Michael K. Whittlesey, Ph.D. - Publications

Affiliations: 
1999- Chemistry Bath Spa University 
Area:
Inorganic Chemistry
Website:
https://researchportal.bath.ac.uk/en/persons/michael-whittlesey

131 high-probability publications. We are testing a new system for linking publications to authors. You can help! If you notice any inaccuracies, please sign in and mark papers as correct or incorrect matches. If you identify any major omissions or other inaccuracies in the publication list, please let us know.

Year Citation  Score
2022 Isaac CJ, Wilson CI, Burnage AL, Miloserdov FM, Mahon MF, Macgregor SA, Whittlesey MK. Experimental and Computational Studies of Ruthenium Complexes Bearing -Acceptor Aluminum-Based Phosphine Pincer Ligands. Inorganic Chemistry. 61: 20690-20698. PMID 36475641 DOI: 10.1021/acs.inorgchem.2c03665  0.383
2022 Isaac CJ, Miloserdov FM, Pécharman AF, Lowe JP, McMullin CL, Whittlesey MK. Structure and Reactivity of [Ru-Al] and [Ru-Sn] Heterobimetallic PPh-Based Complexes. Organometallics. 41: 2716-2730. PMID 36249448 DOI: 10.1021/acs.organomet.2c00344  0.501
2022 Sotorrios L, Miloserdov FM, Pécharman AF, Lowe JP, Macgregor SA, Mahon MF, Whittlesey M. Zinc-Promoted ZnMe/ZnPh Exchange in Eight-Coordinate [Ru(PPh3)2(ZnMe)4H2]. Angewandte Chemie (International Ed. in English). PMID 35213937 DOI: 10.1002/anie.202117495  0.35
2021 Miloserdov FM, Pécharman AF, Sotorrios L, Rajabi NA, Lowe JP, Macgregor SA, Mahon MF, Whittlesey MK. Bonding and Reactivity of a Pair of Neutral and Cationic Heterobimetallic RuZn Complexes. Inorganic Chemistry. 60: 16256-16265. PMID 34661399 DOI: 10.1021/acs.inorgchem.1c02072  0.448
2021 Sabater S, Schmidt D, Schmidt H, Kuntze-Fechner M, Zell T, Isaac C, Rajabi N, Grieve H, Blackaby W, Lowe J, Macgregor S, Mahon M, Radius U, Whittlesey M. [Ni(NHC)2] as a Scaffold for Structurally Characterized trans [H-Ni-PR2] and trans [R2P-Ni-PR2] Complexes. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 34190374 DOI: 10.1002/chem.202101484  0.355
2020 Miloserdov FM, Isaac CJ, Beck ML, Burnage AL, Farmer JCB, Macgregor SA, Mahon MF, Whittlesey MK. Impact of the Novel Z-Acceptor Ligand Bis{(-diphenylphosphino)phenyl}zinc (ZnPhos) on the Formation and Reactivity of Low-Coordinate Ru(0) Centers. Inorganic Chemistry. PMID 33074685 DOI: 10.1021/acs.inorgchem.0c01683  0.413
2020 Cybulski M, Beattie N, Macgregor S, Mahon M, Whittlesey M. Unexpected Vulnerability of DPEphos to C-O Activation in the Presence of Nucleophilic Metal Hydrides. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 32428278 DOI: 10.1002/Chem.202001685  0.458
2020 Espinal-Viguri M, Varela-Izquierdo V, Miloserdov FM, Riddlestone IM, Mahon MF, Whittlesey MK. Correction: Heterobimetallic ruthenium-zinc complexes with bulky N-heterocyclic carbenes: syntheses, structures and reactivity. Dalton Transactions (Cambridge, England : 2003). 49: 6896. PMID 32400775 DOI: 10.1039/D0Dt90091E  0.367
2020 Miloserdov FM, Rajabi NA, Lowe JP, Mahon MF, Macgregor SA, Whittlesey MK. Zn-Promoted C-H Reductive Elimination and H Activation via a Dual Unsaturated Heterobimetallic Ru-Zn Intermediate. Journal of the American Chemical Society. PMID 32134645 DOI: 10.1021/Jacs.0C01062  0.551
2019 Duckett SB, Nicasio MC, Whittlesey MK. Breaking bonds over many timescales: in celebration of Robin Perutz's 70th birthday. Dalton Transactions (Cambridge, England : 2003). PMID 31833503 DOI: 10.1039/C9Dt90277E  0.5
2019 O'Leary N, Miloserdov FM, Mahon MF, Whittlesey MK. Transforming PPh into bidentate phosphine ligands at Ru-Zn heterobimetallic complexes. Dalton Transactions (Cambridge, England : 2003). 48: 14000-14009. PMID 31478040 DOI: 10.1039/C9Dt03106E  0.541
2019 Tolentino DR, Neale SE, Isaac CJ, Macgregor SA, Whittlesey MK, Jazzar R, Bertrand G. Reductive Elimination at Carbon under Steric Control. Journal of the American Chemical Society. PMID 31180660 DOI: 10.1021/Jacs.9B04957  0.701
2019 Espinal-Viguri M, Varela-Izquierdo V, Miloserdov FM, Riddlestone IM, Mahon MF, Whittlesey MK. Heterobimetallic ruthenium-zinc complexes with bulky N-heterocyclic carbenes: syntheses, structures and reactivity. Dalton Transactions (Cambridge, England : 2003). 48: 4176-4189. PMID 30816897 DOI: 10.1039/C8Dt05023F  0.579
2019 Hall JW, Seeberger F, Mahon MF, Whittlesey MK. (carbene)CuF Complexes Featuring Bulky Arduengo-Type, Ring-Expanded, and Cyclic (Alkyl)(amino)carbenes: Applications in Catalytic Aldehyde Allylation Organometallics. 39: 227-233. DOI: 10.1021/Acs.Organomet.9B00772  0.377
2019 Blackaby WJM, Neale SE, Isaac CJ, Sabater S, Macgregor SA, Whittlesey MK. N‐Heterocyclic Carbene Non‐Innocence in the Catalytic Hydrophosphination of Alkynes Chemcatchem. 11: 1893-1897. DOI: 10.1002/Cctc.201900220  0.319
2018 Cybulski MK, Davies CJE, Lowe JP, Mahon MF, Whittlesey MK. C-F Bond Activation of P(CF) by Ruthenium Dihydride Complexes: Isolation and Reactivity of the "Missing" Ru(PPh)H(halide) Complex, Ru(PPh)HF. Inorganic Chemistry. PMID 30303005 DOI: 10.1021/Acs.Inorgchem.8B02286  0.559
2018 Ellul CE, Lowe JP, Mahon MF, Raithby PR, Whittlesey MK. [Ru(6-NHC)(CO)]: synthesis, characterisation and reactivity of rare 46-electron tri-ruthenium clusters. Dalton Transactions (Cambridge, England : 2003). PMID 29505057 DOI: 10.1039/C8Dt00189H  0.378
2018 Hall JW, Unson DML, Brunel P, Collins LR, Cybulski MK, Mahon MF, Whittlesey MK. Copper-NHC-Mediated Semihydrogenation and Hydroboration of Alkynes: Enhanced Catalytic Activity Using Ring-Expanded Carbenes Organometallics. 37: 3102-3110. DOI: 10.1021/Acs.Organomet.8B00467  0.347
2017 Blackaby WJM, Sabater S, Poulten RC, Page MJ, Folli A, Krewald V, Mahon MF, Murphy DM, Richards E, Whittlesey MK. Mono- and dinuclear Ni(i) products formed upon bromide abstraction from the Ni(i) ring-expanded NHC complex [Ni(6-Mes)(PPh3)Br]. Dalton Transactions (Cambridge, England : 2003). PMID 29243762 DOI: 10.1039/C7Dt04187J  0.405
2017 Riddlestone I, Rajabi N, Macgregor S, Mahon M, Whittlesey M. Well-Defined Heterobimetallic Reactivity at Unsupported Ruthenium-Indium Bonds. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 29240969 DOI: 10.1002/Chem.201705796  0.566
2017 Häller LJ, Mas-Marzá E, Cybulski MK, Sanguramath RA, Macgregor SA, Mahon MF, Raynaud C, Russell CA, Whittlesey MK. Computation provides chemical insight into the diverse hydride NMR chemical shifts of [Ru(NHC)4(L)H](0/+) species (NHC = N-heterocyclic carbene; L = vacant, H2, N2, CO, MeCN, O2, P4, SO2, H(-), F(-) and Cl(-)) and their [Ru(R2PCH2CH2PR2)2(L)H](+) congeners. Dalton Transactions (Cambridge, England : 2003). 46: 2861-2873. PMID 28245022 DOI: 10.1039/C7Dt00117G  0.477
2017 Cybulski MK, McKay D, Macgregor SA, Mahon MF, Whittlesey MK. Room Temperature Regioselective Catalytic Hydrodefluorination of Fluoroarenes with trans-[Ru(NHC)4 H2 ] through a Concerted Nucleophilic Ru-H Attack Pathway. Angewandte Chemie (International Ed. in English). PMID 28067455 DOI: 10.1002/Anie.201610820  0.458
2017 Cybulski MK, Nicholls JE, Lowe JP, Mahon MF, Whittlesey MK. Catalytic Hydrodefluorination of Fluoroarenes Using Ru(IMe4)2L2H2 (IMe4 = 1,3,4,5-Tetramethylimidazol-2-ylidene; L2 = (PPh3)2, dppe, dppp, dppm) Complexes Organometallics. 36: 2308-2316. DOI: 10.1021/Acs.Organomet.7B00243  0.532
2017 Sabater S, Page MJ, Mahon MF, Whittlesey MK. Stoichiometric and Catalytic Reactivity of Ni(6-Mes)(PPh3)2 Organometallics. 36: 1776-1783. DOI: 10.1021/Acs.Organomet.7B00129  0.403
2016 Shi S, Collins LR, Mahon MF, Djurovich PI, Thompson ME, Whittlesey MK. Synthesis and characterization of phosphorescent two-coordinate copper(i) complexes bearing diamidocarbene ligands. Dalton Transactions (Cambridge, England : 2003). PMID 27991619 DOI: 10.1039/C6Dt04016K  0.313
2016 Pelties S, Carter E, Folli A, Mahon MF, Murphy DM, Whittlesey MK, Wolf R. Influence of Ring-Expanded N-Heterocyclic Carbenes on the Structures of Half-Sandwich Ni(I) Complexes: An X-ray, Electron Paramagnetic Resonance (EPR), and Electron Nuclear Double Resonance (ENDOR) Study. Inorganic Chemistry. PMID 27731984 DOI: 10.1021/Acs.Inorgchem.6B01540  0.365
2016 Riddlestone IM, Rajabi NA, Lowe JP, Mahon MF, Macgregor SA, Whittlesey MK. Activation of H2 Over the Ru-Zn Bond in the Transition Metal-Lewis Acid Heterobimetallic Species [Ru(IPr)2(CO)ZnEt](+) (IPr = 1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene). Journal of the American Chemical Society. PMID 27490786 DOI: 10.1021/Jacs.6B05243  0.508
2016 Riddlestone IM, McKay D, Gutmann MJ, Macgregor SA, Mahon MF, Sparkes HA, Whittlesey MK. Isolation of [Ru(IPr)2(CO)H]+ (IPr = 1,3-Bis(2,6-diisopropylphenyl)imidazol-2-ylidene) and Reactivity toward E–H (E = H, B) Bonds Organometallics. 35: 1301-1312. DOI: 10.1021/Acs.Organomet.6B00173  0.536
2016 Collins LR, Moffat LA, Mahon MF, Jones MD, Whittlesey MK. Lactide polymerisation by ring-expanded NHC complexes of zinc Polyhedron. 103: 121-125. DOI: 10.1016/J.Poly.2015.09.022  0.413
2015 Collins LR, Riddlestone IM, Mahon MF, Whittlesey MK. A Comparison of the Stability and Reactivity of Diamido- and Diaminocarbene Copper Alkoxide and Hydride Complexes. Chemistry (Weinheim An Der Bergstrasse, Germany). 21: 14075-84. PMID 26310393 DOI: 10.1002/Chem.201502476  0.405
2015 Cybulski MK, Riddlestone IM, Mahon MF, Woodman TJ, Whittlesey MK. Stoichiometric and catalytic C-F bond activation by the trans-dihydride NHC complex [Ru(IEt2Me2)2(PPh3)2H2] (IEt2Me2 = 1,3-diethyl-4,5-dimethylimidazol-2-ylidene). Dalton Transactions (Cambridge, England : 2003). 44: 19597-605. PMID 26185808 DOI: 10.1039/C5Dt01996F  0.566
2015 Giner EA, Santiago A, Gómez-Gallego M, Ramírez de Arellano C, Poulten RC, Whittlesey MK, Sierra MA. Mono- and bimetallic zwitterionic chromium(0) and tungsten(0) allenyls. Inorganic Chemistry. 54: 5450-61. PMID 25952749 DOI: 10.1021/Acs.Inorgchem.5B00492  0.424
2015 Collins LR, Hierlmeier G, Mahon MF, Riddlestone IM, Whittlesey MK. Unexpected migratory insertion reactions of M(alkyl)2 (M=Zn, Cd) and diamidocarbenes. Chemistry (Weinheim An Der Bergstrasse, Germany). 21: 3215-8. PMID 25572627 DOI: 10.1002/Chem.201406406  0.351
2015 McKay D, Riddlestone IM, Macgregor SA, Mahon MF, Whittlesey MK. Mechanistic study of Ru-NHC-catalyzed hydrodefluorination of fluoropyridines: The influence of the NHC on the regioselectivity of C-F activation and chemoselectivity of C-F versus C-H bond cleavage Acs Catalysis. 5: 776-787. DOI: 10.1021/Cs501644R  0.524
2014 Poulten RC, López I, Llobet A, Mahon MF, Whittlesey MK. Stereoelectronic effects in C-H bond oxidation reactions of Ni(I) N-heterocyclic carbene complexes. Inorganic Chemistry. 53: 7160-9. PMID 24972307 DOI: 10.1021/Ic500213H  0.418
2014 Schwartsburd L, Mahon MF, Poulten RC, Warren MR, Whittlesey MK. Mechanistic Studies of the Rhodium NHC Catalyzed Hydrodefluorination of Polyfluorotoluenes Organometallics. 33: 6165-6170. DOI: 10.1021/Om500827D  0.457
2014 Collins LR, Rookes TM, Mahon MF, Riddlestone IM, Whittlesey MK. Use of ring-expanded diamino- and diamidocarbene ligands in copper catalyzed azide-alkyne "click" reactions Organometallics. 33: 5882-5887. DOI: 10.1021/Om5004732  0.345
2014 Bramananthan N, Carmona M, Lowe JP, Mahon MF, Poulten RC, Whittlesey MK. Rh-FHF and Rh-F complexes containing small N-alkyl substituted six-membered ring N-heterocyclic carbenes Organometallics. 33: 1986-1995. DOI: 10.1021/Om500122E  0.363
2013 Poulten RC, Page MJ, Algarra AG, Le Roy JJ, López I, Carter E, Llobet A, Macgregor SA, Mahon MF, Murphy DM, Murugesu M, Whittlesey MK. Synthesis, electronic structure, and magnetism of [Ni(6-Mes)2]+: a two-coordinate nickel(I) complex stabilized by bulky N-heterocyclic carbenes. Journal of the American Chemical Society. 135: 13640-3. PMID 23971827 DOI: 10.1021/Ja407004Y  0.365
2013 Macgregor SA, McKay D, Panetier JA, Whittlesey MK. Computational study of the hydrodefluorination of fluoroarenes at [Ru(NHC)(PR3)2(CO)(H)2]: predicted scope and regioselectivities. Dalton Transactions (Cambridge, England : 2003). 42: 7386-95. PMID 23400241 DOI: 10.1039/C3Dt32962C  0.482
2013 Page MJ, Lu WY, Poulten RC, Carter E, Algarra AG, Kariuki BM, Macgregor SA, Mahon MF, Cavell KJ, Murphy DM, Whittlesey MK. Three-coordinate nickel(I) complexes stabilised by six-, seven- and eight-membered ring n-heterocyclic carbenes: synthesis, EPR/DFT studies and catalytic activity. Chemistry (Weinheim An Der Bergstrasse, Germany). 19: 2158-67. PMID 23292787 DOI: 10.1002/Chem.201202950  0.39
2013 Davies CJE, Lowe JP, Mahon MF, Poulten RC, Whittlesey MK. Synthesis and small molecule reactivity of trans -dihydride isomers of Ru(NHC)2(PPh3)2H2 (NHC = N-Heterocyclic Carbene) Organometallics. 32: 4927-4937. DOI: 10.1021/Om400648X  0.495
2012 Segarra C, Mas-Marzá E, Lowe JP, Mahon MF, Poulten RC, Whittlesey MK. Ring-expanded N-heterocyclic carbene complexes of rhodium with bifluoride, fluoride, and fluoroaryl ligands Organometallics. 31: 8584-8590. DOI: 10.1021/Om300984V  0.409
2012 Batool M, Martin TA, Algarra AG, George MW, MacGregor SA, Mahon MF, Whittlesey MK. Photochemistry of Cp′Mn(CO) 2(NHC) (Cp′ = η 5-C 5H 4Me) species: Synthesis, time-resolved ir spectroscopy, and DFT calculations Organometallics. 31: 4971-4979. DOI: 10.1021/Om300209A  0.43
2012 Bramananthan N, Mas-Marzá E, Fernandéz FE, Ellul CE, Mahon MF, Whittlesey MK. Formation of Cyclometallated N-Heterocyclic Carbene (NHC) Complexes from LnRuCl2 (L = Cyclooctadiene, PPh3, DMSO) Precursors European Journal of Inorganic Chemistry. 2012: 2213-2219. DOI: 10.1002/Ejic.201200117  0.467
2011 Saidi O, Marafie J, Ledger AE, Liu PM, Mahon MF, Kociok-Köhn G, Whittlesey MK, Frost CG. Ruthenium-catalyzed meta sulfonation of 2-phenylpyridines. Journal of the American Chemical Society. 133: 19298-301. PMID 22047022 DOI: 10.1021/Ja208286B  0.417
2011 Batool M, Martin TA, Naser MA, George MW, Macgregor SA, Mahon MF, Whittlesey MK. Comparison of the photochemistry of organometallic N-heterocyclic carbene and phosphine complexes of manganese. Chemical Communications (Cambridge, England). 47: 11225-7. PMID 21918776 DOI: 10.1039/C1Cc14467G  0.472
2011 Page MJ, Mahon MF, Whittlesey MK. Formation and reactivity of the cyclometallated N-heterocyclic carbene complexes [Ru(NHC)'(dppe)(CO)H]. Dalton Transactions (Cambridge, England : 2003). 40: 7858-65. PMID 21725563 DOI: 10.1039/C1Dt10299K  0.567
2011 Ledger AE, Ellul CE, Mahon MF, Williams JM, Whittlesey MK. Ruthenium bidentate phosphine complexes for the coordination and catalytic dehydrogenation of amine- and phosphine-boranes. Chemistry (Weinheim An Der Bergstrasse, Germany). 17: 8704-13. PMID 21678503 DOI: 10.1002/Chem.201100101  0.504
2011 Panetier JA, Macgregor SA, Whittlesey MK. Catalytic hydrodefluorination of pentafluorobenzene by [Ru(NHC)(PPh3)2(CO)H2]: a nucleophilic attack by a metal-bound hydride ligand explains an unusual ortho-regioselectivity. Angewandte Chemie (International Ed. in English). 50: 2783-6. PMID 21387487 DOI: 10.1002/Anie.201006789  0.465
2011 Martin TA, Ellul CE, Mahon MF, Warren ME, Allan D, Whittlesey MK. Neutral and Cationic Mono- and Bis-N-heterocyclic Carbene Complexes Derived From Manganese and Rhenium Carbonyl Precursors Organometallics. 30: 2200-2211. DOI: 10.1021/Om1011853  0.306
2011 Nixon TD, Whittlesey MK, Williams JM. Ruthenium-catalysed transfer hydrogenation reactions with dimethylamine borane Tetrahedron Letters. 52: 6652-6654. DOI: 10.1016/J.Tetlet.2011.10.039  0.371
2011 Guard LM, Ledger AE, Reade SP, Ellul CE, Mahon MF, Whittlesey MK. [Ru(NHC)(P–P)(CO)HF] (NHC = N-heterocyclic carbene; P–P = xantphos, dppf) complexes: Efforts to prepare new hydrodefluorination catalysts Journal of Organometallic Chemistry. 696: 780-786. DOI: 10.1016/J.Jorganchem.2010.09.077  0.522
2010 Häller LJ, Page MJ, Erhardt S, Macgregor SA, Mahon MF, Naser MA, Vélez A, Whittlesey MK. Experimental and computational investigation of C-N bond activation in ruthenium N-heterocyclic carbene complexes. Journal of the American Chemical Society. 132: 18408-16. PMID 21128626 DOI: 10.1021/Ja109702H  0.501
2010 Ledger AE, Moreno A, Ellul CE, Mahon MF, Pregosin PS, Whittlesey MK, Williams JM. Pincer phosphine complexes of ruthenium: formation of Ru(P-O-P)(PPh3)HCl (P-O-P = xantphos, DPEphos, (Ph2PCH2CH2)2O) and Ru(dppf)(PPh3)HCl and characterization of cationic dioxygen, dihydrogen, dinitrogen, and arene coordinated phosphine products. Inorganic Chemistry. 49: 7244-56. PMID 20575584 DOI: 10.1021/Ic100438D  0.471
2010 Davies CJ, Page MJ, Ellul CE, Mahon MF, Whittlesey MK. Ni(I) and Ni(II) ring-expanded N-heterocyclic carbene complexes: C-H activation, indole elimination and catalytic hydrodehalogenation. Chemical Communications (Cambridge, England). 46: 5151-3. PMID 20559596 DOI: 10.1039/C0Cc01335H  0.437
2010 Pridmore SJ, Slatford PA, Taylor JE, Whittlesey MK, Williams JMJ. Ru-Catalyzed Isomerization of Alkynediols and in situ Cyclization Synfacts. 2010: 92-92. DOI: 10.1055/S-0029-1218436  0.306
2010 Armstrong R, Ecott C, Mas-Marzá E, Page MJ, Mahon MF, Whittlesey MK. Ring-expanded N-heterocyclic carbene complexes of ruthenium Organometallics. 29: 991-997. DOI: 10.1021/Om901044U  0.541
2010 Ellul CE, Reed G, Mahon MF, Pascu SI, Whittlesey MK. Tripodal N-heterocyclic carbene complexes of palladium and copper: Syntheses, characterization, and catalytic activity Organometallics. 29: 4097-4104. DOI: 10.1021/Om100758X  0.34
2010 Holdroyd RS, Page MJ, Warren MR, Whittlesey MK. Intramolecular C–H insertion in ring-expanded N-heterocyclic carbenes Tetrahedron Letters. 51: 557-559. DOI: 10.1016/J.Tetlet.2009.11.090  0.317
2010 Ellul CE, Mahon MF, Whittlesey MK. Synthesis and structural characterisation of the palladium N-heterocyclic carbene cluster complexes [Pd3(μ-CO)3(NHC)3] and [Pd3(μ-SO2)3(NHC)3] Journal of Organometallic Chemistry. 695: 6-10. DOI: 10.1016/J.Jorganchem.2009.09.018  0.317
2010 Chatwin SL, Mahon MF, Prior TJ, Whittlesey MK. Reactivity of the N-heterocyclic carbene complexes [Ru(IMes)2(CO)HX] (X=OH, Cl) with alkynes Inorganica Chimica Acta. 363: 625-632. DOI: 10.1016/J.Ica.2008.11.013  0.558
2010 CRONIN L, NICASIO MC, PERUTZ RN, PETERS RG, RODDICK DM, WHITTLESEY MK. ChemInform Abstract: Laser Flash Photolysis and Matrix Isolation Studies of Ru(R2PCH2CH2PR2) 2H2 (R: C2H5, C6H5, C2F5): Control of Oxidative Addition Rates by Phosphine Substituents Cheminform. 27: no-no. DOI: 10.1002/chin.199607074  0.533
2009 Ledger AE, Mahon MF, Whittlesey MK, Williams JM. [Ru(NHC)(xantphos)(CO)H(2)] complexes: intramolecular C-H activation and applications in C-C bond formation. Dalton Transactions (Cambridge, England : 2003). 6941-7. PMID 20449134 DOI: 10.1039/B906010C  0.553
2009 Burrows AD, Harrington RW, Kirk AS, Mahon MF, Marken F, Warren JE, Whittlesey MK. Synthesis, characterization, and electrochemistry of a series of iron(II) complexes containing self-assembled 1,5-diaza-3,7-diphosphabicyclo[3.3.1]nonane ligands. Inorganic Chemistry. 48: 9924-35. PMID 19746954 DOI: 10.1021/Ic900874F  0.352
2009 Burling S, Häller LJ, Mas-Marzá E, Moreno A, Macgregor SA, Mahon MF, Pregosin PS, Whittlesey MK. The influence of N-heterocyclic carbenes (NHC) on the reactivity of [Ru(NHC)(4)H](+) with H(2), N(2), CO and O(2). Chemistry (Weinheim An Der Bergstrasse, Germany). 15: 10912-23. PMID 19746485 DOI: 10.1002/Chem.200901736  0.511
2009 Häller LJ, Mas-Marzá E, Moreno A, Lowe JP, Macgregor SA, Mahon MF, Pregosin PS, Whittlesey MK. Formation of [Ru(NHC)4(eta(2)-O2)H]+: an unusual, high frequency hydride chemical shift and facile, reversible coordination of O2. Journal of the American Chemical Society. 131: 9618-9. PMID 19601678 DOI: 10.1021/Ja9039345  0.4
2009 Ledger AE, Slatford PA, Lowe JP, Mahon MF, Whittlesey MK, Williams JM. Ruthenium xantphos complexes in hydrogen transfer processes: reactivity and mechanistic studies. Dalton Transactions (Cambridge, England : 2003). 716-22. PMID 19378565 DOI: 10.1039/B813543F  0.501
2009 Häller LJ, Page MJ, Macgregor SA, Mahon MF, Whittlesey MK. Activation of an alkyl C-H bond geminal to an agostic interaction: an unusual mode of base-induced C-H activation. Journal of the American Chemical Society. 131: 4604-5. PMID 19281174 DOI: 10.1021/Ja900953D  0.504
2009 Reade SP, Mahon MF, Whittlesey MK. Catalytic hydrodefluorination of aromatic fluorocarbons by ruthenium N-heterocyclic carbene complexes. Journal of the American Chemical Society. 131: 1847-61. PMID 19159257 DOI: 10.1021/Ja806545E  0.47
2009 Nixon TD, Whittlesey MK, Williams JM. Transition metal catalysed reactions of alcohols using borrowing hydrogen methodology. Dalton Transactions (Cambridge, England : 2003). 753-62. PMID 19156265 DOI: 10.1039/B813383B  0.373
2009 Williams J, Owston N, Nixon T, Parker A, Whittlesey M. Conversion of Primary Alcohols and Aldehydes into Methyl Esters by Ruthenium-Catalysed Hydrogen Transfer Reactions Synthesis. 2009: 1578-1581. DOI: 10.1055/S-0028-1088026  0.371
2009 Burling S, Mas-Marzá E, Valpuesta JEV, Mahon MF, Whittlesey MK. Coordination, Agostic Stabilization, and C−H Bond Activation of N-Alkyl Heterocyclic Carbenes by Coordinatively Unsaturated Ruthenium Hydride Chloride Complexes Organometallics. 28: 6676-6686. DOI: 10.1021/Om9007532  0.491
2009 Saker O, Mahon MF, Warren JE, Whittlesey MK. Sequential formation of [Ru(IPr)2(CO)H(OH2)] + and [Ru(IPr)(η6-6H6)(CO)H] + upon protonation of Ru(IPr)2(CO)H(OH) (IPr = l,3-bis(2,6- diisopropylphenyl)imidazol-2-ylidene) Organometallics. 28: 1976-1979. DOI: 10.1021/Om801150V  0.55
2009 Pridmore SJ, Slatford PA, Taylor JE, Whittlesey MK, Williams JM. Synthesis of furans, pyrroles and pyridazines by a ruthenium-catalysed isomerisation of alkynediols and in situ cyclisation Tetrahedron. 65: 8981-8986. DOI: 10.1016/J.Tet.2009.06.108  0.403
2009 Reade SP, Acton AL, Mahon MF, Martin TA, Whittlesey MK. Synthesis and Reactivity of Ru(NHC)(dppp)(CO)H2and Ru(NHC)(dppp)(CO)HF Complexes: C-H and C-F Activation European Journal of Inorganic Chemistry. 2009: 1774-1785. DOI: 10.1002/Ejic.200801105  0.574
2009 Burling S, Häller LJL, Mas-Marzá E, Moreno A, Macgregor SA, Mahon MF, Pregosin PS, Whittlesey MK. The influence of N-heterocyclic carbenes (NHC) on the reactivity of [Ru(NHC)4H]+ with H2, N2, CO and O2 Chemistry - a European Journal. 15: 10912-10923. DOI: 10.1002/chem.200901736  0.343
2008 Crittall MR, Ellul CE, Mahon MF, Saker O, Whittlesey MK. Abnormal coordination of Arduengo's carbene upon reaction with M(3)(CO)(12) (M = Ru, Os). Dalton Transactions (Cambridge, England : 2003). 4209-11. PMID 18682859 DOI: 10.1039/B807923D  0.316
2008 Chantler VL, Chatwin SL, Jazzar RF, Mahon MF, Saker O, Whittlesey MK. Stoichiometric and catalytic reactivity of the N-heterocyclic carbene ruthenium hydride complexes [Ru(NHC)(L)(CO)HCl] and [Ru(NHC)(L)(CO)H(eta2-BH4)] (L=NHC, PPh3). Dalton Transactions (Cambridge, England : 2003). 2603-14. PMID 18443704 DOI: 10.1039/B719373D  0.683
2008 Diggle RA, Kennedy AA, Macgregor SA, Whittlesey MK. Computational studies of intramolecular carbon-heteroatom bond activation of N-aryl heterocyclic carbene ligands Organometallics. 27: 938-944. DOI: 10.1021/Om701151G  0.506
2008 Diggle RA, Macgregor SA, Whittlesey MK. Computational study of C-C activation of 1,3-dimesitylimidazol-2-ylidene (IMes) at ruthenium: The role of Ligand bulk in accessing reactive intermediates Organometallics. 27: 617-625. DOI: 10.1021/Om700977F  0.493
2007 Ellul CE, Mahon MF, Saker O, Whittlesey MK. Abnormally bound N-heterocyclic carbene complexes of ruthenium: C-H activation of both c4 and c5 positions in the same ligand. Angewandte Chemie (International Ed. in English). 46: 6343-5. PMID 17631660 DOI: 10.1002/Anie.200701930  0.482
2007 Burling S, Paine BM, Nama D, Brown VS, Mahon MF, Prior TJ, Pregosin PS, Whittlesey MK, Williams JM. C-H activation reactions of ruthenium N-heterocyclic carbene complexes: application in a catalytic tandem reaction involving C-C bond formation from alcohols. Journal of the American Chemical Society. 129: 1987-95. PMID 17256931 DOI: 10.1021/Ja065790C  0.516
2007 Burrows AD, Dodds D, Kirk AS, Lowe JP, Mahon MF, Warren JE, Whittlesey MK. Substitution and derivatization reactions of a water soluble iron(II) complex containing a self-assembled tetradentate phosphine ligand. Dalton Transactions (Cambridge, England : 2003). 570-80. PMID 17225909 DOI: 10.1039/B614726G  0.365
2007 Ellul CE, Saker O, Mahon MF, Apperley DC, Whittlesey MK. Cleavage of Ru3(CO)12 by N-Heterocyclic Carbenes: Isolation of cis- and trans-Ru(NHC)2(CO)3 and Reaction with O2 To Form Ru(NHC)2(CO)2(CO3) Organometallics. 27: 100-108. DOI: 10.1021/Om700915T  0.447
2007 Reade SP, Nama D, Mahon MF, Pregosin PS, Whittlesey MK. Synthesis and Reactivity of Ru(PPh3)3(CO)HF and the N-Heterocyclic Carbene Derivatives Ru(NHC)(PPh3)2(CO)HF Organometallics. 26: 3484-3491. DOI: 10.1021/Om070164P  0.484
2007 Pridmore SJ, Slatford PA, Daniel A, Whittlesey MK, Williams JMJ. Ruthenium-Catalyzed Conversion of 1,4-Alkynediols into Pyrroles. Cheminform. 38. DOI: 10.1016/J.Tetlet.2007.05.070  0.318
2006 Burling S, Mahon MF, Powell RE, Whittlesey MK, Williams JM. Ruthenium induced C-N bond activation of an N-heterocyclic carbene: isolation of C- and N-bound tautomers. Journal of the American Chemical Society. 128: 13702-3. PMID 17044694 DOI: 10.1021/Ja065582K  0.395
2006 Ampt KA, Burling S, Donald SM, Douglas S, Duckett SB, Macgregor SA, Perutz RN, Whittlesey MK. Photochemical isomerization of N-heterocyclic carbene ruthenium hydride complexes: in situ photolysis, parahydrogen, and computational studies. Journal of the American Chemical Society. 128: 7452-3. PMID 16756294 DOI: 10.1021/Ja0622397  0.741
2006 Black PJ, Cami-Kobeci G, Edwards MG, Slatford PA, Whittlesey MK, Williams JM. Borrowing hydrogen: iridium-catalysed reactions for the formation of C-C bonds from alcohols. Organic & Biomolecular Chemistry. 4: 116-25. PMID 16358005 DOI: 10.1039/B511053J  0.367
2006 Burling S, Mahon MF, Reade SP, Whittlesey MK. Neutral and Cationic Fluorinated N-Heterocyclic Carbene Complexes of Rhodium and Iridium Organometallics. 25: 3761-3767. DOI: 10.1021/Om060324H  0.455
2006 Burling S, Douglas S, Mahon MF, Nama D, Pregosin PS, Whittlesey MK. Cationic Tris N-Heterocyclic Carbene Rhodium Carbonyl Complexes:  Molecular Structures and Solution NMR Studies Organometallics. 25: 2642-2648. DOI: 10.1021/Om060202P  0.486
2006 Chatwin SL, Davidson MG, Doherty C, Donald SM, Jazzar RFR, Macgregor SA, McIntyre CJ, Mahon MF, Whittlesey MK. H - X bond activation via hydrogen transfer to hydride in ruthenium N-heterocyclic carbene complexes: Density functional and synthetic studies Organometallics. 25: 99-110. DOI: 10.1021/Om0507427  0.722
2006 Slatford PA, Whittlesey MK, Williams JM. C–C Bond formation from alcohols using a Xantphos ruthenium complex Tetrahedron Letters. 47: 6787-6789. DOI: 10.1016/J.Tetlet.2006.07.069  0.349
2006 Jazzar RFR, Varrone M, Burrows AD, MacGregor SA, Mahon MF, Whittlesey MK. Synthesis and isomerisation of two metallated N,O-complexes of ruthenium: Models for the Murai reaction Inorganica Chimica Acta. 359: 815-820. DOI: 10.1016/J.Ica.2005.05.021  0.73
2005 Goicoechea JM, Mahon MF, Whittlesey MK, Kumar PG, Pregosin PS. Mononuclear and dinuclear complexes with a [Ru(tBu2PCH2CH2PtBu2)(CO)] core. Dalton Transactions (Cambridge, England : 2003). 588-97. PMID 15672205 DOI: 10.1039/B415812A  0.587
2005 Cami-Kobeci G, Slatford PA, Whittlesey MK, Williams JM. N-Alkylation of phenethylamine and tryptamine. Bioorganic & Medicinal Chemistry Letters. 15: 535-7. PMID 15664808 DOI: 10.1016/J.Bmcl.2004.11.050  0.327
2005 Burling S, Kociok-Köhn G, Mahon MF, Whittlesey MK, Williams JMJ. Ruthenium Hydride Complexes of 1,2-Dicyclohexylimidazol-2-ylidene Organometallics. 24: 5868-5878. DOI: 10.1021/Om050600C  0.56
2005 Douglas S, Lowe JP, Mahon MF, Warren JE, Whittlesey MK. Synthesis and structural characterisation of rhodium hydride complexes bearing N-heterocyclic carbene ligands Journal of Organometallic Chemistry. 690: 5027-5035. DOI: 10.1016/J.Jorganchem.2005.02.017  0.416
2005 Burling S, Whittlesey M, Williams J. Direct and Transfer Hydrogenation of Ketones and Imines with a Ruthenium N-Heterocyclic Carbene Complex Advanced Synthesis & Catalysis. 347: 591-594. DOI: 10.1002/Adsc.200404308  0.488
2004 Higham LJ, Whittlesey MK, Wood PT. Water-soluble hydroxyalkylated phosphines: examples of their differing behaviour toward ruthenium and rhodium. Dalton Transactions (Cambridge, England : 2003). 4202-8. PMID 15573173 DOI: 10.1039/B411701H  0.405
2004 Schott D, Callaghan P, Dunne J, Duckett SB, Godard C, Goicoechea JM, Harvey JN, Lowe JP, Mawby RJ, Müller G, Perutz RN, Poli R, Whittlesey MK. The reaction of M(CO)3(Ph2PCH2CH2PPh2)(M = Fe, Ru) with parahydrogen: probing the electronic structure of reaction intermediates and the internal rearrangement mechanism for the dihydride products. Dalton Transactions (Cambridge, England : 2003). 3218-24. PMID 15483704 DOI: 10.1039/B407457B  0.77
2004 Edwards MG, Jazzar RF, Paine BM, Shermer DJ, Whittlesey MK, Williams JM, Edney DD. Borrowing hydrogen: a catalytic route to C-C bond formation from alcohols. Chemical Communications (Cambridge, England). 90-1. PMID 14737346 DOI: 10.1039/B312162C  0.648
2004 Burling S, Mahon MF, Paine BM, Whittlesey MK, Williams JMJ. Reversible Intramolecular Alkyl C−H Bond Activation, Alcohol Dehydrogenation, and Trans−Cis Dihydride Isomerization in Ruthenium N-Heterocyclic Carbene Complexes Organometallics. 23: 4537-4539. DOI: 10.1021/Om049498U  0.48
2004 Diggle RA, Macgregor SA, Whittlesey MK. Ability of N-Heterocyclic Carbene Ligands to Promote Intermolecular Oxidative Addition Reactions at Unsaturated Ruthenium Centers Organometallics. 23: 1857-1865. DOI: 10.1021/Om034391C  0.495
2003 Chatwin SL, Diggle RA, Jazzar RF, Macgregor SA, Mahon MF, Whittlesey MK. Structure, reactivity, and computational studies of a novel ruthenium hydrogen sulfide dihydride complex. Inorganic Chemistry. 42: 7695-7. PMID 14632475 DOI: 10.1021/Ic030241I  0.736
2003 Kumar PGA, Pregosin PS, Goicoechea JM, Whittlesey MK. PGSE Diffusion Studies on Chelating Phosphine Complexes of Ruthenium(II). Solvent Dependence and Ion Pairing Organometallics. 22: 2956-2960. DOI: 10.1021/Om030145P  0.625
2003 Jazzar RFR, Bhatia PH, Mahon MF, Whittlesey MK. N-Heterocyclic Carbene Stabilizedtrans-Dihydrido Aqua and Ethanol Complexes of Ruthenium:  Precursors to Complexes with Ru−Heteroatom Bonds Organometallics. 22: 670-683. DOI: 10.1021/Om020684E  0.739
2003 Chatwin SL, Diggle RA, Jazzar RFR, Macgregor SA, Mahon MF, Whittlesey MK. Structure, Reactivity, and Computational Studies of a Novel Ruthenium Hydrogen Sulfide Dihydride Complex Inorganic Chemistry. 42: 7695-7697. DOI: 10.1021/ic030241i  0.623
2003 Chilvers M, Jazzar R, Mahon M, Whittlesey M. Reversible CH Bond Activation Reactions of theN-Heterocyclic Carbene Ligands in Ru(Ph2PCH2CH2CH2PPh2)(IMes)(CO)H2 and Ru(Ph2AsCH2CH2PPh2)(IMes)(CO)H2 (IMes=1,3-Dimesityl-1,3-dihydro-2H-imidazol-2-ylidene) Advanced Synthesis & Catalysis. 345: 1111-1114. DOI: 10.1002/Adsc.200303074  0.745
2002 Hargreaves MD, Mahon MF, Whittlesey MK. Substitution reactions of [Ru(dppe)(CO)(H(2)O)(3)][OTf](2). Inorganic Chemistry. 41: 3137-45. PMID 12054992 DOI: 10.1021/Ic020029Z  0.477
2002 Jazzar RF, Macgregor SA, Mahon MF, Richards SP, Whittlesey MK. C-C and C-H bond activation reactions in N-heterocyclic carbene complexes of ruthenium. Journal of the American Chemical Society. 124: 4944-5. PMID 11982343 DOI: 10.1021/Ja012475B  0.724
2002 Parker SF, Marsh NA, Camus LM, Whittlesey MK, Jayasooriya UA, Kearley GJ. Ethylidyne Tricobalt Nonacarbonyl:  Infrared, FT-Raman, and Inelastic Neutron Scattering Spectra The Journal of Physical Chemistry A. 106: 5797-5802. DOI: 10.1021/Jp014667Z  0.311
2001 Kirkham MS, Mahon MF, Whittlesey MK. C–F bond activation of perfluoroalkenes by ruthenium phosphine hydride complexes: X-ray crystal structures of cis-Ru(dmpe)2F(F⋯HF) and [Ru(dcpe)2H]+[(CF3)2CC(O)CF2CF3]− Chemical Communications. 813-814. DOI: 10.1039/B009862K  0.504
2001 Jazzar RFR, Mahon MF, Whittlesey MK. Synthesis and X-ray Structural Characterization of Ru(PPh3)3(CO)(C2H4) and RuH(o-C6H4C(O)CH3)(PPh3)2L (L = PPh3, CO, DMSO):  Ruthenium Complexes with Relevance to the Murai Reaction† Organometallics. 20: 3745-3751. DOI: 10.1021/Om010393Q  0.681
1999 Mahon MF, Whittlesey MK, Wood PT. Synthesis and Structures of Organometallic Aqua Complexes of Ruthenium(II) Organometallics. 18: 4068-4074. DOI: 10.1021/Om990411S  0.454
1998 Higham L, Whittlesey MK. Formation and X-ray structure of a novel water-soluble tertiary–secondary phosphine complex of ruthenium(II): [Ru{P(CH2OH)3}2{P(CH2OH)2H}2Cl2] Chemical Communications. 1107-1108. DOI: 10.1039/A801546E  0.464
1998 Macgregor SA, Eisenstein O, Whittlesey MK, Perutz RN. A theoretical study of [M(PH3)4] (M = Ru or Fe), models for the highly reactive d8 intermediates [M(dmpe)2] (dmpe = Me2PCH2CH2PMe2). Zero activation energies for addition of CO and oxidative addition of H2 Journal of the Chemical Society - Dalton Transactions. 291-300. DOI: 10.1039/A706081E  0.56
1997 Whittlesey MK, Perutz RN, Greener B, Moore MH. Synthesis, molecular structure and NMR spectroscopy of a transition-metal bifluoride complex: Formation via C-F activation or reaction with Et3N·3HF Chemical Communications. 187-188. DOI: 10.1039/A606598H  0.677
1997 Whittlesey MK, Perutz RN, Virrels IG, George MW. Low-Temperature-Matrix and Room-Temperature-Solution Photochemistry of Ru(CO)3(dmpe) (dmpe = Me2PCH2CH2PMe2)† Organometallics. 16: 268-274. DOI: 10.1021/Om960683K  0.585
1996 Ballhorn M, Partridge MG, Perutz RN, Whittlesey MK. Photochemical intermolecular C-H and C-F insertion of rhodium into pentafluoroanisole to generate a metallacycle; conversion to a cyclic carbene complex Chemical Communications. 961-962. DOI: 10.1039/Cc9960000961  0.607
1996 Whittlesey MK, Perutz RN, Moore MH. Facile intermolecular aromatic C-F bond activation reactions of [Ru(dmpe)2H2] (dmpe = Me2PCH2CH2PMe2) Chemical Communications. 787-788. DOI: 10.1039/Cc9960000787  0.686
1996 Whittlesey MK, Perutz RN, Moore MH. Facile insertion of CO2 into the Ru-H bonds of Ru(dmpe)2H2 (dmpe = Me2PCH2CH2PMe2): Identification of three ruthenium formate complexes Organometallics. 15: 5166-5169. DOI: 10.1021/Om960588B  0.65
1995 Mawby RJ, Perutz RN, Whittlesey MK. Matrix Photochemistry of Ru(CO)2(PMe3)2H2 and Ru(CO)3(PMe3)2: Formation of Ru(CO)2(PMe3)2.cntdot. .cntdot. .cntdot.S (S = Ar, CH4, Xe) Organometallics. 14: 3268-3274. DOI: 10.1021/Om00007A030  0.612
1995 Cronin L, Nicasio MC, Perutz RN, Peters RG, Roddick DM, Whittlesey MK. Laser Flash Photolysis and Matrix Isolation Studies of Ru[R2PCH2CH2PR2]2H2 (R = C2H5, C6H5, C2F5): Control of Oxidative Addition Rates by Phosphine Substituents Journal of the American Chemical Society. 117: 10047-10054. DOI: 10.1021/ja00145a016  0.531
1995 Cronin L, Nicasio MC, Perutz RN, Peters RG, Roddick DM, Whittlesey MK. Laser flash photolysis and matrix isolation studies of Ru[R2PCH2CH2PR2]2H 2 (R = C2H5, C6H5, C2F5): Control of oxidative addition rates by phosphine substituents Journal of the American Chemical Society. 117: 10047-10054. DOI: 10.1021/Ja00145A016  0.578
1994 Scaiano JC, Whittlesey MK, Berinstain AB, Malenfant PRL, Schuler RH. Pulse Radiolysis and Laser Flash Photolysis Studies of the Lignin Model .alpha.-(p-Methoxyphenoxy)-p-methoxyacetophenone and Related Compounds Chemistry of Materials. 6: 836-843. DOI: 10.1021/Cm00042A023  0.367
1993 Whittlesey MK, Mawby RJ, Osman R, Perutz RN, Field LD, Wilkinson MP, George MW. Transient and matrix photochemistry of Fe(dmpe)2H2 (dmpe = Me2PCH2CH2Me2): dynamics of C-H and H-H activation Journal of the American Chemical Society. 115: 8627-8637. DOI: 10.1021/Ja00072A016  0.624
1993 Belt ST, Scaiano JC, Whittlesey MK. Determination of metal-hydride and metal-ligand (L = CO, N2) bond energies using photoacoustic calorimetry Journal of the American Chemical Society. 115: 1921-1925. DOI: 10.1021/Ja00058A043  0.481
1992 Hall C, Jones WD, Mawby RJ, Osman R, Perutz RN, Whittlesey MK. Matrix isolation and transient photochemistry of ruthenium complex Ru(dmpe)2H2: characterization and reactivity of Ru(dmpe)2 (dmpe = Me2PCH2CH2PMe2) Journal of the American Chemical Society. 114: 7425-7435. DOI: 10.1021/Ja00045A014  0.645
1990 Perutz RN, Belt ST, McCamley A, Whittlesey MK. C—H activation by organometallics: The role of matrix isolation studies Pure and Applied Chemistry. 62: 1539-1545. DOI: 10.1351/Pac199062081539  0.574
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