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David Milstein, Ph.D. - Publications

Affiliations: 
Organic Chemistry Weizmann Institute of Science, Rehovot, Israel 
Area:
Organometallic chemistry, homogenous catalysis
Website:
https://en.wikipedia.org/wiki/David_Milstein
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375 high-probability publications. We are testing a new system for linking publications to authors. You can help! If you notice any inaccuracies, please sign in and mark papers as correct or incorrect matches. If you identify any major omissions or other inaccuracies in the publication list, please let us know.

Year Citation  Score
2024 Liang Y, Efremenko I, Diskin-Posner Y, Avram L, Milstein D. Calcium-Ligand Cooperation Promoted Activation of N2O, Amine, and H2 as well as Catalytic Hydrogenation of Imines, Quinoline, and Alkenes. Angewandte Chemie (International Ed. in English). e202401702. PMID 38533687 DOI: 10.1002/anie.202401702  0.393
2024 Thiyagarajan S, Diskin-Posner Y, Montag M, Milstein D. Manganese-catalyzed base-free addition of saturated nitriles to unsaturated nitriles by template catalysis. Chemical Science. 15: 2571-2577. PMID 38362414 DOI: 10.1039/d3sc04935c  0.746
2023 Luo J, Lu L, Montag M, Liang Y, Milstein D. Hydrogenative alkene perdeuteration aided by a transient cooperative ligand. Nature Chemistry. PMID 37667011 DOI: 10.1038/s41557-023-01313-y  0.739
2023 Liang Y, Luo J, Diskin-Posner Y, Milstein D. Designing New Magnesium Pincer Complexes for Catalytic Hydrogenation of Imines and -Heteroarenes: H and N-H Activation by Metal-Ligand Cooperation as Key Steps. Journal of the American Chemical Society. PMID 37068165 DOI: 10.1021/jacs.3c01091  0.409
2022 Tocqueville D, Crisanti F, Guerrero J, Nubret E, Robert M, Milstein D, von Wolff N. Electrification of a Milstein-type catalyst for alcohol reformation. Chemical Science. 13: 13220-13224. PMID 36425491 DOI: 10.1039/d2sc04533h  0.801
2022 Liang Y, Das UK, Luo J, Diskin-Posner Y, Avram L, Milstein D. Magnesium Pincer Complexes and Their Applications in Catalytic Semihydrogenation of Alkynes and Hydrogenation of Alkenes: Evidence for Metal-Ligand Cooperation. Journal of the American Chemical Society. PMID 36194894 DOI: 10.1021/jacs.2c08491  0.413
2022 Luo J, Liang Y, Montag M, Diskin-Posner Y, Avram L, Milstein D. Controlled Selectivity through Reversible Inhibition of the Catalyst: Stereodivergent Semihydrogenation of Alkynes. Journal of the American Chemical Society. 144: 13266-13275. PMID 35839274 DOI: 10.1021/jacs.2c04233  0.752
2022 Liang Y, Luo J, Milstein D. Facile synthesis of amides acceptorless dehydrogenative coupling of aryl epoxides and amines. Chemical Science. 13: 5913-5919. PMID 35685791 DOI: 10.1039/d2sc01959k  0.393
2022 Luo J, Zhou QQ, Montag M, Ben-David Y, Milstein D. Acceptorless dehydrogenative synthesis of primary amides from alcohols and ammonia. Chemical Science. 13: 3894-3901. PMID 35432908 DOI: 10.1039/d1sc07102e  0.735
2022 Kar S, Luo J, Rauch M, Diskin-Posner Y, Ben-David Y, Milstein D. Dehydrogenative ester synthesis from enol ethers and water with a ruthenium complex catalyzing two reactions in synergy. Green Chemistry : An International Journal and Green Chemistry Resource : Gc. 24: 1481-1487. PMID 35308195 DOI: 10.1039/d1gc04574a  0.314
2022 Kar S, Milstein D. Sustainable catalysis with fluxional acridine-based PNP pincer complexes. Chemical Communications (Cambridge, England). 58: 3731-3746. PMID 35234797 DOI: 10.1039/d2cc00247g  0.432
2021 Kumar A, Daw P, Milstein D. Homogeneous Catalysis for Sustainable Energy: Hydrogen and Methanol Economies, Fuels from Biomass, and Related Topics. Chemical Reviews. PMID 34727501 DOI: 10.1021/acs.chemrev.1c00412  0.736
2021 Luo J, Kar S, Rauch M, Montag M, Ben-David Y, Milstein D. Efficient Base-Free Aqueous Reforming of Methanol Homogeneously Catalyzed by Ruthenium Exhibiting a Remarkable Acceleration by Added Catalytic Thiol. Journal of the American Chemical Society. 143: 17284-17291. PMID 34617436 DOI: 10.1021/jacs.1c09007  0.761
2021 Zhou QQ, Zou YQ, Kar S, Diskin-Posner Y, Ben-David Y, Milstein D. Manganese-Pincer-Catalyzed Nitrile Hydration, α-Deuteration, and α-Deuterated Amide Formation via Metal Ligand Cooperation. Acs Catalysis. 11: 10239-10245. PMID 34476112 DOI: 10.1021/acscatal.1c01748  0.754
2021 Kar S, Xie Y, Zhou QQ, Diskin-Posner Y, Ben-David Y, Milstein D. Near-Ambient-Temperature Dehydrogenative Synthesis of the Amide Bond: Mechanistic Insight and Applications. Acs Catalysis. 11: 7383-7393. PMID 34168903 DOI: 10.1021/acscatal.1c00728  0.345
2021 Rauch M, Luo J, Avram L, Ben-David Y, Milstein D. Mechanistic Investigations of Ruthenium Catalyzed Dehydrogenative Thioester Synthesis and Thioester Hydrogenation. Acs Catalysis. 11: 2795-2807. PMID 33763290 DOI: 10.1021/acscatal.1c00418  0.403
2020 Zou YQ, Zhou QQ, Diskin-Posner Y, Ben-David Y, Milstein D. Synthesis of oxalamides by acceptorless dehydrogenative coupling of ethylene glycol and amines and the reverse hydrogenation catalyzed by ruthenium. Chemical Science. 11: 7188-7193. PMID 34123004 DOI: 10.1039/d0sc02065f  0.78
2020 Zhou QQ, Zou YQ, Ben-David Y, Milstein D. A Reversible Liquid-to-Liquid Organic Hydrogen Carrier System Based on Ethylene Glycol and Ethanol. Chemistry (Weinheim An Der Bergstrasse, Germany). 26: 15487-15490. PMID 33459426 DOI: 10.1002/Chem.202002749  0.742
2020 Zou YQ, von Wolff N, Rauch M, Feller M, Zhou QQ, Anaby A, Diskin-Posner Y, Shimon L, Avram L, Ben-David Y, Milstein D. Homogeneous Reforming of Aqueous Ethylene Glycol to Glycolic Acid and Pure Hydrogen Catalyzed by Pincer-Ruthenium Complexes Capable of Metal-Ligand Cooperation. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 33369774 DOI: 10.1002/chem.202005450  0.815
2020 Luo J, Rauch M, Avram L, Ben-David Y, Milstein D. Catalytic Hydrogenation of Thioesters, Thiocarbamates, and Thioamides. Journal of the American Chemical Society. PMID 33332968 DOI: 10.1021/jacs.0c10884  0.343
2020 Tang S, Rauch M, Montag M, Diskin-Posner Y, Ben-David Y, Milstein D. Catalytic Oxidative Deamination by Water with H Liberation. Journal of the American Chemical Society. PMID 33237749 DOI: 10.1021/jacs.0c10826  0.71
2020 Rauch M, Kar S, Kumar A, Avram L, Shimon LJW, Milstein D. Metal-Ligand Cooperation Facilitates Bond Activation and Catalytic Hydrogenation with Zinc Pincer Complexes. Journal of the American Chemical Society. PMID 32786799 DOI: 10.1021/Jacs.0C05500  0.484
2020 Kumar A, von Wolff N, Rauch M, Zou YQ, Shmul G, Ben-David Y, Leitus G, Avram L, Milstein D. Hydrogenative Depolymerization of Nylons. Journal of the American Chemical Society. PMID 32706584 DOI: 10.1021/Jacs.0C05675  0.81
2020 Kar S, Rauch M, Kumar A, Leitus G, Ben-David Y, Milstein D. Selective Room-Temperature Hydrogenation of Amides to Amines and Alcohols Catalyzed by a Ruthenium Pincer Complex and Mechanistic Insight. Acs Catalysis. 10: 5511-5515. PMID 32455053 DOI: 10.1021/Acscatal.0C01406  0.499
2020 Gallego CM, Gaviglio C, Ben-David Y, Milstein D, Doctorovich F, Pellegrino J. Synthesis, structure and reactivity of NO, NO˙ and NO pincer PCN-Rh complexes. Dalton Transactions (Cambridge, England : 2003). 49: 7093-7108. PMID 32406454 DOI: 10.1039/D0Dt00962H  0.504
2020 Tang S, Ben-David Y, Milstein D. Oxidation of Alkenes by Water with H Liberation. Journal of the American Chemical Society. PMID 32182050 DOI: 10.1021/Jacs.0C01592  0.318
2020 Janes T, Diskin-Posner Y, Milstein D. Synthesis and Reactivity of Cationic Boron Complexes Distorted by Pyridine-based Pincer Ligands: Isolation of a Photochemical Hofmann-Martius-type Intermediate. Angewandte Chemie (International Ed. in English). PMID 31967728 DOI: 10.1002/Anie.202000406  0.483
2020 Zou Y, Zhou Q, Diskin-Posner Y, Ben-David Y, Milstein D. Synthesis of oxalamides by acceptorless dehydrogenative coupling of ethylene glycol and amines and the reverse hydrogenation catalyzed by ruthenium Chemical Science. 11: 7188-7193. DOI: 10.1039/D0Sc02065F  0.478
2020 Das UK, Janes T, Kumar A, Milstein D. Manganese catalyzed selective hydrogenation of cyclic imides to diols and amines Green Chemistry. 22: 3079-3082. DOI: 10.1039/D0Gc00570C  0.492
2020 Daw P, Kumar A, Oren D, Espinosa-Jalapa NA, Srimani D, Diskin-Posner Y, Leitus G, Shimon LJW, Carmieli R, Ben-David Y, Milstein D. Redox Noninnocent Nature of Acridine-Based Pincer Complexes of 3d Metals and C–C Bond Formation Organometallics. 39: 279-285. DOI: 10.1021/Acs.Organomet.9B00607  0.836
2019 Tang S, Milstein D. Template catalysis by manganese pincer complexes: oxa- and aza-Michael additions to unsaturated nitriles. Chemical Science. 10: 8990-8994. PMID 31762979 DOI: 10.1039/C9Sc03269J  0.556
2019 Bruffaerts J, von Wolff N, Diskin-Posner Y, Ben-David Y, Milstein D. Formamides as Isocyanate Surrogates: A Mechanistically-Driven Approach to the Development of Atom-Efficient, Selective Catalytic Syntheses of Ureas, Carbamates and Heterocycles. Journal of the American Chemical Society. PMID 31532664 DOI: 10.1021/Jacs.9B08942  0.808
2019 Kumar A, Daw P, Espinosa-Jalapa NA, Leitus G, Shimon LJW, Ben-David Y, Milstein D. CO activation by manganese pincer complexes through different modes of metal-ligand cooperation. Dalton Transactions (Cambridge, England : 2003). PMID 31517365 DOI: 10.1039/C9Dt03088C  0.745
2019 Zou YQ, von Wolff N, Anaby A, Xie Y, Milstein D. Ethylene Glycol as an Efficient and Reversible Liquid Organic Hydrogen Carrier. Nature Catalysis. 2: 415-422. PMID 31406959 DOI: 10.1038/s41929-019-0265-z  0.786
2019 Das UK, Kumar A, Ben-David Y, Iron M, Milstein D. Manganese Catalyzed Hydrogenation of Carbamates and Urea Derivatives. Journal of the American Chemical Society. PMID 31365248 DOI: 10.1021/Jacs.9B05591  0.498
2019 Daw P, Kumar A, Espinosa-Jalapa NA, Ben-David Y, Milstein D. Direct Synthesis of Amides by Acceptorless Dehydrogenative Coupling of Benzyl Alcohols and Ammonia Catalyzed by a Manganese Pincer Complex: Unexpected Crucial Role of Base. Journal of the American Chemical Society. PMID 31307194 DOI: 10.1021/Jacs.9B05261  0.781
2019 Tang S, von Wolff N, Diskin-Posner Y, Leitus G, Ben-David Y, Milstein D. Pyridine-based PCP-Ruthenium Complexes: Unusual Structures and Metal-Ligand Cooperation. Journal of the American Chemical Society. PMID 31017407 DOI: 10.1021/Jacs.9B02669  0.839
2019 Xie Y, Hu P, Ben-David Y, Milstein D. A Reversible Liquid Organic Hydrogen Carrier System Based on Methanol-Ethylenediamine and Ethylene Urea. Angewandte Chemie (International Ed. in English). PMID 30791196 DOI: 10.1002/Anie.201901695  0.368
2019 Luque Urrutia JA, Solà M, Milstein D, Poater A. Mechanism of the Manganese-Pincer Catalyzed Acceptorless Dehydrogenative Coupling of Nitriles and Alcohols. Journal of the American Chemical Society. PMID 30632367 DOI: 10.1021/Jacs.8B11308  0.445
2019 Milstein D, Kumar A, Janes T, Chakraborty S, Daw P, Carmieli R, Diskin-Posner Y. C ̶ C Bond Formation of Benzyl Alcohols and Alkynes using Catalytic Amount of KOtBu: Unusual Regioselectivity via a Radical Mechanism. Angewandte Chemie (International Ed. in English). PMID 30605258 DOI: 10.1002/Anie.201812687  0.818
2019 Das UK, Ben-David Y, Leitus G, Diskin-Posner Y, Milstein D. Dehydrogenative Cross-Coupling of Primary Alcohols To Form Cross-Esters Catalyzed by a Manganese Pincer Complex Acs Catalysis. 9: 479-484. DOI: 10.1021/Acscatal.8B04585  0.518
2019 Masdemont J, Luque-Urrutia JA, Gimferrer M, Milstein D, Poater A. Mechanism of Coupling of Alcohols and Amines To Generate Aldimines and H2 by a Pincer Manganese Catalyst Acs Catalysis. 9: 1662-1669. DOI: 10.1021/Acscatal.8B04175  0.439
2018 Zou YQ, Chakraborty S, Nerush A, Oren D, Diskin-Posner Y, Ben-David Y, Milstein D. Highly Selective, Efficient Deoxygenative Hydrogenation of Amides Catalyzed by a Manganese Pincer Complex via Metal-Ligand Cooperation. Acs Catalysis. 8: 8014-8019. PMID 31080688 DOI: 10.1021/Acscatal.8B02902  0.849
2018 Daw P, Kumar A, Espinosa-Jalapa NA, Diskin-Posner Y, Ben-David Y, Milstein D. Synthesis of Pyrazines and Quinoxalines via Acceptorless Dehydrogenative Coupling Routes Catalyzed by Manganese Pincer Complexes. Acs Catalysis. 8: 7734-7741. PMID 31080687 DOI: 10.1021/Acscatal.8B02208  0.795
2018 Oren D, Diskin-Posner Y, Avram L, Feller M, Milstein D. Metal-Ligand Cooperation as Key in Formation of Dearomatized Ni-H Pincer Complexes and in Their Reactivity toward CO and CO. Organometallics. 37: 2217-2221. PMID 31080304 DOI: 10.1021/Acs.Organomet.8B00160  0.506
2018 Chakraborty S, Daw P, Ben David Y, Milstein D. Manganese-Catalyzed α-Alkylation of Ketones, Esters, and Amides Using Alcohols. Acs Catalysis. 8: 10300-10305. PMID 31007965 DOI: 10.1021/Acscatal.8B03720  0.817
2018 Daw P, Ben-David Y, Milstein D. Acceptorless Dehydrogenative Coupling Using Ammonia: Direct Synthesis of N-Heteroaromatics from Diols Catalyzed by Ruthenium. Journal of the American Chemical Society. PMID 30205675 DOI: 10.1021/Jacs.8B08385  0.768
2018 Milstein D, Das UK, Chakraborty S, Diskin-Posner Y. Direct Conversion of Alcohols to Alkenes by Dehydrogenative Coupling with Hydrazine/Hydrazone Catalyzed by Manganese. Angewandte Chemie (International Ed. in English). PMID 30079623 DOI: 10.1002/Anie.201807881  0.711
2018 Kumar A, Janes T, Espinosa-Jalapa NA, Milstein D. Manganese Catalysed Hydrogenation of Organic Carbonates to Methanol and Alcohols. Angewandte Chemie (International Ed. in English). PMID 30035855 DOI: 10.1002/Anie.201806289  0.45
2018 Zeng R, Feller M, Diskin-Posner Y, Shimon LJW, Ben-David Y, Milstein D. CO Oxidation by N2O Homogeneously Catalyzed by Ruthenium Hydride Pincer Complexes Indicating a New Mechanism. Journal of the American Chemical Society. PMID 29812933 DOI: 10.1021/Jacs.8B03927  0.46
2018 Kumar A, Janes T, Espinosa-Jalapa NA, Milstein D. Selective Hydrogenation of Cyclic Imides to Diols and Amines and its Application in the Development of a Liquid Organic Hydrogen Carrier. Journal of the American Chemical Society. PMID 29812921 DOI: 10.1021/Jacs.8B04581  0.374
2018 Kumar A, Feller M, Ben-David Y, Diskin-Posner Y, Milstein D. Formal oxidative addition of a C-H bond by a 16e iridium(i) complex involves metal-ligand cooperation. Chemical Communications (Cambridge, England). PMID 29744491 DOI: 10.1039/C8Cc01885E  0.483
2018 Milstein D, Das UK, Ben-David Y, Diskin-Posner Y. N-Substituted Hydrazones by Manganese Catalyzed Coupling of Alcohols with Hydrazine; 'Borrowing Hydrogen' and Acceptorless Dehydrogenation in One System. Angewandte Chemie (International Ed. in English). PMID 29316100 DOI: 10.1002/Anie.201712593  0.466
2018 Feller M, Ben-Ari E, Diskin-Posner Y, Milstein D. CO2 activation by metal−ligand-cooperation mediated by iridium pincer complexes Journal of Coordination Chemistry. 71: 1679-1689. DOI: 10.1080/00958972.2018.1475662  0.652
2018 Xie Y, Hu P, Bendikov T, Milstein D. Heterogeneously catalyzed selective hydrogenation of amides to alcohols and amines Catalysis Science & Technology. 8: 2784-2788. DOI: 10.1039/C8Cy00112J  0.445
2018 Mukherjee A, Milstein D. Homogeneous Catalysis by Cobalt and Manganese Pincer Complexes Acs Catalysis. 8: 11435-11469. DOI: 10.1021/Acscatal.8B02869  0.713
2017 Gaviglio C, Pellegrino J, Milstein D, Doctorovich F. NO˙ disproportionation by a {RhNO}9 pincer-type complex. Dalton Transactions (Cambridge, England : 2003). 46: 16878-16884. PMID 29188260 DOI: 10.1039/C7Dt03944A  0.459
2017 Das UK, Shimon LJW, Milstein D. Imidazole synthesis by transition metal free, base-mediated deaminative coupling of benzylamines and nitriles. Chemical Communications (Cambridge, England). PMID 29168852 DOI: 10.1039/C7Cc08322J  0.349
2017 Milstein D, Kumar A, Espinosa-Jalapa NA, Leitus G, Diskin-Posner Y, Avram L. Direct Synthesis of Amides by Dehydrogenative Coupling of Amines with Alcohols or Esters Catalysed by a Manganese Pincer Complex. Angewandte Chemie (International Ed. in English). PMID 28967992 DOI: 10.1002/Anie.201709180  0.495
2017 Espinosa-Jalapa NA, Kumar A, Leitus G, Diskin-Posner Y, Milstein D. Synthesis of Cyclic Imides by Acceptorless Dehydrogenative Coupling of Diols and Amines Catalyzed by a Manganese Pincer Complex. Journal of the American Chemical Society. PMID 28795820 DOI: 10.1021/Jacs.7B08341  0.496
2017 Chakraborty S, Das UK, Ben-David Y, Milstein D. Manganese Catalyzed α-Olefination of Nitriles by Primary Alcohols. Journal of the American Chemical Society. PMID 28792761 DOI: 10.1021/Jacs.7B06993  0.679
2017 Zeng R, Feller M, Ben-David Y, Milstein D. Hydrogenation and Hydrosilylation of Nitrous Oxide Homogeneously Catalyzed by a Metal Complex. Journal of the American Chemical Society. PMID 28402635 DOI: 10.1021/Jacs.7B02124  0.456
2017 Chakraborty S, Gellrich U, Diskin-Posner Y, Leitus G, Avram L, Milstein D. Manganese-Catalyzed N-Formylation of Amines by Methanol Liberating H2 : A Catalytic and Mechanistic Study. Angewandte Chemie (International Ed. in English). PMID 28319299 DOI: 10.1002/Anie.201700681  0.713
2017 Dauth A, Gellrich U, Diskin-Posner Y, Ben-David Y, Milstein D. The ferraquinone - ferrahydroquinone couple: combining quinonic and metal-based reactivity. Journal of the American Chemical Society. PMID 28141925 DOI: 10.1021/Jacs.6B13050  0.413
2017 Chakraborty S, Leitus G, Milstein D. Iron-Catalyzed Mild and Selective Hydrogenative Cross-Coupling of Nitriles and Amines to Form Secondary Aldimines. Angewandte Chemie (International Ed. in English). PMID 28078777 DOI: 10.1002/Anie.201608537  0.683
2017 Daw P, Ben-David Y, Milstein D. Direct Synthesis of Benzimidazoles by Dehydrogenative Coupling of Aromatic Diamines and Alcohols Catalyzed by Cobalt Acs Catalysis. 7: 7456-7460. DOI: 10.1021/Acscatal.7B02777  0.791
2017 Bauer JO, Chakraborty S, Milstein D. Manganese-Catalyzed Direct Deoxygenation of Primary Alcohols Acs Catalysis. 7: 4462-4466. DOI: 10.1021/Acscatal.7B01729  0.68
2017 Chakraborty S, Milstein D. Selective Hydrogenation of Nitriles to Secondary Imines Catalyzed by an Iron Pincer Complex Acs Catalysis. 7: 3968-3972. DOI: 10.1021/Acscatal.7B00906  0.693
2017 Daw P, Chakraborty S, Leitus G, Diskin-Posner Y, Ben-David Y, Milstein D. SelectiveN-Formylation of Amines with H2and CO2Catalyzed by Cobalt Pincer Complexes Acs Catalysis. 7: 2500-2504. DOI: 10.1021/Acscatal.7B00116  0.821
2017 Goldberg K, Milstein D. Bond Activation by Metal Complexes: Special Issue in Honor of the 2017 Wolf Prize Laureate in Chemistry, Professor Robert G. Bergman Israel Journal of Chemistry. 57: 915-915. DOI: 10.1002/Ijch.201700125  0.404
2017 Mukherjee A, Srimani D, Ben-David Y, Milstein D. Low-Pressure Hydrogenation of Nitriles to Primary Amines Catalyzed by Ruthenium Pincer Complexes. Scope and mechanism Chemcatchem. 9: 559-563. DOI: 10.1002/Cctc.201601416  0.809
2016 Bauer JO, Leitus G, Ben-David Y, Milstein D. Direct Synthesis of Symmetrical Azines from Alcohols and Hydrazine Catalyzed by a Ruthenium Pincer Complex: Effect of Hydrogen Bonding. Acs Catalysis. 6: 8415-8419. PMID 27990319 DOI: 10.1021/Acscatal.6B02946  0.507
2016 Espinosa-Jalapa NA, Nerush A, Shimon L, Leitus G, Avram L, Ben-David Y, Milstein D. Manganese-Catalyzed Hydrogenation of Esters to Alcohols. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 27796060 DOI: 10.1002/Chem.201604991  0.526
2016 Daw P, Chakraborty S, Garg JA, Ben-David Y, Milstein D. Direct Synthesis of Pyrroles by Dehydrogenative Coupling of Diols and Amines Catalyzed by Cobalt Pincer Complexes. Angewandte Chemie (International Ed. in English). PMID 27730747 DOI: 10.1002/Anie.201607742  0.844
2016 Gellrich U, Diskin-Posner Y, Shimon LJ, Milstein D. Reversible aromaticity transfer in a bora-cycle: Boron-ligand cooperation. Journal of the American Chemical Society. PMID 27629234 DOI: 10.1021/Jacs.6B07454  0.47
2016 Anaby A, Feller M, Ben-David Y, Leitus G, Diskin-Posner Y, Shimon LJ, Milstein D. Bottom-Up Construction of a CO2-Based Cycle for the Photocarbonylation of Benzene Promoted by a Rhodium(I) Pincer Complex. Journal of the American Chemical Society. PMID 27400288 DOI: 10.1021/Jacs.6B05128  0.43
2016 Xie Y, Ben-David Y, Shimon LJ, Milstein D. Highly Efficient Process for Production of Biofuel from Ethanol Catalyzed by Ruthenium-Pincer Complexes. Journal of the American Chemical Society. PMID 27399841 DOI: 10.1021/Jacs.6B05433  0.379
2016 Nerush A, Vogt M, Gellrich U, Leitus G, Ben-David Y, Milstein D. Template Catalysis by Metal-Ligand Cooperation. C-C Bond Formation via Conjugate Addition of Non-activated Nitriles Under Mild, Base-free Conditions Catalyzed by a Manganese Pincer Complex. Journal of the American Chemical Society. PMID 27164437 DOI: 10.1021/Jacs.5B13208  0.515
2016 Hu P, Ben-David Y, Milstein D. General Synthesis of Amino Acid Salts from Amino Alcohols and Basic Water Liberating H2. Journal of the American Chemical Society. PMID 27139983 DOI: 10.1021/Jacs.6B03488  0.335
2016 Feller M, Gellrich U, Anaby A, Diskin-Posner Y, Milstein D. Reductive Cleavage of CO2 by Metal-Ligand-Cooperation Mediated by an Iridium Pincer Complex. Journal of the American Chemical Society. PMID 27124097 DOI: 10.1021/Jacs.6B00202  0.441
2016 Rivada-Wheelaghan O, Chakraborty S, Shimon LJ, Ben-David Y, Milstein D. Z-Selective (Cross-)Dimerization of Terminal Alkynes Catalyzed by an Iron Complex. Angewandte Chemie (International Ed. in English). PMID 27100379 DOI: 10.1002/Anie.201601382  0.657
2016 Garg JA, Chakraborty S, Ben-David Y, Milstein D. Unprecedented iron-catalyzed selective hydrogenation of activated amides to amines and alcohols. Chemical Communications (Cambridge, England). PMID 27001895 DOI: 10.1039/C6Cc01505K  0.711
2016 Mukherjee A, Nerush A, Leitus G, Shimon LJ, Ben-David Y, Espinosa-Jalapa NA, Milstein D. Unprecedented Manganese Catalyzed Environmentally Benign De-hydrogenative Coupling of Alcohols and Amines to Form Imines and H2: A Catalytic and Mechanistic Study. Journal of the American Chemical Society. PMID 26924231 DOI: 10.1021/Jacs.5B13519  0.682
2016 Butschke B, Feller M, Diskin-Posner Y, Milstein D. Ketone hydrogenation catalyzed by a new iron(II)–PNN complex Catalysis Science & Technology. 6: 4428-4437. DOI: 10.1039/C5Cy02036K  0.509
2015 Chakraborty S, Leitus G, Milstein D. Selective hydrogenation of nitriles to primary amines catalyzed by a novel iron complex. Chemical Communications (Cambridge, England). PMID 26667062 DOI: 10.1039/C5Cc08204H  0.688
2015 Khusnutdinova JR, Milstein D. Metal-Ligand Cooperation. Angewandte Chemie (International Ed. in English). 54: 12236-73. PMID 26436516 DOI: 10.1002/Anie.201503873  0.719
2015 Hu P, Ben-David Y, Milstein D. Rechargeable Hydrogen Storage System Based on the Dehydrogenative Coupling of Ethylenediamine with Ethanol. Angewandte Chemie (International Ed. in English). PMID 26211515 DOI: 10.1002/Anie.201505704  0.368
2015 Mukherjee A, Srimani D, Chakraborty S, Ben-David Y, Milstein D. Selective Hydrogenation of Nitriles to Primary Amines Catalyzed by a Cobalt Pincer Complex. Journal of the American Chemical Society. PMID 26131688 DOI: 10.1021/Jacs.5B04879  0.831
2015 Zell T, Milstein D. Hydrogenation and dehydrogenation iron pincer catalysts capable of metal-ligand cooperation by aromatization/dearomatization. Accounts of Chemical Research. 48: 1979-94. PMID 26079678 DOI: 10.1021/Acs.Accounts.5B00027  0.524
2015 Khaskin E, Milstein D. Catalytic, oxidant-free, direct olefination of alcohols using Wittig reagents. Chemical Communications (Cambridge, England). 51: 9002-5. PMID 25940806 DOI: 10.1039/C5Cc02902C  0.408
2015 Butschke B, Fillman KL, Bendikov T, Shimon LJ, Diskin-Posner Y, Leitus G, Gorelsky SI, Neidig ML, Milstein D. How Innocent are Potentially Redox Non-Innocent Ligands? Electronic Structure and Metal Oxidation States in Iron-PNN Complexes as a Representative Case Study. Inorganic Chemistry. 54: 4909-26. PMID 25918944 DOI: 10.1021/Acs.Inorgchem.5B00509  0.394
2015 Srimani D, Mukherjee A, Goldberg AF, Leitus G, Diskin-Posner Y, Shimon LJ, Ben David Y, Milstein D. Cobalt-Catalyzed Hydrogenation of Esters to Alcohols: Unexpected Reactivity Trend Indicates Ester Enolate Intermediacy. Angewandte Chemie (International Ed. in English). PMID 25914240 DOI: 10.1002/Anie.201502418  0.818
2015 Rivada-Wheelaghan O, Dauth A, Leitus G, Diskin-Posner Y, Milstein D. Synthesis and reactivity of iron complexes with a new pyrazine-based pincer ligand, and application in catalytic low-pressure hydrogenation of carbon dioxide. Inorganic Chemistry. 54: 4526-38. PMID 25871886 DOI: 10.1021/Acs.Inorgchem.5B00366  0.463
2015 Feller M, Ben-Ari E, Diskin-Posner Y, Carmieli R, Weiner L, Milstein D. O2 activation by metal-ligand cooperation with Ir(I) PNP pincer complexes. Journal of the American Chemical Society. 137: 4634-7. PMID 25827819 DOI: 10.1021/Jacs.5B01585  0.633
2015 Gellrich U, Khusnutdinova JR, Leitus GM, Milstein D. Mechanistic investigations of the catalytic formation of lactams from amines and water with liberation of H2. Journal of the American Chemical Society. 137: 4851-9. PMID 25808067 DOI: 10.1021/Jacs.5B01750  0.732
2015 Fogler E, Efremenko I, Gargir M, Leitus G, Diskin-Posner Y, Ben-David Y, Martin JM, Milstein D. New ruthenium nitrosyl pincer complexes bearing an O2 ligand. Mono-oxygen transfer. Inorganic Chemistry. 54: 2253-63. PMID 25695626 DOI: 10.1021/Ic502832J  0.64
2015 Milstein D. Metal-ligand cooperation by aromatization-dearomatization as a tool in single bond activation. Philosophical Transactions. Series a, Mathematical, Physical, and Engineering Sciences. 373. PMID 25666071 DOI: 10.1098/Rsta.2014.0189  0.4
2015 Zell T, Ben-David Y, Milstein D. Highly efficient, general hydrogenation of aldehydes catalyzed by PNP iron pincer complexes Catalysis Science and Technology. 5: 822-826. DOI: 10.1039/C4Cy01501K  0.461
2015 Gellrich U, Khusnutdinova JR, Leitus GM, Milstein D. Mechanistic Investigations of the Catalytic Formation of Lactams from Amines and Water with Liberation of H2 Journal of the American Chemical Society. 137: 4851-4859. DOI: 10.1021/jacs.5b01750  0.649
2015 Feller M, Ben-Ari E, Diskin-Posner Y, Carmieli R, Weiner L, Milstein D. O2 Activation by Metal-Ligand Cooperation with IrI PNP Pincer Complexes Journal of the American Chemical Society. 137: 4634-4637. DOI: 10.1021/jacs.5b01585  0.606
2015 Khusnutdinova JR, Garg JA, Milstein D. Combining Low-Pressure CO2 Capture and Hydrogenation to Form Methanol Acs Catalysis. 5: 2416-2422. DOI: 10.1021/Acscatal.5B00194  0.696
2015 Khusnutdinova JR, Milstein D. Metall-Ligand-Kooperation Angewandte Chemie. 127: 12406-12445. DOI: 10.1002/Ange.201503873  0.679
2014 Gunanathan C, Milstein D. Bond activation and catalysis by ruthenium pincer complexes. Chemical Reviews. 114: 12024-87. PMID 25398045 DOI: 10.1021/Cr5002782  0.456
2014 Fogler E, Garg JA, Hu P, Leitus G, Shimon LJ, Milstein D. System with potential dual modes of metal-ligand cooperation: highly catalytically active pyridine-based PNNH-Ru pincer complexes. Chemistry (Weinheim An Der Bergstrasse, Germany). 20: 15727-31. PMID 25331061 DOI: 10.1002/Chem.201405295  0.534
2014 Srimani D, Leitus G, Ben-David Y, Milstein D. Direct catalytic olefination of alcohols with sulfones. Angewandte Chemie (International Ed. in English). 53: 11092-5. PMID 25163718 DOI: 10.1002/Anie.201407281  0.739
2014 Zell T, Ben-David Y, Milstein D. Unprecedented iron-catalyzed ester hydrogenation. Mild, selective, and efficient hydrogenation of trifluoroacetic esters to alcohols catalyzed by an iron pincer complex. Angewandte Chemie (International Ed. in English). 53: 4685-9. PMID 24692198 DOI: 10.1002/Anie.201311221  0.41
2014 Zell T, Milko P, Fillman KL, Diskin-Posner Y, Bendikov T, Iron MA, Leitus G, Ben-David Y, Neidig ML, Milstein D. Iron dicarbonyl complexes featuring bipyridine-based PNN pincer ligands with short interpyridine C-C bond lengths: innocent or non-innocent ligand? Chemistry (Weinheim An Der Bergstrasse, Germany). 20: 4403-13. PMID 24591249 DOI: 10.1002/Chem.201304631  0.44
2014 Khusnutdinova JR, Ben-David Y, Milstein D. Oxidant-free conversion of cyclic amines to lactams and H2 using water as the oxygen atom source Journal of the American Chemical Society. 136: 2998-3001. PMID 24521458 DOI: 10.1021/Ja500026M  0.698
2014 Vogt M, Nerush A, Diskin-Posner Y, Ben-David Y, Milstein D. Reversible CO2 binding triggered by metal-ligand cooperation in a rhenium(i) PNP pincer-type complex and the reaction with dihydrogen Chemical Science. 5: 2043-2051. DOI: 10.1039/C4Sc00130C  0.426
2014 Anaby A, Butschke B, Ben-David Y, Shimon LJW, Leitus G, Feller M, Milstein D. B-H bond cleavage via metal-ligand cooperation by dearomatized ruthenium pincer complexes Organometallics. 33: 3716-3726. DOI: 10.1021/Om500311A  0.536
2014 Hu P, Diskin-Posner Y, Ben-David Y, Milstein D. Reusable homogeneous catalytic system for hydrogen production from methanol and water Acs Catalysis. 4: 2649-2652. DOI: 10.1021/Cs500937F  0.425
2014 Balaraman E, Srimani D, Diskin-Posner Y, Milstein D. Direct Synthesis of Secondary Amines From Alcohols and Ammonia Catalyzed by a Ruthenium Pincer Complex Catalysis Letters. 145: 139-144. DOI: 10.1007/S10562-014-1422-2  0.82
2014 Balaraman E, Milstein D. Hydrogenation of polar bonds catalysed by ruthenium-pincer complexes Topics in Organometallic Chemistry. 48: 19-44. DOI: 10.1007/3418_2014_77  0.719
2014 Srimani D, Leitus G, Ben-David Y, Milstein D. Direct catalytic olefination of alcohols with sulfones Angewandte Chemie - International Edition. 53: 11092-11095. DOI: 10.1002/anie.201407281  0.679
2013 Srimani D, Diskin-Posner Y, Ben-David Y, Milstein D. Iron pincer complex catalyzed, environmentally benign, E-selective semi-hydrogenation of alkynes. Angewandte Chemie (International Ed. in English). 52: 14131-4. PMID 24353233 DOI: 10.1002/Anie.201306629  0.727
2013 Vogt M, Nerush A, Iron MA, Leitus G, Diskin-Posner Y, Shimon LJ, Ben-David Y, Milstein D. Activation of nitriles by metal ligand cooperation. Reversible formation of ketimido- and enamido-rhenium PNP pincer complexes and relevance to catalytic design. Journal of the American Chemical Society. 135: 17004-18. PMID 24187982 DOI: 10.1021/Ja4071859  0.486
2013 Fogler E, Iron MA, Zhang J, Ben-David Y, Diskin-Posner Y, Leitus G, Shimon LJ, Milstein D. Ru(0) and Ru(II) nitrosyl pincer complexes: structure, reactivity, and catalytic activity. Inorganic Chemistry. 52: 11469-79. PMID 24047217 DOI: 10.1021/Ic401780P  0.503
2013 Zell T, Langer R, Iron MA, Konstantinovski L, Shimon LJW, Diskin-Posner Y, Leitus G, Balaraman E, Ben-David Y, Milstein D. Synthesis, structures, and dearomatization by deprotonation of iron complexes featuring bipyridine-based PNN pincer ligands Inorganic Chemistry. 52: 9636-9649. PMID 23902514 DOI: 10.1021/Ic401432M  0.682
2013 Gunanathan C, Milstein D. Applications of acceptorless dehydrogenation and related transformations in chemical synthesis. Science (New York, N.Y.). 341: 1229712. PMID 23869021 DOI: 10.1126/Science.1229712  0.448
2013 Feller M, Diskin-Posner Y, Leitus G, Shimon LJ, Milstein D. Direct observation of reductive elimination of MeX (X = Cl, Br, I) from Rh(III) complexes: mechanistic insight and the importance of sterics. Journal of the American Chemical Society. 135: 11040-7. PMID 23865376 DOI: 10.1021/Ja401852C  0.433
2013 Srimani D, Ben-David Y, Milstein D. Direct synthesis of pyridines and quinolines by coupling of γ-amino-alcohols with secondary alcohols liberating H2 catalyzed by ruthenium pincer complexes. Chemical Communications (Cambridge, England). 49: 6632-4. PMID 23771175 DOI: 10.1039/C3Cc43227K  0.764
2013 Zell T, Butschke B, Ben-David Y, Milstein D. Efficient hydrogen liberation from formic acid catalyzed by a well-defined iron pincer complex under mild conditions. Chemistry (Weinheim An Der Bergstrasse, Germany). 19: 8068-72. PMID 23649981 DOI: 10.1002/Chem.201301383  0.405
2013 Khusnutdinova JR, Ben-David Y, Milstein D. Direct deamination of primary amines by water to produce alcohols. Angewandte Chemie (International Ed. in English). 52: 6269-72. PMID 23620463 DOI: 10.1002/Anie.201301000  0.659
2013 Srimani D, Ben-David Y, Milstein D. Direct synthesis of pyrroles by dehydrogenative coupling of β-aminoalcohols with secondary alcohols catalyzed by ruthenium pincer complexes. Angewandte Chemie (International Ed. in English). 52: 4012-5. PMID 23468418 DOI: 10.1002/Anie.201300574  0.737
2013 Khaskin E, Diskin-Posner Y, Weiner L, Leitus G, Milstein D. Formal loss of an H radical by a cobalt complex via metal-ligand cooperation. Chemical Communications (Cambridge, England). 49: 2771-3. PMID 23443914 DOI: 10.1039/C3Cc39049G  0.468
2013 Langer R, Fuchs I, Vogt M, Balaraman E, Diskin-Posner Y, Shimon LJ, Ben-David Y, Milstein D. Stepwise metal-ligand cooperation by a reversible aromatization/deconjugation sequence in ruthenium complexes with a tetradentate phenanthroline-based ligand. Chemistry (Weinheim An Der Bergstrasse, Germany). 19: 3407-14. PMID 23362113 DOI: 10.1002/Chem.201204003  0.745
2013 Balaraman E, Khaskin E, Leitus G, Milstein D. Catalytic transformation of alcohols to carboxylic acid salts and H2 using water as the oxygen atom source. Nature Chemistry. 5: 122-5. PMID 23344447 DOI: 10.1038/Nchem.1536  0.683
2013 Pellegrino J, Gaviglio C, Milstein D, Doctorovich F. Electron transfer behavior of pincer-type {RhNO}8 complexes: Spectroscopic characterization and reactivity of paramagnetic {RhNO}9 complexes Organometallics. 32: 6555-6564. DOI: 10.1021/Om4008746  0.458
2013 Montag M, Efremenko I, Leitus G, Ben-David Y, Martin JML, Milstein D. CO-induced methyl migration in a rhodium thiophosphoryl pincer complex and its comparison with phosphine-based complexes: The divergent effects of S and P donor ligands Organometallics. 32: 7163-7180. DOI: 10.1021/Om4008696  0.791
2013 Poverenov E, Efremenko I, Leitus G, Martin JML, Milstein D. Benzyl cation stabilized by metal complexation. relative stability of coordinated methylene arenium, π-benzylic, and σ-benzylic structures Organometallics. 32: 4813-4819. DOI: 10.1021/Om400523F  0.444
2013 Barrios-Francisco R, Balaraman E, Diskin-Posner Y, Leitus G, Shimon LJW, Milstein D. PNN ruthenium pincer complexes based on phosphinated 2,2′- dipyridinemethane and 2,2′-oxobispyridine. metal-ligand cooperation in cyclometalation and catalysis Organometallics. 32: 2973-2982. DOI: 10.1021/Om400194W  0.707
2013 Vogt M, Rivada-Wheelaghan O, Iron MA, Leitus G, Diskin-Posner Y, Shimon LJW, Ben-David Y, Milstein D. Anionic nickel(II) complexes with doubly deprotonated PNP pincer-type ligands and their reactivity toward CO2 Organometallics. 32: 300-308. DOI: 10.1021/Om3010838  0.472
2013 Vogt M, Nerush A, Iron MA, Leitus G, Diskin-Posner Y, Shimon LJW, Ben-David Y, Milstein D. Activation of nitriles by metal ligand cooperation. reversible formation of ketimido- and enamido-rhenium PNP pincer complexes and relevance to catalytic design Journal of the American Chemical Society. 135: 17004-17018. DOI: 10.1021/ja4071859  0.344
2013 Fogler E, Iron MA, Zhang J, Ben-David Y, Diskin-Posner Y, Leitus G, Shimon LJW, Milstein D. Ru(0) and Ru(II) nitrosyl pincer complexes: Structure, reactivity, and catalytic activity Inorganic Chemistry. 52: 11469-11479. DOI: 10.1021/ic401780p  0.305
2013 Khaskin E, Milstein D. Simple and efficient catalytic reaction for the selective deuteration of alcohols Acs Catalysis. 3: 448-452. DOI: 10.1021/Cs400092P  0.433
2013 Srimani D, Balaraman E, Hu P, Ben-David Y, Milstein D. Formation of tertiary amides and dihydrogen by dehydrogenative coupling of primary alcohols with secondary amines catalyzed by ruthenium bipyridine-based pincer complexes Advanced Synthesis and Catalysis. 355: 2525-2530. DOI: 10.1002/Adsc.201300620  0.82
2012 Srimani D, Feller M, Ben-David Y, Milstein D. Catalytic coupling of nitriles with amines to selectively form imines under mild hydrogen pressure. Chemical Communications (Cambridge, England). 48: 11853-5. PMID 23125982 DOI: 10.1039/C2Cc36639H  0.76
2012 Vogt M, Gargir M, Iron MA, Diskin-Posner Y, Ben-David Y, Milstein D. A new mode of activation of CO2 by metal-ligand cooperation with reversible C-C and M-O bond formation at ambient temperature Chemistry - a European Journal. 18: 9194-9197. PMID 22736579 DOI: 10.1002/Chem.201201730  0.41
2012 Montag M, Zhang J, Milstein D. Aldehyde binding through reversible C-C coupling with the pincer ligand upon alcohol dehydrogenation by a PNP-ruthenium catalyst. Journal of the American Chemical Society. 134: 10325-8. PMID 22703115 DOI: 10.1021/Ja303121V  0.764
2012 Langer R, Iron MA, Konstantinovski L, Diskin-Posner Y, Leitus G, Ben-David Y, Milstein D. Iron borohydride pincer complexes for the efficient hydrogenation of ketones under mild, base-free conditions: synthesis and mechanistic insight. Chemistry (Weinheim An Der Bergstrasse, Germany). 18: 7196-209. PMID 22532294 DOI: 10.1002/Chem.201200159  0.447
2012 Balaraman E, Fogler E, Milstein D. Efficient hydrogenation of biomass-derived cyclic di-esters to 1,2-diols. Chemical Communications (Cambridge, England). 48: 1111-3. PMID 22038098 DOI: 10.1039/C1Cc15778G  0.699
2012 Prechtl MHG, Wobser K, Theyssen N, Ben-David Y, Milstein D, Leitner W. Direct coupling of alcohols to form esters and amides with evolution of H2 using in situ formed ruthenium catalysts Catalysis Science and Technology. 2: 2039-2042. DOI: 10.1039/C2Cy20429K  0.747
2012 Gargir M, Ben-David Y, Leitus G, Diskin-Posner Y, Shimon LJW, Milstein D. PNS-type ruthenium pincer complexes Organometallics. 31: 6207-6214. DOI: 10.1021/Om300516J  0.514
2012 Feller M, Diskin-Posner Y, Shimon LJW, Ben-Ari E, Milstein D. N-H activation by Rh(I) via metal-ligand cooperation Organometallics. 31: 4083-4101. DOI: 10.1021/Om300248R  0.647
2012 Montag M, Efremenko I, Diskin-Posner Y, Ben-David Y, Martin JML, Milstein D. Exclusive C-C oxidative addition in a rhodium thiophosphoryl pincer complex and computational evidence for an ν 3-C-C-H agostic intermediate Organometallics. 31: 505-512. DOI: 10.1021/Om201205Y  0.777
2012 Gnanaprakasam B, Balaraman E, Gunanathan C, Milstein D. Synthesis of polyamides from diols and diamines with liberation of H 2 Journal of Polymer Science, Part a: Polymer Chemistry. 50: 1755-1765. DOI: 10.1002/Pola.25943  0.694
2012 Srimani D, Balaraman E, Gnanaprakasam B, Ben-David Y, Milstein D. Ruthenium pincer-catalyzed cross-dehydrogenative coupling of primary alcohols with secondary alcohols under neutral conditions Advanced Synthesis and Catalysis. 354: 2403-2406. DOI: 10.1002/Adsc.201200438  0.793
2012 Kossoy E, Diskin-Posner Y, Leitus G, Milstein D. Selective acceptorless conversion of primary alcohols to acetals and dihydrogen catalyzed by the ruthenium(II) complex Ru(PPh 3) 2(NCCH 3) 2(SO 4) Advanced Synthesis and Catalysis. 354: 497-504. DOI: 10.1002/Adsc.201100672  0.828
2011 Balaraman E, Ben-David Y, Milstein D. Unprecedented catalytic hydrogenation of urea derivatives to amines and methanol. Angewandte Chemie (International Ed. in English). 50: 11702-5. PMID 22052711 DOI: 10.1002/Anie.201106612  0.677
2011 Gnanaprakasam B, Balaraman E, Ben-David Y, Milstein D. Synthesis of peptides and pyrazines from β-amino alcohols through extrusion of H2 catalyzed by ruthenium pincer complexes: ligand-controlled selectivity. Angewandte Chemie (International Ed. in English). 50: 12240-4. PMID 22031234 DOI: 10.1002/Anie.201105876  0.685
2011 Langer R, Diskin-Posner Y, Leitus G, Shimon LJ, Ben-David Y, Milstein D. Low-pressure hydrogenation of carbon dioxide catalyzed by an iron pincer complex exhibiting noble metal activity. Angewandte Chemie (International Ed. in English). 50: 9948-52. PMID 21905190 DOI: 10.1002/Anie.201104542  0.381
2011 Balaraman E, Gunanathan C, Zhang J, Shimon LJ, Milstein D. Efficient hydrogenation of organic carbonates, carbamates and formates indicates alternative routes to methanol based on CO2 and CO. Nature Chemistry. 3: 609-14. PMID 21778980 DOI: 10.1038/Nchem.1089  0.714
2011 Gunanathan C, Milstein D. Metal-ligand cooperation by aromatization-dearomatization: a new paradigm in bond activation and "green" catalysis. Accounts of Chemical Research. 44: 588-602. PMID 21739968 DOI: 10.1021/Ar2000265  0.523
2011 Li MJ, Greenblatt HM, Dym O, Albeck S, Pais A, Gunanathan C, Milstein D, Degani H, Sussman JL. Structure of estradiol metal chelate and estrogen receptor complex: the basis for designing a new class of selective estrogen receptor modulators. Journal of Medicinal Chemistry. 54: 3575-80. PMID 21473635 DOI: 10.1021/Jm200192Y  0.332
2011 Langer R, Leitus G, Ben-David Y, Milstein D. Efficient hydrogenation of ketones catalyzed by an iron pincer complex. Angewandte Chemie (International Ed. in English). 50: 2120-4. PMID 21344565 DOI: 10.1002/Anie.201007406  0.41
2011 Gnanaprakasam B, Milstein D. Synthesis of amides from esters and amines with liberation of H2 under neutral conditions. Journal of the American Chemical Society. 133: 1682-5. PMID 21247162 DOI: 10.1021/Ja109944N  0.504
2011 Zhang J, Balaraman E, Leitus G, Milstein D. Electron-rich PNP-and PNN-type ruthenium(ii) hydrido borohydride pincer complexes. synthesis, structure, and catalytic dehydrogenation of alcohols and hydrogenation of esters Organometallics. 30: 5716-5724. DOI: 10.1021/Om200595M  0.737
2011 Fogler E, Balaraman E, Ben-David Y, Leitus G, Shimon LJW, Milstein D. New CNN-type ruthenium pincer NHC complexes. Mild, efficient catalytic hydrogenation of esters Organometallics. 30: 3826-3833. DOI: 10.1021/Om200367J  0.758
2011 Schwartsburd L, Iron MA, Konstantinovski L, Ben-Ari E, Milstein D. A dearomatized anionic PNP pincer rhodium complex: C-H and H-H bond activation by metal-ligand cooperation and inhibition by dinitrogen Organometallics. 30: 2721-2729. DOI: 10.1021/Om200104B  0.724
2011 Salem H, Leitus G, Shimon LJW, Diskin-Posner Y, Milstein D. Aliphatic and aromatic C-H activation of benzo[h]quinolines by Rh(I). Unique precursor dependent formation of mono-, di- and trinuclear complexes Inorganica Chimica Acta. 369: 260-269. DOI: 10.1016/J.Ica.2010.12.064  0.482
2011 Gunanathan C, Milstein D. Bond activation by metal-ligand cooperation: Design of "green" catalytic reactions based on aromatization-dearomatization of pincer complexes Topics in Organometallic Chemistry. 37: 55-84. DOI: 10.1007/3418_2011_6  0.404
2011 Langer R, Leitus G, Ben‐David Y, Milstein D. Cover Picture: Efficient Hydrogenation of Ketones Catalyzed by an Iron Pincer Complex (Angew. Chem. Int. Ed. 9/2011) Angewandte Chemie. 50: 1947-1947. DOI: 10.1002/Anie.201100452  0.409
2011 Langer R, Leitus G, Ben‐David Y, Milstein D. Titelbild: Efficient Hydrogenation of Ketones Catalyzed by an Iron Pincer Complex (Angew. Chem. 9/2011) Angewandte Chemie. 123: 1989-1989. DOI: 10.1002/Ange.201100452  0.411
2010 Balaraman E, Gnanaprakasam B, Shimon LJ, Milstein D. Direct hydrogenation of amides to alcohols and amines under mild conditions. Journal of the American Chemical Society. 132: 16756-8. PMID 21049928 DOI: 10.1021/Ja1080019  0.734
2010 Gunanathan C, Gnanaprakasam B, Iron MA, Shimon LJW, Milstein D. "Long-range" metel-ligand cooperation in h2 activation and ammonia-promoted hydride transfer with a ruthenium-acridine pincer complex Journal of the American Chemical Society. 132: 14763-14765. PMID 20925343 DOI: 10.1021/Ja107770Y  0.482
2010 Efremenko I, Poverenov E, Martin JM, Milstein D. DFT study of the structure and reactivity of the terminal Pt(IV)-oxo complex bearing no electron-withdrawing ligands. Journal of the American Chemical Society. 132: 14886-900. PMID 20879796 DOI: 10.1021/Ja105197X  0.647
2010 Khaskin E, Iron MA, Shimon LJ, Zhang J, Milstein D. N-H activation of amines and ammonia by Ru via metal-ligand cooperation. Journal of the American Chemical Society. 132: 8542-3. PMID 20524608 DOI: 10.1021/Ja103130U  0.455
2010 Gnanaprakasam B, Zhang J, Milstein D. Direct synthesis of imines from alcohols and amines with liberation of H2. Angewandte Chemie (International Ed. in English). 49: 1468-71. PMID 20101664 DOI: 10.1002/Anie.200907018  0.348
2010 Feller M, Ben-Ari E, Iron MA, Diskin-Posner Y, Leitus G, Shimon LJ, Konstantinovski L, Milstein D. Cationic, neutral, and anionic PNP Pd(II) and Pt(II) complexes: dearomatization by deprotonation and double-deprotonation of pincer systems. Inorganic Chemistry. 49: 1615-25. PMID 20067235 DOI: 10.1021/Ic902012Z  0.701
2010 Montag M, Efremenko I, Cohen R, Shimon LJ, Leitus G, Diskin-Posner Y, Ben-David Y, Salem H, Martin JM, Milstein D. Effect of CO on the oxidative addition of arene C-H bonds by cationic rhodium complexes. Chemistry (Weinheim An Der Bergstrasse, Germany). 16: 328-53. PMID 19918810 DOI: 10.1002/Chem.200901526  0.819
2010 Schwartsburd L, Iron MA, Konstantinovski L, Diskin-Posner Y, Leitus G, Shimon LJW, Milstein D. Synthesis and reactivity of an iridium(I) acetonyl PNP complex. Experimental and computational study of metal-ligand cooperation in H-H and C-H bond activation via reversible ligand dearomatization Organometallics. 29: 3817-3827. DOI: 10.1021/Om1004435  0.489
2010 Feller M, Ben-Ari E, Iron MA, Diskin-Posner Y, Leitus G, Linda LJ, Konstantinovski L, Milstein D. Cationic, neutral, and anionic PNP PdII and PtII complexes: Dearomatization by deprotonation and double-deprotonation of pincer systems Inorganic Chemistry. 49: 1615-1625. DOI: 10.1021/ic902012z  0.599
2010 Gunanathan C, Diskin-Posner Y, Milstein D. Lanthanide-organic framework of a rigid bis-Gd complex: Composed by carbonate ions spacers Crystal Growth and Design. 10: 4235-4239. DOI: 10.1021/Cg100843K  0.372
2010 Milstein D. Discovery of environmentally benign catalytic reactions of alcohols catalyzed by pyridine-based pincer Ru complexes, based on metal-ligand cooperation Topics in Catalysis. 53: 915-923. DOI: 10.1007/S11244-010-9523-7  0.508
2010 Gnanaprakasam B, Ben-David Y, Milstein D. Ruthenium pincer-catalyzed acylation of alcohols using esters with liberation of hydrogen under neutral conditions Advanced Synthesis and Catalysis. 352: 3169-3173. DOI: 10.1002/Adsc.201000663  0.457
2009 Iron MA, Ben-Ari E, Cohen R, Milstein D. Metal-ligand cooperation in the trans addition of dihydrogen to a pincer Ir(I) complex: a DFT study. Dalton Transactions (Cambridge, England : 2003). 9433-9. PMID 19859598 DOI: 10.1039/B909852F  0.718
2009 Kohl SW, Weiner L, Schwartsburd L, Konstantinovski L, Shimon LJ, Ben-David Y, Iron MA, Milstein D. Consecutive thermal H2 and light-induced O2 evolution from water promoted by a metal complex. Science (New York, N.Y.). 324: 74-7. PMID 19342584 DOI: 10.1126/Science.1168600  0.478
2009 Gunanathan C, Shimon LJ, Milstein D. Direct conversion of alcohols to acetals and H(2) catalyzed by an acridine-based ruthenium pincer complex. Journal of the American Chemical Society. 131: 3146-7. PMID 19216551 DOI: 10.1021/Ja808893G  0.466
2009 Iron MA, Ben-Ari E, Cohen R, Milstein D. Metal-ligand cooperation in the trans addition of dihydrogen to a pincer Ir(i) complex: A DFT study Dalton Transactions. 9433-9439. DOI: 10.1039/b909852f  0.644
2009 Salem H, Shimon LJW, Diskin-Posner Y, Leitus G, Ben-David Y, Milstein D. Formation of stable trans-dihydride ruthenium(II) and 16-electron ruthenium(0) complexes based on phosphinite PONOP pincer ligands. Reactivity toward water and electrophiles Organometallics. 28: 4791-4806. DOI: 10.1021/Om9004077  0.49
2009 Gaviglio C, Ben-David Y, Shimon LJW, Doctorovich F, Milstein D. Synthesis, structure, and reactivity of nitrosyl pincer-type rhodium complexes Organometallics. 28: 1917-1926. DOI: 10.1021/Om8011536  0.488
2009 Freeh CM, Shimon LJW, Milstein D. Unsaturated rh(i) and rh(iii) naphthyl-based pcp complexes. major steric effect on reactivity Organometallics. 28: 1900-1908. DOI: 10.1021/Om801147W  0.301
2009 Kossoy E, Rybtchinski B, Yael DP, Shimon LJW, Leitus G, Milstein D. Structure and reactivity of rhodium(I) complexes based on electron-withdrawing pyrrolyl-pcp-pincer ligands Organometallics. 28: 523-533. DOI: 10.1021/Om800792Y  0.829
2008 Feller M, Iron MA, Shimon LJ, Diskin-Posner Y, Leitus G, Milstein D. Competitive C-I versus C-CN reductive elimination from a Rh(III) complex. Selectivity is controlled by the solvent. Journal of the American Chemical Society. 130: 14374-5. PMID 18847193 DOI: 10.1021/Ja8046798  0.506
2008 Gunanathan C, Milstein D. Selective synthesis of primary amines directly from alcohols and ammonia. Angewandte Chemie (International Ed. in English). 47: 8661-4. PMID 18846519 DOI: 10.1002/Anie.200803229  0.331
2008 Montag M, Efremenko I, Cohen R, Leitus G, Shimon LJ, Diskin-Posner Y, Ben-David Y, Martin JM, Milstein D. The impact of weak C-H...Rh interactions on the structure and reactivity of trans-[Rh(CO)2(phosphine)2]+: an experimental and theoretical examination. Chemistry (Weinheim An Der Bergstrasse, Germany). 14: 8183-94. PMID 18698575 DOI: 10.1002/Chem.200801171  0.782
2008 Klerman Y, Ben-Ari E, Diskin-Posner Y, Leitus G, Shimon LJ, Ben-David Y, Milstein D. Pyridine-based SNS-iridium and -rhodium sulfide complexes, including d8-d8 metal-metal interactions in the solid state. Dalton Transactions (Cambridge, England : 2003). 3226-34. PMID 18688421 DOI: 10.1039/B802223B  0.7
2008 Korshin EE, Leitus G, Shimon LJ, Konstantinovski L, Milstein D. Silanol-based pincer Pt(II) complexes: synthesis, structure, and unusual reactivity. Inorganic Chemistry. 47: 7177-89. PMID 18637675 DOI: 10.1021/Ic800457U  0.46
2008 Schaub T, Diskin-Posner Y, Radius U, Milstein D. Synthesis, structure, and reactivity of rhodium and iridium complexes of the chelating bis-sulfoxide tBuSOC2H4SOtBu. Selective O-H activation of 2-hydroxy-isopropyl-pyridine. Inorganic Chemistry. 47: 6502-12. PMID 18563881 DOI: 10.1021/Ic800354Q  0.463
2008 Schwartsburd L, Cohen R, Konstantinovski L, Milstein D. A pincer-type anionic platinum(0) complex. Angewandte Chemie (International Ed. in English). 47: 3603-6. PMID 18383469 DOI: 10.1002/Anie.200705927  0.408
2008 Poverenov E, Efremenko I, Frenkel AI, Ben-David Y, Shimon LJW, Leitus G, Konstantinovski L, Martin JML, Milstein D. Evidence for a terminal Pt(iv)-oxo complex exhibiting diverse reactivity Nature. 455: 1093-1096. DOI: 10.1038/Nature07356  0.465
2008 Zhang J, Gandelman M, Shimon LJW, Milstein D. Stable carbene and diazoalkane complexes of the same complex system. Synthesis, structure, and reactivity of PNP-Ru(II) fluorenylidene and diazofluorene complexes Organometallics. 27: 3526-3533. DOI: 10.1021/Om800294V  0.689
2008 Vuzman D, Poverenov E, Shimon LJW, Diskin-Posner Y, Milstein D. Cationic, Neutral, and Anionic Platinum(II) Complexes Based on an Electron-Rich PNN Ligand. New Modes of Reactivity Based on Pincer Hemilability and Dearomatization Organometallics. 27: 2627-2634. DOI: 10.1021/Om8001069  0.511
2008 Salem H, Shimon LJW, Leitus G, Weiner L, Milstein D. B-C bond cleavage of BArF anion upon oxidation of rhodium(I) with AgBArF. Phosphinite rhodium(I), rhodium(II), and rhodium(III) pincer complexes Organometallics. 27: 2293-2299. DOI: 10.1021/Om800034T  0.486
2008 Schaub T, Radius U, Diskin-Posner Y, Leitus G, Shimon LJW, Milstein D. Pyridine-Based Sulfoxide Pincer Complexes of Rhodium and Iridium Organometallics. 27: 1892-1901. DOI: 10.1021/Om701276S  0.404
2008 Frech CM, Leitus G, Milstein D. Processes involved in the reduction of a cyclometalated palladium(II) complex Organometallics. 27: 894-899. DOI: 10.1021/Om7008815  0.398
2008 Prechtl MHG, Hölscher M, Ben-David Y, Theyssen N, Milstein D, Leitner W. Ruthenium dihydrogen complex for C-H activation: Catalytic H/D exchange under mild conditions European Journal of Inorganic Chemistry. 3493-3500. DOI: 10.1002/Ejic.200800359  0.742
2007 Vuzman D, Poverenov E, Diskin-Posner Y, Leitus G, Shimon LJ, Milstein D. Reactivity and stability of platinum(II) formyl complexes based on PCP-type ligands. The significance of sterics. Dalton Transactions (Cambridge, England : 2003). 5692-700. PMID 18060114 DOI: 10.1039/B711444C  0.503
2007 Raitsimring AM, Gunanathan C, Potapov A, Efremenko I, Martin JM, Milstein D, Goldfarb D. Gd3+ complexes as potential spin labels for high field pulsed EPR distance measurements. Journal of the American Chemical Society. 129: 14138-9. PMID 17963387 DOI: 10.1021/Ja075544G  0.5
2007 Montag M, Leitus G, Shimon LJ, Ben-David Y, Milstein D. Solvent-dependent interconversions between Rh(I), Rh(II), and Rh(III) complexes of an aryl-monophosphine ligand. Chemistry (Weinheim An Der Bergstrasse, Germany). 13: 9043-55. PMID 17907122 DOI: 10.1002/Chem.200700805  0.783
2007 Feller M, Ben-Ari E, Gupta T, Shimon LJ, Leitus G, Diskin-Posner Y, Weiner L, Milstein D. Mononuclear Rh(II) PNP-type complexes. Structure and reactivity. Inorganic Chemistry. 46: 10479-90. PMID 17902648 DOI: 10.1021/Ic701044B  0.815
2007 Gunanathan C, Ben-David Y, Milstein D. Direct synthesis of amides from alcohols and amines with liberation of H2. Science (New York, N.Y.). 317: 790-2. PMID 17690291 DOI: 10.1126/Science.1145295  0.477
2007 Poverenov E, Milstein D. Formation of transition metal carbenes using haloalkylzinc reagents. Chemical Communications (Cambridge, England). 3189-91. PMID 17653384 DOI: 10.1039/B705459A  0.433
2007 Frech CM, Shimon LJ, Milstein D. Methylene transfer from SnMe groups mediated by a rhodium(I) pincer complex: Sn-C, C-C, and C-H bond activation. Chemistry (Weinheim An Der Bergstrasse, Germany). 13: 7501-9. PMID 17610224 DOI: 10.1002/Chem.200700320  0.443
2007 Prechtl MH, Hölscher M, Ben-David Y, Theyssen N, Loschen R, Milstein D, Leitner W. H/D exchange at aromatic and heteroaromatic hydrocarbons using D2O as the deuterium source and ruthenium dihydrogen complexes as the catalyst. Angewandte Chemie (International Ed. in English). 46: 2269-72. PMID 17300115 DOI: 10.1002/Anie.200603677  0.746
2007 Montag M, Schwartsburd L, Cohen R, Leitus G, Ben-David Y, Martin JM, Milstein D. The unexpected role of CO in C--H oxidative addition by a cationic rhodium(I) complex. Angewandte Chemie (International Ed. in English). 46: 1901-4. PMID 17274087 DOI: 10.1002/Anie.200604357  0.81
2007 Gauvin RM, Rozenberg H, Shimon LJ, Ben-David Y, Milstein D. Osmium-mediated C--H and C--C bond cleavage of a phenolic substrate: p-quinone methide and methylene arenium pincer complexes. Chemistry (Weinheim An Der Bergstrasse, Germany). 13: 1382-93. PMID 17171738 DOI: 10.1002/Chem.200601385  0.373
2007 Zhang J, Gandelman M, Shimon LJ, Milstein D. Electron-rich, bulky PNN-type ruthenium complexes: synthesis, characterization and catalysis of alcohol dehydrogenation. Dalton Transactions (Cambridge, England : 2003). 107-13. PMID 17160180 DOI: 10.1039/B613438F  0.723
2007 Prechtl MH, Ben-David Y, Giunta D, Busch S, Taniguchi Y, Wisniewski W, Görls H, Mynott RJ, Theyssen N, Milstein D, Leitner W. Synthesis and characterisation of nonclassical ruthenium hydride complexes containing chelating bidentate and tridentate phosphine ligands. Chemistry (Weinheim An Der Bergstrasse, Germany). 13: 1539-46. PMID 17117397 DOI: 10.1002/Chem.200600897  0.778
2007 Schwartsburd L, Poverenov E, Shimon LJW, Milstein D. Naphthyl-Based PCP Platinum Complexes. Nucleophilic Activation of Coordinated CO and Synthesis of a Pt(II) Formyl Complex Organometallics. 26: 2931-2936. DOI: 10.1021/Om0700720  0.502
2007 Poverenov E, Shimon LJW, Milstein D. Quinone Methide Generation Based on a cis-(N,N) Platinum Complex Organometallics. 26: 2178-2182. DOI: 10.1021/Om061178I  0.404
2006 Poverenov E, Leitus G, Milstein D. Synthesis and reactivity of the methylene arenium form of a benzyl cation, stabilized by complexation. Journal of the American Chemical Society. 128: 16450-1. PMID 17177364 DOI: 10.1021/Ja067298Z  0.363
2006 Ben-Ari E, Leitus G, Shimon LJ, Milstein D. Metal-ligand cooperation in C-H and H2 activation by an electron-rich PNP Ir(I) system: facile ligand dearomatization-aromatization as key steps. Journal of the American Chemical Society. 128: 15390-1. PMID 17132002 DOI: 10.1021/Ja066411I  0.681
2006 Frech CM, Milstein D. Direct observation of reductive elimination of methyl iodide from a rhodium(III) pincer complex: the importance of sterics. Journal of the American Chemical Society. 128: 12434-5. PMID 16984191 DOI: 10.1021/Ja064945D  0.356
2006 Feller M, Karton A, Leitus G, Martin JM, Milstein D. Selective sp3 C-H activation of ketones at the beta position by Ir(I). Origin of regioselectivity and water effect. Journal of the American Chemical Society. 128: 12400-1. PMID 16984174 DOI: 10.1021/Ja0641352  0.633
2006 Frech CM, Ben-David Y, Weiner L, Milstein D. Metal-controlled reactivity of a pincer-type, sigma-coordinated naphthyl radical anion. Journal of the American Chemical Society. 128: 7128-9. PMID 16734443 DOI: 10.1021/Ja0615066  0.453
2006 Zhang J, Leitus G, Ben-David Y, Milstein D. Efficient homogeneous catalytic hydrogenation of esters to alcohols. Angewandte Chemie (International Ed. in English). 45: 1113-5. PMID 16389607 DOI: 10.1002/Anie.200503771  0.37
2006 Ben-Ari E, Cohen R, Gandelman M, Shimon LJW, Martin JML, Milstein D. Ortho C - H activation of haloarenes and anisole by an electron-rich iridium(I) complex: Mechanism and origin of regio- and chemoselectivity. An experimental and theoretical study Organometallics. 25: 3190-3210. DOI: 10.1021/Om060078+  0.775
2006 Salem H, Ben-David Y, Shimon LJW, Milstein D. Exclusive C-C activation and an apparent α-H elimination with a rhodium phosphinite pincer complex Organometallics. 25: 2292-2300. DOI: 10.1021/Om060005Q  0.52
2006 Zhang J, Gandelman M, Herrman D, Leitus G, Shimon LJW, Ben-David Y, Milstein D. Iron(II) complexes based on electron-rich, bulky PNN- and PNP-type ligands Inorganica Chimica Acta. 359: 1955-1960. DOI: 10.1016/J.Ica.2005.11.039  0.676
2006 Frech CM, Shimon LJW, Milstein D. Ligand-controlled formation of a low-valent pincer rhodium(I)-dioxygen adduct bearing a very short O-O bond Helvetica Chimica Acta. 89: 1730-1739. DOI: 10.1002/Hlca.200690170  0.364
2005 Gandelman M, Naing KM, Rybtchinski B, Poverenov E, Ben-David Y, Ashkenazi N, Gauvin RM, Milstein D. A general method for preparation of metal carbenes via solution- and polymer-based approaches. Journal of the American Chemical Society. 127: 15265-72. PMID 16248669 DOI: 10.1021/Ja050781+  0.654
2005 Zhang J, Leitus G, Ben-David Y, Milstein D. Facile conversion of alcohols into esters and dihydrogen catalyzed by new ruthenium complexes. Journal of the American Chemical Society. 127: 10840-1. PMID 16076184 DOI: 10.1021/Ja052862B  0.476
2005 Goikhman R, Milstein D. Reactivity of rhodium-triflate complexes with diphenylsilane: evidence for silylene intermediacy in stoichiometric and catalytic reactions. Chemistry (Weinheim An Der Bergstrasse, Germany). 11: 2983-8. PMID 15761852 DOI: 10.1002/Chem.200400568  0.506
2005 Frech CM, Shimon LJ, Milstein D. Redox-induced collapse and regeneration of a pincer-type complex framework: a nonplanar coordination mode of palladium(II). Angewandte Chemie (International Ed. in English). 44: 1709-11. PMID 15712307 DOI: 10.1002/Anie.200462386  0.366
2005 Kossoy E, Iron MA, Rybtchinski B, Ben-David Y, Shimon LJ, Konstantinovski L, Martin JM, Milstein D. Pi-accepting-pincer rhodium complexes: an unusual coordination mode of PCP-type systems. Chemistry (Weinheim An Der Bergstrasse, Germany). 11: 2319-26. PMID 15643661 DOI: 10.1002/Chem.200401116  0.817
2005 Goikhman R, Karakuz T, Shimon LJW, Leitus G, Milstein D. Electron-rich siloxane-platinum complexes - Synthesis, structures, and reactivity Canadian Journal of Chemistry. 83: 786-792. DOI: 10.1139/V05-041  0.412
2005 Poverenov E, Leitus G, Shimon LJW, Milstein D. C-Metalated Diazoalkane Complexes of Platinum Based on PCP- and PCN-Type Ligands Organometallics. 24: 5937-5944. DOI: 10.1021/Om050637X  0.465
2005 Albéniz AC, Espinet P, Martín-Ruiz B, Milstein D. Catalytic System for the Heck Reaction of Fluorinated Haloaryls Organometallics. 24: 3679-3684. DOI: 10.1021/Om050017W  0.488
2005 Poverenov E, Gandelman M, Shimon LJW, Rozenberg H, Ben-David Y, Milstein D. Pincer "hemilabile" effect. PCN platinum(II) complexes with different amine "arm length" Organometallics. 24: 1082-1090. DOI: 10.1021/Om049182M  0.659
2005 Zhang J, Leitus G, Ben-David Y, Milstein D. Facile Conversion of Alcohols into Esters and Dihydrogen Catalyzed by New Ruthenium Complexes [J. Am. Chem. Soc. 2005, 127, 10840−10841]. Journal of the American Chemical Society. 127: 12429-12429. DOI: 10.1021/Ja059914H  0.405
2004 van der Boom ME, Zubkov T, Shukla AD, Rybtchinski B, Shimon LJ, Rozenberg H, Ben-David Y, Milstein D. Self-oxidation of a phenolate complex to a bimetallic stilbene quinone. Angewandte Chemie (International Ed. in English). 43: 5961-3. PMID 15547905 DOI: 10.1002/Anie.200460360  0.587
2004 Dorta R, Dorta R, Shimon LJ, Milstein D. New ligand systems incorporating two and three 4,4'-bipyridine units. Characterization of bi- and trimetallic rhodium and iridium complexes. Inorganic Chemistry. 43: 7180-6. PMID 15500357 DOI: 10.1021/Ic049285X  0.476
2004 Poverenov E, Gandelman M, Shimon LJ, Rozenberg H, Ben-David Y, Milstein D. Nucleophilic de-coordination and electrophilic regeneration of "hemilabile" pincer-type complexes: formation of anionic dialkyl, diaryl, and dihydride Pt(II) complexes bearing no stabilizing pi-acceptors. Chemistry (Weinheim An Der Bergstrasse, Germany). 10: 4673-84. PMID 15372677 DOI: 10.1002/Chem.200400514  0.711
2004 Weissman H, Shimon LJW, Milstein D. Unsaturated Pd(0), Pd(I), and Pd(II) complexes of a new methoxy-substituted benzyl phosphine. Aryl-X (X = Cl, I) oxidative addition, C-O cleavage, and Suzuki-Miyaura coupling of aryl chlorides Organometallics. 23: 3931-3940. DOI: 10.1021/Om0497588  0.433
2004 Zhang J, Gandelman M, Shimon LJW, Rozenberg H, Milstein D. Electron-rich, bulky ruthenium PNP-type complexes. Acceptorless catalytic alcohol dehydrogenation Organometallics. 23: 4026-4033. DOI: 10.1021/Om049716J  0.699
2004 Dorta R, Shimon L, Milstein D. Rhodium complexes with chiral counterions: Achiral catalysts in chiral matrices Journal of Organometallic Chemistry. 689: 751-758. DOI: 10.1016/J.Jorganchem.2003.12.012  0.462
2004 Van Der Boom ME, Liou SY, Shimon LJW, Ben-David Y, Milstein D. Nickel promoted C-H, C-C and C-O bond activation in solution Inorganica Chimica Acta. 357: 4015-4023. DOI: 10.1016/J.Ica.2004.06.002  0.616
2004 Van Der Boom ME, Iron MA, Atasoylu O, Shimon LJW, Rozenberg H, Ben-David Y, Konstantinovski L, Martin JML, Milstein D. sp3 C-H and sp2 C-H agostic ruthenium complexes: A combined experimental and theoretical study Inorganica Chimica Acta. 357: 1854-1864. DOI: 10.1016/J.Ica.2003.11.014  0.673
2003 Vigalok A, Rybtchinski B, Gozin Y, Koblenz TS, Ben-David Y, Rozenberg H, Milstein D. Metal-stabilized phenoxonium cation. Journal of the American Chemical Society. 125: 15692-3. PMID 14677929 DOI: 10.1021/Ja0385639  0.675
2003 Dorta R, Rozenberg H, Shimon LJ, Milstein D. Dimethylsulfoxide as a ligand for RhI and IrI complexes--isolation, structure, and reactivity towards X-H bonds (X=H, OH, OCH3). Chemistry (Weinheim An Der Bergstrasse, Germany). 9: 5237-49. PMID 14613132 DOI: 10.1002/Chem.200305144  0.467
2003 Gandelman M, Shimon LJ, Milstein D. C-C versus C-H activation and versus agostic C-C interaction controlled by electron density at the metal center. Chemistry (Weinheim An Der Bergstrasse, Germany). 9: 4295-300. PMID 14502614 DOI: 10.1002/Chem.200304972  0.64
2003 Rybtchinski B, Cohen R, Ben-David Y, Martin JM, Milstein D. Aromatic vs aliphatic C-H bond activation by rhodium(I) as a function of agostic interactions: catalytic H/D exchange between olefins and methanol or water. Journal of the American Chemical Society. 125: 11041-50. PMID 12952486 DOI: 10.1021/Ja029197G  0.579
2003 Gandelman M, Konstantinovski L, Rozenberg H, Milstein D. Interplay between solvent and counteranion stabilization of highly unsaturated rhodium(III) complexes: facile unsaturation-induced dearomatization. Chemistry (Weinheim An Der Bergstrasse, Germany). 9: 2595-602. PMID 12794902 DOI: 10.1002/Chem.200204457  0.71
2003 Cohen R, Rybtchinski B, Gandelman M, Rozenberg H, Martin JM, Milstein D. Metallacarbenes from diazoalkanes: an experimental and computational study of the reaction mechanism. Journal of the American Chemical Society. 125: 6532-46. PMID 12785793 DOI: 10.1021/Ja028923C  0.777
2003 van der Boom ME, Milstein D. Cyclometalated phosphine-based pincer complexes: mechanistic insight in catalysis, coordination, and bond activation. Chemical Reviews. 103: 1759-92. PMID 12744693 DOI: 10.1021/Cr960118R  0.687
2003 Dorta R, Shimon LJ, Rozenberg H, Ben-David Y, Milstein D. A new ligand system based on a bipyridine-functionalized calix[4]arene backbone leading to mono- and bimetallic complexes. Inorganic Chemistry. 42: 3160-7. PMID 12739954 DOI: 10.1021/Ic020643A  0.505
2003 Cohen R, Rybtchinski B, Gandelman M, Shimon LJ, Martin JM, Milstein D. Novel azine reactivity: facile N-N bond cleavage, C-H activation, and N-N coupling mediated by RhI. Angewandte Chemie (International Ed. in English). 42: 1949-52. PMID 12730978 DOI: 10.1002/Anie.200250571  0.668
2003 Ben-Ari E, Gandelman M, Rozenberg H, Shimon LJ, Milstein D. Selective ortho C-h activation of haloarenes by an Ir(I) system. Journal of the American Chemical Society. 125: 4714-5. PMID 12696882 DOI: 10.1021/Ja028362P  0.757
2003 Milstein D. Challenging metal-based transformations. From single-bond activation to catalysis and metallaquinonoids Pure and Applied Chemistry. 75: 445-460. DOI: 10.1351/Pac200375040445  0.424
2003 Goikhman R, Aizenberg M, Shimon LJW, Milstein D. Iridium- and rhodium-silanol complexes: Synthesis and reactivity Organometallics. 22: 4020-4024. DOI: 10.1021/Om0300427  0.49
2003 Dorta R, Goikhman R, Milstein D. Reactivity of [Ir(COE)2(solvent)2]PF6 complexes toward alkylphosphines: Room-temperature C-H activation (cyclometalation) and isolation of a 14-electron alkyl-iridium(III) complex Organometallics. 22: 2806-2809. DOI: 10.1021/Om020997+  0.463
2003 Dorta R, Konstantinovski L, Shimon LJW, Ben-David Y, Milstein D. Chelation versus cyclometalation in a cationic Dppn-RhI complex - A unique rearrangement of norbornadiene via C-H activation of the pyridazine ring European Journal of Inorganic Chemistry. 70-76. DOI: 10.1002/Ejic.200390015  0.419
2002 Blum O, Milstein D. Oxidative addition of water and aliphatic alcohols by IrCl(trialkylphosphine)(3). Journal of the American Chemical Society. 124: 11456-67. PMID 12236760 DOI: 10.1021/Ja012611C  0.418
2002 Dorta R, Rozenberg H, Milstein D. The first fully characterized neutral and cationic rhodium(I)-complexes containing DMSO as the only dative ligand; S-, O- and bridging S,O-bidentate binding modes. Chemical Communications (Cambridge, England). 710-1. PMID 12119685 DOI: 10.1039/B200321J  0.344
2002 Dorta R, Rozenberg H, Shimon LJ, Milstein D. Oxidative addition of water to novel Ir(I) complexes stabilized by dimethyl sulfoxide ligands. Journal of the American Chemical Society. 124: 188-9. PMID 11782167 DOI: 10.1021/Ja016625U  0.467
2002 Goikhman R, Aizenberg M, Ben-David Y, Shimon LJW, Milstein D. New Tridentate Phosphine Rhodium and Iridium Complexes, Including a Stable Rhodium(I) Silyl. Si−S Activation and a Strong Effect of X in (PP2)M−X (X = H, Cl, Me) on Si−H Activation Organometallics. 21: 5060-5065. DOI: 10.1021/Om020120A  0.463
2002 Hermann D, Gandelman M, Rozenberg H, Shimon LJW, Milstein D. Synthesis, structure, and reactivity of new rhodium and iridium complexes, bearing a highly electron-donating PNP system. Iridium-mediated vinylic C-H bond activation Organometallics. 21: 812-818. DOI: 10.1021/Om010719V  0.668
2002 Dorta R, Shimon LJW, Rozenberg H, Milstein D. Facile oxidative addition of C-Cl bonds to new neutral and cationic rhodium(I)-bipyridine complexes European Journal of Inorganic Chemistry. 1827-1834. DOI: 10.1002/1099-0682(200207)2002:7<1827::Aid-Ejic1827>3.0.Co;2-Q  0.482
2001 Albéniz AC, Espinet P, Martín-Ruiz B, Milstein D. Catalytic system for Heck reactions involving insertion into Pd-(perfluoro-organyl) bonds. Journal of the American Chemical Society. 123: 11504-11505. PMID 11707139 DOI: 10.1021/Ja016315B  0.355
2001 Vigalok A, Milstein D. Advances in metal chemistry of quinonoid compounds: new types of interactions between metals and aromatics. Accounts of Chemical Research. 34: 798-807. PMID 11601964 DOI: 10.1021/Ar970316K  0.694
2001 Rybtchinski B, Oevers S, Montag M, Vigalok A, Rozenberg H, Martin JM, Milstein D. Comparison of steric and electronic requirements for C-C and C-H bond activation. Chelating vs nonchelating case. Journal of the American Chemical Society. 123: 9064-77. PMID 11552814 DOI: 10.1021/Ja016126T  0.808
2001 Gandelman M, Rybtchinski B, Ashkenazi N, Gauvin RM, Milstein D. A new general method for the preparation of metal carbene complexes. Journal of the American Chemical Society. 123: 5372-3. PMID 11457410 DOI: 10.1021/Ja0157393  0.644
2001 Goikhman R, Milstein D. Ligand-Controlled Chemoselectivity in the Classical Oxidative Addition Reactions of MeI and Aldehydes to Rhodium(I) Complexes This work was supported by the Israel Science Foundation, Jerusalem, Israel, by the MINERVA foundation, Munich, Germany, and by the Tashtiyot program of the Israeli Ministry of Science. D.M. is the holder of the Israel Matz Professorial Chair of Organic Chemistry. We thank Dr. L. Shimon and Dr. H. Rozenberg, Weizmann Institute of Science, for performing the X-ray structural analysis. Angewandte Chemie (International Ed. in English). 40: 1119-1122. PMID 11268095 DOI: 10.1002/1521-3773(20010316)40:6<1119::Aid-Anie11190>3.0.Co;2-N  0.353
2001 Kraatz H, van der Boom ME, Ben-David Y, Milstein D. Reaction of Aryl Iodides with (PCP)Pd(II)-Alkyl and Aryl Complexes: Mechanistic Aspects of Carbon-Carbon Bond Formation Israel Journal of Chemistry. 41: 163-172. DOI: 10.1560/V0Q8-T3Xm-N68W-D8Nl  0.574
2001 Gauvin RM, Rozenberg H, Shimon LJW, Milstein D. Synthesis and Structure of New Osmium−PCP Complexes. Osmium-Mediated C−C Bond Activation Organometallics. 20: 1719-1724. DOI: 10.1021/Om000878Z  0.434
2000 Rybtchinski B, Konstantinovsky L, Shimon LJ, Vigalok A, Milstein D. Solvent-stabilized alkylrhodium(III) hydride complexes: a special mode of reversible C-H bond elimination involving an agostic intermediate Chemistry (Weinheim An Der Bergstrasse, Germany). 6: 3287-92. PMID 11003007 DOI: 10.1002/1521-3765(20000901)6:17<3287::Aid-Chem3287>3.0.Co;2-J  0.729
2000 Rabin O, Vigalok A, Milstein D. A novel approach towards intermolecular stabilization of para-quinone methides. First complexation of the elusive, simplest quinone methide, 4-methylene-2,5-cyclohexadien-1-one Chemistry (Weinheim An Der Bergstrasse, Germany). 6: 454-62. PMID 10747411 DOI: 10.1002/(Sici)1521-3765(20000204)6:3<454::Aid-Chem454>3.0.Co;2-Q  0.718
2000 Blum J, Berlin O, Milstein D, Ben-David Y, Wassermann BC, Schutte S, Schumann H. Palladium-catalyzed cross-methylation of aryl chlorides by stabilized dimethylaluminium and -gallium reagents Synthesis. 571-575. DOI: 10.1055/S-2000-6373  0.513
2000 Gandelman M, Milstein D. Homogeneously catalyzed, chelate assisted hydrogenolysis of an amine C–N bond Chemical Communications. 1603-1604. DOI: 10.1039/B004820H  0.666
2000 Vigalok A, Milstein D. Methyl-to-double bond migration in methylene arenium rhodium complexes Organometallics. 19: 2341-2345. DOI: 10.1021/Om990966N  0.713
2000 Vigalok A, Milstein D. Direct Synthesis of Thermally Stable PCP-Type Rhodium Carbenes Organometallics. 19: 2061-2064. DOI: 10.1021/Om990764R  0.727
2000 Gandelman M, Vigalok A, Konstantinovski L, Milstein D. The first observation and kinetic evaluation of a single step metal insertion into a C-C bond [7] Journal of the American Chemical Society. 122: 9848-9849. DOI: 10.1021/Ja993108R  0.737
2000 Ashkenazi N, Vigalok A, Parthiban S, Ben-David Y, Shimon LJW, Martin JML, Milstein D. Discovery of the first metallaquinone [11] Journal of the American Chemical Society. 122: 8797-8798. DOI: 10.1021/Ja001759D  0.564
2000 Sundermann A, Uzan O, Milstein D, Martin JML. Selective C−C vs C−H Bond Activation by Rhodium(I) PCP Pincer Complexes. A Computational Study Journal of the American Chemical Society. 122: 7095-7104. DOI: 10.1021/Ja000943W  0.415
2000 Cohen R, Van Der Boom ME, Shimon LJW, Rozenberg H, Milstein D. The methylene-transfer reaction: Synthetic and mechanistic aspects of a unique C-C coupling and C-C bond activation sequence Journal of the American Chemical Society. 122: 7723-7734. DOI: 10.1021/Ja000157R  0.646
2000 Blum O, Milstein D. Hydride elimination from an iridium(III) alkoxide complex: a case in which a vacant cis coordination site is not required Journal of Organometallic Chemistry. 593: 479-484. DOI: 10.1016/S0022-328X(99)00619-1  0.388
1999 Rybtchinski B, Milstein D. Metal Insertion into C-C Bonds in Solution. Angewandte Chemie (International Ed. in English). 38: 870-883. PMID 29711873 DOI: 10.1002/(Sici)1521-3773(19990401)38:7<870::Aid-Anie870>3.0.Co;2-3  0.354
1999 Weissman H, Milstein D. Highly active PdII cyclometallated imine catalyst for the Suzuki reaction Chemical Communications. 1901-1902. DOI: 10.1039/A906246G  0.393
1999 Ohff M, Ohff A, Milstein D. Highly active PdII cyclometallated imine catalysts for the Heck reaction Chemical Communications. 357-358. DOI: 10.1039/A809883B  0.39
1999 van der Boom ME, Kraatz H, Hassner L, Ben-David Y, Milstein D. Carbon−Carbon vs Carbon−Hydrogen Bond Activation by Ruthenium(II) and Platinum(II) in Solution Organometallics. 18: 3873-3884. DOI: 10.1021/Om990282F  0.565
1999 Boom MEvd, Higgitt aCL, Milstein D. Directly Observed β-H Elimination of Unsaturated PCP-Based Rhodium(III)−Alkyl Complexes Organometallics. 18: 2413-2419. DOI: 10.1021/Om990073V  0.428
1999 Vigalok A, Rybtchinski B, Shimon LJW, Ben-David Y, Milstein D. Metal-Stabilized Methylene Arenium and σ-Arenium Compounds: Synthesis, Structure, Reactivity, Charge Distribution, and Interconversion Organometallics. 18: 895-905. DOI: 10.1021/Om980960I  0.684
1999 Van Der Boom ME, Ben-David Y, Milstein D. Formation of difluoromethylene-arenium complexes by consecutive Aryl- CF3 C-C bond activation and C-F bond cleavage Journal of the American Chemical Society. 121: 6652-6656. DOI: 10.1021/Ja990779G  0.639
1999 Rybtchinski B, Milstein D. Solvent-controlled selectivity toward exclusive C-C or C-H bond activation by a cationic metal center Journal of the American Chemical Society. 121: 4528-4529. DOI: 10.1021/Ja990339P  0.354
1998 Liou S, Boom MEvd, Milstein D. Catalytic selective cleavage of a strong C–C single bond by rhodium in solution Chemical Communications. 687-688. DOI: 10.1039/A800537K  0.415
1998 Boom MEvd, Ott J, Milstein D. Exclusive C-Si bond formation upon reaction of a platinum(II) alkyl with silanes Organometallics. 17: 4263-4266. DOI: 10.1021/Om9802818  0.487
1998 Vigalok A, Uzan O, Shimon LJW, Ben-David Y, Martin JML, Milstein D. Formation of η2 C-H agostic rhodium arene complexes and their relevance to electrophilic bond activation Journal of the American Chemical Society. 120: 12539-12544. DOI: 10.1021/Ja982534U  0.721
1998 Van Der Boom ME, Liou SY, Ben-David Y, Gozin M, Milstein D. Carbon-carbon bond activation by Rhodium(I) in solution. Comparison of sp2-sp3 vs sp3-sp3 C-C, C-H vs C-C, and Ar-CH3 vs Ar-CH2CH3 activation Journal of the American Chemical Society. 120: 13415-13421. DOI: 10.1021/Ja982345B  0.764
1998 Rabin O, Vigalok A, Milstein D. Metal-mediated generation, stabilization, and controlled release of a biologically relevant, simple para quinone methide: BHT-QM [10] Journal of the American Chemical Society. 120: 7119-7120. DOI: 10.1021/Ja9809612  0.609
1998 Van Der Boom ME, Liou SY, Ben-David Y, Shimon LJW, Milstein D. Alkyl- and aryl-oxygen bond activation in solution by rhodium(I), palladium(II), and nickel(II). Transition-metal-based selectivity Journal of the American Chemical Society. 120: 6531-6541. DOI: 10.1021/Ja9738889  0.677
1998 Aizenberg M, Ott J, Elsevier CJ, Milstein D. Rh(I) and Rh(III) silyl PMe3 complexes. Syntheses, reactions and 103Rh NMR spectroscopy Journal of Organometallic Chemistry. 551: 81-92. DOI: 10.1016/S0022-328X(97)00433-6  0.41
1997 Vigalok A, Kraatz HB, Konstantinovsky L, Milstein D. Evidence for Direct trans Insertion in a Hydrido-Olefin Rhodium Complex-Free Nitrogen as a Trap in a Migratory Insertion Process. Chemistry (Weinheim An Der Bergstrasse, Germany). 3: 253-60. PMID 24022956 DOI: 10.1002/Chem.19970030214  0.739
1997 Töllner K, Popovitz-Biro R, Lahav M, Milstein D. Impact of Molecular Order in Langmuir-Blodgett Films on Catalysis Science. 278: 2100-2102. PMID 9405341 DOI: 10.1126/Science.278.5346.2100  0.42
1997 Gandelman M, Vigalok A, Shimon LJW, Milstein D. A PCN Ligand System. Exclusive C−C Activation with Rhodium(I) and C−H Activation with Platinum(II) Organometallics. 16: 3981-3986. DOI: 10.1021/Om9703200  0.756
1997 Rybtchinski B, Ben-David Y, Milstein D. Unexpected Isomerization Of A Cis- Into A Trans-Dihydride Complex. A Neutral Late Transition Metal Complex As A Hydride Donor Organometallics. 16: 3786-3793. DOI: 10.1021/Om970104R  0.469
1997 Ohff M, Ohff A, Van der Boom ME, Milstein D. Highly active Pd(II) PCP-type catalysts for the Heck reaction Journal of the American Chemical Society. 119: 11687-11688. DOI: 10.1021/Ja9729692  0.598
1997 Vigalok A, Milstein D. Metal-stabilized quinone and thioquinone methides Journal of the American Chemical Society. 119: 7873-7874. DOI: 10.1021/Ja970795I  0.613
1997 Boom MEvd, Liou S, Ben‐David Y, Vigalok A, Milstein D. Selective Activation Of Alkyl- And Aryl-Oxygen Single Bonds In Solution With Transition Metal Complexes Angewandte Chemie. 36: 625-626. DOI: 10.1002/Anie.199706251  0.683
1997 Van Der Boom ME, Liou S, Ben-David Y, Vigalok A, Milstein D. Selektive Aktivierung von Alkyl- und Aryl-Sauerstoff-Einfachbindungen in Lösung mit Übergangsmetallkomplexen Angewandte Chemie. 109: 636-637. DOI: 10.1002/Ange.19971090617  0.658
1996 van Der Boom ME, Gozin M, Ben-David Y, Shimon LJ, Frolow F, Kraatz HB, Milstein D. Formation and X-ray Structures of PCP Ligand Based Platinum(II) and Palladium(II) Macrocycles. Inorganic Chemistry. 35: 7068-7073. PMID 11666888 DOI: 10.1021/Ic960285+  0.734
1996 Boom MEvd, Kraatz H, Ben-David Y, Milstein D. Activation of a non-strained C–C bond with plantinum(II) Chemical Communications. 2167-2168. DOI: 10.1039/Cc9960002167  0.575
1996 Vigalok A, Shimon LJW, Milstein D. A unique dioxo alkene hydride metal complex: [RhH(O2){CH2C(CH2CH2PBut2)2}] Chemical Communications. 1673-1674. DOI: 10.1039/Cc9960001673  0.715
1996 Aizenberg M, Milstein D. Reversible Cyclometalation of Silyl Ligands. First X-ray Structure of an Iridium(I) Silyl That Is Not Stabilized by Chelation Organometallics. 15: 3317-3322. DOI: 10.1021/Om960214I  0.478
1996 Boom MEVD, Liou SY, Shimon LJW, Ben-David Y, Milstein D. Consecutive cyclometalation by platinum(II) Organometallics. 15: 2562-2568. DOI: 10.1021/Om9600452  0.412
1996 Vigalok A, Ben-David Y, Milstein D. Complexation of N2, H2, CO2, and Ethylene to a T-Shaped Rhodium(I) Core Organometallics. 15: 1839-1844. DOI: 10.1021/Om950830Z  0.69
1996 Aizenberg M, Goikhman R, Milstein D. Metal-dependent stabilization of Si-S bonds to hydrolysis in iridium and rhodium silyls. Hydrolyzability as a probe for Si-H reductive elimination Organometallics. 15: 1075-1078. DOI: 10.1021/Om950791R  0.389
1996 Rybtchinski B, Vigalok A, Ben-David Y, Milstein D. A room temperature direct metal insertion into a nonstrained carbon-carbon bond in solution. C-C vs C-H bond activation Journal of the American Chemical Society. 118: 12406-12415. DOI: 10.1021/Ja962253R  0.646
1996 Weisman A, Gozin M, Kraatz H, Milstein D. Rhodium and Palladium Complexes of a 3,5-Lutidine-Based Phosphine Ligand Inorganic Chemistry. 35: 1792-1797. DOI: 10.1021/Ic951131H  0.752
1995 Liou SY, Gozin M, Milstein D. Carbon–carbon activation by rhodium in solution; sp2–sp3 is preferred over sp3–sp3 bond cleavage Journal of the Chemical Society, Chemical Communications. 1965-1966. DOI: 10.1039/C39950001965  0.71
1995 Liou S, Gozin M, Milstein D. Directly Observed Oxidative Addition of a Strong Carbon-Carbon Bond to a Soluble Metal Complex Journal of the American Chemical Society. 117: 9774-9775. DOI: 10.1021/Ja00143A028  0.644
1995 Aizenberg M, Milstein D. Homogeneous Metal-Catalyzed Hydrogenolysis Of C-F Bonds Journal of the American Chemical Society. 117: 8674-8675. DOI: 10.1021/Ja00138A027  0.339
1995 Aizenberg M, Milstein D. Facial (methyl)(hydrido)(silyl) Complexes of Iridium: Synthesis, X-ray Structures, and Reductive Elimination Reactions. Facile Formation of Silametalacycles by Metalation of Silyl Ligands Journal of the American Chemical Society. 117: 6456-6464. DOI: 10.1021/Ja00129A007  0.446
1995 Goikhman R, Aizenberg M, Kraatz H, Milstein D. Iridium-Silanol Complexes from Direct Oxidative Addition of Silanols to Ir(I). Synthesis and X-ray Structure of the First Metallosilanolate [(Et3P)2Ir(H)(Cl)(SiiPr2OLi)]2 Journal of the American Chemical Society. 117: 5865-5866. DOI: 10.1021/Ja00126A032  0.569
1995 Blum O, Milstein D. Mechanism of a Directly Observed Beta-Hydride Elimination Process of Iridium Alkoxo Complexes Journal of the American Chemical Society. 117: 4582-4594. DOI: 10.1021/Ja00121A016  0.316
1995 Moshe P, Ben-David Y, Milstein D. Formation of P,C-chelated palladium complexes by phosphine-assisted oxidative addition of an aliphatic CCl bond Journal of Organometallic Chemistry. 503: 149-153. DOI: 10.1016/0022-328X(95)05544-Y  0.506
1995 Kraatz H, Milstein D. The reactions of tridentate cationic palladium(II) complexes with olefins and nucleophiles Journal of Organometallic Chemistry. 488: 223-232. DOI: 10.1016/0022-328X(94)00027-A  0.593
1995 Blum O, Milstein D. Direct Observation of OH Reductive Elimination from IrIII Complexes Angewandte Chemie. 34: 229-231. DOI: 10.1002/Anie.199502291  0.432
1994 Aizenberg M, Milstein D. Catalytic activation of carbon-fluorine bonds by a soluble transition metal complex. Science. 265: 359-361. PMID 17838035 DOI: 10.1126/Science.265.5170.359  0.466
1994 Aizenberg M, Milstein D. Electrophilic ligand abstraction from electron-rich iridium(I) complexes with Me3SiOTf; evidence for direct ligand attack Journal of the Chemical Society, Chemical Communications. 411-412. DOI: 10.1039/C39940000411  0.411
1994 Gozin M, Aizenberg M, Liou S, Weisman A, Ben-David Y, Milstein D. Transfer of methylene groups promoted by metal complexation Nature. 370: 42-44. DOI: 10.1038/370042A0  0.689
1994 Portnoy M, Ben-David Y, Rousso I, Milstein D. Reactions of electron-rich arylpalladium complexes with olefins. Origin of the chelate effect in vinylation catalysis Organometallics. 13: 3465-3479. DOI: 10.1021/Om00021A021  0.768
1994 Portnoy M, Milstein D. A binuclear palladium(I) hydride. Formation, reactions, and catalysis Organometallics. 13: 600-609. DOI: 10.1021/Om00014A035  0.749
1994 Aizenberg M, Milstein D. Competitive generation of C-H and C-Si bonds by reductive elimination: Formation of silametallacycles by metalation of silyl ligands Angewandte Chemie. 33: 317-319. DOI: 10.1002/Anie.199403171  0.397
1993 Schulz M, Milstein D. N–Hvis. C–H activation; a major ligand size effect Journal of the Chemical Society, Chemical Communications. 318-319. DOI: 10.1039/C39930000318  0.428
1993 Gozin M, Weisman A, Ben-David Y, Milstein D. Activation of a carbon–carbon bond in solution by transition-metal insertion Nature. 364: 699-701. DOI: 10.1038/364699A0  0.681
1993 Portnoy M, Ben-David Y, Milstein D. Clarification of a remarkable chelate effect leads to palladium-catalyzed base-free olefin arylation Organometallics. 12: 4734-4735. DOI: 10.1021/Om00036A008  0.763
1993 Portnoy M, Milstein D. Mechanism of aryl chloride oxidative addition to chelated palladium(0) complexes Organometallics. 12: 1665-1673. DOI: 10.1021/Om00029A026  0.767
1993 Portnoy M, Milstein D. Chelate effect on the structure and reactivity of electron-rich palladium complexes and its relevance to catalysis Organometallics. 12: 1655-1664. DOI: 10.1021/Om00029A025  0.753
1993 Burdeniuk J, Milstein D. Polarizable stilbazole-based organometallic complexes and polymers Journal of Organometallic Chemistry. 451: 213-220. DOI: 10.1016/0022-328X(93)83028-T  0.424
1992 Ben-David Y, Portnoy M, Gozin M, Milstein D. Palladium-catalyzed vinylation of aryl chlorides. Chelate effect in catalysis Organometallics. 11: 1995-1996. DOI: 10.1021/Om00042A008  0.831
1992 Ben-David Y, Gozin M, Portnoy M, Milstein D. Reductive dechlorination of aryl chlorides catalyzed by palladium complexes containing basic, chelating phosphines Journal of Molecular Catalysis. 73: 173-180. DOI: 10.1016/0304-5102(92)80070-W  0.822
1991 Blum O, Frolow F, Milstein D. C–F bond activation by iridium(I). A unique process involving P–C bond cleavage, P–F bond formation and net retention of oxidation state Journal of the Chemical Society, Chemical Communications. 258-259. DOI: 10.1039/C39910000258  0.388
1991 Portnoy M, Frolow F, Milstein D. Methanol reduces an organopalladium(II) complex to a palladium(I) hydride. Crystallographic characterization of a hydrido-bridged palladium complex Organometallics. 10: 3960-3962. DOI: 10.1021/Om00058A007  0.781
1991 Koelliker R, Milstein D. Evidence for an unprecedented Ir(H)(NH3) ⇄ Ir(H2)(NH2) equilibrium and hydrogen exchange between NH and CH bonds Journal of the American Chemical Society. 113: 8524-8525. DOI: 10.1021/Ja00022A051  0.351
1990 Stevens RC, Bau R, Milstein D, Blum O, Koetzle TF. Concept of the H(δ+) ⋯ H(δ-) interaction. A low-temperature neutron diffraction study of cis-[IrH(OH)(PMe3)4]PF6 Journal of the Chemical Society, Dalton Transactions. 1429-1432. DOI: 10.1039/Dt9900001429  0.363
1990 Patchornik A, Ben-David Y, Milstein D. 'Caging' of and catalysis by a complex inside a polymer matrix Journal of the Chemical Society, Chemical Communications. 1090-1091. DOI: 10.1039/C39900001090  0.34
1990 Zlota AA, Frolow F, Milstein D. Formation of iridalactones by CH2-O oxidative addition of propiolactone to iridium(I) Organometallics. 9: 1300-1302. DOI: 10.1021/Om00118A063  0.375
1990 Zlota AA, Frolow F, Milstein D. Synthesis and x-ray structure of a simple metallaoxetane. Metal-based selectivity in oxidative addition Journal of the American Chemical Society. 112: 6411-6413. DOI: 10.1021/Ja00173A047  0.428
1989 Zlota AA, Frolow F, Milstein D. Oxidative addition of Si–Cl bonds to electron-rich IrI complexes Journal of the Chemical Society, Chemical Communications. 1826-1827. DOI: 10.1039/C39890001826  0.464
1989 Ben-David Y, Portnoy M, Milstein D. Formylation of aryl chlorides catalysed by a palladium complex Journal of the Chemical Society, Chemical Communications. 1816-1817. DOI: 10.1039/C39890001816  0.781
1989 Ben-David Y, Portnoy M, Milstein D. Chelate-assisted, Pd-catalyzed efficient carbonylation of aryl chlorides Journal of the American Chemical Society. 111: 8742-8744. DOI: 10.1021/Ja00205A039  0.717
1988 Marder TB, Chan DM-, Fultz WC, Milstein D. Synthesis and molecular structures of a rhoda-lactone and its alkylation product; insertion of a pendant alkyne into a rhodium–hydrogen bond Journal of the Chemical Society, Chemical Communications. 996-998. DOI: 10.1039/C39880000996  0.446
1988 Marder TB, Roe DC, Milstein D. Transition-metal-catalyzed carbon-carbon bond formation via carbon-hydrogen activation. Intermolecular hydroacylation: the addition of aldehydes to alkenes Organometallics. 7: 1451-1453. DOI: 10.1021/Om00096A037  0.325
1988 Casalnuovo AL, Calabrese JC, Milstein D. Rational design in homogeneous catalysis. Iridium(I)-catalyzed addition of aniline to norbornylene via nitrogen-hydrogen activation Journal of the American Chemical Society. 110: 6738-6744. DOI: 10.1021/Ja00228A022  0.356
1988 Milstein D. Aspects of intermediacy of carbalkoxymetal complexes in carbon monoxide reactions Accounts of Chemical Research. 21: 428-434. DOI: 10.1021/Ar00155A007  0.378
1987 Marder TB, Chan DM-, Fultz WC, Calabrese JC, Milstein D. Mechanistic studies of the rhodium-catalysed cyclization of α,ω-alkynoci acids to alkylidene lactones. Crystals structures of two iridium model catalytic intermediates Journal of the Chemical Society, Chemical Communications. 1885-1887. DOI: 10.1039/C39870001885  0.304
1987 Marder TB, Fultz WC, Calabrese JC, Harlow RL, Milstein D. Activation of dichloromethane by basic rhodium(I) and iridium(I) phosphine complexes. Synthesis and structures of fac-[Rh(PMe3)3Cl2(CH2PMe3)]Cl·CH2Cl2 and trans-[Rh(Me2PCH2CH2PMe2)2Cl(CH2Cl)]Cl Journal of the Chemical Society, Chemical Communications. 1543-1545. DOI: 10.1039/C39870001543  0.467
1987 Marder TB, Zargarian D, Calabrese JC, Herskovitz TH, Milstein D. C-H rather than O-H activation: Synthesis and molecular structure of a cationic cis-hydrido-σ-acetylide complex of rhodium Journal of the Chemical Society, Chemical Communications. 1484-1485. DOI: 10.1039/C39870001484  0.391
1987 Chan DMT, Marder TB, Milstein D, Taylor NJ. Transition-metal-catalyzed cyclization of alkynoic acids to alkylidene lactones Journal of the American Chemical Society. 109: 6385-6388. DOI: 10.1021/Ja00255A025  0.305
1987 Casalnuovo AL, Calabrese JC, Milstein D. Nitrogen-hydrogen activation. 1. Oxidative addition of ammonia to iridium(I). Isolation, structural characterization and reactivity of amidoiridium hydrides Inorganic Chemistry. 26: 971-973. DOI: 10.1021/Ic00254A001  0.376
1986 Milstein D. The product-forming step in palladium-catalysed methoxycarbonylation of organic halides Journal of the Chemical Society, Chemical Communications. 817-818. DOI: 10.1039/C39860000817  0.396
1986 Milstein D, Calabrese JC, Williams ID. Formation, structures, and reactivity of cis-hydroxy-, cis-methoxy-, and cis-mercaptoiridium hydrides. Oxidative addition of water to Ir(I) Journal of the American Chemical Society. 108: 6387-6389. DOI: 10.1021/Ja00280A045  0.433
1986 Milstein D. C-H vs. O-H reductive elimination of methanol from a metal complex. Which is a more likely process? Journal of the American Chemical Society. 108: 3525-3526. DOI: 10.1021/Ja00272A067  0.405
1986 Milstein D, Fultz WC, Calabrese JC. (Hydroxyacetyl)iridium and -rhodium complexes: model compounds for CO hydrogenation Journal of the American Chemical Society. 108: 1336-1338. DOI: 10.1021/Ja00266A056  0.495
1986 Milstein D. Hexamethylenetetramine formation by Ru-catalyzed methanol hydrogen transfer Journal of Molecular Catalysis. 36: 387-389. DOI: 10.1016/0304-5102(86)85094-5  0.416
1983 Lin YC, Milstein D, Wreford SS. Isolation and chemical properties of ruthenium and iron hydroxymethyl complexes (η5-C5H5)M(CO)2CH2OH Organometallics. 2: 1461-1463. DOI: 10.1021/Om50004A039  0.346
1983 Milstein D, Huckaby JL. Cobalt-Catalyzed Carbalkoxylation Of Olefins: A New Mechanism Cheminform. 14. DOI: 10.1002/Chin.198305127  0.318
1982 Milstein D. Isolation and direct observation of intramolecular hydroacylation of a cis-hydridopent-4-enoylrhodium(III) complex Journal of the Chemical Society, Chemical Communications. 1357-1358. DOI: 10.1039/C39820001357  0.364
1982 Milstein D. Isolation of cis-hydridoacylrhodium(III) complexes not stabilized by chelation. Reductive elimination and decarbonylation Organometallics. 1: 1549-1551. DOI: 10.1021/Om00071A033  0.36
1982 Milstein D, Huckaby JL. Cobalt-catalyzed carbalkoxylation of olefins: a new mechanism Journal of the American Chemical Society. 104: 6150-6152. DOI: 10.1021/Ja00386A068  0.318
1982 Milstein D. The first isolated, stable cis-hydridoalkylrhodium complexes and their reductive elimination reaction Journal of the American Chemical Society. 104: 5227-5228. DOI: 10.1021/Ja00383A039  0.392
1982 Milstein D, Calabrese JC. Oxidative addition of unactivated epoxides to iridium(I) complexes. Formation of stable cis-hydridoformylmethyl and -acylmethyl complexes Journal of the American Chemical Society. 104: 3773-3774. DOI: 10.1021/Ja00377A062  0.409
1982 Milstein D. The First Isolated, Stable Cis-Hydridoalkylrhodium Complexes And Their Reductive Elimination Reaction Cheminform. 13. DOI: 10.1002/Chin.198252309  0.392
1982 Milstein D, Calabrese JC. Oxidative addition of unactivated epoxides to iridium(I) complexes. Formation of stable cis-hydridoformylmethyl and -acylmethyl complexes Cheminform. 13. DOI: 10.1002/Chin.198242325  0.398
1979 Milstein D, Stille JK. Palladium-catalyzed coupling of tetraorganotin compounds with aryl and benzyl halides. Synthetic utility and mechanism Journal of the American Chemical Society. 10: 4992-4998. DOI: 10.1021/Ja00511A032  0.414
1979 Milstein D, Stille JK. Mechanism of reductive elimination. Reaction of alkylpalladium(II) complexes with tetraorganotin, organolithium, and Grignard reagents. Evidence for palladium(IV) intermediacy Journal of the American Chemical Society. 101: 4981-4991. DOI: 10.1021/Ja00511A031  0.628
1979 Milstein D, Stille JK. Mild, selective, general method of ketone synthesis from acid chlorides and organotin compounds catalyzed by palladium Journal of Organic Chemistry. 44: 1613-1618. DOI: 10.1002/Chin.197937184  0.559
1978 Blum J, Zinger B, Milstein D, Buchman O. Dimerization of terminal epoxides by homogeneous transition-metal complexes. A novel synthesis of carboxylic esters Journal of Organic Chemistry. 43: 2961-2967. DOI: 10.1021/Jo00409A006  0.581
1978 Milstein D, Stille JK. A general, selective, and facile method for ketone synthesis from acid chlorides and organotin compounds catalyzed by palladium Journal of the American Chemical Society. 100: 3636-3638. DOI: 10.1021/Ja00479A077  0.32
1978 Blum J, Zinger B, Milstein D, Buchman O. Dimerization Of Terminal Epoxides By Homogeneous Transition Metal Complexes. A Novel Synthesis Of Carboxylic Esters Cheminform. 9. DOI: 10.1002/Chin.197848187  0.557
1978 Milstein D, Stille JK. A General, Selective, And Facile Method For Ketone Synthesis From Acid Chlorides And Organotin Compounds Catalyzed By Palladium Cheminform. 9. DOI: 10.1002/Chin.197836145  0.32
1977 Milstein D, Buchman O, Blum J. Selective transformation of vicinal-disubstituted epoxides into ketones by homogeneous rhodium catalysts Journal of Organic Chemistry. 42: 2299-2308. DOI: 10.1021/Jo00433A023  0.514
1977 Milstein D, Buchman O, Blum J. Selective Transformation Of Vicinal-Disubstituted Epoxides Into Ketones By Homogeneous Rhodium Catalysts Cheminform. 8. DOI: 10.1002/Chin.197743144  0.514
1970 Blum J, Milstein D, Sasson Y. Catalytic transformation of benzoic anhydrides into fluorenones and biphenyls The Journal of Organic Chemistry. 35: 3233-3237. DOI: 10.1021/Jo00835A010  0.595
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