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T. Don Tilley - Publications

Affiliations: 
1983-1994 Chemistry University of California, San Diego, La Jolla, CA 
 1994- University of California, Berkeley, Berkeley, CA, United States 
Area:
Synthetic, structural, and reactivity studies on transition metal compounds
Website:
http://chemistry.berkeley.edu/faculty/chem/tilley
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Year Citation  Score
2022 Kynman AE, Elghanayan LK, Desnoyer AN, Yang Y, Sévery L, Di Giuseppe A, Tilley TD, Maron L, Arnold PL. Controlled monodefluorination and alkylation of C(sp)-F bonds by lanthanide photocatalysts: importance of metal-ligand cooperativity. Chemical Science. 13: 14090-14100. PMID 36540817 DOI: 10.1039/d2sc04192h  0.789
2022 Ríos P, See MS, Handford RC, Teat SJ, Tilley TD. Robust dicopper(i) μ-boryl complexes supported by a dinucleating naphthyridine-based ligand. Chemical Science. 13: 6619-6625. PMID 35756530 DOI: 10.1039/d2sc00848c  0.324
2022 Bergman HM, Beattie DD, Handford RC, Rossomme E, Suslick BA, Head-Gordon M, Cundari TR, Liu Y, Tilley TD. Copper(III) Metallacyclopentadienes via Zirconocene Transfer and Reductive Elimination to an Isolable Phenanthrocyclobutadiene. Journal of the American Chemical Society. PMID 35604847 DOI: 10.1021/jacs.2c02581  0.795
2022 Amtawong J, Nguyen AI, Tilley TD. Mechanistic Aspects of Cobalt-Oxo Cubane Clusters in Oxidation Chemistry. Journal of the American Chemical Society. PMID 35060704 DOI: 10.1021/jacs.1c11445  0.618
2021 Amtawong J, Skjelstad BB, Handford RC, Suslick BA, Balcells D, Tilley TD. C-H Activation by RuCoO Oxo Cubanes: Effects of Oxyl Radical Character and Metal-Metal Cooperativity. Journal of the American Chemical Society. 143: 12108-12119. PMID 34318666 DOI: 10.1021/jacs.1c04069  0.809
2021 Desnoyer AN, Nicolay A, Ziegler MS, Lakshmi KV, Cundari TR, Tilley TD. A Dicopper Nitrenoid by Oxidation of a CuCu Core: Synthesis, Electronic Structure, and Reactivity. Journal of the American Chemical Society. PMID 33877827 DOI: 10.1021/jacs.1c02235  0.833
2021 Suslick BA, Tilley TD. Olefin Hydroarylation Catalyzed by a Single-Component Cobalt(-I) Complex. Organic Letters. PMID 33560852 DOI: 10.1021/acs.orglett.1c00258  0.803
2020 Yang J, Postils V, Lipschutz MI, Fasulo M, Raynaud C, Clot E, Eisenstein O, Tilley TD. Efficient alkene hydrosilation with bis(8-quinolyl)phosphine (NPN) nickel catalysts. The dominant role of silyl-over hydrido-nickel catalytic intermediates. Chemical Science. 11: 5043-5051. PMID 34122961 DOI: 10.1039/d0sc00997k  0.314
2020 Smith PW, Dong Y, Tilley TD. Efficient and selective alkene hydrosilation promoted by weak, double Si-H activation at an iron center. Chemical Science. 11: 7070-7075. PMID 33250975 DOI: 10.1039/D0Sc01749C  0.379
2020 Phillips NA, Smith PW, Tilley TD, Minasian SG. Gauging aromatic conjugation and charge delocalization in the aryl silanes PhSiH ( = 0-4), with silicon K-edge XAS and TDDFT. Dalton Transactions (Cambridge, England : 2003). PMID 32936166 DOI: 10.1039/D0Dt03153D  0.67
2020 Dombrowski JP, Ziegler MS, Phadke NM, Mansoor E, Levine DS, Witzke RJ, Head-Gordon M, Bell AT, Tilley TD. Siloxyaluminate and Siloxygallate Complexes as Models for Framework and Partially-Hydrolyzed Framework Sites in Zeolites and Zeotypes. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 32926472 DOI: 10.1002/Chem.202002926  0.494
2020 Desnoyer AN, Nicolay A, Rios P, Ziegler MS, Tilley TD. Bimetallics in a Nutshell: Complexes Supported by Chelating Naphthyridine-Based Ligands. Accounts of Chemical Research. PMID 32878429 DOI: 10.1021/Acs.Accounts.0C00382  0.832
2020 Suslick BA, Tilley TD. Mechanistic Interrogation of Alkyne Hydroarylations Catalyzed by Highly Reduced, Single-Component Cobalt Complexes. Journal of the American Chemical Society. PMID 32456425 DOI: 10.1021/Jacs.0C04072  0.828
2020 Kiel GR, Bay KL, Samkian AE, Schuster NJ, Lin JB, Handford RC, Nuckolls C, Houk KN, Tilley TD. Expanded Helicenes as Synthons for Chiral Macrocyclic Nanocarbons. Journal of the American Chemical Society. PMID 32450694 DOI: 10.1021/Jacs.0C03177  0.355
2020 Desnoyer AN, Nicolay A, Ziegler MS, Torquato NA, Tilley TD. A Dicopper Platform that Stabilizes the Formation of Pentanuclear Coinage Metal Hydride Complexes. Angewandte Chemie (International Ed. in English). PMID 32372506 DOI: 10.1002/Anie.202004346  0.823
2020 Handford RC, Wheeler TA, Tilley TD. Structure and Bonding in a Diamond-Shaped Tin Cluster Possessing a cyclo-Sn4 Core. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 32219897 DOI: 10.1002/Chem.202000969  0.328
2020 Nicolay A, Ziegler MS, Small DW, Grünbauer R, Scheer M, Tilley TD. Isomerism and dynamic behavior of bridging phosphaalkynes bound to a dicopper complex. Chemical Science. 11: 1607-1616. PMID 32206279 DOI: 10.1039/C9Sc05835D  0.381
2020 Yang J, Postils V, Lipschutz MI, Fasulo M, Raynaud C, Clot E, Eisenstein O, Tilley TD. Efficient alkene hydrosilation with bis(8-quinolyl)phosphine (NPN) nickel catalysts. The dominant role of silyl-over hydrido-nickel catalytic intermediates Chemical Science. 11: 5043-5051. DOI: 10.1039/D0Sc00997K  0.38
2020 Witzke RJ, Hait D, Chakarawet K, Head-Gordon M, Tilley TD. Bimetallic Mechanism for Alkyne Cyclotrimerization with a Two-Coordinate Fe Precatalyst Acs Catalysis. 10: 7800-7807. DOI: 10.1021/Acscatal.0C01828  0.303
2020 Nicolay A, Ziegler MS, Rochlitz L, Tilley TD. Low-valent iron and cobalt complexes supported by a rigid xanthene-based disilylamido ligand Polyhedron. 180: 114420. DOI: 10.1016/J.Poly.2020.114420  0.433
2019 Amtawong J, Balcells D, Wilcoxen J, Handford RC, Biggins N, Nguyen AI, Britt RD, Tilley TD. Isolation and Study of Ruthenium-Cobalt Oxo Cubanes Bearing a High-Valent, Terminal Ru-Oxo with Significant Oxyl Radical Character. Journal of the American Chemical Society. PMID 31697896 DOI: 10.1021/Jacs.9B10320  0.668
2019 Ma W, Zhang JX, Lin Z, Tilley TD, Ye Q. Synthesis, structure and DFT calculations of mononuclear cyclic (alkyl)(amino) carbene supported titanium(ii) complexes. Dalton Transactions (Cambridge, England : 2003). PMID 31549712 DOI: 10.1039/C9Dt03342D  0.547
2019 Geitner FS, Klein W, Storcheva O, Tilley TD, Fässler TF. Early-Transition-Metal Complexes of Functionalized Nonagermanide Clusters: Synthesis and Characterization of [Cp(MeCN)Ti(η-Ge{Si(TMS)})] and K[CpTi(η-Ge{Si(TMS)})]. Inorganic Chemistry. PMID 31532208 DOI: 10.1021/Acs.Inorgchem.9B02158  0.375
2019 Nguyen AI, Van Allsburg KM, Terban MW, Bajdich M, Oktawiec J, Amtawong J, Ziegler MS, Dombrowski JP, Lakshmi KV, Drisdell WS, Yano J, Billinge SJL, Tilley TD. Stabilization of reactive CoO cubane oxygen-evolution catalysts within porous frameworks. Proceedings of the National Academy of Sciences of the United States of America. PMID 31142656 DOI: 10.1073/Pnas.1815013116  0.714
2019 Handford RC, Smith PW, Tilley TD. Activations of all Bonds to Silicon (Si-H, Si-C) in a Silane with Extrusion of [CoSiCo] Silicide Cores. Journal of the American Chemical Society. PMID 31117667 DOI: 10.1021/Jacs.9B04265  0.348
2019 Witzke RJ, Tilley TD. A two-coordinate Ni(i) silyl complex: CO insertion and oxidatively-induced silyl migrations. Chemical Communications (Cambridge, England). PMID 31111837 DOI: 10.1039/C9Cc03128F  0.429
2019 Smith PW, Handford RC, Tilley TD. Heavy Tetrel Complexes of Ru Featuring Ru═E(R)X and Ru–E–R (E = Sn, Pb) Linkages Organometallics. 38: 4060-4065. DOI: 10.1021/Acs.Organomet.9B00550  0.447
2019 Cai IC, Ziegler MS, Bunting PC, Nicolay A, Levine DS, Kalendra V, Smith PW, Lakshmi KV, Tilley TD. Monomeric, Divalent Vanadium Bis(arylamido) Complexes: Linkage Isomerism and Reactivity Organometallics. 38: 1648-1663. DOI: 10.1021/Acs.Organomet.9B00134  0.61
2019 Waterman R, Handford RC, Tilley TD. Element–Hydrogen Bond Activations at Cationic Platinum Centers To Produce Silylene, Germylene, Stannylene, and Stibido Complexes Organometallics. 38: 2053-2061. DOI: 10.1021/Acs.Organomet.9B00097  0.698
2019 Smith PW, Ellis SR, Handford RC, Tilley TD. An Anionic Ruthenium Dihydride [Cp*(iPr2MeP)RuH2]− and Its Conversion to Heterobimetallic Ru(μ-H)2M (M = Ir or Cu) Complexes Organometallics. 38: 336-342. DOI: 10.1021/Acs.Organomet.8B00738  0.448
2018 Arnold J, Tilley TD. An enigmatic trailblazer on the frontier of discovery: Richard A. Andersen. Chemical Communications (Cambridge, England). PMID 30324202 DOI: 10.1039/C8Cc90464B  0.378
2018 Liu HJ, Ziegler MS, Tilley TD. Synthesis, structures, and reactivity studies of cyclometalated N-heterocyclic carbene complexes of ruthenium. Dalton Transactions (Cambridge, England : 2003). PMID 30083678 DOI: 10.1039/C8Dt01925H  0.438
2018 Nguyen AI, Darago LE, Balcells D, Tilley TD. Influence of a "Dangling" Co(II) Ion Bound to a [MnCo3O4] Oxo Cubane. Journal of the American Chemical Society. PMID 30001620 DOI: 10.1021/Jacs.8B04065  0.646
2018 Nicolay A, Tilley TD. Selective synthesis of a series of isostructural MIICuI heterobimetallic complexes spontaneously assembled by an unsymmetrical naphthyridine-based ligand. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 29852541 DOI: 10.1002/Chem.201802623  0.393
2018 Smith PW, Tilley TD. Base-Free Iron Hydrosilylene Complexes via an α-Hydride Migration that Induces Spin Pairing. Journal of the American Chemical Society. PMID 29528225 DOI: 10.1021/Jacs.8B01185  0.393
2018 Olshansky L, Huerta-Lavorie R, Nguyen AI, Vallapurackal J, Furst A, Tilley TD, Borovik AS. Artificial Metalloproteins Containing Co4O4 Cubane Active Sites. Journal of the American Chemical Society. PMID 29401385 DOI: 10.1021/Jacs.7B13052  0.649
2018 Kiel GR, Samkian AE, Nicolay A, Witzke RJ, Tilley TD. Titanocene-Mediated Dinitrile Coupling: A Divergent Route to Nitrogen-Containing Polycyclic Aromatic Hydrocarbons. Journal of the American Chemical Society. PMID 29383934 DOI: 10.1021/Jacs.7B13823  0.355
2018 Lipke MC, Poradowski M, Raynaud C, Eisenstein O, Tilley TD. Catalytic Olefin Hydrosilations Mediated by Ruthenium η3-H2Si σ Complexes of Primary and Secondary Silanes Acs Catalysis. 8: 11513-11523. DOI: 10.1021/Acscatal.8B02161  0.401
2018 Handford RC, Smith PW, Tilley TD. Silylene Complexes of Late 3d Transition Metals Supported by tris-Phosphinoborate Ligands Organometallics. 37: 4077-4085. DOI: 10.1021/Acs.Organomet.8B00635  0.449
2018 Ziegler MS, Torquato NA, Levine DS, Nicolay A, Celik H, Tilley TD. Dicopper Alkyl Complexes: Synthesis, Structure, and Unexpected Persistence Organometallics. 37: 2807-2823. DOI: 10.1021/Acs.Organomet.8B00443  0.445
2017 Ye Q, Ziegler MS, Lakshmi KV, Tilley TD. Titanium Imido Complexes by Displacement of –SiMe3 and C–H Bond Activation in a TiIII Amido Complex, Promoted by a Cyclic (Alkyl)(Amino) Carbene (cAAC) European Journal of Inorganic Chemistry. 2017: 2484-2487. PMID 30505212 DOI: 10.1002/Ejic.201700295  0.695
2017 Kiel GR, Patel SC, Smith PW, Levine DS, Tilley TD. Expanded Helicenes: A General Synthetic Strategy and Remarkable Supramolecular and Solid-State Behavior. Journal of the American Chemical Society. PMID 29215272 DOI: 10.1021/Jacs.7B10902  0.311
2017 Nguyen AI, Wang J, Levine DS, Ziegler MS, Tilley TD. Synthetic control and empirical prediction of redox potentials for Co4O4 cubanes over a 1.4 V range: implications for catalyst design and evaluation of high-valent intermediates in water oxidation. Chemical Science. 8: 4274-4284. PMID 29081963 DOI: 10.1039/C7Sc00627F  0.656
2017 Levine DS, Tilley TD, Andersen RA. Efficient and selective catalysis for hydrogenation and hydrosilation of alkenes and alkynes with PNP complexes of scandium and yttrium. Chemical Communications (Cambridge, England). PMID 29043320 DOI: 10.1039/C7Cc06417A  0.597
2017 Marschner C, Tilley TD. Current advances in the chemistry of silicon: not exactly a carbon copy Dalton Transactions. 46: 8699-8700. PMID 28674710 DOI: 10.1039/C7Dt90112G  0.605
2017 Ziegler MS, Lakshmi KV, Tilley TD. Dicopper Cu(I)Cu(I) and Cu(I)Cu(II) Complexes in Copper-Catalyzed Azide-Alkyne Cycloaddition. Journal of the American Chemical Society. PMID 28394586 DOI: 10.1021/Jacs.6B13261  0.593
2017 Nguyen AI, Suess DL, Darago LE, Oyala PH, Levine DS, Ziegler MS, Britt RD, Tilley TD. Manganese-Cobalt Oxido Cubanes Relevant to Manganese-Doped Water Oxidation Catalysts. Journal of the American Chemical Society. PMID 28347135 DOI: 10.1021/Jacs.7B01792  0.806
2017 Kiel GR, Ziegler MS, Tilley TD. Zirconacyclopentadiene-Annulated Polycyclic Aromatic Hydrocarbons. Angewandte Chemie (International Ed. in English). PMID 28334480 DOI: 10.1002/Anie.201700818  0.329
2017 Swierk JR, Tilley TD. Electrocatalytic Water Oxidation by Single Site and Small Nuclearity Clusters of Cobalt Journal of the Electrochemical Society. 165: H3028-H3033. DOI: 10.1149/2.0041804Jes  0.729
2017 Guillo P, Lipschutz MI, Fasulo ME, Tilley TD. Tantalum–Polyhedral Oligosilsesquioxane Complexes as Structural Models and Functional Catalysts for Epoxidation Acs Catalysis. 7: 2303-2312. DOI: 10.1021/Acscatal.7B00020  0.415
2016 Spanjers CS, Guillo P, Tilley TD, Janik MJ, Rioux RM. Identification of Second Shell Coordination in Transition Metal Species using Theoretical XANES: Example of Ti-O-(C,Si,Ge) Complexes. The Journal of Physical Chemistry. A. PMID 27951643 DOI: 10.1021/Acs.Jpca.6B12197  0.362
2016 Dombrowski JP, Johnson GR, Bell AT, Tilley TD. Correction: Ga[OSi(O(t)Bu)3]3·THF, a thermolytic molecular precursor for high surface area gallium-containing silica materials of controlled dispersion and stoichiometry. Dalton Transactions (Cambridge, England : 2003). PMID 27834429 DOI: 10.1039/C6Dt90202B  0.427
2016 Lipke MC, Liberman-Martin AL, Tilley TD. Electrophilic Activation of Silicon-Hydrogen Bonds in Catalytic Hydrosilations. Angewandte Chemie (International Ed. in English). PMID 27641142 DOI: 10.1002/Anie.201605198  0.808
2016 Lipke MC, Liberman-Martin AL, Tilley TD. Significant Cooperativity Between Ruthenium and Silicon in Catalytic Transformations of an Isocyanide. Journal of the American Chemical Society. PMID 27384746 DOI: 10.1021/Jacs.6B05736  0.821
2016 Dombrowski JP, Johnson GR, Bell AT, Tilley TD. Ga[OSi(O(t)Bu)3]3·THF, a thermolytic molecular precursor for high surface area gallium-containing silica materials of controlled dispersion and stoichiometry. Dalton Transactions (Cambridge, England : 2003). PMID 27312519 DOI: 10.1039/c6dt01676f  0.407
2016 Ziegler MS, Levine DS, Lakshmi KV, Tilley TD. Aryl Group Transfer from Tetraarylborato Anions to an Electrophilic Dicopper(I) Center and Mixed-Valence μ-Aryl Dicopper(I,II) Complexes. Journal of the American Chemical Society. PMID 27176131 DOI: 10.1021/Jacs.6B00802  0.631
2016 Liberman-Martin AL, Levine DS, Ziegler MS, Bergman RG, Tilley TD. Lewis acid-base interactions between platinum(ii) diaryl complexes and bis(perfluorophenyl)zinc: strongly accelerated reductive elimination induced by a Z-type ligand. Chemical Communications (Cambridge, England). PMID 27161155 DOI: 10.1039/C6Cc02433E  0.82
2016 Dong Y, Lipschutz MI, Tilley TD. Regioselective, Transition Metal-Free C-O Coupling Reactions Involving Aryne Intermediates. Organic Letters. PMID 27010921 DOI: 10.1021/Acs.Orglett.6B00183  0.383
2016 Levine DS, Tilley TD, Andersen RA. Evidence for the Existence of Group 3 Terminal Methylidene Complexes Organometallics. 36: 80-88. DOI: 10.1021/Acs.Organomet.6B00394  0.587
2016 Liberman-Martin AL, Levine DS, Liu W, Bergman RG, Tilley TD. Biaryl Reductive Elimination Is Dramatically Accelerated by Remote Lewis Acid Binding to a 2,2′-Bipyrimidyl–Platinum Complex: Evidence for a Bidentate Ligand Dissociation Mechanism Organometallics. 35: 1064-1069. DOI: 10.1021/Acs.Organomet.5B01003  0.798
2016 M. Ugeda M, Bradley AJ, Rodrigo L, Yu M, Liu W, Doak P, Riss A, Neaton JB, Tilley TD, Pérez R, Crommie MF. Covalent Functionalization of GaP(110) Surfaces via a Staudinger-Type Reaction with Perfluorophenyl Azide The Journal of Physical Chemistry C. 120: 26448-26452. DOI: 10.1021/Acs.Jpcc.6B10691  0.312
2016 Liberman-Martin AL, Ziegler MS, DiPasquale AG, Bergman RG, Tilley TD. Functionalization of an iridium-diamidocarbene complex by ligand-based reactions with titanocene and zirconocene sources Polyhedron. DOI: 10.1016/J.Poly.2016.03.044  0.818
2016 Liu HJ, Cai IC, Fedorov A, Ziegler MS, Copéret C, Tilley TD. Tricoordinate Organochromium(III) Complexes Supported by a Bulky Silylamido Ligand Produce Ultra-High-Molecular Weight Polyethylene in the Absence of Activators Helvetica Chimica Acta. DOI: 10.1002/Hlca.201600199  0.387
2015 Panetier JA, Letko CS, Tilley TD, Head-Gordon M. Computational Characterization of Redox Non-Innocence in Cobalt-Bis(Diaryldithiolene) Catalyzed Proton Reduction. Journal of Chemical Theory and Computation. PMID 26598074 DOI: 10.1021/Acs.Jctc.5B00968  0.406
2015 Nguyen AI, Ziegler MS, Oña-Burgos P, Sturzbecher-Hoehne M, Kim W, Bellone DE, Tilley TD. Mechanistic Investigations of Water Oxidation by a Molecular Cobalt Oxide Analogue: Evidence for a Highly Oxidized Intermediate and Exclusive Terminal Oxo Participation. Journal of the American Chemical Society. PMID 26390993 DOI: 10.1021/Jacs.5B08396  0.642
2015 Liu HJ, Landis C, Raynaud C, Eisenstein O, Tilley TD. Donor-Promoted 1,2-Hydrogen Migration from Silicon to a Saturated Ruthenium Center and Access to Silaoxiranyl and Silaiminyl Complexes. Journal of the American Chemical Society. 137: 9186-94. PMID 26135519 DOI: 10.1021/Jacs.5B05571  0.427
2015 Lipschutz MI, Chantarojsiri T, Dong Y, Tilley TD. Synthesis, characterization, and alkyne trimerization catalysis of a heteroleptic two-coordinate fe(i) complex. Journal of the American Chemical Society. 137: 6366-72. PMID 25928273 DOI: 10.1021/Jacs.5B02504  0.37
2015 Liberman-Martin AL, Bergman RG, Tilley TD. Lewis Acidity of Bis(perfluorocatecholato)silane: Aldehyde Hydrosilylation Catalyzed by a Neutral Silicon Compound. Journal of the American Chemical Society. 137: 5328-31. PMID 25879515 DOI: 10.1021/Jacs.5B02807  0.799
2015 Liu HJ, Ziegler MS, Tilley TD. The Ruthenostannylene Complex [Cp*(IXy)H2 Ru-Sn-Trip]: Providing Access to Unusual Ru-Sn Bonded Stanna-imine, Stannene, and Ketenylstannyl Complexes. Angewandte Chemie (International Ed. in English). 54: 6622-6. PMID 25845838 DOI: 10.1002/Anie.201502156  0.428
2015 Van Allsburg KM, Anzenberg E, Drisdell WS, Yano J, Tilley TD. Oxygen-atom transfer chemistry and thermolytic properties of a di-tert-butylphosphate-ligated Mn4O4 cubane. Chemistry (Weinheim An Der Bergstrasse, Germany). 21: 4646-54. PMID 25676196 DOI: 10.1002/Chem.201406114  0.412
2015 Levine DS, Tilley TD, Andersen RA. C-H Bond Activations by Monoanionic, PNP-Supported Scandium Dialkyl Complexes Organometallics. 34: 4647-4655. DOI: 10.1021/Acs.Organomet.5B00213  0.601
2015 Smith PW, Tilley TD. Silane-Allyl Coupling Reactions of Cp∗(iPr2MeP)Fe(η3-C3H5) and Synthetic Access to the Hydrido-Dinitrogen Complex Cp∗(iPr2MeP)FeH(N2) Organometallics. 34: 2134-2138. DOI: 10.1021/Acs.Organomet.5B00184  0.397
2015 Swierk JR, Klaus S, Trotochaud L, Bell AT, Tilley TD. Electrochemical Study of the Energetics of the Oxygen Evolution Reaction at Nickel Iron (Oxy)Hydroxide Catalysts Journal of Physical Chemistry C. 119: 19022-19029. DOI: 10.1021/Acs.Jpcc.5B05861  0.742
2015 Liberman-Martin AL, Bergman RG, Tilley TD. ChemInform Abstract: Lewis Acidity of Bis(perfluorocatecholato)silane: Aldehyde Hydrosilylation Catalyzed by a Neutral Silicon Compound. Cheminform. 46: no-no. DOI: 10.1002/chin.201538046  0.788
2014 Lipke MC, Tilley TD. Hypercoordinate ketone adducts of electrophilic η3-H2SiRR' ligands on ruthenium as key intermediates for efficient and robust catalytic hydrosilation. Journal of the American Chemical Society. 136: 16387-98. PMID 25347044 DOI: 10.1021/Ja509073C  0.361
2014 Arnold J, Brothers PJ, Mountford P, Piers WE, Thomas CM, Tilley TD. The influence of Michael Lappert on the chemistry landscape. Dalton Transactions (Cambridge, England : 2003). 43: 16553-6. PMID 25331627 DOI: 10.1039/C4Dt90167C  0.683
2014 Lipschutz MI, Tilley TD. Useful Method for the Preparation of Low-Coordinate Nickel(I) Complexes via Transformations of the Ni(I) Bis(amido) Complex K{Ni[N(SiMe3)(2,6- (i) Pr2-C6H3)]2} Organometallics. 33: 5566-5570. PMID 25328273 DOI: 10.1021/Om500849U  0.405
2014 Liu HJ, Guihaumé J, Davin T, Raynaud C, Eisenstein O, Tilley TD. 1,2-hydrogen migration to a saturated ruthenium complex via reversal of electronic properties for tin in a stannylene-to-metallostannylene conversion. Journal of the American Chemical Society. 136: 13991-4. PMID 25247392 DOI: 10.1021/Ja507799E  0.421
2014 Cai IC, Lipschutz MI, Tilley TD. A bis(amido) ligand set that supports two-coordinate chromium in the +1, +2, and +3 oxidation states. Chemical Communications (Cambridge, England). 50: 13062-5. PMID 25222516 DOI: 10.1039/C4Cc06615D  0.361
2014 Nguyen AI, Hadt RG, Solomon EI, Tilley TD. Efficient C-H Bond Activations via O2 Cleavage by a Dianionic Cobalt(II) Complex. Chemical Science (Royal Society of Chemistry : 2010). 5: 2874-2878. PMID 25071930 DOI: 10.1039/C4Sc00108G  0.673
2014 Liu HJ, Raynaud C, Eisenstein O, Tilley TD. Cyclometalated N-heterocyclic carbene complexes of ruthenium for access to electron-rich silylene complexes that bind the Lewis acids CuOTf and AgOTf. Journal of the American Chemical Society. 136: 11473-82. PMID 25050912 DOI: 10.1021/Ja5054237  0.467
2014 Letko CS, Panetier JA, Head-Gordon M, Tilley TD. Mechanism of the electrocatalytic reduction of protons with diaryldithiolene cobalt complexes. Journal of the American Chemical Society. 136: 9364-76. PMID 24950387 DOI: 10.1021/Ja5019755  0.453
2014 Lipschutz MI, Tilley TD. Carbon-carbon cross-coupling reactions catalyzed by a two-coordinate nickel(II)-bis(amido) complex via observable Ni(I) , Ni(II) , and Ni(III) intermediates. Angewandte Chemie (International Ed. in English). 53: 7290-4. PMID 24889777 DOI: 10.1002/Anie.201404577  0.383
2014 Davenport TC, Ahn HS, Ziegler MS, Tilley TD. A molecular structural analog of proposed dinuclear active sites in cobalt-based water oxidation catalysts. Chemical Communications (Cambridge, England). 50: 6326-9. PMID 24797957 DOI: 10.1039/C3Cc46865H  0.321
2014 Lipke MC, Neumeyer F, Tilley TD. Interconversion of η3-H2SiRR' σ-complexes and 16-electron silylene complexes via reversible H-H or C-H elimination. Journal of the American Chemical Society. 136: 6092-102. PMID 24666100 DOI: 10.1021/Ja501803W  0.423
2014 Ahn HS, Davenport TC, Tilley TD. Molecular cobalt electrocatalyst for proton reduction at low overpotential. Chemical Communications (Cambridge, England). 50: 3834-7. PMID 24589710 DOI: 10.1039/C3Cc49682A  0.381
2014 Liu W, Sharp ID, Tilley TD. Multifunctional silicon surfaces: reaction of dichlorocarbene generated from Seyferth reagent with hydrogen-terminated silicon (111) surfaces. Langmuir : the Acs Journal of Surfaces and Colloids. 30: 172-8. PMID 24328351 DOI: 10.1021/La403789A  0.35
2014 Gladysz JA, Bedford RB, Fujita M, Gabbaï FP, Goldberg KI, Holland PL, Kiplinger JL, Krische MJ, Louie J, Lu CC, Norton JR, Petrukhina MA, Ren T, Stahl SS, Tilley TD, et al. Organometallics roundtable 2013-2014 Organometallics. 33: 1505-1527. DOI: 10.1021/Om500253Z  0.707
2014 Liu HJ, Ziegler MS, Tilley TD. Ring-opening and double-metallation reactions of the N-Heterocyclic carbene ligand in Cp∗(IXy)Ru (IXy = 1,3-bis(2,6-dimethylphenyl)imidazol-2-ylidene) complexes. Access to an anionic fischer-type carbene complex of ruthenium This paper is dedicated to John Bercaw on the occasion of his 70th birthday Polyhedron. 84: 203-208. DOI: 10.1016/J.Poly.2014.08.052  0.48
2014 Bowring MA, Bergman RG, Tilley TD. ChemInform Abstract: Pt-Catalyzed C-C Activation Induced by C-H Activation. Cheminform. 45: no-no. DOI: 10.1002/chin.201408108  0.358
2014 Gross CL, Brumaghim JL, Jefferis JM, Dickinson PW, Girolami GS, Gribble CW, Tilley TD. Mono(η5-Pentamethylcyclopentadienyl) Complexes of Osmium Inorganic Syntheses. 36: 74-78. DOI: 10.1002/9781118744994.ch15  0.548
2013 Lipschutz MI, Yang X, Chatterjee R, Tilley TD. A structurally rigid bis(amido) ligand framework in low-coordinate Ni(I), Ni(II), and Ni(III) analogues provides access to a Ni(III) methyl complex via oxidative addition. Journal of the American Chemical Society. 135: 15298-301. PMID 24079707 DOI: 10.1021/Ja408151H  0.375
2013 Bowring MA, Bergman RG, Tilley TD. Pt-catalyzed C-C activation induced by C-H activation. Journal of the American Chemical Society. 135: 13121-8. PMID 23962182 DOI: 10.1021/Ja406260J  0.484
2013 Hayes PG, Xu Z, Beddie C, Keith JM, Hall MB, Tilley TD. The osmium-silicon triple bond: synthesis, characterization, and reactivity of an osmium silylyne complex. Journal of the American Chemical Society. 135: 11780-3. PMID 23906040 DOI: 10.1021/Ja406799Y  0.696
2013 Rumberger EM, Ahn HS, Bell AT, Tilley TD. Water oxidation catalysis via immobilization of the dimanganese complex [Mn2(μ-O)2Cl(μ-O2CCH3)(bpy)2(H2O)](NO3)2 onto silica. Dalton Transactions (Cambridge, England : 2003). 42: 12238-47. PMID 23861177 DOI: 10.1039/C3Dt51472B  0.726
2013 Lipke MC, Tilley TD. Silane-isocyanide coupling involving 1,1-insertion of XylNC into the Si-H bond of a σ-silane ligand. Journal of the American Chemical Society. 135: 10298-301. PMID 23834657 DOI: 10.1021/Ja404910H  0.367
2013 Liberman-Martin AL, Bergman RG, Tilley TD. A remote Lewis acid trigger dramatically accelerates biaryl reductive elimination from a platinum complex. Journal of the American Chemical Society. 135: 9612-5. PMID 23789917 DOI: 10.1021/Ja404339U  0.795
2013 Guillo P, Fasulo ME, Lipschutz MI, Tilley TD. Synthesis and characterization of tantalum silsesquioxane complexes. Dalton Transactions (Cambridge, England : 2003). 42: 1991-5. PMID 23283146 DOI: 10.1039/C2Dt32601A  0.413
2013 Fasulo ME, Lipke MC, Tilley TD. Structural and mechanistic investigation of a cationic hydrogen-substituted ruthenium silylene catalyst for alkene hydrosilation Chemical Science. 4: 3882-3887. DOI: 10.1039/C3Sc51585K  0.465
2013 Ahn HS, Yano J, Tilley TD. Photocatalytic water oxidation by very small cobalt domains on a silica surface Energy and Environmental Science. 6: 3080-3087. DOI: 10.1039/C3Ee42067A  0.321
2013 Bowring MA, Bergman RG, Tilley TD. Isolation of a dicationic platinum complex with two accessible coordination sites Organometallics. 32: 5266-5268. DOI: 10.1021/Om4008357  0.548
2013 Fasulo ME, Calimano E, Buchanan JM, Tilley TD. Multiple Si-H bond activations by tBu2PCH 2CH2PtBu2 and tBu 2PCH2PtBu2 Di(phosphine) complexes of rhodium and iridium Organometallics. 32: 1016-1028. DOI: 10.1021/Om300943E  0.834
2013 Cordeiro PJ, Guillo P, Spanjers CS, Chang JW, Lipschutz MI, Fasulo ME, Rioux RM, Tilley TD. Titanium-germoxy precursor route to germanium-modified epoxidation catalysts with enhanced activity Acs Catalysis. 3: 2269-2279. DOI: 10.1021/Cs400529X  0.399
2013 Neumeyer F, Lipschutz MI, Tilley TD. Group 8 transition metal complexes of the tripodal triphosphino ligands PhSi(CH2PR2)3 (R = Ph, iPr) European Journal of Inorganic Chemistry. 6075-6078. DOI: 10.1002/Ejic.201301074  0.407
2013 Ahn HS, Tilley TD. Electrocatalytic water oxidation at neutral pH by a nanostructured Co(PO3)2 Anode Advanced Functional Materials. 23: 227-233. DOI: 10.1002/Adfm.201200920  0.314
2012 Lipke MC, Tilley TD. Stabilization of ArSiH4(-) and SiH6(2-) anions in diruthenium Si-H σ-complexes. Angewandte Chemie (International Ed. in English). 51: 11115-21. PMID 23037588 DOI: 10.1002/Anie.201202328  0.399
2012 Fasulo ME, Tilley TD. Synthesis and reactivity of cationic ruthenium germylene complexes [Cp*(PiPr3)RuH2(=GeRR')]+. Chemical Communications (Cambridge, England). 48: 7690-2. PMID 22740052 DOI: 10.1039/C2Cc32840B  0.462
2012 Lipschutz MI, Tilley TD. Synthesis and reactivity of a conveniently prepared two-coordinate bis(amido) nickel(II) complex. Chemical Communications (Cambridge, England). 48: 7146-8. PMID 22692366 DOI: 10.1039/C2Cc32974C  0.432
2012 Wright RJ, Zhang W, Yang X, Fasulo M, Tilley TD. Isolation, observation, and computational modeling of proposed intermediates in catalytic proton reductions with the hydrogenase mimic Fe2(CO)6S2C6H4. Dalton Transactions (Cambridge, England : 2003). 41: 73-82. PMID 22031098 DOI: 10.1039/C1Dt11428J  0.351
2012 Curley JJ, Bergman RG, Tilley TD. Preparation and physical properties of early-late heterobimetallic compounds featuring Ir-M bonds (M = Ti, Zr, Hf). Dalton Transactions (Cambridge, England : 2003). 41: 192-200. PMID 22020701 DOI: 10.1039/C1Dt11753J  0.51
2012 Fasulo ME, Tilley TD. Stoichiometric reaction chemistry of cationic ruthenium silylene complexes toward polar and nonpolar organic substrates Organometallics. 31: 5049-5057. DOI: 10.1021/Om300390N  0.399
2012 Raboin L, Yano J, Tilley TD. Epoxidation catalysts derived from introduction of titanium centers onto the surface of mesoporous aluminophosphate: Comparisons with analogous catalysts based on mesoporous silica Journal of Catalysis. 285: 168-176. DOI: 10.1016/J.Jcat.2011.09.023  0.344
2011 Davenport TC, Tilley TD. Dinucleating naphthyridine-based ligand for assembly of bridged dicopper(I) centers: three-center two-electron bonding involving an acetonitrile donor. Angewandte Chemie (International Ed. in English). 50: 12205-8. PMID 22038762 DOI: 10.1002/Anie.201106081  0.342
2011 Chou NH, Ross PN, Bell AT, Tilley TD. Comparison of cobalt-based nanoparticles as electrocatalysts for water oxidation. Chemsuschem. 4: 1566-9. PMID 21997965 DOI: 10.1002/Cssc.201100075  0.453
2011 Lipke MC, Tilley TD. High electrophilicity at silicon in η3-silane σ-complexes: Lewis base adducts of a silane ligand, featuring octahedral silicon and three Ru-H-Si interactions. Journal of the American Chemical Society. 133: 16374-7. PMID 21936540 DOI: 10.1021/Ja207169E  0.416
2011 Cordeiro PJ, Tilley TD. Enhancement of epoxidation efficiencies for Ta-SBA15 catalysts. The influence of modification with -EMe3 (E = Si, Ge, Sn) groups. Langmuir : the Acs Journal of Surfaces and Colloids. 27: 6295-304. PMID 21517024 DOI: 10.1021/La200090U  0.351
2011 Gessner VH, Tannaci JF, Miller AD, Tilley TD. Assembly of macrocycles by zirconocene-mediated, reversible carbon-carbon bond formation. Accounts of Chemical Research. 44: 435-46. PMID 21473633 DOI: 10.1021/Ar100148G  0.803
2011 Roggan S, Limberg C, Knispel C, Tilley TD. Transition metal complexes of the novel hexadentate ligand 1,4-bis(di(N-methylimidazol-2-yl)methyl)phthalazine. Dalton Transactions (Cambridge, England : 2003). 40: 4315-23. PMID 21409278 DOI: 10.1039/C0Dt01406K  0.469
2011 Gessner VH, Tilley TD. Diphenylanthracene macrocylces from reductive zirconocene coupling: on the edge of steric overload. Organic Letters. 13: 1154-7. PMID 21288005 DOI: 10.1021/Ol2000099  0.592
2011 Kachian JS, Tannaci J, Wright RJ, Tilley TD, Bent SF. Disulfide passivation of the Ge(100)-2 × 1 surface. Langmuir : the Acs Journal of Surfaces and Colloids. 27: 179-86. PMID 21141841 DOI: 10.1021/La103614F  0.774
2011 Waterman R, Tilley TD. Terminal hafnium phosphinidene complexes and phosphinidene ligand exchange Chemical Science. 2: 1320. DOI: 10.1039/C1Sc00119A  0.706
2011 Fasulo ME, Glaser PB, Tilley TD. Cp*(PiPr 3)RuOTf: A reagent for access to ruthenium silylene complexes Organometallics. 30: 5524-5531. DOI: 10.1021/Om200795X  0.811
2011 Bowring MA, Bergman RG, Tilley TD. Disambiguation of metal and Brønsted acid catalyzed pathways for hydroarylation with platinum(II) catalysts Organometallics. 30: 1295-1298. DOI: 10.1021/Om2000458  0.492
2011 Yoon CW, Hirsekorn KF, Neidig ML, Yang X, Tilley TD. Mechanism of the decomposition of aqueous hydrogen peroxide over heterogeneous TiSBA15 and TS-1 selective oxidation catalysts: Insights from spectroscopic and density functional theory studies Acs Catalysis. 1: 1665-1678. DOI: 10.1021/Cs2003774  0.352
2011 Choi YS, Moschetta EG, Miller JT, Fasulo M, McMurdo MJ, Rioux RM, Tilley TD. Highly dispersed Pd-SBA15 materials from tris(tert-butoxy)siloxy complexes of Pd(II) Acs Catalysis. 1: 1166-1177. DOI: 10.1021/Cs2002719  0.793
2011 Cordeiro PJ, Tilley TD. Enhancement of the catalytic activity of titanium-based terminal olefin epoxidation catalysts via surface modification with functionalized protic molecules Acs Catalysis. 1: 455-467. DOI: 10.1021/Cs200017S  0.359
2011 Fasulo ME, Tilley TD. Interligand H⋯Si interactions in tungsten silyl trihydride complexes Journal of Organometallic Chemistry. 696: 1325-1330. DOI: 10.1016/J.Jorganchem.2010.11.046  0.399
2010 Yang J, Tilley TD. Efficient hydrosilylation of carbonyl compounds with the simple amide catalyst [Fe{N(SiMe3)2}2]. Angewandte Chemie (International Ed. in English). 49: 10186-8. PMID 20949580 DOI: 10.1002/Anie.201005055  0.301
2010 Levi ZU, Tilley TD. Synthesis and electronic properties of extended, fused-ring aromatic systems containing multiple pentalene units. Journal of the American Chemical Society. 132: 11012-4. PMID 20698660 DOI: 10.1021/Ja1043159  0.316
2010 Calimano E, Tilley TD. Synthesis and reactivity of rhodium and iridium alkene, alkyl and silyl complexes supported by a phenyl-substituted PNP pincer ligand. Dalton Transactions (Cambridge, England : 2003). 39: 9250-63. PMID 20401366 DOI: 10.1039/B925856F  0.822
2010 Geramita K, Tao Y, Segalman RA, Tilley TD. Synthesis and characterization of fluorinated heterofluorene-containing donor-acceptor systems. The Journal of Organic Chemistry. 75: 1871-87. PMID 20196535 DOI: 10.1021/Jo902488W  0.784
2010 Guihaumé J, Raynaud C, Eisenstein O, Perrin L, Maron L, Tilley TD. Facile interconversion of [Cp2(Cl)Hf(SnH3)] and [Cp2(Cl)Hf(mu-H)SnH2]: DFT investigations of hafnocene stannyl complexes as masked stannylenes. Angewandte Chemie (International Ed. in English). 49: 1816-9. PMID 20135660 DOI: 10.1002/Anie.200906476  0.412
2010 Yang J, Fasulo M, Tilley TD. (MeQn2SiH)Fe[N(SiMe3)2]2 (Qn = 8-quinolyl): An unusual δ-agostic iron complex containing an η1-SiH interaction New Journal of Chemistry. 34: 2528-2529. DOI: 10.1039/C0Nj00554A  0.3
2010 Calimano E, Tilley TD. Reactions of cationic PNP-supported iridium silylene complexes with polar organic substrates Organometallics. 29: 1680-1692. DOI: 10.1021/Om901078D  0.803
2010 McBee JL, Tilley TD. Nucleophilic attack of amides onto coordinated ethylene in platinum complexes supported by a chelating pyridyl-pyrrolide ligand: Azaplatinacyclobutane and vinylamine complexes Organometallics. 29: 184-192. DOI: 10.1021/Om900569B  0.773
2010 Yang J, Del Rosal I, Fasulo M, Sangtrirutnugul P, Maron L, Tilley TD. Nickel complexes with bis(8-quinolyl)silyl ligands. An unusual Ni 3Si2 cluster containing six-coordinate silicon Organometallics. 29: 5544-5550. DOI: 10.1021/Om1004622  0.767
2010 Gerisch M, Krumper JR, Bergman RG, Tilley TD. ChemInform Abstract: Novel Bis(oxazoline) Pincer Ligands: Formation of Mononuclear Rhodium(II) Complexes. Cheminform. 32: no-no. DOI: 10.1002/chin.200140121  0.816
2010 HEYN RH, TILLEY TD. ChemInform Abstract: Platinum-Mediated Reactions of Hydrosilanes. Isolation of a Complex with Bridging Disilene and Silylene Ligands. Cheminform. 23: no-no. DOI: 10.1002/chin.199227237  0.307
2009 McBee JL, Escalada J, Tilley TD. High oxidation state rhodium and iridium bis(silyl)dihydride complexes supported by a chelating pyridyl-pyrrolide ligand. Journal of the American Chemical Society. 131: 12703-13. PMID 19681602 DOI: 10.1021/Ja9035169  0.791
2009 Shinohara A, McBee J, Tilley TD. Germylene and silylene complexes of molybdenum via E-H (E = Ge, Si) bond activations: steric influences on intramolecular MoH...E interactions. Inorganic Chemistry. 48: 8081-3. PMID 19630379 DOI: 10.1021/Ic901168S  0.773
2009 Calimano E, Tilley TD. Synthesis and structure of PNP-supported iridium silyl and silylene complexes: catalytic hydrosilation of alkenes. Journal of the American Chemical Society. 131: 11161-73. PMID 19603748 DOI: 10.1021/Ja903737J  0.818
2009 Wright RJ, Lim C, Tilley TD. Diiron proton reduction catalysts possessing electron-rich and electron-poor naphthalene-1,8-dithiolate ligands. Chemistry (Weinheim An Der Bergstrasse, Germany). 15: 8518-25. PMID 19575350 DOI: 10.1002/Chem.200900989  0.333
2009 Miller AD, McBee JL, Tilley TD. Zirconocene-mediated macrocyclizations of diynes containing di-o-methylphenylene spacers. The Journal of Organic Chemistry. 74: 2880-3. PMID 19323577 DOI: 10.1021/Jo802715M  0.791
2009 Miller AD, Tannaci JF, Johnson SA, Lee H, McBee JL, Tilley TD. Mesityl alkyne substituents for control of regiochemistry and reversibility in zirconocene couplings: new synthetic strategies for unsymmetrical zirconacyclopentadienes and conjugated polymers. Journal of the American Chemical Society. 131: 4917-27. PMID 19296582 DOI: 10.1021/Ja809896T  0.804
2009 Hayes PG, Gribble CW, Waterman R, Tilley TD. A hydrogen-substituted osmium stannylene complex: isomerization to a metallostannylene complex via an unusual alpha-hydrogen migration from tin to osmium. Journal of the American Chemical Society. 131: 4606-7. PMID 19290659 DOI: 10.1021/Ja901050M  0.791
2009 Tannaci JF, Kratter IH, Rider EA, McBee JL, Miller AD, Tilley TD. Stereoselective macrocyclization through zirconocene-mediated coupling of achiral dialkynes. Chemical Communications (Cambridge, England). 233-4. PMID 19099079 DOI: 10.1039/B815750B  0.789
2009 Geramita K, McBee J, Tilley TD. 2,7-Substituted hexafluoroheterofluorenes as potential building blocks for electron transporting materials. The Journal of Organic Chemistry. 74: 820-9. PMID 19067545 DOI: 10.1021/Jo802171T  0.786
2009 McBee JL, Tilley TD. Synthesis and reactivity of iridium and rhodium silyl complexes supported by a bipyridine ligand Organometallics. 28: 5072-5081. DOI: 10.1021/Om900385A  0.789
2009 Hayes PG, Waterman R, Glaser PB, Tilley TD. Synthesis, structure, and reactivity of neutral hydrogen-substituted ruthenium silylene and germylene complexes Organometallics. 28: 5082-5089. DOI: 10.1021/Om900348M  0.829
2009 Tilley TD, McBee JL. Five-coordinate dihydridosilyl platinum(IV) complexes supported by a chelating monoanionic nitrogen-based ligand Organometallics. 28: 3947-3952. DOI: 10.1021/Om9002686  0.801
2009 Perrin L, Maron L, Eisenstein O, Tilley TD. Bond activations of PhSiH 3 by Cp 2SmH: A mechanistic investigation by the DFT method Organometallics. 28: 3767-3775. DOI: 10.1021/Om900106N  0.328
2009 Bazinet P, Tilley TD. Octa- and nonamethylfluorenyl complexes of zirconium(IV) reactive hydride derivatives and reversible hydrogen migrationbetween the metal and the fluorenyl ligand Organometallics. 28: 2285-2293. DOI: 10.1021/Om900047X  0.397
2009 Esswein AJ, Mcmurdo MJ, Ross PN, Bell AT, Tilley TD. Size-dependent activity of Co3O4 nanoparticle anodes for alkaline water electrolysis Journal of Physical Chemistry C. 113: 15068-15072. DOI: 10.1021/Jp904022E  0.766
2009 Bradley CA, Yuhas BD, McMurdo MJ, Tilley TD. Functionalized sìlìcone nanospheres: Synthesis, transition metal immobilization, and catalytic applications Chemistry of Materials. 21: 174-185. DOI: 10.1021/Cm8018154  0.782
2008 McBee JL, Bell AT, Tilley TD. Mechanistic studies of the hydroamination of norbornene with electrophilic platinum complexes: the role of proton transfer. Journal of the American Chemical Society. 130: 16562-71. PMID 19554728 DOI: 10.1021/Ja8030104  0.799
2008 Geramita K, McBee J, Tao Y, Segalman RA, Tilley TD. Synthesis and characterization of 2,7-bis(pentafluorophenylethynyl)hexafluoroheterofluorenes: new materials with high electron affinities. Chemical Communications (Cambridge, England). 5107-9. PMID 18956037 DOI: 10.1039/B813440E  0.78
2008 Tannaci JF, Noji M, McBee JL, Tilley TD. 9,10-Disubstituted octafluoroanthracene derivatives via palladium-catalyzed cross-coupling. The Journal of Organic Chemistry. 73: 7895-900. PMID 18788782 DOI: 10.1021/Jo8017268  0.791
2008 Ruddy DA, Tilley TD. Kinetics and mechanism of olefin epoxidation with aqueous H2O2 and a highly selective surface-modified TaSBA15 heterogeneous catalyst. Journal of the American Chemical Society. 130: 11088-96. PMID 18662001 DOI: 10.1021/Ja8027313  0.698
2008 Calimano E, Tilley TD. Alkene hydrosilation by a cationic hydrogen-substituted iridium silylene complex. Journal of the American Chemical Society. 130: 9226-7. PMID 18582049 DOI: 10.1021/Ja803332H  0.835
2008 Miller AD, McBee JL, Tilley TD. Mechanism of reversible alkyne coupling at zirconocene: ancillary ligand effects. Journal of the American Chemical Society. 130: 4992-9. PMID 18336028 DOI: 10.1021/Ja800025U  0.82
2008 Shinohara A, McBee J, Waterman R, Tilley TD. Paramagnetic Vanadium Silyl Complexes: Synthesis, Structure, and Reactivity Organometallics. 27: 5717-5722. DOI: 10.1021/Om800712K  0.814
2008 Barros N, Eisenstein O, Maron L, Tilley TD. DFT investigation of the catalytic hydromethylation of olefins by scandocenes. 2. Influence of the ansa ligand on propene and isobutene hydromethylation Organometallics. 27: 2252-2257. DOI: 10.1021/Om701270W  0.401
2008 Sangtrirutnugul P, Tilley TD. Alkyl and hydrido complexes of platinum(IV) supported by the bis(8-quinolyl)methylsilyl ligand Organometallics. 27: 2223-2230. DOI: 10.1021/Om701162H  0.782
2008 Bazinet P, Tilley TD. Octa- and nonamethylfluorenyl complexes of Zr(II), Zr(IV), and Hf(IV). Investigation of steric and electronic effects Organometallics. 27: 1267-1274. DOI: 10.1021/Om701133E  0.441
2008 Fischbach A, Bazinet PR, Waterman R, Tilley TD. β-phosphinoethylboranes as ambiphilic ligands in nickel-methyl complexes Organometallics. 27: 1135-1139. DOI: 10.1021/Om7010886  0.66
2008 Ruddy DA, Brutchey RL, Tilley TD. The Influence of Surface Modification on the Epoxidation Selectivity and Mechanism of TiSBA15 and TaSBA15 Catalysts with Aqueous Hydrogen Peroxide Topics in Catalysis. 48: 99-106. DOI: 10.1007/S11244-008-9040-0  0.755
2007 Ruddy DA, Tilley TD. Highly selective olefin epoxidation with aqueous H2O2 over surface-modified TaSBA15 prepared via the TMP method. Chemical Communications (Cambridge, England). 3350-2. PMID 18019495 DOI: 10.1039/B706443H  0.686
2007 Tannaci JF, Noji M, McBee J, Tilley TD. 9,10-Dichlorooctafluoroanthracene as a building block for n-type organic semiconductors. The Journal of Organic Chemistry. 72: 5567-73. PMID 17590045 DOI: 10.1021/Jo070404A  0.785
2007 Waterman R, Hayes PG, Tilley TD. Synthetic development and chemical reactivity of transition-metal silylene complexes. Accounts of Chemical Research. 40: 712-9. PMID 17477497 DOI: 10.1002/CHIN.200744223  0.775
2007 Sangtrirutnugul P, Tilley TD. Silyl derivatives of [Bis(8-quinolyl)methylsilyl]iridium(III) complexes: Catalytic redistribution of arylsilanes and dehydrogenative arene silylation Organometallics. 26: 5557-5568. DOI: 10.1021/Om700494Q  0.797
2007 Bradley CA, McMurdo MJ, Tilley TD. Selective catalytic cyclohexene oxidation using titanium-functionalized silicone nanospheres? Journal of Physical Chemistry C. 111: 17570-17579. DOI: 10.1021/Jp074512C  0.798
2007 Borodko Y, Humphrey SM, Tilley TD, Frei H, Somorjai GA. Charge-transfer interaction of poly(vinylpyrrolidone) with platinum and rhodium nanoparticles Journal of Physical Chemistry C. 111: 6288-6295. DOI: 10.1021/Jp068742N  0.332
2006 Waterman R, Tilley TD. Antimony-antimony bond formation by reductive elimination from a hafnium bis(stibido) complex. Inorganic Chemistry. 45: 9625-7. PMID 17112252 DOI: 10.1021/Ic061826Q  0.705
2006 Han LB, Tilley TD. Selective homo- and heterodehydrocouplings of phosphines catalyzed by rhodium phosphido complexes. Journal of the American Chemical Society. 128: 13698-9. PMID 17044692 DOI: 10.1021/Ja065346+  0.451
2006 Waterman R, Tilley TD. Terminal stibinidene ligands. Generation of CpCp*Hf=Sb(dmp) and trapping reactions with PMe3 and 2-butyne. Chemical Communications (Cambridge, England). 4030-2. PMID 17003889 DOI: 10.1039/B609773A  0.624
2006 Waterman R, Tilley TD. Catalytic antimony-antimony bond formation through stibinidene elimination from zirconocene and hafnocene complexes. Angewandte Chemie (International Ed. in English). 45: 2926-9. PMID 16555350 DOI: 10.1002/Anie.200600318  0.68
2006 Hayes PG, Beddie C, Hall MB, Waterman R, Tilley TD. Hydrogen-substituted osmium silylene complexes: effect of charge localization on catalytic hydrosilation. Journal of the American Chemical Society. 128: 428-9. PMID 16402827 DOI: 10.1021/Ja057494Q  0.792
2006 Barros N, Eisenstein O, Maron L, Tilley TD. DFT investigation of the catalytic hydromethylation of α-olefins by metallocenes. 1. Differences between scandium and lutetium in propene hydromethylation Organometallics. 25: 5699-5708. DOI: 10.1021/Om060498Z  0.324
2006 Bazinet P, Tupper KA, Tilley TD. Octa- and nonamethylfluorene and an electron-rich permethylfluorenyl ruthenocene derivative Organometallics. 25: 4286-4291. DOI: 10.1021/Om0603464  0.423
2006 Geramita K, McBee J, Shen Y, Radu N, Tilley TD. Synthesis and characterization of perfluoroaryl-substituted siloles and thiophenes: A series of electron-deficient blue light emitting materials Chemistry of Materials. 18: 3261-3269. DOI: 10.1021/Cm060346U  0.781
2006 Fontaine FG, Tupper KA, Tilley TD. Synthesis, characterization and reactivity of tetramethylphospholyl complexes of scandium Journal of Organometallic Chemistry. 691: 4595-4600. DOI: 10.1016/J.Jorganchem.2006.06.042  0.735
2006 Ruddy DA, Ohler NL, Bell AT, Tilley TD. Thermolytic molecular precursor route to site-isolated vanadia-silica materials and their catalytic performance in methane selective oxidation Journal of Catalysis. 238: 277-285. DOI: 10.1016/J.Jcat.2005.11.032  0.716
2005 Neale NR, Tilley TD. Synthesis, structure, and alpha-elimination chemistry of hafnocene triarylstannyl complexes. Journal of the American Chemical Society. 127: 14745-55. PMID 16231929 DOI: 10.1021/Ja0529586  0.666
2005 Brutchey RL, Ruddy DA, Andersen LK, Tilley TD. Influence of surface modification of Ti-SBA15 catalysts on the epoxidation mechanism for cyclohexene with aqueous hydrogen peroxide. Langmuir : the Acs Journal of Surfaces and Colloids. 21: 9576-83. PMID 16207038 DOI: 10.1021/La051182J  0.765
2005 Karshtedt D, Bell AT, Tilley TD. Platinum-based catalysts for the hydroamination of olefins with sulfonamides and weakly basic anilines. Journal of the American Chemical Society. 127: 12640-6. PMID 16144412 DOI: 10.1021/Ja052836D  0.809
2005 Brutchey RL, Drake IJ, Bell AT, Tilley TD. Liquid-phase oxidation of alkylaromatics by a H-atom transfer mechanism with a new heterogeneous CoSBA-15 catalyst. Chemical Communications (Cambridge, England). 3736-8. PMID 16027928 DOI: 10.1039/B506426K  0.68
2005 Sadow AD, Tilley TD. Synthesis and characterization of scandium silyl complexes of the type Cp*2ScSiHRR'. sigma-Bond metathesis reactions and catalytic dehydrogenative silation of hydrocarbons. Journal of the American Chemical Society. 127: 643-56. PMID 15643889 DOI: 10.1021/Ja040141R  0.704
2005 Fontaine FG, Tilley TD. Control of selectivity in the hydromethylation of olefins via ligand modification in scandocene catalysts Organometallics. 24: 4340-4342. DOI: 10.1021/Om0505460  0.759
2005 Jarupatrakorn J, Coles MP, Tilley TD. Synthesis and characterization of MO[OSi(OtBu)3] 4 and MO2[OSt(O≤Bu)3]2 (M = Mo, W): Models for isolated oxo-molybdenum and -tungsten sites on silica and precursors to molybdena- And tungsta-silica materials Chemistry of Materials. 17: 1818-1828. DOI: 10.1021/Cm040344E  0.81
2005 Brutchey RL, Mork BV, Sirbuly DJ, Yang P, Tilley TD. A dimeric molecular precursor [(tBuO)2Ti{μ-O 2Si[OSi(OtBu)3]2}]2 to Ti(IV)/SiO2 catalysts for selective cyclohexene epoxidation Journal of Molecular Catalysis a: Chemical. 238: 1-12. DOI: 10.1016/J.Molcata.2005.04.032  0.821
2005 Tupper KA, Tilley TD. Synthesis and characterization of scandium complexes with reduced ligands: Crystal structures of Cp*ScI2, [C*ScI(bpy)]2, and [Cp*ScCl(bpy)]2 Journal of Organometallic Chemistry. 690: 1689-1698. DOI: 10.1016/J.Jorganchem.2005.01.017  0.435
2005 Holland AW, Li G, Shahin AM, Long GJ, Bell AT, Tilley TD. New Fe/SiO2 materials prepared using diiron molecular precursors: Synthesis, characterization and catalysis Journal of Catalysis. 235: 150-163. DOI: 10.1016/J.Jcat.2005.07.003  0.515
2005 Brutchey RL, Lugmair CG, Schebaum LO, Tilley TD. Thermolytic conversion of a bis(alkoxy)tris(siloxy)tantalum(V) single-source molecular precursor to catalytic tantala-silica materials Journal of Catalysis. 229: 72-81. DOI: 10.1016/J.Jcat.2004.10.015  0.582
2005 Drake IJ, Fujdala KL, Bell AT, Tilley TD. Dimethyl carbonate production via the oxidative carbonylation of methanol over Cu/SiO2 catalysts prepared via molecular precursor grafting and chemical vapor deposition approaches Journal of Catalysis. 230: 14-27. DOI: 10.1016/J.Jcat.2004.10.001  0.763
2005 Hess C, Drake IJ, Hoefelmeyer JD, Tilley TD, Bell AT. Partial oxidation of methanol over highly dispersed vanadia supported on silica SBA-15 Catalysis Letters. 105: 1-8. DOI: 10.1007/S10562-005-7997-X  0.487
2005 Fujdala KL, Tilley TD. Synthesis and characterization of Et2NM{OB[OSi(O tBu)3]2}3 (M = Zr, Hf) molecular precursors to Zr/B/Si/O and Hf/B/Si/O materials Zeitschrift Fur Anorganische Und Allgemeine Chemie. 631: 2619-2622. DOI: 10.1002/Zaac.200500128  0.77
2005 Klei SR, Tan KL, Golden JT, Yung CM, Thalji RK, Ahrendt KA, Ellman JA, Tilley TD, Bergman RG. C—H Bond Activation by Iridium and Rhodium Complexes: Catalytic Hydrogen—Deuterium Exchange and C—C Bond-Forming Reactions Cheminform. 36. DOI: 10.1002/chin.200524251  0.45
2005 Ruddy DA, Ohler NL, Bell AT, Tilley TD. Thermolytic molecular precursor route to site-isolated vanadia-silica catalyts for methane partial oxidation Acs National Meeting Book of Abstracts. 229: INOR-841.  0.615
2004 Jarupatrakorn J, Tilley TD. Synthesis and characterization of [(diene)Rh[mu-OSi(OtBu)3]]2, a precursor to silica-bound rhodium. Dalton Transactions (Cambridge, England : 2003). 2808-13. PMID 15514769 DOI: 10.1039/B407398C  0.823
2004 Krumper JR, Gerisch M, Magistrato A, Rothlisberger U, Bergman RG, Tilley TD. Unusual Ar-H/Rh-H J(HH) NMR coupling in complexes of rhodium(III): experimental evidence and theoretical support for an eta1-arene structure. Journal of the American Chemical Society. 126: 12492-502. PMID 15453783 DOI: 10.1021/Ja047665B  0.814
2004 Fujdala KL, Drake IJ, Bell AT, Tilley TD. Atomic level control over surface species via a molecular precursor approach: isolated Cu(I) sites and Cu nanoparticles supported on mesoporous silica. Journal of the American Chemical Society. 126: 10864-6. PMID 15339170 DOI: 10.1021/Ja048701+  0.752
2004 Mork BV, Tilley TD, Schultz AJ, Cowan JA. Silylene hydride complexes of molybdenum with silicon-hydrogen interactions: neutron structure of (eta(5)-C(5)Me(5))(Me(2)PCH(2)CH(2)PMe(2))Mo(H)(SiEt(2)). Journal of the American Chemical Society. 126: 10428-40. PMID 15315459 DOI: 10.1021/Ja040026G  0.831
2004 Gavenonis J, Tilley TD. Synthesis and reactivity of tris(imido)rhenium complexes containing rhenium-main group element bonds. silicon-carbon bond activations of PhSiH(3) by silyl complexes. Inorganic Chemistry. 43: 4353-62. PMID 15236548 DOI: 10.1021/Ic030282E  0.823
2004 Mork BV, Tilley TD. Synthons for coordinatively unsaturated complexes of tungsten, and their use for the synthesis of high oxidation-state silylene complexes. Journal of the American Chemical Society. 126: 4375-85. PMID 15053627 DOI: 10.1021/Ja030548G  0.83
2004 Lugmair CG, Tilley TD. Synthesis and reactivity of Ti(III) Tris(tert-butoxy)siloxy complexes Zeitschrift Fur Naturforschung - Section B Journal of Chemical Sciences. 59: 1540-1547. DOI: 10.1515/Znb-2004-11-1226  0.314
2004 Karshtedt D, Bell AT, Tilley TD. Pt-Ag catalyst system for hydroarylations with unactivated arenes and olefins Acs National Meeting Book of Abstracts. 228: INOR-45. DOI: 10.1021/Om0495325  0.796
2004 Karshtedt D, Bell AT, Tilley TD. Pt-Ag catalyst system for hydroarylations with unactivated arenes and olefins Acs National Meeting Book of Abstracts. 228: INOR-45. DOI: 10.1021/om0495325  0.778
2004 Mork BV, McMillan A, Yuen H, Tilley TD. The [(η 5-C 5Me 5)(2,2′-bipyridine) ru] - anion and its use in the synthesis of alkyl, gallyl, and stannyl complexes of ruthenium Organometallics. 23: 2855-2859. DOI: 10.1021/Om030695N  0.824
2004 Turculet L, Feldman JD, Tilley TD. Coordination chemistry and reactivity of new zwitterionic rhodium and iridium complexes featuring the tripodal phosphine ligand [PhB(CH 2P iPr 2) 3] -. Activation of H-H, Si-H, and ligand B-C bonds Organometallics. 23: 2488-2502. DOI: 10.1021/Om030686E  0.676
2004 Turculet L, Tilley TD. Synthesis and reactivity of d0 alkyl, silyl, and hydride complexes of titanium and zirconium featuring an aryl-substituted tripodal triamido ligand derived from cis, cis-1,3,5-triaminocyclohexane Organometallics. 23: 1542-1553. DOI: 10.1021/Om0306832  0.32
2004 Gavenonis J, Tilley TD. Synthesis and reactivity of alkyl, hydride, and silyl derivatives of the (terphenyl)imido fragments Cp*(ArMesN=)Ta (Cp* = η5-C5Me5 (see abstract) Organometallics. 23: 31-43. DOI: 10.1021/Om030567Z  0.829
2004 Han WQ, Brutchey R, Tilley TD, Zettl A. Activated Boron Nitride Derived from Activated Carbon Nano Letters. 4: 173-176. DOI: 10.1021/Nl034843A  0.536
2004 Drake IJ, Fujdala KL, Baxamusa S, Bell AT, Tilley TD. Effects of precursor composition on the local structure of Cu dispersed on mesoporous silica: A detailed X-ray absorption spectroscopy study Journal of Physical Chemistry B. 108: 18421-18434. DOI: 10.1021/Jp040255P  0.766
2004 Hess C, Hoefelmeyer JD, Tilley TD. Spectroscopic Characterization of Highly Dispersed Vanadia Supported on SBA-15 The Journal of Physical Chemistry B. 108: 9703-9709. DOI: 10.1021/Jp037714R  0.327
2004 Dai H, Chen L, Tilley TD, Iglesia E, Bell AT. Effects of additives on the activity and selectivity of supported vanadia catalysts for the oxidative dehydrogenation of propane Studies in Surface Science and Catalysis. 147: 679-684. DOI: 10.1016/S0167-2991(04)80131-9  0.45
2004 Neale NR, Tilley TD. Reactions of hafnocene stannyl complexes with stannanes: Implications for the mechanism of the metal-catalyzed dehydropolymerization of secondary stannanes Tetrahedron. 60: 7247-7260. DOI: 10.1016/J.Tet.2004.06.064  0.704
2004 Evans OR, Bell AT, Tilley TD. Oxidative dehydrogenation of propane over vanadia-based catalysts supported on high-surface-area mesoporous MgAl2O4 Journal of Catalysis. 226: 292-300. DOI: 10.1016/J.Jcat.2004.06.002  0.462
2004 Bell AT, Drake IJ, Fujdala KL, Tilley TD. Effects of Cu dispersion and oxidation state on the activity and selectivity of silica-supported Cu for the synthesis of dimethyl carbonate Acs National Meeting Book of Abstracts. 228: CATL-1.  0.707
2004 Gavenonis J, Tilley TD. Synthesis and reactivity of tris(imido)rhenium complexes containing rhenium-main group element bonds. Silicon-carbon bond activations of PhSiH 3 by silyl complexes Inorganic Chemistry. 43: 4353-4362.  0.791
2003 Krumper JR, Gerisch M, Suh JM, Bergman RG, Tilley TD. Monomeric rhodium(II) catalysts for the preparation of aziridines and enantioselective formation of cyclopropanes from ethyl diazoacetate at room temperature. The Journal of Organic Chemistry. 68: 9705-10. PMID 14656097 DOI: 10.1021/Jo035120E  0.816
2003 Glaser PB, Tilley TD. Catalytic hydrosilylation of alkenes by a ruthenium silylene complex. Evidence for a new hydrosilylation mechanism. Journal of the American Chemical Society. 125: 13640-1. PMID 14599184 DOI: 10.1021/Ja037620V  0.813
2003 Sadow AD, Tilley TD. Cationic hafnium silyl complexes and their enhanced reactivity in sigma-bond metathesis processes with Si-H and C-H bonds. Journal of the American Chemical Society. 125: 9462-75. PMID 12889977 DOI: 10.1021/Ja030024G  0.678
2003 Sadow AD, Tilley TD. Homogeneous catalysis with methane. A strategy for the hydromethylation of olefins based on the nondegenerate exchange of alkyl groups and sigma-bond metathesis at scandium. Journal of the American Chemical Society. 125: 7971-7. PMID 12823019 DOI: 10.1021/Ja021341A  0.649
2003 Johnson SA, Liu FQ, Suh MC, Zürcher S, Haufe M, Mao SS, Tilley TD. Regioselective coupling of pentafluorophenyl substituted alkynes: mechanistic insight into the zirconocene coupling of alkynes and a facile route to conjugated polymers bearing electron-withdrawing pentafluorophenyl substituents. Journal of the American Chemical Society. 125: 4199-211. PMID 12670242 DOI: 10.1021/Ja0209161  0.562
2003 Sadow AD, Tilley TD. Catalytic functionalization of hydrocarbons by sigma-bond-metathesis chemistry: dehydrosilylation of methane with a scandium catalyst. Angewandte Chemie (International Ed. in English). 42: 803-5. PMID 12596205 DOI: 10.1002/Anie.200390213  0.629
2003 Fujdala KL, Oliver AG, Hollander FJ, Tilley TD. Tris(tert-butoxy)siloxy derivatives of boron, including the boronous acid HOB[OSi(O(t)Bu)(3)](2) and the metal (siloxy)boryloxide complex Cp(2)Zr(Me)OB[OSi(O(t)Bu)(3)](2): a remarkable crystal structure with 18 independent molecules in its asymmetric unit. Inorganic Chemistry. 42: 1140-50. PMID 12588150 DOI: 10.1021/Ic0205482  0.755
2003 Mork BV, Tilley TD. Multiple bonding between silicon and molybdenum: a transition-metal complex with considerable silylyne character. Angewandte Chemie (International Ed. in English). 42: 357-60. PMID 12548699 DOI: 10.1002/Anie.200390116  0.797
2003 Feldman JD, Mitchell GP, Nolte JO, Tilley TD. Synthesis and study of platinum silylene complexes of the type (R 3P)2Pt=SiMes2 (Mes = 2,4,6-trimethylphenyl) Canadian Journal of Chemistry. 81: 1127-1136. DOI: 10.1139/V03-018  0.647
2003 Turculet L, Feldman JD, Tilley TD. Coordinatively and electronically unsaturated zwitterionic iron silyl complexes featuring the tripodal phosphine ligand [PhB(CH2PiPr2)3]- Organometallics. 22: 4627-4629. DOI: 10.1021/Om030568R  0.629
2003 Karshtedt D, Bell AT, Tilley TD. Synthesis and study of heterobimetallic complexes supported by a ferrocene-based bisphosphine-diamine ligand Organometallics. 22: 2855-2861. DOI: 10.1021/Om0300631  0.812
2003 Sadow AD, Tilley TD. Enhanced reactivity of cationic hafnocene complexes toward σ-bond metathesis reactions. Si-H and Si-C bond activations in stoichiometric and catalytic organosilane conversions Organometallics. 22: 3577-3585. DOI: 10.1021/Om0210107  0.685
2003 Gerisch M, Krumper JR, Bergman RG, Tilley TD. Rhodium(III) and rhodium(II) complexes of novel bis(oxazoline) pincer ligands Organometallics. 22: 47-58. DOI: 10.1021/Om0207562  0.826
2003 Brutchey RL, Goldberger JE, Koffas TS, Tilley TD. Nonaqueous, molecular precursor route to hybrid inorganic/organic zirconia-silica materials containing covalently linked organic bridges Chemistry of Materials. 15: 1040-1046. DOI: 10.1021/Cm020653+  0.625
2003 Fujdala KL, Tilley TD. Thermolytic molecular precursor routes to Cr/Si/Al/O and Cr/Si/Zr/O catalysts for the oxidative dehydrogenation and dehydrogenation of propane Journal of Catalysis. 218: 123-134. DOI: 10.1016/S0021-9517(03)00141-6  0.748
2003 Fujdala KL, Tilley TD. Design and synthesis of heterogeneous catalysts: The thermolytic molecular precursor approach Journal of Catalysis. 216: 265-275. DOI: 10.1016/S0021-9517(02)00106-9  0.746
2003 Gountchev TI, Tilley T. Synthesis of chelating, C2-symmetric bis(silylamido) complexes of zirconium, and their activities as olefin polymerization catalysts Inorganica Chimica Acta. 345: 81-88. DOI: 10.1016/S0020-1693(02)01295-1  0.456
2002 Nozaki C, Lugmair CG, Bell AT, Tilley TD. Synthesis, characterization, and catalytic performance of single-site iron(III) centers on the surface of SBA-15 silica. Journal of the American Chemical Society. 124: 13194-203. PMID 12405848 DOI: 10.1021/Ja020388T  0.487
2002 Gavenonis J, Tilley TD. Reversible intramolecular hydride transfer between tantalum and an aromatic ring: an eta(5)-cyclohexadienyl complex as a masked hydride. Journal of the American Chemical Society. 124: 8536-7. PMID 12121088 DOI: 10.1021/Ja025684K  0.82
2002 Sadow AD, Tilley TD. Activation of arene C[bond]H bonds by a cationic hafnium silyl complex possessing an alpha-agostic Si[bond]H interaction. Journal of the American Chemical Society. 124: 6814-5. PMID 12059188 DOI: 10.1021/Ja025940T  0.657
2002 Neale NR, Tilley TD. A new mechanism for metal-catalyzed stannane dehydrocoupling based on alpha-H-elimination in a hafnium hydrostannyl complex. Journal of the American Chemical Society. 124: 3802-3. PMID 11942796 DOI: 10.1021/Ja017495S  0.705
2002 Klei SR, Golden JT, Tilley TD, Bergman RG. Iridium-catalyzed H/D exchange into organic compounds in water. Journal of the American Chemical Society. 124: 2092-3. PMID 11878944 DOI: 10.1021/Ja017219D  0.524
2002 Schafer LL, Nitschke JR, Mao SS, Liu FQ, Harder G, Haufe M, Tilley TD. Zirconocene-mediated, high-yielding macrocyclizations of silyl-terminated diynes. Chemistry (Weinheim An Der Bergstrasse, Germany). 8: 74-83. PMID 11826866 DOI: 10.1002/1521-3765(20020104)8:1<74::Aid-Chem74>3.0.Co;2-P  0.705
2002 Gavenonis J, Tilley TD. Tantalum alkyl and silyl complexes of the bulky (terphenyl)imido ligand Organometallics. 21: 5549-5563. DOI: 10.1021/Om020509Y  0.806
2002 Feldman JD, Peters JC, Tilley TD. Structural and chemical properties of zwitterionic iridium complexes featuring the tripodal phosphine ligand [PhB(CH2PPh2)3]- Organometallics. 21: 4050-4064. DOI: 10.1021/Om0205086  0.73
2002 Turculet L, Tilley TD. Zirconium amide, halide, and alkyl complexes supported by tripodal amido ligands derived from cis,cis-1,3,5-triaminocyclohexane Organometallics. 21: 3961-3972. DOI: 10.1021/Om020414W  0.408
2002 Klei SR, Tilley TD, Bergman RG. Iridium (III) and rhodium (III) complexes bearing chelating cyclopentadienyl-phosphine ligands as C-H activation catalysts for the deuteration of hydrocarbons in D2O Organometallics. 21: 4905-4911. DOI: 10.1021/Om020375O  0.607
2002 Burckhardt U, Casty GL, Gavenonis J, Tilley TD. Neutral and anionic silyl hydride derivatives of the tantalum imido fragment Cp*(DippN=)Ta (Cp* = η5-C5Me5; Dipp = 2,6-iPr2C6H3). Reactive σ-bonds and intramolecular C-H bond activations involving the silyl ligands Organometallics. 21: 3108-3122. DOI: 10.1021/Om0203227  0.828
2002 Freeman WP, Dysard JM, Tilley TD, Rheingold AL. Synthesis and reactivity of η5-germacyclopentadienyl complexes of iron Organometallics. 21: 1734-1738. DOI: 10.1021/Om0110991  0.817
2002 Fujdala KL, Tilley TD. New vanadium tris(tert-butoxy)siloxy complexes and their thermolytic conversions to vanadia-silica materials Chemistry of Materials. 14: 1376-1384. DOI: 10.1021/Cm011524G  0.769
2002 Lugmair CG, Fujdala KL, Tilley TD. New tris(tert-butoxy)siloxy complexes of aluminum and their transformation to homogeneous aluminosilicate materials via low-temperature thermolytic pathways Chemistry of Materials. 14: 888-898. DOI: 10.1021/Cm010846H  0.756
2002 Tilley TD. Molecular design and synthesis of heterogeneous and single-site, supported catalysts Journal of Molecular Catalysis a: Chemical. 182: 17-24. DOI: 10.1016/S1381-1169(01)00461-7  0.325
2002 Castillo I, Tilley TD. Hafnium imido complexes containing silyl ligands Journal of Organometallic Chemistry. 643: 431-440. DOI: 10.1016/S0022-328X(01)01386-9  0.437
2002 Heyn RH, Tilley TD. Coordinatively and electronically unsaturated tris(trimethylsilyl)silyl complexes of manganese and iron Inorganica Chimica Acta. 341: 91-98. DOI: 10.1016/S0020-1693(02)01182-9  0.4
2002 Pak C, Bell AT, Tilley TD. Oxidative dehydrogenation of propane over vanadia-magnesia catalysts prepared by thermolysis of OV(OtBu)3 in the presence of nanocrystalline MgO Journal of Catalysis. 206: 49-59. DOI: 10.1006/Jcat.2001.3473  0.44
2001 Nitschke JR, Tilley TD. Novel Templating Effect in the Macrocyclization of Functionalized Diynes by Zirconocene Coupling. Angewandte Chemie (International Ed. in English). 40: 2142-2145. PMID 29712218 DOI: 10.1002/1521-3773(20010601)40:11<2142::Aid-Anie2142>3.0.Co;2-3  0.546
2001 Castillo I, Tilley TD. Mechanistic aspects of samarium-mediated sigma-bond activations of arene C-H and arylsilane Si-C bonds. Journal of the American Chemical Society. 123: 10526-34. PMID 11673984 DOI: 10.1021/Ja011472W  0.652
2001 Nitschke JR, Tilley TD. Efficient, high-yield route to long, functionalized p-phenylene oligomers containing perfluorinated segments, and their cyclodimerizations by zirconocene coupling. Journal of the American Chemical Society. 123: 10183-90. PMID 11603967 DOI: 10.1021/Ja011018S  0.584
2001 Fujdala KL, Tilley TD. An efficient, single-source molecular precursor to silicoaluminophosphates. Journal of the American Chemical Society. 123: 10133-4. PMID 11592907 DOI: 10.1021/Ja0167295  0.715
2001 Mork BV, Tilley TD. High oxidation-state (formally d(0)) tungsten silylene complexes via double Si-H bond activation. Journal of the American Chemical Society. 123: 9702-3. PMID 11572703 DOI: 10.1021/ja0165436  0.807
2001 Payne CK, Snee PT, Yang H, Kotz KT, Schafer LL, Tilley TD, Harris CB. Intramolecular rearrangements on ultrafast timescales: femtosecond infrared studies of ring slip in (eta(1)-C(5)Cl(5))Mn(CO)(5). Journal of the American Chemical Society. 123: 7425-6. PMID 11472175 DOI: 10.1021/ja003905l  0.546
2001 Schafer LL, Tilley TD. Efficient diastereoselective syntheses of chiral macrocycles via zirconocene coupling. Synthetic control of size and geometry. Journal of the American Chemical Society. 123: 2683-4. PMID 11456946 DOI: 10.1021/Ja015509O  0.572
2001 Nitschke JR, Tilley TD. Novel Templating Effect in the Macrocyclization of Functionalized Diynes by Zirconocene Coupling This work was supported by the Director, Office of Basic Energy Sciences, Chemical Sciences Division, of the U.S. Department of Energy under Contract No. DE-AC03-76SF00098. The Center for New Directions in Organic Synthesis is supported by Bristol-Myers Squibb as Sponsoring Member. We also thank Dr. F. J. Hollander of the U.C. Berkeley X-ray diffraction facility (CHEXRAY) for help with determination of the X-ray structures. Angewandte Chemie (International Ed. in English). 40: 2142-2145. PMID 11433471 DOI: 10.1002/1521-3773(20010601)40:11<2142::AID-ANIE2142>3.0.CO;2-3  0.468
2001 Gerisch M, Krumper JR, Bergman RG, Tilley TD. Novel bis(oxazoline) pincer ligands: formation of mononuclear rhodium(II) complexes. Journal of the American Chemical Society. 123: 5818-9. PMID 11403623 DOI: 10.1021/Ja005857A  0.815
2001 Stradiotto M, Fujdala KL, Tilley TD. Iridium(III) complexes of the new tridentate bis(8-quinolyl)silyl (‘NSiN’) ligand Chemical Communications. 1200-1201. DOI: 10.1039/B102821A  0.827
2001 Kriesel JW, Tilley TD. A new molecular precursor for magnesia-silica materials Journal of Materials Chemistry. 11: 1081-1085. DOI: 10.1039/B007742I  0.783
2001 Nakamoto M, Tilley TD. Reactions of zirconacyclopentadienes with nitrosobenzene. Characterization of zirconacycle intermediates and formation of N-phenylpyrroles Organometallics. 20: 5515-5517. DOI: 10.1021/Om010873H  0.328
2001 Sadow AD, Tilley TD. Enhanced reactivity of cationic vs neutral hafnocene complexes in stoichiometric and catalytic σ-bond metathesis reactions involving Si-H and Si-C bonds Organometallics. 20: 4457-4459. DOI: 10.1021/Om010737C  0.688
2001 Castillo I, Tilley TD. Organolutetium complexes in σ-bond metathesis reactions involving silicon. Catalysts for the hydrogenolysis of Si-C bonds Organometallics. 20: 5598-5605. DOI: 10.1021/Om010709U  0.653
2001 Dysard JM, Tilley TD, Woo TK. Silabenzene and disilabenzene complexes of ruthenium Organometallics. 20: 1195-1203. DOI: 10.1021/Om000829M  0.836
2001 Kriesel JW, Sander MS, Tilley TD. Block copolymer-assisted synthesis of mesoporous, multicomponent oxides by nonhydrolytic, thermolytic decomposition of molecular precursors in nonpolar media Chemistry of Materials. 13: 3554-3563. DOI: 10.1021/Cm010068T  0.777
2001 Fujdala KL, Tilley TD. Thermolytic transformation of tris(alkoxy)siloxychromium(IV) single-source molecular precursors to catalytic chromia-silica materials Chemistry of Materials. 13: 1817-1827. DOI: 10.1021/Cm010027X  0.762
2001 Kriesel JW, Tilley TD. Carbosilane dendrimers as nanoscopic building blocks for hybrid organic-inorganic materials and catalyst supports Advanced Materials. 13: 1645-1648. DOI: 10.1002/1521-4095(200111)13:21<1645::Aid-Adma1645>3.0.Co;2-1  0.775
2001 Kriesel JW, Sander MS, Tilley TD. General route to homogeneous, mesoporous, multicomponent oxides based on the thermolytic transformation of molecular precursors in non-polar media Advanced Materials. 13: 331-335. DOI: 10.1002/1521-4095(200103)13:5<331::Aid-Adma331>3.0.Co;2-0  0.768
2001 Glaser P, Tilley T. Synthesis and Chemistry of the 16-Electron Osmium Complex [OsBr(η5-C5Me5)(PiPr3)] European Journal of Inorganic Chemistry. 2001: 2747. DOI: 10.1002/1099-0682(200111)2001:11<2747::Aid-Ejic2747>3.0.Co;2-B  0.823
2000 Rulkens R, Coles MP, Tilley TD. Synthesis and Structure of the (tetrahydroxy)oligosiloxane [(tBuO)3SiOSi(OH)2]2O Journal of the Chemical Society-Dalton Transactions. 627-628. DOI: 10.1039/B000322K  0.309
2000 Dysard JM, Tilley TD. Synthesis and Reactivity of (Pentamethylcyclopentadienyl)ruthenium Complexes of the Stable Neutral Silylene Si(tBuNCHCHNtBu) Organometallics. 19: 4726-4732. DOI: 10.1021/Om000517J  0.47
2000 Castillo I, Tilley TD. Synthesis of Sm−SiH3Complexes via σ-Bond Metathesis of the Si−C Bond of Phenylsilane Organometallics. 19: 4733-4739. DOI: 10.1021/Om000516R  0.444
2000 Burckhardt U, Casty GL, Tilley TD, Woo TK, Rothlisberger U. Ditantalum Hydride Complexes with Bridging (2,6-iPr2C6H3)NSiHPh Silanimine Ligands Resulting from PhSiH3−Imido Ligand Coupling. A Combined Spectroscopic and Theoretical Investigation Organometallics. 19: 3830-3841. DOI: 10.1021/Om000455X  0.465
2000 Dysard JM, Tilley TD. Hafnium−Rhodium and Hafnium−Iridium Heterobimetallic Complexes Featuring the Bridging Germole Dianion Ligand [GeC4Me4]2- Organometallics. 19: 2671-2675. DOI: 10.1021/Om000220L  0.481
2000 Lu VY, Tilley TD. Poly(diaryl)stannanes: Influence of substituents on the σ-σ* transition energy Macromolecules. 33: 2403-2412. DOI: 10.1021/Ma991556D  0.308
2000 Dysard JM, Tilley TD. Synthesis and reactivity of η5-silolyl, η5-germolyl, and η5- germole dianion complexes of zirconium and hafnium Journal of the American Chemical Society. 122: 3097-3105. DOI: 10.1021/Ja993563N  0.829
2000 Wanandi PW, Glaser PB, Tilley TD. Reactivity of an osmium silylene complex toward chlorocarbons: Promotion of metal redox chemistry by a silylene ligand and relevance to the mechanism of the direct process [12] Journal of the American Chemical Society. 122: 972-973. DOI: 10.1021/Ja993089L  0.795
2000 Klei SR, Tilley TD, Bergman RG. The mechanism of silicon-hydrogen and carbon-hydrogen bond activation by iridium(III): Production of a silylene complex and the first direct observation of Ir(III)/Ir(V) C-H bond oxidative addition and reductive elimination [8] Journal of the American Chemical Society. 122: 1816-1817. DOI: 10.1021/Ja992954Z  0.496
2000 Nitschke JR, Zurcher S, Tilley TD. New zirconocene-coupling route to large, functionalized macrocycles Journal of the American Chemical Society. 122: 10345-10352. DOI: 10.1021/Ja0020310  0.584
2000 Coles MP, Lugmair CG, Terry KW, Tilley TD. Titania−Silica Materials from the Molecular Precursor Ti[OSi(OtBu)3]4:  Selective Epoxidation Catalysts Chemistry of Materials. 12: 122-131. DOI: 10.1021/Cm990444Y  0.353
1999 Gountchev TI, Tilley TD. Hydrosilylation Catalysis byC2-Symmetric Bis(silylamido) Complexes of Yttrium Organometallics. 18: 5661-5667. DOI: 10.1021/Om990690J  0.441
1999 Gountchev TI, Tilley TD. Yttrium Complexes of the Chelating,C2-Symmetric, Bis(silylamido)biphenyl Ligand [DADMB]2-(={[6,6‘-Me2-(C6H3)2](2,2‘-NSiMe2tBu)2}2-) Organometallics. 18: 2896-2905. DOI: 10.1021/Om9901170  0.484
1999 Peters JC, Feldman JD, Tilley TD. Silylene extrusion from a silane: Direct conversion of Mes2SiH2 to an iridium silylene dihydride [1] Journal of the American Chemical Society. 121: 9871-9872. DOI: 10.1021/Ja992367D  0.655
1999 Burckhardt U, Tilley TD. Carbonylation chemistry of the tantalum silyl hydride Cp*(2,6- (i)Pr2C6H3N=)Ta[Si(SiMe3)3]H: The unexpected formation of a Ta(V) carbonyl complex and the complete reduction of CO [12] Journal of the American Chemical Society. 121: 6328-6329. DOI: 10.1021/Ja9905849  0.419
1999 Rulkens R, Male JL, Terry KW, Olthof B, Khodakov A, Bell AT, Iglesia E, Tilley TD. Vanadyltert-Butoxy Orthosilicate, OV[OSi(OtBu)3]3:  A Model for Isolated Vanadyl Sites on Silica and a Precursor to Vanadia−Silica Xerogels† Chemistry of Materials. 11: 2966-2973. DOI: 10.1021/Cm990350O  0.538
1999 Kriesel JW, Tilley TD. Dendrimers as Building Blocks for Nanostructured Materials:  Micro- and Mesoporosity in Dendrimer-Based Xerogels Chemistry of Materials. 11: 1190-1193. DOI: 10.1021/Cm990058G  0.782
1998 Mitchell GP, Tilley TD. Generation of a Silylene Complex by the 1,2-Migration of Hydrogen from Silicon to Platinum. Angewandte Chemie (International Ed. in English). 37: 2524-2526. PMID 29711339 DOI: 10.1002/(Sici)1521-3773(19981002)37:18<2524::Aid-Anie2524>3.0.Co;2-H  0.418
1998 Lucht BL, Tilley TD. Zirconocene-coupling routes to conjugated polymers: soluble poly(arylenedienylene)s Chemical Communications. 1645-1645. DOI: 10.1039/A802538J  0.512
1998 Liu F, Tilley TD. A coordination network based on d0 transition-metal centers: synthesis and structure of the [2,4]-connected layered compound [(TiCl4)2Si(C6H4CN-p)4]·1.5C7H8 Chemical Communications. 103-104. DOI: 10.1039/A706020C  0.303
1998 Grumbine SK, Mitchell GP, Straus DA, Tilley TD, Rheingold AL. Synthesis and Study of Ruthenium Silylene Complexes of the Type [(η5-C5Me5)(Me3P)2RuSiX2]+(X = Thiolate, Me, and Ph) Organometallics. 17: 5607-5619. DOI: 10.1021/Om980506E  0.413
1998 Mitchell GP, Tilley TD. Hydrogen Migrations in Rhodium Silyl Complexes:  Silylene Intermediates vs Oxidative Addition/Reductive Elimination† Organometallics. 17: 2912-2916. DOI: 10.1021/Om980158G  0.445
1998 Nitschke J, Tilley TD. Bipyridine-Containing Cyclophanes via Zirconocene Coupling The Journal of Organic Chemistry. 63: 3673-3676. DOI: 10.1021/Jo972341+  0.574
1998 Feldman JD, Mitchell GP, Nolte JO, Tilley TD. Isolation and characterization of neutral platinum silylene complexes of the type (R3P)2Pt=SiMes2 (Mes = 2,4,6-trimethylphenyl) [2] Journal of the American Chemical Society. 120: 11184-11185. DOI: 10.1021/Ja981882T  0.61
1998 Rulkens R, Tilley TD. A molecular precursor route to active and selective vanadia-silica- zirconia heterogeneous catalysts for the oxidative dehydrogenation of propane [10] Journal of the American Chemical Society. 120: 9959-9960. DOI: 10.1021/Ja981798D  0.303
1998 Kriesel JW, König S, Freitas MA, Marshall AG, Leary JA, Tilley TD. Synthesis of highly charged organometallic dendrimers and their characterization by electrospray mass spectrometry and single-crystal x-ray diffraction Journal of the American Chemical Society. 120: 12207-12215. DOI: 10.1021/Ja981610Q  0.775
1998 Dysard JM, Tilley TD. η5-silolyl and η5-germolyl complexes of d0 hafnium. Structural characterization of an ν5-silolyl complex [1] Journal of the American Chemical Society. 120: 8245-8246. DOI: 10.1021/Ja9812857  0.81
1998 Mitchell GP, Tilley TD. Reversible 1,2-migration of hydrogen between platinum and silicon via intermediate silylene complexes Journal of the American Chemical Society. 120: 7635-7636. DOI: 10.1021/Ja9808346  0.384
1998 Lucht BL, Mao SSH, Tilley TD. A zirconocene-coupling route to substituted poly(p- phenylenedienylene)s: Band Gap tuning via conformational control Journal of the American Chemical Society. 120: 4354-4365. DOI: 10.1021/Ja9743811  0.553
1998 Lugmair CG, Tilley TD. Di-tert-butyl Phosphate Complexes of Titanium Inorganic Chemistry. 37: 1821-1826. DOI: 10.1021/Ic971347E  0.362
1998 Lugmair CG, Tilley TD. Hydrolysis of Zirconium and Hafnium Siloxide Complexes. Isolation and Characterization of the Intermediate Aqua Complexes M[OSi(OtBu)3]4(H2O)n(M = Zr, Hf;n= 1, 2) Inorganic Chemistry. 37: 764-769. DOI: 10.1021/Ic971211G  0.315
1997 Casty GL, Tilley TD, Yap GPA, Rheingold AL. Synthesis and Reactivity of d0Bis(imido) Silyl and Germyl Complexes of Molybdenum and Tungsten Organometallics. 16: 4746-4754. DOI: 10.1021/Om970527T  0.396
1997 Wanandi PW, Tilley TD. Osmium Alkyl and Silyl Derivatives with Cyclopentadienyl(phosphine) and Pentamethylcyclopentadienyl(phosphine) Ligand Sets Organometallics. 16: 4299-4313. DOI: 10.1021/Om9704197  0.461
1997 Buretea MA, Tilley TD. Poly(ferrocenylenevinylene) from Ring-Opening Metathesis Polymerization ofansa-(Vinylene)ferrocene Organometallics. 16: 1507-1510. DOI: 10.1021/Om960940L  0.338
1997 Casty GL, Lugmair CG, Radu NS, Tilley TD, Walzer JF, Zargarian D. Synthesis and Reactivity of 16-Electron Hafnocene Silyl Hydride Complexes Organometallics. 16: 8-12. DOI: 10.1021/Om9607560  0.785
1997 Gountchev TI, Tilley TD. Structure and reactivity of chelating imido-amido complexes of tantalum. Mechanistic studies on the addition of silanes to Ta-N multiple bonds Journal of the American Chemical Society. 119: 12831-12841. DOI: 10.1021/Ja9721982  0.46
1997 Mitchell GP, Tilley TD. Reversible cycloaddition of isocyanates to ruthenium silylene complexes Journal of the American Chemical Society. 119: 11236-11243. DOI: 10.1021/Ja972020F  0.428
1997 Terry KW, Lugmair CG, Tilley TD. Tris(tert-butoxy)siloxy Complexes as Single-Source Precursors to Homogeneous Zirconia- and Hafnia-Silica Materials. An Alternative to the Sol-Gel Method Journal of the American Chemical Society. 119: 9745-9756. DOI: 10.1021/Ja971405V  0.352
1997 Lugmair CG, Tilley TD, Rheingold AL. Zinc Di(tert-butyl)phosphate Complexes as Precursors to Zinc Phosphates. Manipulation of Zincophosphate Structures Chemistry of Materials. 9: 339-348. DOI: 10.1021/Cm9603821  0.345
1997 Mao SS, Tilley T, Rheingold AL, Hosmane NS. Zirconium bent sandwich complex with a dicarbahexaborate ligand: [Li(THF)3]{[η5-C2B4H4(SiMe3)2](η5-C5Me5)ZrCl2} Journal of Organometallic Chemistry. 533: 257-259. DOI: 10.1016/S0022-328X(96)06826-X  0.418
1996 Heyn RH, Tilley TD. Tris(trimethylstannyl)silyl Complexes of Ruthenium and Platinum Main Group Chemistry. 1: 415-424. DOI: 10.1080/13583149612331338747  0.409
1996 Radu NS, Hollander FJ, Tilley TD, Rheingold AL. Samarium-mediated redistribution of silanes and formation of trinuclear samarium–silicon clusters Chemical Communications. 2459-2460. DOI: 10.1039/Cc9960002459  0.328
1996 Mitchell GP, Tilley TD. Migrations in a Polysilyl Complex of Rhodium. Trapping of an Apparent Silylene Intermediate and Observation of Reversible Si−Si Bond Reductive Elimination Organometallics. 15: 3477-3479. DOI: 10.1021/Om960291D  0.337
1996 Aoyagi K, Gantzel PK, Kalai K, Tilley TD. Bis(triisopropylsilyl)-o-phenylenediamido Complexes of Titanium and Zirconium:  Investigation of a New Ancillary Ligand Organometallics. 15: 923-927. DOI: 10.1021/Om950671J  0.342
1996 Freeman WP, Tilley TD, Liable-Sands LM, Rheingold AL. Synthesis and study of cyclic π-systems containing silicon ang germanium. The question of aromaticity in cyclopentadienyl analogues Journal of the American Chemical Society. 118: 10457-10468. DOI: 10.1021/Ja962103G  0.317
1996 Terry KW, Lugmair CG, Gantzel PK, Tilley TD. Cuprous Tris(tert-butoxy)siloxy Complexes and Their Thermolytic Conversion to Copper−Silica and Copper Oxide−Silica Nanocomposites† Chemistry of Materials. 8: 274-280. DOI: 10.1021/Cm9503700  0.335
1996 Aoyagi K, Gantzel PK, Tilley T. Bis(triisopropylsilyl)-o-phenylenediamido complexes of tantalum. X-ray structure of (η5-C5Me5)[o-C6H4(NSiPri3)2]TaCl2 Polyhedron. 15: 4299-4302. DOI: 10.1016/0277-5387(96)00205-7  0.432
1995 Radu NS, Tilley TD. Autocatalytic Mechanism for .sigma.-Bond Metathesis Reactions of (.eta.5-C5Me5)2SmCH(SiMe3)2 with Silicon-Hydrogen Bonds Journal of the American Chemical Society. 117: 5863-5864. DOI: 10.1021/Ja00126A031  0.308
1995 Radu NS, Engeler MP, Gerlach CP, Tilley TD, Rheingold AL. Isolation of the First d0 Metalloxy Ketene Complexes via "Double Insertion" of Carbon Monoxide into Thorium-Silicon Bonds Journal of the American Chemical Society. 117: 3621-3622. DOI: 10.1021/Ja00117A035  0.323
1994 Radu NS, Tilley TD. Sigma-Bond metathesis reactions involving lanthanide-silicon and lanthanide-hydrogen bonds Phosphorus, Sulfur, and Silicon and the Related Elements. 87: 209-218. DOI: 10.1080/10426509408037454  0.324
1994 Radu NS, Gantzel PK, Tilley TD. Lanthanide–tungsten heterobimetallic complexes viaσ-bond metathesis Journal of the Chemical Society, Chemical Communications. 1175-1176. DOI: 10.1039/C39940001175  0.343
1994 Freeman WP, Tilley TD, Rheingold AL. Stable Silacyclopentadienyl Complexes of Ruthenium: (.eta.5-C5Me5)Ru[.eta.5-Me4C4SiSi(SiMe3)3] and X-ray Structure of Its Protonated Form Journal of the American Chemical Society. 116: 8428-8429. DOI: 10.1021/Ja00097A085  0.377
1994 Grumbine SK, Tilley TD. Transition-Metal-Mediated Redistribution at Silicon: A Bimolecular Mechanism Involving Silylene Complexes Journal of the American Chemical Society. 116: 6951-6952. DOI: 10.1021/Ja00094A066  0.318
1994 Grumbine SK, Tilley TD, Arnold FP, Rheingold AL. Base-Free Silylene Complexes without .pi.-Donor Stabilization. Molecular Structure of [Cp*(PMe3)2Ru:SiMe2][B(C6F5)4] Journal of the American Chemical Society. 116: 5495-5496. DOI: 10.1021/Ja00091A074  0.367
1993 Campion BK, Heyn RH, Tilley TD. Synthesis and reactions of silyl and germyl derivatives of scandocene. Structure of Cp2Sc[Si(SiMe3)3](THF) Organometallics. 12: 2584-2590. DOI: 10.1021/Om00031A031  0.341
1993 Grumbine SD, Tilley TD, Arnold FP, Rheingold AL. A Fischer-type silylene complex of platinum: [trans-(Cy3P)2(H)Pt:Si(SEt)2]BPh4 Journal of the American Chemical Society. 115: 7884-7885. DOI: 10.1021/Ja00070A047  0.371
1993 Campion BK, Heyn RH, Tilley TD, Rheingold AL. Synthesis and study of the ruthenium-silene complexes (.eta.5-C5Me5)(PR3)RuH(.eta.2-CH2:SiR'2) (R = CHMe2, Cy; R' = Me, Ph) Journal of the American Chemical Society. 115: 5527-5537. DOI: 10.1021/Ja00066A022  0.315
1993 Grumbine SD, Tilley TD, Rheingold AL. Synthesis and structure of a transition-metal-substituted silylene complex, (CO)4OsSi(STol-p)[Ru(.eta.5-C5Me5)(PMe3)2] Journal of the American Chemical Society. 115: 358-360. DOI: 10.1021/Ja00054A059  0.364
1993 Terry KW, Gantzel PK, Tilley TD. Chromium(II) and chromium(III) tri-tert-butoxysiloxy complexes Inorganic Chemistry. 32: 5402-5404. DOI: 10.1021/Ic00075A074  0.326
1993 Freeman WP, Tilley TD, Rheingold AL, Ostrander RL. A Stableη5-Germacyclopentadienyl Complex:[(η5 C5Me5)Ru{η5-C4Me4GeSi(SiMe3)3}] Angewandte Chemie International Edition in English. 32: 1744-1745. DOI: 10.1002/Anie.199317441  0.425
1992 Campion BK, Heyn RH, Tilley TD. Silylene-bridged ruthenium dimers via reactions of [(.eta.5-C5Me5)Ru(.mu.-OMe)]2 with silanes. Structure of {[(.eta.5-C5Me5)Ru]2(.mu.-SiPhOMe)(.mu.-OMe)(.mu.-H)} Organometallics. 11: 3918-3920. DOI: 10.1021/Om00059A070  0.364
1992 Radu NS, Tilley TD, Rheingold AL. Synthesis and characterization of the neutral lanthanide silyl complexes (.eta.5-C5Me5)2LnSiH(SiMe3)2 (Ln = Nd, Sm) Journal of the American Chemical Society. 114: 8293-8295. DOI: 10.1021/Ja00047A052  0.436
1992 Woo HG, Walzer JF, Tilley TD. .sigma.-Bond metathesis mechanism for dehydropolymerization of silanes to polysilanes by d0 metal catalysts Journal of the American Chemical Society. 114: 7047-7055. DOI: 10.1021/Ja00044A015  0.349
1992 Heyn RH, Tilley TD. Platinum-mediated reactions of hydrosilanes. Isolation of a complex with bridging disilene and silylene ligands Journal of the American Chemical Society. 114: 1917-1919. DOI: 10.1021/Ja00031A077  0.419
1992 Grumbine SD, Chadha RK, Tilley TD. Transition metal complexes containing donor-stabilized silylyne ligands. Reductive dimerization to a silylene complex Journal of the American Chemical Society. 114: 1518-1520. DOI: 10.1021/Ja00030A079  0.393
1992 Blake RE, Heyn RH, Tilley TD. Synthesis and structure of [(η5-C5Me5Ru(μ-NHPh)]2 ,an electron-deficient ruthenium amide complex Polyhedron. 11: 709-710. DOI: 10.1016/S0277-5387(00)83329-X  0.463
1991 Terry KW, Tilley TD. Trialkoxysiloxy complexes as precursors to MO2.cntdot.4SiO2 (M = Ti, Zr, Hf) materials Chemistry of Materials. 3: 1001-1003. DOI: 10.1021/Cm00018A008  0.343
1991 Zhang C, Grumbine SD, Tilley T. Reactions of the ruthenium silylene derivative [(η5-C5Me5)(PMe3)2RuSiPh2(NCMe)]BPh4 with alcohols, ketones and acetic acid Polyhedron. 10: 1173-1176. DOI: 10.1016/S0277-5387(00)86093-3  0.439
1990 Tilley TD. Mechanistic Aspects of Transition-Metal Catalyzed Dehydrogenative Silane Coupling Reactions Comments On Inorganic Chemistry. 10: 37-51. DOI: 10.1080/02603599008048649  0.358
1990 Campion BK, Heyn RH, Tilley TD. Reactions of alkynes with coordinatively unsaturated (.eta.5-C5Me5)Ru derivatives. X-ray crystal structures of (.eta.5-C5Me5)Cl2Ru(.eta.2:.eta.4-.mu.2-C4H4)Ru(.eta.5-C5Me5) and (.eta.5-C5Me5)3Ru3(.mu.2-Cl)2(.mu.3-Cl)(.eta.2-.mu.2-HC.tplbond.CSiMe3) Organometallics. 9: 1106-1112. DOI: 10.1021/Om00118A032  0.451
1990 Straus DA, Grumbine SD, Tilley TD. Base-free silylene complexes [(.eta.5-C5Me5)(PMe3)2Ru:Si(SR)2]BPh4 (R = Et, p-MeC6H4) Journal of the American Chemical Society. 112: 7801-7802. DOI: 10.1021/Ja00177A053  0.344
1990 Campion BK, Heyn RH, Tilley TD. A stable .eta.2-silene complex of iridium: (.eta.5-C5Me5)(PMe3)Ir(.eta.2-CH2:SiPh2) Journal of the American Chemical Society. 112: 4079-4081. DOI: 10.1021/Ja00166A078  0.351
1990 Woo HG, Tilley TD. .sigma.-Bond metathesis reactions of silicon-hydrogen and metal-silicon bonds. New routes to d0 metal silyl complexes [Erratum to document cited in CA110(25):231799y] Journal of the American Chemical Society. 112: 2843-2843. DOI: 10.1021/Ja00163A078  0.341
1990 Straus DA, Zhang C, Quimbita GE, Grumbine SD, Heyn RH, Tilley TD, Rheingold AL, Geib SJ. Silyl and diphenylsilylene derivatives of (.eta.5-C5Me5)(PMe3)2Ru. Evidence for the base-free silylene complex [(.eta.5-C5Me5)(PMe3)2Ru:SiPh2]+ Journal of the American Chemical Society. 112: 2673-2681. DOI: 10.1021/Ja00163A030  0.482
1990 Arnold J, Tilley TD, Rheingold AL, Geib SJ, Arif AM. Carbonylation chemistry of the tantalum silyl (.eta.5-C5Me5)Cl3TaSiMe3. Synthesis, characterization, and reaction chemistry of (.eta.2-COSiMe3) and derivatives [Erratum to document cited in CA110(9):75695d] Journal of the American Chemical Society. 112: 2468-2468. DOI: 10.1021/Ja00162A084  0.475
1990 Campion BK, Heyn RH, Tilley TD. Carbon dioxide activation by a transition metal-silicon bond. Formation of silanecarboxylate complexes [Cp2Sc[.mu.-O2CSiR3)]2 Inorganic Chemistry. 29: 4355-4356. DOI: 10.1021/Ic00347A001  0.329
1990 Heyn RH, Tilley TD. Preparation and properties of tris(trimethylstannyl)silyl complexes of chromium, molybdenum, and tungsten. X-ray structure of [NEt4][(CO)5WSi(SnMe3)3] Inorganic Chemistry. 29: 4051-4055. DOI: 10.1021/Ic00345A028  0.385
1990 McMullen AK, Tilley TD, Rheingold AL, Geib SJ. Trialkoxysiloxy complexes of nickel. Molecular structures of Na3(.mu.3-I){Ni[.mu.3-OSi(O-tert-Bu)3]3I}.cntdot.0.5THF.cntdot.0.5C5H12 and {(.eta.3-C3H5)Ni[.mu.2-OSi(O-tert-Bu)3]}2 Inorganic Chemistry. 29: 2228-2232. DOI: 10.1021/Ic00337A010  0.368
1990 STRAUS DA, ZHANG C, QUIMBITA GE, GRUMBINE SD, HEYN RH, TILLEY TD, RHEINGOLD AL, GEIB SJ. ChemInform Abstract: Silyl and Diphenylsilylene Derivatives of (η5-C5Me5)(PMe3)2Ru. Evidence for the Base-Free Silylene Complex ((η5-C5Me5)(PMe3)2Ru=SiPh2)+. Cheminform. 21. DOI: 10.1002/chin.199029243  0.319
1989 Arnold J, Engeler MP, Elsner FH, Heyn RH, Tilley TD. Insertion of ethylene into zirconium-silicon and hafnium-silicon bonds Organometallics. 8: 2284-2286. DOI: 10.1021/Om00111A036  0.443
1989 Roddick DM, Heyn RH, Tilley TD. Dimesitylsilyl derivatives of zirconium Organometallics. 8: 324-330. DOI: 10.1021/Om00104A009  0.595
1989 Loren SD, Campion BK, Heyn RH, Tilley TD, Bursten BE, Luth KW. Alkoxy and aryloxy derivatives of (pentamethylcyclopentadienyl)ruthenium. X-ray crystal structures of [(.eta.5-C5Me5)Ru(.mu.-OMe)]2, [(.eta.5-C5Me5)(CO)Ru(.mu.-OEt)]2, and (.eta.5-C5Me5)Ru(.eta.5-2,6-tBu2C6H3O) and molecular orbital analysis of [(.eta.5-C5H5)Ru(.mu.-OMe)]2 Journal of the American Chemical Society. 111: 4712-4718. DOI: 10.1021/Ja00195A026  0.341
1989 Woo HG, Tilley TD. .sigma.-Bond metathesis reactions of silicon-hydrogen and metal-silicon bonds. New routes to d0 metal silyl complexes Journal of the American Chemical Society. 111: 3757-3758. DOI: 10.1021/Ja00192A048  0.347
1989 Arnold J, Tilley TD, Rheingold AL, Geib SJ, Arif AM. Carbonylation chemistry of the tantalum silyl (.eta.5-C5Me5)Cl3TaSiMe3. Synthesis, characterization, and reaction chemistry of (.eta.5-C5Me5)Cl3Ta(.eta.2-COSiMe3) and derivatives Journal of the American Chemical Society. 111: 149-164. DOI: 10.1021/Ja00183A026  0.527
1989 McMullen AK, Tilley TD, Rheingold AL, Geib SJ. Preparation and characterization of the monomeric copper(II) siloxide complex Cu[OSi(OCMe3)3]2(py)2 Inorganic Chemistry. 28: 3772-3774. DOI: 10.1021/Ic00318A032  0.312
1989 Straus DA, Zhang C, Tilley T. Trityl tetraphenylborate as a reagent in organometallic chemistry Journal of Organometallic Chemistry. 369: C13-C17. DOI: 10.1016/0022-328X(89)88013-1  0.351
1989 Tilley TD, Woo H. Dehydrogenative polymerization of silanes to polysilanes by zirconocene and hafnocene catalysts. A new polymerization mechanism Journal of the American Chemical Society. 111: 3-11. DOI: 10.1007/978-94-011-3214-5_1  0.358
1989 RODDICK DM, HEYN RH, TILLEY TD. ChemInform Abstract: Dimesitylsilyl Derivatives of Zirconium. Cheminform. 20. DOI: 10.1002/chin.198922252  0.559
1989 ARNOLD J, TILLEY TD, RHEINGOLD AL, GEIB SJ, ARIF AM. ChemInform Abstract: Carbonylation Chemistry of the Tantalum Silyl (η5-C5Me5)Cl3TaSiMe3. Synthesis, Characterization, and Reaction Chemistry of (η5-C5Me5)Cl3Ta(η2-COSiMe3) and Derivatives. Cheminform. 20. DOI: 10.1002/chin.198915256  0.475
1989 ARNOLD J, RODDICK DM, TILLEY TD, RHEINGOLD AL, GEIB SJ. ChemInform Abstract: Preparation and Characterization of Tris(trimethylsilyl)silyl and Tris(trimethylsilyl)germyl Derivatives of Zirconium and Hafnium. X-Ray Crystal Structures of (η5-C5Me5)Cl2HfSi(SiMe3)3 and (η5-C5Me5)Cl2HfGe(SiMe3)3. Cheminform. 20. DOI: 10.1002/chin.198903234  0.666
1989 ARNOLD J, WOO H, TILLEY TD, RHEINGOLD AL, GEIB SJ. ChemInform Abstract: Reaction of an Early-Transition-Metal η2-Silaacyl Complex with Pyridine. Diastereoselectivity in the Formation of a (2-Pyridyl)silylmethoxy Ligand. Cheminform. 20. DOI: 10.1002/chin.198901220  0.475
1988 Campion BK, Heyn RH, Tilley TD. Preparation and reactivity of 16-electron ‘half-sandwich’ ruthenium complexes; X-ray crystal structure of (η5-C5Me5)Ru(PPri3)Cl Journal of the Chemical Society, Chemical Communications. 278-280. DOI: 10.1039/C39880000278  0.361
1988 Arnold J, Woo HG, Tilley TD, Rheingold AL, Geib SJ. Reaction of an early-transition metal .eta.2-silaacyl complex with pyridine. Diastereoselectivity in the formation of a (2-pyridyl)silylmethoxy ligand Organometallics. 7: 2045-2049. DOI: 10.1021/Om00099A024  0.535
1988 Campion BK, Heyn RH, Tilley TD. Preparation, isolation, and characterization of transition-metal .eta.2-silene complexes. X-ray crystal structure of (.eta.5-C5Me5)[P(iso-Pr)3]Ru(H)(.eta.2-CH2SiPh2) Journal of the American Chemical Society. 110: 7558-7560. DOI: 10.1021/Ja00230A058  0.372
1988 Elsner FH, Woo HG, Tilley TD. Preparation of the first stable formylsilane, (Me3Si)3SiCHO, from a zirconium .eta.2-silaacyl complex Journal of the American Chemical Society. 110: 313-314. DOI: 10.1021/Ja00209A063  0.425
1988 Arnold J, Roddick DM, Tilley TD, Rheingold AL, Geib SJ. Preparation and characterization of tris(trimethylsilyl)silyl and tris(trimethylsilyl)germyl derivatives of zirconium and hafnium. X-ray crystal structures of (.eta.5-C5Me5)Cl2HfSi(SiMe3)3 and (.eta.5-C5Me5)Cl2HfGe(SiMe3)3 Inorganic Chemistry. 27: 3510-3514. DOI: 10.1021/Ic00293A016  0.683
1988 Elsner FH, Tilley T, Rheingold AL, Geib SJ. Reactions of (η5-C5H5)(η5-C5Me5)Zr[Si(SiMe3)3]X (X  Cl, Me) complexes with carbon monoxide and the isocyanide 2,6-Me2C6H3NC. Crystal structure of (η5-C5H5)(η5-C5Me5)Zr[η2-C(N-2,6-Me2C6H3)Si(SiMe3)3]Cl Journal of Organometallic Chemistry. 358: 169-183. DOI: 10.1016/0022-328X(88)87078-5  0.379
1988 ELSNER FH, WOO H, TILLEY TD. ChemInform Abstract: Preparation of the First Stable Formylsilane, (Me3Si)3SiCHO, from a Zirconium η2-Silaacyl Complex. Cheminform. 19. DOI: 10.1002/chin.198815265  0.317
1987 Arnold J, Tilley TD, Rheingold AL, Geib SJ. Formation of the novel benzophenone sila-acylhydrazonato complex (η5-C5Me5)Cl3Ta[OC(SiMe3)NNCPh2] following addition of diphenyldiazomethane to an η2-sila–-acyl ligand Journal of the Chemical Society, Chemical Communications. 793-794. DOI: 10.1039/C39870000793  0.581
1987 Arnold J, Shina DN, Tilley TD, Arif AM. Additions and Corrections - Preparation and Reaction Chemistry of Trimethylsilyl Derivatives of Tantalum. X-ray Structures of d0(n5-C5Me5)Ta(SiMe3)Cl3and d1(n5-C5Me5)Ta-(SiMe3)(PMe3)Cl2 Organometallics. 6: 684-684. DOI: 10.1021/Om00146A602  0.401
1987 Arnold J, Tilley TD, Rheingold AL, Geib SJ. Preparation and reaction chemistry of trimethylsilyl derivatives of niobium. Redox chemistry of (.eta.5-C5H5)2Nb(SiMe3)Cl and x-ray structures of (.eta.5-C5H5)2Nb(SiMe3)(.eta.2-C2H4) and [(.eta.5-C5H5)2Nb(CH2SiMe3)Cl]PF6 Organometallics. 6: 473-479. DOI: 10.1021/Om00146A007  0.464
1987 Straus DA, Tilley TD, Rheingold AL, Geib SJ. Preparation, characterization, and x-ray crystal structure of an acetonitrile-complexed ruthenium silylene Journal of the American Chemical Society. 109: 5872-5873. DOI: 10.1021/Ja00253A062  0.428
1987 Arnold J, Tilley TD. Insertion of organic carbonyls into the tantalum-silicon bond of (.eta.5-C5Me5)Cl3TaSiMe3. Preparation and characterization of the .alpha.-silylalkoxides (.eta.5-C5Me5)Cl3TaOCRR'SiMe3 Journal of the American Chemical Society. 109: 3318-3322. DOI: 10.1021/Ja00245A022  0.466
1987 Roddick DM, Tilley TD, Rheingold AL, Geib SJ. Coordinatively unsaturated tris(trimethylsilyl)silyl complexes of chromium, manganese, and iron Journal of the American Chemical Society. 109: 945-946. DOI: 10.1021/Ja00237A076  0.637
1987 Arnold J, Tilley TD, Rheingold AL, Geib SJ. An Arbuzov-like reaction in the trimethyl phosphite-.eta.2-silaacyl adduct (.eta.5-C5Me5)Cl3Ta[.eta.2-OC(SiMe3)[P(OMe)3]] Inorganic Chemistry. 26: 2556-2559. DOI: 10.1021/Ic00262A044  0.468
1987 Arnold J, Tilley TD, Rheingold AL, Geib SJ. Preparation and characterization of tris(trimethylsilyl)silyl derivatives of zinc, cadmium, and mercury. X-ray crystal structure of Zn[Si(SiMe3)3]2 Inorganic Chemistry. 26: 2106-2109. DOI: 10.1021/Ic00260A019  0.477
1987 ARNOLD J, TILLEY TD, RHEINGOLD AL, GEIB SJ. ChemInform Abstract: An Arbuzov-like Reaction in the Trimethyl Phosphite-η2-Silaacyl Adduct (η5-C5Me5)Cl3Ta(η2-OC(SiMe3)(P(OMe)3)). Cheminform. 18. DOI: 10.1002/chin.198747267  0.422
1987 ARNOLD J, TILLEY TD, RHEINGOLD AL, GEIB SJ. ChemInform Abstract: Preparation and Characterization of Tris(trimethylsilyl)silyl Derivatives of Zinc, Cadmium, and Mercury. X-Ray Crystal Structure of Zn(Si(SiMe3)3)2. Cheminform. 18. DOI: 10.1002/chin.198745251  0.405
1987 ARNOLD J, TILLEY TD. ChemInform Abstract: Insertion of Organic Carbonyls Into the Tantalum-Silicon Bond of (η5-C5Me5)Cl3TaSiMe3. Preparation and Characterization of the α-Silylalkoxides (η5-C5Me5)Cl3TaOCRR′SiMe3. Cheminform. 18. DOI: 10.1002/chin.198740297  0.412
1987 RODDICK DM, TILLEY TD, RHEINGOLD AL, GEIB SJ. ChemInform Abstract: Coordinatively Unsaturated Tris(trimethylsilyl)silyl Complexes of Chromium, Manganese, and Iron. Cheminform. 18. DOI: 10.1002/chin.198724265  0.604
1987 ARNOLD J, SHINA DN, TILLEY TD, ARIF AM. ChemInform Abstract: Preparation and Reaction Chemistry of Trimethylsilyl Derivatives of Tantalum. X-Ray Structures of d0 (η5-C5Me5)Ta(SiMe3)Cl3 and d1 (η5-C5Me5)Ta(SiMe3)(PMe3)Cl2. Cheminform. 18. DOI: 10.1002/chin.198712281  0.426
1986 Arnold J, Shina DN, Tilley TD, Arif AM. Preparation and reaction chemistry of trimethylsilyl derivatives of tantalum. X-ray structures of d0 (.eta.5-C5Me5)Ta(SiMe3)Cl3 and d1 (.eta.5-C5Me5)Ta(SiMe3)(PMe3)Cl2 Organometallics. 5: 2037-2044. DOI: 10.1021/Om00141A017  0.488
1986 Arnold J, Tilley TD, Rheingold AL. Tetrahedral Lewis base adducts of an acyl. Preparation and x-ray structure of the pyridine adduct (.eta.5-C5Me5)Cl3Ta[.eta.2-OC(SiMe3)(NC5H5)] Journal of the American Chemical Society. 108: 5355-5356. DOI: 10.1021/Ja00277A056  0.483
1986 ARNOLD J, TILLEY TD, RHEINGOLD AL. ChemInform Abstract: Tetrahedral Lewis Base Adducts of an Acyl. Preparation and X-Ray Structure of the Pyridine Adduct (η5-C5Me5)Cl3Ta[η2- OC(SiMe3)(NC5H5)]. Chemischer Informationsdienst. 17. DOI: 10.1002/chin.198652236  0.428
1986 ARNOLD J, TILLEY TD. ChemInform Abstract: Ether Cleavage Following Insertion of Carbon Monoxide into the Tantalum - Silicon Bond of (η5-C5Me5)Ta(SiMe3)Cl3. Chemischer Informationsdienst. 17. DOI: 10.1002/chin.198607277  0.404
1985 Arnold J, Tilley TD. Ether cleavage following insertion of carbon monoxide into the tantalum-silicon bond of (.eta.5-C5Me5)Ta(SiMe3)Cl3 Journal of the American Chemical Society. 107: 6409-6410. DOI: 10.1021/Ja00308A052  0.468
1985 Tilley TD. Insertion of carbon monoxide into a transition metal-silicon bond. X-ray structure of the silaacyl chloro(trimethylsilyl-.eta.2-carbonyl)bis(.eta.5-cyclopentadienyl)zirconium Journal of the American Chemical Society. 107: 4084-4085. DOI: 10.1021/Ja00299A058  0.314
1984 Boncella JM, Tilley TD, Andersen RA. Reaction of M(C5Me5)2(OEt2), M = Eu or Yb, with phenylacetylene; formation of mixed-valence Yb3(C5Me5)4(μ-C≡CPh)4 and Eu2(C5Me5)2(µ-C≡CPh)2(tetrahydrofuran)4 Journal of the Chemical Society - Series Chemical Communications. 710-712. DOI: 10.1039/C39840000710  0.707
1984 Tilley TD, Grubbs RH, Bercaw JE. Halide, hydride, and alkyl derivatives of (pentamethylcyclopentadienyl)bis(trimethylphosphine)ruthenium Organometallics. 3: 274-278. DOI: 10.1021/Om00080A019  0.696
1984 Tilley TD, Andersen RA, Zalkin A. Divalent lanthanide chemistry. Preparation and crystal structures of sodium tris[bis(trimethylsilyl)amido]europate(II) and sodium tris[bis(trimethylsilyl)amido]ytterbate(II), NaM[N(SiMe3)2]3 Inorganic Chemistry. 23: 2271-2276. DOI: 10.1021/Ic00183A013  0.498
1983 Tilley TD, Andersen RA, Zalkin A. Tertiary phosphine complexes of the f-block metals. Preparation of pentamethylcyclopentadienyl-tertiary phosphine complexes of ytterbium(II), ytterbium(III) and europium(II). Crystal structure of Yb(Me5C5)2Cl(Me2PCH2PMe2) Inorganic Chemistry. 22: 856-859. DOI: 10.1021/Ic00148A002  0.479
1983 TILLEY TD, ANDERSEN RA, ZALKIN A. ChemInform Abstract: TERTIARY PHOSPHINE COMPLEXES OF THE F-BLOCK METALS. PREPARATION OF PENTAMETHYLCYCLOPENTADIENYL-TERTIARY PHOSPHINE COMPLEXES OF YTTERBIUM(II), YTTERBIUM(III) AND EUROPIUM(II). CRYSTAL STRUCTURE OF YB(ME5C5)2CL(ME2PCH2PME2) Chemischer Informationsdienst. 14. DOI: 10.1002/Chin.198326289  0.555
1982 Tilley TD, Andersen RA, Zalkin A. Tertiary phosphine complexes of the f-block metals. Crystal structure of Yb[N(SiMe3)2]2[Me2PCH2CH2PMe2]: evidence for a ytterbium-.gamma.-carbon interaction Journal of the American Chemical Society. 104: 3725-3727. DOI: 10.1021/Ja00377A033  0.508
1982 Tilley TD, Andersen R. Preparation and crystal structure of bis[bis(pentamethylcyclopentadienyl)ytterbium(III)] undecacarbonyltriferrate, [(C5Me5)2Yb]2 [Fe3(CO)11]; a compound with four isocarbonyl (iron-carbonyl-ytterbium) interactions Journal of the American Chemical Society. 104: 1772-1774. DOI: 10.1021/Ja00370A070  0.487
1982 Tilley TD, Andersen RA, Spencer B, Zalkin A. Crystal structure of bis(pentamethylcyclopentadienyl)bis(pyridine)ytterbium(II) Inorganic Chemistry. 21: 2647-2649. DOI: 10.1021/Ic00137A023  0.494
1982 Tilley TD, Andersen RA, Zalkin A, Templeton DH. Bis(pentamethylcyclopentadienyl)carboxylato and -dithiocarbamato derivatives of neodymium(III) and ytterbium(III). Crystal structure of bis(pentamethylcyclopentadienyl)(diethyldithiocarbamato)ytterbium(III) Inorganic Chemistry. 21: 2644-2647. DOI: 10.1021/Ic00137A022  0.502
1981 Tilley TD, Andersen RA. Preparation and crystal structure of μ-carbonyl-OC-bis(Pentamethyl-cyclopentadienyl)(tetrahydrofuran)ytterbium(III)tricarbonylcobalt(I); A Yb-OC-Co linkage Journal of the Chemical Society - Series Chemical Communications. 985-986. DOI: 10.1039/C39810000985  0.533
1981 Tilley TD, Andersen RA. Pentamethylcyclopentadienyl derivatives of the trivalent lanthanide elements neodymium, samarium, and ytterbium Inorganic Chemistry. 20: 3267-3270. DOI: 10.1021/Ic50224A025  0.463
1981 Tilley TD, Zalkin A, Andersen RA, Templeton DH. Divalent lanthanide chemistry. Preparation of some four- and six-coordinate bis[(trimethylsilyl)amido] complexes of europium(II). Crystal structure of bis[bis(trimethylsilyl)amido]bis(1,2-dimethoxyethane)europium(II) Inorganic Chemistry. 20: 551-554. DOI: 10.1021/Ic50216A047  0.514
1980 Tilley TD, Andersen RA, Spencer B, Ruben H, Zalkin A, Templeton DH. Divalent lanthanide chemistry. Bis (pentamethylcyclopentadienyl) europium(II) and -ytterbium(II) derivatives: crystal structure of bis (pentamethylcyclopentadienyl) (tetrahydrofuran ytterbium(II) -hemitoluene at 176 K Inorganic Chemistry. 19: 2999-3003. DOI: 10.1021/Ic50212A031  0.501
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