Richard Hadley Holm - Publications

Affiliations: 
1962-1965 Harvard University, Cambridge, MA, United States 
 1965-1967 University of Wisconsin, Madison, Madison, WI 
 1967-1975 Massachusetts Institute of Technology, Cambridge, MA, United States 
 1975-1980 Stanford University, Palo Alto, CA 
 1980-2021 Chemistry Harvard University, Cambridge, MA, United States 
Area:
transition element chemistry
Website:
http://faculty.chemistry.harvard.edu/holm

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Year Citation  Score
2019 Xu G, Zhou J, Wang Z, Holm RH, Chen XD. Controlled Incorporation of Nitrides into W-Fe-S Clusters. Angewandte Chemie (International Ed. in English). PMID 31489739 DOI: 10.1002/Anie.201908968  0.502
2018 Xu G, Wang Z, Ling R, Zhou J, Chen XD, Holm RH. Ligand metathesis as rational strategy for the synthesis of cubane-type heteroleptic iron-sulfur clusters relevant to the FeMo cofactor. Proceedings of the National Academy of Sciences of the United States of America. PMID 29654147 DOI: 10.1073/Pnas.1801025115  0.516
2016 Holm RH, Lo W. Structural Conversions of Synthetic and Protein-Bound Iron-Sulfur Clusters. Chemical Reviews. 116: 13685-13713. PMID 27933770 DOI: 10.1021/Acs.Chemrev.6B00276  0.477
2014 Ha Y, Tenderholt AL, Holm RH, Hedman B, Hodgson KO, Solomon EI. Sulfur K-edge X-ray absorption spectroscopy and density functional theory calculations on monooxo Mo(IV) and bisoxo Mo(VI) bis-dithiolenes: insights into the mechanism of oxo transfer in sulfite oxidase and its relation to the mechanism of DMSO reductase. Journal of the American Chemical Society. 136: 9094-105. PMID 24884723 DOI: 10.1021/Ja503316P  0.33
2014 Lee SC, Lo W, Holm RH. Developments in the biomimetic chemistry of cubane-type and higher nuclearity iron-sulfur clusters. Chemical Reviews. 114: 3579-600. PMID 24410527 DOI: 10.1021/Cr4004067  0.63
2013 Tan LL, Holm RH, Lee SC. Structural Analysis of Cubane-Type Iron Clusters. Polyhedron. 58: 206-217. PMID 24072952 DOI: 10.1016/J.Poly.2013.02.031  0.59
2012 Zhang X, Huang D, Chen YS, Holm RH. Synthesis of binucleating macrocycles and their nickel(II) hydroxo- and cyano-bridged complexes with divalent ions: anatomical variation of ligand features. Inorganic Chemistry. 51: 11017-29. PMID 23030366 DOI: 10.1021/Ic301506X  0.375
2012 Lo W, Zhang P, Ling CC, Huang S, Holm RH. Formation, spectroscopic characterization, and solution stability of an [Fe4S4]2+ cluster derived from β-cyclodextrin dithiolate. Inorganic Chemistry. 51: 9883-92. PMID 22934734 DOI: 10.1021/Ic301324U  0.475
2012 Holm RH, Maroney MJ. 50 Years of metals in biology: the Gordon Research Conference. Metallomics : Integrated Biometal Science. 4: 401-2. PMID 22535189 DOI: 10.1039/C2Mt90017C  0.46
2012 Zheng B, Chen XD, Zheng SL, Holm RH. Selenium as a structural surrogate of sulfur: template-assisted assembly of five types of tungsten-iron-sulfur/selenium clusters and the structural fate of chalcogenide reactants. Journal of the American Chemical Society. 134: 6479-90. PMID 22424175 DOI: 10.1021/Ja3010539  0.501
2012 Tenderholt AL, Hodgson KO, Hedman B, Holm RH, Solomon EI. Substrate and metal control of barrier heights for oxo transfer to Mo and W bis-dithiolene sites. Inorganic Chemistry. 51: 3436-42. PMID 22372518 DOI: 10.1021/Ic2020397  0.325
2011 Majumdar A, Holm RH. Specific incorporation of chalcogenide bridge atoms in molybdenum/tungsten-iron-sulfur single cubane clusters. Inorganic Chemistry. 50: 11242-51. PMID 21985054 DOI: 10.1021/Ic2018117  0.757
2011 Lo W, Huang S, Zheng SL, Holm RH. Cubane-type Fe4S4 clusters with chiral thiolate ligation: formation by ligand substitution, detection of intermediates by 1H NMR, and solid state structures including spontaneous resolution upon crystallization. Inorganic Chemistry. 50: 11082-90. PMID 21942299 DOI: 10.1021/Ic2016269  0.42
2011 Huang D, Makhlynets OV, Tan LL, Lee SC, Rybak-Akimova EV, Holm RH. Fast carbon dioxide fixation by 2,6-pyridinedicarboxamidato-nickel(II)-hydroxide complexes: influence of changes in reactive site environment on reaction rates. Inorganic Chemistry. 50: 10070-81. PMID 21905646 DOI: 10.1021/Ic200942U  0.539
2011 Xi B, Holm RH. The [MoFe3S4]2+ oxidation state: synthesis, substitution reactions, and structures of phosphine-ligated cubane-type clusters with the S=2 ground state. Inorganic Chemistry. 50: 6280-8. PMID 21648449 DOI: 10.1021/Ic200641K  0.637
2011 Lo W, Scott TA, Zhang P, Ling CC, Holm RH. Stabilities of cubane type [Fe₄S₄(SR)₄](2-) clusters in partially aqueous media. Journal of Inorganic Biochemistry. 105: 497-508. PMID 21329647 DOI: 10.1016/J.Jinorgbio.2010.12.009  0.689
2011 Huang D, Makhlynets OV, Tan LL, Lee SC, Rybak-Akimova EV, Holm RH. Kinetics and mechanistic analysis of an extremely rapid carbon dioxide fixation reaction. Proceedings of the National Academy of Sciences of the United States of America. 108: 1222-7. PMID 21220298 DOI: 10.1073/Pnas.1017430108  0.545
2011 Holm RH, Solomon EI, Majumdar A, Tenderholt A. Comparative molecular chemistry of molybdenum and tungsten and its relation to hydroxylase and oxotransferase enzymes Coordination Chemistry Reviews. 255: 993-1015. DOI: 10.1016/J.Ccr.2010.10.017  0.7
2010 Deng L, Majumdar A, Lo W, Holm RH. Stabilization of 3:1 site-differentiated cubane-type clusters in the [Fe(4)S(4)](1+) core oxidation state by tertiary phosphine ligation: synthesis, core structural diversity, and S = 1/2 ground states. Inorganic Chemistry. 49: 11118-26. PMID 21038882 DOI: 10.1021/Ic101702B  0.81
2010 Tenderholt AL, Wang JJ, Szilagyi RK, Holm RH, Hodgson KO, Hedman B, Solomon EI. Sulfur K-edge X-ray absorption spectroscopy and density functional calculations on Mo(IV) and Mo(VI)=O bis-dithiolenes: insights into the mechanism of oxo transfer in DMSO reductase and related functional analogues. Journal of the American Chemical Society. 132: 8359-71. PMID 20499905 DOI: 10.1021/Ja910369C  0.368
2010 Huang D, Holm RH. Reactions of the terminal Ni(II)-OH group in substitution and electrophilic reactions with carbon dioxide and other substrates: structural definition of binding modes in an intramolecular Ni(II)...Fe(II) bridged site. Journal of the American Chemical Society. 132: 4693-701. PMID 20218565 DOI: 10.1021/Ja1003125  0.428
2010 Chakrabarti M, Deng L, Holm RH, Münck E, Bominaar EL. The modular nature of all-ferrous edge-bridged double cubanes. Inorganic Chemistry. 49: 1647-50. PMID 20073485 DOI: 10.1021/Ic902050K  0.806
2010 Groysman S, Majumdar A, Zheng SL, Holm RH. Reactions of monodithiolene tungsten(VI) sulfido complexes with copper(I) in relation to the structure of the active site of carbon monoxide dehydrogenase. Inorganic Chemistry. 49: 1082-9. PMID 20030373 DOI: 10.1021/Ic902066M  0.703
2010 Zhou H, Su W, Achim C, Rao PV, Holm RH. ChemInform Abstract: High-Nuclearity Sulfide-Rich Molybdenum-Iron-Sulfur Clusters: Reevaluation and Extension. Cheminform. 33: no-no. DOI: 10.1002/chin.200237025  0.6
2010 Gray TG, Rudzinski CM, Nocera DG, Holm RH. ChemInform Abstract: Highly Emissive Hexanuclear Rhenium(III) Clusters Containing the Cubic Cores [Re6S8]2+ and [Re6Se8]2+. Cheminform. 31: no-no. DOI: 10.1002/chin.200009009  0.548
2010 FRANOLIC JD, LONG JR, HOLM RH. ChemInform Abstract: Comprehensive Tungsten-Iodine Cluster Chemistry: Isolated Intermediates in the Solid-State Nucleation of (W6I14)2-. Cheminform. 26: no-no. DOI: 10.1002/chin.199547044  0.47
2010 LONG JR, WILLIAMSON AS, HOLM RH. ChemInform Abstract: Dimensional Reduction of Re6S8Cl2: Sheets, Chains and Discrete Clusters Composed of Chloride-Terminated (Re6Q8)2+ (Q: S, Se) Cores. Cheminform. 26: no-no. DOI: 10.1002/chin.199517018  0.464
2010 SCHULTZ BE, GHELLER SF, MUETTERTIES MC, SCOTT MJ, HOLM RH. ChemInform Abstract: Molybdenum-Mediated Oxygen Atom Transfer: An Improved Analogue Reaction System of the Molybdenum Oxotransferases. Cheminform. 24: no-no. DOI: 10.1002/chin.199335126  0.363
2010 HOLM RH, DONAHUE JP. ChemInform Abstract: A Thermodynamic Scale for Oxygen Atom Transfer Reactions Cheminform. 24: no-no. DOI: 10.1002/chin.199328330  0.536
2010 YAGHI OM, SCOTT MJ, HOLM RH. ChemInform Abstract: Rhenium-Selenium-Chlorine Solid Phases: Cluster Excision and Core Substitution Reactions of Molecular Species. Cheminform. 24: no-no. DOI: 10.1002/chin.199306034  0.587
2010 HOLM RH, CIURLI S, WEIGEL JA. ChemInform Abstract: Subsite-Specific Structures and Reactions in Native and Synthetic (4Fe - 4S) Cubane-Type Clusters Cheminform. 22: no-no. DOI: 10.1002/CHIN.199139264  0.625
2009 Deng L, Bill E, Wieghardt K, Holm RH. Cubane-type Co4S4 clusters: synthesis, redox series, and magnetic ground states. Journal of the American Chemical Society. 131: 11213-21. PMID 19722678 DOI: 10.1021/Ja903847A  0.665
2009 Huang D, Deng L, Sun J, Holm RH. Cleavage of Ni-(mu(2)-S)-Ni bridges in dinuclear nickel(II) dithiolate pincer complexes and related reactions. Inorganic Chemistry. 48: 6159-66. PMID 19459662 DOI: 10.1021/Ic900494U  0.567
2009 Chakrabarti M, Deng L, Holm RH, Münck E, Bominaar EL. Mössbauer, electron paramagnetic resonance, and theoretical studies of a carbene-based all-ferrous Fe4S4 cluster: electronic origin and structural identification of the unique spectroscopic site. Inorganic Chemistry. 48: 2735-47. PMID 19326927 DOI: 10.1021/Ic802192W  0.816
2009 Groysman S, Holm RH. Biomimetic chemistry of iron, nickel, molybdenum, and tungsten in sulfur-ligated protein sites. Biochemistry. 48: 2310-20. PMID 19206188 DOI: 10.1021/Bi900044E  0.39
2009 Groysman S, Holm RH. A series of mononuclear quasi-two-coordinate copper(I) complexes employing a sterically demanding thiolate ligand. Inorganic Chemistry. 48: 621-7. PMID 19138143 DOI: 10.1021/Ic801836K  0.318
2008 Groysman S, Wang JJ, Tagore R, Lee SC, Holm RH. A biomimetic approach to oxidized sites in the xanthine oxidoreductase family: synthesis and stereochemistry of tungsten(VI) analogue complexes. Journal of the American Chemical Society. 130: 12794-807. PMID 18763763 DOI: 10.1021/Ja804000K  0.573
2008 Deng L, Holm RH. Stabilization of fully reduced iron-sulfur clusters by carbene ligation: the [FenSn]0 oxidation levels (n = 4, 8). Journal of the American Chemical Society. 130: 9878-86. PMID 18593124 DOI: 10.1021/Ja802111W  0.661
2008 Tenderholt AL, Szilagyi RK, Holm RH, Hodgson KO, Hedman B, Solomon EI. Electronic control of the "Bailar twist" in formally d0-d2 molybdenum tris(dithiolene) complexes: a sulfur K-edge X-ray absorption spectroscopy and density functional theory study. Inorganic Chemistry. 47: 6382-92. PMID 18517189 DOI: 10.1021/Ic800494H  0.339
2008 Scott TA, Holm RH. VFe3S4 single and double cubane clusters: synthesis, structures, and dependence of redox potentials and electron distribution on ligation and heterometal. Inorganic Chemistry. 47: 3426-32. PMID 18366157 DOI: 10.1021/Ic702372F  0.714
2008 McNaughton RL, Lim BS, Knottenbelt SZ, Holm RH, Kirk ML. Spectroscopic and electronic structure studies of symmetrized models for reduced members of the dimethylsulfoxide reductase enzyme family. Journal of the American Chemical Society. 130: 4628-36. PMID 18341333 DOI: 10.1021/Ja074691B  0.631
2008 Pryadun R, Holm RH. A new class of binuclear and trinuclear iron-sulfur clusters derived from bis[bis(trimethylsilyl)amido]iron(II). Inorganic Chemistry. 47: 3366-70. PMID 18327895 DOI: 10.1021/Ic7023742  0.501
2008 Lee SC, Holm RH. Toward an expanded oxygen atom transfer reactivity scale: Computational investigation of the energetics of oxo transfer reaction couples Inorganica Chimica Acta. 361: 1166-1176. DOI: 10.1016/J.Ica.2007.10.047  0.506
2007 Wang JJ, Holm RH. Silylation, sulfidation, and benzene-1,2-dithiolate complexation reactions of oxo- and oxosulfidomolybdates(VI) and -tungstates(VI). Inorganic Chemistry. 46: 11156-64. PMID 18044955 DOI: 10.1021/Ic701294Y  0.379
2007 Hlavinka ML, Miyaji T, Staples RJ, Holm RH. Hydroxide-promoted core conversions of molybdenum-iron-sulfur edge-bridged double cubanes: oxygen-ligated topological PN clusters. Inorganic Chemistry. 46: 9192-200. PMID 17892284 DOI: 10.1021/Ic701070W  0.358
2007 Tenderholt AL, Szilagyi RK, Holm RH, Hodgson KO, Hedman B, Solomon EI. Sulfur K-edge XAS of WVO vs. MoVO bis(dithiolene) complexes: contributions of relativistic effects to electronic structure and reactivity of tungsten enzymes. Journal of Inorganic Biochemistry. 101: 1594-600. PMID 17720249 DOI: 10.1016/J.Jinorgbio.2007.07.011  0.338
2007 Wang JJ, Groysman S, Lee SC, Holm RH. Synthesis of structural analogues of the oxidized sites in the xanthine oxidoreductase enzyme family. Journal of the American Chemical Society. 129: 7512-3. PMID 17530853 DOI: 10.1021/Ja0724442  0.551
2007 Groysman S, Holm RH. Synthesis and structures of bis(dithiolene)tungsten(IV,VI) thiolate and selenolate complexes: approaches to the active sites of molybdenum and tungsten formate dehydrogenases. Inorganic Chemistry. 46: 4090-102. PMID 17432849 DOI: 10.1021/Ic062441A  0.393
2007 Sun J, Tessier C, Holm RH. Sulfur ligand substitution at the nickel(II) sites of cubane-type and cubanoid NiFe3S4 clusters relevant to the C-clusters of carbon monoxide dehydrogenase. Inorganic Chemistry. 46: 2691-9. PMID 17346040 DOI: 10.1021/Ic062362Z  0.488
2007 Pesavento RP, Berlinguette CP, Holm RH. Stabilization of reduced molybdenum-iron-sulfur single- and double-cubane clusters by cyanide ligation. Inorganic Chemistry. 46: 510-6. PMID 17279830 DOI: 10.1021/Ic061704Y  0.684
2007 Holm RH, Ciurli S, Weigel JA. Subsite‐Specific Structures and Reactions in Native and Synthetic [4Fe‐4S] Cubane‐Type Clusters Progress in Inorganic Chemistry. 38: 1-74. DOI: 10.1002/9780470166390.Ch1  0.623
2006 Berlinguette CP, Holm RH. Edge-bridged Mo2Fe6S8 to pN-type Mo2Fe6S9 cluster conversion: structural fate of the attacking sulfide/selenide nucleophile. Journal of the American Chemical Society. 128: 11993-2000. PMID 16953641 DOI: 10.1021/Ja063604X  0.683
2006 Bennett MV, Holm RH. Self-assembly of a tetradecanuclear iron nitride cluster. Angewandte Chemie (International Ed. in English). 45: 5613-6. PMID 16858715 DOI: 10.1002/Anie.200601570  0.648
2006 Wang JJ, Tessier C, Holm RH. Analogue reaction systems of selenate reductase. Inorganic Chemistry. 45: 2979-88. PMID 16562954 DOI: 10.1021/Ic0521630  0.385
2006 Berlinguette CP, Miyaji T, Zhang Y, Holm RH. Precursors to clusters with the topology of the P(N) cluster of nitrogenase: edge-bridged double cubane clusters [(Tp)2Mo2Fe6S8L4]z: synthesis, structures, and electron transfer series. Inorganic Chemistry. 45: 1997-2007. PMID 16499360 DOI: 10.1021/Ic051770K  0.684
2006 Friedle S, Partyka DV, Bennett MV, Holm RH. Synthesis of metal dithiolene complexes by Si-S bond cleavage of a bis(silanylsulfanyl)alkene Inorganica Chimica Acta. 359: 1427-1434. DOI: 10.1016/J.Ica.2005.09.067  0.808
2005 Bennett MV, Stoian S, Bominaar EL, Münck E, Holm RH. Initial members of the family of molecular mid-valent high-nuclearity iron nitrides: [Fe4N2X10]4- and [Fe10N8X12]5- (X = Cl-, Br-). Journal of the American Chemical Society. 127: 12378-86. PMID 16131219 DOI: 10.1021/Ja052150L  0.787
2005 Panda R, Berlinguette CP, Zhang Y, Holm RH. Synthesis of MFe3S4 clusters containing a planar M(II) site (M = Ni, Pd, Pt), a structural element in the C-cluster of carbon monoxide dehydrogenase. Journal of the American Chemical Society. 127: 11092-101. PMID 16076217 DOI: 10.1021/Ja052381S  0.682
2005 Scott TA, Berlinguette CP, Holm RH, Zhou HC. Initial synthesis and structure of an all-ferrous analogue of the fully reduced [Fe4S4]0 cluster of the nitrogenase iron protein. Proceedings of the National Academy of Sciences of the United States of America. 102: 9741-4. PMID 15985547 DOI: 10.1073/Pnas.0504258102  0.823
2005 Jiang J, Holm RH. Reaction systems related to dissimilatory nitrate reductase: nitrate reduction mediated by bis(dithiolene)tungsten complexes. Inorganic Chemistry. 44: 1068-72. PMID 15859288 DOI: 10.1021/Ic040109Y  0.387
2005 Rao PV, Bhaduri S, Jiang J, Hong D, Holm RH. On [Fe4S4]2+ -(mu2-SR)-M II bridge formation in the synthesis of an A-cluster analogue of carbon monoxide dehydrogenase/acetylcoenzyme A synthase. Journal of the American Chemical Society. 127: 1933-45. PMID 15701028 DOI: 10.1021/Ja040222N  0.697
2005 Hong D, Zhang Y, Holm RH. Heterometal cubane-type WFe3S4 and related clusters trigonally symmetrized with hydrotris(3,5-dimethylpyrazolyl)borate Inorganica Chimica Acta. 358: 2303-2311. DOI: 10.1016/J.Ica.2004.11.051  0.457
2004 Dey A, Glaser T, Moura JJ, Holm RH, Hedman B, Hodgson KO, Solomon EI. Ligand K-edge X-ray absorption spectroscopy and DFT calculations on [Fe3S4]0,+ clusters: delocalization, redox, and effect of the protein environment. Journal of the American Chemical Society. 126: 16868-78. PMID 15612726 DOI: 10.1021/Ja0466208  0.466
2004 Partyka DV, Holm RH. Oxygen/sulfur substitution reactions of tetraoxometalates effected by electrophilic carbon and silicon reagents. Inorganic Chemistry. 43: 8609-16. PMID 15606212 DOI: 10.1021/Ic040097G  0.751
2004 Wang JJ, Kryatova OP, Rybak-Akimova EV, Holm RH. Comparative kinetics and mechanism of oxygen and sulfur atom transfer reactions mediated by bis(dithiolene) complexes of molybdenum and tungsten. Inorganic Chemistry. 43: 8092-101. PMID 15578849 DOI: 10.1021/Ic040087F  0.319
2004 Rao PV, Bhaduri S, Jiang J, Holm RH. Sulfur bridging interactions of cis-planar NiII-S2N2 coordination units with nickel(II), copper(I,II), zinc(II), and mercury(II): a library of bridging modes, including NiII(micro2-SR)2MI,II rhombs. Inorganic Chemistry. 43: 5833-49. PMID 15360232 DOI: 10.1021/Ic040055S  0.662
2004 Dey A, Glaser T, Couture MM, Eltis LD, Holm RH, Hedman B, Hodgson KO, Solomon EI. Ligand K-edge X-ray absorption spectroscopy of [Fe4S4]1+,2+,3+ clusters: changes in bonding and electronic relaxation upon redox. Journal of the American Chemical Society. 126: 8320-8. PMID 15225075 DOI: 10.1021/Ja0484956  0.395
2004 Panda R, Zhang Y, McLauchlan CC, Venkateswara Rao P, Tiago de Oliveira FA, Münck E, Holm RH. Initial structure modification of tetrahedral to planar nickel(II) in a nickel-iron-sulfur cluster related to the C-cluster of carbon monoxide dehydrogenase. Journal of the American Chemical Society. 126: 6448-59. PMID 15149242 DOI: 10.1021/Ja030627S  0.677
2004 Enemark JH, Cooney JJ, Wang JJ, Holm RH. Synthetic analogues and reaction systems relevant to the molybdenum and tungsten oxotransferases. Chemical Reviews. 104: 1175-200. PMID 14871153 DOI: 10.1021/Cr020609D  0.497
2004 Lee SC, Holm RH. The clusters of nitrogenase: synthetic methodology in the construction of weak-field clusters. Chemical Reviews. 104: 1135-58. PMID 14871151 DOI: 10.1021/Cr0206216  0.564
2004 Venkateswara Rao P, Holm RH. Synthetic analogues of the active sites of iron-sulfur proteins. Chemical Reviews. 104: 527-59. PMID 14871134 DOI: 10.1021/Cr020615+  0.34
2004 Zhang Y, Holm RH. Structural conversions of molybdenum-iron-sulfur edge-bridged double cubanes and P(n)-type clusters topologically related to the nitrogenase P-cluster. Inorganic Chemistry. 43: 674-82. PMID 14731029 DOI: 10.1021/Ic030259T  0.496
2004 Holm RH. Electron Transfer: Iron-Sulfur Clusters Comprehensive Coordination Chemistry Ii. 8: 61-90. DOI: 10.1016/B0-08-043748-6/08133-0  0.305
2003 Szilagyi RK, Lim BS, Glaser T, Holm RH, Hedman B, Hodgson KO, Solomon EI. Description of the ground state wave functions of Ni dithiolenes using sulfur K-edge X-ray absorption spectroscopy. Journal of the American Chemical Society. 125: 9158-69. PMID 15369373 DOI: 10.1021/Ja029806K  0.627
2003 Partyka DV, Staples RJ, Holm RH. Nucleophilic reactivity and oxo/sulfido substitution reactions of MVIO3 Groups (M = Mo, W). Inorganic Chemistry. 42: 7877-86. PMID 14632504 DOI: 10.1021/Ic030185L  0.724
2003 Daley CJ, Holm RH. Reactions of site-differentiated [Fe4S4]2+, 1+ clusters with sulfonium cations: reactivity analogues of biotin synthase and other members of the S-adenosylmethionine enzyme family. Journal of Inorganic Biochemistry. 97: 287-98. PMID 14511891 DOI: 10.1016/S0162-0134(03)00280-0  0.458
2003 Jalilehvand F, Lim BS, Holm RH, Hedman B, Hodgson KO. X-ray absorption spectroscopy of a structural analogue of the oxidized active sites in the sulfite oxidase enzyme family and related molybdenum(V) complexes. Inorganic Chemistry. 42: 5531-6. PMID 12950200 DOI: 10.1021/Ic030039F  0.61
2003 Zuo JL, Zhou HC, Holm RH. Vanadium-iron-sulfur clusters containing the cubane-type [VFe3S4] core unit: synthesis of a cluster with the topology of the PN cluster of nitrogenase. Inorganic Chemistry. 42: 4624-31. PMID 12870953 DOI: 10.1021/Ic0301369  0.748
2003 Gray TG, Rudzinski CM, Meyer EE, Holm RH, Nocera DG. Spectroscopic and photophysical properties of hexanuclear rhenium(III) chalcogenide clusters. Journal of the American Chemical Society. 125: 4755-70. PMID 12696894 DOI: 10.1021/Ja0286371  0.587
2003 Zhang Y, Holm RH. Synthesis of a molecular Mo2Fe6S9 cluster with the topology of the PN cluster of nitrogenase by rearrangement of an edge-bridged Mo2Fe6S8 double cubane. Journal of the American Chemical Society. 125: 3910-20. PMID 12656626 DOI: 10.1021/Ja0214633  0.485
2003 Lee SC, Holm RH. Speculative synthetic chemistry and the nitrogenase problem. Proceedings of the National Academy of Sciences of the United States of America. 100: 3595-600. PMID 12642670 DOI: 10.1073/Pnas.0630028100  0.542
2003 Zhou HC, Holm RH. Synthesis and reactions of cubane-type iron-sulfur-phosphine clusters, including soluble clusters of nuclearities 8 and 16. Inorganic Chemistry. 42: 11-21. PMID 12513073 DOI: 10.1021/Ic020464T  0.666
2002 Sanakis Y, Yoo SJ, Osterloh F, Holm RH, Münck E. Determination of antiferromagnetic exchange coupling in the tetrahedral thiolate-bridged diferrous complex [Fe2(SEt)6]2-. Inorganic Chemistry. 41: 7081-5. PMID 12495348 DOI: 10.1021/Ic0204629  0.75
2002 Zhang Y, Zuo JL, Zhou HC, Holm RH. Rearrangement of symmetrical dicubane clusters into topological analogues of the P cluster of nitrogenase: nature's choice? Journal of the American Chemical Society. 124: 14292-3. PMID 12452688 DOI: 10.1021/Ja0279702  0.737
2002 Gray TG, Holm RH. Site-differentiated hexanuclear rhenium(III) cyanide clusters [Re(6)Se(8)(PEt(3))(n)()(CN)(6)(-)(n)()](n)()(-)(4) (n = 4, 5) and kinetics of solvate ligand exchange on the cubic [Re(6)Se(8)](2+) Core. Inorganic Chemistry. 41: 4211-6. PMID 12160409 DOI: 10.1021/Ic020214C  0.611
2002 Zhou HC, Su W, Achim C, Rao PV, Holm RH. High-nuclearity sulfide-rich molybdenum[bond]iron[bond]sulfur clusters: reevaluation and extension. Inorganic Chemistry. 41: 3191-201. PMID 12054998 DOI: 10.1021/Ic0201250  0.779
2002 Sung KM, Holm RH. Functional analogue reaction systems of the DMSO reductase isoenzyme family: probable mechanism of S-oxide reduction in oxo transfer reactions mediated by bis(dithiolene)-tungsten(IV,VI) complexes. Journal of the American Chemical Society. 124: 4312-20. PMID 11960460 DOI: 10.1021/Ja012735P  0.606
2002 Laplaza CE, Holm RH. Stability and nickel binding properties of peptides designed as scaffolds for the stabilization of Ni(II)-Fe(4)S(4) bridged assemblies. Journal of Biological Inorganic Chemistry : Jbic : a Publication of the Society of Biological Inorganic Chemistry. 7: 451-60. PMID 11941503 DOI: 10.1007/S00775-001-0320-4  0.801
2002 Musgrave KB, Laplaza CE, Holm RH, Hedman B, Hodgson KO. Structural characterization of metallopeptides designed as scaffolds for the stabilization of nickel(II)-Fe(4)S(4) bridged assemblies by X-ray absorption spectroscopy. Journal of the American Chemical Society. 124: 3083-92. PMID 11902899 DOI: 10.1021/Ja011861Q  0.82
2002 Hauser C, Bill E, Holm RH. Single- and double-cubane clusters in the multiple oxidation states [VFe(3)S(4)](3+,2+,1+). Inorganic Chemistry. 41: 1615-24. PMID 11896732 DOI: 10.1021/Ic011011B  0.488
2002 Fomitchev DV, McLauchlan CC, Holm RH. Heterometal cubane-type MFe(3)S(4) clusters (M = Mo, V) trigonally symmetrized with hydrotris(pyrazolyl)borate(1-) and tris(pyrazolyl)methanesulfonate(1-) capping ligands. Inorganic Chemistry. 41: 958-66. PMID 11849099 DOI: 10.1021/Ic011106D  0.482
2001 Laplaza CE, Holm RH. Helix-loop-helix peptides as scaffolds for the construction of bridged metal assemblies in proteins: the spectroscopic A-cluster structure in carbon monoxide dehydrogenase. Journal of the American Chemical Society. 123: 10255-64. PMID 11603975 DOI: 10.1021/Ja010851M  0.815
2001 Lim BS, Willer MW, Miao M, Holm RH. Monodithiolene molybdenum(V, VI) complexes: a structural analogue of the oxidized active site of the sulfite oxidase enzyme family. Journal of the American Chemical Society. 123: 8343-9. PMID 11516283 DOI: 10.1021/Ja010786G  0.81
2001 Sung KM, Holm RH. Substitution and oxidation reactions of bis(dithiolene)tungsten complexes of potential relevance to enzyme sites. Inorganic Chemistry. 40: 4518-25. PMID 11511194 DOI: 10.1021/Ic010421X  0.661
2001 Achim C, Bominaar EL, Staples RJ, Münck E, Holm RH. Influence of extrinsic factors on electron transfer in a mixed-valence Fe(2+)/Fe(3+) complex: experimental results and theoretical considerations. Inorganic Chemistry. 40: 4389-403. PMID 11487347 DOI: 10.1021/Ic010498L  0.753
2001 Lim BS, Fomitchev DV, Holm RH. Nickel dithiolenes revisited: structures and electron distribution from density functional theory for the three-member electron-transfer series [Ni(S2C2Me2)2]0,1-,2-. Inorganic Chemistry. 40: 4257-62. PMID 11487330 DOI: 10.1021/Ic010138Y  0.613
2001 Sung KM, Holm RH. Oxo transfer reactions mediated by bis(dithiolene)tungsten analogues of the active sites of molybdoenzymes in the DMSO reductase family: comparative reactivity of tungsten and molybdenum. Journal of the American Chemical Society. 123: 1931-43. PMID 11456814 DOI: 10.1021/Ja0036559  0.638
2001 Lim BS, Holm RH. Bis(dithiolene)molybdenum analogues relevant to the DMSO reductase enzyme family: synthesis, structures, and oxygen atom transfer reactions and kinetics. Journal of the American Chemical Society. 123: 1920-30. PMID 11456813 DOI: 10.1021/Ja003546U  0.635
2001 Daley CJ, Holm RH. Reactivity of [Fe4S4(SR)4]2-,3- clusters with sulfonium cations: analogue reaction systems for the initial step in biotin synthase catalysis. Inorganic Chemistry. 40: 2785-93. PMID 11375696 DOI: 10.1021/Ic010039K  0.444
2001 Fomitchev DV, Lim BS, Holm RH. Electron distribution in the nonclassical bis(dithiolene) electron transfer series [M(CO)2(S2C2Me2)2]0/1-/2- (M = Mo, W): assessment by structural, spectroscopic, and density functional theory results. Inorganic Chemistry. 40: 645-54. PMID 11225106 DOI: 10.1021/Ic001046W  0.626
2001 Osterloh F, Achim C, Holm RH. Molybdenum-iron-sulfur clusters of nuclearities eight and sixteen, including a topological analogue of the P-cluster of nitrogenase. Inorganic Chemistry. 40: 224-32. PMID 11170527 DOI: 10.1021/Ic000617H  0.768
2001 Thapper A, Balmes O, Lorber C, Svensson PH, Holm RH, Nordlander E. Synthesis and structural characterization of two tungsten(VI) dioxo complexes with N,O- and N,S-coordinating ligands Inorganica Chimica Acta. 321: 162-166. DOI: 10.1016/S0020-1693(01)00509-6  0.603
2001 Selby HD, Zheng Z, Gray TG, Holm RH. Bridged multiclusters derived from the face-capped octahedral [Re6/III(μ3-Se)8]2+ cluster core Inorganica Chimica Acta. 312: 205-209. DOI: 10.1016/S0020-1693(00)00324-8  0.42
2000 Nivorozhkin AL, Segal BM, Musgrave KB, Kates SA, Hedman B, Hodgson KO, Holm RH. Metallocyclopeptide complexes with MII(S.Cys)4 chromophores. Inorganic Chemistry. 39: 2306-13. PMID 12526490 DOI: 10.1021/Ic990421L  0.629
2000 Sung KM, Holm RH. Synthesis and structures of bis(dithiolene)-tungsten(IV) complexes related to the active sites of tungstoenzymes. Inorganic Chemistry. 39: 1275-81. PMID 12526419 DOI: 10.1021/Ic991153U  0.652
2000 Osterloh F, Segal BM, Achim C, Holm RH. Reduced mono-, di-, and tetracubane-type clusters containing the [MoFe3S4]2+ core stabilized by tertiary phosphine ligation. Inorganic Chemistry. 39: 980-9. PMID 12526378 DOI: 10.1021/Ic991016X  0.817
2000 Lim BS, Donahue JP, Holm RH. Synthesis and structures of bis(dithiolene)molybdenum complexes related to the active sites of the DMSO reductase enzyme family. Inorganic Chemistry. 39: 263-73. PMID 11272534 DOI: 10.1021/Ic9908672  0.765
2000 Miao M, Willer MW, Holm RH. Oxo/sulfidotungstate(VI) as precursors to W(VI)O2, W(VI)OS, and W(VI)S2 complexes and W(IV)-dithiolene chelate rings. Inorganic Chemistry. 39: 2843-9. PMID 11232822 DOI: 10.1021/Ic000047L  0.806
2000 Musgrave KB, Lim BS, Sung KM, Holm RH, Hedman B, Hodgson KO. X-ray spectroscopy of enzyme active site analogues and related molecules: bis(dithiolene)molybdenum(IV) and -tungsten(IV,VI) complexes with variant terminal ligands. Inorganic Chemistry. 39: 5238-47. PMID 11154582 DOI: 10.1021/Ic000601R  0.739
2000 Lim BS, Sung KM, Holm RH. Structural and functional bis(dithiolene)-molybdenum/tungsten active site analogues of the dimethylsulfoxide reductase enzyme family [13] Journal of the American Chemical Society. 122: 7410-7411. DOI: 10.1021/Ja001197Y  0.579
2000 Zhou C, Raebiger JW, Segal BM, Holm RH. The influence of net charge on the redox potentials of Fe4S4 cubane-type clusters in aprotic solvents Inorganica Chimica Acta. 300: 892-902. DOI: 10.1016/S0020-1693(99)00593-9  0.667
1999 Osterloh F, Sanakis Y, Staples RJ, Münck E, Holm RH. A Molybdenum-Iron-Sulfur Cluster Containing Structural Elements Relevant to the P-Cluster of Nitrogenase. Angewandte Chemie (International Ed. in English). 38: 2066-2070. PMID 34182709 DOI: 10.1002/(SICI)1521-3773(19990712)38:13/14<2066::AID-ANIE2066>3.0.CO;2-K  0.72
1999 Gray TG, Rudzinski CM, Nocera DG, Holm RH. Highly Emissive Hexanuclear Rhenium(III) Clusters Containing the Cubic Cores [Re(6)S(8)](2+) and [Re(6)Se(8)](2+). Inorganic Chemistry. 38: 5932-5933. PMID 11671297 DOI: 10.1021/Ic991195I  0.608
1999 Zheng Z, Gray TG, Holm RH. Synthesis and Structures of Solvated Monoclusters and Bridged Di- and Triclusters Based on the Cubic Building Block [Re(6)(&mgr;(3)-Se)(8)](2+). Inorganic Chemistry. 38: 4888-4895. PMID 11671221 DOI: 10.1021/Ic9906050  0.63
1999 Musgrave KB, Donahue JP, Lorber C, Holm RH, Hedman B, Hodgson KO. An x-ray spectroscopic investigation of bis(dithiolene)molybdenum(IV,V,VI) and -tungsten(IV,V,VI) complexes: Symmetrized structural representations of the active sites of molybdoenzymes in the DMSO reductase family and of tungstoenzymes in the AOR and F(M)DH families Journal of the American Chemical Society. 121: 10297-10307. DOI: 10.1021/Ja990753P  0.728
1999 Thapper A, Donahue JP, Musgrave KB, Willer MW, Nordlander E, Hedman B, Hodgson KO, Holm RH. The Unperturbed Oxo−Sulfido Functional Groupcis-MoVIOS Related to That in the Xanthine Oxidase Family of Molybdoenzymes:  Synthesis, Structural Characterization, and Reactivity Aspects Inorganic Chemistry. 38: 4104-4114. DOI: 10.1021/Ic990440V  0.797
1999 Goddard CA, Holm RH. Synthesis and reactivity aspects of the bis(dithiolene) chalcogenide series [WIVQ(S2C2R2)2] 2- (Q = O, S, Se) Inorganic Chemistry. 38: 5389-5398. DOI: 10.1021/Ic9903329  0.366
1999 Osterloh F, Sanakis Y, Staples RJ, Münck E, Holm RH. A molybdenum-iron-sulfur cluster containing structural elements relevant to the P-cluster of nitrogenase Angewandte Chemie - International Edition. 38: 2066-2070. DOI: 10.1002/(Sici)1521-3773(19990712)38:13/14<2066::Aid-Anie2066>3.0.Co;2-K  0.736
1999 Osterloh F, Sanakis Y, Staples RJ, Münck E, Holm RH. A Molybdenum-Iron-Sulfur Cluster Containing Structural Elements Relevant to the P-Cluster of Nitrogenase Angewandte Chemie International Edition. 38: 2066-2070. DOI: 10.1002/(SICI)1521-3773(19990712)38:13/14<2066::AID-ANIE2066>3.0.CO;2-K  0.721
1999 Osterloh F, Sanakis Y, Staples RJ, Münck E, Holm RH. Ein Molybdän-Eisen-Schwefel-Cluster mit Strukturelementen des Nitrogenase-P-Clusters Angewandte Chemie. 111: 2199-2203. DOI: 10.1002/(Sici)1521-3757(19990712)111:13/14<2199::Aid-Ange2199>3.0.Co;2-Y  0.733
1999 Thapper A, Donahue JP, Musgrave KB, Willer MW, Nordlander E, Hedman B, Hodgson KO, Holm RH. The unperturbed oxo-sulfido functional group cis-MoVIOS related to that in the xanthine oxidase family of molybdoenzymes: synthesis, structural characterization, and reactivity aspects Inorganic Chemistry. 38: 4104-4114.  0.769
1998 Lim BS, Holm RH. Molecular Heme-Cyanide-Copper Bridged Assemblies: Linkage Isomerism, Trends in nu(CN) Values, and Relation to the Heme-a(3)/Cu(B) Site in Cyanide-Inhibited Heme-Copper Oxidases. Inorganic Chemistry. 37: 4898-4908. PMID 11670655 DOI: 10.1021/Ic9801793  0.59
1998 Huang J, Holm RH. Synthesis, Identification, and Reactivity Properties of Symmetrical MoFe(3)S(4) Double Cubanes with Fe-S-Fe and Fe-O-Fe Bridges. Inorganic Chemistry. 37: 2247-2254. PMID 11670381 DOI: 10.1021/Ic971353A  0.488
1998 Donahue JP, Holm RH. 3,4-Bis(1-adamantyl)-1,2-dithiete: the first structurally characterized dithiete unsupported by a ring or benzenoid frame. Acta Crystallographica. Section C, Crystal Structure Communications. 54: 1175-8. PMID 9760719  0.551
1998 Holm RH. [1:3] Site-differentiated and sulfide-bridged cubane clusters in chemistry and biology Pure and Applied Chemistry. 70: 931-938. DOI: 10.1351/Pac199870040931  0.503
1998 Donahue JP, Goldsmith CR, Nadiminti U, Holm RH. Synthesis, structures, and reactivity of bis(dithiolene)molybdenum(IV,VI) complexes related to the active sites of molybdoenzymes Journal of the American Chemical Society. 120: 12869-12881. DOI: 10.1021/Ja982914F  0.812
1998 Lorber C, Donahue JP, Goddard CA, Nordlander E, Holm RH. Synthesis, structures, and oxo transfer reactivity of bis(dithiolene)tungsten(IV,VI) complexes related to the active sites of tungstoenzymes Journal of the American Chemical Society. 120: 8102-8112. DOI: 10.1021/Ja981015O  0.75
1998 Donahue JP, Lorber C, Nordlander E, Holm RH. Molybdenum and tungsten structural analogues of the active sites of the MoIV + [O] → MoVIO oxygen atom transfer couple of DMSO reductases Journal of the American Chemical Society. 120: 3259-3260. DOI: 10.1021/Ja973917F  0.704
1998 Segal BM, Hoveyda HR, Holm RH. Terminal Ligand Assignments Based on Trends in Metal - Ligand Bond Lengths of Cubane-Type [Fe4S4]2+,+ Clusters Inorganic Chemistry. 37: 3440-3443. DOI: 10.1021/Ic980092H  0.656
1998 Goh C, Nivorozhkin A, Yoo SJ, Bominaar EL, Münck E, Holm RH. The Mixed-Valence Double-Cubanoid Cluster [Fe8S12(ButNC)12]: Synthesis, Structure, and Exchange Coupling of a New Structural Array of Four Fe(III) Sites Inorganic Chemistry. 37: 2926-2932. DOI: 10.1021/Ic980085T  0.714
1998 Goh C, Nivorozhkin A, Yoo SJ, Bominaar EL, Münck E, Holm RH. The Mixed-Valence Double-Cubanoid Cluster [Fe8S12(ButNC)12]:  Synthesis, Structure, and Exchange Coupling of a New Structural Array of Four Fe(III) Sites Inorganic Chemistry. 37: 2926-2932. DOI: 10.1021/ic980085t  0.737
1998 Tucci GC, Donahue JP, Holm RH. Comparative Kinetics of Oxo Transfer to Substrate Mediated by Bis(dithiolene)dioxomolybdenum and -tungsten Complexes Inorganic Chemistry. 37: 1602-1608. DOI: 10.1021/Ic971426Q  0.616
1998 Willer MW, Long JR, McLauchlan CC, Holm RH. Ligand Substitution Reactions of [Re6S8Br6]4-: A Basis Set of Re6S8 Clusters for Building Multicluster Assemblies Inorganic Chemistry. 37: 328-333. DOI: 10.1021/Ic970926G  0.808
1998 Willer MW, Long JR, McLauchlan CC, Holm RH. Ligand Substitution Reactions of [Re6S8Br6]4-:  A Basis Set of Re6S8Clusters for Building Multicluster Assemblies Inorganic Chemistry. 37: 328-333. DOI: 10.1021/ic970926g  0.783
1998 Goh C, Holm RH. Synthesis and structures of the cuboidal iron-sulfur-nitrosyl-phosphine clusters [Fe4S3(NO)4(PR3)3] 0,1+ (R = Et, Pri, C6H11) Inorganica Chimica Acta. 270: 46-54. DOI: 10.1016/S0020-1693(97)05822-2  0.432
1997 Hoveyda HR, Holm RH. Characterization of the Self-Condensation Equilibrium of [Fe(4)S(4)(SH)(4)](2-): Spectroscopic Identification of a Unique Sulfido-Bridged Acyclic Tricubane Cluster. Inorganic Chemistry. 36: 4571-4578. PMID 11670123  0.344
1997 Raebiger JW, Crawford CA, Zhou J, Holm RH. Reactivity of Cubane-Type [(OC)(3)MFe(3)S(4)(SR)(3)](3-) Clusters (M = Mo, W): Interconversion with Cuboidal [Fe(3)S(4)](0) Clusters and Electron Transfer. Inorganic Chemistry. 36: 994-1003. PMID 11669661 DOI: 10.1021/Ic961122O  0.546
1997 Kauffmann KE, Goddard CA, Zang Y, Holm RH, Münck E. Mössbauer and Magnetization Studies of Heme-Copper-Bridged Assemblies Pertinent to Cytochrome c Oxidase. Inorganic Chemistry. 36: 985-993. PMID 11669660 DOI: 10.1021/Ic960826V  0.606
1997 Beinert H, Holm RH, Münck E. Iron-sulfur clusters: nature's modular, multipurpose structures. Science (New York, N.Y.). 277: 653-9. PMID 9235882 DOI: 10.1126/Science.277.5326.653  0.467
1997 Huang J, Mukerjee S, Segal BM, Akashi H, Zhou J, Holm RH. Molybdenum - Iron sulfide-bridged double cubanes Journal of the American Chemical Society. 119: 8662-8674. DOI: 10.1021/Ja971401Q  0.708
1997 Yoo SJ, Hu Z, Goh C, Bominaar EL, Holm RH, Munck E. Determination of the exchange-coupling constant of an Fe3+-Fe3+ pair in a cubane-type iron-sulfur cluster Journal of the American Chemical Society. 119: 8732-8733. DOI: 10.1021/Ja971171F  0.749
1997 Zhou J, Raebiger JW, Crawford CA, Holm RH. Metal ion incorporation reactions of the cluster [Fe 3S 4(LS 3)] 3-, containing the cuboidal [Fe 3S 4] 0 core Journal of the American Chemical Society. 119: 6242-6250. DOI: 10.1021/Ja9704186  0.527
1997 Zheng Z, Long JR, Holm RH. A basis set of Re6Se8 cluster building blocks and demonstration of their linking capability: Directed synthesis of an Re12Se16 dicluster Journal of the American Chemical Society. 119: 2163-2171. DOI: 10.1021/Ja9638519  0.552
1997 Zhang HH, Filipponi A, Di Cicco A, Scott MJ, Holm RH, Hedman B, Hodgson KO. Multiple-edge XAS studies of cyanide-bridged iron-copper molecular assemblies relevant to cyanide-inhibited heme-copper oxidases using four-body multiple-scattering analysis Journal of the American Chemical Society. 119: 2470-2478. DOI: 10.1021/Ja963300I  0.485
1997 Zheng Z, Holm RH. Cluster Condensation by Thermolysis: Synthesis of a Rhomb-Linked Re12Se16 Dicluster and Factors Relevant to the Formation of the Re24Se32 Tetracluster Inorganic Chemistry. 36: 5173-5178. DOI: 10.1021/Ic970727X  0.423
1997 Zhou C, Holm RH. Comparative Isotropic Shifts, Redox Potentials, and Ligand Binding Propensities of [1:3] Site-Differentiated Cubane-Type [Fe4Q4]2+ Clusters (Q = S, Se) Inorganic Chemistry. 36: 4066-4077. DOI: 10.1021/Ic970254U  0.468
1997 Huang J, Goh C, Holm RH. On the Existence in Solution of Doubly Thiolate-Bridged Double Cubanes Containing the Heterometal [MFe3S4] Core (M = Mo, W) Inorganic Chemistry. 36: 356-361. DOI: 10.1021/Ic960844C  0.434
1997 Holm R, Huang J, Akashi H, Crawford C, Mukerjee S, Raebiger J, Segal B, Zhou C. Recent developments in biologically related metal-sulfur clusters Journal of Inorganic Biochemistry. 67: 246. DOI: 10.1016/S0162-0134(97)80118-3  0.358
1996 Holm RH, Kennepohl P, Solomon EI. Structural and Functional Aspects of Metal Sites in Biology. Chemical Reviews. 96: 2239-2314. PMID 11848828 DOI: 10.1021/Cr9500390  0.317
1996 Gardner MT, Deinum G, Kim Y, Babcock GT, Scott MJ, Holm RH. Vibrational Analysis of a Molecular Heme-Copper Assembly with a Nearly Linear Fe(III)-CN-Cu(II) Bridge: Insight into Cyanide Binding to Fully Oxidized Cytochrome c Oxidase. Inorganic Chemistry. 35: 6878-6884. PMID 11666856 DOI: 10.1021/Ic960575Q  0.493
1996 Zhang HH, Filipponi A, Di Cicco A, Lee SC, Scott MJ, Holm RH, Hedman B, Hodgson KO. Multiple-Edge XAS Studies of Synthetic Iron-Copper Bridged Molecular Assemblies Relevant to Cytochrome c Oxidase. Structure Determination Using Multiple-Scattering Analysis with Statistical Evaluation of Errors. Inorganic Chemistry. 35: 4819-4828. PMID 11666681 DOI: 10.1021/Ic960021N  0.644
1996 Goddard CA, Long JR, Holm RH. Synthesis and Characterization of Four Consecutive Members of the Five-Member [Fe(6)S(8)(PEt(3))(6)](n)()(+) (n = 0-4) Cluster Electron Transfer Series. Inorganic Chemistry. 35: 4347-4354. PMID 11666650 DOI: 10.1021/Ic960052I  0.531
1996 James TL, Cai L, Muetterties MC, Holm RH. Dihydrogen Evolution by Protonation Reactions of Nickel(I). Inorganic Chemistry. 35: 4148-4161. PMID 11666623 DOI: 10.1021/Ic960216V  0.315
1996 Scott MJ, Goddard CA, Holm RH. Molecular Assemblies Containing Unsupported [Fe(III)-(&mgr;(2):eta(2)-RCO(2))-Cu(II)] Bridges. Inorganic Chemistry. 35: 2558-2567. PMID 11666470 DOI: 10.1021/Ic9512035  0.516
1996 Goh C, Segal BM, Huang J, Long JR, Holm RH. Polycubane clusters: Synthesis of [Fe4S4(PR3)4]1+,0 (R = Bu(t), Cy, Pr(i)) and [Fe4S4]0 core aggregation upon loss of phosphine Journal of the American Chemical Society. 118: 11844-11853. DOI: 10.1021/Ja9620200  0.705
1996 Long JR, McCarty LS, Holm RH. A solid-state route to molecular clusters: Access to the solution chemistry of [Re6Q8]2+ (Q = S, Se) core-containing clusters via dimensional reduction Journal of the American Chemical Society. 118: 4603-4616. DOI: 10.1021/Ja960216U  0.567
1996 Long JR, McCarty LS, Holm RH. A Solid-State Route to Molecular Clusters:  Access to the Solution Chemistry of [Re6Q8]2+(Q = S, Se) Core-Containing Clusters via Dimensional Reduction Journal of the American Chemical Society. 118: 4603-4616. DOI: 10.1021/ja960216u  0.491
1996 Zhou J, Hu Z, Miinck E, Holm RH. The cuboidal Fe3S4 cluster: Synthesis, stability, and geometric and electronic structures in a non-protein environment Journal of the American Chemical Society. 118: 1966-1980. DOI: 10.1021/Ja9537843  0.564
1996 Zhou C, Cai L, Holm RH. Synthesis of a [Fe4S4]-S-Ferriheme Bridged Assembly Containing an Isobacteriochlorin Component: A Further Analogue of the Active Site of Sulfite Reductase Inorganic Chemistry. 35: 2767-2772. DOI: 10.1021/Ic951493P  0.492
1995 Holm RH. Chemical approaches to bridged biological metal assemblies Pure and Applied Chemistry. 67: 217-224. DOI: 10.1351/Pac199567020217  0.482
1995 Zhou J, Holm RH. Synthesis and metal ion incorporation reactions of the cuboidal Fe3S4 cluster Journal of the American Chemical Society. 117: 11353-11354. DOI: 10.1021/Ja00150A039  0.431
1995 Cai L, Segal BM, Long JR, Scott MJ, Holm RH. Octanuclear iron-sulfur clusters with symmetrically coupled Fe4S4 and Fe4S5 cores Journal of the American Chemical Society. 117: 8863-8864. DOI: 10.1021/Ja00139A025  0.717
1995 Cai L, Segal BM, Long JR, Scott MJ, Holm RH. Octanuclear Iron-Sulfur Clusters with Symmetrically Coupled Fe4S4 and Fe4S5 Cores Journal of the American Chemical Society. 117: 8863-8864. DOI: 10.1021/ja00139a025  0.518
1995 Franolic JD, Long JR, Holm RH. Comprehensive tungsten - Iodine cluster chemistry: Isolated intermediates in the solid-state nucleation of [W6I14]2- Journal of the American Chemical Society. 117: 8139-8153. DOI: 10.1021/Ja00136A011  0.532
1995 Franolic JD, Long JR, Holm RH. Comprehensive Tungsten-Iodine Cluster Chemistry: Isolated Intermediates in the Solid-State Nucleation of [W6I14]2- Journal of the American Chemical Society. 117: 8139-8153. DOI: 10.1021/ja00136a011  0.467
1995 Scott MJ, Zhang HH, Lee SC, Hedman B, Hodgson KO, Holm RH. Oxygen-Bridged Iron-Copper Assemblies Pertinent to Heme-Copper Oxidases: Synthesis and Structure of an [FeIII-(OH)-CuII] Bridge and Exafs Multiple-Scattering Effects of Linear Oxo and Nonlinear Hydroxo Bridges Journal of the American Chemical Society. 117: 568-569. DOI: 10.1021/Ja00106A080  0.646
1995 Tian ZQ, Donahue JP, Holm RH. Synthesis of new types of dithiolene ligands Inorganic Chemistry. 34: 5567-5572. DOI: 10.1021/Ic00126A029  0.598
1995 MacDonnell FM, Ruhlandt-Senge K, Ellison JJ, Holm RH, Power PP. Sterically encumbered iron(II) thiolate complexes: Synthesis and structure of trigonal planar [Fe(SR)3]- (R = 2,4,6-t-Bu3C6H2) and Mössbauer spectra of two- and three-coordinate complexes Inorganic Chemistry. 34: 1815-1822. DOI: 10.1021/Ic00111A032  0.682
1995 MacDonnell FM, Ruhlandt-Senge K, Ellison JJ, Holm RH, Power PP. Sterically Encumbered Iron(II) Thiolate Complexes: Synthesis and Structure of Trigonal Planar [Fe(SR)3]- (R = 2,4,6-t-Bu3C6H2) and Moessbauer Spectra of Two- and Three-Coordinate Complexes Inorganic Chemistry. 34: 1815-1822. DOI: 10.1021/ic00111a032  0.821
1995 Long JR, Holm RH. Protein-bound iron-sulfur clusters: application of a structural database Inorganica Chimica Acta. 229: 229-239. DOI: 10.1016/0020-1693(94)04249-U  0.601
1995 Long JR, Williamson AS, Holm RH. Dimensional reduction of Re6Se8Cl2: sheets, chains, and discrete clusters composed of chloride-terminated [Re6Q8]2+ (Q = S, Se) cores Angewandte Chemie (International Edition in English). 34: 226-229. DOI: 10.1002/Anie.199502261  0.526
1995 Long JR, Williamson AS, Holm RH. Dimensional Reduction of Re6Se8Cl2: Sheets, Chains, and Discrete Clusters Composed of Chloride-Terminated[Re6Q8]2+(Q S, Se) Cores Angewandte Chemie International Edition in English. 34: 226-229. DOI: 10.1002/anie.199502261  0.476
1995 Long JR, Williamson AS, Holm RH. Verringerung der Dimensionalität von Re6Se8Cl2: Schichten, Ketten und isolierte Cluster von [Re6Q8]2+ (Q = S, Se) mit terminalen Cl-Atomen Angewandte Chemie. 107: 248-251. DOI: 10.1002/Ange.19951070228  0.539
1995 Scott MJ, Zhang HH, Lee SC, Hedman B, Hodgson KO, Holm RH. Oxygen-bridged iron-copper assemblies pertinent to heme-copper oxidases: Synthesis and structure of an [FeIII-(OH)-CuII] bridge and EXAFS multiple-scattering effects of linear oxo and nonlinear hydroxo bridges Journal of the American Chemical Society. 117: 568-569.  0.475
1994 Scott MJ, Holm RH. Molecular assemblies containing linear and bent [FeIII-CN-CuII] bridge units: Synthesis, structures, and relevance to cyanide-inhibited heme - Copper oxidases Journal of the American Chemical Society. 116: 11357-11367. DOI: 10.1021/Ja00104A015  0.312
1994 Long JR, Holm RH. Enumeration and Structural Classification of Clusters Derived from Parent Solids: Metal-Chalcogenide Clusters Composed of Edge-Sharing Tetrahedra Journal of the American Chemical Society. 116: 9987-10002. DOI: 10.1021/Ja00101A020  0.522
1994 Cai L, Holm RH. Synthesis and electron delocalization of [Fe4S4]-S-Fe(III) bridged assemblies related to the exchange-coupled catalytic site of sulfite reductases Journal of the American Chemical Society. 116: 7177-7188. DOI: 10.1021/Ja00095A021  0.399
1994 Lee SC, Scott MJ, Kauffmann K, Münck E, Holm RH. Cyanide poisoning: An analogue to the binuclear site of oxidized cyanide-inhibited cytochrome c oxidase Journal of the American Chemical Society. 116: 401-402. DOI: 10.1021/Ja00080A058  0.669
1994 Cen W, MacDonnell FM, Scott MJ, Holm RH. Heterometal clusters containing the cuboidal Fe4S3 fragment: Synthesis, electron distribution, and reactions Inorganic Chemistry. 33: 5809-5818. DOI: 10.1021/Ic00103A031  0.76
1994 Scott MJ, Lee SC, Holm RH. Synthesis and structural characterization of unsupported [FeIII-CN-CuII] bridges related to that in cyanide-inactivated cytochrome c oxidase Inorganic Chemistry. 33: 4651-4662. DOI: 10.1021/Ic00099A015  0.605
1994 Hendrich MP, Day EP, Wang CP, Synder BS, Holm RH, Münck E. Ground-state electronic structures of binuclear iron(II) sites: Experimental protocol and a consistent description of mössbauer, EPR, and magnetization measurements of the bis(phenolate)-bridged complex [Fe2(salmp)2]2- Inorganic Chemistry. 33: 2848-2856. DOI: 10.1021/Ic00091A028  0.429
1994 Hendrich MP, Day EP, Wang C, Synder BS, Holm RH, Munck E. Ground-State Electronic Structures of Binuclear Iron(II) Sites: Experimental Protocol and a Consistent Description of Moessbauer, EPR, and Magnetization Measurements of the Bis(phenolate)-Bridged Complex [Fe2(salmp)2]2- Inorganic Chemistry. 33: 2848-2856. DOI: 10.1021/ic00091a028  0.576
1993 Lee SC, Holm RH. Synthesis and characterization of an asymmetric bridged assembly containing the unsupported [FeIII-O-CuII] bridge: An analogue of the binuclear site in oxidized cytochrome c oxidase Journal of the American Chemical Society. 115: 11789-11798. DOI: 10.1021/Ja00078A018  0.556
1993 Cen W, Lee SC, Li J, MacDonnell FM, Holm RH. Heterometal dependence of electron distributions and redox potentials in clusters with cubane-type [MFe3S4]z cores Journal of the American Chemical Society. 115: 9515-9523. DOI: 10.1021/Ja00074A016  0.748
1993 Cai L, Weigel JA, Holm RH. Analogs of bridged biological active site assemblies: the Fe4S4-sulfide-heme unit Journal of the American Chemical Society. 115: 9289-9290. DOI: 10.1021/Ja00073A055  0.304
1993 Lee SC, Holm RH. A synthetic analogue of the iron/copper bridged assembly in cytochrome c oxidase Journal of the American Chemical Society. 115: 5833-5834. DOI: 10.1021/Ja00066A065  0.535
1993 Nordlander E, Lee SC, Cen W, Wu ZY, Natoli CR, Di Cicco A, Filipponi A, Hedman B, Hodgson KO, Holm RH. Heterometal cuboidal clusters MFe4S6(PEt3)4Cl (M = vanadium, molybdenum): synthesis, structural analysis by crystallography and EXAFS, and relevance to the core structure of the iron-molybdenum cofactor of nitrogenase Journal of the American Chemical Society. 115: 5549-5558. DOI: 10.1021/Ja00066A024  0.61
1993 Schultz BE, Gheller SF, Muetterties MC, Scott MJ, Holm RH. Molybdenum-mediated oxygen atom transfer: An improved analogue reaction system of the molybdenum oxotransferases Journal of the American Chemical Society. 115: 2714-2722. DOI: 10.1021/Ja00060A021  0.339
1993 Lee SC, Holm RH. Fluoride-bridged dimers: Binuclear copper(II) complexes and iron(III)-copper(II) assemblies Inorganic Chemistry. 32: 4745-4753. DOI: 10.1021/Ic00074A016  0.529
1993 Holm R, Donahue JP. A thermodynamic scale for oxygen atom transfer reactions Polyhedron. 12: 571-589. DOI: 10.1016/S0277-5387(00)84972-4  0.576
1993 Yu SB, Holm RH. Tetrahedral and square-pyramidal sulphur-rich complexes of manganese(II) Polyhedron. 12: 263-266. DOI: 10.1016/S0277-5387(00)81637-X  0.397
1993 Scott MJ, Holm RH. Tetranuclear Cuboidal and Hexanuclear Prismatic Iron–Sulfur–Nitrosyl Clusters Angewandte Chemie International Edition in English. 32: 564-566. DOI: 10.1002/Anie.199305641  0.531
1993 Scott MJ, Holm RH. Vierkernige quaderförmige und sechskernige prismenförmige Nitrosylsulfidoeisen-Cluster Angewandte Chemie. 105: 621-623. DOI: 10.1002/Ange.19931050434  0.529
1993 Nordlander E, Lee SC, Cen W, Wu ZY, Natoli CR, Di Cicco A, Filipponi A, Hedman B, Hodgson KO, Holm RH. Heterometal cuboidal clusters MFE4S6(PEt3)4Cl (M = V, Mo): Syntehesis, structural analysis by crystallography and EXAFS, and relevance to the core structure of the iron-molydenum cofactor of nitrogenase Journal of the American Chemical Society. 115: 5549-5558.  0.556
1993 Scott MJ, Holm RH. Tetranuclear cuboidal and hexanuclear prismatic iron - sulfur - nitrosyl clusters Angewandte Chemie (International Edition in English). 32: 564-566.  0.325
1992 Tan GO, Ensign SA, Ciurli S, Scott MJ, Hedman B, Holm RH, Ludden PW, Korszun ZR, Stephens PJ, Hodgson KO. On the structure of the nickel/iron/sulfur center of the carbon monoxide dehydrogenase from Rhodospirillum rubrum: an x-ray absorption spectroscopy study. Proceedings of the National Academy of Sciences of the United States of America. 89: 4427-31. PMID 1584775 DOI: 10.1073/Pnas.89.10.4427  0.694
1992 Zhou J, Scott MJ, Hu Z, Peng G, Munck E, Holm RH. Synthesis and comparative reactivity and electronic structural features of [MFe3S4]z+ cubane-type clusters (M = iron, cobalt, nickel) Journal of the American Chemical Society. 114: 10843-10854. DOI: 10.1021/Ja00053A021  0.744
1992 Gheller SF, Schultz BE, Scott MJ, Holm RH. A broad-substrate analog reaction system of the molybdenum oxotransferases Journal of the American Chemical Society. 114: 6934-6935. DOI: 10.1021/Ja00043A059  0.437
1992 Ciurli S, Ross PK, Scott MJ, Yu SB, Holm RH. Synthetic nickel-containing heterometal cubane-type clusters with NiFe3Q4 cores (Q = sulfur, selenium) Journal of the American Chemical Society. 114: 5415-5423. DOI: 10.1021/Ja00039A063  0.678
1992 You JF, Papaefthymiou GC, Holm RH. [β-Na2Fe18S30]8- and [Na9Fe20Se38]9-: High-nuclearity clusters by mono- or bicyclization of unidimensional polymeric fragments and the existence of isomeric monocyclic clusters Journal of the American Chemical Society. 114: 2697-2710. DOI: 10.1021/Ja00033A050  0.422
1992 Yaghi OM, Scott MJ, Holm RH. Rhenium-selenium-chlorine solid phases: Cluster excision and core substitution reactions of molecular species Inorganic Chemistry. 31: 4778-4784. DOI: 10.1021/Ic00049A013  0.551
1992 Yaghi OM, Scott MJ, Holm RH. Rhenium-selenium-chlorine solid phases: cluster excision and core substitution reactions of molecular species Inorganic Chemistry. 31: 4778-4784. DOI: 10.1021/ic00049a013  0.584
1992 Lee SC, Li J, Mitchell JC, Holm RH. Group 5 tetrathiometalates: Simplified syntheses and structures Inorganic Chemistry. 31: 4333-4338. DOI: 10.1021/Ic00047A021  0.51
1992 Holm RH. Trinuclear Cuboidal and Heterometallic Cubane-Type Iron-Sulfur Clusters: New Structural and Reactivity Themes in Chemistry and Biology Advances in Inorganic Chemistry. 38: 1-71. DOI: 10.1016/S0898-8838(08)60061-6  0.451
1992 Ciurli S, Ross PK, Scott MJ, Yu SB, Holm RH. Synthetic nickel-containing heterometal cubane-type clusters with NiFe3Q4 cores (Q = S, Se) Journal of the American Chemical Society. 114: 5415-5423.  0.565
1992 Zhou J, Scott MJ, Hu Z, Peng G, Münck E, Holm RH. Synthesis and comparative reactivity and electronic structural features of [MFe3S4]z+ cubane-type clusters (M = Fe, Co, Ni) Journal of the American Chemical Society. 114: 10843-10854.  0.321
1991 Liu HY, Scharbert B, Holm RH. An initial approach to biologically related bridged assemblies: PYridinethiolate-Linked Fe4S4-Fe complex systems Journal of the American Chemical Society. 113: 9529-9539. DOI: 10.1021/Ja00025A018  0.364
1991 Stavropoulos P, Muetterties MC, Carrié M, Holm RH. Structural and reaction chemistry of nickel complexes in relation to carbon monoxide dehydrogenase: A reaction system simulating acetyl-coenzyme A synthase activity Journal of the American Chemical Society. 113: 8485-8492. DOI: 10.1021/Ja00022A041  0.305
1991 Weigel JA, Holm RH. Intrinsic Binding Properties of a Differentiated Iron Subsite in Analogues of Native [Fe4S4]2+ Clusters Journal of the American Chemical Society. 113: 4184-4191. DOI: 10.1021/Ja00011A020  0.408
1991 Yu SB, Wang CP, Day EP, Holm RH. A binuclear manganese system with three isolated oxidation states: Synthesis, structures, and properties of molecules with a Mn2(OR)2 bridge unit containing MnIIIMnIII, MnIIIMnII, and MnIIMnII Inorganic Chemistry. 30: 4067-4074. DOI: 10.1021/Ic00021A019  0.313
1991 Yu SB, Papaefthymiou GC, Holm RH. Comprehensive iron-selenium-thiolate cluster chemistry Inorganic Chemistry. 30: 3476-3485. DOI: 10.1021/Ic00018A018  0.437
1991 Ciurli S, Holm RH. Heterometal cubane-type clusters: a rhenium-iron-sulfur (ReFe3S4) single-cubane cluster by cleavage of an iron-bridged double cubane and the site-voided cubane [Fe3S4] as a cluster ligand Inorganic Chemistry. 30: 743-750. DOI: 10.1021/Ic00004A026  0.653
1991 Snyder BS, Reynolds MS, Holm RH, Papaefthymiou GC, Frankel RB. Electronic properties of monocapped prismane and basket iron-sulphur clusters Polyhedron. 10: 203-213. DOI: 10.1016/S0277-5387(00)81590-9  0.423
1991 Ciurli S, Holm RH. Heterometal cubane-type clusters: A ReFe3S4 single-cubane cluster by cleavage of an iron-bridged double cubane and the site-voided cubane [Fe3S4] as a cluster ligand Inorganic Chemistry. 30: 743-750.  0.611
1991 Whitener MA, Peng G, Holm RH. Subsite-differentiated analogues of biological [4Fe-4S] clusters effected by binding of a macrocyclic polyether trithiol Inorganic Chemistry. 30: 2411-2417.  0.315
1990 Lee SC, Holm RH. Entry to the solution chemistry of niobium and tantalum sulfides: Synthesis of soluble forms of the tetrathiometalates [MS4]3- Journal of the American Chemical Society. 112: 9654-9655. DOI: 10.1021/Ja00182A043  0.471
1990 Ciurli S, Yu SB, Holm RH, Srivastava KKP, Munck E. Synthetic nickel-iron NiFe3Q4 cubane-type clusters (S = 3/2) by reductive rearrangement of linear [Fe3Q4(SEt)4]3- (Q = sulfur, selenium) Journal of the American Chemical Society. 112: 8169-8171. DOI: 10.1021/Ja00178A053  0.72
1990 Weigel JA, Srivastava KKP, Day EP, Münck E, Holm RH. Isonitrile binding to a site-differentiated synthetic analogue of biological [4Fe-4S] clusters: Equilibria, magnetic interactions and the spin-isolated [3Fe-4S] cluster fragment, and the structure of a low-spin iron(II) subsite Journal of the American Chemical Society. 112: 8015-8023. DOI: 10.1021/Ja00178A026  0.638
1990 Ciurli S, Carrie M, Weigel JA, Carney MJ, Stack TDP, Papaefthymiou GC, Holm RH. Subsite-differentiated analogs of native iron sulfide [4Fe-4S]2+ clusters: preparation of clusters with five- and six-coordinate subsites and modulation of redox potentials and charge distributions Journal of the American Chemical Society. 112: 2654-2664. DOI: 10.1021/Ja00163A028  0.822
1990 You JF, Snyder BS, Papaefthymiou GC, Holm RH. On the molecular solid-state boundary. A cyclic iron-sulfur cluster of nuclearity eighteen: synthesis, structure, and properties Journal of the American Chemical Society. 112: 1067-1076. DOI: 10.1021/Ja00159A028  0.361
1990 Stack TDP, Weigel JA, Holm RH. The cavitand concept in the synthesis of subsite-differentiated analogues of biological [4Fe-4S/Se]2+ clusters: Cluster capture reactions, ligand conformational analysis, and the structure of a trigonal [4Fe-4Se]2+ analogue Inorganic Chemistry. 29: 3745-3760. DOI: 10.1021/Ic00344A022  0.679
1990 Ciurli S, Carrie M, Holm RH. Clusters containing the iron-rhenium-sulfur [ReFe3(.mu.3-S)4] core: an expansion of the heterometal cubane-type cluster series MFe3S4 Inorganic Chemistry. 29: 3493-3501. DOI: 10.1021/Ic00343A042  0.649
1990 Zhang Y, Holm RH. Vanadium-mediated oxygen atom transfer reactions Inorganic Chemistry. 29: 911-917. DOI: 10.1021/Ic00330A005  0.342
1990 CIURLI S, CARRIE M, HOLM RH. ChemInform Abstract: Clusters Containing the (ReFe3(μ3-S)4) Core: An Expansion of the Heterometal Cubane-Type Cluster Series MFe3S4. Cheminform. 21. DOI: 10.1002/CHIN.199051324  0.584
1990 YOU J, SNYDER BS, PAPAEFTHYMIOU GC, HOLM RH. ChemInform Abstract: On the Molecular/Solid-State Boundary. A Cyclic Iron-Sulfur Cluster of Nuclearity Eighteen: Synthesis, Structure, and Properties. Cheminform. 21. DOI: 10.1002/CHIN.199020031  0.31
1990 WEIGEL JA, HOLM RH, SURERUS KK, MUENCK E. ChemInform Abstract: Spin Isolation of the (3Fe-4S) Fragment of a (4Fe-4S) Cluster: Electronic Properties of the (3Fe-4S)0 Cluster. Cheminform. 21. DOI: 10.1002/CHIN.199013042  0.33
1990 Lee SC, Holm RH. Nonmolecular metal chalcogenide/halide solids and their molecular cluster analogues Angewandte Chemie (International Edition in English). 29: 840-856. DOI: 10.1002/Anie.199008401  0.555
1990 Lee SC, Holm RH. „Nichtmolekulare” Metallchalcogenid/-halogenid-Festkörperverbindungen und ihre molekularen Cluster-Analoga Angewandte Chemie. 102: 868-885. DOI: 10.1002/Ange.19901020805  0.558
1990 Ciurli S, Carrié M, Weigel JA, Carney MJ, Stack TDP, Papaefthymiou GC, Holm RH. Subsite-differentiated analogues of native [4Fe-4S]2+ clusters: Preparation of clusters with five- and six-coordinate subsites and modulation of redox potentials and charge distributions Journal of the American Chemical Society. 112: 2654-2664.  0.718
1989 Weigel JA, Holm RH, Surerus KK, Munck E. Spin-isolation of the [3Fe-4S] fragment of a [4Fe-4S] cluster: electronic properties of the [3Fe-4S]0 cluster Journal of the American Chemical Society. 111: 9246-9247. DOI: 10.1021/Ja00208A027  0.63
1989 Surerus KK, Munck E, Snyder BS, Holm RH. A binuclear mixed-valence ferromagnetic iron system with an S = 9/2 ground state and valence trapped and detrapped states Journal of the American Chemical Society. 111: 5501-5502. DOI: 10.1021/Ja00196A086  0.548
1989 Snyder BS, Patterson GS, Abrahamson AJ, Holm RH. Binuclear iron system ferromagnetic in three oxidation states: synthesis, structures, and electronic aspects of molecules with a Fe2(OR)2 bridge unit containing Fe(III,III), Fe(III,II), and Fe(II,II) Journal of the American Chemical Society. 111: 5214-5223. DOI: 10.1021/Ja00196A031  0.397
1989 Stack TDP, Carney MJ, Holm RH. Formation of bridged [4Fe-4S]2+ double cubanes by site-specific reactions: electron-transfer coupling across sulfur-containing bridges of variable length Journal of the American Chemical Society. 111: 1670-1676. DOI: 10.1021/Ja00187A020  0.743
1989 Yu SB, Holm RH. Aspects of the oxygen atom transfer chemistry of tungsten Inorganic Chemistry. 28: 4385-4391. DOI: 10.1021/Ic00323A021  0.315
1989 Ciurli S, Carney MJ, Holm RH, Papaefthymiou GC. Stability range of heterometal cubane-type clusters MFe3S4: assembly of double-cubane clusters with the rhenium-iron-sulfur [[ReFe3S4]] core Inorganic Chemistry. 28: 2696-2698. DOI: 10.1021/Ic00313A002  0.806
1989 Craig JA, Harlan EW, Snyder BS, Whitener MA, Holm RH. Oxomolybdenum(IV,V,VI) complexes: structures, reactivities, and criteria of detection of binuclear (.mu.-oxo)molybdenum(V) products in oxygen atom transfer systems Inorganic Chemistry. 28: 2082-2091. DOI: 10.1021/Ic00310A015  0.336
1989 Ciurli S, Holm RH. Insertion of vanadium-iron-sulfur, [VFe3S4]2+, and molybdenum-iron-sulfur, [MoFe3S4]3+, cores into a semirigid trithiolate cavitand ligand: regiospecific reactions at a vanadium site similar to that in nitrogenase Inorganic Chemistry. 28: 1685-1690. DOI: 10.1021/Ic00308A018  0.655
1989 Carney MJ, Papaefthymiou GC, Frankel RB, Holm RH. Alternative spin states in synthetic analogs of biological iron-sulfur [4Fe-4S]+ clusters: further cases of variable ground states and the structure of (Et4N)3[Fe4S4(S-o-C6H4S-tert-Bu)4], containing a reduced cluster with a compressed tetragonal distortion Inorganic Chemistry. 28: 1497-1503. DOI: 10.1021/Ic00307A015  0.772
1989 Krueger HJ, Holm RH. Chemical and electrochemical reactivity of nickel(II,I) thiolate complexes: examples of ligand-based oxidation and metal-centered oxidative addition Inorganic Chemistry. 28: 1148-1155. DOI: 10.1021/Ic00305A026  0.339
1989 Reynolds MS, Holm R. Binding of oxysulfur anions to macrocyclic iron(II,III): [(Fe(TPP))2SO4] and Fe(Me6[14]-4,11-dieneN4)(S2O5)] Inorganica Chimica Acta. 155: 113-123. DOI: 10.1016/S0020-1693(00)89291-9  0.439
1989 Scharbert B, Stack T, Weigel J, Whitener M, Holm R. Subsite-specific reactivity of Fe4S4 clusters bound to tridentate, trithiol ligands as models for enzyme active sites Journal of Inorganic Biochemistry. 36: 230. DOI: 10.1016/0162-0134(89)84247-3  0.615
1989 Carney M, Carrié M, Ciurli S, Holm R. Effects of pentacoordination at a single iron atom of site-functionalized Fe4S4 clusters Journal of Inorganic Biochemistry. 36: 230. DOI: 10.1016/0162-0134(89)84246-1  0.626
1989 You J, Snyder B, Holm R, Papaefthymiou G. [Na2Fe18S30]8−, A high-nuclearity cyclic cluster containing no terminal ligands: Amidate supported formation, structural diversity, novel physical properties Journal of Inorganic Biochemistry. 36: 175. DOI: 10.1016/0162-0134(89)84090-5  0.399
1989 CIURLI S, CARNEY MJ, HOLM RH, PAPAEFTHYMIOU GC. ChemInform Abstract: Stability Range of Heterometal Cubane-Type Clusters MFe3S4: Assembly of Double-Cubane Clusters with the ReFe3S4 Core. Cheminform. 20. DOI: 10.1002/CHIN.198942286  0.566
1989 CIURLI S, HOLM RH. ChemInform Abstract: Insertion of (VFe3S4)2+ and (MoFe3S4)3+ Cores into a Semirigid Trithiolate Cavitand Ligand: Regiospecific Reactions at a Vanadium Site Similar to That in Nitrogenase. Cheminform. 20. DOI: 10.1002/CHIN.198931227  0.529
1989 CARNEY MJ, PAPAEFTHYMIOU GC, FRANKEL RB, HOLM RH. ChemInform Abstract: Alternative Spin States in Synthetic Analogues of Biological (4Fe-4S)+ Clusters: Further Cases of Variable Ground States and the Structure of (Et4N)3(Fe4S4(S-o-C6H4StBu)4), Containing a Reduced Cluster with a Compressed Tetragonal Dis Cheminform. 20. DOI: 10.1002/CHIN.198931048  0.319
1989 Stack TDP, Carney MJ, Holm RH. Formation of bridged [4Fe-4S]2+ double cubanes by site-specific reactions: Electron-transfer coupling across sulfur-containing bridges of variable length Journal of the American Chemical Society. 111: 1670-1676.  0.574
1988 Carney MJ, Papaefthymiou GC, Spartalian K, Frankel RB, Holm RH. Ground spin state variability in [Fe4S4(SR)4]3-. Synthetic analogs of the reduced clusters in ferredoxins and other iron-sulfur proteins: cases of extreme sensitivity of electronic state and structure to extrinsic factors. Journal of the American Chemical Society. 110: 6084-95. PMID 22148785 DOI: 10.1021/Ja00226A025  0.746
1988 You JF, Snyder BS, Holm RH. [Na2Fe18S30]8-. A high-nuclearity cyclic cluster generated solely by iron-sulfur bridge bonding Journal of the American Chemical Society. 110: 6589-6591. DOI: 10.1021/Ja00227A064  0.425
1988 Caradonna JP, Reddy PR, Holm RH. Kinetics, mechanisms, and catalysis of oxygen atom transfer reactions of S-oxide and pyridine N-oxide substrates with molybdenum(IV,VI) complexes: relevance to molybdoenzymes Journal of the American Chemical Society. 110: 2139-2144. DOI: 10.1021/Ja00215A022  0.679
1988 Mukherjee RN, Stack TDP, Holm RH. Angle dependence of the properties of the [Fe2X]4+ bridge unit (X = O, S): structures, antiferromagnetic coupling, and properties in solution Journal of the American Chemical Society. 110: 1850-1861. DOI: 10.1021/Ja00214A030  0.331
1988 Reynolds MS, Holm RH. Iron-sulfur-thiolate basket clusters Inorganic Chemistry. 27: 4494-4499. DOI: 10.1021/Ic00297A031  0.388
1988 Synder BS, Holm RH. Hexanuclear iron-sulfur basket clusters: topological isomers of prismanes. Synthesis, structure, and reactions Inorganic Chemistry. 27: 2339-2347. DOI: 10.1021/Ic00286A024  0.386
1988 Mukherjee RN, Abrahamson AJ, Patterson GS, Stack TDP, Holm RH. A new class of (N,N'-bis(salicylideneamino)ethanato)iron(II) complexes: five-coordinate [FeII(salen)L]-. Preparation, properties, and mechanism of electron-transfer reactions Inorganic Chemistry. 27: 2137-2144. DOI: 10.1021/Ic00285A026  0.384
1988 Snyder BS, Reynolds MS, Noda I, Holm RH. Core conversion reactions of iron-sulfur clusters: topological isomer of the Fe6S6-prismane core Inorganic Chemistry. 27: 595-597. DOI: 10.1021/Ic00277A004  0.438
1988 Carney MJ, Papaefthymiou GC, Whitener MA, Spartalian K, Frankel RB, Holm RH. Alternative spin states in synthetic analogs of biological clusters: spin-quartet ground states and structures of tetrakis(benzenethiolato)tetrasulfidotetraferrate(3-) and tetrakis(benzenethiolato)tetraselenidotetraferrate(3-) as their tetramethylammonium salts Inorganic Chemistry. 27: 346-352. DOI: 10.1021/Ic00275A023  0.733
1988 YOU J, SNYDER BS, HOLM RH. ChemInform Abstract: (Na2Fe18S30)8-: A High-Nuclearity Cyclic Cluster Generated Solely by Iron-Sulfur Bridge Bonding. Cheminform. 19. DOI: 10.1002/CHIN.198849038  0.313
1988 SNYDER BS, HOLM RH. ChemInform Abstract: Hexanuclear Iron-Sulfur Basket Clusters: Topological Isomers of Prismanes. Synthesis, Structure, and Reactions. Cheminform. 19. DOI: 10.1002/CHIN.198843303  0.357
1988 STACK TDP, HOLM RH. ChemInform Abstract: Subsite-Differentiated Analogues of Biological (4 Fe-4 S)2+ Clusters: Synthesis, Solution and Solid-State Structures, and Subsite-Specific Reactions. Cheminform. 19. DOI: 10.1002/CHIN.198831253  0.335
1988 SNYDER BS, REYNOLDS MS, NODA I, HOLM RH. ChemInform Abstract: Core Conversion Reactions of Iron-Sulfur Clusters: Topological Isomer of the Fe6S6-Prismance Core. Cheminform. 19. DOI: 10.1002/CHIN.198825291  0.33
1988 Caradonna JP, Reddy PR, Holm RH. Kinetics, mechanisms, and catalysis of oxygen atom transfer reactions of S-oxide and pyridine N-oxide substrates with molybdenum(IV,VI) complexes: Relevance to molybdoenzymes Journal of the American Chemical Society. 110: 2139-2144.  0.653
1988 Mukherjee RN, Stack TDP, Holm RH. Angle dependence of the properties of the [Fe2X]4+ bridge unit (X = O, S): Structures, antiferromagnetic coupling, and properties in solution Journal of the American Chemical Society. 110: 1850-1861.  0.509
1988 Stack TDP, Holm RH. Subsite-differentiated analogues of biological [4Fe-4S]2+ clusters: Synthesis, solution and solid-state structures, and subsite-specific reactions Journal of the American Chemical Society. 110: 2484-2494.  0.613
1988 Mukherjee RN, Abrahamson AJ, Patterson GS, Stack TDP, Holm RH. A new class of (N,N′-bis(salicylideneamino)ethanato)iron(II) complexes: Five-coordinate [FeII(salen)L]-. Preparation, properties, and mechanism of electron-transfer reactions Inorganic Chemistry. 27: 2137-2144.  0.577
1987 Krueger HJ, Holm RH. Stabilization of nickel(III) in a classical N2S2 coordination environment containing anionic sulfur Inorganic Chemistry. 26: 3645-3647. DOI: 10.1021/Ic00269A002  0.331
1987 Carney MJ, Kovacs JA, Zhang YP, Papaefthymiou GC, Spartalian K, Frankel RB, Holm RH. Comparative electronic properties of vanadium-iron-sulfur and molybdenum-iron-sulfur clusters containing isoelectronic cubane-type [VFe3S4]2+ and [MoFe3S4]3+ cores Inorganic Chemistry. 26: 719-724. DOI: 10.1021/Ic00252A016  0.802
1987 Kovacs JA, Holm RH. Structural chemistry of vanadium-iron-sulfur clusters containing the cubane-type [VFe3S4]2+ core Inorganic Chemistry. 26: 711-718. DOI: 10.1021/Ic00252A015  0.573
1987 Kovacs JA, Holm RH. Heterometallic clusters: synthesis and reactions of vanadium-iron-sulfur single- and double-cubane clusters and the structure of [V2Fe6S8Cl4(C2H4S2)2]4- Inorganic Chemistry. 26: 702-711. DOI: 10.1021/Ic00252A014  0.656
1987 Zhang YP, Bashkin JK, Holm RH. Phosphine cleavage of iron(III)-bridged double cubanes: a new route to MoFe3S4 single cubanes Inorganic Chemistry. 26: 694-702. DOI: 10.1021/Ic00252A013  0.618
1987 Kovacs JA, Bashkin JK, Holm RH. [Fe2S2(CO)6]2- as a cluster precursor: synthesis and structure of [MoFe3S6(CO)6]2- and oxidative decarbonylation to a persulfide-bridged MoFe3S4 double cubane Polyhedron. 6: 1445-1456. DOI: 10.1016/S0277-5387(00)80908-0  0.777
1987 STACK TDP, HOLM RH. ChemInform Abstract: Subsite-Specific Functionalization of the (4 Fe-4 S)2+ Analogue of Iron-Sulfur Protein Clusters. Cheminform. 18. DOI: 10.1002/CHIN.198734287  0.345
1987 CARNEY MJ, KOVACS JA, ZHANG Y, PAPAEFTHYMIOU GC, SPARTALIAN K, FRANKEL RB, HOLM RH. ChemInform Abstract: Comparative Electronic Properties of Vanadium-Iron-Sulfur and Molybdenum-Iron-Sulfur Clusters Containing Isoelectronic Cubane-Type (VFe3S4)2+ and (MoFe3S4)3+ Cores. Cheminform. 18. DOI: 10.1002/chin.198730247  0.589
1987 KOVACS JA, HOLM RH. ChemInform Abstract: Structural Chemistry of Vanadium-Iron-Sulfur Clusters Containing the Cubane-Type (VFe3S4)2+ Core. Cheminform. 18. DOI: 10.1002/chin.198730246  0.611
1987 KOVACS JA, HOLM RH. ChemInform Abstract: Heterometallic Clusters: Synthesis and Reactions of Vanadium-Iron-Sulfur Single- and Double-Cubane Clusters and the Structure of (V2Fe6S8Cl4(C2H4S2)2)4-. Cheminform. 18. DOI: 10.1002/chin.198730245  0.618
1987 NODA I, SNYDER BS, HOLM RH. ChemInform Abstract: Fe7S6(PEt3)4Cl3: A Topological Link Between the Prismatic and Cuboctahedral Structures of Iron-Sulfur Clusters. Cheminform. 18. DOI: 10.1002/CHIN.198709056  0.332
1987 Zhang YP, Bashkin JK, Holm RH. Phosphine cleavage of iron(III)-bridged double cubanes: A new route to MoFe3S4 single cubanes Inorganic Chemistry. 26: 694-702.  0.626
1987 Stack TDP, Holm RH. Subsite-specific functionalization of the [4Fe-4S]2+ analogue of iron-sulfur protein clusters Journal of the American Chemical Society. 109: 2546-2547.  0.618
1986 Caradonna JP, Harlan EW, Holm RH. Thiol as an electron donor in molybdenum oxo-transferase analog reaction systems: observations by fluorine-19 NMR spectroscopy and biological implications. Journal of the American Chemical Society. 108: 7856-8. PMID 22283311 DOI: 10.1021/Ja00284A073  0.666
1986 Harlan EW, Berg JM, Holm RH. Thermodynamic fitness of molybdenum(IV,VI) complexes for oxygen-atom transfer reactions, including those with enzymic substrates Journal of the American Chemical Society. 108: 6992-7000. DOI: 10.1021/Ja00282A025  0.54
1986 Whitener MA, Bashkin JK, Hagen KS, Girerd JJ, Gamp E, Edelstein N, Holm RH. A new inorganic ring system: Planar Fe3(μ2-SR)3 in [Fe3(SR)3X6]3- - Synthesis, structures, and solution conformation and equilibrium Journal of the American Chemical Society. 108: 5607-5620. DOI: 10.1021/Ja00278A040  0.608
1986 Carney MJ, Holm RH, Papaefthymiou GC, Frankel RB. Demonstration of alternative spin states in clusters containing the biologically relevant [Fe4S4]1+ core Journal of the American Chemical Society. 108: 3519-3521. DOI: 10.1021/Ja00272A064  0.73
1986 Kovacs JA, Holm RH. Assembly of vanadium-iron-sulfur cubane clusters from mononuclear and linear trinuclear reactants Journal of the American Chemical Society. 108: 340-341. DOI: 10.1021/Ja00262A050  0.633
1986 Noda I, Snyder BS, Holm RH. Trichlorotetrakis(triethylphosphine)hexathioheptairon (Fe7S6(PEt3)4Cl3): a topological link between the prismatic and cube-octahedral structures of iron-sulfur clusters Inorganic Chemistry. 25: 3851-3853. DOI: 10.1021/Ic00242A004  0.371
1986 Holm RH, Berg JM. Toward functional models of metalloenzyme active sites: analog reaction systems of the molybdenum oxo transferases Accounts of Chemical Research. 19: 363-370. DOI: 10.1021/Ar00131A006  0.517
1986 Mukherjee RN, Pulla Rao C, Holm RH. Solution chemistry of ethane-1,2-dithiolate complexes: equilibria and electron-transfer reactions Inorganic Chemistry. 25: 2979-2989. DOI: 10.1002/Chin.198652062  0.303
1986 MUKHERJEE RN, RAO CP, HOLM RH. ChemInform Abstract: Solution Chemistry of Ethane-1,2-dithiolate Complexes: Equilibria and Electron-Transfer Reactions. Chemischer Informationsdienst. 17. DOI: 10.1002/chin.198652062  0.505
1986 CARNEY MJ, HOLM RH, PAPAEFTHYMIOU GC, FRANKEL RB. ChemInform Abstract: Demonstration of Alternative Spin States in Clusters Containing the Biologically Relevant (Fe4S4)+ Core. Chemischer Informationsdienst. 17. DOI: 10.1002/Chin.198641062  0.732
1986 Rao CP, Dorfman JR, Holm RH. Synthesis and structural systematics of ethane-1,2-dithiolato complexes Inorganic Chemistry. 25: 428-439. DOI: 10.1002/Chin.198627243  0.698
1986 RAO CP, DORFMAN JR, HOLM RH. ChemInform Abstract: Synthesis and Structural Systematics of Ethane-1,2-dithiolato Complexes. Chemischer Informationsdienst. 17. DOI: 10.1002/chin.198627243  0.525
1986 KOVACS JA, HOLM RH. ChemInform Abstract: Assembly of Vanadium - Iron - Sulfur Cubane Clusters from Mononuclear and Linear Trinuclear Reactants. Chemischer Informationsdienst. 17. DOI: 10.1002/Chin.198618039  0.635
1986 CONRADSON SD, BURGESS BK, NEWTON WE, HODGSON KO, MCDONALD JW, RUBINSON JF, GHELLER SF, MORTENSON LE, ADAMS MWW, MASCHARAK PK, ARMSTRONG WA, HOLM RH. ChemInform Abstract: Structural Insights from the Mo K-Edge X-Ray Absorption Near Edge Structure of the Iron-Molybdenum Protein of Nitrogenase and Its Iron-Molybdenum Cofactor by Comparison with Synthetic Fe Chemischer Informationsdienst. 17. DOI: 10.1002/Chin.198616065  0.665
1986 Caradonna JP, Harlan EW, Holm RH. Thiol as an electron donor in molybdenum oxo-transferase analogue reaction systems: Observations by 19F NMR spectroscopy and biological implications Journal of the American Chemical Society. 108: 7856-7858.  0.631
1985 Watson AD, Rao CP, Dorfman JR, Holm RH. Systematic stereochemistry of metal(II) thiolates: synthesis and structures of [M2(SC2H5)6]2- (M = Mn(II), Ni(II), Zn(II), Cd(II)) Inorganic Chemistry. 24: 2820-2826. DOI: 10.1021/Ic00212A024  0.68
1985 Do Y, Simhon ED, Holm RH. Oxo sulfido ligand substitution in dimolybdate ([Mo2O7]2-): reaction sequence and characterization of the final product, [MoS3(OSiMe3)]- Inorganic Chemistry. 24: 1831-1838. DOI: 10.1021/Ic00206A028  0.31
1985 WATSON AD, RAO CP, DORFMAN JR, HOLM RH. ChemInform Abstract: SYSTEMATIC STEREOCHEMISTRY OF METAL(II) THIOLATES: SYNTHESIS AND STRUCTURES OF (M2(SC2H5)6)2- (M = MN(II), NI(II), ZN(II), CD(II)) Chemischer Informationsdienst. 16. DOI: 10.1002/chin.198550282  0.496
1985 Sola J, Do Y, Berg JM, Holm RH. Soluble sulfides of niobium(V) and tantalum(V): synthesis, structures, and properties of the fivefold symmetric cages [M6S17]4- Inorganic Chemistry. 24: 1706-1713. DOI: 10.1002/Chin.198539038  0.509
1985 CHRISTOU G, HAGEN KS, BASHKIN JK, HOLM RH. ChemInform Abstract: THE CLUSTERS (CO8S6(SPH)8)4-,5-: PREPARATIONS, PROPERTIES, AND STRUCTURAL RELATIONSHIP OF NEAR-CUBIC CO8(μ4-S)6 CORES TO THE CLUSTERS IN SYNTHETIC PENTLANDITE Chemischer Informationsdienst. 16. DOI: 10.1002/chin.198532302  0.705
1985 Christou G, Hagen KS, Bashkin JK, Holm RH. The clusters [Co8S6(SPh)8]4-,5-: Preparations, properties, and structural relationship of near-cubic Co8(μ4-S)6 cores to the clusters in synthetic pentlandite Inorganic Chemistry. 24: 1010-1018. DOI: 10.1002/Chin.198532302  0.681
1985 Kovacs JA, Bashkin JK, Holm RH. Persulfide-bridged iron-molybdenum-sulfur clusters of biological relevance: two synthetic routes and the structures of intermediate and product clusters Journal of the American Chemical Society. 107: 1784-1786. DOI: 10.1002/Chin.198530341  0.77
1985 KOVACS JA, BASHKIN JK, HOLM RH. ChemInform Abstract: PERSULFIDE-BRIDGED IRON-MOLYBDENUM-SULFUR CLUSTERS OF BIOLOGICAL RELEVANCE: TWO SYNTHETIC ROUTES AND THE STRUCTURES OF INTERMEDIATE AND PRODUCT CLUSTERS Chemischer Informationsdienst. 16. DOI: 10.1002/chin.198530341  0.755
1985 DORFMAN JR, RAO CP, HOLM RH. ChemInform Abstract: STRUCTURAL DIVERSITY OF HOMOLEPTIC ETHANE-1,2-DITHIOLATO COMPLEXES OF THE FIRST TRANSITION SERIES Chemischer Informationsdienst. 16. DOI: 10.1002/chin.198529307  0.509
1985 Dorfman JR, Rao CP, Holm RH. Structural diversity of homoleptic ethane-1,2-dithiolato complexes of the first transition series Inorganic Chemistry. 24: 453-454. DOI: 10.1002/Chin.198529307  0.687
1985 Berg JM, Holm RH. Model for the active sites of oxo-transfer molybdoenzymes: reactivity, kinetics, and catalysis Journal of the American Chemical Society. 107: 925-932. DOI: 10.1002/Chin.198527294  0.51
1985 Berg JM, Holm RH. Model for the active site of oxo-transfer molybdoenzymes: synthesis, structure, and properties Journal of the American Chemical Society. 107: 917-925. DOI: 10.1002/Chin.198527293  0.535
1985 DORFMAN JR, GIRERD JJ, SIMHON ED, STACK TDP, HOLM RH. ChemInform Abstract: SYNTHESIS, STRUCTURE, AND ELECTRONIC FEATURES OF (μ-SULFIDO)BIS((N,N′-ETHYLENEBIS(SALICYLALDIMINATO))IRON(III)), (FE(SALEN))2S, CONTAINING THE ONLY AUTHENTICATED EXAMPLE OF THE IRON(III)-SULFUR-IRON(III) SINGLE BRIDGE Chemischer Informationsdienst. 16. DOI: 10.1002/Chin.198520283  0.743
1985 GIRERD JJ, PAPAEFTHYMIOU GC, WATSON AD, GAMP E, HAGEN KS, EDELSTEIN N, FRANKEL RB, HOLM RH. ChemInform Abstract: ELECTRONIC PROPERTIES OF THE LINEAR ANTIFERROMAGNETICALLY COUPLED CLUSTERS (FE3S4(SR)4)3-, STRUCTURAL ISOMERS OF THE IRON-SULFUR(1+) ((FE3S4)1+) UNIT IN IRON-SULFUR PROTEINS Chemischer Informationsdienst. 16. DOI: 10.1002/chin.198503067  0.324
1985 HAGEN KS, WATSON AD, HOLM RH. ChemInform Abstract: ANALOGS OF THE (FE4S4)+ SITES OF REDUCED FERREDOXINS: SINGLE-STEP SYNTHESIS OF THE CLUSTERS (FE4S4(SR)4)3- AND EXAMPLES OF COMPRESSED TETRAGONAL COR STRUCTURES Chemischer Informationsdienst. 16. DOI: 10.1002/Chin.198501289  0.417
1984 Holm RH, Berg JM. Mononuclear active sites of molybdoenzymes: chemical approaches to structure and reactivity Pure and Applied Chemistry. 56: 1645-1657. DOI: 10.1351/Pac198456111645  0.596
1984 Palermo RE, Singh R, Bashkin JK, Holm RH. Molybdenum atom ligand substitution reactions of molybdenum-iron-sulfur (MoFe3S4) cubane-type clusters: synthesis and structures of clusters containing molybdenum-bound pseudosubstrates of nitrogenase Journal of the American Chemical Society. 106: 2600-2612. DOI: 10.1021/Ja00321A019  0.692
1984 Dorfman JR, Girerd JJ, Simhon ED, Stack TDP, Holm RH. Synthesis, structure, and electronic features of (.mu.-sulfido)bis[(N,N'-ethylenebis(salicylaldiminato))iron(III)], [Fe(salen)]2S, containing the only authenticated example of the iron(III)-sulfur-iron(III) single bridge Inorganic Chemistry. 23: 4407-4412. DOI: 10.1021/Ic00194A002  0.739
1984 Hagen KS, Watson AD, Holm RH. Analogs of the [Fe4S4]+ sites of reduced ferredoxins: single-step synthesis of the clusters [Fe4S4(SR)4]3- and examples of compressed tetragonal core structures Inorganic Chemistry. 23: 2984-2990. DOI: 10.1021/Ic00187A017  0.432
1984 Hagen KS, Holm RH. Synthesis and stereochemistry of metal(II) thiolates of the types [M(SR)4]2-, [M2(SR)6]2-, and [M4(SR)10]2- (M = Fe(II), Co(II)) Inorganic Chemistry. 23: 418-427. DOI: 10.1021/Ic00172A009  0.344
1984 Armstrong WH, Youinou MT, Palermo RE, Holm RH. Synthesis of a new class of polydentate ligands: [bis(2-imidazolyl)methyl] amino-thioether-thiols Inorganica Chimica Acta. 88: 21-27. DOI: 10.1016/S0020-1693(00)81865-4  0.579
1984 Holm RH, Hagen KS, Watson AD. Assembly Of Biologically Relevant Iron-Sulfur Clusters Cheminform. 15: 115-124. DOI: 10.1016/B978-0-08-029249-6.50017-9  0.47
1984 Reynolds MS, Berg JM, Holm RH. Kinetics of oxygen atom transfer reactions involving oxomolybdenum complexes. General treatment for reactions with intermediate oxo-bridged molybdenum(V) dimer formation Inorganic Chemistry. 23: 3057-3062. DOI: 10.1002/Chin.198503290  0.544
1984 Girerd JJ, Papaefthymiou GC, Watson AD, Gamp E, Hagen KS, Edelstein N, Frankel RB, Holm RH. Electronic properties of the linear antiferromagnetically coupled clusters [Fe3S4(SR)4]3-, structural isomers of the iron-sulfur(1+) ([Fe3S4]1+) unit in iron-sulfur proteins Journal of the American Chemical Society. 106: 5941-5947. DOI: 10.1002/Chin.198503067  0.434
1984 Berg JM, Holm RH. Synthetic approach to the mononuclear active sites of molybdoenzymes: catalytic oxygen atom transfer reactions by oxomolybdenum(IV,VI) complexes with saturation kinetics and without molybdenum(V) dimer formation Journal of the American Chemical Society. 106: 3035-3036. DOI: 10.1002/Chin.198434262  0.558
1984 PALERMO RE, SINGH R, BASHKIN JK, HOLM RH. ChemInform Abstract: MOLYBDENUM ATOM LIGAND SUBSTITUTION REACTIONS OF MOLYBDENUM-IRON-SULFUR (MOFE3S4) CUBANE-TYPE CLUSTERS: SYNTHESIS AND STRUCTURES OF CLUSTERS CONTAINING MOLYBDENUM-BOUND PSEUDOSUBSTRATES OF NITROGENASE Chemischer Informationsdienst. 15. DOI: 10.1002/Chin.198433252  0.717
1984 HOLM RH, HAGEN KS, WATSON AD. ChemInform Abstract: Assembly of Biologically Relevant Iron-Sulfur Clusters Chemischer Informationsdienst. 15. DOI: 10.1002/chin.198431337  0.321
1984 HAGEN KS, HOLM RH. ChemInform Abstract: SYNTHESIS AND STEREOCHEMISTRY OF METAL(II) THIOLATES OF THE TYPES (M(SR)4)2-, (M2(SR)6)2-, AND (M4(SR)10)2- (M = FE(II), CO(II)) Chemischer Informationsdienst. 15. DOI: 10.1002/Chin.198421287  0.311
1984 MIZOBE Y, MASCHARAK PK, PALERMO RE, HOLM RH. ChemInform Abstract: SYNTHESIS AND SELECTED PROPERTIES OF A REDUCED SINGLE-CUBANE CLUSTER CONTAINING THE (MOFE3S4)2+ (S = 2) CORE Chemischer Informationsdienst. 15. DOI: 10.1002/chin.198405274  0.647
1984 MASCHARAK PK, PAPAEFTHYMIOU GC, ARMSTRONG WH, FONER S, FRANKEL RB, HOLM RH. ChemInform Abstract: ELECTRONIC PROPERTIES OF SINGLE- AND DOUBLE-MOFE3S4 CUBANE-TYPE CLUSTERS Chemischer Informationsdienst. 15. DOI: 10.1002/chin.198401052  0.634
1984 Palermo RE, Singh R, Bashkin JK, Holm RH. Molybdenum atom ligand substitution reactions of MoFe3S4 cubane-type clusters: Synthesis and structures of clusters containing Mo-bound pseudosubstrates of nitrogenase Journal of the American Chemical Society. 106: 2600-2612.  0.669
1983 Palermo RE, Holm RH. Reactivity properties of single molybdenum iron sulfide (MoFe3S4) cubane-type clusters: synthesis, structure, and ligand substitution reactions of [MoFe3S4Cl3(3,6-(C3H5)2C6H2O2)(THF)]2- Journal of the American Chemical Society. 105: 4310-4318. DOI: 10.1021/ja00351a032  0.344
1983 Hagen KS, Watson AD, Holm RH. Synthetic routes to iron sulfide (Fe2S2, Fe3S4, Fe4S4, and Fe6S9), clusters from the common precursor tetrakis(ethanethiolate)ferrate(2-) ion ([Fe(SC2H5)4]2-): structures and properties of [Fe3S4(SR)4]3- and bis(ethanethiolate)nonathioxohexaferrate(4-) ion ([Fe6S9(SC2H5)2]4-), examples of the newest types of Fe-S-SR clusters Journal of the American Chemical Society. 105: 3905-3913. DOI: 10.1021/Ja00350A028  0.454
1983 Mascharak PK, Armstrong WH, Mizobe Y, Holm RH. Single cubane-type MFe3S4 clusters (M = Mo, W): synthesis and properties of oxidized and reduced forms and the structure of (Et4N)3[MoFe3S4(S-p-C6H4Cl)4(3,6-(C3H5)2C6H2O2)] Journal of the American Chemical Society. 105: 475-483. DOI: 10.1021/Ja00341A029  0.672
1983 Mascharak PK, Papaefthymiou GC, Armstrong WH, Foner S, Frankel RB, Holm RH. Electronic properties of single- and double-MoFe3S4 cubane-type clusters Inorganic Chemistry. 22: 2851-2858. DOI: 10.1021/Ic00162A017  0.652
1983 Berg JM, Holm RH. Structure proofs of ligated and polymeric dioxomolybdenum(VI)-tridentate complexes: MoO2(C5H3N-2,6-(CH2S)2)(C4H8SO) and [MoO2(C5H3N-2,6-(CH2O)2)]n Inorganic Chemistry. 22: 1768-1771. DOI: 10.1021/Ic00154A015  0.538
1983 Stephan DW, Papaefthymiou GC, Frankel RB, Holm RH. Analogs of the [4Fe-4S]+ sites of reduced ferredoxins: structural and spectroscopic properties of [(C2H5)4N]3[Fe4S4(S-p-C6H4Br)4] in crystalline and solution phases Inorganic Chemistry. 22: 1550-1557. DOI: 10.1021/Ic00152A026  0.501
1983 Yamamura T, Christou G, Holm RH. The homogeneous hydrogen-evolving systems [Mo2Fe6S8(SPh)9]4-,5-/C6H5SH: reaction characteristics, kinetics, and possible mechanisms Inorganic Chemistry. 22: 939-949. DOI: 10.1021/Ic00148A019  0.409
1983 Hagen KS, Christou G, Holm RH. Trinuclear metal(II)-sulfide-thiolate complexes: synthesis, structures, and properties of [M3S(1,2-(SCH2)2C6H4)3]2- (M = Fe(II), Co(II)) Inorganic Chemistry. 22: 309-314. DOI: 10.1021/Ic00144A021  0.514
1983 Mascharak PK, Hagen KS, Spence JT, Holm RH. Structural distortions of the [Fe4S4]2+ core of [Fe4S4(S-t-C4H9)4]2- in different crystalline environments and detection and instability of oxidized ([Fe4S4]3+) clusters Inorganica Chimica Acta. 80: 157-170. DOI: 10.1016/S0020-1693(00)91277-5  0.681
1983 Mizobe Y, Mascharak P, Palermo R, Holm R. Synthesis and selected properties of a reduced single-cubane cluster containing the [MoFe3,S4]2+ (S = 2) core Inorganica Chimica Acta. 80: L65-L67. DOI: 10.1016/S0020-1693(00)91249-0  0.641
1983 Costa T, Dorfman JR, Hagen KS, Holm RH. Synthesis and stereochemistry of mono-, bi-, and tetranuclear manganese thiolates Inorganic Chemistry. 22: 4091-4099. DOI: 10.1002/Chin.198413263  0.582
1983 Sola J, Do Y, Berg JM, Holm RH. Soluble metal sulfides. Synthesis and structures of [M6S17]4- (M = niobium or tantalum): icosahedral-fragment cages containing four types of coordinated sulfide Journal of the American Chemical Society. 105: 7784-7786. DOI: 10.1002/Chin.198413038  0.533
1983 Johnson RE, Papaefthymiou GC, Frankel RB, Holm RH. Effects of secondary bonding interactions on the iron-sulfur cubane-type [Fe4S4]2+ core of ferredoxin site analogs: [Fe4S4(SC6H4-o-OH)4]2-, a distorted cubane-type cluster with one five-coordinate iron atom Journal of the American Chemical Society. 105: 7280-7287. DOI: 10.1002/Chin.198412291  0.412
1983 Dorfman JR, Holm RH. Tetrakis(ethane-1,2-dithiolato)divanadate(III): a binuclear complex with a quadruple bridge, a metal-metal bond, and nonoctahedral stereochemistry Inorganic Chemistry. 22: 3179-3181. DOI: 10.1002/Chin.198405262  0.568
1983 MASCHARAK PK, HAGEN KS, SPENCE JT, HOLM RH. ChemInform Abstract: STRUCTURAL DISTORTIONS OF THE (FE4S4)2+ CORE OF (FE4S4(S-TERT-C4H9)4)2- IN DIFFERENT CRYSTALLINE ENVIRONMENTS AND DETECTION AND INSTABILITY OF OXIDIZED ((FE4S4)3+) CLUSTERS Chemischer Informationsdienst. 14. DOI: 10.1002/chin.198348271  0.633
1983 HAGEN KS, WATSON AD, HOLM RH. ChemInform Abstract: SYNTHETIC ROUTES TO IRON SULFIDE (FE2S2, FE3S4, FE4S4, AND FE6S9), CLUSTERS FROM THE COMMON PRECURSOR TETRAKIS(ETHANETHIOLATE)FERRATE(2-) ION ((FE(SC2H5)4)2-): STRUCTURES AND PROPERTIES OF (FE3S4(SR)4)3- AND BIS(ETHANETHIOLATE)NONATHI Chemischer Informationsdienst. 14. DOI: 10.1002/Chin.198339297  0.46
1983 YAMAMURA T, CHRISTOU G, HOLM RH. ChemInform Abstract: THE HOMOGENEOUS HYDROGEN-EVOLVING SYSTEMS (MO2FE6S8(SPH)9)4-,5-/C6H5SH: REACTION CHARACTERISTICS, KINETICS, AND POSSIBLE MECHANISMS Chemischer Informationsdienst. 14. DOI: 10.1002/chin.198326303  0.33
1983 MASCHARAK PK, ARMSTRONG WH, MIZOBE Y, HOLM RH. ChemInform Abstract: SINGLE CUBANE-TYPE MFE3S4 CLUSTERS (M = MO, W): SYNTHESIS AND PROPERTIES OF OXIDIZED AND REDUCED FORMS AND THE STRUCTURE OF (ET4N)3(MOFE3S4(S-P-C6H4CL)4(3,6-(C3H5)2C6H2O2)) Chemischer Informationsdienst. 14. DOI: 10.1002/chin.198321281  0.643
1983 HAGEN KS, STEPHAN DW, HOLM RH. ChemInform Abstract: METAL ION EXCHANGE REACTIONS IN CAGE MOLECULES: THE SYSTEMS (M4-NM′N(SC6H5)10)2- (M, M′ = FE(II), CO(II), ZN(II), CD(II)) WITH ADAMANTANE-LIKE STEREOCHEMISTRY AND THE STRUCTURE OF (FE4(SC6H5)10)2- Chemischer Informationsdienst. 14. DOI: 10.1002/chin.198304317  0.428
1982 Mascharak PK, Smith MC, Armstrong WH, Burgess BK, Holm RH. Fluorine-19 chemical shifts as structural probes of metal-sulfur clusters and the cofactor of nitrogenase. Proceedings of the National Academy of Sciences of the United States of America. 79: 7056-60. PMID 6960364 DOI: 10.1073/Pnas.79.22.7056  0.788
1982 Hagen KS, Holm RH. Systematic iron(II)-thiolate chemistry: synthetic entry to trinuclear complexes Journal of the American Chemical Society. 104: 5496-5497. DOI: 10.1021/Ja00384A045  0.395
1982 Armstrong WH, Mascharak PK, Holm RH. Doubly bridged double cubanes containing MFe3S4 clusters (M = Mo, W). Synthesis, structure, and conversion to spin-quartet single clusters in solution Journal of the American Chemical Society. 104: 4373-4383. DOI: 10.1021/Ja00380A011  0.682
1982 Christou G, Mascharak PK, Armstrong WH, Papaefthymiou GC, Frankel RB, Holm RH. Electron-transfer series of MoFe3S4 double-cubane clusters: electronic properties of components and the structure of [(C2H5)4N]5[Mo2Fe6S8(SC6H5)9] Journal of the American Chemical Society. 104: 2820-2831. DOI: 10.1021/Ja00374A021  0.652
1982 Christou G, Hagen KS, Holm RH. Synthesis, structure, and properties of [Co8S6(SC6H5)8]4-, containing an octanuclear Co8S6 rhombic dodecahedron related to that of cobalt pentlandite Journal of the American Chemical Society. 104: 1744-1745. DOI: 10.1021/Ja00370A054  0.463
1982 Hagen KS, Stephan DW, Holm RH. Metal ion exchange reactions in cage molecules: the systems [M4-nM'n(SC6H5)10]2- (M, M' = Fe(II), Co(II), Zn(II), Cd(II)) with adamantane-like stereochemistry and the structure of [Fe4(SC6H5)10]2- Inorganic Chemistry. 21: 3928-3936. DOI: 10.1021/Ic00141A015  0.497
1982 Christou G, Sabat M, Ibers JA, Holm RH. A new structural type in iron-sulfide-thiolate chemistry: preparation, properties, and structure of the hexanuclear cluster [Fe6S9(S-tert-C4H9)2]4- Inorganic Chemistry. 21: 3518-3526. DOI: 10.1021/Ic00139A048  0.636
1982 Papaefthymiou GC, Laskowski EJ, Frota-Pessoa S, Frankel RB, Holm RH. Antiferromagnetic exchange interactions in [Fe4S4(SR)4]2-,3- clusters Inorganic Chemistry. 21: 1723-1728. DOI: 10.1021/Ic00135A005  0.363
1982 Armstrong WH, Mascharak PK, Holm RH. Demonstration of the existence of single cubane-type molybdenum iron sulfide (MoFe3S4) clusters with S = 3/2 ground states: preparation, structure, and properties Inorganic Chemistry. 21: 1699-1701. DOI: 10.1021/Ic00134A095  0.777
1982 Strauss SH, Holm RH. Carbon monoxide affinities of iron(II) octaethylporphyrin, octaethylchlorin, and octaethylisobacteriochlorin Inorganic Chemistry. 21: 863-868. DOI: 10.1021/Ic00133A005  0.546
1982 Palermo RE, Power PP, Holm RH. Ligand substitution properties of the MFe3S4 double-cubane cluster complexes [Mo2Fe6S8(SR)9]3- and [M2Fe7S8(SR)12]3- (M = molybdenum, tungsten) Inorganic Chemistry. 21: 173-181. DOI: 10.1021/Ic00131A033  0.563
1982 CHRISTOU G, SABAT M, IBERS JA, HOLM RH. ChemInform Abstract: A NEW STRUCTURAL TYPE IN IRON-SULFIDE-THIOLATE CHEMISTRY: PREPARATION, PROPERTIES, AND STRUCTURE OF THE HEXANUCLEAR CLUSTER (FE6S9(S-TERT-C4H9)2)4- Chemischer Informationsdienst. 13. DOI: 10.1002/chin.198249281  0.594
1982 CHRISTOU G, MASCHARAK PK, ARMSTRONG WH, PAPAEFTHYMIOU GC, FRANKEL RB, HOLM RH. ChemInform Abstract: ELECTRON-TRANSFER SERIES OF MOFE3S4 DOUBLE-CUBANE CLUSTERS: ELECTRONIC PROPERTIES OF COMPONENTS AND THE STRUCTURE OF ((C2H5)4N)5(MO2FE6S8(SC6H5)9) Chemischer Informationsdienst. 13. DOI: 10.1002/chin.198235269  0.621
1982 ARMSTRONG WH, MASCHARAK PK, HOLM RH. ChemInform Abstract: DEMONSTRATION OF THE EXISTENCE OF SINGLE CUBANE-TYPE MOLYBDENUM IRON SULFIDE (MOFE3S4) CLUSTERS WITH S = 3/2 GROUND STATES: PREPARATION, STRUCTURE, AND PROPERTIES Chemischer Informationsdienst. 13. DOI: 10.1002/CHIN.198229252  0.347
1982 STRAUSS SH, HOLM RH. ChemInform Abstract: CARBON MONOXIDE AFFINITIES OF IRON(II) OCTAETHYLPORPHYRIN, OCTAETHYLCHLORIN, AND OCTAETHYLISOBACTERIOCHLORIN Chemischer Informationsdienst. 13. DOI: 10.1002/CHIN.198224094  0.425
1982 PALERMO RE, POWER PP, HOLM RH. ChemInform Abstract: LIGAND SUBSTITUTION PROPERTIES OF THE MFE3S4 DOUBLE-CUBANE CLUSTER COMPLEXES (MO2FE6S8(SR)9)3- AND (M2FE7S8(SR)12)3- (M = MOLYBDENUM, TUNGSTEN) Chemischer Informationsdienst. 13. DOI: 10.1002/Chin.198216281  0.421
1982 CHRISTOU G, HOLM RH, SABAT M, IBERS JA. ChemInform Abstract: A HEXANUCLEAR IRON-SULFIDE-THIOLATE CLUSTER: ASSEMBLY AND PROPERTIES OF (FE6S9(S-TERT-C4H9)2)4- CONTAINING THREE TYPES OF BRIDGING SULFUR ATOMS Chemischer Informationsdienst. 13. DOI: 10.1002/chin.198203262  0.498
1982 MASCHARAK PK, PAPAEFTHYMIOU GC, FRANKEL RB, HOLM RH. ChemInform Abstract: EVIDENCE FOR THE LOCALIZED IRON(III)/IRON(II) OXIDATION STATE CONFIGURATION AS AN INTRINSIC PROPERTY OF (FE2S2(SR)4)3- CLUSTERS Chemischer Informationsdienst. 13. DOI: 10.1002/chin.198203260  0.668
1981 Paech C, Reynolds JG, Singer TP, Holm RH. Structural identification of iron-sulfur clusters of the respiratory chain-linked NADH dehydrogenase. The Journal of Biological Chemistry. 256: 3167-70. PMID 7204398  0.365
1981 Holm RH. Centenary Lecture. Metal clusters in biology: quest for a synthetic representation of the catalytic site of nitrogenase Chemical Society Reviews. 10: 455. DOI: 10.1039/Cs9811000455  0.37
1981 Christou G, Holm RH, Sabat M, Ibers JA. A hexanuclear iron-sulfide-thiolate cluster: assembly and properties of [Fe6S9(S-tert-C4H9)2]4- containing three types of bridging sulfur atoms Journal of the American Chemical Society. 103: 6269-6271. DOI: 10.1021/Ja00410A071  0.629
1981 Armstrong WH, Holm RH. Synthesis and structure of a new type of molybdenum-iron-sulfur double-cubane cluster and evidence for formation of magnetically uncoupled S = 3/2 MoFe3S4 subclusters Journal of the American Chemical Society. 103: 6246-6248. DOI: 10.1021/Ja00410A057  0.651
1981 Mascharak PK, Papaefthymiou GC, Frankel RB, Holm RH. Evidence for the localized iron(III)/iron(II) oxidation state configuration as an intrinsic property of [Fe2S2(SR)4]3- clusters Journal of the American Chemical Society. 103: 6110-6116. DOI: 10.1021/Ja00410A021  0.695
1981 Stolzenberg AM, Strauss SH, Holm RH. Iron(II, III)-chlorin and -isobacteriochlorin complexes. Models of the heme prosthetic groups in nitrite and sulfite reductases: Means of formation and spectroscopic and redox properties Journal of the American Chemical Society. 103: 4763-4778. DOI: 10.1021/Ja00406A018  0.76
1981 Hagen KS, Reynolds JG, Holm RH. Definition of reaction sequences resulting in self-assembly of [Fe4S4(SR)4]2- clusters from simple reactants Journal of the American Chemical Society. 103: 4054-4063. DOI: 10.1021/Ja00404A013  0.334
1981 Reynolds JG, Holm RH. Core chalcogenide atom substitution reactions of [Fe2X2(SR)4]2- and [Fe4X4(SR)4]2-,3- clusters (X = sulfur, selenium) Inorganic Chemistry. 20: 1873-1878. DOI: 10.1021/Ic50220A052  0.386
1981 Wolff TE, Berg JM, Holm RH. Synthesis, structure, and properties of the cluster complex [MoFe4S4(SC2H5)3(C6H4O2)3]3-, containing a single cubane-type molybdenum-iron-sulfur (MoFe3S4) core Inorganic Chemistry. 20: 174-180. DOI: 10.1021/Ic50215A036  0.655
1981 STOLZENBERG AM, STRAUSS SH, HOLM RH. ChemInform Abstract: IRON(II, III)-CHLORIN AND -ISOBACTERIOCHLORIN COMPLEXES. MODELS OF THE HEME PROSTHETIC GROUPS IN NITRITE AND SULFITE REDUCTASES: MEANS OF FORMATION AND SPECTROSCOPIC AND REDOX PROPERTIES Chemischer Informationsdienst. 12. DOI: 10.1002/CHIN.198146272  0.492
1981 WOLFF TE, BERG JM, HOLM RH. ChemInform Abstract: SYNTHESIS, STRUCTURE, AND PROPERTIES OF THE CLUSTER COMPLEX (MOFE4S4(SC2H5)3(C6H4O2)3)3-, CONTAINING A SINGLE CUBANE-TYPE MOLYBDENUM-IRON-SULFUR (MOFE3S4) CORE Chemischer Informationsdienst. 12. DOI: 10.1002/CHIN.198117319  0.379
1981 CHRISTOU G, HAGEMAN RV, HOLM RH. ChemInform Abstract: HYDROGEN EVOLUTION FROM HOMOGENEOUS REACTION SYSTEMS CONTAINING REDUCED MOLYBDENUM-IRON-SULFUR CLUSTERS Chemischer Informationsdienst. 12. DOI: 10.1002/CHIN.198111298  0.3
1980 Ibers JA, Holm RH. Modeling coordination sites in metallobiomolecules. Science (New York, N.Y.). 209: 223-35. PMID 7384796 DOI: 10.1126/Science.7384796  0.432
1980 Frankel RB, Wolff TE, Power PP, Holm RH. ELECTRONIC PROPERTIES OF MOLYBDENUM-IRON-SULFUR-CLUSTERS : APPROACHES TO THE MOLYBDENUM SITE IN NITROGENASE Le Journal De Physique Colloques. 41: C1-495-C1-496. DOI: 10.1051/Jphyscol:19801196  0.572
1980 Papaefthymiou GC, Frankel RB, Foner S, Laskowski EJ, Holm RH. MAGNETIC PROPERTIES OF [Fe4S4(SR)4]3- CLUSTERS Le Journal De Physique Colloques. 41: C1-493-C1-494. DOI: 10.1051/Jphyscol:19801195  0.354
1980 Christou G, Hageman RV, Holm RH. Hydrogen evolution from homogeneous reaction systems containing reduced molybdenum-iron-sulfur clusters Journal of the American Chemical Society. 102: 7600-7601. DOI: 10.1021/ja00545a052  0.485
1980 Wolff TE, Power PP, Frankel RB, Holm RH. Synthesis and electronic and redox properties of "double-cubane" cluster complexes containing molybdenum iron sulfide (MoFe3S4) and tungsten iron sulfide (WFe3S4) cores Journal of the American Chemical Society. 102: 4694-4703. DOI: 10.1021/Ja00534A023  0.586
1980 Reynolds JG, Coyle CL, Holm RH. Electron exchange kinetics of [Fe4S4(SR)4]2-/[Fe4S4(SR)4]3- and [Fe4Se4(SR)4]2-/[Fe4Se4(SR)4]3- systems. Estimates of the intrinsic self-exchange rate constant of 4-Fe sites in oxidized and reduced ferredoxins Journal of the American Chemical Society. 102: 4350-4355. DOI: 10.1021/Ja00533A010  0.324
1980 Stolzenberg AM, Spreer LO, Holm RH. Octaethylisobacteriochlorin, a model of the sirohydrochlorin ring system of siroheme enzymes: preparation and spectroscopic and electrochemical properties of the free base and its zinc(II) complex Journal of the American Chemical Society. 102: 364-370. DOI: 10.1021/Ja00521A059  0.666
1980 Reynolds JG, Holm RH. Improved syntheses of the dimeric complexes [Fe2X2(SC6H4Y)4]2- and [Fe2X2((SCH2)2C6H4)2]2- (X = sulfur, selenium), analogs of the 2-Fe sites of oxidized ferredoxin proteins Inorganic Chemistry. 19: 3257-3260. DOI: 10.1021/Ic50213A011  0.367
1980 Wolff TE, Berg JM, Power PP, Hodgson KO, Holm RH. Structural characterization of the iron-bridged "double-cubane" cluster complexes [Mo2Fe7S8(SC2H5)12]3- and [M2Fe7S8(SCH2C6H5)12]4- (M = molybdenum, tungsten) containing MFe3S4 cores Inorganic Chemistry. 19: 430-437. DOI: 10.1021/Ic50204A029  0.712
1980 Hagen KS, Berg JM, Holm RH. The synthesis and structure of deca(benzenethiolato)tetraferrate(II) dianion, an intermediate in the assembly of [Fe4S4(SC6H5)4]2- from simple reagents Inorganica Chimica Acta. 45. DOI: 10.1016/S0020-1693(00)80078-X  0.327
1980 WOLFF TE, POWER PP, FRANKEL RB, HOLM RH. ChemInform Abstract: SYNTHESIS AND ELECTRONIC AND REDOX PROPERTIES OF “DOUBLE-CUBANE” CLUSTER COMPLEXES CONTAINING MOLYBDENUM IRON SULFIDE (MOFE3S4) AND TUNGSTEN IRON SULFIDE (WFE3S4) CORES Chemischer Informationsdienst. 11. DOI: 10.1002/chin.198040291  0.528
1979 McMillan RS, Renaud J, Reynolds JG, Holm RH. Biologically related iron-sulfur clusters as reaction centers. Reduction of acetylene to ethylene in systems based on [Fe4S4(SR)4]3-. Journal of Inorganic Biochemistry. 11: 213-27. PMID 512659 DOI: 10.1016/S0162-0134(00)80019-7  0.458
1979 Kurtz DM, Holm RH, Ruzicka FJ, Beinert H, Coles CJ, Singer TP. The high potential iron-sulfur cluster of aconitase is a binuclear iron-sulfur cluster. The Journal of Biological Chemistry. 254: 4967-9. PMID 447628  0.361
1979 Kurtz DM, McMillan RS, Burgess BK, Mortenson LE, Holm RH. Identification of iron-sulfur centers in the iron-molybdenum proteins of nitrogenase. Proceedings of the National Academy of Sciences of the United States of America. 76: 4986-9. PMID 291915 DOI: 10.1073/Pnas.76.10.4986  0.397
1979 Coles CJ, Holm RH, Kurtz DM, Orme-Johnson WH, Rawlings J, Singer TP, Wong GB. Characterization of the iron-sulfur centers in succinate dehydrogenase. Proceedings of the National Academy of Sciences of the United States of America. 76: 3805-8. PMID 226982 DOI: 10.1073/Pnas.76.8.3805  0.619
1979 Stolzenberg AM, Spreer LO, Holm RH. Iron octaethylisobacteriochlorin, a model system for the siroheme prosthetic group of nitrite and sulphite reductases Journal of the Chemical Society, Chemical Communications. 1077-1078. DOI: 10.1039/C39790001077  0.692
1979 Laskowski EJ, Reynolds JG, Frankel RB, Foner S, Papaefthymiou GC, Holm RH. Demonstration of the generality of the [Fe4S4(SR)4]2- (compressed D2d)/[Fe4S4(SR)4]3- (elongated D2d) structural change in electron-transfer reactions of ferredoxin 4-Fe site analogs. A model for unconstrained structural changes in ferredoxin proteins Journal of the American Chemical Society. 101: 6562-6570. DOI: 10.1021/Ja00516A014  0.366
1979 Wolff TE, Berg JM, Power PP, Hodgson KO, Holm RH, Frankel RB. Self-assembly of molybdenum-iron-sulfur clusters as a synthetic approach to the molybdenum site in nitrogenase. Identification of the major products formed by the system FeCl3/MS42-/C2H5SH (M = Molybdenum, tungsten) Journal of the American Chemical Society. 101: 5454-5456. DOI: 10.1021/Ja00512A076  0.661
1979 Berg JM, Hodgson KO, Holm RH. Crystal structure of [(C2H5)4N]3[Fe4S4(SCH2Ph)4], a reduced ferredoxin site analog with a nontetragonal Fe4S4 core structure in the solid state Journal of the American Chemical Society. 101: 4586-4593. DOI: 10.1021/Ja00510A025  0.534
1979 Wolff TE, Berg JM, Hodgson KO, Frankel RB, Holm RH. Synthetic approaches to the molybdenum site in nitrogenase. Preparation and structural properties of the molybdenum-iron-sulfur "double-cubane" cluster complexes [Mo2Fe6S8(SC2H5)9]3- and [Mo2Fe6S9(SC2H5)8]3- Journal of the American Chemical Society. 101: 4140-4150. DOI: 10.1021/Ja00509A021  0.656
1979 Wong GB, Kurtz DM, Holm RH, Mortenson LE, Upchurch RG. A fluorine-19 NMR method for identification of iron-sulfur cores extruded from active centers of proteins, with applications to milk xanthine oxidase and the iron-molybdenum proteins of nitrogenase Journal of the American Chemical Society. 101: 3078-3090. DOI: 10.1021/Ja00505A041  0.331
1979 WOLFF TE, BERG JM, POWER PP, HODGSON KO, HOLM RH, FRANKEL RB. ChemInform Abstract: SELF-ASSEMBLY OF MOLYBDENUM-IRON-SULFUR CLUSTERS AS A SYNTHETIC APPROACH TO THE MOLYBDENUM SITE IN NITROGENASE. IDENTIFICATION OF THE MAJOR PRODUCTS FORMED BY THE SYSTEM FECL3/MS42-/C2H5SH (M = MOLYBDENUM, TUNGSTEN) Chemischer Informationsdienst. 10. DOI: 10.1002/chin.197951081  0.47
1979 WOLFF TE, BERG JM, HODGSON KO, FRANKEL RB, HOLM RH. ChemInform Abstract: SYNTHETIC APPROACHES TO THE MOLYBDENUM SITE IN NITROGENASE. PREPARATION AND STRUCTURAL PROPERTIES OF THE MOLYBDENUM-IRON-SULFUR “DOUBLE-CUBANE” CLUSTER COMPLEXES (MO2FE6S8(SC2H5)9)3- AND (MO2FE6S9(SC2H5)8)3- Chemischer Informationsdienst. 10. DOI: 10.1002/chin.197944059  0.377
1978 Orme-Johnson WH, Holm RH. Identification of iron--sulfur clusters in proteins. Methods in Enzymology. 53: 268-74. PMID 213682 DOI: 10.1016/S0076-6879(78)53032-2  0.598
1978 Kurtz DM, Wong GB, Holm RH. Structural identification of the extruded cores of the active centers of iron-sulfur proteins by fluorine-19 nuclear magnetic resonance spectroscopy. Application to milk xanthine oxidase [18] Journal of the American Chemical Society. 100: 6777-6779. DOI: 10.1021/Ja00489A051  0.324
1978 Johnson RW, Holm RH. Reaction chemistry of the iron-sulfur protein site analogs [Fe4S4(SR)4]2-. Sequential thiolate ligand substitution reactions with electrophiles Journal of the American Chemical Society. 100: 5338-5344. DOI: 10.1021/Ja00485A014  0.378
1978 Laskowski EJ, Frankel RB, Gillum WO, Papaefthymiou GC, Renaud J, Ibers JA, Holm RH. Synthetic analogs of the 4-Fe active sites of reduced ferredoxins. Electronic properties of the tetranuclear trianions [Fe4S4(SR)4]3- and the structure of [(C2H5)3(CH3)N]3[Fe4S4(SC6H5)4] Journal of the American Chemical Society. 100: 5322-5337. DOI: 10.1021/Ja00485A013  0.46
1978 Reynolds JG, Laskowski EJ, Holm RH. Proton magnetic resonance properties of the tetranuclear clusters [Fe4S4(SR)4]3-, analogs of the 4-Fe sites of reduced ferredoxins Journal of the American Chemical Society. 100: 5315-5322. DOI: 10.1021/Ja00485A012  0.402
1978 Wolff TE, Berg JM, Warrick C, Hodgson KO, Holm RH, Frankel RB. The molybdenum-iron-sulfur cluster complex [Mo2Fe6S9(SC2H5)8]3-. A synthetic approach to the molybdenum site in nitrogenase Journal of the American Chemical Society. 100: 4630-4632. DOI: 10.1021/Ja00482A070  0.642
1978 Wong GB, Bobrik MA, Holm RH. Inorganic derivatives of iron sulfide thiolate dimers and tetramers: synthesis and properties of the halide series [Fe2S2X4]2- and [Fe4S4X4]2- (X = chlorine, bromine, iodine) Inorganic Chemistry. 17: 578-584. DOI: 10.1021/Ic50181A012  0.375
1978 LASKOWSKI EJ, FRANKEL RB, GILLUM WO, PAPAEFTHYMIOU GC, RENAUD J, IBERS JA, HOLM RH. ChemInform Abstract: SYNTHETIC ANALOGS OF THE 4-FE ACTIVE SITES OF REDUCED FERREDOXINS. ELECTRONIC PROPERTIES OF THE TETRANUCLEAR TRIANIONS (FE4S4(SR)4)3- AND THE STRUCTURE OF ((C2H5)3(CH3)N)3(FE4S4(SC6H5)4) Chemischer Informationsdienst. 9. DOI: 10.1002/Chin.197848068  0.462
1978 REYNOLDS JG, LASKOWSKI EJ, HOLM RH. ChemInform Abstract: PROTON MAGNETIC RESONANCE PROPERTIES OF THE TETRANUCLEAR CLUSTERS (FE4S4(SR)4)3-, ANALOGS OF THE 4-FE SITES OF REDUCED FERREDOXINS Chemischer Informationsdienst. 9. DOI: 10.1002/Chin.197848055  0.405
1977 Lane RW, Ibers JA, Frankel RB, Papaefthymiou GC, Holm RH. Synthetic analogues of the active sites of iron-sulfur proteins. 14. Synthesis, properties, and structures of bis(o-xylyl-alpha,alpha'-dithiolato)ferrate(II, III) anions, analogues of oxidized and reduced rubredoxin sites. Journal of the American Chemical Society. 99: 84-98. PMID 830690 DOI: 10.1021/Ja00443A017  0.477
1977 Hill CL, Steenkamp DJ, Holm RH, Singer TP. Identification of the iron-sulfur center in trimethylamine dehydrogenase. Proceedings of the National Academy of Sciences of the United States of America. 74: 547-51. PMID 265519 DOI: 10.1073/Pnas.74.2.547  0.595
1977 Bobrik MA, Hodgson KO, Holm RH. Inorganic derivatives of iron-sulfide-thiolate dimers and tetramers. Structures of tetrachloro-.mu.-disulfido-diferrate(III) and tetrakis(chloro-.mu.3-sulfido-iron) dianions Inorganic Chemistry. 16: 1851-1858. DOI: 10.1021/Ic50174A005  0.377
1977 Holm RH. Synthetic approaches to the active sites of iron-sulfur proteins Accounts of Chemical Research. 10: 427-434. DOI: 10.1021/Ar50120A001  0.326
1977 HILL CL, RENAUD J, HOLM RH, MORTENSON LE. ChemInform Abstract: SYNTHETIC ANALOGS OF THE ACTIVE SITES OF IRON-SULFUR PROTEINS. 15. COMPARATIVE POLAROGRAPHIC POTENTIALS OF THE (FE4S4(SR)4)2-,3- AND CLOSTRIDIUM PASTEURIANUM FERREDOXIN REDOX COUPLES Chemischer Informationsdienst. 8. DOI: 10.1002/Chin.197727287  0.532
1977 Lane RW, Wedd AG, Gillum WO, Laskowski EJ, Holm RH, Frankel RB, Papaethymiou GC. Synthesis And Electronic Properties Of The Tetranuclear Trianions (Fe4S4(Sr)4)3-, Analogs Of The 4-Fe Active Sites Of Reduced Ferrodoxins Cheminform. 8. DOI: 10.1002/Chin.197724336  0.366
1977 LANE RW, IBERS JA, FRANKEL RB, PAPAEFTHYMIOU GC, HOLM RH. ChemInform Abstract: SYNTHETIC ANALOGS OF THE ACTIVE SITES OF IRON-SULFUR PROTEINS. 14. SYNTHESIS, , PROPERTIES, AND STRUCTURES OF BIS(O-XYLYL-α,α′-DITHIOLATO)FERRATE(II,III) ANIONS, ANALOGS OF OXIDIZED AND REDUCED RUBREDOXIN SITES Chemischer Informationsdienst. 8: no-no. DOI: 10.1002/Chin.197714054  0.511
1977 PENG S, IBERS JA, MILLAR M, HOLM RH. ChemInform Abstract: Crystal and Molecular Structure of [Ni(Me4[14]hexaenato N4)]2(CF3SO3)2: Conversion of a Metal-Stabilized π-Radical to a Diamagnetic Dimer with a Long Metal-Metal Bond and Eclipsed Macrocyclic Ligands upon Crystallization. Chemischer Informationsdienst. 8: no-no. DOI: 10.1002/Chin.197710079  0.417
1976 Holm RH, Tang SC, Koch S, Papaefthymiou GC, Foner S, Frankel RB, Ibers JA. Model system studies of axial ligation in the oxidized reaction states of cytochrome P-450 enzymes. Advances in Experimental Medicine and Biology. 74: 321-34. PMID 183472 DOI: 10.1007/978-1-4684-3270-1_25  0.437
1976 Tang SC, Koch S, Papaefthymiou GC, Foner S, Frankel RB, Ibers JA, Holm RH. Axial ligation modes in iron(III) Porphyrins. Models for the oxidized reaction states of cytochrome P-450 enzymes and the molecular structure of iron(III) protoporphyrin IX dimethyl ester p-nitrobenzenethiolate. Journal of the American Chemical Society. 98: 2414-34. PMID 177476 DOI: 10.1021/Ja00425A008  0.497
1976 PAPAEFTHYMIOU GC, FRANKEL RB, FONER S, TANG SC, KOCH S, HOLM RH. MODEL Fe(III) PORPHYRIN SYSTEMS : AXIAL LIGATION IN OXIDIZED CYTOCHROME P-450.S Le Journal De Physique Colloques. 37: C6-209-C6-215. DOI: 10.1051/Jphyscol:1976644  0.406
1976 FRANKEL RB, PAPAEFTHYMIOU GC, LANE RW, HOLM RH. SYNTHETIC ANALOGS OF THE ACTIVE SITES OF OXIDIZED AND REDUCED RUBREDOXIN Le Journal De Physique Colloques. 37: C6-165-C6-170. DOI: 10.1051/Jphyscol:1976635  0.367
1976 Peng S, Ibers JA, Millar M, Holm RH. Crystal and molecular structure of bis[(tetramethyl[14]hexaenatotetraaza)nickel] bis(trifluoromethanesulfonate): conversion of a metal-stabilized .pi.-radical to a diamagnetic dimer with a long metal-metal bond and eclipsed macrocyclic ligands upon crystallization Journal of the American Chemical Society. 98: 8037-8041. DOI: 10.1021/Ja00441A026  0.416
1976 Gillum WO, Frankel RB, Foner S, Holm RH. Synthetic analogues of the active sites of iron-sulfur proteins. XIII. Further electronic structural relationships between the analogues [Fe2S2(SR)4]2- and the active sites of oxidized 2Fe-2S* proteins Inorganic Chemistry. 15: 1095-1100. DOI: 10.1021/Ic50159A023  0.385
1975 Koch S, Tang SC, Holm RH, Frankel RH, Ibers JA. Letter: Ferric porphyrin thiolates. Possible relationship to cytochrome P-450 enzymes and the structure of (p-nitrobenzenethiolato)iron(III) protoporphyrin IX dimethyl ester. Journal of the American Chemical Society. 97: 916-8. PMID 1133375 DOI: 10.1021/Ja00837A052  0.471
1975 Dukes GR, Holm RH. Synthetic analogs of the active sites of iron-sulfur proteins; X. Kinetics and mechanism of the ligand substitution reactions of arylthiols with the tetranuclear clusters [Fe4S4(SR)4]2 minus;. Journal of the American Chemical Society. 97: 528-33. PMID 1133365  0.345
1975 Que L, Holm RH, Mortenson LE. Letter: Extrusion of Fe2S2 and Fe4S4 cores from the active sites of ferredoxin proteins. Journal of the American Chemical Society. 97: 463-4. PMID 1133364 DOI: 10.1021/Ja00835A064  0.625
1975 Patterson GS, Holm RH. Structural and electronic effects on the polarographic half-wave potentials of copper (II) chelate complexes. Bioinorganic Chemistry. 4: 257-75. PMID 1125339 DOI: 10.1016/S0006-3061(00)80108-8  0.343
1975 Lane RW, Ibers JA, Frankel RB, Holm RH. Synthetic analogs of active sites of iron-sulfur proteins: bis (o-xylyldithiolato) ferrate (III) monoanion, a structurally unconstrained model for the rubredoxin Fe-S4 unit. Proceedings of the National Academy of Sciences of the United States of America. 72: 2868-72. PMID 1059080 DOI: 10.1073/Pnas.72.8.2868  0.551
1975 Holm RH. Iron-sulphur clusters in natural and synthetic systems. Endeavour. 34: 38-43. PMID 54250  0.301
1975 Millar M, Holm RH. Electronic structure of 5,7,12,14-tetramethyl-1,4,8,11-tetra-azacyclotetradeca-2,4,6,9,11,13-hexaenato–nickel(II) cation radical, the central member of a ligand-based electron-transfer series Journal of the Chemical Society, Chemical Communications. 169-170. DOI: 10.1039/C39750000169  0.348
1975 Koch S, Holm RH, Frankel RB. Synthesis and ground state electronic properties of tetraaza macrocyclic iron(II, III) complexes containing [14]-, [15]-, and [16]-membered rings Journal of the American Chemical Society. 97: 6714-6723. DOI: 10.1021/Ja00856A020  0.725
1975 Millar M, Holm RH. Ligand-based redox reactions. Analysis of the electron paramagnetic resonance spectrum of the [Ni(Me4[14]hexaenatoN4)]+ cation radical, the central member of a three-membered electron transfer series containing a tetraaza[14]annulene ligand system Journal of the American Chemical Society. 97: 6052-6058. DOI: 10.1021/Ja00854A017  0.327
1975 Tang SC, Holm RH. Synthetic transformations of tetraaza macrocyclic metal complexes. Preparation of the corrinoid and other unsaturated ring systems by oxidative dehydrogenation reactions of nickel(II), copper(II), and cobalt(II) macrocycles Journal of the American Chemical Society. 97: 3359-3366. DOI: 10.1021/Ja00845A014  0.327
1975 Mayerle JJ, Denmark SE, DePamphilis BV, Ibers JA, Holm RH. Synthetic analogs of the active sites of iron-sulfur proteins. XI. Synthesis and properties of complexes containing the iron sulfide (Fe2S2) core and the structures of bis[o-xylyl-.alpha.,.alpha.'-dithiolato-.mu.-sulfido-ferrate(III)] and bis[p-tolylthiolato-.mu.-sulfido-ferrate(III)] dianions Journal of the American Chemical Society. 97: 1032-1045. DOI: 10.1021/Ja00838A015  0.509
1975 Koch S, Tang SC, Holm RH, Frankel RB. [FeIIIN4SR] coordination unit. Synthesis and ground state electronic properties of macrocyclic ferric thilates Journal of the American Chemical Society. 97: 914-916. DOI: 10.1021/Ja00837A051  0.678
1975 Herskovitz T, DePamphilis BV, Gillum WO, Holm RH. Bis[bis(1,2-ethanedithiolato)ferrate(III)] dianion, a .mu.2-thiolato dimer. Synthesis and properties Inorganic Chemistry. 14: 1426-1429. DOI: 10.1021/Ic50148A051  0.344
1975 MAYERLE JJ, DENMARK SE, DEPAMPHILIS BV, IBERS JA, HOLM RH. ChemInform Abstract: SYNTHETIC ANALOGS OF THE ACTIVE SITES OF IRON-SULFUR PROTEINS PART 11, SYNTHESIS AND PROPERTIES OF COMPLEXES CONTAINING THE FE2S2 CORE AND THE STRUCTURES OF BIS(O-XYLYL-ALPHA,ALPHA′-DITHIOLATO-MU-SULFIDO-FERRATE(III)) AND BIS(P-TOLYLT Chemischer Informationsdienst. 6: no-no. DOI: 10.1002/Chin.197520393  0.505
1975 KOCH S, TANG SC, HOLM RH, FRANKEL RB, IBERS JA. ChemInform Abstract: FERRIC PORPHYRIN THIOLATES, POSSIBLE RELATIONSHIP TO CYTOCHROME P-450 ENZYMES AND THE STRUCTURE OF (P-NITROBENZENETHIOLATO)IRON(III) PROTOPORPHYRIN IX DIMETHYL ESTER Chemischer Informationsdienst. 6: no-no. DOI: 10.1002/Chin.197518394  0.731
1975 KOCH S, TANG SC, HOLM RH, FRANKEL RB. ChemInform Abstract: THE (FE(III)N4SR) COORDINATION UNIT, SYNTHESIS AND GROUND STATE ELECTRONIC PROPERTIES OF MACROCYCLIC FERRIC THIOLATES Chemischer Informationsdienst. 6: no-no. DOI: 10.1002/chin.197518393  0.698
1975 DUKES GR, HOLM RH. ChemInform Abstract: SYNTHETIC ANALOGS OF THE ACTIVE SITES OF IRON-SULFUR PROTEINS PART 10, KINETICS AND MECHANISM OF THE LIGAND SUBSTITUTION REACTIONS OF ARYLTHIOLS WITH THE TETRANUCLEAR CLUSTERS (FE4S4(SR)4)(2-) Chemischer Informationsdienst. 6. DOI: 10.1002/chin.197516398  0.354
1974 Que L, Bobrik MA, Ibers JA, Holm RH. Synthetic analogs of the active sites of iron-sulfur proteins. VII. Ligand substitution reactions of the tetranuclear clusters (Fe4S4(SR)4)2- and the structure of ((CH3)4N)2(Fe4S4(SC6H5)4). Journal of the American Chemical Society. 96: 4168-78. PMID 4854592 DOI: 10.1021/Ja00820A018  0.733
1974 DePamphilis BV, Averill BA, Herskovitz T, Que L, Holm RH. Synthetic analogs of the active sites of iron-sulfur proteins. VI. Spectral and redox characteristics of the tetranuclear clusters (Fe4S4(SR)4).2-. Journal of the American Chemical Society. 96: 4159-67. PMID 4854591 DOI: 10.1021/Ja00820A017  0.782
1974 Holm RH, Averill BA, Herskovitz T, Frankel RB, Gray HB, Siiman O, Grunthaner FJ. Equivalence of metal centers in the iron-sulfur protein active site analogs (Fe4S4(SR)4)2-. Journal of the American Chemical Society. 96: 2644-6. PMID 4833717 DOI: 10.1002/Chin.197426417  0.592
1974 Holm RH, Phillips WD, Averill BA, Mayerle JJ, Herskovitz T. Synthetic analogs of the active sites of iron-sulfur proteins. V. Proton resonance properties of the tetranuclear clusters (Fe4S4(SR)4). Evidence for dominant contact interactions. Journal of the American Chemical Society. 96: 2109-17. PMID 4833642 DOI: 10.1021/Ja00814A020  0.634
1974 Bobrik MA, Que L, Holm RH. Synthetic analogs of the active sites of iron-sulfur proteins. IV. Ligand substitution reactions of the tetranuclear clusters (Fe4S4(SR)4)2-. Journal of the American Chemical Society. 96: 285-7. PMID 4810571 DOI: 10.1021/Ja00808A064  0.73
1974 Que L, Anglin JR, Bobrik MA, Davison A, Holm RH. Synthetic analogs of the active sites of iron-sulfur proteins. IX. Formation and some electronic and reactivity properties of Fe4S4 Glycyl-L-cysteinylglycyl oligopeptide complexes obtained by ligand substitution reactions. Journal of the American Chemical Society. 96: 6042-8. PMID 4416035 DOI: 10.1021/Ja00826A014  0.699
1974 Frankel RB, Herskovitz T, Averill BA, Holm RH, Krusic PJ, Phillips WD. Synthetic analogs of the active sites of iron-sulfur proteins. 8. Some electronic properties of (Fe4S4(SR)4)3-, analogs of reduced bacterial ferredoxins. Biochemical and Biophysical Research Communications. 58: 974-82. PMID 4365892 DOI: 10.1016/S0006-291X(74)80239-1  0.621
1974 FRANKEL RB, AVERILL BA, HOLM RH. MÖSSBAUER PROPERTIES OF SYNTHETIC ANALOGS OF ACTIVE SITES OF THE IRON-SULFUR PROTEINS Le Journal De Physique Colloques. 35: C6-107-C6-112. DOI: 10.1051/Jphyscol:1974609  0.623
1974 Pignolet LH, Patterson GS, Weiher JF, Holm RH. Magnetic and Moessbauer properties of bis (N,N-disubstituted dithiocarbamato)dithioleneiron complexes. Evidence for a singlet-triplet spin-state equilibrium Inorganic Chemistry. 13: 1263-1268. DOI: 10.1021/Ic50136A001  0.671
1974 Que LJ, Anglin JR, Bobrik MA, Davison A, Holm RH. Synthetic Analogs Of The Active Sites Of Iron-Sulfur Proteins Part 9, Formation And Some Electronic And Reactivity Properties Of Fe4S4 Glycyl-L-Cysteinylglycyl Oligopeptide Complexes Obtained By Ligand Substitution Reactions Cheminform. 5. DOI: 10.1002/Chin.197448437  0.409
1974 Que LJ, Bobrik MA, Ibers JA, Holm RH. Synthetic Analogs Of The Active Sites Of Iron-Sulfur Proteins Part 7, Ligand Substitution Reactions Of The Tetranuclear Clusters (Fe4S4(Sr)4)(2-) And The Structure Of ((Ch3)4N)2(Fe4S4(Sc6H5)4) Cheminform. 5. DOI: 10.1002/Chin.197436362  0.563
1974 DEPAMPHILIS BV, AVERILL BA, HERSKOVITZ T, QUE LJ, HOLM RH. ChemInform Abstract: SYNTHETIC ANALOGS OF THE ACTIVE SITES OF IRON-SULFUR PROTEINS PART 6, SPECTRAL AND REDOX CHARACTERISTICS OF THE TETRANUCLEAR CLUSTERS (FE4S4(SR)4)(2-) Chemischer Informationsdienst. 5: no-no. DOI: 10.1002/Chin.197436361  0.653
1974 PIGNOLET LH, PATTERSON GS, WEIHER JF, HOLM RH. ChemInform Abstract: MAGNETIC AND MOESSBAUER PROPERTIES OF BIS(N,N-DISUBSTITUTED DITHIOCARBAMATO)DITHIOLENEIRON COMPLEXES, EVIDENCE FOR A SINGLET-TRIPLET SPIN-STATE EQUILIBRIUM Chemischer Informationsdienst. 5: no-no. DOI: 10.1002/CHIN.197433384  0.647
1974 HOLM RH, PHILLIPS WD, AVERILL BA, MAYERLE JJ, HERSKOVITZ T. ChemInform Abstract: SYNTHETIC ANALOGS OF THE ACTIVE SITES OF IRON-SULFUR PROTEINS PART 5, PROTONRESONANCE PROPERTIES OF THE TETRANUCLEAR CLUSTERS (FE4S4(SR)4)(2-), EVIDENCE FOR DOMINANT CONTACT INTERACTIONS Chemischer Informationsdienst. 5: no-no. DOI: 10.1002/Chin.197424351  0.641
1974 BOBRIK MA, QUE LJ, HOLM RH. ChemInform Abstract: SYNTHETIC ANALOGS OF THE ACTIVE SITES OF IRON-SULFUR PROTEINS PART 4, LIGAND SUBSTITUTION REACTIONS OF THE TETRANUCLEAR CLUSTERS (FE4S4(SR)4)(2-) Chemischer Informationsdienst. 5: no-no. DOI: 10.1002/Chin.197412417  0.466
1974 TANG SC, KOCH S, WEINSTEIN GN, LANE RW, HOLM RH. ChemInform Abstract: SYNTHETIC APPROACHES TO 14-, 15-, AND 16-MEMBERED TETRAAZA MACROCYCLES AND THEIR METAL COMPLEXES Chemischer Informationsdienst. 5: no-no. DOI: 10.1002/chin.197402329  0.649
1973 Averill BA, Herskovitz T, Holm RH, Ibers JA. Synthetic analogs of the active sites of iron-sulfur proteins. II. Synthesis and structure of the tetra(mercapto-m 3 -sulfido-iron) clusters, (Fe 4 S 4 (SR) 4 ) 2- . Journal of the American Chemical Society. 95: 3523-34. PMID 4708377 DOI: 10.1021/Ja00792A013  0.714
1973 Mayerle JJ, Frankel RB, Holm RH, Ibers JA, Phillips WD, Weiher JF. Synthetic analogs of the active sites of iron-sulfur proteins. Structure and properties of bis(o-xylyldithiolato-m2-sulfidoferrate (3)), an analog of the 2Fe-2S proteins. Proceedings of the National Academy of Sciences of the United States of America. 70: 2429-33. PMID 4525429 DOI: 10.1073/Pnas.70.8.2429  0.529
1973 Bonnet JJ, Eaton SS, Eaton GR, Holm RH, Ibers JA. Spectroscopic and structural characterization of ruthenium(II) carbonyl-porphine complexes Journal of the American Chemical Society. 95: 2141-2149. DOI: 10.1021/Ja00788A011  0.608
1973 Eaton SS, Eaton GR, Holm RH, Muetterties EL. Intramolecular rearrangement reactions of tris-chelate complexes. IV. Rearrangements of tris(.alpha.-isopropenyl- and .alpha.-isopropyltropolonate)metal(III,IV) complexes Journal of the American Chemical Society. 95: 1116-1124. DOI: 10.1021/Ja00785A020  0.498
1973 La Mar GN, Eaton GR, Holm RH, Walker FA. Proton magnetic resonance investigation of antiferromagnetic oxo-bridged ferric dimers and related high-spin monomeric ferric complexes Journal of the American Chemical Society. 95: 63-75. DOI: 10.1021/Ja00782A012  0.566
1973 Tang SC, Koch S, Weinstein GN, Lane RW, Holm RH. Synthetic approaches to 14-, 15-, and 16-membered tetraaza macrocycles and their metal complexes Inorganic Chemistry. 12: 2589-2595. DOI: 10.1021/Ic50129A020  0.671
1973 Parks J, Wagner B, Holm R. Syntheses employing pyridyllithium reagents: new routes to 2,6-disubstituted pyridines and 6,6′-disubstituted 2,2′-bipyridyls Journal of Organometallic Chemistry. 56: 53-66. DOI: 10.1016/S0022-328X(00)89953-2  0.309
1973 AVERILL BA, HERSKOVITZ T, HOLM RH, IBERS JA. ChemInform Abstract: SYNTHETIC ANALOGS OF THE ACTIVE SITES OF IRON-SULFUR PROTEINS PART 2, SYNTHESIS AND STRUCTURE OF THE TETRA(MERCAPTO-MU(3)-SULFIDO-IRON) CLUSTERS, (FE4S4(SR)4)(2-) Chemischer Informationsdienst. 4: no-no. DOI: 10.1002/Chin.197332390  0.698
1973 BONNET JJ, EATON SS, EATON GR, HOLM RH, IBERS JA. ChemInform Abstract: NMR- UND MASSENSPEKTROSKOPISCHE CHARAKTERISIERUNG, KRISTALLSTRUKTUR UND NEUERKENNUNG VON CARBONYL-AETHANOL-TETRAPHENYL- UND -TETRAKIS-(P-ISOPROPYLPHENYL)-PORPHINATORUTHENIUM(II) Chemischer Informationsdienst. 4: no-no. DOI: 10.1002/Chin.197324392  0.558
1973 EATON SS, EATON GR, HOLM RH, MUETTERTIES EL. ChemInform Abstract: INTRAMOLEKULARE UMLAGERUNGSRK. VON TRIS-(CHELAT)-KOMPLEXEN 4. MITT. WEITERE NMR-SPEKTROSKOPISCHE UNTERSUCHUNG DER UMLAGERUNGEN VON TRIS-(ALPHA-ISOPROPENYL- UND ALPHA-ISOPROPYLTROPOLONATO)-METALL(III)- UND -METALL(IV)-KOMPLEXEN (I) Chemischer Informationsdienst. 4: no-no. DOI: 10.1002/Chin.197317383  0.454
1973 LA MAR GN, EATON GR, HOLM RH, WALKER FA. ChemInform Abstract: PMR-UNTERSUCHUNG VON ANTIFERROMAGNETISCHEN SAUERSTOFF-UEBERBRUECKTEN DIMEREN SOWIE ANALOGEN MONOMEREN HIGH-SPIN EISEN(III)-KOMPLEXEN VON RINGSUBSTITUIERTEN N,N′-AETHYLEN-BIS-(SALICYLIDENAMINEN) UND TETRAPHENYL-, -P-TOLYL-, -N-PROPYL-P Chemischer Informationsdienst. 4: no-no. DOI: 10.1002/Chin.197311392  0.469
1972 Herskovitz T, Averill BA, Holm RH, Ibers JA, Phillips WD, Weiher JF. Structure and properties of a synthetic analogue of bacterial iron--sulfur proteins. Proceedings of the National Academy of Sciences of the United States of America. 69: 2437-41. PMID 4506765 DOI: 10.1073/Pnas.69.9.2437  0.686
1972 Eaton SS, Hutchison JR, Holm RH, Muetterties EL. Intramolecular rearrangement reactions of tris-chelate complexes. III. Analysis of the rearrangements of tris(.alpha.-isopropenyl- and .alpha.-isopropyltropolonato)aluminum(III) and -cobalt(III). Examples of stereochemically nonrigid aluminum(III) and cobalt(III) complexes Journal of the American Chemical Society. 94: 6411-6426. DOI: 10.1021/Ja00773A026  0.323
1972 Larsen E, LaMar GN, Wagner BE, Parks JE, Holm RH. Three-dimensional macrocyclic encapsulation reactions. III. Geometrical and electronic features of tris(diimine) complexes of trigonal-prismatic, antiprismatic, and intermediate stereochemistry Inorganic Chemistry. 11: 2652-2668. DOI: 10.1021/Ic50117A019  0.34
1972 Patterson GS, Holm RH. Effects of chelate ring substituents on the polarographic redox potentials of tris(.beta.-diketonato)ruthenium(II,III) complexes Inorganic Chemistry. 11: 2285-2288. DOI: 10.1021/Ic50115A072  0.308
1972 Herskovitz T, Forbes CE, Holm RH. Dithiotropolonates. III. Ring-alkylation reactions of bis(dithiotropolonato)nickel(II) and -zinc(II) complexes Inorganic Chemistry. 11: 1318-1323. DOI: 10.1021/Ic50112A032  0.335
1972 Pignolet LH, Lewis RA, Holm RH. Synthesis and stereochemistry of bis(N,N-disubstituted-dithiocarbamato)maleonitriledithioleneiron complexes Inorganic Chemistry. 11: 99-104. DOI: 10.1021/Ic50107A023  0.672
1972 Eaton SS, Eaton GR, Holm RH. Inter- and intramolecular ligand exchange reactions of ruthenium(II) carbonyl porphine complexes with nitrogen bases Journal of Organometallic Chemistry. 39: 179-195. DOI: 10.1016/S0022-328X(00)88918-4  0.541
1972 Baldwin JE, Holm RH, Harper RW, Huff J, Koch S, Truex TJ. The structure of dihydrooctaaza-[14]-annulenes and their nickel(II) complexes Inorganic and Nuclear Chemistry Letters. 8: 393-398. DOI: 10.1016/0020-1650(72)80019-9  0.342
1972 EATON SS, EATON GR, HOLM RH. ChemInform Abstract: INTER- UND INTRAMOLEKULARE LIGANDENAUSTAUSCH-RK. VON RUTHENIUM(II)-CARBONYL-PORPHIN-KOMPLEXEN MIT STICKSTOFF-BASEN Chemischer Informationsdienst. 3: no-no. DOI: 10.1002/Chin.197240449  0.492
1972 PIGNOLET LH, LEWIS RA, HOLM RH. ChemInform Abstract: SYNTH. UND STEREOCHEMIE VON BIS-(DITHIOCARBAMATO)-MALEINSAEUREDINITRILDITHIOLATO-EISEN-KOMPLEXEN Chemischer Informationsdienst. 3: no-no. DOI: 10.1002/Chin.197211383  0.664
1972 EATON SS, EATON GR, HOLM RH. ChemInform Abstract: DIE LABILITAET VON RUTHENIUM(II)-CARBONYL-PORPHIN-KOMPLEXEN MIT STICKSTOFFBASEN Chemischer Informationsdienst. 3. DOI: 10.1002/Chin.197204404  0.492
1971 Holm RH, Pinolet LH, Lewis RA. Synthesis and stereochemical rearrangements of complexes containing the Fe-S6 core Journal of the American Chemical Society. 93: 360-371. DOI: 10.1021/Ja00731A011  0.42
1971 Holm RH, Truex TJ. Nontemplate synthesis of an unsaturated tetraaza[14]macrocycle and its metal(II) complexes Journal of the American Chemical Society. 93: 285-286. DOI: 10.1021/Ja00730A067  0.316
1971 Parks JE, Wagner BE, Holm RH. Three-dimensional macrocyclic encapsulation reactions. II. Synthesis and properties of nonoctahedral clathro chelates derived from tris(2-aldoximo-6-pyridyl)phosphine and boron trifluoride or tetrafluoroborate Inorganic Chemistry. 10: 2472-2478. DOI: 10.1021/Ic50105A021  0.335
1971 Eaton SS, Holm RH. Inversion and ligand-exchange kinetics of tetrahedral bis-chelate complexes of zinc(II) and cadmium(II) Inorganic Chemistry. 10: 1446-1452. DOI: 10.1021/Ic50101A026  0.34
1971 Holm RH, Hutchison JR, Gordon JG. Intramolecular rearrangement reactions of tris-chelate complexes. II. Kinetics and probable mechanism of the isomerization and racemization of the "fast" complexes tris(1-phenyl-5-methylhexane-2,4-dionato)aluminum(III) and -gallium(III) Inorganic Chemistry. 10: 1004-1017. DOI: 10.1021/Ic50099A031  0.356
1971 Holm RH, Eaton GR. Bridged binuclear bis(dithiolene) complexes of iron and cobalt Inorganic Chemistry. 10: 805-811. DOI: 10.1021/Ic50098A028  0.556
1971 Eaton SS, Eaton GR, Holm RH. Lability of ruthenium(II) carbonyl porphine complexes with nitrogen bases Journal of Organometallic Chemistry. 32. DOI: 10.1016/S0022-328X(00)85063-9  0.515
1971 Gordon J, O'Connor M, Holm R. Stereochemistry and rearrangement rates of some tris(β-diketonato)- and tris(β-thioketonato)metal(III) complexes Inorganica Chimica Acta. 5: 381-391. DOI: 10.1016/S0020-1693(00)95951-6  0.35
1971 EATON GR, HOLM RH. ChemInform Abstract: ZWEIKERNIGE BRUECKEN- BIS-DITHIOLEN-KOMPLEXE VON EISEN UND KOBALT Chemischer Informationsdienst. Organische Chemie. 2: no-no. DOI: 10.1002/chin.197125043  0.408
1971 PIGNOLET LH, LEWIS RA, HOLM RH. ChemInform Abstract: SYNTH. UND STEREOCHEMISCHE UMLAGERUNGEN VON FE-S6-KERNEN ENTHALTENDEN KOMPLEXEN Chemischer Informationsdienst. Organische Chemie. 2: no-no. DOI: 10.1002/Chin.197115058  0.703
1970 Gordon JG, Holm RH. Intramolecular rearrangement reactions of tris-chelate complexes. I. General theory and the kinetics and probable mechanism of the isomerization and racemization of tris(5-methylhexane-2,4-dionato)cobalt(III) Journal of the American Chemical Society. 92: 5319-5332. DOI: 10.1021/Ja00721A007  0.323
1970 Parks JE, Wagner BE, Holm RH. Three-dimensional macrocyclic encapsulation reactions. I. Synthesis of six-coordinate complexes with nonoctahedral stereochemistry Journal of the American Chemical Society. 92: 3500-3502. DOI: 10.1021/Ja00714A064  0.332
1970 Forbes CE, Holm RH. Dithiotropolonates. II. Synthesis and properties of dithiotropolone and its metal(II) complexes Journal of the American Chemical Society. 92: 2297-2303. DOI: 10.1021/Ja00711A016  0.312
1970 Pignolet LH, Horrocks WD, Holm RH. Thermodynamics and kinetics of the planar-tetrahedral interconversion of dihalobis(diarylmethylphosphine)nickel(II) complexes Journal of the American Chemical Society. 92: 1855-1863. DOI: 10.1021/Ja00710A011  0.694
1970 Pignolet LH, Holm RH. Complexes containing the Fe-S6 core with unusual magnetic, electrochemical, and stereochemical properties Journal of the American Chemical Society. 92: 1791-1793. DOI: 10.1021/Ja00709A080  0.716
1970 Gerlach DH, Holm RH. Solution stereochemistry of four-coordinate bis(chelate)metal(II) complexes. Further experimental results and a summary of stereochemical trends Inorganic Chemistry. 9: 588-594. DOI: 10.1021/Ic50085A030  0.318
1970 PIGNOLET LH, HORROCKS WDJ, HOLM RH. ChemInform Abstract: THERMODYNAMIK UND KINETIK DER UMWANDLUNG PLANAR-TETRAEDRISCH VON DIHALOGENO-BIS-(DIARYLMETHYLPHOSPHIN)-NICKEL(II)-KOMPLEXEN Chemischer Informationsdienst. Organische Chemie. 1: no-no. DOI: 10.1002/Chin.197027095  0.671
1970 PIGNOLET LH, HOLM RH. ChemInform Abstract: DEN FE-S6-KERN ENTHALTENDE KOMPLEXE MIT UNGEWOEHNLICHEN, MAGNETISCHEN, ELEKTROCHEMISCHEN UND STEREOCHEMISCHEN EIGENSCHAFTEN Chemischer Informationsdienst. Organische Chemie. 1: no-no. DOI: 10.1002/CHIN.197024341  0.686
1970 GANSOW OA, HOLM RH. ChemInform Abstract: H-NMR-UNTERSUCHUNG DER GLEICHGEWICHTE, STRUKTUR DES GELOESTEN UND DER TRANSAMINIERUNG IN WAESSRIGEN PYRIDOXAMIN-BRENZTRAUBENSAEURE-ZINK(II)- UND ALUMINIUM(III)-SYST. Chemischer Informationsdienst. Organische Chemie. 1: no-no. DOI: 10.1002/chin.197003077  0.505
1969 Gerlach DH, Holm RH. Relative stereochemical and electronic effects of oxygen and sulfur donor atoms in planar and tetrahedral complexes of nickel(II) Journal of the American Chemical Society. 91: 3457-3467. DOI: 10.1021/Ja01041A009  0.32
1969 Gansow OA, Holm RH. Equilibria and solute structures in the aqueous systems pyridoxal-alanine-zinc(II) and aluminum (III) as investigated by proton resonance Journal of the American Chemical Society. 91: 573-581. DOI: 10.1021/Ja01031A009  0.568
1969 Gerlach DH, Holm RH. Preparation and stereochemistry of bis-chelate chromium(II), manganese(II), iron(II), and cobalt(II) complexes of the types M-O4 and M-O2S2 Inorganic Chemistry. 8: 2292-2297. DOI: 10.1021/Ic50081A014  0.343
1969 Holm RH. Applications of isotropic shifts to the investigation of structures and structural equilibriums of metal complexes Accounts of Chemical Research. 2: 307-316. DOI: 10.1021/Ar50022A004  0.303
1969 Olcott R, Holm R. The crystal and molecular structure of the electron transfer complex butane-2, 3-dione-bis(2′-pyridyl-hydrazonato)nickel, [Ni(BDPH)-2H] Inorganica Chimica Acta. 3: 431-437. DOI: 10.1016/S0020-1693(00)92526-X  0.333
1968 Ernst RE, O'Connor MJ, Holm RH. Diastereoisomeric four-coordinate complexes. VI. Paramagnetic nickel(II) complexes with four asymmetric ligand centers Journal of the American Chemical Society. 90: 5735-5744. DOI: 10.1021/Ja01023A014  0.352
1968 Gansow OA, Holm RH. Detection and identification of intermediates and products of a nonenzymic transamination reaction by proton resonance Journal of the American Chemical Society. 90: 5629-5631. DOI: 10.1021/Ja01022A068  0.528
1968 Ernst RE, O'Connor MJ, Holm RH. Diastereoisomeric four-coordinate complexes. VII. Proton resonance detection of the nonequivalence of enantiomeric nickel(II) complexes in an optically active solvent Journal of the American Chemical Society. 90: 5305-5306. DOI: 10.1021/Ja01021A063  0.306
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