerolactones with Isocyanides Chemistry Letters. 38: 204-205. DOI: 10.1246/Cl.2009.204  0.519
2009 Shintani R, Hayashi T, Tsutsumi Y, Nagaosa M, Nishimura T. Synthesis of All-Carbon Quaternary Stereocenters Synfacts. 2009: 1376-1376. DOI: 10.1055/S-0029-1218255  0.331
2009 Shintani R, Hayashi S-, Murakami M, Takeda M, Hayashi T. Stereoselective Synthesis of Spirooxindoles Synfacts. 2009: 1079-1079. DOI: 10.1055/S-0029-1217903  0.436
2009 Shintani R, Hayashi T, Murakami M. Palladium-Catalyzed Decarboxylative Cyclization Synfacts. 2009: 0286-0286. DOI: 10.1055/S-0028-1087749  0.576
2009 Shintani R, Hayashi T, Ichikawa Y, Takatsu K, Chen F. Rhodium-Catalyzed 1,4-Addition of Boronic Acids to α,β-Unsaturated Ketones Synfacts. 2009: 0288-0288. DOI: 10.1055/S-0028-1087748  0.401
2009 Shintani R, Park S, Shirozu F, Murakami M, Hayashi T. Palladium-Catalyzed Synthesis of Chiral Lactams from RacemicLactones Synfacts. 2009: 165-165. DOI: 10.1055/S-0028-1087631  0.572
2009 Nishimura T, Ichikawa Y, Hayashi T, Onishi N, Shiotsuki M, Masuda T. Asymmetric Polymerization of Achiral Arylacetylenes Giving Helical Polyacetylenes in the Presence of a Rhodium Catalyst with aC2-Symmetric Tetrafluorobenzobarrelene Ligand Organometallics. 28: 4890-4893. DOI: 10.1021/Om9003797  0.537
2009 Park S, Shintani R, Hayashi T. ChemInform Abstract: Palladium-Catalyzed Decarboxylative [4 + 1] Cyclization of γ-Methylidene-δ-valerolactones with Isocyanides. Cheminform. 40. DOI: 10.1002/chin.200934093  0.432
2009 Shintani R, Park S, Shirozu F, Murakami M, Hayashi T. ChemInform Abstract: Palladium-Catalyzed Asymmetric Decarboxylative Lactamization of γ-Methylidene-δ-valerolactones with Isocyanates: Conversion of Racemic Lactones to Enantioenriched Lactams. Cheminform. 40. DOI: 10.1002/chin.200918141  0.481
2008 Shintani R, Park S, Shirozu F, Murakami M, Hayashi T. Palladium-catalyzed asymmetric decarboxylative lactamization of gamma-methylidene-delta-valerolactones with isocyanates: conversion of racemic lactones to enantioenriched lactams. Journal of the American Chemical Society. 130: 16174-5. PMID 18998676 DOI: 10.1021/Ja807662B  0.607
2008 Okamoto K, Hayashi T, Rawal VH. Simple chiral diene ligands provide high enantioselectivities in transition-metal-catalyzed conjugate addition reactions. Organic Letters. 10: 4387-9. PMID 18771267 DOI: 10.1021/Ol801931V  0.604
2008 Nishimura T, Tsurumaki E, Kawamoto T, Guo XX, Hayashi T. Rhodium-catalyzed asymmetric ring-opening alkynylation of azabenzonorbornadienes. Organic Letters. 10: 4057-60. PMID 18710240 DOI: 10.1021/Ol801549T  0.517
2008 Nishimura T, Guo XX, Hayashi T. Rhodium-catalyzed asymmetric addition of terminal alkynes to diarylphosphinylallenes. Chemistry, An Asian Journal. 3: 1505-10. PMID 18464238 DOI: 10.1002/Asia.200800042  0.53
2008 Shirakawa E, Ikeda D, Yamaguchi S, Hayashi T. Fe-Cu cooperative catalysis in the isomerization of alkyl Grignard reagents. Chemical Communications (Cambridge, England). 1214-6. PMID 18309421 DOI: 10.1039/B717717H  0.319
2008 Shintani R, Takatsu K, Hayashi T. Rhodium-catalyzed kinetic resolution of tertiary homoallyl alcohols via stereoselective carbon-carbon bond cleavage. Organic Letters. 10: 1191-3. PMID 18303902 DOI: 10.1021/Ol800120P  0.454
2008 Sörgel S, Tokunaga N, Sasaki K, Okamoto K, Hayashi T. Rhodium/chiral diene-catalyzed asymmetric 1,4-addition of arylboronic acids to arylmethylene cyanoacetates. Organic Letters. 10: 589-92. PMID 18217766 DOI: 10.1021/Ol702879U  0.546
2008 Nishimura T, Guo XX, Uchiyama N, Katoh T, Hayashi T. Steric tuning of silylacetylenes and chiral phosphine ligands for rhodium-catalyzed asymmetric conjugate alkynylation of enones. Journal of the American Chemical Society. 130: 1576-7. PMID 18197670 DOI: 10.1021/Ja710540S  0.585
2008 Shintani R, Takatsu K, Katoh T, Nishimura T, Hayashi T. Rhodium-catalyzed rearrangement of aryl bis(alkynyl) carbinols to 3-alkynyl-1-indanones. Angewandte Chemie (International Ed. in English). 47: 1447-9. PMID 18188852 DOI: 10.1002/Anie.200704818  0.599
2008 Shintani R, Murakami M, Hayashi T. γ-Methylidene-δ-valerolactones as a coupling partner for cycloaddition: Palladium-catalyzed [4+3] cycloaddition with nitrones Pure and Applied Chemistry. 80: 1135-1140. DOI: 10.1351/Pac200880051135  0.494
2008 Nishimura T, Nagaosa M, Hayashi T. Chiral Tetrafluorobenzobarrelenes as Highly Efficient Ligands for the Rhodium-catalyzed Asymmetric 1,4-Addition of Arylboronic Acids Chemistry Letters. 37: 860-861. DOI: 10.1246/Cl.2008.860  0.533
2008 Hayashi T, Sasaki K. Platinum-catalyzed 1,4-Addition of Arylboronic Acids to β-Substituted α,β-Unsaturated Ketones Chemistry Letters. 37: 842-843. DOI: 10.1246/Cl.2008.842  0.411
2008 Shintani R, Hayashi T. Ruthenium-catalyzed 1,4-Addition of Organoboronic Acids to α,β-Unsaturated Ketones Chemistry Letters. 37: 724-725. DOI: 10.1246/Cl.2008.724  0.431
2008 Shirakawa E, Imazaki Y, Hayashi T. Cobalt-catalyzed Coupling of Alkenyl Triflates with Aryl and Alkenyl Grignard Reagents Chemistry Letters. 37: 654-655. DOI: 10.1246/Cl.2008.654  0.411
2008 Nakao Y, Takeda M, Chen J, Hiyama T, Ichikawa Y, Shintani R, Hayashi T. Rhodium-catalyzed Addition of Organo[2-(hydroxymethyl)phenyl]dimethylsilanes to Arenesulfonylimines Chemistry Letters. 37: 290-291. DOI: 10.1246/Cl.2008.290  0.553
2008 Okamoto K, Hayashi T. Platinum-catalyzed Generation of Silylenes from Hydrodisilanes and Their Addition to α,β-Unsaturated Ketones Chemistry Letters. 37: 108-109. DOI: 10.1246/Cl.2008.108  0.469
2008 Nishimura T, Guo X-, Uchiyama N, Katoh T, Hayashi T. Rhodium-Catalyzed Conjugate Addition of Sterically Bulky Silylacetylene to Enones Synfacts. 2008: 512-512. DOI: 10.1055/S-2008-1072640  0.577
2008 Sörgel S, Tokunaga N, Sasaki K, Okamoto K, Hayashi T. Enantioselective Addition of Organoboron Nucleophiles to Conjugated Alkenes Synfacts. 2008: 389-389. DOI: 10.1055/S-2008-1042783  0.583
2008 Nishimura T, Hayashi T, Yasuhara Y, Nagaosa M. New Chiral Diene Ligands for Iridium-Catalyzed [3+2] Annulation Synfacts. 2008: 1190-1190. DOI: 10.1055/S-0028-1083447  0.511
2008 Nishimura T, Hayashi T, Tsurumaki E, Kawamoto T, Guo X. Enantioselective Desymmetrization via Ring Opening of Strained Alkenes Synfacts. 2008: 1191-1191. DOI: 10.1055/S-0028-1083422  0.302
2008 Nishimura T, Yasuhara Y, Nagaosa M, Hayashi T. C2-Symmetric tetrafluorobenzobarrelenes as highly efficient ligands for the iridium-catalyzed asymmetric annulation of 1,3-dienes with 2-formylphenylboron reagents Tetrahedron-Asymmetry. 19: 1778-1783. DOI: 10.1016/J.Tetasy.2008.07.014  0.557
2008 Shirakawa E, Imazaki Y, Hayashi T. ChemInform Abstract: Cobalt-Catalyzed Coupling of Alkenyl Triflates with Aryl and Alkenyl Grignard Reagents. Cheminform. 39. DOI: 10.1002/chin.200844043  0.399
2008 Nakao Y, Takeda M, Chen J, Hiyama T, Ichikawa Y, Shintani R, Hayashi T. ChemInform Abstract: Rhodium-Catalyzed Addition of Organo[2-(hydroxymethyl)phenyl]dimethylsilanes to Arenesulfonylimines. Cheminform. 39. DOI: 10.1002/chin.200830027  0.459
2008 Nishimura T, Guo X, Ohnishi K, Hayashi T. ChemInform Abstract: Rhodium-Catalyzed Hydroalkynylation of Internal Alkynes with Silylacetylenes: An Alkynylrhodium(I) Intermediate Generated from the Hydroxorhodium(I) Complex [Rh(OH)(binap)]2. Cheminform. 39. DOI: 10.1002/chin.200815176  0.374
2008 Shintani R, Murakami M, Hayashi T. ChemInform Abstract: γ-Methylidene-δ-valerolactones as a Coupling Partner for Cycloaddition: Palladium-Catalyzed [4 + 3] Cycloaddition with Nitrones. Cheminform. 39. DOI: 10.1002/chin.200807148  0.362
2007 Shintani R, Hayashi T. Preparation of arylzinc reagents and their use in the rhodium-catalyzed asymmetric 1,4-addition for the synthesis of 2-aryl-4-piperidones. Nature Protocols. 2: 2903-9. PMID 18007626 DOI: 10.1038/Nprot.2007.424  0.549
2007 Shintani R, Park S, Hayashi T. Palladium-catalyzed synthesis of spiro[2.4]heptanes: ligand-dependent position control in the nucleophilic attack to a pi-allylpalladium intermediate. Journal of the American Chemical Society. 129: 14866-7. PMID 17994753 DOI: 10.1021/Ja077236O  0.545
2007 Okamoto K, Hayashi T. Platinum-catalyzed addition of dimethylsilylene to beta-methyl alpha,beta-unsaturated ketones: gamma-silylation forming 1-oxa-2-silacyclohex-5-enes. Organic Letters. 9: 5067-9. PMID 17973489 DOI: 10.1021/Ol702357N  0.427
2007 Shirakawa E, Sato T, Imazaki Y, Kimura T, Hayashi T. Cobalt-catalyzed cross-coupling of alkynyl Grignard reagents with alkenyl triflates. Chemical Communications (Cambridge, England). 4513-5. PMID 17971973 DOI: 10.1039/B711884H  0.542
2007 Nishimura T, Katoh T, Takatsu K, Shintani R, Hayashi T. Rhodium-catalyzed asymmetric rearrangement of alkynyl alkenyl carbinols: synthetic equivalent to asymmetric conjugate alkynylation of enones. Journal of the American Chemical Society. 129: 14158-9. PMID 17963393 DOI: 10.1021/Ja076346S  0.532
2007 Shintani R, Ichikawa Y, Hayashi T, Chen J, Nakao Y, Hiyama T. Catalytic asymmetric synthesis of allylsilanes through rhodium/chiral diene-catalyzed 1,4-addition of alkenyl[2-(hydroxymethyl)phenyl]dimethylsilanes. Organic Letters. 9: 4643-5. PMID 17914835 DOI: 10.1021/Ol702125Q  0.541
2007 Shintani R, Murakami M, Hayashi T. Gamma-methylidene-delta-valerolactones as a coupling partner for cycloaddition: palladium-catalyzed [4 + 3] cycloaddition with nitrones. Journal of the American Chemical Society. 129: 12356-7. PMID 17894493 DOI: 10.1021/Ja073997F  0.518
2007 Shintani R, Sannohe Y, Tsuji T, Hayashi T. A cationic rhodium-chiral diene complex as a high-performance catalyst for the intramolecular asymmetric [4+2] cycloaddition of alkyne-1,3-dienes. Angewandte Chemie (International Ed. in English). 46: 7277-80. PMID 17722126 DOI: 10.1002/Anie.200702586  0.56
2007 Nakao Y, Chen J, Imanaka H, Hiyama T, Ichikawa Y, Duan WL, Shintani R, Hayashi T. Organo[2-(hydroxymethyl)phenyl]dimethylsilanes as mild and reproducible agents for rhodium-catalyzed 1,4-addition reactions. Journal of the American Chemical Society. 129: 9137-43. PMID 17602629 DOI: 10.1021/Ja071969R  0.579
2007 Shintani R, Park S, Duan WL, Hayashi T. Palladium-catalyzed asymmetric [3+3] cycloaddition of trimethylenemethane derivatives with nitrones. Angewandte Chemie (International Ed. in English). 46: 5901-3. PMID 17579913 DOI: 10.1002/Anie.200701529  0.571
2007 Nishimura T, Yasuhara Y, Hayashi T. Iridium-catalyzed [3 + 2] annulation of 1,3-dienes with ortho-carbonylated phenylboronic acids. A catalytic process involving regioselective 1,2-addition. Journal of the American Chemical Society. 129: 7506-7. PMID 17530761 DOI: 10.1021/Ja072369V  0.516
2007 Nishimura T, Katoh T, Hayashi T. Rhodium-catalyzed aryl transfer from trisubstituted aryl methanols to alpha,beta-unsaturated carbonyl compounds. Angewandte Chemie (International Ed. in English). 46: 4937-9. PMID 17508386 DOI: 10.1002/Anie.200700902  0.341
2007 Shintani R, Takatsu K, Hayashi T. Rhodium-catalyzed asymmetric synthesis of 3,3-disubstituted 1-indanones. Angewandte Chemie (International Ed. in English). 46: 3735-7. PMID 17407122 DOI: 10.1002/Anie.200700226  0.542
2007 Yamagami T, Shintani R, Shirakawa E, Hayashi T. Iron-catalyzed arylmagnesiation of aryl(alkyl)acetylenes in the presence of an N-heterocyclic carbene ligand. Organic Letters. 9: 1045-8. PMID 17291003 DOI: 10.1021/Ol063132R  0.52
2007 Nishimura T, Kawamoto T, Sasaki K, Tsurumaki E, Hayashi T. Rhodium-catalyzed asymmetric cyclodimerization of oxa- and azabicyclic alkenes. Journal of the American Chemical Society. 129: 1492-3. PMID 17283982 DOI: 10.1021/Ja068488C  0.6
2007 Duan WL, Iwamura H, Shintani R, Hayashi T. Chiral phosphine-olefin ligands in the rhodium-catalyzed asymmetric 1,4-addition reactions. Journal of the American Chemical Society. 129: 2130-8. PMID 17249670 DOI: 10.1021/Ja0671013  0.578
2007 Berthon-Gelloz G, Hayashi T. Expanding the C2-symmetric bicyclo[2.2.1]hepta-2,5-diene ligand family: concise synthesis and catalytic activity in rhodium-catalyzed asymmetric addition. The Journal of Organic Chemistry. 71: 8957-60. PMID 17081029 DOI: 10.1021/Jo061385S  0.572
2007 Shintani R, Yamagami T, Hayashi T. Rhodium-catalyzed multicomponent-coupling reactions involving a carborhodation-cross-coupling sequence. Organic Letters. 8: 4799-801. PMID 17020306 DOI: 10.1021/Ol061858H  0.443
2007 Shintani R, Hayashi T. Palladium-catalyzed [3 + 3] cycloaddition of trimethylenemethane with azomethine imines. Journal of the American Chemical Society. 128: 6330-1. PMID 16683793 DOI: 10.1021/Ja061662C  0.543
2007 Shintani R, Duan WL, Hayashi T. Rhodium-catalyzed asymmetric construction of quaternary carbon stereocenters: ligand-dependent regiocontrol in the 1,4-addition to substituted maleimides. Journal of the American Chemical Society. 128: 5628-9. PMID 16637617 DOI: 10.1021/Ja061430D  0.567
2007 Shintani R, Inoue M, Hayashi T. Rhodium-catalyzed asymmetric addition of aryl- and alkenylboronic acids to isatins. Angewandte Chemie (International Ed. in English). 45: 3353-6. PMID 16596682 DOI: 10.1002/Anie.200600392  0.48
2007 Ogasawara M, Sakamoto T, Ito A, Ge Y, Nakajima K, Takahashi T, Hayashi T. Unprecedented Formation of μ-Vinylidene Complexes from Phospharuthenocene and Acyl Chloride via Activation of the CO Double Bond Organometallics. 26: 6698-6700. DOI: 10.1021/Om701063K  0.412
2007 Duan W, Imazaki Y, Shintani R, Hayashi T. Asymmetric Construction of Chiral C—N Axes Through Rhodium-Catalyzed 1,4-Addition. Cheminform. 38. DOI: 10.1016/J.Tet.2007.05.025  0.58
2007 Duan W, Imazaki Y, Shintani R, Hayashi T. Asymmetric construction of chiral C–N axes through rhodium-catalyzed 1,4-addition Tetrahedron. 63: 8529-8536. DOI: 10.1016/j.tet.2007.05.025  0.45
2007 Shintani R, Takatsu K, Hayashi T. Rhodium-Catalyzed Asymmetric Synthesis of 3,3-Disubstituted 1-Indanones. Cheminform. 38. DOI: 10.1002/chin.200735107  0.452
2007 Duan W, Iwamura H, Shintani R, Hayashi T. Chiral Phosphine—Olefin Ligands in the Rhodium-Catalyzed Asymmetric 1,4-Addition Reactions. Cheminform. 38. DOI: 10.1002/chin.200724034  0.497
2007 Nishimura T, Kawamoto T, Sasaki K, Tsurumaki E, Hayashi T. Rhodium-Catalyzed Asymmetric Cyclodimerization of Oxa- and Azabicyclic Alkenes. Cheminform. 38. DOI: 10.1002/chin.200722092  0.531
2007 Shintani R, Duan W, Park S, Hayashi T. Rhodium-Catalyzed Isomerization of Unactivated Alkynes to 1,3-Dienes. Cheminform. 38. DOI: 10.1002/chin.200703039  0.52
2007 Nishimura T, Guo X, Ohnishi K, Hayashi T. Rhodium-Catalyzed Hydroalkynylation of Internal Alkynes with Silylacetylenes: An Alkynylrhodium(I) Intermediate Generated from the Hydroxorhodium(I) Complex [Rh(OH)(binap)]2 Advanced Synthesis & Catalysis. 349: 2669-2672. DOI: 10.1002/Adsc.200700334  0.496
2007 Tokunaga N, Hayashi T. Asymmetric 1,4-Addition of Organoboron Reagents to Quinone Monoketals Catalyzed by a Chiral Diene/Rhodium Complex: A New Synthetic Route to Enantioenriched 2-Aryltetralones. Cheminform. 38. DOI: 10.1002/Adsc.200600632  0.548
2006 Kina A, Yasuhara Y, Nishimura T, Iwamura H, Hayashi T. Kinetic studies prove high catalytic activity of a diene-rhodium complex in 1,4-addition of phenylboronic acid to alpha,beta-unsaturated ketones. Chemistry, An Asian Journal. 1: 707-11. PMID 17441112 DOI: 10.1002/Asia.200600184  0.397
2006 Shintani R, Duan WL, Park S, Hayashi T. Rhodium-catalyzed isomerization of unactivated alkynes to 1,3-dienes. Chemical Communications (Cambridge, England). 3646-7. PMID 17047793 DOI: 10.1039/B605368H  0.567
2006 Nishimura T, Yasuhara Y, Hayashi T. Highly selective 1,6-addition of aryl boronic acids to alpha,beta,gamma,delta-unsaturated carbonyl compounds catalyzed by an iridium complex. Angewandte Chemie (International Ed. in English). 45: 5164-6. PMID 16819750 DOI: 10.1002/Anie.200601719  0.36
2006 Kina A, Iwamura H, Hayashi T. A kinetic study on Rh/binap-catalyzed 1,4-addition of phenylboronic acid to enones: negative nonlinear effect caused by predominant homochiral dimer contribution. Journal of the American Chemical Society. 128: 3904-5. PMID 16551086 DOI: 10.1021/Ja060225V  0.459
2006 Shintani R, Yashio K, Nakamura T, Okamoto K, Shimada T, Hayashi T. Rhodium-catalyzed asymmetric synthesis of indanones: development of a new "axially chiral" bisphosphine ligand. Journal of the American Chemical Society. 128: 2772-3. PMID 16506735 DOI: 10.1021/Ja056584S  0.518
2006 Nishimura T, Yasuhara Y, Hayashi T. Asymmetric addition of dimethylzinc to N-tosylarylimines catalyzed by a rhodium-diene complex toward the synthesis of chiral 1-arylethylamines. Organic Letters. 8: 979-81. PMID 16494489 DOI: 10.1021/Ol060213E  0.551
2006 Nishimura T, Hirabayashi S, Yasuhara Y, Hayashi T. Rhodium-catalyzed asymmetric hydroarylation of diphenylphosphinylallenes with arylboronic acids. Journal of the American Chemical Society. 128: 2556-7. PMID 16492038 DOI: 10.1021/Ja058763F  0.562
2006 Chen FX, Kina A, Hayashi T. High performance of a chiral diene-rhodium catalyst for the asymmetric 1,4-addition of arylboroxines to alpha,beta-unsaturated ketones. Organic Letters. 8: 341-4. PMID 16408910 DOI: 10.1021/Ol052756E  0.494
2006 Kina A, Ueyama K, Hayashi T. Enantiomerically pure rhodium complexes bearing 1,5-diphenyl-1,5-cyclooctadiene as a chiral diene ligand. Their use as catalysts for asymmetric 1,4-addition of phenylzinc chloride. Organic Letters. 7: 5889-92. PMID 16354092 DOI: 10.1021/Ol0524914  0.536
2006 Shintani R, Yamagami T, Kimura T, Hayashi T. Asymmetric synthesis of 2-aryl-2,3-dihydro-4-quinolones by rhodium-catalyzed 1,4-addition of arylzinc reagents in the presence of chlorotrimethylsilane. Organic Letters. 7: 5317-9. PMID 16268567 DOI: 10.1021/Ol052257D  0.611
2006 Shintani R, Okamoto K, Hayashi T. Carbon-carbon bond-forming enantioselective synthesis of chiral organosilicon compounds by rhodium/chiral diene-catalyzed asymmetric 1,4-addition reaction. Organic Letters. 7: 4757-9. PMID 16209528 DOI: 10.1021/Ol051978+  0.466
2006 Shintani R, Duan WL, Nagano T, Okada A, Hayashi T. Chiral phosphine-olefin bidentate ligands in asymmetric catalysis: rhodium-catalyzed asymmetric 1,4-addition of aryl boronic acids to maleimides. Angewandte Chemie (International Ed. in English). 44: 4611-4. PMID 15973757 DOI: 10.1002/Anie.200501305  0.58
2006 Hayashi T, Yamamoto S, Tokunaga N. Rhodium-catalyzed asymmetric 1,6-addition of aryl zinc reagents to dienones. Angewandte Chemie (International Ed. in English). 44: 4224-7. PMID 15929152 DOI: 10.1055/S-2005-916019  0.579
2006 Chen G, Tokunaga N, Hayashi T. Rhodium-catalyzed asymmetric 1,4-addition of arylboronic acids to coumarins: asymmetric synthesis of (R)-tolterodine. Organic Letters. 7: 2285-8. PMID 15901190 DOI: 10.1021/Ol0507367  0.515
2006 Shintani R, Tsurusaki A, Okamoto K, Hayashi T. Highly chemo- and enantioselective arylative cyclization of alkyne-tethered electron-deficient olefins catalyzed by rhodium complexes with chiral dienes. Angewandte Chemie (International Ed. in English). 44: 3909-12. PMID 15900524 DOI: 10.1002/Anie.200500843  0.55
2006 Shintani R, Hayashi T. Rhodium-catalyzed addition of arylzinc reagents to aryl alkynyl ketones: synthesis of beta,beta-disubstituted indanones. Organic Letters. 7: 2071-3. PMID 15876057 DOI: 10.1021/Ol0506819  0.502
2006 Nagano T, Hayashi T. Iron-catalyzed oxidative homo-coupling of aryl Grignard reagents. Organic Letters. 7: 491-3. PMID 15673272 DOI: 10.1021/ol047509+  0.326
2006 Otomaru Y, Tokunaga N, Shintani R, Hayashi T. C2-symmetric bicyclo[3.3.1]nonadiene as a chiral ligand for rhodium-catalyzed asymmetric arylation of N-(4-nitrobenzenesulfonyl)arylimines. Organic Letters. 7: 307-10. PMID 15646984 DOI: 10.1021/Ol0476063  0.536
2006 Shintani R, Okamoto K, Hayashi T. Rhodium-Catalyzed Synthesis of Indenols by Regioselective Coupling of Alkynes with ortho-Carbonylated Arylboronic Acids. Cheminform. 37. DOI: 10.1246/Cl.2005.1294  0.519
2006 Hayashi T, Shintani R, Yashio K, Nakamura T, Okamoto K, Shimada T. Development of a New ‘Axially Chiral’ Bisphosphine Ligand Synfacts. 2006: 0686-0686. DOI: 10.1055/S-2006-941815  0.335
2006 Hayashi T, Nishimura T, Hirabayashi S, Yasuhara Y. Synthesis of Chiral Allylic Phosphine Oxides Synfacts. 2006: 0575-0575. DOI: 10.1055/S-2006-934475  0.44
2006 Shirakawa E, Yamagami T, Kimura T, Yamaguchi S, Hayashi T. Arylmagnesiation of Alkynes Catalyzed by Iron and Copper Complexes Synfacts. 2006: 265-265. DOI: 10.1055/S-2006-932004  0.332
2006 Shintani R, Yamagami T, Kimura T, Hayashi T. Rhodium-Catalyzed 1,4-Addition of Arylzinc Reagents Synfacts. 2006: 141-141. DOI: 10.1055/S-2005-924817  0.584
2006 Ogasawara M, Ito A, Yoshida K, Hayashi T. Synthesis of 2,5-Bis(binaphthyl)phospholes and Phosphametallocene Derivatives and Their Application in Palladium-Catalyzed Asymmetric Hydrosilylation Organometallics. 25: 2715-2718. DOI: 10.1021/Om060138B  0.58
2006 Tokunaga N, Hayashi T. Highly enantioselective 1,4-addition of arylzinc reagents to 3-arylpropenals catalyzed by a rhodium–binap complex in the presence of chlorotrimethylsilane Tetrahedron-Asymmetry. 17: 607-613. DOI: 10.1016/J.Tetasy.2006.01.036  0.568
2006 Shirakawa E, Yasuhara Y, Hayashi T. Nickel-Catalyzed Conjugate Addition of Arylboron Reagents to α,β-Unsaturated Carbonyl Compounds with the Aid of a Catalytic Amount of an Alkyne. Cheminform. 37. DOI: 10.1002/chin.200651056  0.328
2006 Shintani R, Hayashi T. Palladium-Catalyzed [3 + 3] Cycloaddition of Trimethylenemethane with Azomethine Imines. Cheminform. 37. DOI: 10.1002/chin.200639039  0.523
2006 Shintani R, Duan W, Hayashi T. Rhodium-Catalyzed Asymmetric Construction of Quaternary Carbon Stereocenters: Ligand-Dependent Regiocontrol in the 1,4-Addition to Substituted Maleimides. Cheminform. 37. DOI: 10.1002/chin.200638110  0.365
2006 Shintani R, Inoue M, Hayashi T. Rhodium-Catalyzed Asymmetric Addition of Aryl- and Alkenylboronic Acids to Isatins. Cheminform. 37. DOI: 10.1002/chin.200637109  0.377
2006 Shintani R, Yashio K, Nakamura T, Okamoto K, Shimada T, Hayashi T. Rhodium-Catalyzed Asymmetric Synthesis of Indanones: Development of a New “Axially Chiral” Bisphosphine Ligand. Cheminform. 37. DOI: 10.1002/chin.200629083  0.402
2006 Chen F, Kina A, Hayashi T. High Performance of a Chiral Diene—Rhodium Catalyst for the Asymmetric 1,4-Addition of Arylboroxines to α,β-Unsaturated Ketones. Cheminform. 37. DOI: 10.1002/chin.200621033  0.38
2006 Nishimura T, Yasuhara Y, Hayashi T. Highly Selective 1,6-Addition of Aryl Boronic Acids to α,β,γ,δ-Unsaturated Carbonyl Compounds Catalyzed by an Iridium Complex Angewandte Chemie. 118: 5288-5290. DOI: 10.1002/Ange.200601719  0.44
2005 Shirakawa E, Yamagami T, Kimura T, Yamaguchi S, Hayashi T. Arylmagnesiation of alkynes catalyzed cooperatively by iron and copper complexes. Journal of the American Chemical Society. 127: 17164-5. PMID 16332046 DOI: 10.1021/Ja0542136  0.387
2005 Shirakawa E, Otsuka H, Hayashi T. Reduction of alkynes into 1,2-dideuterioalkenes with hexamethyldisilane and deuterium oxide in the presence of a palladium catalyst. Chemical Communications (Cambridge, England). 5885-6. PMID 16317463 DOI: 10.1039/B512245G  0.435
2005 Ogasawara M, Nagano T, Hayashi T. A new route to methyl (R,E)-(-)-tetradeca-2,4,5-trienoate (pheromone of Acanthoscelides obtectus) utilizing a palladium-catalyzed asymmetric allene formation reaction. The Journal of Organic Chemistry. 70: 5764-7. PMID 15989370 DOI: 10.1021/Jo050684Z  0.507
2005 Shintani R, Kimura T, Hayashi T. Rhodium/diene-catalyzed asymmetric 1,4-addition of arylboronic acids to alpha,beta-unsaturated Weinreb amides. Chemical Communications (Cambridge, England). 3213-4. PMID 15968375 DOI: 10.1039/B502921J  0.389
2005 Otomaru Y, Okamoto K, Shintani R, Hayashi T. Preparation of C2-symmetric bicyclo[2.2.2]octa-2,5-diene ligands and their use for rhodium-catalyzed asymmetric 1,4-addition of arylboronic acids. The Journal of Organic Chemistry. 70: 2503-8. PMID 15787536 DOI: 10.1021/Jo047831Y  0.572
2005 Shintani R, Okamoto K, Hayashi T. Rhodium-catalyzed isomerization of alpha-arylpropargyl alcohols to indanones: involvement of an unexpected reaction cascade. Journal of the American Chemical Society. 127: 2872-3. PMID 15740121 DOI: 10.1021/Ja042582G  0.406
2005 Shintani R, Okamoto K, Otomaru Y, Ueyama K, Hayashi T. Catalytic asymmetric arylative cyclization of alkynals: phosphine-free rhodium/diene complexes as efficient catalysts. Journal of the American Chemical Society. 127: 54-5. PMID 15631445 DOI: 10.1021/Ja044021V  0.559
2005 Hayashi T, Kawai M, Tokunaga N. Asymmetric synthesis of diarylmethyl amines by rhodium-catalyzed asymmetric addition of aryl titanium reagents to imines. Angewandte Chemie (International Ed. in English). 43: 6125-8. PMID 15549756 DOI: 10.1002/Anie.200461338  0.595
2005 Shintani R, Ueyama K, Yamada I, Hayashi T. Chiral norbornadienes as efficient ligands for the rhodium-catalyzed asymmetric 1,4-addition of arylboronic acids to fumaric and maleic compounds. Organic Letters. 6: 3425-7. PMID 15355068 DOI: 10.1021/Ol048421Z  0.563
2005 Otomaru Y, Senda T, Hayashi T. Preparation of an amphiphilic resin-supported BINAP ligand and its use for rhodium-catalyzed asymmetric 1,4-addition of phenylboronic acid in water. Organic Letters. 6: 3357-9. PMID 15355051 DOI: 10.1021/Ol048695M  0.478
2005 Nagano T, Hayashi T. Iron-catalyzed Grignard cross-coupling with alkyl halides possessing beta-hydrogens. Organic Letters. 6: 1297-9. PMID 15070321 DOI: 10.1021/ol049779y  0.33
2005 Hayashi T, Tokunaga N, Inoue K. Rhodium-catalyzed asymmetric 1,6-addition of aryltitanates to enynones giving axially chiral allenes. Organic Letters. 6: 305-7. PMID 14723554 DOI: 10.1021/Ol036309F  0.615
2005 Hayashi T. Rhodium-Catalyzed Asymmetric 1,4-Addition of Organometallic Reagents Frontiers in Natural Product Chemistry. 1: 3-17. DOI: 10.2174/1574089054583713  0.615
2005 Hayashi T, Tokunaga N, Okamoto K, Shintani R. Asymmetric 1,4-Addition of Arylboronic Acids to α,β-Unsaturated Aldehydes Catalyzed by a Chiral Diene–Rhodium Complex Chemistry Letters. 34: 1480-1481. DOI: 10.1246/Cl.2005.1480  0.535
2005 Nagano T, Hayashi T. Silver-catalyzed alkyl-alkyl homo-coupling of Grignard reagents Chemistry Letters. 34: 1152-1153. DOI: 10.1246/Cl.2005.1152  0.491
2005 Hayashi T, Tokunaga N, Okamoto K, Shintani R. Chiral Diene-Rhodium Complex Catalyzed 1,4-Addition of Arylboronic Acids Synfacts. 2005: 313-313. DOI: 10.1055/S-2005-921641  0.511
2005 Chen G, Tokunaga N, Hayashi T. Synthesis of (R)-Tolterodine Synfacts. 2005: 279-279. DOI: 10.1055/S-2005-921603  0.341
2005 Nagano T, Hayashi T. Iron-catalyzed oxidative homo-coupling of aryl grignard reagents Organic Letters. 7: 491-493. DOI: 10.1021/Ol047509+  0.39
2005 Shintani R, Duan W, Okamoto K, Hayashi T. Palladium/chiral phosphine–olefin complexes: X-ray crystallographic analysis and the use in catalytic asymmetric allylic alkylation Tetrahedron: Asymmetry. 16: 3400-3405. DOI: 10.1016/J.Tetasy.2005.08.050  0.525
2005 Otomaru Y, Kina A, Shintani R, Hayashi T. C2-Symmetric bicyclo[3.3.1]nona-2,6-diene and bicyclo[3.3.2]deca-2,6-diene: new chiral diene ligands based on the 1,5-cyclooctadiene framework Tetrahedron: Asymmetry. 16: 1673-1679. DOI: 10.1016/J.Tetasy.2005.02.022  0.534
2005 Shintani R, Duan W, Nagano T, Okada A, Hayashi T. Chiral Phosphine—Olefin Bidentate Ligands in Asymmetric Catalysis: Rhodium-Catalyzed Asymmetric 1,4-Addition of Aryl Boronic Acids to Maleimides. Cheminform. 36. DOI: 10.1002/chin.200548026  0.484
2004 Tokunaga N, Otomaru Y, Okamoto K, Ueyama K, Shintani R, Hayashi T. C2-symmetric bicyclo[2.2.2]octadienes as chiral ligands: their high performance in rhodium-catalyzed asymmetric arylation of N-tosylarylimines. Journal of the American Chemical Society. 126: 13584-5. PMID 15493893 DOI: 10.1021/Ja044790E  0.509
2004 Cho YH, Kina A, Shimada T, Hayashi T. Asymmetric synthesis of axially chiral biaryls by nickel-catalyzed grignard cross-coupling of dibenzothiophenes. The Journal of Organic Chemistry. 69: 3811-23. PMID 15153014 DOI: 10.1021/Jo035880P  0.512
2004 Shintani R, Tokunaga N, Doi H, Hayashi T. A new entry of nucleophiles in rhodium-catalyzed asymmetric 1,4-addition reactions: addition of organozinc reagents for the synthesis of 2-aryl-4-piperidones. Journal of the American Chemical Society. 126: 6240-1. PMID 15149215 DOI: 10.1021/Ja048825M  0.558
2004 Hayashi T, Yamasaki K, Mimura M, Uozumi Y. Deuterium-labeling studies establishing stereochemistry at the oxypalladation step in Wacker-type oxidative cyclization of an o-allylphenol. Journal of the American Chemical Society. 126: 3036-7. PMID 15012118 DOI: 10.1021/Ja031946M  0.554
2004 Tokunaga N, Yoshida K, Hayashi T. Mechanistic studies on the catalytic cycle of rhodium-catalyzed asymmetric 1,4-addition of aryltitanate reagents to alpha,beta-unsaturated ketones. Proceedings of the National Academy of Sciences of the United States of America. 101: 5445-9. PMID 14981257 DOI: 10.1073/Pnas.0307260101  0.516
2004 Shimada T, Kina A, Hayashi T. A new synthetic route to enantiomerically pure axially chiral 2,2'-bipyridine N,N'-dioxides. Highly efficient catalysts for asymmetric allylation of aldehydes with allyl(trichloro)silanes. The Journal of Organic Chemistry. 68: 6329-37. PMID 12895068 DOI: 10.1021/Jo0300800  0.484
2004 Hayashi T. Rhodium-catalyzed asymmetric addition of aryl- and alkenylboron reagents to electron-deficient olefins Pure and Applied Chemistry. 76: 465-475. DOI: 10.1351/Pac200476030465  0.61
2004 Hayashi T. Rhodium-Catalyzed Asymmetric Addition of Organo-Boron and -Titanium Reagents to Electron-Deficient Olefins Bulletin of the Chemical Society of Japan. 77: 13-21. DOI: 10.1246/Bcsj.77.13  0.541
2004 Nagano T, Hayashi T. Iron-catalyzed grignard cross-coupling with alkyl halides possessing β-hydrogens Organic Letters. 6: 1297-1299. DOI: 10.1021/Ol049779Y  0.463
2004 Otomaru Y, Hayashi T. Rhodium-catalyzed asymmetric 1,4-addition of alkenylsilanes generated by hydrosilylation of alkynes: a one-pot procedure where a rhodium/(S)-binap complex catalyzes the two successive reactions Tetrahedron-Asymmetry. 15: 2647-2651. DOI: 10.1016/J.Tetasy.2004.07.003  0.569
2004 Aoki K, Shimada T, Hayashi T. Immobilization of chiral phosphine ligands on silica gel by means of the allylsilane method and their use for catalytic asymmetric reactions Tetrahedron: Asymmetry. 15: 1771-1777. DOI: 10.1016/J.Tetasy.2004.03.044  0.559
2004 Hayashi T, Suzuka T, Okada A, Kawatsura M. Palladium-catalyzed asymmetric allylic alkylation with an indenide Tetrahedron: Asymmetry. 15: 545-548. DOI: 10.1016/J.Tetasy.2003.11.028  0.604
2004 Kina A, Miki H, Cho Y, Hayashi T. Palladium-Catalyzed Heck and Carbonylation Reactions of a Dinaphthaleneiodonium Salt Forming Functionalized 2-Iodo-1,1′-binaphthyls Advanced Synthesis & Catalysis. 346: 1728-1732. DOI: 10.1002/Adsc.200404202  0.563
2004 Kina A, Shimada T, Hayashi T. A New Approach to Axially Chiral BipyridineN,N′-Dioxides Bearing Aromatic Substituents and their Use for Catalytic Asymmetric Allylation of Aldehydes with Allyl(trichloro)silane Advanced Synthesis & Catalysis. 346: 1169-1174. DOI: 10.1002/Adsc.200404054  0.529
2003 Hayashi T, Ueyama K, Tokunaga N, Yoshida K. A chiral chelating diene as a new type of chiral ligand for transition metal catalysts: its preparation and use for the rhodium-catalyzed asymmetric 1,4-addition. Journal of the American Chemical Society. 125: 11508-9. PMID 13129348 DOI: 10.1021/Ja037367Z  0.56
2003 Hayashi T, Yamasaki K. Rhodium-catalyzed asymmetric 1,4-addition and its related asymmetric reactions. Chemical Reviews. 103: 2829-44. PMID 12914482 DOI: 10.1021/cr020022z  0.414
2003 Hayashi T, Okada A, Suzuka T, Kawatsura M. High enantioselectivity in rhodium-catalyzed allylic alkylation of 1-substituted 2-propenyl acetates. Organic Letters. 5: 1713-5. PMID 12735759 DOI: 10.1021/Ol0343562  0.616
2003 Yoshida K, Hayashi T. A New cine-Substitution of Alkenyl Sulfones with Aryltitanium Reagents Catalyzed by Rhodium: Mechanistic Studies and Catalytic Asymmetric Synthesis of Allylarenes Journal of the American Chemical Society. 125: 2872-2873. PMID 12617643 DOI: 10.1021/Ja0295568  0.582
2003 Yoshida K, Ogasawara M, Hayashi T. Generation of chiral boron enolates by rhodium-catalyzed asymmetric 1,4-addition of 9-aryl-9-borabicyclo[3.3.1]nonanes (B-Ar-9BBN) to alpha,beta-unsaturated ketones. The Journal of Organic Chemistry. 68: 1901-5. PMID 12608808 DOI: 10.1021/jo020659i  0.441
2003 Ogasawara M, Ueyama K, Nagano T, Mizuhata Y, Hayashi T. Palladium-Catalyzed Asymmetric Synthesis of Axially Chiral (Allenylmethyl)silanes and Chirality Transfer to Stereogenic Carbon Centers in SE‘ Reactions Organic Letters. 5: 217-219. PMID 12529144 DOI: 10.1021/Ol027291W  0.579
2003 Shimada T, Cho YH, Hayashi T. Nickel-catalyzed asymmetric grignard cross-coupling of dinaphthothiophene giving axially chiral 1,1'-binaphthyls. Journal of the American Chemical Society. 124: 13396-7. PMID 12418887 DOI: 10.1021/Ja0282588  0.549
2003 Hayashi T, Yoshida K. Rhodium-catalyzed Asymmetric 1,4- Addition of 3-Thiopheneboronic Acid to a,b-Unsaturated Carbonyl Compounds Heterocycles. 59: 605. DOI: 10.3987/Com-02-S59  0.43
2003 Hayashi T. Rhodium-catalyzed asymmetric 1,4-addition of organometallic reagents Russian Chemical Bulletin. 52: 2595-2605. DOI: 10.1023/B:RUCB.0000019877.06933.4d  0.539
2003 Ogasawara M, Nagano T, Hayashi T. Synthesis of 1,1‘-Diphospha[4]ferrocenophanes by Molybdenum-Catalyzed Ring-Closing Metathesis Organometallics. 22: 1174-1176. DOI: 10.1021/Om021058K  0.544
2003 Ogasawara M, Yoshida K, Hayashi T. Induction of Atropisomeric Chirality on Heavily Substituted Phosphametallocenes Organometallics. 22: 1783-1786. DOI: 10.1021/Om020835D  0.424
2003 Yoshida K, Ogasawara M, Hayashi T. Generation of Chiral Boron Enolates by Rhodium-Catalyzed Asymmetric 1,4-Addition of 9-Aryl-9-borabicyclo[3.3.1]nonanes (B-Ar-9BBN) to α,β-Unsaturated Ketones. Cheminform. 34. DOI: 10.1021/Jo020659I  0.565
2003 Suzuka T, Kawatsura M, Okada A, Hayashi T. Palladium-catalyzed asymmetric allylic substitution with a cyclopentadienide: asymmetric synthesis of metallocenes Tetrahedron: Asymmetry. 14: 511-515. DOI: 10.1016/S0957-4166(02)00862-5  0.574
2003 Shi Q, Xu L, Li X, Jia X, Wang R, Au-Yeung TT, Chan AS, Hayashi T, Cao R, Hong M. Bipyridyl-based diphosphine as an efficient ligand in the rhodium-catalyzed asymmetric conjugate addition of arylboronic acids to α,β-unsaturated ketones Tetrahedron Letters. 44: 6505-6508. DOI: 10.1016/S0040-4039(03)01592-2  0.522
2003 Shimada T, Kina A, Hayashi T. A New Synthetic Route to Enantiomerically Pure Axially Chiral 2,2′-Bipyridine N,N′-Dioxides. Highly Efficient Catalysts for Asymmetric Allylation of Aldehydes with Allyl(trichloro)silanes. Cheminform. 34. DOI: 10.1002/chin.200349031  0.466
2003 Hayashi T, Takahashi M, Takaya Y, Ogasawara M. (R)‐3‐Phenylcyclohexanon Organic Syntheses. 84-84. DOI: 10.1002/0471264180.Os079.10  0.397
2003 Uozumi Y, Kawatsura M, Hayashi T. (R)‐2‐Diphenylphosphino‐2′‐Methoxy‐1,1′‐Binaphthyl Organic Syntheses. 1-1. DOI: 10.1002/0471264180.Os078.01  0.508
2002 Hayashi T, Tokunaga N, Yoshida K, Han JW. Rhodium-catalyzed asymmetric 1,4-addition of aryltitanium reagents generating chiral titanium enolates: isolation as silyl enol ethers. Journal of the American Chemical Society. 124: 12102-3. PMID 12371843 DOI: 10.1021/Ja027663W  0.489
2002 Yoshida K, Ogasawara M, Hayashi T. A new type of catalytic tandem 1,4-addition-aldol reaction which proceeds through an (oxa-pi-allyl)rhodium intermediate. Journal of the American Chemical Society. 124: 10984-5. PMID 12224938 DOI: 10.1021/Ja0271025  0.476
2002 Shimada T, Kina A, Ikeda S, Hayashi T. A novel axially chiral 2,2'-bipyridine N,N'-dioxide. Its preparation and use for asymmetric allylation of aldehydes with allyl(trichloro)silane as a highly efficient catalyst. Organic Letters. 4: 2799-801. PMID 12153238 DOI: 10.1021/Ol026376U  0.509
2002 Ogasawara M, Nagano T, Hayashi T. Metathesis route to bridged metallocenes. Journal of the American Chemical Society. 124: 9068-9. PMID 12149008 DOI: 10.1021/Ja026401R  0.476
2002 Suzuka T, Ogasawara M, Hayashi T. Asymmetric synthesis of metallocenes through enantioselective addition of organolithium reagents to 6-(dimethylamino)fulvene. The Journal of Organic Chemistry. 67: 3355-9. PMID 12003546 DOI: 10.1021/Jo0111199  0.385
2002 Hayashi T, Takahashi M, Takaya Y, Ogasawara M. Catalytic cycle of rhodium-catalyzed asymmetric 1,4-addition of organoboronic acids. Arylrhodium, oxa-pi-allylrhodium, and hydroxorhodium intermediates. Journal of the American Chemical Society. 124: 5052-8. PMID 11982369 DOI: 10.1021/Ja012711I  0.566
2002 Shimada T, Mukaide K, Shinohara A, Han JW, Hayashi T. Asymmetric synthesis of 1-aryl-1,2-ethanediols from arylacetylenes by palladium-catalyzed asymmetric hydrosilylation as a key step. Journal of the American Chemical Society. 124: 1584-5. PMID 11853426 DOI: 10.1021/Ja017617G  0.597
2002 Han JW, Tokunaga N, Hayashi T. Palladium- or nickel-catalyzed cross-coupling of organotitanium reagents with aryl triflates and halides Synlett. 2002: 871-874. DOI: 10.1055/S-2002-31930  0.518
2002 Ogasawara M, Takizawa K, Hayashi T. Effects of Bidentate Phosphine Ligands onsyn−antiIsomerization in π-Allylpalladium Complexes Organometallics. 21: 4853-4861. DOI: 10.1021/Om020680+  0.392
2002 Ogasawara M, Nagano T, Yoshida K, Hayashi T. Synthesis and Characterization of 1,1‘-Diphospharuthenocenes Organometallics. 21: 3062-3065. DOI: 10.1021/Om020189I  0.406
2002 Han JW, Hayashi T. Enhanced catalytic activity in asymmetric hydrosilylation of 1,3-dienes with a soluble palladium catalyst Tetrahedron: Asymmetry. 13: 325-331. DOI: 10.1016/S0957-4166(02)00094-0  0.588
2002 Hayashi T. Catalytic asymmetric cross-coupling Journal of Organometallic Chemistry. 653: 41-45. DOI: 10.1016/S0022-328X(02)01272-X  0.508
2002 Han J, Tokunaga N, Hayashi T. Preparation of New Ferrocenylmonophosphine Ligands Containing Two Planar Chiral Ferrocenyl Moieties and Their Use for Palladium-Catalyzed Asymmetric Hydrosilylation of 1,3-Dienes Helvetica Chimica Acta. 85: 3848-3854. DOI: 10.1002/1522-2675(200211)85:11<3848::Aid-Hlca3848>3.0.Co;2-V  0.558
2001 Shimada T, Kurushima H, Cho Y, Hayashi T. Preparation of enantiomerically pure 2'-substituted 2-diphenylphosphino-1,1'-binaphthyls by reductive cleavage of the carbon-phosphorus bond in a borane complex of 2-diphenylphosphino-2'-diphenylphosphinyl-1,1'-binaphthyl. Journal of Organic Chemistry. 66: 8854-8858. PMID 11749615 DOI: 10.1021/Jo010691X  0.452
2001 Han JW, Tokunaga N, Hayashi T. Palladium-catalyzed asymmetric hydrosilylation of 4-substituted 1-buten-3-ynes. Catalytic asymmetric synthesis of axially chiral allenylsilanes. Journal of the American Chemical Society. 123: 12915-12916. PMID 11749556 DOI: 10.1021/Ja017138H  0.608
2001 Senda T, Ogasawara M, Hayashi T. Rhodium-catalyzed asymmetric 1,4-addition of organoboron reagents to 5,6-dihydro-2(1H)-pyridinones. Asymmetric synthesis of 4-aryl-2-piperidinones. Journal of Organic Chemistry. 66: 6852-6856. PMID 11597202 DOI: 10.1021/Jo0103930  0.584
2001 Hayashi T, Inoue K, Taniguchi N, Ogasawara M. Rhodium-Catalyzed Hydroarylation of Alkynes with Arylboronic Acids: 1,4-Shift of Rhodium from 2-Aryl-1-alkenylrhodium to 2-Alkenylarylrhodium Intermediate Journal of the American Chemical Society. 123: 9918-9919. PMID 11583565 DOI: 10.1021/Ja0165234  0.481
2001 Ogasawara M, Ikeda H, Nagano T, Hayashi T. Chloroprene as a source of fine chemicals: palladium-catalyzed synthesis of terminal allenes. Organic Letters. 3: 2615-2617. PMID 11483074 DOI: 10.1021/Ol016320K  0.523
2001 Ogasawara M, Ikeda H, Nagano T, Hayashi T. Palladium-Catalyzed Asymmetric Synthesis of Axially Chiral Allenes: A Synergistic Effect of Dibenzalacetone on High Enantioselectivity Journal of the American Chemical Society. 123: 2089-2090. PMID 11456845 DOI: 10.1021/Ja005921O  0.58
2001 Hayashi T, Hirate S, Kitayama K, Tsuji H, Torii aA, Uozumi Y. Asymmetric Hydrosilylation of Styrenes Catalyzed by Palladium−MOP Complexes: Ligand Modification and Mechanistic Studies Journal of Organic Chemistry. 66: 1441-1449. PMID 11312978 DOI: 10.1021/Jo001614P  0.769
2001 Han JW, Hayashi T. Preparation of a New MOP Ligand Containing a Long-Chain Alkyl Group and Its Use for Palladium-Catalyzed Asymmetric Hydrosilylation of Cyclic 1,3-Dienes Chemistry Letters. 30: 976-977. DOI: 10.1246/Cl.2001.976  0.578
2001 Hayashi T. Rhodium-Catalyzed Asymmetric 1,4-Addition of Organoboronic Acids and Their Derivatives to Electron Deficient Olefins Synlett. 2001: 0879-0887. DOI: 10.1055/S-2001-14657  0.575
2001 Ogasawara M, Yoshida K, Hayashi T. A Novel Chiral Phosphino−Phosphaferrocene:  Its Coordination Behavior and Application to Palladium-Catalyzed Asymmetric Allylic Alkylation Organometallics. 20: 3913-3917. DOI: 10.1021/Om010440E  0.536
2001 Ogasawara M, Yoshida K, Hayashi T. Synthesis and Characterization of a Novel Chiral Phosphole and Its Derivatives Organometallics. 20: 1014-1019. DOI: 10.1021/Om000952D  0.535
2001 Hayashi T, Ishigedani M. Rhodium-catalyzed asymmetric arylation of α,β-unsaturated imines with arylstannanes. Catalytic asymmetric synthesis of allylic amines Tetrahedron. 57: 2589-2595. DOI: 10.1016/S0040-4020(01)00075-8  0.592
2001 Hayashi T, Senda T, Ogasawara M. ChemInform Abstract: Rhodium-Catalyzed Asymmetric Conjugate Addition of Organoboronic Acids to Nitroalkenes. Cheminform. 32: no-no. DOI: 10.1002/chin.200111025  0.355
2001 Hayashi T, Han J, Takeda A, Tang T, Nohmi K, Mukaide K, Tsuji H, Uozumi Y. Modification of Chiral Monodentate Phosphine Ligands (MOP) for Palladium-Catalyzed Asymmetric Hydrosilylation of Cyclic 1,3-Dienes Advanced Synthesis & Catalysis. 343: 279-283. DOI: 10.1002/1615-4169(20010330)343:3<279::Aid-Adsc279>3.0.Co;2-5  0.782
2000 Hayashi T. Chiral monodentate phosphine ligand MOP for transition-metal-catalyzed asymmetric reactions. Accounts of Chemical Research. 33: 354-362. PMID 10891053 DOI: 10.1021/Ar990080F  0.597
2000 Takaya Y, Ogasawara M, Hayashi T. Asymmetric 1,4-addition of phenylboronic acid to 2-cyclohexenone catalyzed by Rh(I)/binap complexes. Chirality. 12: 469-471. PMID 10824171 DOI: 10.1002/(Sici)1520-636X(2000)12:5/6<469::Aid-Chir29>3.0.Co;2-H  0.534
2000 Hayashi T, Ogasawara M, Yoshida K. Novel Palladium Chiral Phosphinooxazoline Complexes: Crystal Strucutre Studies and Application to Asymmetric Heck Reaction Heterocycles. 52: 195. DOI: 10.3987/Com-99-S8  0.483
2000 Ogasawara M, Ikeda H, Ohtsuki K, Hayashi T. Palladium-Catalyzed Synthesis of Butatrienes Chemistry Letters. 2000: 776-777. DOI: 10.1246/Cl.2000.776  0.536
2000 Ogasawara M, Yoshida K, Hayashi T. 2,2‘-Bis(diphenylphosphino)-1,1‘-biphenyl:  New Entry of Bidentate Triarylphosphine Ligand to Transition Metal Catalysts Organometallics. 19: 1567-1571. DOI: 10.1021/Om9909587  0.468
2000 Hayashi T, Senda aT, Ogasawara M. Rhodium-Catalyzed Asymmetric Conjugate Addition of Organoboronic Acids to Nitroalkenes Journal of the American Chemical Society. 122: 10716-10717. DOI: 10.1021/Ja002805C  0.441
2000 Hayashi T. Axially chiral monophosphine ligands (MOPs) and their use for palladium-catalyzed asymmetric hydrosilylation of olefins Catalysis Today. 62: 3-15. DOI: 10.1016/S0920-5861(00)00404-1  0.563
2000 Kawatsura M, Uozumi Y, Ogasawara M, Hayashi T. Palladium-Catalyzed Asymmetric Reduction of Racemic Allylic Esters with Formic Acid: Effects of Phosphine Ligands on Isomerization of π-Allylpalladium Intermediates and Enantioselectivity Tetrahedron. 56: 2247-2257. DOI: 10.1016/S0040-4020(99)01107-2  0.63
1999 Uozumi Y, Danjo H, Hayashi T. Cross-Coupling of Aryl Halides and Allyl Acetates with Arylboron Reagents in Water Using an Amphiphilic Resin-Supported Palladium Catalyst. The Journal of Organic Chemistry. 64: 3384-3388. PMID 11674453 DOI: 10.1021/Jo982438B  0.545
1999 Uozumi Y, Kyota H, Kato K, Ogasawara M, Hayashi T. Design and Preparation of 3,3'-Disubstituted 2,2'-Bis(oxazolyl)-1,1'-binaphthyls (boxax): New Chiral Bis(oxazoline) Ligands for Catalytic Asymmetric Wacker-Type Cyclization. The Journal of Organic Chemistry. 64: 1620-1625. PMID 11674227 DOI: 10.1021/Jo982104M  0.636
1999 Hayashi T. Catalysis Surveys From Japan. 3: 127-135. DOI: 10.1023/A:1019075719151  0.487
1999 Hayashi T, Tang J, Kato K. Palladium-Catalyzed Enantioselective Carbonylative Cyclization of Aryl and Alkenyl Triflates with Carbon Monoxide Organic Letters. 1: 1487-1489. DOI: 10.1021/Ol9902879  0.485
1999 Hayashi T, Senda T, Takaya Y, Ogasawara M. Rhodium-Catalyzed Asymmetric 1,4-Addition to 1-Alkenylphosphonates Journal of the American Chemical Society. 121: 11591-11592. DOI: 10.1021/Ja993184U  0.604
1999 Takaya Y, Senda T, Kurushima H, Ogasawara M, Hayashi T. Rhodium-catalyzed asymmetric 1,4-addition of arylboron reagents to α,β-unsaturated esters Tetrahedron: Asymmetry. 10: 4047-4056. DOI: 10.1016/S0957-4166(99)00417-6  0.545
1999 Takaya Y, Ogasawara M, Hayashi T. Rhodium-catalyzed asymmetric 1,4-addition of arylboron compounds generated in situ from aryl bromides Tetrahedron Letters. 40: 6957-6961. DOI: 10.1016/S0040-4039(99)01412-4  0.503
1999 Danjo H, Tanaka D, Hayashi T, Uozumi Y. Allylic substitution in water catalyzed by amphiphilic resin-supported palladium-phosphine complexes Tetrahedron. 55: 14341-14352. DOI: 10.1016/S0040-4020(99)00883-2  0.537
1999 Kamikawa T, Hayashi T. Enantioposition-selective arylation of biaryl ditriflates by palladium- catalyzed asymmetric Grignard cross-coupling Tetrahedron. 55: 3455-3466. DOI: 10.1016/S0040-4020(98)01154-5  0.53
1999 Hayashi T. Catalytic asymmetric reactions via π-allylpalladium complexes coordinated with chiral monophosphine ligands Journal of Organometallic Chemistry. 576: 195-202. DOI: 10.1016/S0022-328X(98)01058-4  0.633
1999 Ozawa F, Sugawara M, Hasebe K, Hayashi T. Reactions of bis(silyl)palladium(II) complexes with allyl halides. Synthesis of mono(silyl)palladium(II) halides and X-ray structure of trans-PdCl(SiF2Ph)(PMe2Ph)2 Inorganica Chimica Acta. 296: 19-25. DOI: 10.1016/S0020-1693(99)00298-4  0.339
1998 Uozumi Y, Tsuji H, Hayashi T. Cyclization of o-Allylstyrene via Hydrosilylation: Mechanistic Aspects of Hydrosilylation of Styrenes Catalyzed by Palladium-Phosphine Complexes. The Journal of Organic Chemistry. 63: 6137-6140. PMID 11672242 DOI: 10.1021/Jo980100B  0.742
1998 Kawatsura M, Uozumi Y, Hayashi T. Regiocontrol in palladium-catalysed allylic alkylation by addition of lithium iodide Chemical Communications. 217-218. DOI: 10.1039/A707652E  0.555
1998 Kamikawa T, Hayashi T. Dichloro[(2-dimethylamino)propyldiphenylphosphine]palladium(II) (PdCl2(alaphos)): An efficient catalyst for cross-coupling of aryl triflates with alkynyl grignard reagents Journal of Organic Chemistry. 63: 8922-8925. DOI: 10.1021/Jo981191F  0.549
1998 Uozumi Y, Kato K, Hayashi T. Cationic Palladium/Boxax Complexes for Catalytic Asymmetric Wacker-Type Cyclization The Journal of Organic Chemistry. 63: 5071-5075. DOI: 10.1021/Jo980245I  0.492
1998 Takaya Y, Ogasawara M, Hayashi T, Sakai M, Miyaura N. Rhodium-Catalyzed Asymmetric 1,4-Addition of Aryl- and Alkenylboronic Acids to Enones Journal of the American Chemical Society. 120: 5579-5580. DOI: 10.1021/Ja980666H  0.484
1998 Hayashi T, Kawatsura M, Uozumi Y. Retention of Regiochemistry of Allylic Esters in Palladium-Catalyzed Allylic Alkylation in the Presence of a MOP Ligand Journal of the American Chemical Society. 120: 1681-1687. DOI: 10.1021/Ja973150R  0.561
1998 Ogasawara M, Yoshida K, Kamei H, Kato K, Uozumi Y, Hayashi T. Synthesis and application of novel chiral phosphino-oxazoline ligands with 1,1′-binaphthyl skeleton Tetrahedron: Asymmetry. 9: 1779-1787. DOI: 10.1016/S0957-4166(98)00136-0  0.661
1998 Uozumi Y, Kato K, Hayashi T. Asymmetric aza-Claisen rearrangement of allyl imidates catalyzed by homochiral cationic palladium(II) complexes Tetrahedron: Asymmetry. 9: 1065-1072. DOI: 10.1016/S0957-4166(98)00059-7  0.54
1998 Takaya Y, Ogasawara M, Hayashi T. Rhodium-catalyzed asymmetric 1,4-addition of 2-alkenyl-1,3,2-benzodioxaboroles to α,β-unsaturated ketones Tetrahedron Letters. 39: 8479-8482. DOI: 10.1016/S0040-4039(98)01866-8  0.555
1998 Uozumi Y, Danjo H, Hayashi T. Palladium-catalyzed asymmetric allylic substitution in aqueous media using amphiphilic resin-supported MOP ligands Tetrahedron Letters. 39: 8303-8306. DOI: 10.1016/S0040-4039(98)01812-7  0.61
1997 Kamikawa T, Hayashi T. Palladium Catalysts for Cross-Coupling of Ortho-Substituted Aryl Triflates with Grignard Reagents Synlett. 1997: 163-164. DOI: 10.1055/S-1997-750  0.502
1997 Hayashi T, Kawatsura M, Uozumi Y. Regio- And Enantio-Selective Allylic Alkylation Catalysed By A Chiral Monophosphine-Palladium Complex Chemical Communications. 561-562. DOI: 10.1039/A700045F  0.636
1997 Soloshonok VA, Kacharov AD, Avilov DV, Ishikawa K, Nagashima N, Hayashi T. Transition Metal/Base-Catalyzed Aldol Reactions of Isocyanoacetic Acid Derivatives with Prochiral Ketones, a Straightforward Approach to Stereochemically Defined β,β-Disubstituted-β-hydroxy-α-amino Acids.1Scope and Limitations The Journal of Organic Chemistry. 62: 3470-3479. DOI: 10.1021/Jo9623402  0.506
1997 Uozumi Y, Kato K, Hayashi T. Catalytic Asymmetric Wacker-Type Cyclization Journal of the American Chemical Society. 119: 5063-5064. DOI: 10.1021/Ja9701366  0.527
1997 Kamikawa T, Hayashi T. Control of reactive site in Palladium-Catalyzed grignard Cross-Coupling of arenes containing both bromide and triflate Tetrahedron Letters. 38: 7087-7090. DOI: 10.1016/S0040-4039(97)01655-9  0.495
1997 Uozumi Y, Danjo H, Hayashi T. New Amphiphilic Palladium-Phosphine Complexes Bound To Solid Supports : Preparation And Use For Catalytic Allylic Substitution In Aqueous Media Tetrahedron Letters. 38: 3557-3560. DOI: 10.1016/S0040-4039(97)00702-8  0.601
1997 Harada N, Hiyoshi N, Vassilev VP, Hayashi T. Synthesis, circular dichroism, and absolute stereochemistry of 1,1?:4?,1?-ternaphthalene compounds Chirality. 9: 623-625. DOI: 10.1002/(Sici)1520-636X(1997)9:5/6<623::Aid-Chir33>3.0.Co;2-O  0.378
1996 Hayashi T, Jermann TM, Opitz JG, Raillard SA, Zankel TR, Trautwein-Fritz K, Stackhouse J, Ciglic MI, Haugg M, Trabesinger-Rüf N, Weinhold EG. Asymmetric Hydrosilylation Of Olefins Catalyzed By Mop-Palladium Complexes Acta Chemica Scandinavica. 50: 259-266. DOI: 10.3891/Acta.Chem.Scand.50-0259  0.525
1996 Hayashi T, Kawatsura M, Iwamura H, Yamaura Y, Uozumi Y. Catalytic Asymmetric Synthesis Of Optically Active Alkenes By Palladium-Catalysed Asymmetric Reduction Of Racemic Allylic Esters With Formic Acid Chemical Communications. 1767-1768. DOI: 10.1039/Cc9960001767  0.652
1996 Uozumi Y, Kyota H, Kishi E, Kitayama K, Hayashi T. Homochiral 2,2′-bis(oxazolyl)-1,1′-binaphthyls as ligands for copper(I)-catalyzed asymmetric cyclopropanation Tetrahedron: Asymmetry. 7: 1603-1606. DOI: 10.1016/0957-4166(96)00193-0  0.62
1996 Soloshonok VA, Kacharov AD, Avilov DV, Hayashi T. Transition metal-catalyzed diastereoselective aldol reactions of prochiral ketones with methyl isocyanoacetate Tetrahedron Letters. 37: 7845-7848. DOI: 10.1016/0040-4039(96)01746-7  0.479
1996 Hayashi T, Kishi E, Soloshonok VA, Uozumi Y. Erythro-Selective aldol-type reaction of N-sulfonylaldimines with methyl isocyanoacetate catalyzed by gold(I) Tetrahedron Letters. 37: 4969-4972. DOI: 10.1016/0040-4039(96)00981-1  0.516
1996 Kitayama K, Tsuji H, Uozumi Y, Hayashi T. Asymmetric hydrosilylation of cyclic 1,3-dienes catalyzed by an axially chiral monophosphine-palladium complex Tetrahedron Letters. 37: 4169-4172. DOI: 10.1016/0040-4039(96)00786-1  0.759
1996 Kamikawa T, Uozumi Y, Hayashi T. Enantioposition-selective alkynylation of biaryl ditriflates by palladium-catalyzed asymmetric cross-coupling Tetrahedron Letters. 37: 3161-3164. DOI: 10.1016/0040-4039(96)00517-5  0.614
1996 Soloshonok VA, Kacharov AD, Hayashi T. Gold(I)-catalyzed asymmetric aldol reactions of isocyanoacetic acid derivatives with fluoroaryl aldehydes Tetrahedron. 52: 245-254. DOI: 10.1016/0040-4020(95)00893-D  0.487
1995 Hikida T, Onitsuka K, Sonogashira K, Hayashi T, Ozawa F. A Remarkable Difference in the Reactivity betweencis- andtrans-Silylplatinum Complexes toword Insertion of Acetylene Chemistry Letters. 24: 985-986. DOI: 10.1246/Cl.1995.985  0.322
1995 Uozumi Y, Kitayama K, Hayashi T, Yanagi K, Fukuyo E. Asymmetric Hydrosilylation of 1-Alkenes Catalyzed by Palladium–MOP Bulletin of the Chemical Society of Japan. 68: 713-722. DOI: 10.1246/Bcsj.68.713  0.46
1995 Kitayama K, Uozumi Y, Hayashi T. Palladium-catalysed asymmetric hydrosilylation of styrenes with a new chiral monodentate phosphine ligand Journal of the Chemical Society, Chemical Communications. 1533-1534. DOI: 10.1039/C39950001533  0.617
1995 Hayashi T, Niizuma S, Kamikawa T, Suzuki N, Uozumi Y. Catalytic asymmetric synthesis of axially chiral biaryls by palladium-catalyzed enantioposition-selective cross-coupling. Journal of the American Chemical Society. 117: 9101-9102. DOI: 10.1021/Ja00140A041  0.613
1995 Hayashi T, Hayashi C, Uozumi Y. Catalytic asymmetric hydrosilylation of ketones with new chiral ferrocenylphosphine-imine ligands Tetrahedron: Asymmetry. 6: 2503-2506. DOI: 10.1016/0957-4166(95)00326-K  0.621
1995 Ohno A, Yamane M, Hayashi T, Oguni N, Hayashi M. Preparation and use of chiral ferrocenylphosphines containing new alkyl substituents on the ferrocenylmethyl position Tetrahedron: Asymmetry. 6: 2495-2502. DOI: 10.1016/0957-4166(95)00325-J  0.427
1994 Hayashi T. MOP: A Monodentate Chiral Phosphine Ligand for Catalytic Asymmetric Reactions. Journal of Synthetic Organic Chemistry Japan. 52: 900-911. DOI: 10.5059/Yukigoseikyokaishi.52.900  0.578
1994 Hayashi T, Iwamura H, Uozumi Y, Matsumoto Y, Ozawa F. A New Optically Active Monodentate Phosphine Ligand, (R)-(+)-3-Diphenylphosphino-3′-methoxy-4,4′-biphenanthryl (MOP-phen): Preparation and Use for Palladium-Catalyzed Asymmetric Reduction of Allylic Esters with Formic Acid Synthesis. 1994: 526-532. DOI: 10.1055/S-1994-25517  0.589
1994 Ozawa F, Kobatake Y, Kubo A, Hayashi T. Palladium-catalysed asymmetric hydroalkenylation of norbornene Journal of the Chemical Society, Chemical Communications. 1323-1324. DOI: 10.1039/C39940001323  0.459
1994 Ozawa F, Sugawara M, Hayashi T. A New Reactive System for Catalytic Bis-Silylation of Acetylenes and Olefins Organometallics. 13: 3237-3243. DOI: 10.1021/Om00020A042  0.477
1994 Hayashi T, Ohno A, Lu S, Matsumoto Y, Fukuyo E, Yanagi K. Optically Active Ruthenocenylbis(phosphines): New Efficient Chiral Phosphine Ligands for Catalytic Asymmetric Reactions Journal of the American Chemical Society. 116: 4221-4226. DOI: 10.1021/Ja00089A011  0.556
1994 Hayashi T, Iwamura H, Naito M, Matsumoto Y, Uozumi Y, Miki M, Yanagi K. Catalytic Asymmetric Reduction of Allylic Esters with Formic Acid Catalyzed by Palladium-MOP Complexes Journal of the American Chemical Society. 116: 775-776. DOI: 10.1021/Ja00081A051  0.618
1994 Soloshonok VA, Hayashi T, Ishikawa K, Nagashima N. Highly diastereoselective aldol reaction of fluoroalkyl aryl ketones with methyl isocyanoacetate catalyzed by silver(I)/triethylamine Tetrahedron Letters. 35: 1055-1058. DOI: 10.1016/S0040-4039(00)79964-3  0.529
1994 Soloshonok VA, Hayashi T. Gold(I)-catalyzed asymmetric aldol reaction of methyl isocyanoacetate with fluorinated benzaldehydes Tetrahedron Letters. 35: 2713-2716. DOI: 10.1016/S0040-4039(00)77013-4  0.466
1994 Hayashi T, Iwamura H, Uozumi Y. Asymmetric synthesis of allylsilanes by palladium-catalyzed asymmetric reduction of allylic carbonates with formic acid Tetrahedron Letters. 35: 4813-4816. DOI: 10.1016/S0040-4039(00)76975-9  0.636
1994 Uozumi Y, Suzuki N, Ogiwara A, Hayashi T. Preparation of optically active binaphthylmonophosphines (MOP's) containing various functional groups Tetrahedron. 50: 4293-4302. DOI: 10.1016/S0040-4020(01)89366-2  0.525
1994 Matsumoto Y, Hayashi T, Ito Y. Catalytic asymmetric synthesis of β-hydroxy ketones by palladium-catalyzed asymmetric 1,4-disilylation of α,β-unsaturated ketones Tetrahedron. 50: 335-346. DOI: 10.1016/S0040-4020(01)80758-4  0.73
1994 Soloshonok VA, Hayashi T. Gold(I)-catalyzed asymmetric aldol reactions of fluorinated benzaldehydes with an α-isocyanoacetamide Tetrahedron: Asymmetry. 5: 1091-1094. DOI: 10.1016/0957-4166(94)80059-6  0.481
1994 Uemura M, Nishimura H, Hayashi T. Catalytic asymmetric induction of planar chirality: Palladium-catalyzed asymmetric cross-coupling of meso tricarbonyl(arene) chromium complexes with alkenyl- and arylboronic acids Journal of Organometallic Chemistry. 473: 129-137. DOI: 10.1016/0022-328X(94)80113-4  0.548
1993 Uozumi Y, Hayashi T. The Development and Application of a New Class of Monodentate Optically Active Phosphines (MOP's). Asymmetric Hydrosilylation of Olefins Catalyzed by Palladium-MOP Complexes Journal of Synthetic Organic Chemistry Japan. 51: 1087-1096. DOI: 10.5059/Yukigoseikyokaishi.51.1087  0.505
1993 Matsumoto Y, Naito M, Uozumi Y, Hayashi T. Axially chiral allenylboranes: catalytic asymmetric synthesis by palladium-catalysed hydroboration of but-1-en-3-ynes and their reaction with an aldehyde Journal of the Chemical Society, Chemical Communications. 1468-1469. DOI: 10.1039/C39930001468  0.65
1993 Ozawa F, Kubo A, Matsumoto Y, Hayashi T, Nishioka E, Yanagi K, Moriguchi K. Palladium-catalyzed asymmetric arylation of 2,3-dihydrofuran with phenyl triflate. A novel asymmetric catalysis involving a kinetic resolution process Organometallics. 12: 4188-4196. DOI: 10.1021/Om00034A064  0.514
1993 Matsumoto Y, Ohno A, Hayashi T. Preparation of silafunctional allylsilanes by palladium-catalyzed silylation of allylic chlorides with 1,1-dichloro-1-phenyl-2,2,2-trimethyldisilane Organometallics. 12: 4051-4055. DOI: 10.1021/Om00034A043  0.586
1993 Uozumi Y, Tanahashi A, Hayashi T. Catalytic asymmetric construction of morpholines and piperazines by palladium-catalyzed tandem allylic substitution reactions Journal of Organic Chemistry. 58: 6826-6832. DOI: 10.1021/Jo00076A052  0.557
1993 Uozumi Y, Tanahashi A, Lee SY, Hayashi T. Synthesis of optically active 2-(diarylphosphino)-1,1'-binaphthyls, efficient chiral monodentate phosphine ligands The Journal of Organic Chemistry. 58: 1945-1948. DOI: 10.1021/Jo00059A059  0.575
1993 Uozumi Y, Kitayama K, Hayashi T. Regio- and enantioselective hydrosilylation of 1-arylalkenes by use of palladium-MOP catalyst Tetrahedron: Asymmetry. 4: 2419-2422. DOI: 10.1016/S0957-4166(00)82214-4  0.629
1993 Matsumoto Y, Ohno A, Lu S, Hayashi T, Oguni N, Hayashi M. Enantioselective synthesis of 1-metallocenylalkanols by catalytic asymmetric alkylation of metallocenecarboxaldehydes with dialkylzincs Tetrahedron: Asymmetry. 4: 1763-1766. DOI: 10.1016/S0957-4166(00)80411-5  0.377
1993 Uozumi Y, Hayashi T. Asymmetric hydrosilylation of dihydrofurans by use of palladium-MOP catalyst Tetrahedron Letters. 34: 2335-2338. DOI: 10.1016/S0040-4039(00)77607-6  0.613
1993 Ozawa F, Kobatake Y, Hayashi T. Palladium-catalyzed asymmetric alkenylation of cyclic olefins Tetrahedron Letters. 34: 2505-2508. DOI: 10.1016/S0040-4039(00)60453-7  0.547
1993 Uemura M, Nishimura H, Hayashi T. Catalytic asymmetric induction of planar chirality by palladium-catalyzed asymmetric cross-coupling of a meso (arene)chromium complex Tetrahedron Letters. 34: 107-110. DOI: 10.1016/S0040-4039(00)60069-2  0.538
1992 Hayashi T, Uozumi Y. Catalytic asymmetric synthesis of optically active alcohols via hydrosilylation of olefins with a chiral monophosphine-palladium catalyst Pure and Applied Chemistry. 64: 1911-1916. DOI: 10.1351/Pac199264121911  0.588
1992 Hayashi T, Kubo A, Ozawa F. Catalytic asymmetric arylation of olefins Pure and Applied Chemistry. 64: 421-427. DOI: 10.1351/Pac199264030421  0.562
1992 Ozawa F, Kubo A, Hayashi T. Generation of Tertiary Phosphine-Coordinated Pd(0) Species from Pd(OAc)2in the Catalytic Heck Reaction Chemistry Letters. 21: 2177-2180. DOI: 10.1246/Cl.1992.2177  0.301
1992 Matsumoto Y, Naito M, Hayashi T. Palladium(0)-catalyzed hydroboration of 1-buten-3-ynes: preparation of allenylboranes Organometallics. 11: 2732-2734. DOI: 10.1021/Om00043A075  0.578
1992 Uemura M, Miyake R, Nishimura H, Matsumoto Y, Hayashi T. New chiral phosphine ligands containing (η6-arene)chromium and catalytic asymmetric cross-coupling reactions Tetrahedron-Asymmetry. 3: 213-216. DOI: 10.1016/S0957-4166(00)80193-7  0.578
1992 Ozawa F, Kubo A, Hayashi T. Palladium-catalyzed asymmetric arylation of 2,3-dihydrofuran: 1,8-Bis(dimethylamino)naphthalene as an efficient base Tetrahedron Letters. 33: 1485-1488. DOI: 10.1016/S0040-4039(00)91654-X  0.546
1992 Uozumi Y, Sang-Yong L, Hayashi T. Asymmetric functionalization of bicycloalkenes by catalytic enantioposition-selective hydrosilylation Tetrahedron Letters. 33: 7185-7188. DOI: 10.1016/S0040-4039(00)60868-7  0.569
1992 Hayashi T, Sawamura M, Ito Y. Asymmetric synthesis catalyzed by chiral ferrocenylphosphine transition metal complexes. 10 gold(i)-catalyzed asymmetric aldol reaction of isocyanoacetate Tetrahedron. 48: 1999-2012. DOI: 10.1016/S0040-4020(01)88870-0  0.824
1992 Ozawa F, Hayashi T. Catalytic asymmetric arylation of N-substituted 2-pyrrolines with aryl triflates Journal of Organometallic Chemistry. 428: 267-277. DOI: 10.1016/0022-328X(92)83236-B  0.551
1991 Matsumoto Y, Hayashi T. Selective 1,4-Hydroboration of Phenyl 1-Alkenyl Ketones with 9-Borabicyclo [3.3.1]nonane and Catecholborane Forming Boron (Z)-Enolates Synlett. 1991: 349-350. DOI: 10.1055/S-1991-34744  0.384
1991 Ozawa F, Hayashi T, Koide H, Yamamoto A. Insertion of alkenes into a palladium–acetyl bond Journal of the Chemical Society, Chemical Communications. 1469-1470. DOI: 10.1039/C39910001469  0.382
1991 Uozumi Y, Hayashi T. Catalytic asymmetric synthesis of optically active 2-alkanols via hydrosilylation of 1-alkenes with a chiral monophosphine-palladium catalyst Journal of the American Chemical Society. 113: 9887-9888. DOI: 10.1021/Ja00026A044  0.613
1991 Ozawa F, Kubo A, Hayashi T. Catalytic asymmetric arylation of 2,3-dihydrofuran with aryl triflates Journal of the American Chemical Society. 113: 1417-1419. DOI: 10.1021/Ja00004A056  0.589
1991 Hayashi T, Kishi K, Uozumi Y. Catalytic asymmetric elimination forming chiral 1,3-dienes via π-allylpalladium intermediate Tetrahedron: Asymmetry. 2: 195-198. DOI: 10.1016/S0957-4166(00)82357-5  0.646
1991 Matsumoto Y, Hayashi T. Asymmetric double hydroboration of 1,3-dienes catalyzed by chiral phosphine-rhodium complexes Tetrahedron Letters. 32: 3387-3390. DOI: 10.1016/S0040-4039(00)92714-X  0.604
1991 Hayashi T, Uozumi Y, Yamazaki A, Sawamura M, Hamashima H, Ito Y. Silver(I)-catalyzed asymmetric aldol reaction of isocyanoacetate Tetrahedron Letters. 32: 2799-2802. DOI: 10.1016/0040-4039(91)85090-R  0.83
1991 Hayashi T, Yamazaki A. Asymmetric synthesis catalyzed by chiral ferrocenylphosphine-transition metal complexes. IX. Preparation of chiral ferrocenylbisphosphines containing an aminoalkyl side chain Journal of Organometallic Chemistry. 413: 295-302. DOI: 10.1016/0022-328X(91)80058-R  0.497
1990 HAYASHI T, ITO Y. Asymmetric Aldol Reaction Catalyzed by Chiral Complexes Journal of Japan Oil Chemists' Society. 39: 846-851. DOI: 10.5650/Jos1956.39.10_846  0.784
1990 HAYASHI T. New reagents. II. Reagents for asymmetric synthesis. Reagent for asymmetric cross-coupling(chiral ferrocenylphosphine-Pd complex). Journal of Synthetic Organic Chemistry, Japan. 48: 994-995. DOI: 10.5059/Yukigoseikyokaishi.48.994  0.464
1990 Hayashi T, Hengrasmee S, Matsumoto Y. Selective Synthesis of (Z)-1-Ethylidene-2-silylcycloalkanes by Palladium-Catalyzed Hydrosilylation of 1-Vinylcycloalkenes Chemistry Letters. 19: 1377-1380. DOI: 10.1246/Cl.1990.1377  0.521
1990 Hayashi T, Matsumoto Y, Morikawa I, Ito Y. Catalytic asymmetric hydrosilylation of 1,3-dienes with new chiral ferrocenylphosphine-palladium complexes Tetrahedron: Asymmetry. 1: 151-154. DOI: 10.1016/S0957-4166(00)82367-8  0.759
1990 Sawamura M, Ito Y, Hayashi T. NMR studies of the gold(I)-catalyzed asymmetric aldol reaction of isocyanoacetate Tetrahedron Letters. 31: 2723-2726. DOI: 10.1016/S0040-4039(00)94683-5  0.777
1990 Hayashi T, Kishi K, Yamamoto A, Ito Y. Asymmetric allylic amination catalyzed by chiral ferrocenylphosphine-palladium complexes Tetrahedron Letters. 31: 1743-1746. DOI: 10.1016/S0040-4039(00)88870-X  0.806
1990 HAYASHI T, YAMAMOTO A, HOJO M, KISHI K, ITO Y, NISHIOKA E, MIURA H, YANAGI K. ChemInform Abstract: Asymmetric Synthesis Catalyzed by Chiral Ferrocenylphosphin-Transition Metal Complexes. Part 7. New Chiral Ferrocenylphosphines with C2 Symmetry. Cheminform. 21. DOI: 10.1002/chin.199003253  0.375
1989 Hayashi T, Ito Y. Asymmetric synthesis catalyzed by chiral phosphine-metal complexes. Nippon Kagaku Kaishi. 1965-1971. DOI: 10.1246/Nikkashi.1989.1965  0.48
1989 Hayashi T, Yamamoto A, Ito Y. Palladium(Ti)-Catalyzed Claisen Rearrangement of 1-Phenylethenyl 2-Propenyl Ethers Synthetic Communications. 19: 2109-2115. DOI: 10.1080/00397918908052605  0.766
1989 Hayashi T, Yamamoto A, Hojo M, Ito Y. A new chiral ferrocenylphosphine ligand with C2 symmetry: prepration and use for palladium-catalysed asymmetric cross-coupling Journal of the Chemical Society, Chemical Communications. 495-496. DOI: 10.1039/C39890000495  0.496
1989 Hayashi T, Yamamoto A, Ito Y, Nishioka E, Miura H, Yanagi K. Asymmetric synthesis catalyzed by chiral ferrocenylphosphine - transition-metal complexes. 8. Palladium-catalyzed asymmetric allylic amination Journal of the American Chemical Society. 111: 6301-6311. DOI: 10.1021/Ja00198A048  0.753
1989 Hayashi T, Matsumoto Y, Ito Y. Catalytic asymmetric hydroboration of styrenes Journal of the American Chemical Society. 111: 3426-3428. DOI: 10.1021/Ja00191A049  0.737
1989 Ito Y, Sawamura M, Hamashima H, Emura T, Hayashi T. Asymmetric aldol reaction of α-ketoesters with isocyanoacetate and isocyanoacetamide catalyzed by a chiral ferrocenylphosphine-gold(I) complex Tetrahedron Letters. 30: 4681-4684. DOI: 10.1016/S0040-4039(01)80773-5  0.811
1989 Sawamura M, Ito Y, Hayashi T. Asymmetric Synthesis of (1-Aminoalkyl)phosphonic Acids via Asymmetric Aldol Reaction of (Isocyanomethyl)phosphonates Catalyzed by a Chiral Ferrocenylphosphine-Gold(I) Complex Tetrahedron Letters. 30: 2247-2250. DOI: 10.1016/S0040-4039(00)99660-6  0.807
1989 Yamamoto A, Ito Y, Hayashi T. Asymmetric [3 + 2] cycloaddition of 2-(sulfonylmethyl)-2-propenyl carbonate catalyzed by chiral ferrocenylphosphine-palladium complexes Tetrahedron Letters. 30: 375-378. DOI: 10.1016/S0040-4039(00)95206-7  0.77
1989 Hayashi T, Hayashizaki K, Ito Y. Asymmetric synthesis of axially chiral 1,1′:5′,1″- and 1,1′:4′,1″-ternaphthalenes by asymmetric cross-coupling with a chiral ferrocenylphosphine-nickel catalyst Tetrahedron Letters. 30: 215-218. DOI: 10.1016/S0040-4039(00)95163-3  0.749
1989 Hayashi T, Yamamoto A, Hojo M, Kishi K, Ito Y, Nishioka E, Miura H, Yanagi K. Asymmetric synthesis catalyzed by chiral ferrocenylphosphine-transition metal complexes Journal of Organometallic Chemistry. 370: 129-139. DOI: 10.1016/0022-328X(89)87280-8  0.729
1989 HAYASHI T, YAMAMOTO A, ITO Y, NISHIOKA E, MIURA H, YANAGI K. ChemInform Abstract: Asymmetric Synthesis Catalyzed by Chiral Ferrocenylphosphine-Transition-Metal Complexes. Part 8. Palladium-Catalyzed Asymmetric Allylic Amination. Cheminform. 20. DOI: 10.1002/chin.198948089  0.459
1988 Hayashi T. Asymmetric synthesis catalyzed by chiral ferrocenylphosphine-metal complexes Pure and Applied Chemistry. 60: 7-12. DOI: 10.1351/Pac198860010007  0.612
1988 Hayashi T, Kanehira K, Hagihara T, Kumada M. Asymmetric synthesis catalyzed by chiral ferrocenylphosphine-transition metal complexes. 5. Palladium-catalyzed asymmetric allylation of active methine compounds Journal of Organic Chemistry. 53: 113-120. DOI: 10.1021/Jo00236A023  0.646
1988 Hayashi T, Hayashizaki K, Kiyoi T, Ito Y. Asymmetric synthesis catalyzed by chiral ferrocenylphosphine-transition-metal complexes. 6. Practical asymmetric synthesis of 1,1'-binaphthyls via asymmetric cross-coupling with a chiral [(alkoxyalkyl)ferrocenyl]monophosphine/nickel catalyst Journal of the American Chemical Society. 110: 8153-8156. DOI: 10.1021/Ja00232A030  0.545
1988 Hayashi T, Matsumoto Y, Ito Y. Palladium-catalyzed asymmetric 1,4-disilylation of .alpha.,.beta.-unsaturated ketones: catalytic asymmetric synthesis of .beta.-hydroxy ketones Journal of the American Chemical Society. 110: 5579-5581. DOI: 10.1021/Ja00224A057  0.373
1988 Ito Y, Sawamura M, Kobayashi M, Hayashi T. Asymmetric aldol reaction of α-isocyanoacetamides with aldehydes catalyzed by a chiral ferrocenylphosphine-gold(I) complex Tetrahedron Letters. 29: 6321-6324. DOI: 10.1016/S0040-4039(00)82336-9  0.825
1988 Hayashi T, Kawamura N, Ito Y. Catalytic asymmetric hydrogenation of β-disubstituted α-phenylacrylic acids asymmetric synthesis of carboxylic acids containing two vicinal chiral carbon centers Tetrahedron Letters. 29: 5969-5972. DOI: 10.1016/S0040-4039(00)82242-X  0.728
1988 Hayashi T, Matsumoto Y, Kiyoi T, Ito Y, Kohra S, Tominaga Y, Hosomi A. Stereochemistry and mechanism of asymmetric allylation of aldehydes with optically active allylsiliconates Tetrahedron Letters. 29: 5667-5670. DOI: 10.1016/S0040-4039(00)80841-2  0.76
1988 Hayashi T, Matsumoto Y, Ito Y. Palladium-catalyzed 1, 4-disylation of α, β-unsaturated ketones with 1, 1-dichloro-1-phenyl-2,2,2-trimethyldisilane Tetrahedron Letters. 29: 4147-4150. DOI: 10.1016/S0040-4039(00)80440-2  0.688
1988 Hayashi T, Yamamoto A, Ito Y. Palladium-catalyzed asymmetric intramolecular allylation forming optically active vinylcyclopropane and vinyldihydrofurans Tetrahedron Letters. 29: 669-672. DOI: 10.1016/S0040-4039(00)80179-3  0.748
1988 Ito Y, Sawamura M, Hayashi T. Asymmetric synthesis of threo- and erythro-sphingosines by asymmetric aldol reaction of α-isocyanoacetate catalyzed by a chiral ferrocenylphosphine-gold(I) complex Tetrahedron Letters. 29: 239-240. DOI: 10.1016/S0040-4039(00)80064-7  0.816
1988 Ito Y, Sawamura M, Shirakawa E, Hayashizaki K, Hayashi T. Asymmetric aldol reaction of α-isocyanocarboxylates with paraformaldehyde catalyzed by chiral ferrocenylphosphine-gold(I) complexes: Catalytic asymmetric synthesis of α-alkylserines Tetrahedron Letters. 29: 235-238. DOI: 10.1016/S0040-4039(00)80063-5  0.805
1988 Ito Y, Sawamura M, Shirakawa E, Hayashizaki K, Hayashi T. Asymmetric synthesis of β-hydroxy-α-alkylamino acids by asymmetric aldol reaction of α-isocyanocarboxylates catalyzed by chiral ferrocenylphosphine-gold(I) complexes Tetrahedron. 44: 5253-5262. DOI: 10.1016/S0040-4020(01)86034-8  0.804
1988 Hayashi T, Yamamoto A, Ito Y. Asymmetric cyclization of 2-butenylene dicarbamates catalyzed by chiral ferrocenylphosphine-palladium complexes: Catalytic asymmetric synthesis of optically active 2-amino-3-butenols Tetrahedron Letters. 29: 99-102. DOI: 10.1016/0040-4039(88)80027-3  0.749
1988 Hayashi T, Yamamoto A, Ito Y. Stereochemistry and mechanism of the ligand-coupling reaction of an optically active acetylacetonato(π-allyl) palladium complex Journal of Organometallic Chemistry. 338: 261-264. DOI: 10.1016/0022-328X(88)80511-4  0.756
1987 Hayashi T, Matsumoto Y, Ito Y. Anti Stereochemistry inSE″ Reaction of an Optically Active 2,4-Dienylsilane Chemistry Letters. 16: 2037-2040. DOI: 10.1246/Cl.1987.2037  0.35
1987 Hayashi T, Yamamoto A, Ito Y. Asymmetric Allylic Alkylation of 1,3-Disubstituted 2-Propenyl Acetates Catalyzed by a Chiral Ferrocenylphosphine–Palladium Complex Chemistry Letters. 16: 177-180. DOI: 10.1246/Cl.1987.177  0.622
1987 Hayashi T, Yamamoto A, Iwata T, Ito Y. 1,1,1-Trichloro-2,2,2-trimethyldisilane: reagent for stereospecific silylation of π-allylpalladium complexes Journal of the Chemical Society, Chemical Communications. 398-399. DOI: 10.1039/C39870000398  0.467
1987 Hayashi T, Kawamura N, Ito Y. Asymmetric hydrogenation of trisubstituted acrylic acids catalyzed by a chiral (aminoalkyl)ferrocenylphosphine-rhodium complex Journal of the American Chemical Society. 109: 7876-7878. DOI: 10.1021/Ja00259A043  0.495
1987 Ito Y, Sawamura M, Matsuoka M, Matsumoto Y, Hayashi T. Palladium-catalyzed allylation of α-isocyanocarboxylates Tetrahedron Letters. 28: 4849-4852. DOI: 10.1016/S0040-4039(00)96642-5  0.802
1987 Hayashi T, Yamamoto A, Ito Y. Palladium(0)-catalyzed cyclization of 2-butenylene dicarbamates forming 4-vinyl-2-oxazolidones Tetrahedron Letters. 28: 4837-4840. DOI: 10.1016/S0040-4039(00)96638-3  0.773
1987 Ito Y, Sawamura M, Hayashi T. Asymmetric aldol reaction of an isocyanoacetate with aldehydes bychiral ferrocenylphosphine-gold(I) complexes: Design and preparation of new efficient ferrocenylphosphine ligands Tetrahedron Letters. 28: 6215-6218. DOI: 10.1016/S0040-4039(00)61850-6  0.811
1987 Hayashi T, Kumada M, Higuchi T, Hirotsu K. Asymmetric synthesis catalyzed by chiral ferrocenylphosphine-transition metal complexes Journal of Organometallic Chemistry. 334: 195-203. DOI: 10.1016/0022-328X(87)80049-9  0.348
1986 Hayashi T, Yamamoto A, Ito Y. Kinetic resolution of racemic allyl acetates in asymmetric allylic alkylation catalysed by a chiral ferrocenylphosphine–palladium complex Journal of the Chemical Society, Chemical Communications. 1090-1092. DOI: 10.1039/C39860001090  0.579
1986 Hayashi T, Konishi M, Okamoto Y, Kabeta K, Kumada M. Asymmetric synthesis catalyzed by chiral ferrocenylphosphine-transition metal complexes. 3. Preparation of optically active allylsilanes by palladium-catalyzed asymmetric Grignard cross-coupling The Journal of Organic Chemistry. 51: 3772-3781. DOI: 10.1021/Jo00370A006  0.659
1986 Hayashi T, Yamamoto A, Hagihara T. Stereo- and regiochemistry in palladium-catalyzed nucleophilic substitution of optically active (E)- and (Z)-allyl acetates The Journal of Organic Chemistry. 51: 723-727. DOI: 10.1021/Jo00355A025  0.365
1986 Ito Y, Sawamura M, Hayashi T. Catalytic asymmetric aldol reaction: reaction of aldehydes with isocyanoacetate catalyzed by a chiral ferrocenylphosphine-gold(I) complex Journal of the American Chemical Society. 108: 6405-6406. DOI: 10.1021/Ja00280A056  0.806
1986 Hayashi T, Yamamoto A, Hagihara T, Ito Y. Modification of optically active ferrocenylphosphine ligands for palladium-catalyzed asymmetric allylic alkylation Tetrahedron Letters. 27: 191-194. DOI: 10.1016/S0040-4039(00)83974-X  0.729
1986 Hayashi T, Kumada M. Optically Active Allylsilanes Organometallic Syntheses. 514-516. DOI: 10.1016/B978-0-444-42607-9.50144-3  0.468
1986 Hayashi T, Yamamoto A, Ito Y. Kinetic Resolution of Racemic Allyl Acetates in Asymmetric Allylic Alkylation Catalysed by a Chiral Ferrocenylphosphine-Palladium Complex. Cheminform. 17. DOI: 10.1002/Chin.198651076  0.578
1985 Hayashi T, Kabeta K. Preparation of optically active allylsilanes by catalytic asymmetric hydrosilylation of 1-arylbutadienes1 Tetrahedron Letters. 26: 3023-3026. DOI: 10.1016/S0040-4039(00)98608-8  0.522
1985 Hayashi T, Konishi M, Yokota K, Kumada M. Regio- and stereo-chemistry in allylation of aryl Grignard reagents catalyzed by phosphine-nickel and -palladium complexes Journal of Organometallic Chemistry. 285: 359-373. DOI: 10.1016/0022-328X(85)87380-0  0.705
1985 HAYASHI T. Preparation and reaction of optically active allylsilanes. Journal of Synthetic Organic Chemistry, Japan. 43: 419-428. DOI: 10.1002/Chin.198543374  0.417
1984 Hayashi T, Konishi M, Kumada M. Stereochemistry of the reaction of an optically active π-allylpalladium complex with nucleophiles Journal of the Chemical Society, Chemical Communications. 107-108. DOI: 10.1039/C39840000107  0.638
1984 Hayashi T, Okamoto Y, Kabeta K, Hagihara T, Kumada M. Optically active allylsilanes. 8. Stereochemistry in the reaction of optically active allylsilanes with m-chloroperoxybenzoic acid The Journal of Organic Chemistry. 49: 4224-4226. DOI: 10.1021/Jo00196A023  0.522
1984 Hayashi T, Konishi M, Kobori Y, Kumada M, Higuchi T, Hirotsu K. Dichloro[1,1'-bis(diphenylphosphino)ferrocene]palladium(II): an effective catalyst for cross-coupling of secondary and primary alkyl Grignard and alkylzinc reagents with organic halides Journal of the American Chemical Society. 106: 158-163. DOI: 10.1021/Ja00313A032  0.575
1984 Hayashi T, Kabeta K, Kumada M. Selective synthesis of (E)-crotylsilanes by reaction of crotylmagnesium bromide with hydrosilanes in the presence of dichloro[1,1′-bis(diphenylphosphino)ferrocene]nickel(II) Tetrahedron Letters. 25: 1499-1500. DOI: 10.1016/S0040-4039(01)80196-9  0.626
1983 Hayashi T, Hagihara T, Katsuro Y, Kumada M. Asymmetric Cross-coupling of Organozinc Reagents with Alkenyl Bromides Catalyzed by a Chiral Ferrocenylphosphine-Palladium Complex Bulletin of the Chemical Society of Japan. 56: 363-364. DOI: 10.1246/Bcsj.56.363  0.661
1983 Hayashi T, Konishi M, Kumada M. Chirality transfer from optically active allylsilanes to π-allylpalladium complexes Journal of the Chemical Society, Chemical Communications. 736-737. DOI: 10.1039/C39830000736  0.604
1983 Hayashi T, Konishi M, Fukushima M, Kanehira K, Hioki T, Kumada M. Chiral (.beta.-aminoalkyl)phosphines. Highly efficient phosphine ligands for catalytic asymmetric Grignard cross-coupling The Journal of Organic Chemistry. 48: 2195-2202. DOI: 10.1021/Jo00161A013  0.601
1983 Hayashi T, Konishi M, Kumada M. Optically active allylsilanes. 4. Enantioselective allylation of aldehydes with an optically active allylsilane The Journal of Organic Chemistry. 48: 281-282. DOI: 10.1021/Jo00150A034  0.525
1983 Hayashi T, Kabeta K, Yamamoto T, Tamao K, Kumada M. Optically active cyclic allylsilanes Tetrahedron Letters. 24: 5661-5664. DOI: 10.1016/S0040-4039(00)94167-4  0.701
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