Kevin H. Shaughnessy, Ph.D. - Publications

Affiliations: 
1999- Chemistry The University of Alabama, Tuscaloosa, AL 
Area:
Organometallic Chemistry, Metal-catalyzed reactions
Website:
http://bama.ua.edu/~kshaughn

66 high-probability publications. We are testing a new system for linking publications to authors. You can help! If you notice any inaccuracies, please sign in and mark papers as correct or incorrect matches. If you identify any major omissions or other inaccuracies in the publication list, please let us know.

Year Citation  Score
2022 Shaughnessy KH. Covalent Modification of Nucleobases using Water-Soluble Palladium Catalysts. Chemical Record (New York, N.Y.). e202200190. PMID 36074958 DOI: 10.1002/tcr.202200190  0.426
2020 Barnett KL, Vasiliu M, Stein TH, Delahay MV, Qu F, Gerlach DL, Dixon DA, Shaughnessy KH. Experimental and Computational Study of the Structure, Steric Properties, and Binding Equilibria of Neopentylphosphine Palladium Complexes. Inorganic Chemistry. PMID 32271012 DOI: 10.1021/Acs.Inorgchem.0C00266  0.338
2020 Shaughnessy KH. Monodentate Trialkylphosphines: Privileged Ligands in Metal-catalyzed Crosscoupling Reactions Current Organic Chemistry. 24: 231-264. DOI: 10.2174/1385272824666200211114540  0.409
2020 Hu H, Gilliam AM, Qu F, Shaughnessy KH. Enolizable Ketones as Activators of Palladium(II) Precatalysts in Amine Arylation Reactions Acs Catalysis. 10: 4127-4135. DOI: 10.1021/Acscatal.0C00221  0.513
2019 Hu H, Vasiliu M, Stein TH, Qu F, Gerlach DL, Dixon DA, Shaughnessy KH. Synthesis, Structural Characterization, and Coordination Chemistry of (Trineopentylphosphine)palladium(aryl)bromide Dimer Complexes ([(NpP)Pd(Ar)Br]). Inorganic Chemistry. PMID 31553584 DOI: 10.1021/Acs.Inorgchem.9B02164  0.455
2019 Hartwig JF, Shaughnessy KH, Shekhar S, Green RA. Palladium‐Catalyzed Amination of Aryl Halides Organic Reactions. 853-958. DOI: 10.1002/0471264180.Or100.14  0.726
2018 Barnett KL, Howard JR, Treager CJ, Shipley AT, Stullich RM, Qu F, Gerlach DL, Shaughnessy KH. Air-Stable [(R3P)PdCl2]2 Complexes of Neopentylphosphines as Cross-Coupling Precatalysts: Catalytic Application and Mechanism of Catalyst Activation and Deactivation Organometallics. 37: 1410-1424. DOI: 10.1021/Acs.Organomet.8B00082  0.547
2017 Hu H, Qu F, Gerlach DL, Shaughnessy KH. Mechanistic Study of the Role of Substrate Steric Effects and Aniline Inhibition on the Bis(trineopentylphosphine)palladium(0)-Catalyzed Arylation of Aniline Derivatives Acs Catalysis. 7: 2516-2527. DOI: 10.1021/Acscatal.7B00024  0.543
2017 Kotbagi TV, Shaughnessy KH, LeDoux C, Cho H, Tay-Agbozo S, Zee Jv, Bakker MG. Copolymerization of transition metal salen complexes and conversion into metal nanoparticles supported on hierarchically porous carbon monoliths: a one pot synthesis Journal of Sol-Gel Science and Technology. 84: 258-273. DOI: 10.1007/S10971-017-4510-0  0.308
2016 Lauer MG, Headford BR, Gobble OM, Weyhaupt MB, Gerlach DL, Zeller M, Shaughnessy KH. A Trialkylphosphine-Derived Palladacycle as a Catalyst in the Selective Cross-Dimerization of Terminal Arylacetylenes with Terminal Propargyl Alcohols and Amides Acs Catalysis. 6: 5834-5842. DOI: 10.1021/Acscatal.6B01541  0.47
2015 Shaughnessy KH. Palladium-catalyzed modification of unprotected nucleosides, nucleotides, and oligonucleotides. Molecules (Basel, Switzerland). 20: 9419-54. PMID 26007192 DOI: 10.3390/Molecules20059419  0.477
2015 Semmes JG, Bevans SL, Mullins CH, Shaughnessy KH. Arylation of diethyl malonate and ethyl cyanoacetate catalyzed by palladium/di-tert-butylneopentylphosphine Tetrahedron Letters. 56: 3447-3450. DOI: 10.1016/J.Tetlet.2015.01.072  0.542
2015 Moore JN, Laskay NM, Duque KS, Kelley SP, Rogers RD, Shaughnessy KH. Synthesis of 4-sulfonatobenzylphosphines and their application in aqueous-phase palladium-catalyzed cross-coupling Journal of Organometallic Chemistry. 777: 16-24. DOI: 10.1016/J.Jorganchem.2014.11.011  0.732
2015 Moore JN, Laskay NM, Duque KS, Kelley SP, Rogers RD, Shaughnessy KH. ChemInform Abstract: Synthesis of 4-Sulfonatobenzylphosphines and Their Application in Aqueous-Phase Palladium-Catalyzed Cross-Coupling. Cheminform. 46: no-no. DOI: 10.1002/CHIN.201522123  0.338
2015 Sabio JC, Domier RC, Moore JN, Shaughnessy KH, Hartman RL. Palladium Theory of Aqueous-Phase Heck Alkynylations for Intensification of Discovery and Manufacture Chemical Engineering and Technology. 38: 1717-1725. DOI: 10.1002/Ceat.201500117  0.61
2014 Lauer MG, Thompson MK, Shaughnessy KH. Controlling olefin isomerization in the heck reaction with neopentyl phosphine ligands. The Journal of Organic Chemistry. 79: 10837-48. PMID 25333873 DOI: 10.1021/Jo501840U  0.556
2014 Bhattarai BT, Adhikari S, Kimball EA, Moore JN, Shaughnessy KH, Snowden TS, Fronczek FR, Dolliver DD. Palladium-catalyzed ortho-halogenation of diaryl oxime ethers Tetrahedron Letters. 4801-4806. DOI: 10.1016/J.Tetlet.2014.06.080  0.649
2014 Raders SM, Jones JM, Semmes JG, Kelley SP, Rogers RD, Shaughnessy KH. Di-tert-butylneopentylphosphine (DTBNpP): An efficient ligand in the palladium-catalyzed α-arylation of ketones European Journal of Organic Chemistry. 2014: 7395-7404. DOI: 10.1002/Ejoc.201402474  0.837
2013 Raders SM, Moore JN, Parks JK, Miller AD, Leißing TM, Kelley SP, Rogers RD, Shaughnessy KH. Trineopentylphosphine: a conformationally flexible ligand for the coupling of sterically demanding substrates in the Buchwald-Hartwig amination and Suzuki-Miyaura reaction. The Journal of Organic Chemistry. 78: 4649-64. PMID 23638733 DOI: 10.1021/Jo400435Z  0.829
2013 Dolliver DD, Bhattarai BT, Pandey A, Lanier ML, Bordelon AS, Adhikari S, Dinser JA, Flowers PF, Wills VS, Schneider CL, Shaughnessy KH, Moore JN, Raders SM, Snowden TS, McKim AS, et al. Stereospecific Suzuki, Sonogashira, and Negishi coupling reactions of N-alkoxyimidoyl iodides and bromides. The Journal of Organic Chemistry. 78: 3676-87. PMID 23534335 DOI: 10.1021/Jo400179U  0.82
2013 Domier RC, Moore JN, Shaughnessy KH, Hartman RL. Kinetic analysis of aqueous-phase Pd-catalyzed, Cu-free direct arylation of terminal alkynes using a hydrophilic ligand Organic Process Research and Development. 17: 1262-1271. DOI: 10.1021/Op4001274  0.676
2013 Shaughnessy KH. Cross-Coupling Reactions in Aqueous Media Palladium-Catalyzed Coupling Reactions: Practical Aspects and Future Developments. 235-286. DOI: 10.1002/9783527648283.ch7  0.354
2012 Cho JH, Shaughnessy KH. Aqueous-phase Sonogashira alkynylation to synthesize 5-substituted pyrimidine and 8-substituted purine nucleosides. Current Protocols in Nucleic Acid Chemistry / Edited by Serge L. Beaucage ... [Et Al.]. Unit1.27. PMID 22700334 DOI: 10.1002/0471142700.Nc0127S49  0.607
2011 Cho JH, Shaughnessy KH. Aqueous-phase heck coupling of 5-iodouridine and alkenes under phosphine-free conditions Synlett. 2963-2966. DOI: 10.1055/S-0031-1289886  0.677
2010 Hill LL, Crowell JL, Tutwiler SL, Massie NL, Hines CC, Griffin ST, Rogers RD, Shaughnessy KH, Grasa GA, Johansson Seechurn CC, Li H, Colacot TJ, Chou J, Woltermann CJ. Synthesis and X-ray structure determination of highly active Pd(II), Pd(I), and Pd(0) complexes of di(tert-butyl)neopentylphosphine (DTBNpP) in the arylation of amines and ketones. The Journal of Organic Chemistry. 75: 6477-88. PMID 20806983 DOI: 10.1021/Jo101187Q  0.675
2010 Craciun R, Vincent AJ, Shaughnessy KH, Dixon DA. Prediction of reliable metal-PH3 bond energies for Ni, Pd, and Pt in the 0 and +2 oxidation states. Inorganic Chemistry. 49: 5546-53. PMID 20438058 DOI: 10.1021/Ic1004853  0.366
2010 Hyung Cho J, Prickett CD, Shaughnessy KH. Efficient sonogashira coupling of unprotected halonucleosides in aqueous solvents using water-soluble palladium catalysts European Journal of Organic Chemistry. 3678-3683. DOI: 10.1002/Ejoc.201000313  0.573
2010 SHAUGHNESSY KH, WAYMOUTH RM. ChemInform Abstract: Carbometalation of α,ω-Dienes and Olefins Catalyzed by Zirconocenes. Cheminform. 26: no-no. DOI: 10.1002/CHIN.199539096  0.46
2009 Vongsutilers V, Daft JR, Shaughnessy KH, Gannett PM. A general synthesis of C8-arylpurine phosphoramidites. Molecules (Basel, Switzerland). 14: 3339-52. PMID 19783928 DOI: 10.3390/Molecules14093339  0.429
2009 Shaughnessy KH. Hydrophilic ligands and their application in aqueous-phase metal-catalyzed reactions. Chemical Reviews. 109: 643-710. PMID 19152291 DOI: 10.1021/Cr800403R  0.396
2008 Brown WS, Boykin DD, M. Quentin Sonnier Jr., William DC, Brown FV, Shaughnessy KH. Sterically demanding, zwitterionic trialkylphosphonium sulfonates as air-stable ligand precursors for efficient palladium-catalyzed cross-couplings of aryl bromides and chlorides Synthesis. 1965-1970. DOI: 10.1055/S-2008-1067095  0.586
2008 Moore LR, Western EC, Craciun R, Spruell JM, Dixon DA, O'Halloran KP, Shaughnessy KH. Sterically demanding, sulfonated, triarylphosphines: Application to palladium-catalyzed cross-coupling, steric and electronic properties, and coordination chemistry Organometallics. 27: 576-593. DOI: 10.1021/Om7008606  0.798
2008 Hill LL, Smith JM, Brown WS, Moore LR, Guevera P, Pair ES, Porter J, Chou J, Wolterman CJ, Craciun R, Dixon DA, Shaughnessy KH. Neopentylphosphines as effective ligands in palladium-catalyzed cross-couplings of aryl bromides and chlorides Tetrahedron. 64: 6920-6934. DOI: 10.1016/J.Tet.2008.02.037  0.818
2008 Moore LR, Western EC, Craciun R, Spruell JM, Dixon DA, O'Halloran KP, Shaughnessy KH. ChemInform Abstract: Sterically Demanding, Sulfonated, Triarylphosphines: Application to Palladium-Catalyzed Cross-Coupling, Steric and Electronic Properties, and Coordination Chemistry. Cheminform. 39. DOI: 10.1002/chin.200829089  0.674
2008 Shaughnessy K. Comprehensive Organic Reactions in Aqueous Media. 2nd ed. By Chao-Jun Li and Tak-Hang Chan. Angewandte Chemie International Edition. 47: 1988-1988. DOI: 10.1002/Anie.200785542  0.334
2008 Shaughnessy K. Comprehensive Organic Reactions in Aqueous Media. 2. Ausg. Von Chao-Jun Li und Tak-Hang Chan. Angewandte Chemie. 120: 2014-2014. DOI: 10.1002/Ange.200785542  0.344
2007 Cho JH, Brown FV, Shaughnessy KH. A selective and tin-free Pd-catalyzed phenylselenylation of aryl bromides Main Group Chemistry. 6: 201-214. DOI: 10.1080/10241220801967367  0.621
2006 Hill LL, Moore LR, Huang R, Craciun R, Vincent AJ, Dixon DA, Chou J, Woltermann CJ, Shaughnessy KH. Bulky alkylphosphines with neopentyl substituents as ligands in the amination of aryl bromides and chlorides. The Journal of Organic Chemistry. 71: 5117-25. PMID 16808497 DOI: 10.1021/Jo060303X  0.831
2006 Moore LR, Cooks SM, Anderson MS, Schanz HJ, Griffin ST, Rogers RD, Kirk MC, Shaughnessy KH. Synthesis and characterization of water-soluble silver and palladium imidazol-2-ylidene complexes with noncoordinating anionic substituents Organometallics. 25: 5151-5158. DOI: 10.1021/Om060552B  0.672
2006 Huang R, Shaughnessy KH. Water-soluble palladacycles as precursors to highly recyclable catalysts for the Suzuki coupling of aryl bromides in aqueous solvents Organometallics. 25: 4105-4112. DOI: 10.1021/Om050940Y  0.707
2006 Shaughnessy KH. Cover Picture: Beyond TPPTS: New Approaches to the Development of Efficient Palladium-Catalyzed Aqueous-Phase Cross-Coupling Reactions (Eur. J. Org. Chem. 8/2006) European Journal of Organic Chemistry. 2006: 1817-1817. DOI: 10.1002/Ejoc.200690016  0.529
2006 Shaughnessy KH. Beyond TPPTS: New approaches to the development of efficient palladium-catalyzed aqueous-phase cross-coupling reactions European Journal of Organic Chemistry. 1827-1835. DOI: 10.1002/Ejoc.200500972  0.591
2005 Huang R, Shaughnessy KH. t-Bu-Amphos-RhCl3.3H2O: a highly recyclable catalyst system for the cross-coupling of aldehydes and aryl- and alkenylboronic acids in aqueous solvents. Chemical Communications (Cambridge, England). 4484-6. PMID 16136259 DOI: 10.1039/B509406B  0.665
2005 Western EC, Shaughnessy KH. Inhibitory effects of the guanine moiety on Suzuki couplings of unprotected halonucleosides in aqueous media. The Journal of Organic Chemistry. 70: 6378-88. PMID 16050700 DOI: 10.1021/Jo050832L  0.809
2005 Shaughnessy KH, DeVasher RB. Palladium-catalyzed cross-coupling in aqueous media: Recent progress and current applications Current Organic Chemistry. 9: 585-604. DOI: 10.2174/1385272053765042  0.786
2005 DeVasher RB, Spruell JM, Dixon DA, Broker GA, Griffin ST, Rogers RD, Shaughnessy KH. Experimental and computational study of steric and electronic effects on the coordination of bulky, water-soluble alkylphosphines to palladium under reducing conditions: Correlation to catalytic activity Organometallics. 24: 962-971. DOI: 10.1021/Om049241W  0.809
2005 Klingshirn MA, Rogers RD, Shaughnessy KH. Palladium-catalyzed hydroesterification of styrene derivatives in the presence of ionic liquids Journal of Organometallic Chemistry. 690: 3620-3626. DOI: 10.1016/J.Jorganchem.2005.05.031  0.388
2005 P'Pool SJ, Klingshirn MA, Rogers RD, Shaughnessy KH. Kinetic study of the oxidative addition of methyl iodide to Vaska's complex in ionic liquids Journal of Organometallic Chemistry. 690: 3522-3528. DOI: 10.1016/J.Jorganchem.2005.02.024  0.765
2005 Sliger MD, P'Pool SJ, Traylor RK, McNeill J, Young SH, Hoffman NW, Klingshirn MA, Rogers RD, Shaughnessy KH. Promoting effect of ionic liquids on ligand substitution reactions Journal of Organometallic Chemistry. 690: 3540-3545. DOI: 10.1016/J.Jorganchem.2005.02.018  0.719
2005 Sliger MD, Broker GA, Griffin ST, Rogers RD, Shaughnessy KH. Di-t-butyl(ferrocenylmethyl)phosphine: Air-stability, structural characterization, coordination chemistry, and application to palladium-catalyzed cross-coupling reactions Journal of Organometallic Chemistry. 690: 1478-1486. DOI: 10.1016/J.Jorganchem.2004.12.022  0.792
2005 Sliger MD, Broker GA, Giffin ST, Rogers RD, Shaughnessy KH. Di-t-butyl(ferrocenylmethyl)phosphine: Air-Stability, Structural Characterization, Coordination Chemistry, and Application to Palladium-Catalyzed Cross-Coupling Reactions. Cheminform. 36. DOI: 10.1002/chin.200531101  0.38
2004 DeVasher RB, Moore LR, Shaughnessy KH. Aqueous-phase, palladium-catalyzed cross-coupling of aryl bromides under mild conditions, using water-soluble, sterically demanding alkylphosphines. The Journal of Organic Chemistry. 69: 7919-27. PMID 15527271 DOI: 10.1021/Jo048910C  0.824
2004 Moore LR, Shaughnessy KH. Efficient aqueous-phase Heck and Suzuki couplings of aryl bromides using tri(4,6-dimethyl-3- sulfonatophenyl)phosphine trisodium salt (TXPTS). Organic Letters. 6: 225-8. PMID 14723534 DOI: 10.1021/Ol0360288  0.761
2003 Western EC, Daft JR, Johnson EM, Gannett PM, Shaughnessy KH. Efficient one-step Suzuki arylation of unprotected halonucleosides, using water-soluble palladium catalysts. The Journal of Organic Chemistry. 68: 6767-74. PMID 12919046 DOI: 10.1021/Jo034289P  0.818
2002 Klingshirn MA, Broker GA, Holbrey JD, Shaughnessy KH, Rogers RD. Polar, non-coordinating ionic liquids as solvents for the alternating copolymerization of styrene and CO catalyzed by cationic palladium catalysts. Chemical Communications (Cambridge, England). 1394-5. PMID 12125572 DOI: 10.1039/B203367D  0.419
2002 Shaughnessy KH, Huang R. Acid-mediated, chromium-catalyzed allylation of aldehydes Synthetic Communications. 32: 1923-1928. DOI: 10.1081/Scc-120004841  0.649
2001 Shaughnessy KH, Booth RS. Sterically demanding, water-soluble alkylphosphines as ligands for high activity Suzuki coupling of aryl bromides in aqueous solvents. Organic Letters. 3: 2757-9. PMID 11506627 DOI: 10.1021/ol0163629  0.523
2001 Stambuli JP, Stauffer SR, Shaughnessy KH, Hartwig JF. Screening of homogeneous catalysts by fluorescence resonance energy transfer. Identification of catalysts for room-temperature Heck reactions. Journal of the American Chemical Society. 123: 2677-8. PMID 11456943 DOI: 10.1021/ja0058435  0.74
1999 Hartwig JF, Kawatsura M, Hauck SI, Shaughnessy KH, Alcazar-Roman LM. Room-Temperature Palladium-Catalyzed Amination of Aryl Bromides and Chlorides and Extended Scope of Aromatic C-N Bond Formation with a Commercial Ligand. The Journal of Organic Chemistry. 64: 5575-5580. PMID 11674624 DOI: 10.1021/Jo990408I  0.818
1999 Shaughnessy KH, Kim P, Hartwig JF. A fluorescence-based assay for high-throughput screening of coupling reactions. Application to Heck chemistry Journal of the American Chemical Society. 121: 2123-2132. DOI: 10.1021/Ja983419M  0.571
1998 Shaughnessy KH, Waymouth RM. Enantio- and diastereoselective catalytic carboalumination of 1-alkenes and α,ω-dienes with cationic zirconocenes: Scope and mechanism Organometallics. 17: 5728-5745. DOI: 10.1021/Om9807811  0.612
1998 Shaughnessy KH, Hamann BC, Hartwig JF. Palladium-Catalyzed Inter- and Intramolecular α-Arylation of Amides. Application of Intramolecular Amide Arylation to the Synthesis of Oxindoles The Journal of Organic Chemistry. 63: 6546-6553. DOI: 10.1021/Jo980611Y  0.648
1998 Shaughnessy KH, Hamann BC, Hartwig JF. Palladium-Catalyzed Inter- and Intramolecular α-Arylation of Amides. Application of Intramolecular Amide Arylation to the Synthesis of Oxindoles Journal of Organic Chemistry. 63: 6546-6553.  0.32
1997 Shaughnessy KH, Waymouth RM. Regioselective Cyclocarboxylation of Nonconjugated Dienes to Cyclic Keto Esters Organometallics. 16: 1001-1007. DOI: 10.1021/Om9607513  0.567
1995 Shaughnessy KH, Waymouth RM. Carbometalation of .alpha.,.omega.-Dienes and Olefins Catalyzed by Zirconocenes Journal of the American Chemical Society. 117: 5873-5874. DOI: 10.1021/Ja00126A036  0.493
1993 Zhu L, Shaughnessy KH, Rieke RD. A facile method for the preparation of functionalized 2-halo-1-olefins Synthetic Communications. 23: 525-529. DOI: 10.1080/00397919308009808  0.397
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