Hansjörg Grützmacher - Publications

Affiliations: 
DCHAB Eidgenössische Technische Hochschule Zürich, Zürich, ZH, Switzerland 

122 high-probability publications. We are testing a new system for linking publications to authors. You can help! If you notice any inaccuracies, please sign in and mark papers as correct or incorrect matches. If you identify any major omissions or other inaccuracies in the publication list, please let us know.

Year Citation  Score
2024 Himmelbauer D, Müller F, Schweinzer C, Casas F, Pribanic B, Le Corre G, Thöny D, Trincado M, Grützmacher H. Selective dehydrogenation of ammonia borane to polycondensated BN rings catalysed by ruthenium olefin complexes. Chemical Communications (Cambridge, England). PMID 38165285 DOI: 10.1039/d3cc05709g  0.347
2023 Abels AS, Eiler F, Le Corre G, Jurt P, Wörle M, Verel R, Benkő Z, Grützmacher H. The coordination chemistry of 2,4,6-oxy functionalised 1,3,5-triphosphinines. Dalton Transactions (Cambridge, England : 2003). 52: 3308-3314. PMID 36785885 DOI: 10.1039/d3dt00057e  0.339
2021 Jurt P, Abels AS, Gamboa-Carballo JJ, Fernández I, Le Corre G, Aebli M, Baker MG, Eiler F, Müller F, Wörle M, Verel R, Gauthier S, Trincado M, Gianetti TL, Grützmacher H. Reduction of Nitrogen Oxides by Hydrogen with Rh(I)-Pt(II) Olefin Complexes as Catalysts. Angewandte Chemie (International Ed. in English). PMID 34510678 DOI: 10.1002/anie.202109642  0.718
2020 Coburger P, Wolf R, Grützmacher H. Isomerism and Biradical Character of Tetrapnictide Dianions: A Computational Study. European Journal of Inorganic Chemistry. 2020: 3580-3586. PMID 33132751 DOI: 10.1002/Ejic.202000422  0.327
2020 Bloch J, Kradolfer S, L Gianetti T, Ostendorf D, Dey S, Mougel V, Grützmacher H. Synthesis and Characterization of Ion Pairs between Alkaline Metal Ions and Anionic Anti-Aromatic and Aromatic Hydrocarbons with π-Conjugated Central Seven- and Eight-Membered Rings. Molecules (Basel, Switzerland). 25. PMID 33076581 DOI: 10.3390/molecules25204742  0.304
2020 Li Z, Chen X, Liu LL, Liu S, Grützmacher H. A Room Temperature Stable Distonic Radical Cation. Angewandte Chemie (International Ed. in English). PMID 32914528 DOI: 10.1002/Anie.202011677  0.628
2020 Togni A, Bornemann D, Brüning F, Wettstein L, Küng S, Grützmacher H, Pitts CR, Guan L, Trapp N. Deoxygenative Fluorination of Phosphine Oxides: A General Route to Fluorinated Organophosphorus(V) Compounds and Beyond. Angewandte Chemie (International Ed. in English). PMID 32852879 DOI: 10.1002/Anie.202010943  0.336
2020 Suter R, Wagner M, Querci L, Conti R, Benkő Z, Grützmacher H. 1,3,4-Azadiphospholides as building blocks for scorpionate and bidentate ligands in multinuclear complexes. Dalton Transactions (Cambridge, England : 2003). PMID 32501468 DOI: 10.1039/D0Dt01864C  0.45
2020 Liang S, Hemberger P, Steglich M, Simonetti P, Levalois-Grützmacher J, Grützmacher H, Gaan S. The Underlying Chemistry to Formation of Phosphoryl Radicals from Organophosphorus Compounds - A Missing Puzzle Piece in the Flame Chemistry. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 32428377 DOI: 10.1002/Chem.202001388  0.312
2020 Cosola A, Conti R, Rana VK, Sangermano M, Chiappone A, Levalois-Grützmacher J, Grützmacher H. Synthesis of γ-cyclodextrin substituted bis(acyl)phosphane oxide derivative (BAPO-γ-CyD) serving as multiple photoinitiator and crosslinking agent. Chemical Communications (Cambridge, England). PMID 32236208 DOI: 10.1039/D0Cc01732A  0.334
2020 Pribanic B, Trincado M, Eiler F, Vogt M, Comas-Vives A, Grützmacher H. Hydrogenolysis of Polysilanes Catalyzed by Low Valent Nickel Complexes. Angewandte Chemie (International Ed. in English). PMID 32049402 DOI: 10.1002/Anie.201907525  0.348
2020 Li Z, Chen X, Liu LL, Scharnhölz MT, Grützmacher H. N-Heterocyclic Carbenes Stabilized Dicarbondiphosphides: Strong Neutral Four-Membered Heterocyclic 6π-electron Donors. Angewandte Chemie (International Ed. in English). PMID 31917503 DOI: 10.1002/Anie.201914015  0.616
2019 Jurt P, Salnikov OG, Gianetti TL, Chukanov NV, Baker MG, Le Corre G, Borger JE, Verel R, Gauthier S, Fuhr O, Kovtunov KV, Fedorov A, Fenske D, Koptyug IV, Grützmacher H. Low-valent homobimetallic Rh complexes: influence of ligands on the structure and the intramolecular reactivity of Rh-H intermediates. Chemical Science. 10: 7937-7945. PMID 31673319 DOI: 10.1039/C9Sc02683E  0.747
2019 Hou Y, Li Z, Li Y, Liu P, Su CY, Puschmann F, Grützmacher H. Making the unconventional μ-P bridging binding mode more conventional in phosphinine complexes. Chemical Science. 10: 3168-3180. PMID 30996898 DOI: 10.1039/C8Sc05281F  0.413
2019 Mei Y, Borger JE, Wu DJ, Grützmacher H. Salen supported Al-O-C[triple bond, length as m-dash]P and Ga-P[double bond, length as m-dash]C[double bond, length as m-dash]O complexes. Dalton Transactions (Cambridge, England : 2003). PMID 30860527 DOI: 10.1039/C9Dt00485H  0.403
2019 Yang X, Gianetti TL, Wörle MD, van Leest NP, de Bruin B, Grützmacher H. A low-valent dinuclear ruthenium diazadiene complex catalyzes the oxidation of dihydrogen and reversible hydrogenation of quinones. Chemical Science. 10: 1117-1125. PMID 30774909 DOI: 10.1039/C8Sc02864H  0.741
2018 Bispinghoff M, Benkő Z, Grützmacher H, Calvo FD, Caporali M, Peruzzini M. Ruthenium mediated halogenation of white phosphorus: synthesis and reactivity of the unprecedented PCl moiety. Dalton Transactions (Cambridge, England : 2003). PMID 30444502 DOI: 10.1039/c8dt01840e  0.362
2018 Meyer K, Hoerger CJ, Heinemann FW, Louyriac E, Rigo M, Maron L, Grützmacher H, Driess M. Cyaarside (CAs-) and 1,3-Diarsaallendiide (AsCAs2-) Ligands Coordinated to Uranium and Generated via Activation of the Arsaethynolate Ligand (OCAs-). Angewandte Chemie (International Ed. in English). PMID 30427562 DOI: 10.1002/Anie.201811332  0.313
2018 Sinha V, Trincado M, Grützmacher H, de Bruin B. DFT provides insight into the additive-free conversion of aqueous methanol to dihydrogen catalyzed by [Ru(tropdad)]: Importance of the (electronic) flexibility of the diazadiene moiety. Journal of the American Chemical Society. PMID 30215248 DOI: 10.1021/Jacs.8B09011  0.421
2018 Sinha V, Pribanic B, de Bruin B, Trincado M, Grützmacher H. Ligand- and Metal-Based Reactivity of a Neutral Ruthenium Diolefin Diazadiene Complex; The Innocent, the Guilty, and the Suspicious. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 29341297 DOI: 10.1002/Chem.201705957  0.343
2018 Sinha V, Pribanic B, de Bruin B, Trincado M, Grützmacher H. Front Cover: Ligand- and Metal-Based Reactivity of a Neutral Ruthenium Diolefin Diazadiene Complex: The Innocent, the Guilty and the Suspicious (Chem. Eur. J. 21/2018) Chemistry - a European Journal. 24: 5396-5396. DOI: 10.1002/Chem.201800438  0.396
2017 Gilliard RJ, Heift D, Benkő Z, Keiser JM, Rheingold AL, Grützmacher H, Protasiewicz JD. An isolable magnesium diphosphaethynolate complex. Dalton Transactions (Cambridge, England : 2003). PMID 29242885 DOI: 10.1039/C7Dt04539E  0.747
2017 Grützmacher H, Li Z, Hou Y, Li Y, Hinz A, Harmer J, Su CY, Bertrand G. L3C3P3: Tricarbontriphosphide Cage Radicals and Cations Stabilized by Cyclic (alkyl)(amino)carbenes. Angewandte Chemie (International Ed. in English). PMID 29106069 DOI: 10.1002/Anie.201710099  0.568
2017 Gilliard RJ, Suter R, Schrader E, Benkő Z, Rheingold AL, Grützmacher H, Protasiewicz JD. Synthesis of P2C2O2 and P2CO via NHC-mediated coupling of the phosphaethynolate anion. Chemical Communications (Cambridge, England). PMID 29095454 DOI: 10.1039/C7Cc07654A  0.769
2017 Slootweg C, Krachko T, Bispinghoff M, Tondreau A, Stein D, Baker M, Ehlers A, Grützmacher H. Facile Phenylphosphinidene Transfer Reactions from Carbene-Phosphinidene Zinc Complexes. Angewandte Chemie (International Ed. in English). PMID 28505382 DOI: 10.1002/Anie.201703672  0.709
2017 Driess M, Yao S, Großheim Y, Kastenko A, Ballestero-Martínez E, Schutte S, Bispinghoff M, Grützmacher H. Facile Access to NaOC≡As and Its Use as an Arsenic Source to Form Germylidenylarsinidene Complexes. Angewandte Chemie (International Ed. in English). PMID 28464389 DOI: 10.1002/Anie.201703731  0.37
2017 Trincado M, Sinha V, Rodriguez-Lugo RE, Pribanic B, de Bruin B, Grützmacher H. Homogeneously catalysed conversion of aqueous formaldehyde to H2 and carbonate. Nature Communications. 8: 14990. PMID 28452367 DOI: 10.1038/Ncomms14990  0.397
2017 Kieser JM, Gilliard RJ, Rheingold AL, Grützmacher H, Protasiewicz JD. Insertion of sodium phosphaethynolate, Na[OCP], into a zirconium-benzyne complex. Chemical Communications (Cambridge, England). PMID 28430281 DOI: 10.1039/C7Cc01482A  0.76
2017 Grant LN, Pinter B, Manor BC, Suter R, Grützmacher H, Mindiola DJ. A Planar Ti2P2 Core Assembled by Reductive Decarbonylation of -O-C≡P and P-P Radical Coupling. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 28297126 DOI: 10.1002/Chem.201701054  0.358
2017 Fischbach U, Trincado M, Grützmacher H. Oxidative formation of phosphinyl radicals from a trigonal pyramidal terminal phosphide Rh(i) complex, with an unusually long Rh-P bond. Dalton Transactions (Cambridge, England : 2003). PMID 28217796 DOI: 10.1039/C7Dt00070G  0.342
2017 Rodriguez Lugo RE, de Bruin B, Trincado M, Grützmacher H. Stable Aminyl Radical Coordinated to Cobalt. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 28164405 DOI: 10.1002/Chem.201605624  0.351
2017 Hoerger CJ, Heinemann FW, Louyriac E, Maron L, Grützmacher H, Meyer K. Formation of a Uranium-Bound η1-Cyaphide (CP–) Ligand via Activation and C–O Bond Cleavage of Phosphaethynolate (OCP–) Organometallics. 36: 4351-4354. DOI: 10.1021/Acs.Organomet.7B00590  0.415
2017 Rodríguez-Lugo RE, de Bruin B, Trincado M, Grützmacher H. Inside Back Cover: A Stable Aminyl Radical Coordinated to Cobalt (Chem. Eur. J. 28/2017) Chemistry - a European Journal. 23: 6937-6937. DOI: 10.1002/Chem.201701240  0.329
2016 Liu L, Ruiz DA, Dahcheh F, Bertrand G, Suter R, Tondreau AM, Grützmacher H. Isolation of Au-, Co-ηPCO and Cu-ηPCO complexes, conversion of an Ir-ηPCO complex into a dimetalladiphosphene, and an interaction-free PCO anion. Chemical Science. 7: 2335-2341. PMID 29997776 DOI: 10.1039/C5Sc04504E  0.763
2016 Gianetti TL, Rodríguez-Lugo RE, Harmer JR, Trincado M, Vogt M, Santiso-Quinones G, Grützmacher H. Zero-Valent Amino-Olefin Cobalt Complexes as Catalysts for Oxygen Atom Transfer Reactions from Nitrous Oxide. Angewandte Chemie (International Ed. in English). PMID 27860082 DOI: 10.1002/Anie.201609173  0.731
2016 Yang X, Gianetti TL, Harbort J, Wörle MD, Tan L, Su CY, Jurt P, Harmer JR, Grützmacher H. From 0 to II in One-Electron Steps: A Series of Ruthenium Complexes Supported by TropPPh2. Angewandte Chemie (International Ed. in English). PMID 27557780 DOI: 10.1002/Anie.201605687  0.733
2016 Prokopchuk DE, Lough AJ, Rodriguez-Lugo RE, Morris RH, Grützmacher H. Insights into metal-ligand hydrogen transfer: a square-planar ruthenate complex supported by a tetradentate amino-amido-diolefin ligand. Chemical Communications (Cambridge, England). PMID 27072981 DOI: 10.1039/C6Cc00041J  0.325
2016 Li Z, Chen X, Benkő Z, Liu L, Ruiz DA, Peltier JL, Bertrand G, Su CY, Grützmacher H. N-Heterocyclic Carbenes as Promotors for the Rearrangement of Phosphaketenes to Phosphaheteroallenes: A Case Study for OCP to OPC Constitutional Isomerism. Angewandte Chemie (International Ed. in English). PMID 27060924 DOI: 10.1002/Anie.201600903  0.694
2016 Gianetti TL, Annen SP, Santiso-Quinones G, Reiher M, Driess M, Grützmacher H. Nitrous Oxide as a Hydrogen Acceptor for the Dehydrogenative Coupling of Alcohols. Angewandte Chemie (International Ed. in English). 55: 1854-8. PMID 26693955 DOI: 10.1002/Anie.201509288  0.729
2016 Beil A, Gilliard RJ, Grützmacher H. From the parent phosphinidene-carbene adduct NHC = PH to cationic P4-rings and P2-cycloaddition products. Dalton Transactions (Cambridge, England : 2003). 45: 2044-52. PMID 26400646 DOI: 10.1039/C5Dt03014E  0.701
2016 Chen X, Li Z, Yanan F, Grützmacher H. Synthesis and Photoluminescence Properties of CuIComplexes with Chelating Phosphinito Phosphinine Ligands: CuIComplexes with Chelating Phosphinito Phosphinine Ligands European Journal of Inorganic Chemistry. 2016: 633-638. DOI: 10.1002/Ejic.201500933  0.368
2015 Lichtenberg C, Bloch J, Gianetti TL, Büttner T, Geier J, Grützmacher H. Diolefins with an ether/thioether functionality as ligands in the coordination sphere of Ni and Rh. Dalton Transactions (Cambridge, England : 2003). 44: 20056-66. PMID 26525295 DOI: 10.1039/C5Dt03279B  0.727
2015 Bispinghoff M, Tondreau AM, Grützmacher H, Faradji CA, Pringle PG. Carbene insertion into a P-H bond: parent phosphinidene-carbene adducts from PH3 and bis(phosphinidene)mercury complexes. Dalton Transactions (Cambridge, England : 2003). PMID 26122315 DOI: 10.1039/C5Dt01741F  0.682
2014 Chen X, Alidori S, Puschmann FF, Santiso-Quinones G, Benk? Z, Li Z, Becker G, Grützmacher HF, Grützmacher H. Sodium phosphaethynolate as a building block for heterocycles. Angewandte Chemie (International Ed. in English). 53: 1641-5. PMID 24453139 DOI: 10.1002/Anie.201308220  0.365
2014 Tondreau AM, Benko Z, Harmer JR, Grützmacher H. Sodium phosphaethynolate, Na(OCP), as a "p" transfer reagent for the synthesis of N-heterocyclic carbene supported P3 and PAsP radicals Chemical Science. 5: 1545-1554. DOI: 10.1039/C3Sc53140F  0.722
2013 Santiso-Quinones G, Rodriguez-Lugo R, Sacchetti V, Grützmacher H. Ru(II)-hydride-trop complexes: X-ray single-crystal determination and quantum-chemical calculations. Acta Crystallographica. Section C, Crystal Structure Communications. 69: 1421-6. PMID 24311484 DOI: 10.1107/S0108270113024505  0.402
2013 Rodríguez-Lugo RE, Trincado M, Vogt M, Tewes F, Santiso-Quinones G, Grützmacher H. A homogeneous transition metal complex for clean hydrogen production from methanol-water mixtures. Nature Chemistry. 5: 342-7. PMID 23511424 DOI: 10.1038/Nchem.1595  0.391
2013 Rosenthal AJ, Vogt M, Bruin Bd, Grützmacher H. A Diolefin Diamide Rhodium(I) Complex and Its One‐Electron Oxidation Resulting in a Two‐Center, Three‐Electron Rh–N Bond European Journal of Inorganic Chemistry. 2013: 5831-5835. DOI: 10.1002/Ejic.201301207  0.412
2012 Alidori S, Heift D, Santiso-Quinones G, Benk? Z, Grützmacher H, Caporali M, Gonsalvi L, Rossin A, Peruzzini M. Synthesis and characterization of terminal [Re(XCO)(CO)2(triphos)] (X=N, P): isocyanate versus phosphaethynolate complexes. Chemistry (Weinheim An Der Bergstrasse, Germany). 18: 14805-11. PMID 23019045 DOI: 10.1002/Chem.201202590  0.32
2011 Trincado M, Kühlein K, Grützmacher H. Metal-ligand cooperation in the catalytic dehydrogenative coupling (DHC) of polyalcohols to carboxylic acid derivatives. Chemistry (Weinheim An Der Bergstrasse, Germany). 17: 11905-13. PMID 21901769 DOI: 10.1002/Chem.201101084  0.351
2011 Shevchenko I, Tarasevich A, Turcheniuk K, Mikolenko R, Andrushko V, Rozhenko A, Schmutzler R, Grützmacher H, Röschenthaler G-. Compounds Featuring the Structural Fragment P-C-P Phosphorus Sulfur and Silicon and the Related Elements. 186: 621-625. DOI: 10.1080/10426507.2010.520285  0.35
2011 Vogt M, de Bruin B, Berke H, Trincado M, Grützmacher H. Amino olefin nickel(i) and nickel(0) complexes as dehydrogenation catalysts for amine boranes Chemical Science. 2: 723. DOI: 10.1039/C0Sc00483A  0.423
2009 Yao S, Xiong Y, Vogt M, Grützmacher H, Herwig C, Limberg C, Driess M. O-O bond activation in heterobimetallic peroxides: synthesis of the peroxide [LNi(mu,eta2:eta2-O2)K] and its conversion into a bis(mu-hydroxo) nickel zinc complex. Angewandte Chemie (International Ed. in English). 48: 8107-10. PMID 19768826 DOI: 10.1002/Anie.200903772  0.312
2009 Kirchhoff D, Grützmacher HF, Grützmacher H. Trends in the Periodic System: the mass spectrum of dimethylphenyl phosphane and a comparison of the gas phase reactivity of dimethylphenyl pnictogene radical cations C(6)H(5)E(CH(3))(2)(*+), (E = N, P, As)(dagger). European Journal of Mass Spectrometry (Chichester, England). 15: 131-44. PMID 19423899 DOI: 10.1255/Ejms.940  0.318
2009 Zweifel T, Naubron JV, Grützmacher H. Catalyzed dehydrogenative coupling of primary alcohols with water, methanol, or amines. Angewandte Chemie (International Ed. in English). 48: 559-63. PMID 19072802 DOI: 10.1002/Anie.200804757  0.349
2009 Stein D, Ott T, Grützmacher H. Phosphorus heterocycles from sodium dihydrogen phosphide: Simple synthesis and structure of 3,5-diphenyl-2,4-diazaphospholide Zeitschrift Fur Anorganische Und Allgemeine Chemie. 635: 682-686. DOI: 10.1002/Zaac.200900007  0.359
2009 Zweifel T, Scheschkewitz D, Ott T, Vogt M, Grützmacher H. Chiral [Bis(olefin)amine]rhodium(I) Complexes – Transfer Hydrogenation in Ethanol European Journal of Inorganic Chemistry. 2009: 5561-5576. DOI: 10.1002/Ejic.200900875  0.765
2007 Ehlers A, Cordaro JG, Stein D, Grützmacher H. Mechanisms of cyaphide (C[triple bond]P(-)) formation. Angewandte Chemie (International Ed. in English). 46: 7878-81. PMID 17768747 DOI: 10.1002/Anie.200702442  0.737
2007 Bruin Bd, Russcher JC, Grützmacher H. Spin density distribution in mononuclear Rh(0) complexes: A combined experimental and DFT study Journal of Organometallic Chemistry. 692: 3167-3173. DOI: 10.1016/J.Jorganchem.2007.01.041  0.388
2007 Donati N, Königsmann M, Stein D, Udino L, Grützmacher H. Iridium aminyl radical complexes as catalysts for the catalytic dehydrogenation of primary hydroxyl functions in natural products Comptes Rendus Chimie. 10: 721-730. DOI: 10.1016/J.Crci.2007.03.017  0.337
2007 Ruflin C, Fischbach U, Grützmacher H, Levalois-Grützmacher J. Tetrakis(trimethysilyl)hypophosphate P2O2(OTMS)4: Synthesis, reactivity and application as flame retardant Heteroatom Chemistry. 18: 721-731. DOI: 10.1002/Hc.20373  0.353
2007 Fischbach U, Rüegger H, Grützmacher H. Tris(dibenzo[a,d]cycloheptenyl)phosphane: A Bulky Monodentate or Tetrapodal Ligand European Journal of Inorganic Chemistry. 2007: 2654-2667. DOI: 10.1002/Ejic.200601008  0.421
2006 Cordaro JG, Stein D, Grützmacher H. A synthetic cycle for the ruthenium-promoted formation of 1H-phosphindoles from phosphaalkynes. Journal of the American Chemical Society. 128: 14962-71. PMID 17105307 DOI: 10.1021/ja0651198  0.737
2006 Cordaro JG, Stein D, Rüegger H, Grützmacher H. Making the true "CP" ligand. Angewandte Chemie (International Ed. in English). 45: 6159-62. PMID 16937421 DOI: 10.1002/anie.200602499  0.702
2006 Kirchhoff D, Grützmacher HF, Grützmacher H. Isomerization and fragmentation reactions of gaseous dimethyl phenylarsane radical cations and methyl phenylarsenium cations. A study by tandem mass spectrometry and density functional theory calculations. European Journal of Mass Spectrometry (Chichester, England). 12: 171-80. PMID 16819108 DOI: 10.1255/Ejms.802  0.361
2006 Letzel M, Kirchhoff D, Grützmacher HF, Stein D, Grützmacher H. Isomerization and fragmentation reactions of gaseous phenylarsane radical cations and phenylarsanyl cations. A study by tandem mass spectrometry and theoretical calculations. Dalton Transactions (Cambridge, England : 2003). 2008-16. PMID 16609772 DOI: 10.1039/B514312H  0.357
2006 Meyer C, Scherer M, Schönberg H, Rüegger H, Loss S, Gramlich V, Grützmacher H. Coordination chemistry of phosphanyl amino acids: solid state and solution structures of neutral and cationic rhodium complexes. Dalton Transactions (Cambridge, England : 2003). 137-48. PMID 16357969 DOI: 10.1039/b512653c  0.346
2006 Stein D, Dransfeld A, Flock M, Rüegger H, Grützmacher H. Lithium Oligophosphanediides in the Li/PhPCl2 System European Journal of Inorganic Chemistry. 2006: 4157-4167. DOI: 10.1002/Ejic.200600571  0.32
2006 Cordaro JG, Stein D, Rüegger H, Grützmacher H. Cover Picture: Making the True “CP” Ligand (Angew. Chem. Int. Ed. 37/2006) Angewandte Chemie International Edition. 45: 6063-6063. DOI: 10.1002/Anie.200690125  0.715
2006 Cordaro JG, Stein D, Rüegger H, Grützmacher H. Titelbild: Making the True “CP” Ligand (Angew. Chem. 37/2006) Angewandte Chemie. 118: 6209-6209. DOI: 10.1002/Ange.200690125  0.717
2005 Büttner T, Geier J, Frison G, Harmer J, Calle C, Schweiger A, Schönberg H, Grützmacher H. A stable aminyl radical metal complex. Science (New York, N.Y.). 307: 235-8. PMID 15653498 DOI: 10.1126/Science.1106070  0.596
2005 Läng F, Breher F, Stein D, GRüTZMACHER H. Chiral Olefins as Steering Ligands: Syntheses of C1-Symmetric Dibenzo[a,e]cyclooctenes (Rdbcot) Organometallics. 24: 2997-3007. DOI: 10.1021/Om050093Z  0.426
2005 Maire P, Breher F, Schönberg H, Grützmacher H. Chiral Rhodium(I) and Iridium(I) Amino−Olefin Complexes: pKa, N−H Bond Dissociation Energy, and Catalytic Transfer Hydrogenation Organometallics. 24: 3207-3218. DOI: 10.1021/Om0500927  0.322
2004 Büttner T, Breher F, Grützmacher H. Amine olefin rhodium(I) complexes: pKa and NH bond strength. Chemical Communications (Cambridge, England). 2820-1. PMID 15599423 DOI: 10.1039/B409981H  0.455
2004 Maire P, Deblon S, Breher F, Geier J, Böhler C, Rüegger H, Schönberg H, Grützmacher H. Olefins as steering ligands for homogeneously catalyzed hydrogenations. Chemistry (Weinheim An Der Bergstrasse, Germany). 10: 4198-205. PMID 15352102 DOI: 10.1002/chem.200400441  0.326
2004 Kirchhoff D, Grützmacher H, Grützmacher H. Unimolecuclar Fragmentation and Isomerization of Gaseous Arsanyl Cations Y—C6H4As+X (X=F, Cl, Br, I). The Role of Non-Classical Nido Structures European Journal of Mass Spectrometry. 10: 857-867. DOI: 10.1255/Ejms.702  0.312
2003 Geier J, Grützmacher H. Synthesis and structure of [Na11(OtBu)10(OH)]: 1H NMR shift of a hydroxide ion encapsulated in a 21-vertex alcoholate cage. Chemical Communications (Cambridge, England). 2942-3. PMID 14680252 DOI: 10.1039/B308105B  0.314
2003 Geier J, Frison G, Grützmacher H. Dibenzophosphasemibullvalene. Angewandte Chemie (International Ed. in English). 42: 3955-7. PMID 12949879 DOI: 10.1002/anie.200351388  0.499
2003 Breher F, Böhler C, Frison G, Harmer J, Liesum L, Schweiger A, Grützmacher H. Tropad: a new ligand for the synthesis of water-stable paramagnetic [16+1]-electron rhodium and iridium complexes. Chemistry (Weinheim An Der Bergstrasse, Germany). 9: 3859-66. PMID 12916110 DOI: 10.1002/Chem.200204700  0.583
2003 Laporte C, Frison G, Grützmacher H, Hillier AC, Sommer W, Nolan SP. Binding of specialty phosphines to metals: Synthesis, structure, and solution calorimetry of the phosphirane complex [PtMe2(iPrBABAR-Phos)2] Organometallics. 22: 2202-2208. DOI: 10.1021/Om020642Q  0.659
2002 Deblon S, Liesum L, Harmer J, Schönberg H, Schweiger A, Grützmacher H. High-resolution EPR spectroscopic investigations of a homologous set of d9-cobalt(0), d9-rhodium(0), and d9-iridium(0) complexes. Chemistry (Weinheim An Der Bergstrasse, Germany). 8: 601-11. PMID 11855708 DOI: 10.1002/1521-3765(20020201)8:3<601::Aid-Chem601>3.0.Co;2-C  0.328
2002 Shevchenko I, Andrushko V, Mikolenko R, Shakhnin D, Grützmacher H, Röschenthaler G-. Some Unusual Reactions in Organophosphorus Chemistry Phosphorus Sulfur and Silicon and the Related Elements. 177: 1413-1416. DOI: 10.1080/10426500212235  0.333
2002 Böhler C, Stein D, Donati N, Grützmacher H. Synthesis of a transient tropylidene substituted N-heterocyclic carbene (tropNHC): rearrangement and formation of its gold complex New Journal of Chemistry. 26: 1291-1295. DOI: 10.1039/B203670C  0.375
2002 Laporte C, Böhler C, Schönberg H, Grützmacher H. Strain in organometallics: synthesis of rhodium and iridium complexes with a novel rigid tetrachelating phosphine olefin ligand and their redox properties Journal of Organometallic Chemistry. 641: 227-234. DOI: 10.1016/S0022-328X(01)01362-6  0.348
2002 Frison G, Grützmacher H. Coordinated olefins, H2C=CHR, and phosphanes, PH2R: A theoretical study of the R substituent effect Journal of Organometalic Chemistry. 643: 285-291. DOI: 10.1016/S0022-328X(01)01276-1  0.63
2001 Rissler J, Hartmann M, Marchand CM, Grützmacher H, Frenking G. π‐Donation and Stabilizing Effects of Pnicogens in Carbenium and Silicenium Ions: A Theoretical Study of [C(XH2)3]+ and [Si(XH2)3]+ (X=N, P, As, Sb, Bi) Chemistry: a European Journal. 7: 2834-2841. PMID 11486960 DOI: 10.1002/1521-3765(20010702)7:13<2834::Aid-Chem2834>3.0.Co;2-E  0.324
2001 Deblon S, Rüegger H, Schönberg H, Loss S, Gramlich V, Grützmacher H. Highly distorted d8-rhodium(+I) and d10-rhodium(−I) complexes: synthesis, reactivity, and structures in solution and solid state New Journal of Chemistry. 25: 83-92. DOI: 10.1039/B002906H  0.448
2001 Böhler C, Avarvari N, Schönberg H, Wörle M, Rüegger H, Grützmacher H. Protonation and Hydrogenation Experiments with Iridium(0) and Iridium(−1) tropp Complexes: Formation of Hydrides Helvetica Chimica Acta. 84: 3127-3147. DOI: 10.1002/1522-2675(20011017)84:10<3127::Aid-Hlca3127>3.0.Co;2-5  0.425
2000 Liedtke J, Rüegger H, Loss S, Grützmacher H. BABAR-Phos Rhodium Complexes: Reversible Metal Insertion into a Three-Membered Ring and Catalytic Hydroborations Angewandte Chemie. 39: 2478-2481. PMID 10941108 DOI: 10.1002/1521-3773(20000717)39:14<2478::Aid-Anie2478>3.0.Co;2-G  0.359
2000 Grützmacher H, Fässler TF. Topographical Analyses of Homonuclear Multiple Bonds between Main Group Elements Chemistry: a European Journal. 6: 2317-2325. PMID 10939733 DOI: 10.1002/1521-3765(20000703)6:13<2317::Aid-Chem2317>3.0.Co;2-X  0.306
2000 Liedtke J, Loss S, Widauer C, Grützmacher H. Phosphiranes as Ligands for Platinum Catalysed Hydrosilylations Tetrahedron. 56: 143-156. DOI: 10.1016/S0040-4020(99)00783-8  0.429
1999 Liedtke J, Loss S, Alcaraz G, Gramlich V, Grützmacher H. Very Stable Phosphiranes. Angewandte Chemie (International Ed. in English). 38: 1623-1626. PMID 29710990 DOI: 10.1002/(Sici)1521-3773(19990601)38:11<1623::Aid-Anie1623>3.0.Co;2-K  0.414
1999 Loss S, Widauer C, Grützmacher H. Strong P=P π Bonds: The First Synthesis of a Stable Phosphanyl Phosphenium Ion Angewandte Chemie. 38: 3329-3331. PMID 10602186 DOI: 10.1002/(Sici)1521-3773(19991115)38:22<3329::Aid-Anie3329>3.0.Co;2-Q  0.32
1999 Dez I, Levalois-Mitjaville J, Grützmacher H, Gramlich V, Jaeger RD. Stereochemistry Of Some Bis-Spirocyclic Phosphazenes Phosphorus Research Bulletin. 10: 720-723. DOI: 10.3363/Prb1992.10.0_720  0.379
1999 Grützmacher H, Meyer C, Boulmaâz S, Schönberg H, Deblon S, Liedtke J, Loss S, Wörle M. Ligands Make the Catalyst: Synthesis of Novel Functionalized Phosphines Phosphorus Sulfur and Silicon and the Related Elements. 144: 465-468. DOI: 10.1080/10426509908546282  0.366
1999 Widauer C, Grützmacher H, Shevchenko I, Gramlich V. Insights into the Staudinger Reaction: Experimental and Theoretical Studies on the Stabilization of cis‐Phosphazides European Journal of Inorganic Chemistry. 1999: 1659-1664. DOI: 10.1002/(Sici)1099-0682(199910)1999:10<1659::Aid-Ejic1659>3.0.Co;2-I  0.314
1998 Schönberg H, Boulmaâz S, Wörle M, Liesum L, Schweiger A, Grützmacher H. A Monomeric d -Rhodium(0) Complex. Angewandte Chemie (International Ed. in English). 37: 1423-1426. PMID 29710907 DOI: 10.1002/(Sici)1521-3773(19980605)37:10<1423::Aid-Anie1423>3.0.Co;2-X  0.404
1998 Grützmacher H, Chen GS, Ohlmann D, Marchand CM, Glaser R. Seleno- and Tellurocarbenium Ions Phosphorus Sulfur and Silicon and the Related Elements. 136: 287-290. DOI: 10.1080/10426509808545952  0.367
1998 Boulmaâz S, Loss S, Schönberg H, Deblon S, Wörle M, Nesper R, Grützmacher H, Mlakar M. Synthesis of stable monomeric iridium(0) and iridium(–1) complexes Chemical Communications. 2623-2624. DOI: 10.1039/A807804A  0.39
1998 Vaugeois Y, Jaeger RD, Levalois-Mitjaville J, Mazzah A, Wörle M, Grützmacher H. Synthesis and structure of new eight-membered Si–O–λ5σ4–P heterocycles New Journal of Chemistry. 22: 783-785. DOI: 10.1039/A803283A  0.338
1998 Thomaier J, Boulmaâz S, Schönberg H, Rüegger H, Currao A, Grützmacher H, Hillebrecht H, Pritzkow H. Dibenzotropylidene phosphanes (TROPPs): synthesis and coinage metal complexes New Journal of Chemistry. 22: 947-958. DOI: 10.1039/A801003J  0.444
1998 Klinkhammer KW, Fässler TF, Grützmacher H. The Formation Of Heteroleptic Carbene Homologues By Ligand Exchange : Synthesis Of The First Plumbanediyl Dimer Angewandte Chemie. 37: 124-126. DOI: 10.1002/(Sici)1521-3773(19980202)37:1/2<124::Aid-Anie124>3.0.Co;2-C  0.376
1997 Marchand CM, Pidun U, Frenking G, Grützmacher H. Structure and Stability of Y-Conjugated Silylium Cations [Si(XH)3]+ (X = O, S, Se, and Te) Journal of the American Chemical Society. 119: 11078-11085. DOI: 10.1021/Ja972226G  0.31
1997 Frenking G, Fau S, Marchand CM, Grützmacher H. The π-Donor Ability of the Halogens in Cations and Neutral Molecules. A Theoretical Study of AX3+, AH2X+, YX3, and YH2X (A = C, Si, Ge, Sn, Pb; Y = B, Al, Ga, In, Tl; X = F, Cl, Br, I) Journal of the American Chemical Society. 119: 6648-6655. DOI: 10.1021/Ja970335P  0.353
1997 Thomaier J, Alcaraz G, Grützmacher H, Hillebrecht H, Marchand C, Heim U. Reactions of a carbosilylated methylenephosphonium ion with π-conjugated hydrocarbons Journal of Organometallic Chemistry. 535: 91-97. DOI: 10.1016/S0022-328X(96)06960-4  0.355
1997 Grützmacher H, Marchand CM. Heteroatom stabilized carbenium ions Coordination Chemistry Reviews. 163: 287-344. DOI: 10.1016/S0010-8545(97)00043-X  0.325
1996 Ohlmann D, Marchand CM, Schönberg H, Grützmacher H, Pritzkow H. Darstellung und Kristallstruktur der Kupfer(I)‐chalkogenolat‐2,2′‐Bipyridin‐Komplexe [CuS(2,4,6‐iPr3C6H2)]4(Bipy)2 und [CuSe(2,4,6‐iPr3C6H2)]2(Bipy)2 Zeitschrift FüR Anorganische Und Allgemeine Chemie. 622: 1349-1357. DOI: 10.1002/Zaac.19966220813  0.378
1996 Driess M, Grützmacher H. Main Group Element Analogues of Carbenes, Olefins, and Small Rings Angewandte Chemie International Edition in English. 35: 828-856. DOI: 10.1002/Anie.199608281  0.339
1993 Heim U, Pritzkow H, Schönberg H, Grützmacher H. Phosphorus lone pairs stabilization of carbocations: the synthesis and dynamics of unsymmetrical methylene phosphonium ions Journal of the Chemical Society, Chemical Communications. 673-674. DOI: 10.1039/C39930000673  0.314
1992 Steiner M, Grützmacher H, Zolnai L, Huttner G. Synthesis and structure of bridged twelve-membered silver–zinc–sulfur cyclic compound: a combination of hard and soft Lewis acidic and basic centres Journal of the Chemical Society, Chemical Communications. 689-690. DOI: 10.1039/C39920000689  0.404
1992 Lay U, Pritzkow H, Grützmacher H. A second crystal modification of bis[2,4,6,-tris(trifluoromethyl)phenyl]stannylene: a stannylene (stannanediyl) dimer with weak tin–tin interactions Journal of the Chemical Society, Chemical Communications. 260-262. DOI: 10.1039/C39920000260  0.311
1991 Fleischer U, Grützmacher H, Krüger U. 2-[Tris(dimethylamino)phosphonio]-1-phosphaethyne tetraphenylborate, a phosphonio-substituted phosphaalkyne Journal of the Chemical Society, Chemical Communications. 302-303. DOI: 10.1039/C39910000302  0.311
1991 Grützmacher H, Pritzkow H. Synthese und Struktur eines Azadistanniridins Angewandte Chemie. 103: 976-978. DOI: 10.1002/Ange.19911030812  0.307
1990 Grützmacher H. Spaltung der Ylid-Bindung in Phosphor-Yliden: Photolyse von thiophosphoranylsubstituierten (Triphenylphosphoranyliden)methanen / Cleavage of Ylidic Bonds in Phosphorus Ylides: Photolysis of Thiophosphoranyl-Substituted (Triphenylphosphoranylidene)methanes Zeitschrift FüR Naturforschung B. 45: 170-174. DOI: 10.1515/Znb-1990-0210  0.335
1990 Bertrand G, Igau A, Baceireco A, Grutzmacher H. Synthesis and Reactivity of the First Stable λ5-Phosphaacetylene Phosphorus Sulfur and Silicon and the Related Elements. 301-304. DOI: 10.1080/10426509008038965  0.586
1990 Grützmacher H, Pritzkow H, Stephan M. An example of cheletropic reactivity of a methylene phosphane Tetrahedron. 46: 2381-2388. DOI: 10.1016/S0040-4020(01)82019-6  0.315
1990 Granier M, Baceiredo A, Grützmacher H, Pritzkow H, Bertrand G. Nachweis einer Nitrilimin-Imidoylnitren-Umlagerung: Röntgenstrukturanalyse eines ungewöhnlichen Nitren-Komplexes Angewandte Chemie. 102: 671-672. DOI: 10.1002/Ange.19901020608  0.547
1988 Igau A, Grutzmacher H, Baceiredo A, Bertrand G. Analogous .alpha.,.alpha.'-bis-carbenoid, triply bonded species: synthesis of a stable .lambda.3-phosphino carbene-.lambda.5-phosphaacetylene Journal of the American Chemical Society. 110: 6463-6466. DOI: 10.1021/Ja00227A028  0.539
1987 Grützmacher H, Roesky HW, Noltemeyer M, Sheldrick GM. Substitutionsreaktionen am N-[1-Chlor-2,2,2-trifluor-1-(trifluormethyl)ethyl]-dimethyIformamidin / Substitution Reactions with N-[1-Chloro-2,2,2-trifluoro-1-(trifluoromethyl)ethyl]-dimethylformamidine Zeitschrift FüR Naturforschung B. 42: 1245-1248. DOI: 10.1515/Znb-1987-1006  0.497
1985 Jones PG, Roesky HW, Grützmacher H, Sheldrick GM. Oxidative Knüpfung einer Phosphor-Phosphor-Bindung unter Einwirkung von Ag(I)- bzw. Cu(II)-Ionen: Synthese und Struktur von [(C6H5)PH2Ag{μ-(C6H5PH)2}]2 (AsF6)2, einem sechsgliedrigen Silber-Phosphor-Ring / The Oxidative Formation of a Phosphorus-Phosphorus Bond in the Presence of Ag(I) and Cu(II) Ions: Synthesis and Structure of [(C6H5)PH2Ag{μ-(C6H5PH)2}]2 (AsF6)2, Containing a Six-Membered Silver-Phosphorus Ring Zeitschrift FüR Naturforschung B. 40: 590-593. DOI: 10.1515/Znb-1985-0506  0.436
1984 Jones PG, Gries T, Grützmacher H, Roesky HW, Schimkowiak J, Sheldrick GM. Silver-Catalyzed Formation of Crown Ethers; Synthesis and Structure of[Ag([12]crown-4)2][AsF6] Angewandte Chemie International Edition in English. 23: 376-376. DOI: 10.1002/Anie.198403761  0.407
1984 Jones PG, Gries T, Grutzmacher H, Roesky HW, Schimkowiak J, Sheldrick GM. Silber-katalysierte Bildung von Kronenethern: Synthese und Struktur von [Ag([12]Krone-4)2][AsF6] Angewandte Chemie. 96: 357-358. DOI: 10.1002/Ange.19840960514  0.349
Show low-probability matches.