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Hendrik Klare - Publications

Affiliations: 
2007-2011 Westfälische Wilhelms-Universität Münster, Münster, Nordrhein-Westfalen, Germany 
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63 high-probability publications. We are testing a new system for linking publications to authors. You can help! If you notice any inaccuracies, please sign in and mark papers as correct or incorrect matches. If you identify any major omissions or other inaccuracies in the publication list, please let us know.

Year Citation  Score
2024 Zuo H, Klare HFT, Irran E, Oestreich M. Electrophilic Activation of S-Si Reagents by Silylium Ions for Their Regio- and Diastereoselective Addition Across C-C Multiple Bonds. Angewandte Chemie (International Ed. in English). e202401599. PMID 38323886 DOI: 10.1002/anie.202401599  0.826
2023 Jiang HJ, Zuo H, Zhu M, Sharanov I, Irran E, Klare HFT, Tshepelevitsh S, Lõkov M, Leito I, Oestreich M. Chiral Carborane Acids Decorated with Binol-Based Phosphonates: Synthesis, Characterization, and Application. The Journal of Organic Chemistry. 89: 756-760. PMID 38109189 DOI: 10.1021/acs.joc.3c02162  0.768
2023 He T, Klare HFT, Oestreich M. Arenium-ion-catalysed halodealkylation of fully alkylated silanes. Nature. 623: 538-543. PMID 37821704 DOI: 10.1038/s41586-023-06646-9  0.65
2023 Zuo H, Klare HFT, Oestreich M. Intramolecular 7---Selective Carbosilylation of Internal Alkynes Involving Silylium-Ion Regeneration. The Journal of Organic Chemistry. 88: 4024-4027. PMID 36881803 DOI: 10.1021/acs.joc.3c00261  0.826
2023 He T, Klare HFT, Oestreich M. Catalytically Generated Meerwein's Salt-Type Oxonium Ions for Friedel-Crafts C(sp)-H Methylation with Methanol. Journal of the American Chemical Society. PMID 36724501 DOI: 10.1021/jacs.2c13341  0.648
2023 Rej S, Klare HFT, Oestreich M. The [3]Dendralene Motif as an Entry into Nazarov Cyclizations by Silylium-Ion Initiation. Organic Letters. 25: 426-431. PMID 36603195 DOI: 10.1021/acs.orglett.2c04166  0.823
2022 He T, Qu ZW, Klare HFT, Grimme S, Oestreich M. Intermolecular Carbosilylation of α-Olefins with C(sp3)-C(sp) Bond Formation Involving Silylium-Ion Regeneration. Angewandte Chemie (International Ed. in English). PMID 35344257 DOI: 10.1002/anie.202203347  0.66
2022 He T, Klare HFT, Oestreich M. Perdeuteration of Deactivated Aryl Halides by H/D Exchange under Superelectrophile Catalysis. Journal of the American Chemical Society. PMID 35258291 DOI: 10.1021/jacs.2c00080  0.577
2022 Rej S, Klare HFT, Oestreich M. Silylium-Ion-Promoted Hydrosilylation of Aryl-Substituted Allenes: Interception by Cyclization of the Allyl-Cation Intermediate. Organic Letters. 24: 1346-1350. PMID 35113570 DOI: 10.1021/acs.orglett.2c00011  0.81
2021 Gao H, Müller R, Irran E, Klare HFT, Kaupp M, Oestreich M. Competition for Hydride between Silicon and Boron: Synthesis and Characterization of a Hydroborane-Stabilized Silylium Ion. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 34918852 DOI: 10.1002/chem.202104464  0.828
2021 Klare HFT, Oestreich M. The Power of the Proton: From Superacidic Media to Superelectrophile Catalysis. Journal of the American Chemical Society. PMID 34520196 DOI: 10.1021/jacs.1c07614  0.485
2021 Klare HFT, Albers L, Süsse L, Keess S, Müller T, Oestreich M. Silylium Ions: From Elusive Reactive Intermediates to Potent Catalysts. Chemical Reviews. PMID 33861564 DOI: 10.1021/acs.chemrev.0c00855  0.784
2020 He T, Wang G, Long PW, Kemper S, Irran E, Klare HFT, Oestreich M. Intramolecular Friedel-Crafts alkylation with a silylium-ion-activated cyclopropyl group: formation of tricyclic ring systems from benzyl-substituted vinylcyclopropanes and hydrosilanes. Chemical Science. 12: 569-575. PMID 34163787 DOI: 10.1039/d0sc05553k  0.811
2020 He T, Wang G, Bonetti V, Klare HFT, Oestreich M. Silylium-Ion-Promoted (5+1) Cycloaddition of Aryl-Substituted Vinylcyclopropanes and Hydrosilanes Involving Aryl Migration. Angewandte Chemie (International Ed. in English). PMID 32302454 DOI: 10.1002/Anie.202004320  0.709
2020 Wu Q, Roy A, Wang G, Irran E, Klare HFT, Oestreich M. Synthesis of a Counteranion-Stabilized Bis(silylium) Ion. Angewandte Chemie (International Ed. in English). PMID 32216163 DOI: 10.1002/Anie.202003799  0.79
2020 Roy A, Bonetti V, Wang G, Wu Q, Klare HFT, Oestreich M. Silylium-Ion-Promoted Ring-Opening Hydrosilylation and Disilylation of Unactivated Cyclopropanes. Organic Letters. PMID 31951144 DOI: 10.1021/Acs.Orglett.0C00173  0.802
2020 Wu Q, Roy A, Wang G, Irran E, Klare HFT, Oestreich M. Synthese eines gegenanionstabilisierten Bis(silylium)ions Angewandte Chemie. 132: 10609-10613. DOI: 10.1002/Ange.202003799  0.781
2019 Fuchs J, Irran E, Hrobárik P, Klare HFT, Oestreich M. Si-H Bond Activation with Bullock's Cationic Tungsten(II) Catalyst: CO as Cooperating Ligand. Journal of the American Chemical Society. PMID 31692343 DOI: 10.1021/Jacs.9B10304  0.54
2019 Wu Q, Roy A, Irran E, Qu ZW, Grimme S, Klare H, Oestreich M. Catalytic Difunctionalization of Unactivated Alkenes with Unreactive Hexamethyldisilane through Regeneration of Silylium Ions. Angewandte Chemie (International Ed. in English). PMID 31566863 DOI: 10.1002/Anie.201911282  0.795
2019 Wu Q, Irran E, Müller R, Kaupp M, Klare HFT, Oestreich M. Characterization of hydrogen-substituted silylium ions in the condensed phase. Science (New York, N.Y.). 365: 168-172. PMID 31296768 DOI: 10.1126/Science.Aax9184  0.632
2019 Walker JCL, Klare HFT, Oestreich M. Cationic silicon Lewis acids in catalysis Nature Reviews Chemistry. 4: 54-62. DOI: 10.1038/s41570-019-0146-7  0.776
2019 Wu Q, Roy A, Irran E, Qu Z, Grimme S, Klare HFT, Oestreich M. Katalytische Difunktionalisierung von nichtaktivierten Alkenen mit reaktionsträgem Hexamethyldisilan durch Neubildung von Silyliumionen Angewandte Chemie. 131: 17468-17472. DOI: 10.1002/Ange.201911282  0.668
2018 Müller T, Merk A, Großekappenberg H, Luecke MP, Lorent C, Driess M, Oestreich M, Klare H. Single-Electron Transfer Reactions in Silylium Ion/Phosphane Frustrated and Conventional Lewis Pairs. Angewandte Chemie (International Ed. in English). PMID 30178534 DOI: 10.1002/Anie.201808922  0.527
2018 Omann L, Pudasaini B, Irran E, Klare HFT, Baik MH, Oestreich M. Thermodynamic kinetic control in substituent redistribution reactions of silylium ions steered by the counteranion. Chemical Science. 9: 5600-5607. PMID 30061992 DOI: 10.1039/C8Sc01833B  0.818
2018 Wu Q, Qu ZW, Omann L, Irran E, Klare H, Oestreich M. Cleavage of Unactivated Si-C(sp3) Bonds with Reed's Carborane Acids: Clean Formation of Known and Unknown Silylium Ions. Angewandte Chemie (International Ed. in English). PMID 29775241 DOI: 10.1002/Anie.201805637  0.833
2018 Omann L, Qu ZW, Irran E, Klare H, Grimme S, Oestreich M. Electrophilic Formylation of Arenes by Silylium Ion-Mediated Activation of Carbon Monoxide. Angewandte Chemie (International Ed. in English). PMID 29741219 DOI: 10.1002/Anie.201803181  0.812
2018 Merk A, Großekappenberg H, Schmidtmann M, Luecke M, Lorent C, Driess M, Oestreich M, Klare HFT, Müller T. Einelektronenübertragungsreaktionen in frustrierten und klassischen Silyliumion/Phosphan‐Lewis‐Paaren Angewandte Chemie. 130: 15487-15492. DOI: 10.1002/Ange.201808922  0.338
2018 Wu Q, Qu Z, Omann L, Irran E, Klare HFT, Oestreich M. Spaltung nicht aktivierter Si-C(sp3)-Bindungen mit Reedschen Carboransäuren: Bildung bekannter und unbekannter Silyliumionen Angewandte Chemie. 130: 9317-9320. DOI: 10.1002/Ange.201805637  0.773
2018 Omann L, Qu Z, Irran E, Klare HFT, Grimme S, Oestreich M. Elektrophile Formylierung von Aromaten durch silyliumionvermittelte Aktivierung von Kohlenmonoxid Angewandte Chemie. 130: 8433-8437. DOI: 10.1002/Ange.201803181  0.741
2017 Omann L, Königs CD, Klare HF, Oestreich M. Cooperative Catalysis at Metal-Sulfur Bonds. Accounts of Chemical Research. PMID 28406290 DOI: 10.1021/Acs.Accounts.7B00089  0.811
2017 Liu WB, Schuman DP, Yang YF, Toutov AA, Liang Y, Klare HF, Nesnas N, Oestreich M, Blackmond DG, Virgil SC, Banerjee S, Zare RN, Grubbs RH, Houk KN, Stoltz BM. KOt-Bu-Catalyzed Dehydrogenative C-H Silylation of Heteroaromatics: A Combined Experimental and Computational Mechanistic Study. Journal of the American Chemical Society. PMID 28403611 DOI: 10.1021/Jacs.6B13031  0.696
2017 Yin Q, Klare HF, Oestreich M. Catalytic Friedel-Crafts C-H Borylation of Electron-Rich Arenes: Dramatic Rate Acceleration by Added Alkenes. Angewandte Chemie (International Ed. in English). PMID 28244623 DOI: 10.1002/Anie.201611536  0.68
2017 Klare HF, Goldberg AF, Duquette DC, Stoltz BM. Oxidative Fragmentations and Skeletal Rearrangements of Oxindole Derivatives. Organic Letters. PMID 28195736 DOI: 10.1021/Acs.Orglett.6B03789  0.619
2017 Fuchs J, Klare HFT, Oestreich M. Two-Silicon Cycle for Carbonyl Hydrosilylation with Nikonov’s Cationic Ruthenium(II) Catalyst Acs Catalysis. 7: 8338-8342. DOI: 10.1021/Acscatal.7B03336  0.502
2017 Klare HFT. Catalytic C–H Arylation of Unactivated C–H Bonds by Silylium Ion-Promoted C(sp2)–F Bond Activation Acs Catalysis. 7: 6999-7002. DOI: 10.1021/acscatal.7b02658  0.355
2017 Yin Q, Klare HFT, Oestreich M. Katalytische Friedel-Crafts-C-H-Borylierung elektronenreicher Arene: starke Reaktionsbeschleunigung durch Versetzen mit Alkenen Angewandte Chemie. 129: 3766-3771. DOI: 10.1002/Ange.201611536  0.569
2016 Klare HF, Oestreich M. Teaching nature the unnatural. Science (New York, N.Y.). 354: 970. PMID 27884992 DOI: 10.1126/Science.Aal1951  0.426
2016 Yin Q, Kemper S, Klare H, Oestreich M. Boron Lewis Acid-Catalyzed Hydroboration of Alkenes with Pinacolborane: BArF3 Does What B(C6F5)3 Cannot Do! Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 27447683 DOI: 10.1002/Chem.201603466  0.608
2016 Chen QA, Klare HF, Oestreich M. Brønsted Acid-Promoted Formation of Stabilized Silylium Ions for Catalytic Friedel-Crafts C-H Silylation. Journal of the American Chemical Society. PMID 27303857 DOI: 10.1021/Jacs.6B04878  0.7
2016 Schmidt RK, Klare HF, Fröhlich R, Oestreich M. Planar Chiral, Ferrocene-Stabilized Silicon Cations. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 26929105 DOI: 10.1002/Chem.201504777  0.69
2016 Yin Q, Klare HF, Oestreich M. Friedel-Crafts-Type Intermolecular C-H Silylation of Electron-Rich Arenes Initiated by Base-Metal Salts. Angewandte Chemie (International Ed. in English). PMID 26821860 DOI: 10.1002/Anie.201510469  0.626
2016 Yin Q, Klare HFT, Oestreich M. Durch Nichtedelmetallsalze ausgelöste Friedel-Crafts-artige intermolekulare C-H-Silylierung von elektronenreichen Arenen Angewandte Chemie. 128: 3256-3260. DOI: 10.1002/Ange.201510469  0.561
2015 Stahl T, Hrobárik P, Königs CDF, Ohki Y, Tatsumi K, Kemper S, Kaupp M, Klare HFT, Oestreich M. Mechanism of the cooperative Si-H bond activation at Ru-S bonds. Chemical Science. 6: 4324-4334. PMID 29218203 DOI: 10.1039/C5Sc01035G  0.706
2015 Stahl T, Hrobárik P, Königs CDF, Ohki Y, Tatsumi K, Kemper S, Kaupp M, Klare HFT, Oestreich M. Mechanism of the cooperative Si-H bond activation at Ru-S bonds Chemical Science. 6: 4324-4334. DOI: 10.1039/c5sc01035g  0.663
2014 Hermeke J, Klare HF, Oestreich M. Direct catalytic access to N-silylated enamines from enolizable imines and hydrosilanes by base-free dehydrogenative Si-N coupling. Chemistry (Weinheim An Der Bergstrasse, Germany). 20: 9250-4. PMID 24867619 DOI: 10.1002/Chem.201402866  0.81
2014 Metsänen TT, Hrobárik P, Klare HF, Kaupp M, Oestreich M. Insight into the mechanism of carbonyl hydrosilylation catalyzed by Brookhart's cationic iridium(III) pincer complex. Journal of the American Chemical Society. 136: 6912-5. PMID 24784900 DOI: 10.1021/Ja503254F  0.795
2014 Oestreich M, Klare H, Müther K, Fröhlich R. Taming Super Lewis Acids for Catalysis: The Family of Ferrocene-Stabilized Silicon Cations Scienceopen Posters. DOI: 10.14293/P2199-8442.1.Sop-Chem.Pmugh7.V1  0.774
2014 Rohde VHG, Pommerening P, Klare HFT, Oestreich M. Intramolecularly sulfur-stabilized silicon cations as Lewis acid catalysts Organometallics. 33: 3618-3628. DOI: 10.1021/Om500570D  0.801
2013 Königs CD, Klare HF, Oestreich M. Catalytic 1,4-selective hydrosilylation of pyridines and benzannulated congeners. Angewandte Chemie (International Ed. in English). 52: 10076-9. PMID 23907997 DOI: 10.1002/Anie.201305028  0.481
2013 Königs CD, Müller MF, Aiguabella N, Klare HF, Oestreich M. Catalytic dehydrogenative Si-N coupling of pyrroles, indoles, carbazoles as well as anilines with hydrosilanes without added base. Chemical Communications (Cambridge, England). 49: 1506-8. PMID 23328998 DOI: 10.1039/C3Cc38900F  0.478
2013 Stahl T, Klare HF, Oestreich M. C(sp3)-F bond activation of CF3-substituted anilines with catalytically generated silicon cations: spectroscopic evidence for a hydride-bridged Ru-S dimer in the catalytic cycle. Journal of the American Chemical Society. 135: 1248-51. PMID 23311960 DOI: 10.1021/Ja311398J  0.718
2013 Stahl T, Klare HFT, Oestreich M. Main-group lewis acids for C-F bond activation Acs Catalysis. 3: 1578-1587. DOI: 10.1021/Cs4003244  0.688
2013 Königs CDF, Klare HFT, Oestreich M. Katalytische 1,4-selektive Hydrosilylierung von Pyridinverbindungen und benzanellierten Verwandten Angewandte Chemie. 125: 10260-10263. DOI: 10.1002/Ange.201305028  0.343
2012 Königs CD, Klare HF, Ohki Y, Tatsumi K, Oestreich M. Base-free dehydrogenative coupling of enolizable carbonyl compounds with silanes. Organic Letters. 14: 2842-5. PMID 22621382 DOI: 10.1021/Ol301089R  0.552
2012 Nie W, Klare HFT, Oestreich M, Fröhlich R, Kehr G, Erker G. Reversible heterolytic Si-H bond activation by an intramolecular frustrated Lewis pair Zeitschrift Fur Naturforschung - Section B Journal of Chemical Sciences. 67: 987-994. DOI: 10.5560/Znb.2012-0181  0.478
2011 Klare HF, Oestreich M, Ito J, Nishiyama H, Ohki Y, Tatsumi K. Cooperative catalytic activation of Si-H bonds by a polar Ru-S bond: regioselective low-temperature C-H silylation of indoles under neutral conditions by a Friedel-Crafts mechanism. Journal of the American Chemical Society. 133: 3312-5. PMID 21341748 DOI: 10.1021/Ja111483R  0.524
2010 Klare HF, Oestreich M. Silylium ions in catalysis. Dalton Transactions (Cambridge, England : 2003). 39: 9176-84. PMID 20405073 DOI: 10.1039/C003097J  0.578
2009 Klare HF, Bergander K, Oestreich M. Taming the silylium ion for low-temperature Diels-Alder reactions. Angewandte Chemie (International Ed. in English). 48: 9077-9. PMID 19862787 DOI: 10.1002/Anie.200904520  0.483
2009 Klare HF, Oestreich M. Asymmetric ring-closing metathesis with a twist. Angewandte Chemie (International Ed. in English). 48: 2085-9. PMID 19199310 DOI: 10.1002/Anie.200806254  0.475
2009 Klare H, Bergander K, Oestreich M. Ein gezähmtes Silyliumion für Diels-Alder-Reaktionen bei niedrigen Temperaturen Angewandte Chemie. 121: 9241-9243. DOI: 10.1002/Ange.200904520  0.4
2009 Klare H, Oestreich M. Asymmetrische Ringschlussmetathese mit Pfiff Angewandte Chemie. 121: 2119-2123. DOI: 10.1002/Ange.200806254  0.408
2007 Klare HF, Oestreich M. Chiral recognition with silicon-stereogenic silanes: remarkable selectivity factors in the kinetic resolution of donor-functionalized alcohols. Angewandte Chemie (International Ed. in English). 46: 9335-8. PMID 17990256 DOI: 10.1002/Anie.200703847  0.366
2007 Klare H, Oestreich M. Chirale Erkennung mit siliciumstereogenen Silanen: außergewöhnliche Selektivitätsfaktoren bei der kinetischen Racematspaltung von donorfunktionalisierten Alkoholen Angewandte Chemie. 119: 9496-9499. DOI: 10.1002/Ange.200703847  0.348
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